CN106804597A - A kind of Pesticidal combination of the nitrile of worm containing acetyl and fipronil bisamide - Google Patents
A kind of Pesticidal combination of the nitrile of worm containing acetyl and fipronil bisamide Download PDFInfo
- Publication number
- CN106804597A CN106804597A CN201510848525.5A CN201510848525A CN106804597A CN 106804597 A CN106804597 A CN 106804597A CN 201510848525 A CN201510848525 A CN 201510848525A CN 106804597 A CN106804597 A CN 106804597A
- Authority
- CN
- China
- Prior art keywords
- nitrile
- fipronil bisamide
- acetyl
- worm
- fipronil
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N41/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom
- A01N41/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom containing a sulfur-to-oxygen double bond
- A01N41/10—Sulfones; Sulfoxides
Abstract
The invention discloses a kind of nitrile of worm containing acetyl and the Pesticidal combination of fipronil bisamide, effective active composition is acetyl worm nitrile and fipronil bisamide, and the weight ratio of acetyl worm nitrile and fipronil bisamide is the ︰ 1 of 1 ︰ 80~80.The present composition has synergistic effect to the various pests for endangering agricultural production, reduces pesticide usage amount, reduces residual quantity of the agricultural chemicals on crop, alleviates environmental pollution, and to person poultry safety, Environmental compatibility is good, and insect is not likely to produce the resistance to the action of a drug.
Description
Technical field
The invention belongs to technical field of pesticide, it is related to a kind of nitrile of worm containing acetyl and fipronil bisamide
Application of the Pesticidal combination on crop pests.
Background technology
Acetyl worm nitrile：Molecular formula：C13H10Cl2F3N3O2S, acetyl worm nitrile is a wide spectrum
Insecticide, its insecticidal mechanism is the chlorine for hindering insect GABA (GABA) control
Compound is metabolized.
Fipronil bisamide：Belong to new phthalic amide insecticides, the blue Buddhist nun's alkali acceptor of activation
Calcium release passage, causes to store the runaway release of calcium ion.It is at present to count not to be
Many compounds for acting on insect cell orchid Buddhist nun alkali (Ryanodine) acceptor.Lepidoptera is done harm to
Worm has spectrum preventive effect, is produced with existing insecticide no interactions resistance, is extremely suitable for existing killing
Worm agent produces the preventing and treating of the insect of resistance.There is very prominent preventive effect to larva, it is anti-to adult
Effect is limited, does not have ovicidal action.Slightly has conduction by xylem after in infiltration plant body.It is resistance to
Rain drop erosion.
But in the real process of agricultural production, pest control is easiest to generate the problem that
The generation of pest resistance to insecticide.Different cultivars composition is compounded, and is that preventing and treating resistant insect is very normal
The method seen.Heterogeneity is compounded, and judges that certain is answered according to practical application effect
Be synergy, plus and or antagonism.In most cases, the compounding effect of agricultural chemicals
All it is additive effect, really has the compounding of synergistic effect seldom, especially synergistic effect is very
Substantially, co-toxicity coefficient compounding very high is just less.Studied by inventor, found second
The relevant report of acyl worm nitrile and fipronil bisamide compounding is not yet disclosed.
The content of the invention
Have that synergistic function, use cost be low, preventive effect the purpose of the present invention is to propose to one kind
The good nitrile of worm containing acetyl and the Pesticidal combination of fipronil bisamide.
The Pesticidal combination of the nitrile of worm containing acetyl proposed by the present invention and fipronil bisamide, acetyl worm nitrile
It is the ︰ 1 of 1 ︰ 80~80 with fipronil bisamide weight ratio, acetyl worm nitrile and fipronil bisamide are preferred
Weight ratio is the ︰ 1 of 1 ︰ 40~40；The weight ratio of more preferably acetyl worm nitrile and fipronil bisamide is
20:1~1:20.
The Pesticidal combination of the nitrile of worm containing acetyl proposed by the present invention and fipronil bisamide is used to prevent and treat
The purposes of insect on crops, described crops include cereal crops, legume crop, fibre
Dimension crop, sugar crop, melon crop, fruits crop, dry fruit crop, hobby crop,
Root crop, oil crops, flower crop, medicinal crop, crop, green manure herbage
Crop；Described insect be beetle, leafhopper, aphid, aleyrodid, beet armyworm, diamondback moth,
Rice leaf roller, striped rice borer or yellow rice borer.
The weight ratio of acetyl worm nitrile and fipronil bisamide is the ︰ 1 of 1 ︰ 80~80.In usual composition
The weight percentage of active component for gross weight 0.5%~90%, preferably 5%~
80%.According to different preparation types, active component content scope is different.Generally, liquid
Body preparation contains by weight 1%~70% active material, preferably 5%~50%；Gu
Body preparation contains by weight 5%~80% active material, preferably 10%~80%.
At least contain a kind of surfactant in Pesticidal combination of the invention, be beneficial to when applying
Dispersion of the active component in water.Surface-active contents are the 5%~30% of total formulation weight,
Balance of solid or liquid diluent.
Pesticidal combination of the invention can by user using it is preceding through dilute or directly use.
Its preparation can be prepared by common processing method known in those skilled in the art, will activity
After material mixes with liquid flux or solid carrier, surfactant such as dispersant, steady is added
Determine one or more in agent, wetting agent, binding agent, defoamer, disintegrant, antifreeze etc..
Pesticidal combination of the invention, can be processed into acceptable dose on any agricultural chemicals on demand
Type, wherein more preferably formulation be wettable powder, water dispersible granules, suspending agent, suspension emulsion,
Aqueous emulsion, microemulsion, microcapsule suspending agent, microcapsule suspension-suspendinagent agent, can also be made effervesce
Tablet, seed coat agent, ultra-low-volume formulation, aqua, soluble liquid, soluble powder, hot mist
Agent.
Composition is when being made wettable powder comprising following constituent content：Acetyl worm nitrile 0.1%~
80%th, fipronil bisamide 0.1%~80%, dispersant 2%~10%, wetting agent 2%~10%,
Filler surplus.
Composition includes following constituent content when being made water dispersible granules：Acetyl worm nitrile 0.1%~
80%th, fipronil bisamide 0.1%~80%, dispersant 3%~12%, wetting agent 1%~8%, collapse
Solution agent 1%~10%, binding agent 0~8%, filler surplus.
Composition includes following constituent content when being made suspending agent：Acetyl worm nitrile 0.1%~50%,
Fipronil bisamide 0.1%~50%, dispersant 2%~10%, wetting agent 2%~10%, defoamer
0.01%~2%, thickener 0~2%, antifreeze 0~8%, deionized water add to 100%.
Composition includes following constituent content when being made suspension emulsion：Acetyl worm nitrile 0.1%~50%,
Fipronil bisamide 0.1%~50%, dispersant 2%~10%, defoamer 0.01%~2%, solvent
1%~15%, thickener 0~2%, emulsifying agent 2%~12%, antifreeze 0~8%, deionized water
Add to 100%.
Composition is when being made aqueous emulsion comprising following constituent content：Acetyl worm nitrile 0.1%~50%,
Fipronil bisamide 0.1%~50%, solvent 1%~30%, emulsifying agent 1%~15%, antifreeze 0~8%,
Thickener 0~2%, defoamer 0.01%~2%, deionized water supply surplus.
Composition includes following constituent content when being made microcapsule suspending agent：Acetyl worm nitrile
0.1%~50%, fipronil bisamide 0.1%~50%, macromolecule cyst material 2%~10%, dispersion
Agent 1%~10%, organic solvent 1%~10%, defoamer 0.01%~2%, emulsifying agent 1%~7%,
PH adjusting agent 0.01%~5%, deionized water adds to 100%.
Composition includes following constituent content when being made microcapsule suspension-suspendinagent agent：Acetyl worm nitrile
0.1%~50%, fipronil bisamide 0.1%~50%, macromolecule cyst material 2%~10%, dispersion
Agent 1%~12%, wetting agent 1%~8%, organic solvent 1%~15%, emulsifying agent 1%~6%,
Defoamer 0.01%~2%, thickener 0~2%, pH adjusting agent 0.01%~5%, deionized water
Add to 100%.
Wettable powder the key technical indexes of the invention：
Water dispersible granules the key technical indexes of the invention：
Suspending agent the key technical indexes of the invention：
Suspension emulsion the key technical indexes of the invention：
Aqueous emulsion the key technical indexes of the invention：
Microcapsule suspending agent the key technical indexes of the invention：
Microcapsule suspension-suspendinagent agent the key technical indexes of the invention：
The advantage of the invention is that：
(1) after acetyl worm nitrile is compounded with fipronil bisamide, with obvious synergy and lasting effect；
(2) to cereal crops, legume crop, fibre crops, sugar crop, melon crop, water
Orchard crop, dry fruit crop, hobby crop, root crop, oil crops, flowers make
Thing, medicinal crop, crop, green manure pasture crop insect have greater activity；(3) subtract
Lack pesticide usage amount, reduced residual quantity of the agricultural chemicals on crop, alleviate environmental pollution；
(4) to person poultry safety, Environmental compatibility is good；And preparation adhesion strength strengthens, resistance to rainwater punching
Brush.
Specific embodiment
With reference to embodiment to further instruction of the present invention, the percentage in embodiment is
Percentage by weight, but the invention is not limited in this.
Application Example one
The wettable powder of embodiment 1~4
Acetyl worm nitrile, fipronil bisamide, dispersant, wetting agent, filler are mixed in mixed cylinder
Close uniform, remixed after being crushed through airslide disintegrating mill uniform, you can be obtained it is of the present invention can
WP product, is specifically shown in Table 1.
The each component of 1 embodiment of table 1~4 and weight portion
The water dispersible granules of embodiment 5~8
By acetyl worm nitrile, fipronil bisamide, dispersant, wetting agent, disintegrant, filler etc.
Play the particle diameter that is needed through air-flow crushing, add binding agent (can add to be not added with) etc. other
Auxiliary agent, obtains materials of pelletizing.Item is quantitatively sent into fluidized bed granulating dryer by granulation
And after drying, you can water dispersible granules product of the present invention is obtained, 2 are specifically shown in Table.
The each component of 2 embodiment of table 5~8 and weight portion
The suspending agent of embodiment 9~12
By dispersant, wetting agent, defoamer, thickener (can add to be not added with), antifreeze (can
Plus can be not added with), it is well mixed by high speed shear, acetyl worm nitrile, fipronil bisamide are added,
Ball milling 2~3 hours in ball mill, make diameter of particle all below 5 μm, and surplus spends
Ionized water is supplied, you can suspending agent product of the present invention is obtained, 3 are specifically shown in Table.
The each component of 3 embodiment of table 9~12 and weight portion
The suspension emulsion of embodiment 13~15
By dispersant, defoamer, thickener (can add to be not added with), (can add can for antifreeze
It is not added with) it is well mixed by high speed shear, add fipronil bisamide, the ball milling in ball mill
2~3 hours, make diameter of particle all below 5 μm, fipronil bisamide suspension agent is obtained, so
Afterwards by acetyl worm nitrile, solvent (can add to be not added with), emulsifying agent and various auxiliary agent high-speed stirrings
Mix device directly to emulsify in suspending agent, surplus is supplied with deionized water, be obtained of the present invention
Suspension emulsion product, be specifically shown in Table 4.
The each component of 4 embodiment of table 13~15 and weight portion
The aqueous emulsion of embodiment 16~18
Acetyl worm nitrile, fipronil bisamide, solvent, emulsifying agent are added together, make to be dissolved into
Even oil phase；By deionized water, antifreeze (can add to be not added with), thickener (can add to be not added with),
Defoamer is mixed, into homogeneous water phase.Under high velocity agitation, water is added to oil phase,
Surplus is supplied with deionized water；Aqueous emulsion product of the present invention is can be prepared by, is specifically shown in Table
5。
The each component of 5 embodiment of table 16~18 and weight portion
The microemulsion of embodiment 19~21
Acetyl worm nitrile, fipronil bisamide are dissolved in the homogenizer equipped with solvent, by emulsifying agent,
Antifreeze (can add to be not added with), defoamer are added in the homogenizer equipped with above-mentioned solution, remaining
Amount deionized water mixes and homogenizes strongly after supplying, and finally obtains clear appearance transparent
Microemulsion product of the present invention, is specifically shown in Table 6.
The each component of 6 embodiment of table 19~21 and content
Embodiment 22,23 microcapsule suspending agents
Acetyl worm nitrile, fipronil bisamide, macromolecule cyst material, solvent, defoamer are mixed,
Make to be dissolved into homogeneous oil phase, in a shear condition, oil phase is added to and contains emulsifying agent, pH
In conditioning agent, the aqueous phase solution of dispersant, surplus is supplied with deionized water, and two kinds of materials are in oil
Water termination reacts, and forms high score ascus wall, is made well dispersed micro- of the present composition
Capsule suspending agent product, is specifically shown in Table 7.
The embodiment 22 of table 7,23 each components and weight portion
Embodiment 24,25 microcapsule suspension-suspendinagent agents
Acetyl worm nitrile, macromolecule cyst material, solvent are mixed, make to be dissolved into homogeneous oil phase,
During oil phase is added in a shear condition containing emulsifying agent, the aqueous phase solution of pH adjusting agent,
It is made well dispersed microcapsule suspending agent.By dispersant, wetting agent, defoamer, thickener (can
Plus can be not added with) well mixed by high speed shear, add fipronil bisamide, the ball in ball mill
Mill 2~3 hours, makes diameter of particle all below 5 μm, and suspending agent is obtained, then will be outstanding
Floating agent is added in the aqueous phase solution of micro-capsule suspension, and deionized water supplies surplus, is made this
The well dispersed microcapsule suspension-suspendinagent agent product of inventive composition, is specifically shown in Table 8.
The embodiment 24 of table 8,25 each components and weight portion
The embodiment of the present invention is the method being combined using Toxicity Determination and field test.First
By Toxicity Determination, clear and definite two kinds of medicaments compound by a certain percentage after co-toxicity coefficient
(CTC), CTC ＜ 80 are antagonism, and 80≤CTC≤120 are summation action, CTC
＞ 120 is synergistic effect, on this basis, then carries out field test.
Test method：The mother liquor of each mixed agent is diluted to five series concentrations respectively during experiment,
It is respectively placed in standby in beaker.Using the method that first leaching leaf is followed by worm, will be not in contact with any medicament
Blade of the same size 5s is soaked in the liquid for having configured after take out, dry naturally, put
Enter in insect box, then connect for examination larva, raised under the conditions of 25 DEG C, often process 3 times
Repeat, often repeat test worm number used for 50, while setting blank, check dead in 72h
Borer population, calculates the death rate and corrected mortality, tries to achieve virulence regression equation and calculates LC50Value.
If the control death rate is more than 10%, it is considered as invalid experiment.Computing formula is as follows：
Insect corrected mortality is converted into probit value (y), concentration for the treatment of (μ g/ml) is converted into
Logarithm value (x), virulence regression equation is drawn with least square method, and thus calculates every kind of medicine
The value of agent, co-toxicity coefficient CTC is calculated according to the abundant equations of Sun Yun.Computing formula it is following (with
Acetyl worm nitrile is standard agent, and its toxicity index is for 100)：
TI × the P of the theoretical toxicity index (TTI) of M=acetyl worm nitrileAcetyl worm nitrile+Fipronil bisamide
TI × PFipronil bisamide
In formula：M is the mixture of different ratio
PFipronil bisamideIt is fipronil bisamide ratio shared in the composition
PAcetyl worm nitrileIt is acetyl worm nitrile ratio shared in the composition
Application Example two：
For examination insect：Brassicaceous vegetable diamondback moth
Test medicine is provided by Shaanxi Welch Crop Protection Co., Ltd..
Experimental design：By pilot study determine acetyl worm nitrile and fipronil bisamide active compound and the two
Effective lethasl concentration scope of different ratio mixture.
Toxicity test result
The acetyl worm nitrile of table 9 compounds the toxicity test analysis of results table to brassicaceous vegetable diamondback moth with fipronil bisamide
| Reagent agent | Proportioning | Co-toxicity coefficient (CTC) | |
| Acetyl worm nitrile | — | 1.35 | — |
| Fipronil bisamide | — | 1.19 | — |
| Acetyl Chong Jing ︰ fipronil bisamides | 80:1 | 0.73 | 184.62 |
| Acetyl Chong Jing ︰ fipronil bisamides | 60:1 | 0.68 | 198.09 |
| Acetyl Chong Jing ︰ fipronil bisamides | 40:1 | 0.65 | 207.01 |
| Acetyl Chong Jing ︰ fipronil bisamides | 20:1 | 0.58 | 231.28 |
| Acetyl Chong Jing ︰ fipronil bisamides | 9:1 | 0.55 | 242.20 |
| Acetyl Chong Jing ︰ fipronil bisamides | 4:1 | 0.51 | 257.77 |
| Acetyl Chong Jing ︰ fipronil bisamides | 1:1 | 0.48 | 263.53 |
| Acetyl Chong Jing ︰ fipronil bisamides | 1:4 | 0.47 | 259.33 |
| Acetyl Chong Jing ︰ fipronil bisamides | 1:9 | 0.49 | 245.76 |
| Acetyl Chong Jing ︰ fipronil bisamides | 1:20 | 0.51 | 234.65 |
| Acetyl Chong Jing ︰ fipronil bisamides | 1:40 | 0.55 | 216.98 |
| Acetyl Chong Jing ︰ fipronil bisamides | 1:60 | 0.58 | 205.56 |
| Acetyl Chong Jing ︰ fipronil bisamides | 1:80 | 0.61 | 195.36 |
As shown in Table 9, acetyl worm nitrile is matched 1 with fipronil bisamide to brassicaceous vegetable diamondback moth
During 80~80 ︰ 1 of ︰, co-toxicity coefficient is all higher than 120, illustrates both in the scopes of 1 ︰, 80~80 ︰ 1
Interior mixture shows synergistic effect, when the proportioning of acetyl worm nitrile and fipronil bisamide is 1：
20~20：When 1, synergistic effect becomes apparent protruding, and co-toxicity coefficient is all higher than 230.Through application
People's experiment finds that acetyl worm nitrile is 20 ︰ 1,19 ︰ 1,18 with the optimum ratio of fipronil bisamide
︰ 1,17 ︰ 1,16 ︰ 1,15 ︰ 1,14 ︰ 1,13 ︰ 1,12 ︰ 1,11 ︰ 1,10 ︰ 1,
9 ︰ 1,8 ︰ 1,7 ︰ 1,6 ︰ 1,5 ︰ 1,4 ︰ 1,3 ︰ 1,2 ︰ 1,1 ︰ 1,1 ︰ 2,
1 ︰ 3,1 ︰ 4,1 ︰ 5,1 ︰ 6,1 ︰ 7,1 ︰ 8,1 ︰ 9,1 ︰ 10,1 ︰ 11,1 ︰
12nd, 1 ︰ 13,1 ︰ 14,1 ︰ 15,1 ︰ 16,1 ︰ 17,1 ︰ 18,1 ︰ 19,1 ︰ 20,
Wherein when acetyl worm nitrile and fipronil bisamide weight ratio are 1：Co-toxicity coefficient is maximum when 1, synergy
Effect the most substantially, to the beetle in various crop, leafhopper, aphid, aleyrodid, beet armyworm,
The preventing and treating of diamondback moth, rice leaf roller, striped rice borer or yellow rice borer has obvious synergistic effect,
Co-toxicity coefficient is more than 120.
Effect experiment part：Test medicine is researched and developed by Shaanxi Welch Crop Protection Co., Ltd., carried
For acetyl worm nitrile suspending agent (autogamy) of comparison medicament 10%, 20% fipronil bisamide moisture dissipate
Granula (purchased in market).
Application Example triacetyl worm nitrile and fipronil bisamide and its compounding preventing and treating cotton aphid drug effect
Experiment
This test arrangement is investigated cotton aphid insect pest and is referred in Shaanxi Province Weinan City Dali County, before medicine
Number, in insect pest early period of origination dispenser, 3 days after dispenser, investigates insect pest index in 10 days, 20 days
And calculate preventive effect.Result of the test is as follows：
The acetyl worm nitrile of table 10 and fipronil bisamide and its compounding preventing and treating cotton aphid test of pesticide effectiveness
As can be seen from Table 10, cotton can effectively be prevented and treated after acetyl worm nitrile and fipronil bisamide compounding
Flower aphid, prevention effect is above 96%, and better than the preventive effect of single dose, and preventive effect phase is long.In examination
Test target crop is had no adverse effects in scope of medication.
The acetyl worm nitrile of Application Example four and fipronil bisamide and its compounding preventing and treating paddy rice cnaphalocrocis
The snout moth's larva test of pesticide effectiveness
This test arrangement investigates paddy rice rice leaf roller worm in Shaanxi Province Hanzhong suburban area before medicine
Evil index, in insect pest early period of origination dispenser, 3 days after dispenser, investigates insect pest in 10 days, 20 days
Index simultaneously calculates preventive effect.Result of the test is as follows：
The acetyl worm nitrile of table 11 prevents and treats the paddy rice rice leaf roller test of pesticide effectiveness with fipronil bisamide and its compounding
As can be seen from Table 11, can effectively prevent harnessing the river after acetyl worm nitrile and fipronil bisamide compounding
Rice rice leaf roller, proves that acetyl worm nitrile also may be used after being compounded with fipronil bisamide through inventor's experiment
Effectively to prevent and treat rice-stem borer, yellow rice borer, prevention effect is above 96%, better than single dose
Preventive effect, and preventive effect phase is long.Target crop is had no adverse effects in experiment scope of medication.
The acetyl worm nitrile of Application Example five and fipronil bisamide and its compounding preventing and treating brassicaceous vegetable
The diamondback moth test of pesticide effectiveness
This test arrangement investigates brassicaceous vegetable pickles in Shaanxi Province Hanzhong suburban area before medicine
Moth insect pest index, in insect pest early period of origination dispenser, 3 days after dispenser, investigates for 10 days, 20 days
Insect pest index simultaneously calculates preventive effect.Result of the test is as follows：
The acetyl worm nitrile of table 12 and fipronil bisamide and its compounding preventing and treating brassicaceous vegetable diamondback moth test of pesticide effectiveness
As can be seen from Table 12, ten can effectively be prevented and treated after acetyl worm nitrile and fipronil bisamide compounding
Zi Hua sections vegetables diamondback moth, after proving that acetyl worm nitrile is compounded with fipronil bisamide through inventor's experiment
Brassicaceous vegetable beet armyworm can also effectively be prevented and treated, prevention effect is above 96%, excellent
In the preventive effect of single dose, and preventive effect phase is long.To target crop without bad shadow in experiment scope of medication
Ring.
The acetyl worm nitrile of Application Example six and fipronil bisamide and its compounding preventing and treating cabbage flea beetle drug effect
Experiment
This test arrangement is investigated cabbage flea beetle insect pest and is referred in Shaanxi Province Weinan City Dali County, before medicine
Number, in insect pest early period of origination dispenser, 3 days after dispenser, investigates insect pest index in 10 days, 20 days
And calculate preventive effect.Result of the test is as follows：
The acetyl worm nitrile of table 13 and fipronil bisamide and its compounding preventing and treating cabbage flea beetle test of pesticide effectiveness
As can be seen from Table 13, can effectively prevent and treat sweet after acetyl worm nitrile and fipronil bisamide compounding
Blue flea beetle, proves that acetyl worm nitrile can also be effective after being compounded with fipronil bisamide through inventor's experiment
Preventing and treating cabbage aphid, diamondback moth, beet armyworm, prevention effect is above 96%, better than list
The preventive effect of agent, and preventive effect phase is long.Target crop is had no adverse effects in experiment scope of medication.
Drawn by the experiment of different places throughout the country afterwards, acetyl worm nitrile and fipronil bisamide
After compounding to the beetle in various crop, leafhopper, aphid, aleyrodid, beet armyworm, diamondback moth,
The preventive effect of the common insect pests such as rice leaf roller, striped rice borer or yellow rice borer is better than more than 96%
Single dose preventive effect, synergistic effect is obvious.
Claims (6)
1. the Pesticidal combination of a kind of nitrile of worm containing acetyl and fipronil bisamide, it is characterised in that：
Active ingredient is the weight ratio of acetyl worm nitrile and fipronil bisamide, acetyl worm nitrile and fipronil bisamide
It is the ︰ 1 of 1 ︰ 80~80.
2. Insecticidal combinations of the nitrile of worm containing acetyl according to claim 1 and fipronil bisamide
Thing, it is characterised in that：The weight ratio of acetyl worm nitrile and fipronil bisamide is the ︰ 1 of 1 ︰ 40~40.
3. Insecticidal combinations of the nitrile of worm containing acetyl according to claim 2 and fipronil bisamide
Thing, it is characterised in that：The weight ratio of second azoles mite nitrile and fipronil bisamide is 20:1~1:20.
4. double acyls of the nitrile of worm containing acetyl according to any one of claim 1 to 3 and fluorine worm
The Pesticidal combination of amine, it is characterised in that：Composition be made wettable powder, water dispersible granules,
Suspending agent, suspension emulsion, aqueous emulsion, microemulsion, microcapsule suspending agent, microcapsule suspension-suspendinagent agent,
Thermal fog, ultra-low-volume formulation.
5. Insecticidal combinations of the nitrile of worm containing acetyl according to claim 4 and fipronil bisamide
Thing is used to prevent and treat the purposes of insect on crops.
6. purposes according to claim 5, it is characterised in that：Described insect is first
Worm, leafhopper, aphid, aleyrodid, beet armyworm, diamondback moth, rice leaf roller, striped rice borer or
Yellow rice borer.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510848525.5A CN106804597A (en) | 2015-11-27 | 2015-11-27 | A kind of Pesticidal combination of the nitrile of worm containing acetyl and fipronil bisamide |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510848525.5A CN106804597A (en) | 2015-11-27 | 2015-11-27 | A kind of Pesticidal combination of the nitrile of worm containing acetyl and fipronil bisamide |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106804597A true CN106804597A (en) | 2017-06-09 |
Family
ID=59103151
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510848525.5A Pending CN106804597A (en) | 2015-11-27 | 2015-11-27 | A kind of Pesticidal combination of the nitrile of worm containing acetyl and fipronil bisamide |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106804597A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109221149A (en) * | 2018-10-10 | 2019-01-18 | 深圳诺普信农化股份有限公司 | A kind of fertilizer granules containing bromine worm fluorobenzene bisamide and its application |
| CN113197208A (en) * | 2021-05-11 | 2021-08-03 | 安徽丰乐农化有限责任公司 | Insecticidal composition containing flubendiamide and acetoprole and application thereof |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102084862A (en) * | 2011-03-19 | 2011-06-08 | 陕西汤普森生物科技有限公司 | Insecticidal composition containing ethiprole |
-
2015
- 2015-11-27 CN CN201510848525.5A patent/CN106804597A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102084862A (en) * | 2011-03-19 | 2011-06-08 | 陕西汤普森生物科技有限公司 | Insecticidal composition containing ethiprole |
Non-Patent Citations (2)
| Title |
|---|
| PIERLUIGI CABONI 等: ""phenylpyrazole insectcide photochemistry,metabolism, and GABA ergic action:ethiprole compared with fipronil"", 《JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY》 * |
| 狄凤娟: ""2016年-2020年专利到期的农药品种之乙酰虫腈"", 《今日农药》 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109221149A (en) * | 2018-10-10 | 2019-01-18 | 深圳诺普信农化股份有限公司 | A kind of fertilizer granules containing bromine worm fluorobenzene bisamide and its application |
| CN113197208A (en) * | 2021-05-11 | 2021-08-03 | 安徽丰乐农化有限责任公司 | Insecticidal composition containing flubendiamide and acetoprole and application thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104996431B (en) | A kind of Efficient insecticidal composition containing propylene glycol alginate | |
| CN106605654A (en) | Insecticidal composition containing SYP-9625 | |
| CN106605657A (en) | Pesticide combination containing SYP-9625 | |
| CN104430369A (en) | Insecticidal composition containing trifluoro-phenylpyridine and amides | |
| CN104115845B (en) | A kind of high-efficient pesticide composition containing fluorobenzene insect amide | |
| CN104738045B (en) | A kind of Pesticidal combination containing propylene glycol alginate | |
| CN106804597A (en) | A kind of Pesticidal combination of the nitrile of worm containing acetyl and fipronil bisamide | |
| CN106614697A (en) | SYP-9625-containing insecticidal pesticide composition | |
| CN106804612A (en) | A kind of Pesticidal combination of the nitrile of worm containing acetyl and thiacloprid | |
| CN107027785A (en) | A kind of Pesticidal combination containing four Tolfenpyrads and antibioticses | |
| CN103931641A (en) | Insecticidal composition containing silvchongxian'an and carbamate | |
| CN104115830B (en) | A kind of Pesticidal combination containing fluorobenzene insect amide and neires toxin | |
| CN105104383B (en) | A kind of Efficient insecticidal composition containing Spiromesifen | |
| CN106804600A (en) | A kind of Pesticidal combination of the nitrile of worm containing acetyl and pymetrozine | |
| CN106804596A (en) | A kind of Pesticidal combination of the nitrile of worm containing acetyl and Rynaxypyr | |
| CN106804613A (en) | A kind of Pesticidal combination of the nitrile of worm containing acetyl and Diacloden | |
| CN106852338A (en) | A kind of Pesticidal combination of the nitrile of worm containing acetyl and clothianidin | |
| CN108077286A (en) | A kind of Pesticidal combination containing ethyl pleocidin and butene-fipronil | |
| CN106852328A (en) | A kind of Pesticidal combination of the nitrile of worm containing acetyl and multiple killing teichomycin | |
| CN104106587A (en) | Insecticidal composition containing flubendiamide and carbamate | |
| CN105746526B (en) | A kind of Pesticidal combination for containing four chlorantraniliproles and biogenic substances | |
| CN103371168B (en) | High-efficiency insecticide composition | |
| CN106804602A (en) | A kind of Pesticidal combination of the nitrile of worm containing acetyl and AVM | |
| CN106852337A (en) | A kind of Pesticidal combination of the nitrile of worm containing acetyl and sulfoxaflor | |
| CN103858925B (en) | A kind of Pesticidal combination containing carbosulfan and diazinon |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170609 |