CN108477193A - A kind of composition pesticide containing folpet and nitrile bacterium azoles - Google Patents
A kind of composition pesticide containing folpet and nitrile bacterium azoles Download PDFInfo
- Publication number
- CN108477193A CN108477193A CN201810719816.8A CN201810719816A CN108477193A CN 108477193 A CN108477193 A CN 108477193A CN 201810719816 A CN201810719816 A CN 201810719816A CN 108477193 A CN108477193 A CN 108477193A
- Authority
- CN
- China
- Prior art keywords
- folpet
- bacterium azoles
- nitrile bacterium
- composition pesticide
- composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having no bond to a nitrogen atom
- A01N47/04—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having no bond to a nitrogen atom containing >N—S—C≡(Hal)3 groups
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
- A01N43/647—Triazoles; Hydrogenated triazoles
- A01N43/653—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
Abstract
The invention discloses a kind of composition pesticide containing folpet and nitrile bacterium azoles, which is characterized in that the active constituent of the composition pesticide includes folpet and nitrile bacterium azoles.The weight ratio of the active component folpet and nitrile bacterium azoles is 1:80‑60:1, the weight percentage that the two accounts for composition is 5% 90%, this composition can be configured to the suspending agent agriculturally allowed, wettable powder, water dispersible granules, missible oil, microemulsion, aqueous emulsion agent.Instant component is reasonable, and activity and bactericidal effect are not the active simple superposition of each component, compared with existing single formulation, in addition to significant bactericidal effect, and have significant synergistic effect, good to crop safety.
Description
Technical field
The present invention relates to a kind of composition pesticides, and in particular to active constituent includes the pesticide combination of folpet and nitrile bacterium azoles
Object.The invention further relates to the purposes that folpet and nitrile bacterium azoles are used to prevent or control plant disease.
Background technology
Folpet as a kind of contact fungicide, can by S-H be bonded close so that the respiration of interference fungi come
The leaf class disease of a variety of cereals of prevention and control and fruit trees and vegetables, has good prevention to various vegetables downy mildew, powdery mildew, leaf spot etc.
And protective effect.Can prevent potato and tomato early blight, late blight, cowpea powdery mildew, ring spot etc., folpet can with it is interior
Absorption fungicide compounding uses, and absorbability drug resistance is delayed to develop.
Nitrile bacterium azoles are a kind of absorbability triazole bactericidal agents, are sterol demethylation inhibitors, and there is protection and treatment to make
With.For preventing various crop by the multiple diseases caused by sac fungus, basidiomycetes, the agent lasting period is long, to crop safety, has
Certain stimulating growth effect.In addition, nitrile bacterium azoles have the characteristics that strong absorbability, drug effect are high, are grown to crop safety, lasting period, and
With preventive and therapeutic action.
The characteristics of downy mildew belongs to oomycetes disease, and feature is that morbidity is rapid, it is fast to propagate, it is serious to endanger, powdery mildew is can be right
The plant of the season of growth is infected repeatedly, and is propagated soon, main with chemistry at present about the prevention of cucumber downy mildew and powdery mildew
Means are prevented.
Chemical prevention is agriculturally to prevent and control an important means of plant disease, but long-term due to pesticide single dose
It uses, causes many plant diseases to generate resistance to common pesticides, pesticide dosage is promoted to continue to increase, risk increases, and is unfavorable for
Improvement of the ecological environment.There is an urgent need to develop the novel pesticides gone out for preventing these plant diseases.The pesticide of different types of structure has
After imitating ingredient mixing, typically exhibit three kinds of type of action, i.e. summation action, synergistic effect and antagonism, but it is specific why
Kind effect, it is unpredictable, only just it can know that by a large number of experiments.Compound synergic is formulated well, can improve practical prevention effect
Fruit reduces the usage amount of pesticide, contributes to the generation of delaying drug resistance, is the important means of scientific prevention and cure pest and disease damage.It has no at present
The report of folpet and myclobutanil compositional more has no report of the two compounding to cucumber downy mildew and powdery mildew of cucumber.
Invention content
Purpose of the present invention is to places against the above deficiency, provide a kind of composition pesticide, active constituent includes chemical combination
Object A and compound B, wherein A are folpet, and B is nitrile bacterium azoles.
It is especially yellow it is another object of the present invention to the purposes that the composition pesticide is used to prevent and control plant disease
Melon downy mildew and powdery mildew of cucumber.
The present invention provides a kind of composition pesticide and application thereof containing folpet and nitrile bacterium azoles and takes following technical scheme real
It is existing：
A kind of active component of present invention offer includes the composition pesticide of folpet (A) and nitrile bacterium azoles (B), wherein folpet
(A) and nitrile bacterium azoles (B) are synergistic effective quantities, and the weight ratio of the active component folpet (A) and nitrile bacterium azoles (B) is 1:
80-60:1, preferably 1:60-50:1, more preferably 1:30-20:1.
In composition pesticide of the present invention, the active component folpet accounts for the weight percent of composition with nitrile bacterium azoles
Content is 5%-90%, preferably 10%-80%, more preferable 20%-60%.
In a kind of composition pesticide containing folpet and nitrile bacterium azoles, the active component folpet and nitrile bacterium azoles with
Liquid or solid carrier or the mixing of other auxiliary agents.
Effect ingredient can be only comprised only in a kind of composition pesticide containing folpet and nitrile bacterium azoles of the present invention,
It can be mixed together with additive, therefore a kind of composition pesticide containing folpet and nitrile bacterium azoles of the present invention can be prepared into
The dosage form of various dosage forms, the composition pesticide is suspending agent, wettable powder, water dispersible granules, missible oil, microemulsion, water
Emulsion.
These preparations can be produced by known method.For example, in the case where selectively using surfactant, lead to
It crosses and reactive compound is mixed with filler and prepares preparation, the filler is the dilution of liquid or liquid gas or solid
Agent or carrier, the surfactant are emulsifier, dispersant, wetting agent.In the case where using water as filler, also may be used
Using organic solvent, for example, organic solvent is used as cosolvent.
According to the present invention, term " carrier " refers both to be combined with reactive compound or combine to make it easier for being administered to
The natural or synthetic organic or inorganic compound of controlling object.Therefore, the carrier is preferably inert, at least should be agricultural
Acceptable, the carrier can be solid or liquid.
The preparation of the present invention can be prepared by known way mixes the reactive compound with conven-tional adjuvants.Institute
It states such as conventional extender of conven-tional adjuvants and solvent or diluent, emulsifier, dispersant, adhesive, stabilizer, wetting agent, prevent
Aqua, if it is desired, can also include antifoaming agent, preservative, thickener, synergist, water and other processing aids.
These compositions can not only by can such as spraying or dusting equipment of suitable equipment handle object to be prevented, and
And concentration commercial composition can also be diluted into before process object.
The present invention composition be made in the form of the composition of its active compound component suitable for application preparation, also with
The form of the combination of the commercial preparation of its suitable dosage is applied.
The composition of the present invention can also be applied with other active ingredient combinations, and other active constituents are for example antifungal
Agent, bactericide, attractant, insecticide, acaricide, nematicide, plant growth regulator, herbicide, safener, fertilizer
Or semiochemical etc..
Folpet and nitrile bacterium azoles are creatively combined into one by the present invention, can prevent cereal, water fruits and vegetables, flowers, warp
The germ harm of Ji crop, especially has special efficacy to cucumber downy mildew and powdery mildew of cucumber.
The invention solves the defect existing in the background technology, and the present invention has following advantageous effect：
(1) a kind of composition pesticide containing folpet and nitrile bacterium azoles provided by the invention, folpet and nitrile bacterium azoles are answered
Match, there is synergistic function, the composition can prevent cereal, water fruits and vegetables, upper a variety of diseases of flowers, industrial crops
Evil, has special efficacy to cucumber downy mildew and powdery mildew of cucumber.
(2) synergistic composition pesticide of the invention has both preventive effect and therapeutic effect, passes through different role
The active constituent of mechanism carry out compounding can further enlarged composition prevention spectrum, while overcoming or having delayed the anti-of pathogen
Pharmacological property extends the service life of composition pesticide.
(3) active constituent folpet and the interaction after myclobutanil compositional in synergistic composition pesticide of the invention
It is not superimposed not instead of simply, plays synergistic effect, it is possible to reduce pesticide activity component usage amount improves prevention effect
Fruit reduces the pollution to environment.
Specific implementation mode
Preferably to describe the present invention, following exemplary embodiment is provided.Content mentioned by embodiment cannot recognize
To be limitation of the invention, the selection of material prescription can be according to actual conditions by other equivalent or replacing with similar purpose
It is replaced for feature.That is, being such as not particularly limited, each feature is a series of equivalent or similar characteristics a example, this
The protection domain of the technical solution of invention is subject to claim and is limited.
One, indoor biological determination of activity
Sun Yunpei's Method calculates the toxicity index of each medicament and the co-toxicity coefficient (CTC values) of mixture, when CTC≤80, then group
It closes object and shows antagonism, when 80≤CTC≤120, then composition shows summation action, when CTC >=120, then composition
Show synergistic effect.
Survey toxicity index (ATI)=(standard agent EC50/ reagent agent EC50)×100；
Percentage composition+B the medicament toxicity index of A in theoretical toxicity index (TTI)=A medicament toxicity index × mixture × mixed
The percentage composition of B in agent；
Co-toxicity coefficient (CTC)=[mixture surveys toxicity index (ATI)/mixtures theoretical toxicity index (TTI)] × 100.
Test medicine：Folpet and nitrile bacterium azoles weight proportion are set as 1:90、1:80、1:60、1:30、5:2、7:4、2:1、
5:7、6:5、1:1、20:1、50:1、60:1、70:1 is compounded and folpet and two kinds of single doses of nitrile bacterium azoles 16 kinds of medicaments totally,
And set clear water blank control.
1, the Toxicity Determination of folpet and myclobutanil compositional preparation to powdery mildew of cucumber
Test method：Using spray-on process, room of the folpet of different proportion with myclobutanil compositional to powdery mildew of cucumber is measured
Interior virulence.Using 1 leaf, the 2 heart stage cucumber seedling of hot-house culture as the experiment host plant of powdery mildew of cucumber.Respectively by each mixture
The mother liquor of agent and single dose is diluted to 0.05,0.125,0.25,0.5,0.75, totally 6 concentration gradients are spare by 1mg/L, using crop
Spraying machine, by the medicine liquid spray prepared in host plant cauline leaf, treated, and test material dries in the shade naturally, and inoculation is sick afterwards for 24 hours
Opportunistic pathogen and moisturizing for 24 hours, investigation records incidence after 5~7d, and calculate co-toxicity coefficient, test result such as table 1.
1 folpet of table is with myclobutanil compositional preparation to the Toxicity Determination of powdery mildew of cucumber
By folpet and myclobutanil compositional preparation to the biological activity determination of powdery mildew of cucumber it is found that folpet and nitrile bacterium azoles
1:80-60:Compounding shows synergistic function to powdery mildew of cucumber in 1 range, and co-toxicity coefficient is all higher than 120, the two compounding
Than 1:30、5:2、7:4、2:1、5:7、6:5、1:1、20:1、50:It is synergistic notable when 1, co-toxicity coefficient 150 or more,
When folpet and myclobutanil compositional are 7:When 4, synergistic most notable, co-toxicity coefficient 172.27.
2, the Toxicity Determination of folpet and myclobutanil compositional preparation to cucumber downy mildew
Test method：Experiment uses pot-culture method, chooses and grows consistent two panels leaf period cucumber seedling, and each processing selects 10
For basin for trying melon seedling, number is spare.It is sprayed under 50PSI pressure with Potter spray towers, per basin 5mL.Each medicament setting 6 is dense
Gradient is spent, to spray the processing of equivalent clear water as blank control.The downy mildew leaf for picking up from field is taken, 10 DEG C or so are dipped with writing brush
Distillation washing lower back face sporangium, be made into a concentration of 3 × 105The sporangia suspension of a/mL.In chemicals treatment for 24 hours after
Cucumber seedling is placed in growth cabinet (relative humidity 100%, 15~20 DEG C of temperature) training by spray inoculation spore cyst fluid after inoculation
It supports, keeps 15~24 DEG C of temperature, 90% or so moisturizing of relative humidity to induce afterwards for 24 hours, investigation record incidence, calculates after 10d
Disease index and control effect.Concentration EC in inhibiting is calculated with least square method50, then according to Sun Yunpei's Method calculating co-toxicity coefficient
(CTC)。
2 folpet of table is with myclobutanil compositional preparation to the Toxicity Determination of cucumber downy mildew
By folpet and myclobutanil compositional preparation to the biological activity determination of cucumber downy mildew it is found that folpet and nitrile bacterium azoles
1:80-60:Compounding shows synergistic function to cucumber downy mildew in 1 range, and co-toxicity coefficient is all higher than 120, the two compounding
Than 1:30、5:2、7:4、2:1、5:7、6:5、1:1、20:Synergistic notable when 1, co-toxicity coefficient is 140 or more, when going out
Bacterium pellet is 5 with myclobutanil compositional:When 7, synergistic most notable, co-toxicity coefficient 188.26.
Two, example of formulations
Embodiment 1:70% folpet myclobutanil micro-emulsion (5:2)
Above-mentioned material is mixed in proportion, after high shear agitation is uniform, you can 70% folpet nitrile bacterium azoles are made
Microemulsion.
Embodiment 2:55% folpet nitrile bacterium azoles wettable powder (7:4)
The making step of the wettable powder is：By above-mentioned formula by folpet and nitrile bacterium azoles and dispersant, wetting agent
It mixes, in a stirring kettle uniform stirring, is being uniformly mixed after airslide disintegrating mill, you can this 55% folpet is made with filler
Nitrile bacterium azoles wettable powder.
Embodiment 3：15% folpet nitrile bacterium azoles missible oil (2:1)
The specific production stage of the cream preparation is：First folpet, nitrile bacterium azoles are added in solvent after being completely dissolved and are added again
Enter emulsifier, after synergist stirs evenly at homogeneous and transparent oily liquids, it is filling, obtain 15% sterilizing of the present invention
Red nitrile bacterium azoles missible oil.
Embodiment 4：48% folpet nitrile bacterium azoles water dispersible granules (5:7)
Above-mentioned substance is uniformly mixed, grinds, mixes suitable quantity of water and is granulated, up to 48% folpet nitrile bacterium azoles after drying
Water dispersible granules.
Embodiment 5：33% folpet nitrile bacterium azoles suspending agent (6:5)
The specific production stage of the suspending agent is first to mix other auxiliary agents, is uniformly mixed through high speed shear, and sterilizing is added
Red and nitrile bacterium azoles, abrading-ball 2~3 hours in ball crusher make a diameter be below 5mm, and are made of the present invention containing going out
The aqueous suspension formulations of bacterium pellet and the composition pesticide of nitrile bacterium azoles.
Embodiment 6:25% folpet myclobutanil micro-emulsion (1:1)
In a solvent by active compound dissolving, surfactant is added, is uniformly mixed as oil phase.By water-soluble component and water
It is mixed to prepare water phase, then is added in oil phase during the oil phase is added to the aqueous phase or by water phase, it is stirring while adding, 25% folpet is made
Myclobutanil micro-emulsion.
Three, field trial surveys powdery mildew of cucumber and cucumber downy mildew
1. reagent agent：The complex preparation of embodiment described above 1-6 folpets and nitrile bacterium azoles, comparison medicament are gone out for 50%
Bacterium pellet suspending agent and 10% nitrile bacterium azoles missible oil, blank control are clear water.
2. application method：Experimental field it is arranged in zunyi, guizhou city cucumber producing region, long-term powdery mildew of cucumber and downy mildew cause harm
More serious, each plot area is 50m2, be repeated 4 times, in cucumber early stage carry out foliar spray processing, dispenser twice,
When making up a prescription, after first fully being dissolved medicament with a small amount of water, adds suitable quantity of water and carry out whole plant spray treatment, with spraying equipment WS-
16 type back carried hand even sprayings carry out powdery mildew of cucumber and the investigation of downy mildew disease index before chemicals treatment.
3. investigation method：
Powdery mildew of cucumber：Before dispenser investigate state of an illness radix, 7 days after last time dispenser, 15 days each experimental investigations as a result, altogether
Investigation 2 times.Take at random per cell at 4 points, whole blades of every 2 plants of investigation, every leaf accounts for the percentage of leaf area according to scab
Classification record, calculates relative control effect, test result such as table 3.Stage division：
0 grade：Disease-free spot；
1 grade：Lesion area accounts for 5% or less entire leaf area；
3 grades：Lesion area accounts for the 6%~10% of entire leaf area；
5 grades：Lesion area accounts for the 11%~20% of entire leaf area；
7 grades：Lesion area accounts for the 21%~40% of entire leaf area；
9 grades：Lesion area accounts for 40% or more of entire leaf area.
Disease index=[(the disease numbers of sheets at different levels × opposite value of series)/(investigation total leaf number × 9) Σ] × 100
Control effect (%)=[1- (disease index after disease index × processing dispenser before control dispenser)/(after control dispenser
Disease index before disease index × processing dispenser] × 100
Cucumber downy mildew：Disease index investigation is carried out respectively within 7,15 days after second of dispenser, each cell investigates at 5 points,
5 plants of cucumber of every investigation, record total number of sheets, the sick number of sheets at different levels and sick series, calculate disease index, are calculated by disease index anti-
Effect, test result are shown in Table 4.Grade scale is:
0 grade, disease-free spot；
1 grade, lesion area accounts for 5% or less entire leaf area；
3 grades, lesion area accounts for the 6%-10% of entire leaf area；
5 grades, lesion area accounts for the 11%-20% of entire leaf area；
7 grades, lesion area accounts for the 21%-50% of entire leaf area；
9 grades, lesion area accounts for 50% or more of entire leaf area.
Disease index and control effect computational methods：
Disease index=Σ (the disease numbers of sheets at different levels × opposite value of series)/investigation total number of sheets × 9 × 100%
Control effect (%)=(disease index after disease index-chemicals treatment district dispenser after blank district dispenser)/sky
Disease index × 100% after white check plot dispenser
3 folpet of table prevents powdery mildew of cucumber field control effectiveness test result with myclobutanil compositional preparation
From upper table 3 it is found that folpet and myclobutanil compositional have an apparent synergistic function to powdery mildew of cucumber, effectively at
Point dosage is 200g/ hectares, and preventive effect is 90% or more, and the preventive effect after dispenser 15 days remains to maintain 95%, and the lasting period is long.
4 folpet of table prevents cucumber downy mildew field control effectiveness test result with myclobutanil compositional preparation
From upper table 4 it is found that folpet has apparent synergistic function, embodiment with myclobutanil compositional to cucumber downy mildew
When the composition pesticide active ingredient of 1-6 is 280g/ hectares, 80% is above to the preventive effect of cucumber downy mildew, hence it is evident that be better than each
A control single dose.In addition, do not observed in scope of medication the present invention composition pesticide and control group test medicine to Huang
Melon crop has poisoning generation, to also having no adverse effects beneficial to natural enemy.
In conclusion the composition of the present invention is to use two kinds of active components compound scheme, activity and bactericidal effect are not
It is the active simple superposition of each component, compared with existing single formulation, other than there is significant bactericidal effect, more has significantly
Synergistic effect, safety is good to making, and meets the security requirement of pesticidal preparations.
Based on the above description of the preferred embodiments of the present invention, through the above description, related personnel completely can be with
Without departing from the scope of the technological thought of the present invention', various changes and amendments are carried out.The technical scope of this invention
It is not limited to the contents of the specification, it is necessary to determine the technical scope according to the scope of the claims.
Claims (8)
1. a kind of composition pesticide containing folpet and nitrile bacterium azoles, which is characterized in that the active constituent packet of the composition pesticide
Include folpet and nitrile bacterium azoles.
2. a kind of composition pesticide containing folpet and nitrile bacterium azoles according to claim 1, it is characterised in that：The activity
The weight ratio of component folpet and nitrile bacterium azoles is 1:80-60:1.
3. a kind of composition pesticide containing folpet and nitrile bacterium azoles according to claim 1, it is characterised in that：The activity
The weight ratio of component folpet and nitrile bacterium azoles is 1:60-50:1.
4. a kind of composition pesticide containing folpet and nitrile bacterium azoles according to claim 1, it is characterised in that：The activity
The weight ratio of component folpet and nitrile bacterium azoles is 1:30-20:1.
5. a kind of composition pesticide containing folpet and nitrile bacterium azoles according to any one of claim 1-4 claims,
It is characterized in that：The composition pesticide can be prepared into any one dosage form used in suitable agricultural production.
6. a kind of composition pesticide containing folpet and nitrile bacterium azoles according to claim 5, it is characterised in that：The dosage form
For suspending agent, wettable powder, water dispersible granules, missible oil, microemulsion, aqueous emulsion.
7. a kind of composition pesticide containing folpet and nitrile bacterium azoles according to any one of claim 1-6 claims,
It is characterized in that：The composition pesticide is used to prevent the purposes of corps diseases.
8. a kind of composition pesticide containing folpet and nitrile bacterium azoles according to claim 7, it is characterised in that：The farming
Object disease is cucumber downy mildew and powdery mildew of cucumber.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810719816.8A CN108477193A (en) | 2018-07-03 | 2018-07-03 | A kind of composition pesticide containing folpet and nitrile bacterium azoles |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810719816.8A CN108477193A (en) | 2018-07-03 | 2018-07-03 | A kind of composition pesticide containing folpet and nitrile bacterium azoles |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108477193A true CN108477193A (en) | 2018-09-04 |
Family
ID=63343314
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810719816.8A Pending CN108477193A (en) | 2018-07-03 | 2018-07-03 | A kind of composition pesticide containing folpet and nitrile bacterium azoles |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108477193A (en) |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1252690A (en) * | 1997-04-18 | 2000-05-10 | 拜尔公司 | Fungicide active substance combinations |
| CN105766952A (en) * | 2016-04-26 | 2016-07-20 | 南京华洲药业有限公司 | Sterilization composition containing isopyrazam and folpet and application of sterilization composition |
-
2018
- 2018-07-03 CN CN201810719816.8A patent/CN108477193A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1252690A (en) * | 1997-04-18 | 2000-05-10 | 拜尔公司 | Fungicide active substance combinations |
| CN105766952A (en) * | 2016-04-26 | 2016-07-20 | 南京华洲药业有限公司 | Sterilization composition containing isopyrazam and folpet and application of sterilization composition |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101548677B (en) | Sterilizing compound of ethirimol and triazole | |
| CN106912490A (en) | A kind of efficient bactericidal composite containing tetramycin | |
| CN102258057B (en) | Sterilizing agent composition with synergizing action | |
| CN106605657A (en) | Pesticide combination containing SYP-9625 | |
| CN102696622A (en) | Pesticide composition capable of preventing and controlling plant disease | |
| CN104115845B (en) | A kind of high-efficient pesticide composition containing fluorobenzene insect amide | |
| CN106857599A (en) | A kind of bactericidal composition containing pyraclostrobin and folpet and its application | |
| CN107912437A (en) | A kind of bactericidal composition and its application containing pyraziflumid | |
| CN109258656A (en) | Composition pesticide and its preparation method and application containing Ningnanmycin and copper 8-hydroxyquinolinate | |
| CN107372548A (en) | Composition pesticide containing captan and fluorine azoles ring bacterium amine and application thereof | |
| CN107318865A (en) | The composition pesticide of captan and furametpyr compounding | |
| CN102715182A (en) | Sterilization composition containing active components Bellkute and imazalil | |
| CN108477193A (en) | A kind of composition pesticide containing folpet and nitrile bacterium azoles | |
| CN101536690A (en) | Epoxiconazole and kresoxim-methyl sterilizing composite | |
| CN105831132A (en) | Sterilization composition containing benzothiostrobin and fluoride ether bacteria amide | |
| CN101502264B (en) | Composition containing triazole bactericidal agent | |
| CN106804597A (en) | A kind of Pesticidal combination of the nitrile of worm containing acetyl and fipronil bisamide | |
| CN107926951A (en) | A kind of bactericidal composition and its application containing terpenol and trifloxystrobin | |
| CN107484770A (en) | Agricultural chemical compound conjugate containing terpenol and phosethyl-Al | |
| CN103918699A (en) | Pesticide composition containing thiamethoxam and hexaconazole | |
| CN108077286A (en) | A kind of Pesticidal combination containing ethyl pleocidin and butene-fipronil | |
| CN114982765B (en) | Pesticide composition and preparation and application thereof | |
| CN107980777A (en) | A kind of bactericidal composition containing bromothalonil and eugenol | |
| CN105746526B (en) | A kind of Pesticidal combination for containing four chlorantraniliproles and biogenic substances | |
| CN107087609A (en) | Microbicide compositions containing anthraquinone analog compound and S-Ethyl ethylthio sulfonate |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20180904 |
|
| RJ01 | Rejection of invention patent application after publication |