CN106538571A - The bactericidal composition and its application of a kind of containing fluopyram and zineb - Google Patents
The bactericidal composition and its application of a kind of containing fluopyram and zineb Download PDFInfo
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- CN106538571A CN106538571A CN201510594378.3A CN201510594378A CN106538571A CN 106538571 A CN106538571 A CN 106538571A CN 201510594378 A CN201510594378 A CN 201510594378A CN 106538571 A CN106538571 A CN 106538571A
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- zineb
- fluopyram
- bactericidal composition
- containing fluopyram
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Abstract
The invention discloses the bactericidal composition and its application of a kind of containing fluopyram and zineb.The bactericidal composition of a kind of containing fluopyram and zineb,, with fluopyram and zineb as main active, the weight ratio of described fluopyram and zineb is 1～70 for it：1～50.The invention also discloses application of the bactericidal composition on preventing and treating resistance plant fungal disease medicine is prepared, can be applicable to prevent and treat Cereal, fruit tree, vegetable disease, with higher synergistic function, overcome and delayed the Drug resistance of pathogenic bacteria, sterilization speed is fast, lasting period length, reduce application cost, and prevention effect is substantially better than its single dose and uses.The present invention can be used for preventing and treating the fungal disease on crops, it is particularly possible to which, for preventing and treating the fungal diseases such as gray mold, rust, powdery mildew, downy mildew, early blight, late blight, anthrax, effect is better than single dose use.
Description
Technical field
The present invention relates to a kind of bactericidal composition and application thereof, the especially bactericidal composition of a kind of containing fluopyram and zineb
And its application.
Background technology
Fluopyram (Fluopyram), molecular formula：C16H11ClF6N2O, chemical name：N- [2- [chloro- 5- (the fluoroforms of 3-
Base) -2- pyridines] ethyl] -2- (trifluoromethyl) Benzoylamide, structural formula：
Fluopyram is a kind of new pyridine ethyl benzamide series bactericidal agent, by hindering succinate dehydrogenase in respiratory chain
Electron transfer and suppress mitochondrial respiratory.It is mainly used on broad leaf crop, preventing and treating the microbial disease of capsule, to Fructus Cucumidis sativi, Cucurbita pepo L. etc.
Downy mildew, powdery mildew on vegetable, downy mildew of fruit tree etc. cause multiple diseases to have favorable effect by pathogenic bacteria.
Zineb (Zineb), sterling are white powder, and odorless, industrial goods are in canescence or faint yellow, have foreign odor.Without molten
Point.Vapour pressure<0.0lMPa(20℃).In room temperature water, dissolubility is 10mg/L, insoluble in most of organic solvents, but can be dissolved in
Pyridine.It is unstable to light, heat, dampness, easily decompose, meet alkaline matter or cupric, the material of hydrargyrum, also easily decompose.Molecule
Formula：C4H6N2S4Zn, chemical name：Ethylene is double (zinc dithiocarbamate), chemical structural formula：
Zineb is protectiveness organosulfureous fungicide, can prevent and treat various fungus-caused diseases, but act on poor to powdery mildew, preventing and treating
Target, late blight, Fructus Lycopersici esculenti early blight, late blight, spot blight, leaf mold, anthrax, gray mold, Fructus Solani melongenae
Cotton disease, Phomopisis vexans, Chinese cabbage, Radix Raphani, cabbage downy mildew, melasma, leukoderma, soft rot, black rot, melon anthrax
Disease, downy mildew, epidemic disease, blight dis-ease, Fructus Benincasae silk floss epidemic disease, beans anthrax, brown spot, rust etc..
The difficulty of prevention and cure of phytopathogen is increasing at present, on the one hand, with economy such as the change of pattern of farming, melon fruits and vegetables
Crops planting area progressively expands, and disease occurrence degree, generation quantity increase, and in preventing and treating, difficulty is increased；The opposing party
Face, the resistance of pathogen rise under lasting medicament selection pressure year by year, and the prevention effect of single dose is had a greatly reduced quality, plant disease
Preventing and treating is faced with significant challenge.
The content of the invention
The purpose of the present invention is to provide a kind of applied widely, low cost, effect good fluorine-containing pyrrole bacterium acyl for above-mentioned technical problem
The plant bactericidal composition of amine and zineb.
The purpose of the present invention is realized by following measures：
A kind of bactericidal composition of containing fluopyram and zineb, it with fluopyram and zineb as main active,
The weight ratio of described fluopyram and zineb is 1～70：1～50, wherein in bactericidal composition, active ingredient is with potentiation
Effective dose is present in compositionss.
In bactericidal composition of the present invention, the weight ratio preferably 5～50 of described fluopyram and zineb：10～
50, more preferably 5～40：10～45, most preferably 1：1～9.
In bactericidal composition of the present invention, both described fluopyram and zineb account for the weight percent of compositionss and contain
Measure as 2～80%, preferably 5.5～70%.
Described bactericidal composition is re-dubbed with fluopyram and zineb as main active with known auxiliary agent and excipient
Any one dosage form allowed on pesticide.Known to these, auxiliary agent, excipient have dispersant, diffusant, defoamer, moistening
Agent, disintegrating agent etc., can be using to methoxyl group fatty acyl amido benzene sulfonic acid sodium salt, sodium methylene bis-naphthalene sulfonate, detergent alkylate sulphur
Sour calcium, alkylphenol polyoxyethylene, alkylaryl polyoxyethylene polyoxypropylene ether again, Ben-zylphenol Polyoxyethyl Ether, phenethyl phenol are gathered
Oxygen vinyl Ether, three phenethyl phenol polyoxyethylene ether phosphates, fatty alcohol-polyoxyethylene ether and its similar products, fatty amine polyoxy second
Alkene ether, fatty acid ethylene oxide addition product, polyoxyethylene polyoxypropylene block compound, castor oil polyoxyethylene ether, nonyl phenol
Polyoxyethylene ether, TWEEN Series, Polyethylene Glycol series, Sulfonateses, carboxylate, sulfate, phosphate, phosphite,
One or more combinations in lignosulfonates, xanthan gum, phenol formaldehyde condensate, ammonium salt, quaternary etc., excipient bag
Include Ketohexamethylene, dimethylbenzene, various solvent naphthas, water, antifreezing agent (such as Propylene Glycol), deionized water etc..Above auxiliary agent, figuration
Agent and other adjuvants can be with alone or be used in combination.
Described dosage form is cream, wettable powder, suspending agent, aqueous emulsion, microemulsion or water dispersion granule.
It is a still further object of the present invention to provide the bactericidal composition is preparing the fungus-caused fungal disease medicine of preventing and treating resistance plant
On application.Preferably, described bactericidal composition is preparing preventing and treating Cereal, fruit tree, vegetable crop refractory fungal disease medicine
The application in object space face, especially prevents and treats gray mold, rust, powdery mildew, downy mildew, early blight, late blight, anthrax in preparation
Application on the fungal disease medicine such as disease, the most preferably application on preventing and treating pepper anthracnose medicine is prepared.Described Bactericidal composite
Thing is respectively provided with significant effect to above-mentioned resistance plant fungal disease, can produce higher synergistic function.
Compared with prior art, beneficial effects of the present invention：
(1), compared with single dose, the bactericidal composition scope of application of the present invention increases, and expands preventing and treating spectrum, it is adaptable to prevent and treat cereal
Class, fruit tree, the refractory fungal disease of vegetable, have preventing and treating effect well to ascomycetess, basidiomycetes, Fungi Imperfecti fungal disease
Really, it is particularly suitable for preventing and treating gray mold, rust, powdery mildew, downy mildew, early blight, late blight, anthrax, is respectively provided with
Significant effect, can produce higher synergistic function.
(2), compared with single dose, overcome and delayed Drug resistance, funguses can be suppressed to unitary agent (fluopyram and generation
Gloomy zinc is arbitrary) drug-fast generation, alternative routine and be also easy to produce the pesticide of resistance.
(3), the consumption of the amount ratio independent reactive compound of bactericidal composition of the present invention is substantially reduced, i.e. the activity of mixture is big
In the activity of independent component, compared with single dose, preventing and treating recruitment, drug cost are reduced.
Specific embodiment
With reference to embodiments technical scheme is described further, two kinds of reactive compounds can be processed into permission
Any one dosage form, but the preparation that can process of the two kinds of active components be not limited only to it is set forth below.The system of dosage form in embodiment
Preparation Method is conventional method.
" % " of the present invention is weight percentage.
Embodiment 1
Weigh fluopyram 5g, zineb 10g, detergent LS (to methoxyl group fatty acyl amido benzene sulfonic acid sodium salt) 2g, expansion
Powder NNO (sodium methylene bis-naphthalene sulfonate) 4g, white carbon 5g, Kaolin add to 100g, and mixture carries out comminution by gas stream,
Prepared effective ingredient weight percentage is 15% fluopyram-Zineb wettable powder.
Embodiment 2
Fluopyram 3g, zineb 12g, sodium lauryl sulphate 3g, dispersing agent NNO 4g, white carbon 5g are weighed, it is high
Ridge soil adds to 100g, and mixture carries out comminution by gas stream, and it is 15% fluopyram-generation that effective ingredient weight percentage is obtained
Gloomy zinc wettable powder.
Embodiment 3
Fluopyram 2g, zineb 18g, sodium lauryl sulphate 3g, dispersing agent NNO 4g, white carbon 5g are weighed, it is high
Ridge soil adds to 100g, and mixture carries out comminution by gas stream, and it is 20% fluopyram-generation that effective ingredient weight percentage is obtained
Gloomy zinc wettable powder.
Embodiment 4
Weigh fluopyram 5g, zineb 50g, three phenethyl phenol polyoxyethylene ether phosphate 3g, agriculture breast 33# (alkyl
Aryl polyoxyethylene polyoxypropylene ether) 2g, alkylphenol polyoxyethylene 1g, 150# solvent naphtha 13g, add water to 100g.Will
Above raw material routinely prepares the method input mixing kettle high speed mixing of aqueous emulsion, and making effective Ingredients Weight percentage composition is
55% fluopyram-zineb aqueous emulsion.
Embodiment 5
Weigh fluopyram 2g, zineb 30g, calcium dodecyl benzene sulfonate 6g, three phenethyl phenol polyoxyethylene ether phosphates
3g, agriculture breast 33#2g, alkylphenol polyoxyethylene 1g, isopropanol 10g, add water to 100g.Above raw material is routinely matched somebody with somebody
Mix in the method input mixing kettle of microemulsion processed, effective Ingredients Weight percentage composition is made for 32% fluopyram-zineb
Microemulsion.
Embodiment 6
Weigh fluopyram 1g, zineb 5g, three phenethyl phenol polyoxyethylene ether phosphate 3g, agriculture breast 33#2g, alkyl
Phenol polyethenoxy ether 1g, 150# solvent naphtha 13g, adds water to 100g.The method that above raw material routinely prepares aqueous emulsion is thrown
Enter the mixing of mixing kettle high speed, effective Ingredients Weight percentage composition is made for 6% fluopyram-zineb aqueous emulsion.
Embodiment 7
Weigh fluopyram 50g, zineb 20g, calcium dodecyl benzene sulfonate 5g, phenethyl phenol polyethenoxy ether 2g, castor
Oleum Sesami polyoxyethylene ether 2g, plus 150# solvent naphthas are to 100g.Above raw material is routinely prepared into the method input mixing kettle of cream
Middle mixing, makes effective Ingredients Weight percentage composition for 70% fluopyram-zineb cream.
Embodiment 8
Fluopyram 2g, zineb 40g, calcium dodecyl benzene sulfonate 8g, phenethyl phenol polyethenoxy ether 5g are weighed, plus
150# solvent naphthas are to 100g.Mix in the method input mixing kettle that above raw material is routinely prepared cream, make effective ingredient
Weight percentage is 42% fluopyram-zineb cream.
Embodiment 9
Weigh fluopyram 5g, zineb 20g, calcium dodecyl benzene sulfonate 6g, three phenethyl phenol polyethenoxy ether phosphoric acid
Ester 3g, agriculture breast 33#2g, alkylphenol polyoxyethylene 1g, isopropanol 10g, add water to 100g.By above raw material routinely
Mix in the method input mixing kettle for preparing microemulsion, effective Ingredients Weight percentage composition is made for 25% fluopyram-Dai Sen
Zinc microemulsion.
Embodiment 10
Fluopyram 5g, zineb 0.5g, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether 7g are weighed, plus
150# solvent naphthas are to 100g.Mix in the method input mixing kettle that above raw material is routinely prepared cream, make effective ingredient
Weight percentage is 5.5% fluopyram-zineb cream.
Embodiment 11
Fluopyram 5g, zineb 30g, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 4g are weighed, plus
150# solvent naphthas are to 100g.Mix in the method input mixing kettle that above raw material is routinely prepared cream, make effective ingredient
Weight percentage is 35% fluopyram-zineb cream.
Embodiment 12
Weigh fluopyram 10g, zineb 10g, lignin 2g, polyoxyethylene poly-oxygen propylene aether 4g, xanthan gum
0.15g, ethylene glycol 5g, siloxanes 0.10g, aluminium-magnesium silicate 0.5g, complement to 100g with water, make in the presence of sand mill
It is 20% fluopyram-zineb suspending agent into effective ingredient weight percentage.
Embodiment 13
Weigh fluopyram 30g, zineb 12g, lignin 2g, polyoxyethylene poly-oxygen propylene aether 4g, xanthan gum
0.15g, ethylene glycol 5g, siloxanes 0.10g, aluminium-magnesium silicate 0.5g, complement to 100g with water, make in the presence of sand mill
It is 42% fluopyram-zineb suspending agent into effective ingredient weight percentage.
Embodiment 14
Weigh fluopyram 2g, zineb 5g, sodium lignin sulfonate 8g, sodium lauryl sulphate 2g, ammonium sulfate 5g,
Polyvinyl alcohol 5g, Borax 2g, white carbon 3g, kieselguhr complement to 100g, and above raw material is pressed water dispersible granular agent method system
It is 7% fluopyram-zineb water dispersion granule into effective ingredient weight percentage.
Embodiment 15
Weigh fluopyram 4g, zineb 13g, sodium lignin sulfonate 8g, sodium lauryl sulphate 2g, ammonium sulfate 5g,
Polyvinyl alcohol 5g, Borax 2g, kieselguhr complement to 100g, and above raw material is formed with imitating into by water dispersible granular agent method
Weight percentage is divided to be 17% fluopyram-zineb water dispersion granule.
Embodiment 16
Weigh fluopyram 5g, zineb 15g, lignin 2g, polyoxyethylene poly-oxygen propylene aether 4g, xanthan gum 0.15g,
Ethylene glycol 5g, siloxanes 0.10g, aluminium-magnesium silicate 0.5g, complement to 100g with water, make in the presence of sand mill effectively into
Weight percentage is divided to be 20% fluopyram-zineb suspending agent.
Embodiment 17
Indoor biometricses are tested：
Mycelial growth rate method is adopted indoors, determines different agents to pepper anthracnose bacterial strain (Colletrichum Capsici
(Syd.) Butl.) EC50Value, using co-toxicity coefficient computational methods, calculates the co-toxicity coefficient (CTC) of mixture, it is determined that mixed
Agent it is building performance, circular is as follows：
With in mixture, a certain single dose (generally selects EC as standard agent50Junior), calculated：
Single dose toxicity index=standard agent EC50/ certain single dose EC50×100
Toxicity index × the B of the toxicity index of theoretical toxicity index=A single doses × A single doses proportion+B single doses in mixture is mono-
Agent proportion in mixture
The EC of actual measurement toxicity index=standard single dose50The EC of value/mixture50Value × 100
Co-toxicity coefficient=actual measurement toxicity index/theoretical toxicity index × 100
Co-toxicity coefficient is classified：When CTC is more than 120, mixture has synergetic, and CTC exists for antagonism, CTC when being less than 80
It is summation action between 80-120.
Table 1：Indoor biometricses result of the fluopyram+zineb different ratio to pepper anthracnose bacterial strain
| Medicament | Virulence regression equation | EC50(mg/L) | Co-toxicity coefficient |
| Fluopyram (A) | Y=1.42X+7.48 | 0.018 | - |
| Zineb (B) | Y=2.60X+4.18 | 2.065 | - |
| A:B=80:1 | Y=1.11X+4.58 | 2.389 | 87.52 |
| A:B=1:1 | Y=1.14X+4.45 | 3.028 | 135.23 |
| A:B=1:3 | Y=2.05X+3.50 | 5.421 | 148.49 |
| A:B=1:6 | Y=1.11X+4.07 | 6.866 | 200.08 |
| A:B=1:9 | Y=2.91X+1.96 | 11.096 | 172.56 |
| A:B=1:60 | Y=1.25X+2.62 | 80.565 | 102.66 |
1 indoor biometricses of table test result indicate that, fluopyram and zineb weight ratio are 1～70：1～50 compositionss are altogether
Malicious coefficient is both greater than 120, has obvious synergistic function to Colletotrichum capsici.
Field control effectiveness test：
Carried out preventing and treating pepper anthracnose test with pesticidal preparations obtained in above-described embodiment.
1st, test process：This test medicine consumption sets three concentration for the treatment of, comparison medicament point respectively according to the difference of each composition
It is not 41.7% fluopyram SC of pesticide single dose and 80% zineb WP and blank clean water experiment.
2nd, each plot area of test method is 66.7m2, it is repeated 3 times；Investigation drug effect method after investigating and prevent and treat before dispenser
For：5 points of randomization (takes 5m per in the test process area2), the state of an illness point is carried out according to national field test relevant criterion
Level, calculates preventive effect.
3rd, result of the test see the table below：
Table 2：Field efficacy result of the fluopyram+zineb different ratio to pepper anthracnose
As shown in Table 2：Compared with single dose, fluopyram and zineb compositionss have significant effect to pepper anthracnose,
Higher synergistic function can be produced.The consumption of the amount ratio independent reactive compound of bactericidal composition is substantially reduced, that is, mix
Activity of the activity of thing more than independent component, compared with single dose, reduces preventing and treating recruitment, drug cost.
Shown by indoor biometricses and field efficacy result, fluopyram there is obvious Synergistic to make with zineb compositionss
With the prevention effect of compositionss is excellent, and prevention effect is better than single dose kind, in agricultural application has using value.
Claims (10)
1. the bactericidal composition of a kind of containing fluopyram and zineb, it is characterised in that it with fluopyram and zineb is
Main active, described fluopyram and the weight ratio of zineb are 1～70：1～50.
2. the bactericidal composition of containing fluopyram according to claim 1 and zineb, it is characterised in that described fluorine
Pyrrole bacterium amide is 5～50 with the weight ratio of zineb：10～50.
3. the bactericidal composition of containing fluopyram according to claim 2 and zineb, it is characterised in that described fluorine
The weight ratio of pyrrole bacterium amide and zineb is 5～40：10～45.
4. the bactericidal composition of containing fluopyram according to claim 3 and zineb, it is characterised in that described fluorine
The weight ratio of pyrrole bacterium amide and zineb is 1：1～9.
5. the bactericidal composition of containing fluopyram according to claim 1 and zineb, it is characterised in that fluorine pyrrole bacterium acyl
It is 2～80% that both amine and zineb account for the weight percentage of compositionss.
6. the bactericidal composition of containing fluopyram according to claim 5 and zineb, it is characterised in that described fluorine
It is 5.5～70% that both pyrrole bacterium amide and zineb account for the weight percentage of compositionss.
7. the bactericidal composition of containing fluopyram according to claim 1 and zineb, it is characterised in that it is with fluorine pyrrole
Bacterium amide and zineb are that principle active component and insecticides adjuvant, excipient are configured to any one dosage form allow on pesticide.
8. the bactericidal composition of containing fluopyram according to claim 7 and zineb, it is characterised in that described agent
Type is cream, suspending agent, aqueous emulsion, wettable powder, microemulsion or water dispersion granule.
9. the bactericidal composition of the containing fluopyram and zineb described in claim 1 is preparing preventing and treating resistance plant mycosises
Application on evil medicine.
10. the bactericidal composition of the containing fluopyram and zineb described in claim 1 preparation prevent and treat gray mold, rust,
Application on powdery mildew, downy mildew, early blight, late blight, anthrax medicine, is preferably preparing preventing and treating pepper anthracnose medicine
On application.
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1917762A (en) * | 2004-02-12 | 2007-02-21 | 拜尔农科股份有限公司 | Fungicidal composition comprising a pyridylethylbenzamide derivative and a compound capable of inhibiting the spores germination or mycelium growth by acting on different metabolic routes |
| EP2039772A2 (en) * | 2009-01-06 | 2009-03-25 | Bayer CropScience AG | Method for improved utilization of the production potential of transgenic plants introduction |
| CN102726426A (en) * | 2011-04-16 | 2012-10-17 | 青岛凯源祥化工有限公司 | Bactericidal composition containing fluopicolide and polyoxin |
-
2015
- 2015-09-17 CN CN201510594378.3A patent/CN106538571A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1917762A (en) * | 2004-02-12 | 2007-02-21 | 拜尔农科股份有限公司 | Fungicidal composition comprising a pyridylethylbenzamide derivative and a compound capable of inhibiting the spores germination or mycelium growth by acting on different metabolic routes |
| EP2039772A2 (en) * | 2009-01-06 | 2009-03-25 | Bayer CropScience AG | Method for improved utilization of the production potential of transgenic plants introduction |
| CN102726426A (en) * | 2011-04-16 | 2012-10-17 | 青岛凯源祥化工有限公司 | Bactericidal composition containing fluopicolide and polyoxin |
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