CN106804613A - A kind of Pesticidal combination of the nitrile of worm containing acetyl and Diacloden - Google Patents
A kind of Pesticidal combination of the nitrile of worm containing acetyl and Diacloden Download PDFInfo
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- CN106804613A CN106804613A CN201510846286.XA CN201510846286A CN106804613A CN 106804613 A CN106804613 A CN 106804613A CN 201510846286 A CN201510846286 A CN 201510846286A CN 106804613 A CN106804613 A CN 106804613A
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- diacloden
- nitrile
- acetyl
- worm
- pesticidal combination
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Abstract
The invention discloses a kind of nitrile of worm containing acetyl and the Pesticidal combination of Diacloden, effective active composition is acetyl worm nitrile and Diacloden, and the weight ratio of acetyl worm nitrile and Diacloden is the ︰ 1 of 1 ︰ 80~80.The present composition has synergistic effect to the various pests for endangering agricultural production, reduces pesticide usage amount, reduces residual quantity of the agricultural chemicals on crop, alleviates environmental pollution, and to person poultry safety, Environmental compatibility is good, and insect is not likely to produce the resistance to the action of a drug.
Description
Technical field
The invention belongs to technical field of pesticide, it is related to the desinsection of a kind of nitrile of worm containing acetyl and Diacloden
Application of the composition on crop pests.
Background technology
Acetyl worm nitrile：Molecular formula：C13H10Cl2F3N3O2S, acetyl worm nitrile is a wide spectrum
Insecticide, its insecticidal mechanism is the chlorine for hindering insect GABA (GABA) control
Compound is metabolized.
Diacloden：The medicine is a kind of new High-efficiency low-toxicity broad spectrum.It is the new second generation
The first generation anabasine insecticides such as nicotinic insecticide, the mechanism of action and imidacloprid are similar,
But with activity higher.Have to insect stomach toxicity, tag, systemic action, speed of action
Hurry up, the features such as the lasting period is long.To sucking pest such as aphid, plant hopper, leafhopper, aleyrodid etc.
Preventive effect is preferable.
But in the real process of agricultural production, pest control is easiest to generate the problem that
The generation of pest resistance to insecticide.Different cultivars composition is compounded, and is that preventing and treating resistant insect is very normal
The method seen.Heterogeneity is compounded, and judges that certain is answered according to practical application effect
Be synergy, plus and or antagonism.In most cases, the compounding effect of agricultural chemicals
All it is additive effect, really has the compounding of synergistic effect seldom, especially synergistic effect is very
Substantially, co-toxicity coefficient compounding very high is just less.Studied by inventor, found second
The relevant report of acyl worm nitrile and Thiamethoxam compound is not yet disclosed.
The content of the invention
Have that synergistic function, use cost be low, preventive effect the purpose of the present invention is to propose to one kind
The good nitrile of worm containing acetyl and the Pesticidal combination of Diacloden.
The Pesticidal combination of the nitrile of worm containing acetyl proposed by the present invention and Diacloden, acetyl worm nitrile and thiophene
Worm piperazine weight ratio is the ︰ 1 of 1 ︰ 80~80, and acetyl worm nitrile and the preferred weight ratio of Diacloden are 1 ︰
40~40 ︰ 1；More preferably the weight ratio of acetyl worm nitrile and Diacloden is 20:1~1:20.
The Pesticidal combination of the nitrile of worm containing acetyl proposed by the present invention and Diacloden is used to prevent and treat farming
The purposes of insect on thing, described crops include cereal crops, legume crop, fibre crops,
Sugar crop, melon crop, fruits crop, dry fruit crop, hobby crop, tubers
Crop, oil crops, flower crop, medicinal crop, crop, green manure pasture crop；
Described insect is beetle, leafhopper, aphid, aleyrodid, scale insect, thrips, plant hopper, two changes
Snout moth's larva, yellow rice borer, rice leaf roller or diamondback moth.
The weight ratio of acetyl worm nitrile and Diacloden is the ︰ 1 of 1 ︰ 80~80.Activity in usual composition
The weight percentage of component is the 0.5%~90% of gross weight, preferably 5%~80%.
According to different preparation types, active component content scope is different.Generally, liquid preparation
Contain by weight 1%~70% active material, preferably 5%~50%；Solid pharmaceutical preparation
Contain by weight 5%~80% active material, preferably 10%~80%.
At least contain a kind of surfactant in Pesticidal combination of the invention, be beneficial to when applying
Dispersion of the active component in water.Surface-active contents are the 5%~30% of total formulation weight,
Balance of solid or liquid diluent.
Pesticidal combination of the invention can by user using it is preceding through dilute or directly use.
Its preparation can be prepared by common processing method known in those skilled in the art, will activity
After material mixes with liquid flux or solid carrier, surfactant such as dispersant, steady is added
Determine one or more in agent, wetting agent, binding agent, defoamer, disintegrant, antifreeze etc..
Pesticidal combination of the invention, can be processed into acceptable dose on any agricultural chemicals on demand
Type, wherein more preferably formulation be wettable powder, water dispersible granules, suspending agent, suspension emulsion,
Aqueous emulsion, microemulsion, microcapsule suspending agent, microcapsule suspension-suspendinagent agent, can also be made effervesce
Tablet, seed coat agent, ultra-low-volume formulation, aqua, soluble liquid, soluble powder, hot mist
Agent.
Composition is when being made wettable powder comprising following constituent content：Acetyl worm nitrile 0.1%~
80%th, Diacloden 0.1%~80%, dispersant 2%~10%, wetting agent 2%~10%, filler
Surplus.
Composition includes following constituent content when being made water dispersible granules：Acetyl worm nitrile 0.1%~
80%th, Diacloden 0.1%~80%, dispersant 3%~12%, wetting agent 1%~8%, disintegrant
1%~10%, binding agent 0~8%, filler surplus.
Composition includes following constituent content when being made suspending agent：Acetyl worm nitrile 0.1%~50%,
Diacloden 0.1%~50%, dispersant 2%~10%, wetting agent 2%~10%, defoamer
0.01%~2%, thickener 0~2%, antifreeze 0~8%, deionized water add to 100%.
Composition includes following constituent content when being made suspension emulsion：Acetyl worm nitrile 0.1%~50%,
Diacloden 0.1%~50%, dispersant 2%~10%, defoamer 0.01%~2%, solvent 1%~15%,
Thickener 0~2%, emulsifying agent 2%~12%, antifreeze 0~8%, deionized water add to 100%.
Composition is when being made aqueous emulsion comprising following constituent content：Acetyl worm nitrile 0.1%~50%,
Diacloden 0.1%~50%, solvent 1%~30%, emulsifying agent 1%~15%, antifreeze 0~8%,
Thickener 0~2%, defoamer 0.01%~2%, deionized water supply surplus.
Composition includes following constituent content when being made microcapsule suspending agent：Acetyl worm nitrile
0.1%~50%, Diacloden 0.1%~50%, macromolecule cyst material 2%~10%, dispersant
1%~10%, organic solvent 1%~10%, defoamer 0.01%~2%, emulsifying agent 1%~7%,
PH adjusting agent 0.01%~5%, deionized water adds to 100%.
Composition includes following constituent content when being made microcapsule suspension-suspendinagent agent：Acetyl worm nitrile
0.1%~50%, Diacloden 0.1%~50%, macromolecule cyst material 2%~10%, dispersant
1%~12%, wetting agent 1%~8%, organic solvent 1%~15%, emulsifying agent 1%~6%, disappear
Infusion 0.01%~2%, thickener 0~2%, pH adjusting agent 0.01%~5%, deionized water add
To 100%.
Wettable powder the key technical indexes of the invention：
Water dispersible granules the key technical indexes of the invention：
Suspending agent the key technical indexes of the invention：
Suspension emulsion the key technical indexes of the invention：
Aqueous emulsion the key technical indexes of the invention：
Microcapsule suspending agent the key technical indexes of the invention：
Microcapsule suspension-suspendinagent agent the key technical indexes of the invention：
The advantage of the invention is that：
(1) after acetyl worm nitrile and Thiamethoxam compound, with obvious synergy and lasting effect；(2)
Cereal crops, legume crop, fibre crops, sugar crop, melon crop, fruits are made
Thing, dry fruit crop, hobby crop, root crop, oil crops, flower crop, medicine
There is greater activity with crop, crop, green manure pasture crop insect；(3) agriculture is reduced
Medicinal dose, reduces residual quantity of the agricultural chemicals on crop, alleviates environmental pollution；(4) it is right
Person poultry safety, Environmental compatibility is good；And preparation adhesion strength strengthens, resistance of rainwater washing against.
Specific embodiment
With reference to embodiment to further instruction of the present invention, the percentage in embodiment is
Percentage by weight, but the invention is not limited in this.
Application Example one
The wettable powder of embodiment 1~4
Acetyl worm nitrile, Diacloden, dispersant, wetting agent, filler are mixed in mixed cylinder
It is even, remixed after being crushed through airslide disintegrating mill uniform, you can wettable of the present invention is obtained
Powder product, is specifically shown in Table 1.
The each component of 1 embodiment of table 1~4 and weight portion
The water dispersible granules of embodiment 5~8
Acetyl worm nitrile, Diacloden, dispersant, wetting agent, disintegrant, filler etc. are passed through together
The particle diameter that air-flow crushing is needed, adds other auxiliary agents such as binding agent (can add to be not added with),
Obtain materials of pelletizing.Item is quantitatively sent into fluidized bed granulating dryer by granulation and dried
Afterwards, you can water dispersible granules product of the present invention is obtained, 2 are specifically shown in Table.
The each component of 2 embodiment of table 5~8 and weight portion
The suspending agent of embodiment 9~12
By dispersant, wetting agent, defoamer, thickener (can add to be not added with), antifreeze (can
Plus can be not added with), it is well mixed by high speed shear, acetyl worm nitrile, Diacloden are added, in ball
Ball milling 2~3 hours in grinding machine, make diameter of particle all below 5 μm, surplus deionization
Water is supplied, you can suspending agent product of the present invention is obtained, 3 are specifically shown in Table.
The each component of 3 embodiment of table 9~12 and weight portion
The suspension emulsion of embodiment 13~15
By dispersant, defoamer, thickener (can add to be not added with), (can add can for antifreeze
It is not added with) it is well mixed by high speed shear, add Diacloden, ball milling 2~3 in ball mill
Hour, make diameter of particle all below 5 μm, Diacloden suspending agent is obtained, then by second
Acyl worm nitrile, solvent (can add to be not added with), emulsifying agent and various auxiliary agent high speed agitators are straight
Connect and emulsify in suspending agent, surplus is supplied with deionized water, outstanding breast of the present invention is obtained
Agent product, is specifically shown in Table 4.
The each component of 4 embodiment of table 13~15 and weight portion
The aqueous emulsion of embodiment 16~18
Acetyl worm nitrile, Diacloden, solvent, emulsifying agent are added together, make to be dissolved into uniform oil
Phase；By deionized water, antifreeze (can add to be not added with), thickener (can add to be not added with), disappear
Infusion is mixed, into homogeneous water phase.Under high velocity agitation, water is added to oil phase, it is remaining
Amount is supplied with deionized water；Aqueous emulsion product of the present invention is can be prepared by, 5 are specifically shown in Table.
The each component of 5 embodiment of table 16~18 and weight portion
The microemulsion of embodiment 19~21
Acetyl worm nitrile, Diacloden are dissolved in the homogenizer equipped with solvent, by emulsifying agent, are resisted
Freeze agent (can add to be not added with), defoamer to be added in the homogenizer equipped with above-mentioned solution, surplus
Mix strongly after being supplied with deionized water and homogenize, finally obtain the transparent sheet of clear appearance
The described microemulsion product of invention, is specifically shown in Table 6.
The each component of 6 embodiment of table 19~21 and content
Embodiment 22,23 microcapsule suspending agents
Acetyl worm nitrile, Diacloden, macromolecule cyst material, solvent, defoamer are mixed, is made
Homogeneous oil phase is dissolved into, in a shear condition, oil phase is added to and is adjusted containing emulsifying agent, pH
In section agent, the aqueous phase solution of dispersant, surplus is supplied with deionized water, and two kinds of materials are in profit
Interface reacts, and forms high score ascus wall, is made the well dispersed micro-capsule of the present composition
Suspending agent product, is specifically shown in Table 7.
The embodiment 22 of table 7,23 each components and weight portion
Embodiment 24,25 microcapsule suspension-suspendinagent agents
Acetyl worm nitrile, macromolecule cyst material, solvent are mixed, make to be dissolved into homogeneous oil phase,
During oil phase is added in a shear condition containing emulsifying agent, the aqueous phase solution of pH adjusting agent,
It is made well dispersed microcapsule suspending agent.By dispersant, wetting agent, defoamer, thickener (can
Plus can be not added with) well mixed by high speed shear, add Diacloden, the ball milling in ball mill
2~3 hours, make diameter of particle all below 5 μm, suspending agent is obtained, then by suspending agent
It is added in the aqueous phase solution of micro-capsule suspension, deionized water supplies surplus, is made the present invention
The well dispersed microcapsule suspension-suspendinagent agent product of composition, is specifically shown in Table 8.
The embodiment 24 of table 8,25 each components and weight portion
The embodiment of the present invention is the method being combined using Toxicity Determination and field test.First
By Toxicity Determination, clear and definite two kinds of medicaments compound by a certain percentage after co-toxicity coefficient
(CTC), CTC ＜ 80 are antagonism, and 80≤CTC≤120 are summation action, CTC
＞ 120 is synergistic effect, on this basis, then carries out field test.
Test method：The mother liquor of each mixed agent is diluted to five series concentrations respectively during experiment,
It is respectively placed in standby in beaker.Using the method that first leaching leaf is followed by worm, will be not in contact with any medicament
Blade of the same size 5s is soaked in the liquid for having configured after take out, dry naturally, put
Enter in insect box, then connect for examination larva, raised under the conditions of 25 DEG C, often process 3 times
Repeat, often repeat test worm number used for 50, while setting blank, check dead in 72h
Borer population, calculates the death rate and corrected mortality, tries to achieve virulence regression equation and calculates LC50Value.
If the control death rate is more than 10%, it is considered as invalid experiment.Computing formula is as follows：
Insect corrected mortality is converted into probit value (y), concentration for the treatment of (μ g/ml) is converted into
Logarithm value (x), virulence regression equation is drawn with least square method, and thus calculates every kind of medicine
The value of agent, co-toxicity coefficient CTC is calculated according to the abundant equations of Sun Yun.Computing formula it is following (with
Acetyl worm nitrile is standard agent, and its toxicity index is for 100)：
TI × the P of the theoretical toxicity index (TTI) of M=acetyl worm nitrileAcetyl worm nitrile+Diacloden
TI×PDiacloden
In formula：M is the mixture of different ratio
PDiaclodenIt is Diacloden ratio shared in the composition
PAcetyl worm nitrileIt is acetyl worm nitrile ratio shared in the composition
Application Example two：
For examination insect：Orange caterpillar
Test medicine is provided by Shaanxi Welch Crop Protection Co., Ltd..
Experimental design：Determine acetyl worm nitrile and Diacloden active compound by pilot study and the two is different
Match effective lethasl concentration scope of mixture.
Toxicity test result
The toxicity test analysis of results table of the acetyl worm nitrile of table 9 and Thiamethoxam compound to orange caterpillar
| Reagent agent | Proportioning | Co-toxicity coefficient (CTC) | |
| Acetyl worm nitrile | — | 1.48 | — |
| Diacloden | — | 0.95 | — |
| Acetyl Chong Jing ︰ Diaclodens | 80:1 | 0.73 | 201.35 |
| Acetyl Chong Jing ︰ Diaclodens | 60:1 | 0.68 | 215.67 |
| Acetyl Chong Jing ︰ Diaclodens | 40:1 | 0.65 | 224.64 |
| Acetyl Chong Jing ︰ Diaclodens | 20:1 | 0.58 | 248.57 |
| Acetyl Chong Jing ︰ Diaclodens | 9:1 | 0.54 | 259.59 |
| Acetyl Chong Jing ︰ Diaclodens | 4:1 | 0.51 | 261.07 |
| Acetyl Chong Jing ︰ Diaclodens | 3:2 | 0.44 | 275.00 |
| Acetyl Chong Jing ︰ Diaclodens | 1:1 | 0.44 | 263.00 |
| Acetyl Chong Jing ︰ Diaclodens | 1:4 | 0.39 | 262.38 |
| Acetyl Chong Jing ︰ Diaclodens | 1:9 | 0.38 | 259.28 |
| Acetyl Chong Jing ︰ Diaclodens | 1:20 | 0.39 | 247.81 |
| Acetyl Chong Jing ︰ Diaclodens | 1:40 | 0.42 | 228.18 |
| Acetyl Chong Jing ︰ Diaclodens | 1:60 | 0.44 | 217.18 |
| Acetyl Chong Jing ︰ Diaclodens | 1:80 | 0.46 | 207.44 |
As shown in Table 9, acetyl worm nitrile is matched in the ︰ 1 of 1 ︰ 80~80 with Diacloden to orange caterpillar
When, co-toxicity coefficient is all higher than 120, illustrates both equal tables of mixture in the range of the ︰ 1 of 1 ︰ 80~80
Reveal synergistic effect, when the proportioning of acetyl worm nitrile and Diacloden is 1：20~20：When 1, synergy
Effect becomes apparent protruding, and co-toxicity coefficient is all higher than 245.Acetyl worm is found through applicant's experiment
Nitrile is 20 ︰ 1,19 ︰ 1,18 ︰ 1,17 ︰ 1,16 ︰ 1,15 with the optimum ratio of Diacloden
︰ 1,14 ︰ 1,13 ︰ 1,12 ︰ 1,11 ︰ 1,10 ︰ 1,9 ︰ 1,8 ︰ 1,7 ︰ 1,6
︰ 1,5 ︰ 1,4 ︰ 1,3 ︰ 1,2 ︰ 1,3:2nd, 1 ︰ 1,1 ︰ 2,1 ︰ 3,1 ︰ 4,1
︰ 5,1 ︰ 6,1 ︰ 7,1 ︰ 8,1 ︰ 9,1 ︰ 10,1 ︰ 11,1 ︰ 12,1 ︰ 13,1
︰ 14,1 ︰ 15,1 ︰ 16,1 ︰ 17,1 ︰ 18,1 ︰ 19,1 ︰ 20, wherein when acetyl worm
Nitrile is 3 with Diacloden weight ratio：Co-toxicity coefficient is maximum when 2, and synergistic effect is the most obvious, right
Beetle, leafhopper, aphid, aleyrodid, scale insect, thrips, plant hopper, two changes in various crop
The preventing and treating of snout moth's larva, yellow rice borer, rice leaf roller or diamondback moth has obvious synergistic effect, altogether
Malicious coefficient is more than 120.
Effect experiment part：Test medicine is researched and developed by Shaanxi Welch Crop Protection Co., Ltd., carried
For acetyl worm nitrile suspending agent (autogamy) of comparison medicament 10%, 25% Diacloden water dispersible granules
(purchased in market).
Application Example triacetyl worm nitrile and Diacloden and its compounding preventing and treating Cucumber blight drug effect examination
Test
This test arrangement is investigated Cucumber blight insect pest and is referred in Shaanxi Province Weinan City Dali County, before medicine
Number, in insect pest early period of origination dispenser, 3 days after dispenser, investigates insect pest index in 10 days, 20 days
And calculate preventive effect.Result of the test is as follows：
The acetyl worm nitrile of table 10 and Diacloden and its compounding preventing and treating Cucumber blight test of pesticide effectiveness
As can be seen from Table 10, cucumber aphid can effectively be prevented and treated after acetyl worm nitrile and Thiamethoxam compound
Worm, cucumber can also be effectively prevented and treated after proving acetyl worm nitrile and Thiamethoxam compound through inventor's experiment
Aleyrodid, prevention effect is above 96%, and better than the preventive effect of single dose, and preventive effect phase is long.In examination
Test target crop is had no adverse effects in scope of medication.
The acetyl worm nitrile of Application Example four and Diacloden and its compounding preventing and treating water rice hopper test of pesticide effectiveness
This test arrangement investigates water rice hopper insect pest index in Shaanxi Province Hanzhong suburban area before medicine,
In insect pest early period of origination dispenser, 3 days after dispenser, investigate insect pest indexes and count within 10 days, 20 days
Calculate preventive effect.Result of the test is as follows：
The acetyl worm nitrile of table 11 and Diacloden and its compounding preventing and treating water rice hopper test of pesticide effectiveness
As can be seen from Table 11, paddy rice can be effectively prevented and treated after acetyl worm nitrile and Thiamethoxam compound to fly
Lice, paddy rice can also be effectively prevented and treated after proving acetyl worm nitrile and Thiamethoxam compound through inventor's experiment
Striped rice borer, yellow rice borer, cnaphalocrocis, prevention effect are above 96%, anti-better than single dose
Effect, and preventive effect phase is long.Target crop is had no adverse effects in experiment scope of medication.
The acetyl worm nitrile of Application Example five and Diacloden and its compounding preventing and treating brassicaceous vegetable flea beetle
The test of pesticide effectiveness
This test arrangement investigates brassicaceous vegetable flea beetle in Shaanxi Province Hanzhong suburban area before medicine
Insect pest index, in insect pest early period of origination dispenser, 3 days after dispenser, investigates worm in 10 days, 20 days
Evil index simultaneously calculates preventive effect.Result of the test is as follows：
The acetyl worm nitrile of table 12 and Diacloden and its compounding preventing and treating brassicaceous vegetable flea beetle test of pesticide effectiveness
As can be seen from Table 12, cruciate flower can effectively be prevented and treated after acetyl worm nitrile and Thiamethoxam compound
Section's vegetables flea beetle, can also be effective after proving acetyl worm nitrile and Thiamethoxam compound through inventor's experiment
Preventing and treating brassicaceous vegetable aphid, diamondback moth, prevention effect is above 96%, better than single dose
Preventive effect, and preventive effect phase is long.Target crop is had no adverse effects in experiment scope of medication.
The acetyl worm nitrile of Application Example six and Diacloden and its compounding preventing and treating oranges and tangerines scale insect drug effect examination
Test
This test arrangement is investigated oranges and tangerines shell pests and is referred in Shaanxi Province Hanzhong suburban area, before medicine
Number, in insect pest early period of origination dispenser, 3 days after dispenser, investigates insect pest index in 10 days, 20 days
And calculate preventive effect.Result of the test is as follows：
The acetyl worm nitrile of table 13 and Diacloden and its compounding preventing and treating oranges and tangerines scale insect test of pesticide effectiveness
As can be seen from Table 13, oranges and tangerines Jie can effectively be prevented and treated after acetyl worm nitrile and Thiamethoxam compound
Shell worm, mandarin orange can also be effectively prevented and treated after proving acetyl worm nitrile and Thiamethoxam compound through inventor's experiment
Tangerine aphid, prevention effect is above 96%, and better than the preventive effect of single dose, and preventive effect phase is long.
Target crop is had no adverse effects in experiment scope of medication.
Drawn by the experiment of different places throughout the country afterwards, acetyl worm nitrile and Thiamethoxam compound
Afterwards to the beetle in various crop, leafhopper, aphid, aleyrodid, beet armyworm, diamondback moth, rice
The preventive effect of the common insect pests such as leaf-roller, striped rice borer or yellow rice borer more than 96%, better than list
Agent preventive effect, synergistic effect is obvious.
Claims (6)
1. the Pesticidal combination of a kind of nitrile of worm containing acetyl and Diacloden, it is characterised in that：Effectively
Composition is acetyl worm nitrile and Diacloden, and the weight ratio of acetyl worm nitrile and Diacloden is 1 ︰ 80~80
︰ 1.
2. the Pesticidal combination of the nitrile of worm containing acetyl according to claim 1 and Diacloden,
It is characterized in that：The weight ratio of acetyl worm nitrile and Diacloden is the ︰ 1 of 1 ︰ 40~40.
3. the Pesticidal combination of the nitrile of worm containing acetyl according to claim 2 and Diacloden,
It is characterized in that：The weight ratio of second azoles mite nitrile and Diacloden is 20:1~1:20.
4. the nitrile of worm containing acetyl according to any one of claim 1 to 3 and Diacloden
Pesticidal combination, it is characterised in that：Composition is made wettable powder, water dispersible granules, hangs
Floating agent, suspension emulsion, aqueous emulsion, microemulsion, microcapsule suspending agent, microcapsule suspension-suspendinagent agent,
Thermal fog, ultra-low-volume formulation.
5. the Pesticidal combination of the nitrile of worm containing acetyl according to claim 4 and Diacloden is used
In the purposes of insect on preventing and treating crops.
6. purposes according to claim 5, it is characterised in that：Described insect is first
Worm, leafhopper, aphid, aleyrodid, scale insect, thrips, plant hopper, striped rice borer, yellow rice borer, rice
Leaf-roller or diamondback moth.
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108432791A (en) * | 2018-03-26 | 2018-08-24 | 青岛瀚生生物科技股份有限公司 | Agricultural insecticidal composite and its application |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN1968606A (en) * | 2004-06-16 | 2007-05-23 | 拜尔农作物科学股份公司 | Synergistic insecticidal mixtures |
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2015
- 2015-11-27 CN CN201510846286.XA patent/CN106804613A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1968606A (en) * | 2004-06-16 | 2007-05-23 | 拜尔农作物科学股份公司 | Synergistic insecticidal mixtures |
Non-Patent Citations (1)
| Title |
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| 郎玉成等: "吡唑类农药品种的研究开发进展", 《现代农药》 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108432791A (en) * | 2018-03-26 | 2018-08-24 | 青岛瀚生生物科技股份有限公司 | Agricultural insecticidal composite and its application |
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Application publication date: 20170609 |