CN106804596A - A kind of Pesticidal combination of the nitrile of worm containing acetyl and Rynaxypyr - Google Patents
A kind of Pesticidal combination of the nitrile of worm containing acetyl and Rynaxypyr Download PDFInfo
- Publication number
- CN106804596A CN106804596A CN201510846878.1A CN201510846878A CN106804596A CN 106804596 A CN106804596 A CN 106804596A CN 201510846878 A CN201510846878 A CN 201510846878A CN 106804596 A CN106804596 A CN 106804596A
- Authority
- CN
- China
- Prior art keywords
- rynaxypyr
- nitrile
- acetyl
- worm
- agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a kind of nitrile of worm containing acetyl and the Pesticidal combination of Rynaxypyr, effective active composition is acetyl worm nitrile and Rynaxypyr, and the weight ratio of acetyl worm nitrile and Rynaxypyr is the ︰ 1 of 1 ︰ 80~80.The present composition has synergistic effect to the various pests for endangering agricultural production, reduces pesticide usage amount, reduces residual quantity of the agricultural chemicals on crop, alleviates environmental pollution, and to person poultry safety, Environmental compatibility is good, and insect is not likely to produce the resistance to the action of a drug.
Description
Technical field
The invention belongs to technical field of pesticide, it is related to a kind of nitrile of worm containing acetyl and Rynaxypyr
Application of the Pesticidal combination on crop pests.
Background technology
Acetyl worm nitrile：Molecular formula：C13H10Cl2F3N3O2S, acetyl worm nitrile is a wide spectrum
Insecticide, its insecticidal mechanism is the chlorine for hindering insect GABA (GABA) control
Compound is metabolized.
Rynaxypyr：Category O-formammidotiazol-benzamide insecticide.Mainly activate
Blue Buddhist nun's alkali acceptor, the calcium ion of storage, causes muscle in release smooth muscle and striated muscle cell
Regulation is weak, paralysis, until last insect is dead.The active ingredient shows dynamic to lactation
Thing and insect orchid Buddhist nun's alkali extremely significant selective difference of acceptor, substantially increase to mammal
With the security of other vertebrates.
But in the real process of agricultural production, pest control is easiest to generate the problem that
The generation of pest resistance to insecticide.Different cultivars composition is compounded, and is that preventing and treating resistant insect is very normal
The method seen.Heterogeneity is compounded, and judges that certain is answered according to practical application effect
Be synergy, plus and or antagonism.In most cases, the compounding effect of agricultural chemicals
All it is additive effect, really has the compounding of synergistic effect seldom, especially synergistic effect is very
Substantially, co-toxicity coefficient compounding very high is just less.Studied by inventor, found second
The relevant report of acyl worm nitrile and Rynaxypyr compounding is not yet disclosed.
The content of the invention
Have that synergistic function, use cost be low, preventive effect the purpose of the present invention is to propose to one kind
The good nitrile of worm containing acetyl and the Pesticidal combination of Rynaxypyr.
The Pesticidal combination of the nitrile of worm containing acetyl proposed by the present invention and Rynaxypyr, acetyl worm
Nitrile and Rynaxypyr weight ratio are the ︰ 1 of 1 ︰ 80~80, acetyl worm nitrile and Rynaxypyr
Preferred weight ratio is the ︰ 1 of 1 ︰ 40~40；More preferably acetyl worm nitrile and Rynaxypyr
Weight ratio is 20:1~1:20.
The Pesticidal combination of the nitrile of worm containing acetyl proposed by the present invention and Rynaxypyr is used to prevent
Control the purposes of insect on crops, described crops include cereal crops, legume crop,
Fibre crops, sugar crop, melon crop, fruits crop, dry fruit crop, hobby are made
Thing, root crop, oil crops, flower crop, medicinal crop, crop, green manure
Pasture crop；Described insect is beetle, leafhopper, aphid, aleyrodid, beet armyworm, pickles
Moth, apple leaf miner, heart-eating worm, rice leaf roller, striped rice borer or yellow rice borer.
The weight ratio of acetyl worm nitrile and Rynaxypyr is the ︰ 1 of 1 ︰ 80~80.Usual composition
The weight percentage of middle active component for gross weight 0.5%~90%, preferably 5%~
80%.According to different preparation types, active component content scope is different.Generally, liquid
Body preparation contains by weight 1%~70% active material, preferably 5%~50%；Gu
Body preparation contains by weight 5%~80% active material, preferably 10%~80%.
At least contain a kind of surfactant in Pesticidal combination of the invention, be beneficial to when applying
Dispersion of the active component in water.Surface-active contents are the 5%~30% of total formulation weight,
Balance of solid or liquid diluent.
Pesticidal combination of the invention can by user using it is preceding through dilute or directly use.
Its preparation can be prepared by common processing method known in those skilled in the art, will activity
After material mixes with liquid flux or solid carrier, surfactant such as dispersant, steady is added
Determine one or more in agent, wetting agent, binding agent, defoamer, disintegrant, antifreeze etc..
Pesticidal combination of the invention, can be processed into acceptable dose on any agricultural chemicals on demand
Type, wherein more preferably formulation be wettable powder, water dispersible granules, suspending agent, suspension emulsion,
Aqueous emulsion, microemulsion, microcapsule suspending agent, microcapsule suspension-suspendinagent agent, can also be made effervesce
Tablet, seed coat agent, ultra-low-volume formulation, aqua, soluble liquid, soluble powder, hot mist
Agent.
Composition is when being made wettable powder comprising following constituent content：Acetyl worm nitrile 0.1%~
80%th, Rynaxypyr 0.1%~80%, dispersant 2%~10%, wetting agent 2%~10%,
Filler surplus.
Composition includes following constituent content when being made water dispersible granules：Acetyl worm nitrile 0.1%~
80%th, Rynaxypyr 0.1%~80%, dispersant 3%~12%, wetting agent 1%~8%,
Disintegrant 1%~10%, binding agent 0~8%, filler surplus.
Composition includes following constituent content when being made suspending agent：Acetyl worm nitrile 0.1%~50%,
Rynaxypyr 0.1%~50%, dispersant 2%~10%, wetting agent 2%~10%, froth breaking
Agent 0.01%~2%, thickener 0~2%, antifreeze 0~8%, deionized water add to 100%.
Composition includes following constituent content when being made suspension emulsion：Acetyl worm nitrile 0.1%~50%,
It is Rynaxypyr 0.1%~50%, dispersant 2%~10%, defoamer 0.01%~2%, molten
Agent 1%~15%, thickener 0~2%, emulsifying agent 2%~12%, antifreeze 0~8%, deionization
Water adds to 100%.
Composition is when being made aqueous emulsion comprising following constituent content：Acetyl worm nitrile 0.1%~50%,
Rynaxypyr 0.1%~50%, solvent 1%~30%, emulsifying agent 1%~15%, antifreeze
0~8%, thickener 0~2%, defoamer 0.01%~2%, deionized water supply surplus.
Composition includes following constituent content when being made microcapsule suspending agent：Acetyl worm nitrile
0.1%~50%, Rynaxypyr 0.1%~50%, macromolecule cyst material 2%~10%, point
Powder 1%~10%, organic solvent 1%~10%, defoamer 0.01%~2%, emulsifying agent 1%~7%,
PH adjusting agent 0.01%~5%, deionized water adds to 100%.
Composition includes following constituent content when being made microcapsule suspension-suspendinagent agent：Acetyl worm nitrile
0.1%~50%, Rynaxypyr 0.1%~50%, macromolecule cyst material 2%~10%, point
Powder 1%~12%, wetting agent 1%~8%, organic solvent 1%~15%, emulsifying agent 1%~6%,
Defoamer 0.01%~2%, thickener 0~2%, pH adjusting agent 0.01%~5%, deionized water
Add to 100%.
Wettable powder the key technical indexes of the invention：
Water dispersible granules the key technical indexes of the invention：
Suspending agent the key technical indexes of the invention：
Suspension emulsion the key technical indexes of the invention：
Aqueous emulsion the key technical indexes of the invention：
Microcapsule suspending agent the key technical indexes of the invention：
Microcapsule suspension-suspendinagent agent the key technical indexes of the invention：
The advantage of the invention is that：
(1) after acetyl worm nitrile is compounded with Rynaxypyr, with obvious synergy and lasting effect；
(2) to cereal crops, legume crop, fibre crops, sugar crop, melon crop, water
Orchard crop, dry fruit crop, hobby crop, root crop, oil crops, flowers make
Thing, medicinal crop, crop, green manure pasture crop insect have greater activity；(3) subtract
Lack pesticide usage amount, reduced residual quantity of the agricultural chemicals on crop, alleviate environmental pollution；
(4) to person poultry safety, Environmental compatibility is good；And preparation adhesion strength strengthens, resistance to rainwater punching
Brush.
Specific embodiment
With reference to embodiment to further instruction of the present invention, the percentage in embodiment is
Percentage by weight, but the invention is not limited in this.
Application Example one
The wettable powder of embodiment 1~4
By acetyl worm nitrile, Rynaxypyr, dispersant, wetting agent, filler in mixed cylinder
It is well mixed, remixed after being crushed through airslide disintegrating mill uniform, you can be obtained of the present invention
Wettable powder product, is specifically shown in Table 1.
The each component of 1 embodiment of table 1~4 and weight portion
The water dispersible granules of embodiment 5~8
By acetyl worm nitrile, Rynaxypyr, dispersant, wetting agent, disintegrant, filler etc.
The particle diameter for being needed through air-flow crushing together, add binding agent (can add to be not added with) etc. its
Its auxiliary agent, obtains materials of pelletizing.Item is quantitatively sent into fluidized bed granulating dryer by system
After grain and drying, you can water dispersible granules product of the present invention is obtained, 2 are specifically shown in Table.
The each component of 2 embodiment of table 5~8 and weight portion
The suspending agent of embodiment 9~12
By dispersant, wetting agent, defoamer, thickener (can add to be not added with), antifreeze (can
Plus can be not added with), it is well mixed by high speed shear, acetyl worm nitrile, Rynaxypyr are added,
Ball milling 2~3 hours in ball mill, make diameter of particle all below 5 μm, and surplus spends
Ionized water is supplied, you can suspending agent product of the present invention is obtained, 3 are specifically shown in Table.
The each component of 3 embodiment of table 9~12 and weight portion
The suspension emulsion of embodiment 13~15
By dispersant, defoamer, thickener (can add to be not added with), (can add can for antifreeze
It is not added with) it is well mixed by high speed shear, add Rynaxypyr, the ball in ball mill
Mill 2~3 hours, makes diameter of particle all below 5 μm, and Rynaxypyr suspending agent is obtained,
Then by acetyl worm nitrile, solvent (can add to be not added with), emulsifying agent and various auxiliary agents at a high speed
Agitator is directly emulsified in suspending agent, and surplus is supplied with deionized water, and institute of the present invention is obtained
The suspension emulsion product stated, is specifically shown in Table 4.
The each component of 4 embodiment of table 13~15 and weight portion
The aqueous emulsion of embodiment 16~18
Acetyl worm nitrile, Rynaxypyr, solvent, emulsifying agent are added together, make to be dissolved into
Homogeneous oil phase；By deionized water, antifreeze (can add to be not added with), (can add can not for thickener
Plus), defoamer mix, into homogeneous water phase.Under high velocity agitation, water is added to
Oil phase, surplus is supplied with deionized water；Aqueous emulsion product of the present invention is can be prepared by, is had
Body is shown in Table 5.
The each component of 5 embodiment of table 16~18 and weight portion
The microemulsion of embodiment 19~21
Acetyl worm nitrile, Rynaxypyr are dissolved in the homogenizer equipped with solvent, will be emulsified
Agent, antifreeze (can add to be not added with), defoamer are added in the homogenizer equipped with above-mentioned solution,
Surplus deionized water mixes and homogenizes strongly after supplying, and finally obtains clear appearance transparent
Microemulsion product of the present invention, be specifically shown in Table 6.
The each component of 6 embodiment of table 19~21 and content
Embodiment 22,23 microcapsule suspending agents
Acetyl worm nitrile, Rynaxypyr, macromolecule cyst material, solvent, defoamer are mixed
Close, make to be dissolved into homogeneous oil phase, in a shear condition, by oil phase be added to containing emulsifying agent,
In pH adjusting agent, the aqueous phase solution of dispersant, surplus is supplied with deionized water, two kinds of materials
Reacted in oil-water interfaces, form high score ascus wall, be made the present composition well dispersed
Microcapsule suspending agent product, be specifically shown in Table 7.
The embodiment 22 of table 7,23 each components and weight portion
Embodiment 24,25 microcapsule suspension-suspendinagent agents
Acetyl worm nitrile, macromolecule cyst material, solvent are mixed, make to be dissolved into homogeneous oil phase,
During oil phase is added in a shear condition containing emulsifying agent, the aqueous phase solution of pH adjusting agent,
It is made well dispersed microcapsule suspending agent.By dispersant, wetting agent, defoamer, thickener (can
Plus can be not added with) well mixed by high speed shear, Rynaxypyr is added, in ball mill
Ball milling 2~3 hours, makes diameter of particle all below 5 μm, and suspending agent is obtained, and then will
Suspending agent is added in the aqueous phase solution of micro-capsule suspension, and deionized water supplies surplus, is made
The well dispersed microcapsule suspension-suspendinagent agent product of the present composition, is specifically shown in Table 8.
The embodiment 24 of table 8,25 each components and weight portion
The embodiment of the present invention is the method being combined using Toxicity Determination and field test.First
By Toxicity Determination, clear and definite two kinds of medicaments compound by a certain percentage after co-toxicity coefficient
(CTC), CTC ＜ 80 are antagonism, and 80≤CTC≤120 are summation action, CTC
＞ 120 is synergistic effect, on this basis, then carries out field test.
Test method：The mother liquor of each mixed agent is diluted to five series concentrations respectively during experiment,
It is respectively placed in standby in beaker.Using the method that first leaching leaf is followed by worm, will be not in contact with any medicament
Blade of the same size 5s is soaked in the liquid for having configured after take out, dry naturally, put
Enter in insect box, then connect for examination larva, raised under the conditions of 25 DEG C, often process 3 times
Repeat, often repeat test worm number used for 50, while setting blank, check dead in 72h
Borer population, calculates the death rate and corrected mortality, tries to achieve virulence regression equation and calculates LC50Value.
If the control death rate is more than 10%, it is considered as invalid experiment.Computing formula is as follows：
Insect corrected mortality is converted into probit value (y), concentration for the treatment of (μ g/ml) is converted into
Logarithm value (x), virulence regression equation is drawn with least square method, and thus calculates every kind of medicine
The value of agent, co-toxicity coefficient CTC is calculated according to the abundant equations of Sun Yun.Computing formula it is following (with
Acetyl worm nitrile is standard agent, and its toxicity index is for 100)：
TI × the P of the theoretical toxicity index (TTI) of M=acetyl worm nitrileAcetyl worm nitrile+Chlorine worm benzoyl
TI × the P of amineRynaxypyr
In formula：M is the mixture of different ratio
PRynaxypyrIt is Rynaxypyr ratio shared in the composition
PAcetyl worm nitrileIt is acetyl worm nitrile ratio shared in the composition
Application Example two：
For examination insect：Brassicaceous vegetable diamondback moth
Test medicine is provided by Shaanxi Welch Crop Protection Co., Ltd..
Experimental design：Determine acetyl worm nitrile and Rynaxypyr active compound and two by pilot study
Effective lethasl concentration scope of person's different ratio mixture.
Toxicity test result
The acetyl worm nitrile of table 9 compounds the toxicity test analysis of results table to brassicaceous vegetable diamondback moth with Rynaxypyr
| Reagent agent | Proportioning | Co-toxicity coefficient (CTC) | |
| Acetyl worm nitrile | — | 1.42 | — |
| Rynaxypyr | — | 0.80 | — |
| Acetyl Chong Jing ︰ Rynaxypyrs | 80:1 | 0.73 | 192.68 |
| Acetyl Chong Jing ︰ Rynaxypyrs | 60:1 | 0.68 | 206.20 |
| Acetyl Chong Jing ︰ Rynaxypyrs | 40:1 | 0.65 | 214.41 |
| Acetyl Chong Jing ︰ Rynaxypyrs | 20:1 | 0.58 | 236.11 |
| Acetyl Chong Jing ︰ Rynaxypyrs | 9:1 | 0.54 | 244.05 |
| Acetyl Chong Jing ︰ Rynaxypyrs | 4:1 | 0.48 | 256.13 |
| Acetyl Chong Jing ︰ Rynaxypyrs | 3:2 | 0.41 | 264.38 |
| Acetyl Chong Jing ︰ Rynaxypyrs | 1:1 | 0.39 | 262.42 |
| Acetyl Chong Jing ︰ Rynaxypyrs | 1:4 | 0.35 | 250.44 |
| Acetyl Chong Jing ︰ Rynaxypyrs | 1:9 | 0.34 | 246.04 |
| Acetyl Chong Jing ︰ Rynaxypyrs | 1:20 | 0.35 | 233.42 |
| Acetyl Chong Jing ︰ Rynaxypyrs | 1:40 | 0.38 | 212.79 |
| Acetyl Chong Jing ︰ Rynaxypyrs | 1:60 | 0.39 | 206.61 |
| Acetyl Chong Jing ︰ Rynaxypyrs | 1:80 | 0.41 | 196.18 |
As shown in Table 9, acetyl worm nitrile is matched with Rynaxypyr to brassicaceous vegetable diamondback moth
During 1 80~80 ︰ 1 of ︰, co-toxicity coefficient is all higher than 120, illustrates both in the models of 1 ︰, 80~80 ︰ 1
Enclose interior mixture and show synergistic effect, when the proportioning of acetyl worm nitrile and Rynaxypyr is 1：
20~20：When 1, synergistic effect becomes apparent protruding, and co-toxicity coefficient is all higher than 230.Through application
People's experiment find the optimum ratio of acetyl worm nitrile and Rynaxypyr be 20 ︰ 1,19 ︰ 1,
18 ︰ 1,17 ︰ 1,16 ︰ 1,15 ︰ 1,14 ︰ 1,13 ︰ 1,12 ︰ 1,11 ︰ 1,10
︰ 1,9 ︰ 1,8 ︰ 1,7 ︰ 1,6 ︰ 1,5 ︰ 1,4 ︰ 1,3 ︰ 1,2 ︰ 1,3：2、1
︰ 1,1 ︰ 2,1 ︰ 3,1 ︰ 4,1 ︰ 5,1 ︰ 6,1 ︰ 7,1 ︰ 8,1 ︰ 9,1 ︰ 10,
1 ︰ 11,1 ︰ 12,1 ︰ 13,1 ︰ 14,1 ︰ 15,1 ︰ 16,1 ︰ 17,1 ︰ 18,1 ︰
19th, 1 ︰ 20, wherein when acetyl worm nitrile and Rynaxypyr weight ratio are 3：Poison is altogether when 2
Number is maximum, and synergistic effect is the most obvious, to the beetle in various crop, leafhopper, aphid, powder
Lice, beet armyworm, diamondback moth, apple leaf miner, heart-eating worm, rice leaf roller, striped rice borer or
The preventing and treating of yellow rice borer has obvious synergistic effect, and co-toxicity coefficient is more than 120.
Effect experiment part：Test medicine is researched and developed by Shaanxi Welch Crop Protection Co., Ltd., carried
For acetyl worm nitrile suspending agent (autogamy) of comparison medicament 10%, 20% Rynaxypyr moisture
Shot agent (purchased in market).
Application Example triacetyl worm nitrile and Rynaxypyr and its compounding preventing and treating cotton aphid medicine
Effect experiment
This test arrangement is investigated cotton aphid insect pest and is referred in Shaanxi Province Weinan City Dali County, before medicine
Number, in insect pest early period of origination dispenser, 3 days after dispenser, investigates insect pest index in 10 days, 20 days
And calculate preventive effect.Result of the test is as follows：
The acetyl worm nitrile of table 10 and Rynaxypyr and its compounding preventing and treating cotton aphid test of pesticide effectiveness
As can be seen from Table 10, can effectively be prevented and treated after acetyl worm nitrile and Rynaxypyr compounding
Cotton aphid, prevention effect is above 96%, and better than the preventive effect of single dose, and preventive effect phase is long.
Target crop is had no adverse effects in experiment scope of medication.
The acetyl worm nitrile of Application Example four and Rynaxypyr and its vertical volume of compounding preventing and treating paddy rice rice
The leaf snout moth's larva test of pesticide effectiveness
This test arrangement investigates paddy rice rice leaf roller worm in Shaanxi Province Hanzhong suburban area before medicine
Evil index, in insect pest early period of origination dispenser, 3 days after dispenser, investigates insect pest in 10 days, 20 days
Index simultaneously calculates preventive effect.Result of the test is as follows：
The acetyl worm nitrile of table 11 prevents and treats the paddy rice rice leaf roller test of pesticide effectiveness with Rynaxypyr and its compounding
As can be seen from Table 11, can effectively be prevented and treated after acetyl worm nitrile and Rynaxypyr compounding
Paddy rice rice leaf roller, after proving that acetyl worm nitrile is compounded with Rynaxypyr through inventor's experiment
Rice-stem borer, yellow rice borer can also be effectively prevented and treated, prevention effect is above 96%, is better than
The preventive effect of single dose, and preventive effect phase is long.Target crop is had no adverse effects in experiment scope of medication.
The acetyl worm nitrile of Application Example five and Rynaxypyr and its compounding preventing and treating Cruciferae vegetable
The dish diamondback moth test of pesticide effectiveness
This test arrangement investigates brassicaceous vegetable pickles in Shaanxi Province Hanzhong suburban area before medicine
Moth insect pest index, in insect pest early period of origination dispenser, 3 days after dispenser, investigates for 10 days, 20 days
Insect pest index simultaneously calculates preventive effect.Result of the test is as follows：
The acetyl worm nitrile of table 12 and Rynaxypyr and its compounding preventing and treating brassicaceous vegetable diamondback moth test of pesticide effectiveness
As can be seen from Table 12, can effectively be prevented and treated after acetyl worm nitrile and Rynaxypyr compounding
Brassicaceous vegetable diamondback moth, proves that acetyl worm nitrile is answered with Rynaxypyr through inventor's experiment
Brassicaceous vegetable beet armyworm can also be effectively prevented and treated after matching somebody with somebody, prevention effect is above 96%,
Better than the preventive effect of single dose, and preventive effect phase is long.To target crop without bad in experiment scope of medication
Influence.
The acetyl worm nitrile of Application Example six and Rynaxypyr and its compounding preventing and treating cabbage flea beetle medicine
Effect experiment
This test arrangement is investigated cabbage flea beetle insect pest and is referred in Shaanxi Province Weinan City Dali County, before medicine
Number, in insect pest early period of origination dispenser, 3 days after dispenser, investigates insect pest index in 10 days, 20 days
And calculate preventive effect.Result of the test is as follows：
The acetyl worm nitrile of table 13 and Rynaxypyr and its compounding preventing and treating cabbage flea beetle test of pesticide effectiveness
As can be seen from Table 13, can effectively be prevented and treated after acetyl worm nitrile and Rynaxypyr compounding
Cabbage flea beetle, proves that acetyl worm nitrile can also after being compounded with Rynaxypyr through inventor's experiment
Effectively preventing and treating cabbage aphid, diamondback moth, beet armyworm, prevention effect is above 96%, excellent
In the preventive effect of single dose, and preventive effect phase is long.To target crop without bad shadow in experiment scope of medication
Ring.
Drawn by the experiment of different places throughout the country afterwards, acetyl worm nitrile and chlorine worm benzoyl
To the beetle in various crop, leafhopper, aphid, aleyrodid, beet armyworm, pickles after amine compounding
The common insect pests such as moth, apple leaf miner, heart-eating worm, rice leaf roller, striped rice borer or yellow rice borer
More than 96%, better than single dose preventive effect, synergistic effect is obvious for preventive effect.
Claims (6)
1. the Pesticidal combination of a kind of nitrile of worm containing acetyl and Rynaxypyr, it is characterised in that：
Active ingredient is the weight of acetyl worm nitrile and Rynaxypyr, acetyl worm nitrile and Rynaxypyr
Amount is than being the ︰ 1 of 1 ︰ 80~80.
2. the desinsection group of the nitrile of worm containing acetyl according to claim 1 and Rynaxypyr
Compound, it is characterised in that：The weight ratio of acetyl worm nitrile and Rynaxypyr is 1 ︰ 40~40
︰ 1.
3. the desinsection group of the nitrile of worm containing acetyl according to claim 2 and Rynaxypyr
Compound, it is characterised in that：The weight ratio of second azoles mite nitrile and Rynaxypyr is 20:1~1:20.
4. the nitrile of worm containing acetyl according to any one of claim 1 to 3 and chlorine worm benzene first
The Pesticidal combination of acid amides, it is characterised in that：Composition is made wettable powder, water-dispersible grain
Agent, suspending agent, suspension emulsion, aqueous emulsion, microemulsion, microcapsule suspending agent, microcapsule suspension-outstanding
Floating agent, thermal fog, ultra-low-volume formulation.
5. the desinsection group of the nitrile of worm containing acetyl according to claim 4 and Rynaxypyr
Compound is used to prevent and treat the purposes of insect on crops.
6. purposes according to claim 5, it is characterised in that：Described insect is first
Worm, leafhopper, aphid, aleyrodid, beet armyworm, diamondback moth, apple leaf miner, heart-eating worm, rice
Leaf-roller, striped rice borer or yellow rice borer.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510846878.1A CN106804596A (en) | 2015-11-27 | 2015-11-27 | A kind of Pesticidal combination of the nitrile of worm containing acetyl and Rynaxypyr |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510846878.1A CN106804596A (en) | 2015-11-27 | 2015-11-27 | A kind of Pesticidal combination of the nitrile of worm containing acetyl and Rynaxypyr |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106804596A true CN106804596A (en) | 2017-06-09 |
Family
ID=59103165
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510846878.1A Pending CN106804596A (en) | 2015-11-27 | 2015-11-27 | A kind of Pesticidal combination of the nitrile of worm containing acetyl and Rynaxypyr |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106804596A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109221149A (en) * | 2018-10-10 | 2019-01-18 | 深圳诺普信农化股份有限公司 | A kind of fertilizer granules containing bromine worm fluorobenzene bisamide and its application |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101014247A (en) * | 2004-07-01 | 2007-08-08 | 杜邦公司 | Synergistic mixtures of anthranilamide invertebrate pest control agents |
-
2015
- 2015-11-27 CN CN201510846878.1A patent/CN106804596A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101014247A (en) * | 2004-07-01 | 2007-08-08 | 杜邦公司 | Synergistic mixtures of anthranilamide invertebrate pest control agents |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109221149A (en) * | 2018-10-10 | 2019-01-18 | 深圳诺普信农化股份有限公司 | A kind of fertilizer granules containing bromine worm fluorobenzene bisamide and its application |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106605654A (en) | Insecticidal composition containing SYP-9625 | |
| CN104430369A (en) | Insecticidal composition containing trifluoro-phenylpyridine and amides | |
| CN106605657A (en) | Pesticide combination containing SYP-9625 | |
| CN104738045B (en) | A kind of Pesticidal combination containing propylene glycol alginate | |
| CN103960280A (en) | High-efficiency insecticidal composition containing tetrachlorantraniliprole | |
| CN106804612A (en) | A kind of Pesticidal combination of the nitrile of worm containing acetyl and thiacloprid | |
| CN106804597A (en) | A kind of Pesticidal combination of the nitrile of worm containing acetyl and fipronil bisamide | |
| CN103931641A (en) | Insecticidal composition containing silvchongxian'an and carbamate | |
| CN104115830B (en) | A kind of Pesticidal combination containing fluorobenzene insect amide and neires toxin | |
| CN106804596A (en) | A kind of Pesticidal combination of the nitrile of worm containing acetyl and Rynaxypyr | |
| CN104509534A (en) | Insect disinfestation composition containing trifluorobenzene pyrimidine and nereistoxin | |
| CN106852338A (en) | A kind of Pesticidal combination of the nitrile of worm containing acetyl and clothianidin | |
| CN106804613A (en) | A kind of Pesticidal combination of the nitrile of worm containing acetyl and Diacloden | |
| CN103931620A (en) | Insecticidal composition containing silvchongxian'an and nereistoxin insecticide | |
| CN104106587A (en) | Insecticidal composition containing flubendiamide and carbamate | |
| CN105746526B (en) | A kind of Pesticidal combination for containing four chlorantraniliproles and biogenic substances | |
| CN106852328A (en) | A kind of Pesticidal combination of the nitrile of worm containing acetyl and multiple killing teichomycin | |
| CN106804602A (en) | A kind of Pesticidal combination of the nitrile of worm containing acetyl and AVM | |
| CN103858925B (en) | A kind of Pesticidal combination containing carbosulfan and diazinon | |
| CN106818763A (en) | A kind of Pesticidal combination of the nitrile of worm containing acetyl and ethyl pleocidin | |
| CN106857538A (en) | A kind of Pesticidal combination of the nitrile of worm containing acetyl and Tolfenpyrad | |
| CN105557735A (en) | Insecticidal composition containing N-(2-tert-butylamineformoxyl-4-chloro-6-methylphenyl)-1-(3-chloropyridine-2-pyridinyl)-3-fluoro-methoxy-1H-pyrazole-5-carboxamide | |
| CN106852327A (en) | A kind of Pesticidal combination of the nitrile of worm containing acetyl and Nitenpyram | |
| CN106852337A (en) | A kind of Pesticidal combination of the nitrile of worm containing acetyl and sulfoxaflor | |
| CN106719773A (en) | A kind of high-efficient pesticide composition of the nitrile of worm containing acetyl |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170609 |
|
| RJ01 | Rejection of invention patent application after publication |