CN1968606A - Synergistic insecticidal mixtures - Google Patents
Synergistic insecticidal mixtures Download PDFInfo
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- CN1968606A CN1968606A CN 200580020100 CN200580020100A CN1968606A CN 1968606 A CN1968606 A CN 1968606A CN 200580020100 CN200580020100 CN 200580020100 CN 200580020100 A CN200580020100 A CN 200580020100A CN 1968606 A CN1968606 A CN 1968606A
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Abstract
The invention relates to insecticidal mixtures, comprising ethiprole and at least one other known active substance, belonging to the neonicotinoid family as well as to the use of said mixtures for controlling animal pests.
Description
The present invention relates to new active agent combinations (combination), this active agent combinations comprises active component second worm nitrile (ethiprole) and the other at least a reactive compound that is selected from anabasine (neonicotinoid) class series, and this bond has extraordinary insecticidal properties.
Known second worm nitrile can be used for preventing and treating animal pest, particularly insect.Also known anabasine, for example Imidacloprid (imidacloprid), thiophene worm quinoline (thiacloprid), thiophene worm amine (clothianidin), thiophene worm piperazine (thiamethoxam), Acetamiprid (acetamiprid), Nitenpyram (nitenpyram) and MTI-446 (dinotefuran), be suitable for preventing and treating animal pest, particularly insect.
The activity of these compounds is good; Yet, low or during at indivedual insect, they also have many parts that have much room for improvement under many circumstances at rate of application.
The mixture that is selected from the compound of anabasine series has synergistic activity to have now found that to comprise second worm nitrile and at least a separately---preferably just in time a kind of---, and is suitable for preventing and treating animal pest.Because should act synergistically, the consumption of reactive compound can significantly reduce, i.e. the effect of mixture is greater than the effect of component separately.
Cited compound is known.
Second worm nitrile has following structural formula:
And be known in for example " agricultural chemicals handbook (The Pesticide Manual) ", and the 13rd edition, 2003, British Crop Protection Council publishes, the 382nd page.
Anabasine compound can be by formula (I) expression,
Wherein
The Het representative is selected from the heterocyclic system of following heterocycle:
2-chloropyridine-5-base, 2-picoline-5-base, 1-oxidation-3-pyridine radicals (1-oxido-3-pyridinio), 2-chloro-1-oxidation-5-pyridine radicals, 2,3-two chloro-1-oxidation-5-pyridine radicals, oxolane-3-base, 5-methyl-oxolane-3-base, 2-diuril azoles-5-base
A representative-N (R
1) (R
2) or S (R
2),
Wherein
R
1Represent hydrogen, C
1-C
6Alkyl, phenyl-C
1-C
4Alkyl, C
3-C
6Cycloalkyl, C
2-C
6Alkenyl or C
2-C
6Alkynyl group, and
R
2Represent C
1-C
6Alkyl, C
2-C
6Alkenyl, C
2-C
6Alkynyl group ,-C (=O)-CH
3Or benzyl,
R represents C
1-C
6Alkyl, C
2-C
6Alkenyl, C
2-C
6Alkynyl group ,-C (=O)-CH
3Or benzyl, or and R
2Represent one of following groups together:
-CH
2-CH
2-,-CH
2-CH
2-CH
2-,-CH
2-O-CH
2-,-CH
2-S-CH
2-,-CH
2-NH-CH
2-,-CH
2-N (CH
3)-CH
2-, and
X represents N-NO
2, N-CN or CH-NO
2,
(seeing for example EP-A1-192 606, EP-A2-580 533, EP-A2-376 279, EP-A2-235 725).
Enumerate following compound respectively:
Thiophene worm piperazine has following structural formula, and is known in EP A2 0 580 553,
Thiophene worm amine has following structural formula, and is known in EP A2 0 376 279,
Thiophene worm quinoline has following structural formula, and is known in EP A2 0 235 725,
MTI-446 has following structural formula, and is known in EP A1 0 649 845,
Acetamiprid has following structural formula, and is known in WO A1 91/04965,
Nitenpyram has following structural formula, and is known in EP A2 0 302 389,
Imidacloprid has following structural formula, and is known in EP 0 192 060,
Ratio that used reactive compound is mutual and mixture use kind and the occurrence rate that total amount depends on insect.For the various situations of using, best ratio and use total amount and can be determined by a series of tests separately.
The particularly preferred mixture of the present invention comprises reactive compound second worm nitrile and Imidacloprid.In this mixture, two kinds of mutual weight ratios of reactive compound are preferably 125: 1 to 1: 50, and more preferably 25: 1 to 1: 5, and wherein here and in the following various situation, what at first mention in the mixture is second worm nitrile.
The another kind of particularly preferred mixture of the present invention comprises reactive compound second worm nitrile and Acetamiprid.In this mixture, the weight ratio between two kinds of reactive compounds is preferably 125: 1 to 1: 50, and more preferably 25: 1 to 1: 5.
The another kind of particularly preferred mixture of the present invention comprises reactive compound second worm nitrile and Nitenpyram.In this mixture, the weight ratio between two kinds of reactive compounds is preferably 125: 1 to 1: 50, and more preferably 25: 1 to 1: 5.
The another kind of particularly preferred mixture of the present invention comprises reactive compound second worm nitrile and MTI-446.In this mixture, the weight ratio between two kinds of reactive compounds is preferably 125: 1 to 1: 50, and more preferably 25: 1 to 1: 5.
The another kind of particularly preferred mixture of the present invention comprises reactive compound second worm nitrile and thiophene worm piperazine.In this mixture, the weight ratio between two kinds of reactive compounds is preferably 125: 1 to 1: 50, and more preferably 25: 1 to 1: 5.
The another kind of particularly preferred mixture of the present invention comprises reactive compound second worm nitrile and thiophene worm amine.In this mixture, the weight ratio between two kinds of reactive compounds is preferably 125: 1 to 1: 50, and more preferably 25: 1 to 1: 5.
The another kind of particularly preferred mixture of the present invention comprises reactive compound second worm nitrile and thiophene worm quinoline.In this mixture, the weight ratio between two kinds of reactive compounds is preferably 125: 1 to 1: 50, and more preferably 25: 1 to 1: 5.
This active agent combinations is suitable for preventing and treating animal pest; the particularly insect that in agricultural, forestry, storage area, material protection and hygiene department, runs into, arachnid and nematode; have good plant compatibility simultaneously, and warm blooded animal is had favourable toxicity.They can be used as plant protection product usually.They have activity to species and whole or indivedual developmental stage of common sensitivity and resistance.Above-mentioned insect comprises:
Isopoda (Isopoda), for example, comb beach louse (Oniscus asellus), pillworm (Armadillidium vulgare) and ball pillworm (Porcellio scaber),
Doubly sufficient order (Diplopoda), for example, Blaniulus guttulatus,
Lip foot order (Chilopoda), for example, Geophilus carpophagus, Scutigeraspp.,
Comprehensive order (Symphyla), for example, Scutigerella immaculata,
Thysanoptera (Thysanura), for example, silverfish (Lepisma saccharina),
Collembola (Collembola), for example, arms Onychiurus arcticus (Onychiurus armatus),
Orthoptera (Orthoptera), for example, the Xi (Acheta domesticus) of family, Gryllotalpa spp (Gryllotalpa spp.), African migratory locust (Locusta migratoria migratorioides), black locust belong to (Melanoplus spp.), desert locust (Schistocerca gregaria)
Blattaria (Blattaria), for example, oriental cockroach (Blatta orientalis), American cockroach (Periplaneta americana), leucophaea maderae (Leucophaea maderae), blatta germanica (Blattella germanica),
Dermaptera (Dermaptera), for example, European earwig (Forficula auricularia),
Isoptera (Isoptera), for example, Reticulitermes (Reticulitermes spp.),
Anoplura (Phthiraptera), for example, body louse (Pediculus humanus corporis), Haematopinus (Haematopinus spp.), Linognathus (Linognathus spp.), Trichodectes (Trichodectes spp.), Damalinia (Damalinia spp.)
Thrips (Thysanoptera), for example, greenhouse bar hedge thrips (Hercinothripsfemoralis), onion thrips (Thrips tabaci), palm thrips (Thrips palmi), alfalfa thrips (Frankliniella occidentalis),
Heteroptera (Heteroptera), for example, Eurygasterspp belongs to (Eurygaster spp.), Dysdercus intermedius, square butt stinkbug (Piesma quadrata), bed bug (Cimexlectularius), phodnius prolixus (Rhodnius prolixus), Triatoma (Triatomaspp.)
Homoptera (Homoptera), for example, wild cabbage aleyrodid (Aleurodes brassicae), cassava aleyrodid (Bemisia tabaci), greenhouse whitefly (Trialeurodes vaporariorum), cotten aphid (Aphis gossypii), cabbage aphid (Brevicoryne brassicae), the tea Fischer conceals knurl aphid (Cryptomyzus ribis), aphis fabae (Aphis fabae), apple aphid (Aphis pomi), wooly aphis (Eriosoma lanigerum), mealy plum aphid (Hyalopterus arundinis), grape phylloxera (Phylloxera vastatrix), the goitre woolly aphid belongs to (Pemphigus spp.), English grain aphid (Macrosiphum avenae), tumor aphid genus (Myzus spp.), phorodon aphid (Phorodon humuli), rhopalosiphum padi (Rhopalosiphum padi), Empoasca flavescens (Empoasca spp.), Euscelis bilobatus, rice leafhopper (Nephotettixcincticeps), water wood hard a red-spotted lizard (Lecanium corni), black scale (Saissetia oleae), small brown rice planthopper (Laodelphax striatellus), brown planthopper (Nilaparvata lugens), red kidney Aspidiotus (Aonidiella aurantii), ivy Aspidiotus (Aspidiotus hederae), mealybug belongs to (Pseudococcus spp.), Psylla spp (Psylla spp.)
Lepidoptera (Lepidoptera), for example, Pectinophora gossypiella (Pectinophoragossypiella), loose looper (Bupalus piniarius), winter geometrid moth (Cheimatobiabrumata), the thin moth of apple (Lithocolletis blancardella), apple ermine moth (Hyponomeuta padella), diamond-back moth (Plutella xylostella), malacosoma neustria (Malacosoma neustria), pornography and drug moth (Euproctis chrysorrhoea), Euproctis (Lymantria spp.), cotton lyonetid (Bucculatrix thurberiella), tangerine lyonetid (Phyllocnistis citrella), Agrotis (Agrotis spp.), root eating insect belongs to (Euxoaspp.), the dirty Noctua (Feltia spp.) of cutting, earias insulana (Earias insulana), Heliothis (Heliothis spp.), tomato moth (Mamestra brassicae), small noctuid (Panolis flammea), Spodoptera (Spodoptera spp.), cabbage looper (Trichoplusia ni), codling moth (Carpocapsa pomonella), Pieris spp (Pieris spp.), straw borer spp (Chilo spp.), corn borer (Pyrausta nubilalis), Anagasta kuehniella (Ephestia kuehniella), greater wax moth (Galleria mellonella), curtain rain moth (Tineola bisselliella), bag rain moth (Tinea pellionella), brownly knit moth (Hofmannophila pseudospretella), the yellow volume of flax moth (Cacoecia podana), Capua reticulana, spruce bunworm (Choristoneura fumiferana), grape codling moth (Clysia ambiguella) (Clysia ambiguella), tea long paper moth (Homona magnanima), the green volume of oak moth (Tortrix viridana), Cnaphalocerus spp., Oulema oryzae (Oulemaoryzae)
Coleoptera (Coleoptera), for example, furniture death watch beetle (Anobium punctatum), lesser grain borer (Rhizopertha dominica), dislike bar bean weevil (Bruchidius obtectus), acanthoscelides obtectus (Acanthoscelides obtectus), North America house longhorn beetle (Hylotrupes bajulus), willow firefly chrysomelid (Agelastica alni), colorado potato beetle (Leptinotarsadecemlineata), horseradish daikon leaf beetle (Phaedon cochleariae), chrysomelid genus (Diabroticaspp.), rape golden head flea beetle (Psylliodes chrysocephala), the big Epilachna spp of Mexico (Epilachna varivestis), Atomaria spp., saw-toothed grain beetle (Oryzaephilussurinamensis), flower resembles genus (Anthonomus spp.), grain weevil belongs to (Sitophilus spp.), black grape ear image (Otiorrhynchus sulcatus), the banana collar resembles (Cosmopolitessordidus), Chinese cabbage seed tortoise resembles (Ceuthorrhynchus assimilis), alfalfa leaf resembles (Hypera postica), khapra beetle belongs to (Dermestes spp.), the spot khapra beetle belongs to (Trogodermaspp.), Anthrenus (Anthrenus spp.), moth-eaten belong to (the Attagenus spp.) of fur, moth-eaten belong to (the Lyctus spp.) of powder, pollen beetle (Meligethes aeneus), Ptinus (Ptinus spp.), golden spider beetle (Niptus hololeucus), globose spider beetle (Gibbiumpsylloides), Tribolium (Tribolium spp.), yellow mealworm (Tenebrio molitor), click beetle belongs to (Agriotes spp.), wide chest Agriotes spp (Conoderus spp.), the west melolonthid in May (Melolontha melolontha), the potato melolonthid (Amphimallonsolstitialis), the brown New Zealand rib wing melolonthid (Costelytra zealandica), rice root weevil (Lissorhoptrus oryzophilus)
Hymenoptera (Hymenoptera), for example, pine sawfoy belongs to (Diprion spp.), real tenthredinidae (Hoplocampa spp.), the hair ant belongs to (Lasius spp.), MonomoriumMayr (Monomorium pharaonis), Vespa (Vespa spp.),
Diptera (Diptera), for example, Aedes (Aedes spp.), Anopheles (Anophelesspp.), Culex (Culex spp.), black-tailed fruit flies (Drosophila melanogaster), Musca (Musca spp.), Fannia (Fannia spp.), calliphora erythrocephala (Calliphoraerythrocephala), Lucilia (Lucilia spp.), Carysomyia (Chrysomyia spp.), Cuterebra (Cuterebra spp.), Gasterophilus (Gastrophilus spp.), Hyppoboscaspp., Genus Stomoxys (Stomoxys spp.), Oestrus (Oestrus spp.), Hypoderma (Hypoderma spp.), Gadfly (Tabanus spp.), Tannia spp., Bibiohortulanus, Oscinella frit (Oscinella frit), grass Hylemyia (Phorbia spp.), lamb's-quarters spring fly (Pegomyia hyoscyami), Mediterranean Ceratitis spp (Ceratitis capitata), the big trypetid of olive (Dacus oleae), Europe daddy-longlegs (Tipula paludosa), Hylemyia (Hylemyia spp.), liriomyza bryoniae belongs to (Liriomyza spp.)
Siphonaptera (Siphonaptera), for example, Xanthopsyllacheopis (Xenopsylla cheopis), Ceratophyllus (Ceratophyllus spp.),
Arachnids (Arachnida), for example, Middle East gold scorpion (Scorpio maurus), latrodectus mactans (Latrodectus mactans), Acarus siro (Acarus siro), Argas (Argas spp.), Ornithodoros (Ornithodoros spp.), Dermanyssus gallinae (Dermanyssus gallinae), tea Fischer goitre mite (Eriophyes ribis), the tangerine rust mite (Phyllocoptruta oleivora) that rues, Boophilus (Boophilus spp.), Rh (Rhipicephalus spp.), Amblyomma (Amblyomma spp.), Hyalomma (Hyalomma spp.), hard tick belongs to (Ixodes spp.), Psoroptes (Psoroptes spp.), Chorioptes (Chorioptes spp.), itch mite belongs to (Sarcoptes spp.), tarsonemid belongs to (Tarsonemus spp.), Bryobia praetiosa (Bryobia praetiosa), Panonychus citri belongs to (Panonychus spp.), Tetranychus (Tetranychus spp.), half tarsonemid belongs to (Hemitarsonemus spp.), short whisker Acarapis (Brevipalpus spp.).
Plant nematode comprises, for example, Pratylenchidae belongs to (Pratylenchus spp.), similar similes thorne (Radopholus similis), fuller's teasel stem eelworm (Ditylenchusdipsaci), the nematode (Tylenchulus semipenetrans) of partly puncturing, Heterodera (Heterodera spp.), ball Heterodera (Globodera spp.), Meloidogyne (Meloidogyne spp.), Aphelenchoides (Aphelenchoides spp.), minute hand Turbatrix (Longidorus spp.), Xiphinema (Xiphinema spp.), burr Turbatrix (Trichodorus spp.), umbrella Aphelenchoides (Bursaphelenchus spp.).
All plants and plant parts all can be handled according to the present invention.The implication of plant is all plant and plant populations, for example need with unwanted wild plant or cultivated species (comprising the cultivated species that nature exists).Cultivated species can be by routine breeding and optimum seeking method or the plant that obtains by biotechnology and gene engineering method or the combination by described method, comprises genetically modified plants, also comprises the plant variety that is subjected to the protection of plant seedling power or is not subjected to its protection.The implication of plant parts is all grounds of plant and underground position and organ, for example bud, leaf, Hua Hegen, and wherein the example that can list has leaf, needle, stem, branch, flower, fruit body, fruit and seed, also has root, bulb and rhizome.Plant parts also comprises harvested material and asexual and sexual propagation thing, for example transplants, bulb, rhizome, running roots and seed.
What should emphasize is, medicament of the present invention (agent) has particularly advantageous effect when being used for following plant, and described plant comprises: cereal, for example wheat, oat, barley, spelt, triticale and rye; And corn, grain, rice, sugarcane, soybean, sunflower, potato, cotton, rape, Canadian rape (canola), tobacco, sugar beet, fodder beet, asparagus, lupulus and fruit plant (comprise pomaceous fruits fruit, for example apple and pears; Stone fruit, for example peach, honey peach, cherry, Li Hexing; Citrus fruit, for example orange, grapefruit, bitter orange, lemon, cumquat (kumquat), oranges and tangerines (mandarin), the Sa tangerine (satsuma) that rubs; Nut fruits, for example pistachio (pistachio), almond (almond), English walnut (walnut) and pecan (pecan nut); Tropical fruit (tree), for example mango, papaw (papaya), pineapple, nipa palm (date), banana, and grape) and vegetables (comprise leaf vegetables, for example corn sow thistle (endive), tame levisticum (lambs lettuce), fennel (fennel), ball lettuce and leaf lettuce, Switzerland's beet (chard), spinach (spinach) and salad are with witloof (chicory); Cole vegetables, for example cauliflower, stem cabbage (broccoli), Chinese cabbage (Chinese cabbage), kale (winter wild cabbage (winter kale) or savoy cabbage (curlykale)), blue (kohlrabi), the brussels sprouts (brussel sprout) of left-falling stroke, red cabbage, white cabbage and savoy cabbage (savoy); Fruit vegetables, for example eggplant (aubergine), cucumber, red lantern capsicum (paprika), custard squash (marrow), tomato, bush pumpkin (courgette) and sweet corn; Root vegetables, for example celeriac (celeriac), wild turnip (turnip), carrot, Sweden turnip (swede), wild radish, horseradish (horse radish), table beet (beetroot), salsify (salsify), celery (celery); Pulses leguminous plants, for example pea and Kidney bean; And green onion section vegetables, for example leek and onion).
The processing that active agent combinations used according to the invention carries out plant and plant parts, directly carry out by conventional treatment method, or realize by acting on its environment of living in, habitat or storage area, the for example immersion liquid of described conventional treatment method, spraying, evaporation, atomizing, broadcast sowing, smear, and, for breeding thing, especially seed, also can smear one or more layers.
Mixture of the present invention is particularly suitable for handling seed.Most of infringement that cause by insect, that cultivated species is caused during seed storage, seed is broadcast after the soil and just taken place when being subjected to invading and harassing during the plant germination and after the rudiment just.This stage is crucial especially, since just responsive especially at root and the bud of growing plants, even very Xiao Liang injury also can cause the withered of whole strain plant.Therefore, by using proper drug to protect seed and just having special significant meaning the plant of rudiment.
Come pest control with regard to known by handling plant seed since long duration, it also is the theme of updating.Yet the processing of seed exists many problems that can not always solve with satisfactory way.Therefore, need exploitation needn't after planting or plant use plant protection product in addition after emerging and protect seed and just in the method for the plant of rudiment.In addition, also need with the dosage optimization of active substance for can to seed and just the plant of rudiment protection as well as possible is provided in case be subjected to insect invasion and attack, simultaneously again can be owing to employed reactive compound injures plant itself.Especially, method for treating seeds also should consider genetically modified plants intrinsic insecticidal properties so that by using minimum plant protection product to obtain to seed with just in the best protection of the plant of rudiment.
Therefore, The present invention be more particularly directed to a kind of by protecting seed with fungicide-treated seed of the present invention and just avoiding the method for insect invasion and attack the plant of rudiment.The present invention equally also relates to medicament of the present invention and is used to handle seed with the protection seed with just avoiding the purposes that insect attacks the plant of rudiment.In addition, the invention still further relates to cross with chemicals treatment of the present invention, avoid the seed of insect invasion and attack to protect it.
One of advantage of the present invention is, because the special interior absorption energy of medicament of the present invention has not only been protected seed self with these chemicals treatment, but also has protected the plant after emerging to avoid the insect invasion and attack.In this mode, can save at seeding time or interior direct processing of short period after this crop.
Another advantage is that medicament of the present invention is compared with independent separately reactive compound has the collaborative insect active extremely that increases, and this surpasses the active summation of two kinds of reactive compounds of using separately.In this way, can optimize the consumption of reactive compound.
What also can be considered advantage is that mixture of the present invention also can be used in particular for transgenic seed, can express a kind of albumen at insect by the plant that above-mentioned transgenic seed grows.By with the above-mentioned seed of chemicals treatment of the present invention; only the expression by for example insecticidal protein can prevent and treat some insect, and, unexpectedly; adopt medicament of the present invention to obtain the activity of cooperative compensating, this has further improved the drug effect of the protection of opposing insect invasion and attack.
Medicament of the present invention is suitable for protecting the seed of all types plant variety of having mentioned that is used for agricultural, greenhouse, forestry, gardening construction or vineyard.Especially, above-mentioned seed relates to the seed of following plant: corn, peanut, Canadian rape, rape, opium poppy, olive, coconut, cocoa, soybean, cotton, beet (for example sugar beet and fodder beet), rice, grain, wheat, barley, oat, rye, sunflower, sugarcane or tobacco.Medicament of the present invention also is applicable to handles the fruit plant mentioned the front and the seed of vegetables.Particularly importantly to the processing of corn, soybean, cotton, wheat and Canadian rape or rape seeds.For example, the mixture that comprises reactive compound methiocarb (methiocarb) and Imidacloprid of the present invention is particularly suitable for the processing of corn seed.
As mentioned above, with chemicals treatment transgenic seed of the present invention also particular importance.This relates to the seed of the plant that comprises at least a heterologous gene of arranging the expression of polypeptides with special insecticidal properties usually.Heterologous gene in the transgenic seed can come from microorganism, for example bacillus (Bacillus), rhizobium (Rhizobium), false unicellular bacterium (Pseudomonas), Serratieae (Serratia), wood mould (Trichoderma), rod shape bacillus (Clavibacter), sacculus mould (Glomus) or sticking broom mould (Gliocladium).The present invention is particularly suitable for processing and comprises at least a transgenic seed that comes from the heterologous gene of bacillus (Bacillus sp.), and the gene outcome of described gene shows the activity of anti-European corn borer (European corn borer) and/or western corn root worm (western corn rootworm).The heterologous gene that especially preferably comes from bacillus thuringiensis (Bacillus thuringiensis).
Among the present invention, medicament of the present invention can be applied to seed separately or be applied to seed with the appropriate formulation form.Preferably, stable as it to be handled under the state that is enough in processing, be without prejudice at seed.Generally can gather and sow between any time point handle seed.Usually used seed is separated with plant, and has broken away from steady axle, shell, stem, epidermis, hair or pulp.
Handle kind of a period of the day from 11 p.m. to 1 a.m and generally must be noted that, the sprouting that the amount of the amount of medicament of the present invention of seed and/or other additive of being applied to should be chosen as seed not have to damage and do not injure the plant that grows.In showing under some amount of application under the situation of phytotoxic effect, should at first note this point at reactive compound.
Medicament of the present invention can directly be used, and that is to say the component that need not to comprise other, also need not dilution.In general, preferably with a kind of mode of appropriate formulation with pharmacy application to seed.Suitable preparation that is used for seed treatment and method are for known to those of ordinary skills, and on the books in following document for example: US 4,272,417 A, US 4,245,432 A, US4,808,430 A, US 5,876,739 A, US 2003/0176428 A1, WO2002/080675A1, WO2002/028186 A2.
Active component bond of the present invention can be converted into conventional formulation, for example solution, emulsion, the agent of dusting, suspending agent, pulvis, powder agent, paste, soluble powder, granule, outstanding newborn concentrating agents, through the natural and synthetic material of activity component impregnation, and the microcapsule formulations in the polymer.
These preparations are made in common mode, for example with active component and mixing diluents, that is, mix with liquid flux and/or solid carrier, can choose the use surfactant wantonly simultaneously, i.e. emulsifier and/or dispersant and/or blowing agent.
If make water, for example also can use organic solvent as cosolvent as thinner.Suitable liquid flux mainly contains: aromatic compound, for example dimethylbenzene, toluene or Fluhyzon; Chlorinated aromatic compound and chloro aliphatic hydrocarbon, for example chlorobenzene, vinyl chloride or carrene; Aliphatic hydrocarbon, for example cyclohexane or paraffin, for example natural oil cut, mineral oil and vegetable oil; Alcohol, for example butanols or ethylene glycol, and ether and ester; Ketone, for example acetone, MEK, methyl iso-butyl ketone (MIBK) or cyclohexanone; Intensive polar solvent, for example dimethyl formamide and dimethyl sulfoxide (DMSO); And water.
The solid carrier that is fit to has:
For example, ammonium salt; Natural mineral powder, for example kaolin, clay, talcum, chalk, quartz, attapulgite, montmorillonite or diatomite; And synthetic mineral powder, for example fine-particle silicon dioxide, aluminium oxide and silicate.The solid carrier that is applicable to granule is: for example pulverize the also natural rock of classification, for example calcite, marble, float stone, sepiolite, dolomite; And the particle of synthetic inorganic and organic dust, as the particle of organic material, for example sawdust, coconut husk, corncob and tobacco stem.The emulsifier and/or the blowing agent that are fit to are: for example nonionic and anion emulsifier, for example cithrol, polyethylene glycol fatty alcohol ether, for example alkyl aryl polyethyleneglycol ether, alkylsulfonate, alkyl sulfate, arylsulphonate; And protein hydrolysate.The dispersant that is fit to is: for example lignin sulfite waste liquor and methylcellulose.
Can use adhesive in the preparation, the natural and synthetic polymer of for example carboxymethyl cellulose, and powder, particle or latex shape, for example gum Arabic, polyvinyl alcohol and polyvinyl acetate; And natural phospholipid, for example cephalin and lecithin, and synthetic phospholipid.Other additive can be mineral oil and vegetable oil.
Can use colouring agent, for example inorganic pigment, for example iron oxide, titanium oxide, ferrocyanide indigo plant (ferrocyanblue); And organic dyestuff, for example alizarin dyes, azo dyes and metal phthalocyanine dyestuff; And trace element, for example molysite, manganese salt, boron salt, mantoquita, cobalt salt, molybdenum salt and zinc salt.
Preparation generally contains the reactive compound of 0.1 to 95 weight %, preferred 0.5 to 90 weight %.
Randomly, active agent combinations of the present invention can be common the commercial preparation form and the administration form that is mixed with by described preparation and other reactive compound exist, described other reactive compound comprises for example insecticide, attractant, disinfectant, bactericide, miticide, nematocide, fungicide, growth regulator or weed killer herbicide.Insecticide comprises, for example phosphoric acid ester, carbamates, carboxylic acid esters, chlorinated hydrocarbon, phenylurea class and material of being made by microorganism etc.
The example of specially suitable component of mixture is as follows:
Fungicide:
Aldimorph, ammonia propyl-phosphine acid (ampropylfos), ammonia propyl-phosphine acid potassium, andoprim, anilazine (anilazine), oxygen ring azoles (azaconazole), Fluoxastrobin (azoxystrobin),
M 9834 (benalaxyl), benodanil (benodanil), benomyl (benomyl), benzyl olefin(e) acid (benzamacril), isobutyl group benzyl olefin(e) acid, bialaphos (bialaphos), binapacryl (binapacryl), biphenyl, bitertanol (bitertanol), blasticidin-S (blasticidin-S), bromuconazole (bromuconazole), bupirimate (bupirimate), buthiobate (buthiobat),
Calcium polysulfide, capsimycin (capsimycin), difoltan (captafol), captan (captan), carbendazim (carbendazim), carboxin (carboxin), carvol (carvone), chinomethionat (chinomethionat, quinomethionat), the pest of going out azoles (chlobenthiazone), benzene imidazoles bacterium (chlorfenazole), chloroneb (chloroneb), chloropicrin (chloropicrin), tpn (chlorothalonil), chlozolinate (chlozolinate), clozylacon, cufraneb (cufraneb), frost urea cyanogen (cymoxanil), Cyproconazole (cyproconazole), cyprodinil (cyprodinil), cyprofuram (cyprofuram);
Debacarb (debacarb), antiphen (dichlorophen), diclobutrazol (diclobutrazol), diclofluanid, diclomezin (diclomezine), botran (dicloran), the mould prestige of second (diethofencarb), Difenoconazole (difenoconazole), dimethirimol (dimethirimol), dimethomorph (dimethomorph), alkene azoles alcohol (diniconazol), alkene azoles alcohol-M (diniconazole-M), karathane (dinocap), diphenylamines (diphenylamine), pyrrole bacterium sulphur (dipyrithione), Plondrel (ditalimfos), dithianon (dithianon), dodemorph (dodemorph), dodine (dodine), drazoxolon (drazoxolon);
Edifenphos (ediphenphos), fluorine ring azoles (epoxiconazole), etaconazole (etaconazole), the phonetic phenol of second (ethirimol), kobam (etridiazole),
Famoxate (famoxadone), fenapanil (fenapanil), Fenarimol (fenarimol), RH-7592 (fenbuconazole), fenfuram (fenfuram), plant clothing ester (fenitropan), fenpiclonil (fenpiclonil), fenpropidin (fenpropidin); butadiene morpholine (fenpropimorph); fentin acetate (fentin acetate); hydroxyl fentin (fentin hydroxyde); ferbam (ferbam); ferimzone (ferimzone); fluazinam (fluazinam); fluorine acyl bacterium amine (flumetover); fluoromide (fluoromide); Fluquinconazole (fluquinconazole); flurprimidol (flurprimidol); Flusilazole (flusilazole); flusulfamide (flusulphamide); flutolanil (flutolanil); Flutriafol (flutriafol); folpet (folpet); three second aluminium phosphates (fosetyl-aluminium); three second sodium phosphates (fosetyl-sodium); Rabcide (phthalide); furidazol (fuberidazole); furalaxyl (furalaxyl); furan pyrrole bacterium amine (furametpyr); furcarbonil; furconazole (furconazole); furconazole_cis (furconazole-cis); seed dressing amine (furmecyclox);
Guazatine (guazatin),
Hexachloro-benzene (hexachlorobenzene), own azoles alcohol (hexaconazole), dislike mould spirit (hymexazole),
Press down mould azoles (imazalil), glyoxalin (imibenconazole), iminoctadine (iminoctadine), two eight guanidinesalts (iminoctadinealbesilate), iminoctadine triacetate (iminoctadine triacetate), iodocarb, kind bacterium azoles (ipconazole), iprobenfos (iprobenfos, IBP), iprodione (iprodione), people's metamycin (irumamycin), Isoprothiolane (isoprothiolane), chlorobenzene Climbazole (isovaledione),
Kasugarnycin (kasugamycin), kresoxim-methyl (kresoxim-methyl), copper agent, for example Kocide SD, copper naphthenate, COPPER OXYCHLORIDE 37,5 (copper oxychloride), copper sulphate, copper monoxide, copper 8-hydroxyquinolinate (oxine-copper) and bordeaux mixture,
Mancopper (mancopper), mancozeb (mancozeb), maneb (maneb), meferimzone, mepanipyrim (mepanipyrim), mebenil (mepronil), metalaxyl (metalaxyl), metconazole (metconazole), methasulfocarb (methasulphocarb), methuroxam (methfuroxam), Carbatene (metiram), metomeclam, metsulfovax (metsulphovax), midolthromycin (mildiomycin), nitrile bacterium azoles (myclobutanil), myclozolin (myclozolin);
Sankel (nickel dimethyldithiocarbamate), nitrothalisopropyl (nitrothal-isopropyl), nuarimol (nuarimol),
Ofurace (ofurace), Wakil (oxadixyl), oxamocarb, oxolinic acide (oxolinicacid), oxycarboxim, oxyfenthiin,
Paclobutrazol (paclobutrazol), pefurazoate (pefurazoate), penconazole (penconazole), Pencycuron (pencycuron), phosdiphen (phosdiphen), myprozine (pimaricin), disease is spent spirit (piperalin), polyoxin (polyoxin), polyoxorim, probenazole (probenazole), Prochloraz (prochloraz), procymidone (procymidone), Propamocarb (propamocarb), propanosine-sodium, propiconazole (propiconazole), Propineb (propineb), pyrazophos (pyrazophos), pyrifenox (pyrifenox), phonetic mould amine (pyrimethanil), pyroquilon (pyroquilon), chlorine pyrrole furan ether (pyroxyfur);
Azoles oxolinic acide (quinconazole), pcnb (quintozene, PCNB),
Sulphur and sulphur preparation,
Tebuconazole (tebuconazole), tecloftalam (tecloftalam), tecnazene (tecnazene), tetcyclacis (tetcyclacis), tetraconazole (tetraconazole), probenazole (thiabendazole), thicyofen (thicyofen), thiophene fluorine bacterium amine (thifluzamide), thiophanate-methyl (thiophanate-methyl), tmtd (thiram), sulphur benzonitrile formamide (tioxymid), tolelofos-methyl (tolclofos-methyl), Tolylfluanid (tolylfluanid), triazolone (triadimefon), Triadimenol (triadimenol), butrizol (triazbutil), triazoxide (triazoxide), trichlamide (trichlamide), tricyclazole (tricyclazole), tridemorph (tridemorph), fluorine bacterium azoles (triflumizole), triforine (triforine), triticonazole (triticonazole);
Uniconazole P (uniconazole),
Valida (validamycin A), vinclozolin (vinclozolin), alkene frost benzene azoles (viniconazole),
Zarilamid (zarilamid), zineb (zineb), ziram (ziram) and
Miaow oxalic acid (Dagger) G,
OK-8705、
OK-8801、
α-(1, the 1-dimethyl ethyl)-β-(2-phenoxy group ethyl)-1H-1,2,4-triazole-1-ethanol,
α-(2,4 dichloro benzene base)-β-fluoro-b-propyl group-1H-1,2,4-triazole-1-ethanol,
α-(2,4 dichloro benzene base)-'beta '-methoxy-a-methyl isophthalic acid H-1,2,4-triazole-1-ethanol,
α-(5-methyl isophthalic acid, 3-diox-5-yl)-β-[[4-(trifluoromethyl)-phenyl]-methylene]-1H-1,2,4-triazole-1-ethanol,
(5RS, 6RS)-6-hydroxyl-2,2,7,7-tetramethyl-5-(1H-1,2,4-triazol-1-yl)-3-octanone,
(E)-a-(methoxyimino)-N-methyl-2-Phenoxyphenyl acetamide,
{ 2-methyl isophthalic acid-[[[1-(4-aminomethyl phenyl) ethyl] amino] carbonyl] propyl group } carbamic acid-1-isopropyl ester,
1-(2,4 dichloro benzene base)-2-(1H-1,2,4-triazol-1-yl) ethyl ketone-O-(phenyl methyl) oxime,
1-(2-methyl isophthalic acid-naphthyl)-1H-pyrroles-2, the 5-diketone,
1-(3, the 5-dichlorophenyl)-3-(2-acrylic)-2, the 5-pyrrolidine-diones,
The 1-[(diiodomethyl) sulfonyl]-the 4-methylbenzene,
1-[[2-(2,4 dichloro benzene base)-1,3-dioxolanes-2-yl] methyl]-the 1H-imidazoles,
1-[[2-(4-chlorphenyl)-3-phenyl epoxy ethyl] methyl]-1H-1,2, the 4-triazole,
1-[1-[2-[(2, the 4-dichlorophenyl) methoxyl group] phenyl] vinyl]-the 1H-imidazoles,
1-methyl-5-nonyl-2-(phenyl methyl)-3-pyrrolidinol,
2 ', 6 '-two bromo-2-methyl-4 '-trifluoromethoxy-4 '-Trifluoromethyl-1,3-thiazole-5-formailide,
2,2-two chloro-N-[1-(4-chlorphenyl) ethyl]-1-ethyl-3-methyl cyclopropane formamide,
2,6-two chloro-5-(methyl mercapto)-4-pyrimidine radicals thiocyanates,
2,6-two chloro-N-(4-trifluoromethyl benzyl) benzamide,
2,6-two chloro-N-[[4-(trifluoromethyl) phenyl] methyl] benzamide,
2-(2,3,3-three iodo-2-acrylic)-2H-tetrazolium,
The 2-[(1-Methylethyl) sulfonyl]-5-(trichloromethyl)-1,3, the 4-thiadiazoles,
2-[[6-deoxidation-4-O-(4-O-methyl-β-D-glycopyranosyl)-a-D-glycopyranosyl] amino]-4-methoxyl group-1H-pyrrolo-[2,3-d] pyrimidine-5-nitrile,
The 2-butylamine,
2-bromo-2-(bromomethyl) glutaronitrile,
2-chloro-N-(2,3-dihydro-1,1,3-trimethyl-1H-indenes-4-yl)-3-pyridine carboxamide,
2-chloro-N-(2, the 6-3,5-dimethylphenyl)-N-(different sulphur cyanato methyl) acetamide,
2-phenylphenol (OPP),
3,4-two chloro-1-[4-(difluoro-methoxy) phenyl]-1H-pyrroles-2, the 5-diketone,
3,5-two chloro-N-[cyano group-[(1-methyl-2-propynyl) oxygen] methyl] benzamide,
3-(1,1-dimethyl propyl-1-oxo)-1H-indenes-2-nitrile,
3-[2-(4-chlorphenyl)-5-ethyoxyl-3-isoxazole alkyl] pyridine,
4-chloro-2-cyano group-N, N-dimethyl-5-(4-aminomethyl phenyl)-1H-imidazoles-1-sulfonamide,
4-methyl-tetrazolo [1,5-a] quinazoline-5 (4H)-ketone,
8-(1, the 1-dimethyl ethyl)-N-ethyl-N-propyl group-1,4-dioxo spiro [4.5] decane-2-methylamine,
The oxine hydrosulphate,
9H-xanthene-9-carboxyl-2-[(phenyl amino) carbonyl] hydrazides,
3-methyl-4-[(3-methyl benzoyl) oxygen]-2, the 5-thiophene dicarboxylic acid is two-(1-Methylethyl) ester,
Suitable-1-(4-chlorphenyl)-2-(1H-1,2,4-triazol-1-yl) suberol,
Suitable-4-[3-[4-(1, the 1-dimethyl propyl) phenyl-2-methyl-propyl]-2,6-thebaine hydrochloride,
[(4-chlorphenyl) azo] cyan-acetic ester,
Saleratus,
Methane four mercaptan sodium salts,
1-(2,3-dihydro-2,2-dimethyl-1H-indenes-1-yl)-1H-imidazoles-5-methyl formate,
N-(2, the 6-3,5-dimethylphenyl)-N-(5-isoxazolyl carbonyl)-DL-methyl lactamine,
N-(chloracetyl)-N-(2, the 6-3,5-dimethylphenyl)-DL-methyl lactamine,
N-(2,3-two chloro-4-hydroxy phenyls)-1-hexahydrotoluene formamide,
N-(2, the 6-3,5-dimethylphenyl)-2-methoxyl group-N-(tetrahydrochysene-2-oxo-3-furyl) acetamide,
N-(2, the 6-3,5-dimethylphenyl)-2-methoxyl group-N-(tetrahydrochysene-2-oxo-3-thienyl) acetamide,
N-(2-chloro-4-nitrobenzophenone)-4-methyl-3-nitro benzsulfamide,
N-(4-cyclohexyl phenyl)-1,4,5,6-tetrahydrochysene-2-pyrilamine,
N-(4-hexyl phenyl)-1,4,5,6-tetrahydrochysene-2-pyrilamine,
N-(5-chloro-2-aminomethyl phenyl)-2-methoxyl group-N-(2-oxo-3-oxazole alkyl) acetamide,
N-(6-methoxyl group)-3-pyridine radicals) cyclopropane carboxamide,
N-[2,2,2-three chloro-1-[(chloracetyls) amino] ethyl] benzamide,
N-[3-chloro-4,5-pair-(2-third alkynyloxy group) phenyl]-N '-methoxyl group carbonamidine (methaneimidamide),
N-formoxyl-N-hydroxyl-DL-alanine sodium salt,
O, O-diethyl-[2-(dipropyl amino)-2-oxoethyl] ethylenebis dithiocarbamate phosphinylidyne amino ester,
O-methyl-S-phenyl-phenyl propyl thiophosphoryl amino ester,
The S-methyl isophthalic acid, 2,3-diazosulfide-7-thiocarboxylic,
Spiral shell [2H]-1-chromene-2,1 ' (3 ' H)-isobenzofuran-3 '-ketone.
Bactericide:
Bronopol (bronopol), antiphen, trichloromethyl pyridine (nitrapyrin), Sankel (nickel-dimethyldithiocarbamate), kasugarnycin, octhilinone (octhilinone), furancarboxylic acid (furoic acid), terramycin (oxytetracyclin), probenazole (probenazole), streptomycin (streptomycin), tecloftalam, copper sulphate and other copper agents.
Insecticide/miticide/nematocide
1. acetylcholinesterase (AChE) inhibitor
1.1 carbamates
Alanycarb (alanycarb) for example, Aldicarb (aldicarb), aldoxycarb (aldoxycarb), allyxycarb (allyxycarb), aminocarb (aminocarb), dislike worm and become (bendiocarb), Benfuracard micro (benfuracarb), metalkamate (bufencarb), butacarb (butacarb), butocarboxim (butocarboxim), butanone sulfone prestige (butoxycarboxim), carbaryl (carbaryl), carbofuran (carbofuran), carbosulfan (carbosulfan), remove line and become (cloethocarb), dimetilan (dimetilan), ethiofencarb (ethiofencarb), Bassa (fenobucarb), fenothiocarb (fenothiocarb), Carzol (formetanate), furathiocarb (furathiocarb), Mobucin (isoprocarb), metham-sodium (metam-sodium), methiocarb (methiocarb), Methomyl (methomyl), meta-tolyl-N-methylcarbamate (MTMC) (metolcarb), oxamyl (oxamyl), Aphox (pirimicarb), Carbamult (promecarb), unden (propoxur), the two prestige (thiodicarb) of sulphur, imitate (thiofanox) for a long time, Landrin (trimethacarb), go out and remove (XMC), Meobal (xylylcarb);
Triaguron (triazamate)
1.2 organophosphorus compounds
Orthene (acephate) for example; Azamethiphos (azamethiphos); Azinphos-methyl (M;-A) (azinphos (methyl ,-ethyl)); Rilariol (bromophos-ethyl); Bromobenzene alkene phosphorus (methyl) (bromfenvinfos (methyl)); Special Pyrimitate (butathiofos); Cadusafos (cadusafos); Carbophenothion (carbophenothion); Chlorethoxyfos (chlorethoxyfos); Chlorfenviphos (chlorfenvinphos); Chlormephos (chlormephos); Chlopyrifos (methyl/-ethyl) (chlorpyrifos (methyl/-ethyl)); Resistox (coumaphos); Surecide (cyanofenphos); Cynock (cyanophos); Chlorfenviphos (chlorfenvinphos); Demeton-methyl (demeton-S-methyl); Metilomerkaptofosoksid (demeton-S-methylsulphone); Dialifos (dialifos); Diazinon (diazinon); Dichlofenthion (dichlofenthion); DDVP (dichlorvos)/DDVP; Carbicron (dicrotophos); Rogor (dimethoate); Dimethylvinphos (dimethylvinphos); Salithion (dioxabenzofos); Disulfoton (disulphoton); EPN (EPN); Ethodan (ethion); Phonamiphos (ethoprophos); Etrimfos (etrimfos); Famphur (famphur); Fenamiphos (fenamiphos); Fenifrothion (fenitrothion); Fensulfothion (fensulphothion); Entex (fenthion); Pyrrole fluorine sulphur phosphorus (flupyrazofos); Fonofos (fonofos); Formothion (formothion); Fosmethilan (fosmethilan); Lythidathion (fosthiazate); Heptenophos (heptenophos); Iodfenphos (iodofenphos); IBP (iprobenfos); Isazofos (isazofos); Isofenphos (isofenphos); Ortho-, meta-or p-isopropyl salicylate (isopropyl O-salicylate); Isoxathion (isoxathion); Malathion (malathion); Afos (mecarbam); Methacrifos (methacrifos); Acephatemet (methamidophos); Methidathion (methidathion); Menite (mevinphos); Azodrin (monocrotophos); 2-dichloroethylk dimethyl phosphate (naled); Omethoate (omethoate); Oxydemeton_methyl (oxydemeton-methyl); Parathion (methyl/-ethyl) (parathion (methyl/-ethyl)); Phenthoate dimephenthoate cidial (phenthoate); Thimet (phorate); Phosalone (phosalone); Phosmet (phosmet); Phosphamidon (phosphamidon); Second the third phosphorus becomes (phosphocarb); Phoxim (phoxim); Diothyl (methyl/-ethyl) (pirimiphos (methyl/-ethyl)); Profenofos (profenofos); Kayaphos (propaphos); Propetamphos (propetamphos); Toyodan (prothiofos); Prothoate (prothoate); Pyraclofos (pyraclofos); Pyridaphethione (pyridaphenthion); Pyridathion; Quinalphos (quinalphos); Cadusafos (sebufos); Sulfotep (sulphotep); Sulprofos (sulprofos); Butyl pyrimidine phosphorus (tebupirimfos); Swebate (temephos); Terbufos (terbufos); Ravap (tetrachlorvinphos); Thiometon (thiometon); Hostathion (triazophos); Triclorfon; Vamidothion (vamidothion).
2. sodium channel modulators/the depend on sodium channel blockers of current potential
2.1 pyrethroid
Acrinathrin (acrinathrin) for example, allethrin (d-is suitable-and anti-, d-is suitable) (allethrin (d-cis-trans, d-trans)), betacyfluthrin (beta-cyfluthrin), Biphenthrin (bifenthrin), bioallethrin (bioallethrin), bioallethrin-S-cyclopenta isomer (bioallethrin-S-cyclopentyl-isomer), bioethanomethrin, biopermethrin (biopermethrin), bioresmethrin (bioresmethrin), dichloro alkyne valerate (chlovaporthrin), suitable-cypermethrin (cis-cypermethrin), suitable-resmethrin (cis-resmethrin), suitable-permethrin (cis-permethrin), cyhalothrin (clocythrin), cycloprothrin (cycloprothrin), cyfloxylate (cyfluthrin), cyhalothrin (cyhalothrin), cypermethrin (nail body, the second body, hot body, own body) (cypermethrin (alpha-, beta-, theta-, zeta-)), cyphenothrin (cyphenothrin), decis (deltamethrin), empenthrin (1R-isomer) (empenthrin (1R-isomer)), S-sumicidin (esfenvalerate), ether chrysanthemum ester (etofenprox), fenfluthrin (fenfluthrin), fenpropathrin (fenpropathrin), fenpirithrin (fenpyrithrin), sumicidin (fenvalerate), brofluthrinate (flubrocythrinate), flucythrinate (flucythrinate), trifluoro chrysanthemum ester (flufenprox), flumethrin (flumethrin), taufluvalinate (fluvalinate), fubfenprox, gamma-cyhalothrin, miaow alkynes chrysanthemum ester (imiprothrin), kadethrin (kadethrin), gamma cyhalothrin (lambda-cyhalothrin), metofluthrin, permethrin (suitable-, instead-) (permethrin (cis-, trans-)), phenothrin (1R-cis-isomer) (phenothrin (1R-trans isomer)), prallethrin (prallethrin), profluthrin, protrifenbute, anti-Chryson (pyresmethrin), resmethrin (resmethrin), kadethrin (RU 15525), silafluofene (silafluofen), taufluvalinate (tau-fluvalinate), tefluthrin (tefluthrin), terallethrin (terallethrin), tetramethrin (1R-isomer) (tetramethrin (1R-isomer)), tralomethrin (tralomethrin), transfluthrin (transfluthrin), brofluthrinate (ZXI 8901), pyrethrin (pyrethrins, pyrethrum)
Dichlorodiphenyl trichloroethane (DDT)
2.2 oxadiazine (oxadiazine) class, for example the indenes worm becomes (indoxacarb)
3. acetyl choline receptor agonists/antagonist
3.1 chloro nicotinyl (chloronicotinyl) class
For example Acetamiprid (acetamiprid), thiophene worm amine (clothianidin), MTI-446 (dinotefuran), Imidacloprid (imidacloprid), Nitenpyram (nitenpyram), Nithiazine (nithiazine), thiophene worm quinoline (thiacloprid), thiophene worm piperazine (thiamethoxam)
3.2 nicotine (nicotine), bensultap (bensultap), cartap (cartap)
4. acetylcholine receptor modulators
4.1spinosyn class, for example pleocidin (spinosad)
5.GABA control chloride channel antagonist
5.1 cyclic diolefine organochlorine class
For example toxaphene (camphechlor), Niran (chlordane), 5a,6,9,9a-hexahydro-6,9-methano-2,4 (endosulphan), lindane (gamma-HCH), hexachlorcyclohexane (HCH), heptachlor (heptachlor), lindane (lindane), methoxychlor (methoxychlor)
5.2fiprole class
For example acetoprole, second worm nitrile (ethiprole), fluorine worm nitrile (fipronil), fluorine pyrazoles worm (vaniliprole)
6. chloride channel activator
6.1mectin class
For example Avermectin (avermectin), emaricin (emamectin), emamectin-benzoate (emamectin-benzoate), ivermectin (ivermectin), milbemycin (milbemycin)
7. juvenoid
For example difenolan (diofenolan), protect young ether (epofenonane), fenoxycarb (fenoxycarb), hydroprene (hydroprene), kinoprene (kinoprene), methoprene (methoprene), pyrrole propyl ether (pyriproxifen), triprene (triprene)
8. ecdysone agonist/agent interfering (disruptor)
8.1 diacyl hydrazide class
For example encircle worm hydrazides (chromafenozide), chlorine worm hydrazides (halofenozide), methoxyfenozide (methoxyfenozide), worm hydrazides (tebufenozide)
9. chitin biosynthesis inhibitor
9.1 benzoyl area kind
For example two three flufenoxurons (bistrifluron), chlofluazuron, diflubenzuron (diflubenzuron), fluazuron (fluazuron), flucycloxuron (flucycloxuron), flufenoxuron (flufenoxuron), fluorine bell urea (hexaflumuron), Acarus tritici urea (lufenuron), fluorine uride (novaluron), noviflumuron (noviflumuron), penfluron (penfluron), fluorobenzene urea (teflubenzuron), kill bell urea (triflumuron)
9.2 Buprofezin (buprofezin)
9.3 fly eradication amine (cyromazine)
10. oxidative phosphorylation inhibitor, the ATP agent interfering
10.1 butyl ether urea (diafenthiuron)
10.2 organic tin, for example azacyclotin (azocyclotin), plictran (cyhexatin), fenbutatin oxide (fenbutatin oxide)
11. pass through the uncoupler of the oxidative phosphorylation of interruption H-proton gradient
11.1 pyroles, for example capillary (chlorfenapyr)
11.2 the dinitro benzene phenols, for example binapacyrl, dinobuton (dinobuton), karathane (dinocap), 4,6-dinitro-o-cresol (DNOC)
12.I site electron transfer inhibitor
12.1METI class, for example fenazaquin (fenazaquin), azoles mite ester (fenpyroximate), pyrimidifen (pyrimidifen), pyridaben (pyridaben), tebufenpyrad (tebufenpyrad), azoles insect amide (tolfenpyrad)
12.2 Hydramethylnon Bait (hydramethylnon)
12.3 dicofol (dicofol)
13.II site electron transfer inhibitor
Rotenone (rotenone)
14.III site electron transfer inhibitor
Mite quinone (acequinocyl), fluacrypyrim (fluacrypyrim) go out
15. the microorganism agent interfering of insect goldbeater's skin
Bacillus thuringiensis,Bt strain (Bacillus thuringiensis strain)
16. lipogenesis inhibitor
The tetronic acid class
For example spiral shell mite ester (spirodiclofen), spiromesifen
The tetramates acids
For example 3-(2, the 5-3,5-dimethylphenyl)-8-methoxyl group-2-oxo-1-azaspiro [4.5] last of the ten Heavenly stems-3-alkene-4-base ethyl carbonate ester (another name: carbonic acid 3-(2, the 5-3,5-dimethylphenyl)-8-methoxyl group-2-oxo-1-azaspiro [4.5] last of the ten Heavenly stems-3-alkene-4-base ethyl ester, the CAS number of registration: 382608-10-8) and carbonic acid suitable-3-(2, the 5-3,5-dimethylphenyl)-8-methoxyl group-2-oxo-1-azaspiro [4.5] last of the ten Heavenly stems-3-alkene-4-base ethyl ester (CAS number of registration: 203313-25-1)
17. amide-type, for example flonicamid (flonicamid)
18. octopaminergic agonist, for example Amitraz (amitraz)
19. magnesium stimulates the inhibitor of ATP enzyme (magnesium-stimulated ATPase), for example alkynes mite spy (propargite)
20.BDCA class, N-2-[1 for example, 1-dimethyl-2-(mesyl) ethyl]-3-iodo-N1-[2-methyl-4-[1,2,2,2-tetrafluoro-1-(trifluoromethyl) ethyl] phenyl]-1,2-benzenedicarboxamide (CAS number of registration: 272451-65-7)
21. the similar thing of nereistoxin, for example thiocyclam oxalate (thiocyclam hydrogenoxalate), dimehypo (thiosultap-sodium)
22. biologic artifact, hormone or pheromones
For example nimbin (azadirachtin), bacillus kind (Bacillus spec.), white muscardine fungi kind (Beauveria spec.), Pherocon CM (Codlemone), green muscardine fungus kind (Metarrhizium spec.), Paecilomyces varioti kind (Paecilomyces spec.), enemy Bei Te (Thuringiensin), Verticillium dahliae kind (Verticillium spec.)
23. the mechanism of action is unknown or indefinite reactive compound
23.1 fumigant
For example aluminum phosphate, bromomethane, vikane
23.2 selectivity food refusal agent
For example ice crystal (cryolite), flonicamid (flonicamid), pyrrole aphid ketone (pymetrozine)
23.3 acarid growth inhibitor
For example four mite piperazines (clofentezine), second mite azoles (etoxazole), Hexythiazox (hexythiazox)
23.4amidoflumet, benclothiaz, Citrazon (benzoximate), Bifenazate (bifenazate), fenisobromolate (bromopropylate), Buprofezin (buprofezin), chinomethionat (chinomethionat), galecron (chlordimeform), chlorobenzilate (chloro benzilate), chloropicrin (chloropicrin), clothiazoben, cycloprene, CGA 183893 (dicyclanil), fenoxacrim, fluorine nitre diphenylamines (fentrifanil), thiazole mite (flubenzimine), flufenerim, fluorine mite piperazine (flutenzin), gossyplure (gossyplure), Hydramethylnon Bait (hydramethylnone), japonilure, metoxadiazone (metoxadiazone), oil, piperonyl butoxide, potassium oleate, pyridalyl, sulfluramid (sulphluramid), tetradiphon (tetradifon), kill mite thioether (tetrasul), triarathene (triarathene), synergy alkynes ether (verbutin)
And also have
(1R-is suitable)-[5-(benzyl)-3-furyl] methyl-3-[(dihydro-2-oxo--3 (2H) furans subunit) methyl]-2,2-dinethyl cyclopropane carboxylic acid ester,
(3-Phenoxyphenyl) methyl-2,2,3,3-tetramethyl-ring propane formic acid esters,
1-[(2-chloro-5-thiazolyl) methyl] tetrahydrochysene-3,5-dimethyl-N-nitro-1,3,5-triazines-2 (1H)-imines,
2-(2-chloro-6-fluorophenyl)-4-[4-(1, the 1-dimethyl ethyl) phenyl]-4, the 5-dihydro-oxazole,
2-(acetoxyl group)-3-dodecyl-1, the 4-naphthalenedione,
2-chloro-N-[[[4-(1-phenyl ethoxy) phenyl] amino] carbonyl] benzamide,
2-chloro-N-[[[4-(2,2-two chloro-1,1-difluoroethoxy) phenyl] amino] carbonyl] benzamide, propyl carbamic acid 3-methyl phenyl ester,
4-[4-(4-ethoxyl phenenyl)-4-methyl amyl]-1-fluoro-2-phenoxy group benzene,
4-chloro-2-(1, the 1-dimethyl ethyl)-5-[[2-(2,6-dimethyl-4-phenoxy group phenoxy group) ethyl] sulfo-]-3 (2H)-pyridazinones,
4-chloro-2-(2-chloro-2-methyl-propyl)-5-[(6-iodo-3-pyridine radicals) methoxyl group]-3 (2H)-pyridazinones,
4-chloro-5-[(6-chloro-3-pyridine radicals) methoxyl group]-2-(3, the 4-dichlorophenyl)-3 (2H)-pyridazinones, bacillus thuringiensis,Bt (Bacillus thuringiensis) bacterial strain EG-2348,
Benzoic acid [2-benzoyl-1-(1, the 1-dimethyl ethyl) hydrazides,
Butyric acid 2,2-dimethyl-3-(2,4 dichloro benzene base)-2-oxo-1-oxaspiro [4.5] last of the ten Heavenly stems-3-alkene-4-base ester,
[3-[(6-chloro-3-pyridine radicals) methyl]-2-thiazolidine subunit (thiazolidinyliden)] ammonia cyanogen, dihydro-2-(Nitromethylene)-2H-1,3-thiazine-3 (4H) formaldehyde,
[2-[[1,6-dihydro-6-oxo-1-(benzyl)-4-pyridazinyl] oxygen] ethyl] urethanes,
N-(3,4,4-three fluoro-1-oxo-3-cyclobutenyls) glycine,
N-(4-chlorphenyl)-3-[4-(difluoro-methoxy) phenyl]-4,5-dihydro-4-phenyl-1H-pyrazoles-1-formamide,
N-methyl-N '-(1-methyl-2-acrylic)-1,2-hydrazine carbodithioic acid acid amides (hydrazindicarbothioamide),
N-methyl-N '-2-acrylic-1,2-hydrazine carbodithioic acid acid amides,
O, O-diethyl-[2-(dipropyl amino)-2-oxoethyl]-ethylenebis dithiocarbamate phosphinylidyne amino ester.
Also can mix, perhaps mix with other known reactive compounds---for example weed killer herbicide---with fertilizer and growth regulator.
When the insecticide, active agent combinations of the present invention can be further exists with its common commercial preparation form and by the administration form that mixes with synergist of described formulation preparation.Synergist itself not necessarily has active compound for improving the reactive compound activity.
Reactive compound content by the administration form of common commercial preparation preparation can change in wide scope.The activity compound concentration of administration form can be the reactive compound of 0.0000001 to 95 weight %, preferred 0.0001 to 1 weight %.
The usual manner of using to adapt with administration form carries out.
When being used to prevent and treat sanitary insect pest and storage area insect, the active component bond has following characteristics, i.e. fabulous residual activity on timber and the clay, and to the good stability of the alkali on the lime matrix.
Active agent combinations of the present invention not only has activity to plant insect, sanitary insect pest and storage area insect, also in veterinary applications to parazoon (vermin), for example hard tick, soft ticks, itch mite, trombiculid, fly (bite and suck), parasitic fly larva, lice, sting lice (poultry louse) and flea also has activity.Described parasite comprises:
Anoplura (Anoplurida), for example Haematopinus (Haematopinus spp.), Linognathus (Linognathus spp.), lice belong to (Pediculus spp.), Phtirus spp., the pipe lice belongs to (Solenopotes spp.),
Mallophaga (Mallophagida) and Amblycera (Amblycerina) and thin angle suborder (Ischnocerina), for example hair Trichodectes (Trimenopon spp.), Menopon (Menoponspp.), huge Trichodectes (Trinoton spp.), Bovicola (Bovicola spp.), Werneckiella spp., Lepikentron spp., Damalinia (Damalina spp.), Trichodectes (Trichodectes spp.), Felicola (Felicola spp.)
Diptera and Nematocera (Nematocerina) and Brachycera (Brachycerina), Aedes (Aedes spp.) for example, Anopheles (Anopheles spp.), Culex (Culexspp.), Simulium (Simulium spp.), Eusimulium (Eusimulium spp.), owl midge (Phlebotomus spp.), Lutzomyia (Lutzomyia spp.), Bitting midge (Culicoidesspp.), Chrysops (Chrysops spp.), knurl Gadfly (Hybomitra spp.), Atylotus (Atylotus spp.), Gadfly (Tabanus spp.), Chrysozona (Haematopota spp.), Philipomyia spp., honeybee Hippobosca (Braula spp.), Musca (Musca spp.), Hydrotaea (Hydrotaea spp.), Genus Stomoxys (Stomoxys spp.), Haematobia (Haematobia spp.), fly does not belong to (Morellia spp.), Fannia (Fannia spp.), Glossina (Glossina spp.), Calliphora (Calliphora spp.), Lucilia (Luciliaspp.), Carysomyia (Chrysomyia spp.), Wohlfahrtia (Wohlfahrtia spp.), Sarcophaga (Sarcophaga spp.), Oestrus (Oestrus spp.), Hypoderma (Hypodermaspp.), Gasterophilus (Gasterophilus spp.), Hippobosca (Hippobosca spp.), Lipoptena (Lipoptena spp.), Melophagus (Melophagus spp.)
Siphonaptera (Siphonapterida), for example flea belongs to (Pulex spp.), Ctenocephalus (Ctenocephalides spp.), objective flea belongs to (Xenopsylla spp.), Ceratophyllus (Ceratophyllus spp.),
Heteroptera (Heteropterida), for example Cimex (Cimex spp.), Triatoma (Triatoma spp.), Rhodnius (Rhodnius spp.), Triatoma (Panstrongylusspp.),
Blattaria (Blattarida), for example oriental cockroach (Blatta orientalis), American cockroach (Periplaneta americana), blatta germanica (Blattela germanica), Supella (Supella spp.),
Acari (Acari or Acarina) and back valve order (Metastigmata) and Mesostigmata (Mesostigmata), Argas (Argas spp.) for example, Ornithodoros (Ornithodorus spp.), residual beak tick belongs to (Otobius spp.), hard tick belongs to (Ixodes spp.), Amblyomma (Amblyomma spp.), Boophilus (Boophilus spp.), Dermacentor (Dermacentor spp.), Haemophysalis spp., Hyalomma (Hyalommaspp.), Rh (Rhipicephalus spp.), Dermanyssus (Dermanyssus spp.), sting sharp mite and belong to (Raillietia spp.), Pneumonyssus (Pneumonyssus spp.), chest thorn mite belongs to (Sternostoma spp.), Vespacarus (Varroa spp.)
Axle Acarina (Actinedida) (preceding valve suborder (Prostigmata)) and flour mite order (Acaridida) (Astigmata (Astigmata)), for example honeybee shield mite belongs to (Acarapisspp.), Cheyletiella (Cheyletiella spp.), Ornithocheyletia (Ornithocheyletia spp.), Myobia (Myobia spp.), Psorergates (Psorergates spp.), Demodex (Demodexspp.), Trombidium (Trombicula spp.), Listrophorus spp., Tyroglyphus (Acarusspp.), Tyrophagus (Tyrophagus spp.), have a liking for wooden mite and belong to (Caloglyphus spp.), mite belongs to (Hypodectes spp.) under the neck, the wing mite belongs to (Pterolichus spp.), Psoroptes (Psoroptes spp.), Chorioptes (Chorioptes spp.), the ear itch mite belongs to (Otodectesspp.), itch mite belongs to (Sarcoptes spp.), Notoedres (Notoedres spp.), the lump mite belongs to (Knemidocoptes spp.), Cytodites (Cytodites spp.), Laminosioptes (Laminosioptes spp.)
Active compound combinations of the present invention also is applicable to the arthropods of the following animal of control invasion: agriculture livestock comprises for example ox, sheep, goat, horse, pig, donkey, camel, buffalo, rabbit, tame chicken, turkey, duck, goose, honeybee, other domestic animal is dog, cat, cage bird, pet fish for example, reaches so-called laboratory animal for example hamster, cavy, rat and mouse.By preventing and treating above-mentioned arthropods, the situation that death condition and (meat, milk, hair, skin, egg, honey etc.) output descend can reduce, thereby but the active compound combinations of the application of the invention makes livestock breeding more economical and simpler.
Active compound combinations of the present invention is used for veterinary applications in known manner, can be by for example tablet, capsule, potus, preserved material, granule, paste, pill, feed (feed-through) method, the mode of suppository is carried out administration in the intestines, can be by for example injection (intramuscular, subcutaneous, vein, in the peritonaeum etc.), the intestines external administration is carried out in implantation, but nasal administration, can be by for example soaking or embathe or bathing, spraying, sprinkle and water (sprinkle and water and drop), clean, the form of dusting is carried out percutaneous drug delivery, and by means of the apparatus that contains reactive compound, necklace for example, ear tag, tail tag, limbs ligature (limb band), halter, concentrator marker etc.
When being used for livestock, poultry, domestic animal etc., reactive compound can comprise that the form of preparation (for example pulvis, emulsion, free-pouring medicament) of the reactive compound of 1 to 80 weight % amount directly uses or dilute 100 to 10, use after 000 times, or use with chemical Medicatedbath lotion (chemical bath) form.
And, found that active agent combinations of the present invention shows the strong insect active that kills to the insect of damaging industrial materials.
In the non-limiting instance mode following insect can be proposed preferably:
Beetle, for example
North America house longhorn beetle (Hylotrupes bajulus), Chlorophorus pilosis, furniture death watch beetle (Anobium punctatum), report dead death watch beetle (Xestobium rufovillosum), Ptilinus pectinicornis (Ptilinus pecticornis), Dendrobium pertinex, pine death watch beetle (Ernobius mollis), Priobium carpini, Lyctus brunneus Stephens (Lyctus brunneus), Africa powder moth (Lyctus africanus), south powder moth (Lyctus planicollis), quercitron moth (Lyctus linearis), pubescence powder moth (Lyctus pubescens), Trogoxylonaequale, minthea rugicollis (Minthes rugicollis), material bark beetle kind (Xyleborus spec.), Tryptodendron spec., coffee black long moth-eaten (Apate monachus), Mongolian oak long moth-eaten (Bostrychus capucins), brown different wing long moth-eaten (Heterobostrychus brunneus), long moth-eaten plant (the Sinoxylon spec.) of sour jujube, dinoderus minutus (Dinoderus minutus)
Hymenopteran (Hymenoptera), for example
Big wood wasp (Sirex juvencus), the big wood wasp of fir (Urocerus gigas), safe wood wasp (Urocerus gigas taignus), the Urocerus augur of strengthening,
Termite, for example
Europe kalotermitid (Kalotermes flavicollis), a fiber crops heap sand termite (Cryptotermesbrevis), ash point different termite (Heterotermes indicola), American-European reticulitermes flavipe (Reticulitermes flavipes), Sang Te reticulitermes flavipe (Reticulitermes santonensis), southern Europe reticulate pattern termite (Reticulitermes lucifugus), Darwin Australia termite (Mastotermesdarwiniensis), the ancient termite (Zootermopsis nevadensis) in Nevada, coptotermes formosanus (Coptotermes formosanus)
Moth (Bristletail), for example silverfish (Lepisma saccharina).
The implication of industrial materials is interpreted as non-living body (non-living) material among the present invention, for example, is preferably plastics, adhesive, sizing material, paper and cardboard, leather, timber, timber-work and coating.
To be protected with the material of avoiding insect pest infestation most preferably timber and timber-work.
Can or contain the timber of mixture protection of described medicament and the implication of timber-work is interpreted as by medicament of the present invention, for example:
The jetty of construction timber, wooden frame, railroad tie, bridge module, ship, the wooden vehicles, case, goods plate, container, electric pole, wooden covering (wood covering), wooden doors and windows, plywood, particle board, carpenter's product, or be usually used in the Wood products of house building or construction carpenter.
Active agent combinations can directly be used, perhaps with concentrate or generally use dosage form to use, and described general use formulation example such as pulvis, granule, solution, suspending agent, emulsion or paste.
Described preparation can be known usually method preparation, for example reactive compound and at least a solvent or thinner, emulsifier, dispersant and/or adhesive or fixative, waterproofing agent are mixed, optional also can mix, and choose wantonly also and can mix with colouring agent and pigment and other processing aid with desiccant and UV stabilizing agent.
Be used to protect the insecticide or the concentrate of timber or timber-work, containing concentration is 0.0001 to 95 weight %, the particularly reactive compound of the present invention of 0.001 to 60 weight %.
The usage amount of medicament or concentrate depends on kind and occurrence rate and the medium of insect.Optimum spraying amount can be determined by a series of test respectively.But generally speaking, be benchmark with material to be protected, use 0.0001 to 20 weight %, the reactive compound of preferred 0.001 to 10 weight % is just enough.
Solvent and/or thinner can be organic solvent or solvent mixture, and/or the organic solvent of low volatility oiliness or oily or solvent mixture, and/or polar organic solvent or solvent mixture, and/or water, and, optional emulsifier and/or wetting agent.
The preferred organic solvent that uses as evaporation number (evaporation number) be higher than 35, flash-point is higher than 30 ℃, preferably is higher than 45 ℃ the oiliness or the solvent of oily.The described water-fast low volatility oiliness of using and the solvent of oily are mineral oil or its aromaticity cut that suits or the solvent mixture that contains mineral oil, preferred petroleum solvent, oil and/or alkylbenzene.
Advantageously, can use oil or aromatic and the turpentine oil and the analog of 160 to 280 ℃ of bobbin oil, boiling ranges of 250 to 350 ℃ of petroleum solvent, boiling ranges of 170 to 220 ℃ of mineral oil, the boiling ranges of 170 to 220 ℃ of boiling ranges.
In a preferred embodiment, use the liquid aliphatic hydrocarbon of 180 to 210 ℃ of boiling ranges, or 180 to 220 ℃ the aromatic hydrocarbon and the high boiling mixture of aliphatic hydrocarbon, and/or bobbin oil, and/or naphthalene monochloride, preferred α-naphthalene monochloride.
Evaporation number is higher than 35, flash-point is higher than 30 ℃, preferably is higher than 45 ℃ the organic oiliness of low volatility or the solvent of oily, can partly replace with volatility or medium volatile organic solvent, as long as solvent mixture also has and is higher than 35 evaporation number and is higher than 30 ℃, preferably is higher than 45 ℃ flash-point, but and the mixture of described insecticide-fungicide solvable or emulsification in this solvent mixture.
In a preferred embodiment, the part of organic solvent or solvent mixture is replaced by polarity aliphatic series organic solvent or solvent mixture.The preferred aliphatic organic solvent that uses hydroxyl and/or ester group and/or ether, for example glycol ether, ester or analog.
Among the present invention available can in water, dilute and/or can be in the organic solvent that uses the known synthetic resin and/or the bonding drying oil (binding drying oil) of dissolving or dispersion or emulsification, particularly form or comprise the adhesive of following material: acrylate by following material, vinylite is polyvinyl acetate for example, mylar, polycondensation or polyaddition resin, polyurethane resin, alkyd resins or modified alkyd resin, phenol resin, hydrocarbon resins is coal-tar resin for example, silicone resin, dry vegetable oil and/or drying oil and/or based on natural and/or Albertol's physics dry adhesive.
As the Albertol of adhesive can emulsion, dispersion or solution form use.Pitch or bitumen can be used as adhesive, and consumption is up to 10 weight %.In addition, also can use known colouring agent, pigment, waterproofing agent, mask agent and inhibitor or corrosion inhibitor and analog.
According to the present invention, preferably exist at least a alkyd resins or modified alkyd resin and/or dry vegetable oil in medicament or the concentrate as adhesive.Preferred oil content is higher than the alkyd resins of 45 weight %, preferred 50 to 68 weight % according to the present invention.
Described adhesive can be fixed agent (mixture) or all or part of replacement of plasticizer (mixture).Described additive should prevent volatilization and the crystallization or the precipitation of reactive compound.Described additive preferably replaces 0.01 to 30% adhesive (is 100% in employed adhesive).
Plasticizer comes from following chemical classes: phthalic acid ester, for example dibutyl phthalate, dioctyl phthalate or phthalic acid benzyl butyl ester; Phosphate, for example tributyl phosphate; Adipate ester, for example adipic acid two (2-ethylhexyl) ester; Stearate, for example butyl stearate or amyl stearate; Oleate, for example butyl oleate; Glycerine ether or HMW glycol ether, glycerine ester and p-toluenesulfonic esters.
Fixative is chemically based on polyethylene alkyl ether, polyvinyl methyl ethermaleic anhydride for example, or based on ketone, for example benzophenone, ethylene Benzophenone.
Water also is particularly suitable as solvent or thinner, and water can be chosen wantonly and one or more above-mentioned organic solvents or thinner, emulsifier and dispersant.
Especially effectively wood protection is finished by plant-scale impregnation technology, for example vacuum, two vacuum or pressure process.
Promptly the medicament of usefulness can be chosen the insecticide that contains other wantonly, and optional one or more fungicide that contains.
Active agent combinations of the present invention also can be used for protecting the object that contacts with seawater or brackish water, particularly hull, sieve, net, building, mooring arrangement and signal system, in case produce dirt.
By the Oligochaeta animal (Oligochaete) of anchorage polychaete worm (tube worm) and for example by mollusk (mollusc) and Ledamorpha population (goose tender tea leaves lotus (goosebarnacles)), for example various tender tea leaves lotuses belong to (Lepas) and plant and armour tender tea leaves lotus genus (Scalpellum) kind, or by barnacle (Balanomorpha) population (barnacle (acorn or rock barnacles)), for example Balanus (Balanus) is planted or the tortoise foot belongs to the dirt that (Pollicipes) kind causes, can increase the frictional resistance of ship, the result because higher energy consumption and on dry dock extra frequent stop cause running expense significantly to increase.
Remove algae, for example outside the dirt that Ectocarpus (Ectocarpus sp.) and Ceratium (Ceramium sp.) cause, by being included into also particular importance of dirt that the anchorage Entomostraca class that is generically and collectively referred to as cirrus guiding principle (Cirripedia) (barnacle (barnacles)) causes.
Beat all is to have now found that active agent combinations of the present invention shows outstanding antifouling effect.
Use active component bond of the present invention can avoid using heavy metal, the heavy metal that in following compound, uses for example: two (trialkyltin) sulphide, lauric acid-three-normal-butyl tin, three normal-butyl chlorination tin, cuprous oxide (I), ethyl tin chloride, three normal-butyls (2-phenyl-4-chlorophenoxy) tin, tributyltin oxide, molybdenum bisuphide, antimony oxide, n-butyl titanate polymer, phenyl (two pyridine) bismuth trichloride, tri-n-butyl tin fluoride, ethylenebis thiocarbamic acid manganese (manganese ethylenebisthiocarbamate), zine dimethyldithiocarbamate, ethylenebis thiocarbamic acid zinc, 2-pyridine mercaptan-1-oxygen zinc salt and 2-pyridine mercaptan-1-oxygen mantoquita, ethylene thiocarbamic acid-two Methyl disulfide are for carbamyl zinc (bisdimethyldithiocarbamoylzinc ethylenebisthiocarbamate), zinc oxide, ethylenebis aminodithioformic acid cuprous (copper (I) ethylenebisdithiocarbamate), cupric thiocyanate, copper naphthenate and tributyltin halide, or significantly reduce the concentration of above-claimed cpd.
Promptly the antifouling paint of usefulness can be chosen wantonly and comprise other reactive compound, preferred algicide, fungicide, weed killer herbicide, invertebrate poison or other antifouling activity compound.
The preferred ingredient that is fit to combine with antifouling composition of the present invention has:
Algicide, for example
2-tert-butyl group amino-4-cyclopropyl amino-6-methyl mercapto-1,3,5-triazine, antiphen, diuron (diuron), endothal (endothal), fentin acetate, isoproturon (isoproturon), methabenzthiazuron (methabenzthiazuron), Oxyfluorfen (oxyfluorfen), quinoclamine (quinoclamine) and terbutryn (terbutryn);
Fungicide, for example:
Benzo [b] thiophene carboxylic acid cyclohexyl amide-S, S-dioxide, dichlofluanid (dichlofluanid), fluorfolpet, 3-iodo-2-propynyl butyl carbamate, Tolylfluanid (tolylfluanid) and pyroles for example:
Oxygen ring azoles (azaconazole), Cyproconazole (cyproconazole), oxole bacterium (epoxyconazole), own azoles alcohol (hexaconazole), metconazole (metconazole), propiconazole (propiconazole) and Tebuconazole (tebuconazole);
Invertebrate poison, for example:
Fe chelating agent, fentin acetate, the methaldehyde (metaldehyd), methiocarb (methiocarb), niclosamide (niclosamid), second worm nitrile (ethiprole) and Landrin (trimethacarb);
Or conventional anti-fouling compound, for example
4,5-two chloro-2-octyl groups-4-isothiazoline-3-ketone, diiodomethylparatryl 2-(N, N-dimethyl thiocarbamoyl sulphur)-5-nitrothiazole base
(2-(N, N-dimethylthiocarbamoylthio)-5-nitrothiazyl) sulfone, 2-pyridine mercaptan-1-oxygen sylvite, mantoquita, sodium salt and zinc salt; pyridine-triphenyl borane, the tetrabutyl two tin oxirane, 2; 3,5,6-tetrachloro-4-(mesyl) pyridine; 2,4,5; the 6-daconil M; tetramethylthiuram disulfide and 2,4,6-trichlorophenyl maleimide.
The antifouling composition that uses comprises 0.001 to 50 weight %, the particularly reactive compound of 0.01 to 20 weight % concentration.
In addition, antifouling composition also comprises for example Ungerer, Chem.Ind.1985,37,730-732 and Williams, Antifouling Marine Coatings, Noyes, Park Ridge, the conventional component described in 1973.
Except that killing algae, antifungal, killing mollusk and kill the insect active compound, antifouling paint also comprises adhesive especially.
The example of generally acknowledging adhesive has: the polyvinyl chloride in the dicyandiamide solution, chlorinated rubber in the dicyandiamide solution, dicyandiamide solution is the acrylic resin in the aqueous systems particularly, the vinyl chloride of aqueous dispersion form or organic solvent system form/vinyl acetate copolymer system, Butadiene/acrylic-nitrile rubber, drying oil, for example Linseed oil, resin ester or the modification animi resin that combines with tar or pitch, pitch and epoxide, a small amount of chlorinated rubber, chlorinated polypropylene and vinylite.
Randomly, coating also comprises inorganic pigment, organic pigment or the colouring agent that preferably is insoluble to seawater.This rustproof lacquer can comprise the material that makes the reactive compound controlled release, for example rosin.Coating also can comprise plasticizer, influence modifier and other conventional components of rheological properties.Active component bond of the present invention also can be contained in the polishing antifouling system.
Active component bond of the present invention also is suitable for preventing and treating the animal pest in the confined space, particularly insect, arachnid and acarid, described enclosure space comprises for example residence, factory floor, office, vehicles workplace (vehicle cabin) etc.They can be separately or combine the family expenses that are used for preventing and treating described insect with other reactive compounds and auxiliary agent and kill the insect product.They are all effective to responsive and resistance species and whole developmental stage.Described insect comprises:
Scorpionida (Scorpionidea), the yellow scorpion (Buthus occitanus) in Mediterranean for example,
Acarina (Acarina), adobe tick (Argas persicus) for example, argas reflexus (Argas reflexus), tongue mite subspecies (Bryobia ssp.), Dermanyssus gallinae (Dermanyssusgallinae), sweet mite (Glyciphagus domesticus) is had a liking for by family, tampan tick (Ornithodorus moubat), brown dog tick (Rhipicephalus sanguineus), eutrombicula alfreddugesi (Trombicula alfreddugesi), Neutrombicula autumnalis, the spy has a liking for skin mite (Dermatophagoides pteronissimus), method is had a liking for skin mite (Dermatophagoides forinae)
Araneida (Araneae), for example catching bird spider (Aviculariidae), the circle spider (Araneidae),
Opiliones (Opiliones), for example chelifer (Pseudoscorpiones chelifer), the blind spider of the Chang Shin of Pseudoscorpiones cheiridium, (Opiliones phalangium),
Isopoda, for example comb beach louse, ball pillworm.
Doubly sufficient order, for example Blaniulus guttulatus, mountain cricket worm (Polydesmus spp.).
Lip foot order, for example DIWUGONG (Geophilus spp.).
Silverfish order (Zygentoma), for example the comb silverfish belongs to (Ctenolepisma spp.), silverfish, robber fireworm (Lepismodes inquilinus).
Blattaria, for example oriental cockroach, blatta germanica, Asia Lian (Blattella asahinai), leucophaea maderae, angle abdomen Lian belong to (Panchlora spp.), wooden Lian belongs to (Parcoblatta spp.), Australian cockroach (Periplaneta australasiae), American cockroach, big brown big Lian (Periplanetabrunnea), smoke Perilpaneta americana (Periplaneta fuliginosa), brown belt blattaria (Supellalongipalpa)
Saltatoria (Saltatoria), for example tame Xi,
Dermaptera, European earwig for example,
Isoptera, for example kalotermitid belongs to (Kalotermes spp.), Reticulitermes.
Corrodentia (Psocoptera), for example Lepinatus spp., powder corrodent belong to (Liposcelisspp.),
Coleoptera, for example Anthrenus, fur moth-eatenly belong to, khapra beetle belongs to, a long ostomatid (Latheticusoryzae), latent instep cuckoo Eimeria (Necrobia spp.), Ptinus, lesser grain borer, grain weevil (Sitophilusgranarius), rice weevil (Sitophilus oryzae), corn weevil (Sitophilus zeamais), Stegobium paniceum (Stegobium paniceum)
Diptera, Aedes aegypti (Aedes aegypti) for example, aedes albopictus (Aedesalbopictus), aedes taeniorhynchus (Aedes taeniorhynchus), Anopheles, calliphora erythrocephala, great number fiber crops horsefly (Chrysozona pluvialis), five band Culex pipiens pallens (Culexquinquefasciatus), northern house (Culex pipiens), ring beak culex (Culextarsalis), Drosophila (Drosophila spp.), Fannia canicularis (Fannia canicularis), housefly (Musca domestica), owl midge, Sarcophaga carnaria, Simulium, tatukira (Stomoxys calcitrans), the Europe daddy-longlegs
Lepidoptera, for example lesser wax-moth (Achroia grisella), greater wax moth, Indian meal moth (Plodiainterpunctella), stopper rain moth (Tinea cloacella), bag rain moth, curtain rain moth,
Siphonaptera, for example ctenocephalides canis (Ctenocephalides canis), ctenocephalides felis (Ctenocephalides felis), Pulex irritans (Pulex irritans), chigo (Tungapenetrans), Xanthopsyllacheopis,
Hymenoptera, for example blazon hunchbacked ant (Camponotus herculeanus), black smelly ant (Lasius fuliginosus), black ant (Lasius niger), Lasius umbratus, MonomoriumMayr, Paravespula spp., Pavement Ant (Tetramorium caespitum)
Anoplura (Anoplura), for example head louse (Pediculus humanus capitis), body louse, crab louse (Phthirus pubis),
Heteroptera, for example cimex hemipterus (Cimex hemipterus), bed bug, phodnius prolixus, invasion triatomid (Triatoma infestans),
Application in family expenses insecticide field also can combine realization with other suitable reactive compound, and above-mentioned suitable reactive compound comprises phosphate for example, carbamate, pyrethroid, growth regulator or from the reactive compound of other known insecticide kind.
Use can following product form carry out: aerosol, vacuum spraying (non-pressurised spray) product, for example pump and atomizer (nebuliser) spraying, automatic atomizing system, aerosol, foaming agent, gel, evaporation product with the evaporating pan (evaporator plate) that makes by cellulose or plastics, liquid evaporator, gel and thin film evaporation agent, the evaporant of propellant actuated, unpowered (non-energy) or passive (passive) vapo(u)rization system, catch moth paper, catch the moth bag and catch moth glue, and in the bait or Poison bait station (bait station) that are used for shedding as granule or powder agent.
When using active agent combinations of the present invention, amount of application can change in wide region according to application process.When handling plant parts, the consumption of active agent combinations is generally 0.1-10,000g/ha (hectare), preferred 10-1,000g/ha.
Following examples have demonstrated the good insect active that kills of active agent combinations of the present invention.Though independent reactive compound shows active faint, the activity that bond shows surpassed simply adding of compound activity and.
The expection activity of two kinds of given active component bonds can calculate as follows (referring to Colby, S.R., " Calculating Synergistic and Antagonistic Responses ofHerbicide Combinations ", Weeds
15, 20-22 page or leaf, 1967):
If
X representative when with
mLethality when the amount of application of ppm uses active component A is expressed as the percentage of untreated control group,
Y representative when with
nLethality when the amount of application of ppm uses active component B is expressed as the percentage of untreated control group,
E representative when with
mWith
nLethality when the amount of application of ppm uses active component A and B is expressed as the percentage of untreated control group,
Then
If actual insect mortality surpasses calculated value, then the lethality of bond has superadditivity, promptly has synergistic effect.In this case, actual observation to lethality must surpass adopt following formula calculate expected mortality value (E).
Embodiment A
Brown planthopper test (land for growing field crops)
Product (standard preparation): Imidacloprid EC 050
Second worm nitrile SC 100
Be preparation suitable actives matter preparation, the water of appropriate amount mixed with the product of aequum, and it is diluted to desired concn.
Rice (Oryza sativa) plant is invaded and harassed with the product spraying of desired concn and with brown planthopper (Nilaparvata lugen).
Through behind the required time, determine the number of brown planthopper alive and calculate lethality with %, wherein all brown planthoppers are killed in 100% expression, and the no brown planthopper of 0% expression is killed.
In this test, the application's following active agent combinations shows the activity of Synergistic with respect to the reactive compound of using separately:
Table A
The insect of harm plant
Brown planthopper test (field experiment)
| Product | Concentration (g ai/ha) | Lethality after 21 days (%) | |
| Imidacloprid EC 050 | 12.5 | 0 | |
| Second worm nitrile SC 100 | 12.5 | 3.1 | |
| Imidacloprid EC 050+ second worm nitrile SC of the present invention 100 (1: 1) | 12.5+12.5 | Measured value * | Calculated value ** |
| 90.8 | 3.1 | ||
*Measured value=measurement is active
*Calculated value=usefulness Colby formula activity calculated
Embodiment B
The black peach aphid test
Solvent: the dimethyl formamide of 7 weight portions
Emulsifier: the alkylaryl polyglycol ether of 2 weight portions
Be preparation suitable actives matter preparation,, and the water that dope usefulness contains emulsifier be diluted to desired concn the solvent and the emulsifier of active substance and the specified rate of 1 weight portion.
Wild cabbage (Brassica oleracea) leaf that will seriously be infected by black peach aphid (Myzus persicae) immerses in the active mixture preparation of desired concn to be handled.
Through behind the required time, calculate lethality with %, wherein all aphids are killed in 100% expression; The no aphid of 0% expression is killed.Calculate lethality with the Colby formula.
In this test, for example, the application's following active agent combinations shows the activity of Synergistic with respect to the reactive compound of using separately.
Table B
The insect of harm plant
The black peach aphid test
| Reactive compound | Concentration (ppm) | Lethality after 6 days (%) | |
| Second worm nitrile | 4 | 0 | |
| Thiophene worm amine | 4 | 0 | |
| Second worm nitrile of the present invention+thiophene worm amine (1: 1) | 4+4 | Measured value * | Calculated value ** |
| 20 | 0 | ||
*Measured value=measurement is active
*Calculated value=usefulness Colby formula activity calculated
Table B
The insect of harm plant
The black peach aphid test
| Reactive compound | Concentration (ppm) | Lethality after 6 days (%) | |
| Second worm nitrile | 0.8 | 0 | |
| Imidacloprid | 0.16 | 0 | |
| Second worm nitrile+Imidacloprid of the present invention (5: 1) | 0.8+0.16 | Measured value * | Calculated value ** |
| 70 | 0 | ||
*Measured value=measurement is active
*Calculated value=usefulness Colby formula activity calculated
Table B
The insect of harm plant
The black peach aphid test
| Reactive compound | Concentration (ppm) | Lethality after 6 days (%) | |
| Second worm nitrile | 4 | 10 | |
| Thiophene worm quinoline | 0.8 | 15 | |
| Second worm nitrile of the present invention+thiophene worm quinoline (5: 1) | 4+0.8 | Measured value * | Calculated value ** |
| 45 | 23.5 | ||
*Measured value=measurement is active
*Calculated value=usefulness Colby formula activity calculated
Embodiment C
Diamond-back moth test (standard sensitive strain (normal sensitive strain))
Solvent: the dimethyl formamide of 7 weight portions
Emulsifier: the alkylaryl polyglycol ether of 2 weight portions
Be preparation suitable actives matter preparation,, and the water that dope usefulness contains emulsifier be diluted to desired concn the solvent and the emulsifier of active substance and the specified rate of 1 weight portion.
Cabbage leaves is immersed in the active mixture preparation of desired concn and handle, and when leaf is still moistening, infect with diamond-back moth (Plutella xylostella, standard sensitive strain) larva.
Through behind the required time, calculate lethality with %, wherein all larvas are killed in 100% expression, and the no larva of 0% expression is killed.Calculate lethality with the Colby formula.
In this test, for example, the application's following active agent combinations shows the activity of Synergistic with respect to the reactive compound of using separately:
Table C
The insect of harm plant
Diamond-back moth (standard sensitive strain) test
| Reactive compound | Concentration (ppm) | Lethality after 6 days (%) | |
| Second worm nitrile | 4 | 0 | |
| Thiophene worm amine | 4 | 10 | |
| Second worm nitrile of the present invention+thiophene worm amine (1: 1) | 4+4 | Measured value * | Calculated value ** |
| 75 | 10 | ||
*Measured value=measurement is active
*Calculated value=usefulness Colby formula activity calculated
Table C
The insect of harm plant
Diamond-back moth (standard sensitive strain) test
| Reactive compound | Concentration (ppm) | Lethality after 4 days (%) | |
| Second worm nitrile | 20 | 35 | |
| Thiophene worm quinoline | 4 | 0 | |
| Second worm nitrile of the present invention+thiophene worm quinoline (5: 1) | 20+4 | Measured value * | Calculated value ** |
| 55 | 35 | ||
*Measured value=measurement is active
*Calculated value=usefulness Colby formula activity calculated
Embodiment D
The fall army worm test
Solvent: the dimethyl formamide of 7 weight portions
Emulsifier: the alkylaryl polyglycol ether of 2 weight portions
Be preparation suitable actives matter preparation,, and the water that dope usefulness contains emulsifier be diluted to desired concn the solvent and the emulsifier of active substance and the specified rate of 1 weight portion.
Cabbage leaves is immersed in the active mixture preparation of desired concn and handle, and when leaf is still moistening, infect with the larva of fall army worm (Spodoptera frugiperda).
Through behind the required time, calculate lethality with %, wherein all larvas are killed in 100% expression, and the no larva of 0% expression is killed.Calculate lethality with the Colby formula.
In this test, for example, the application's following active agent combinations shows the activity of Synergistic with respect to the reactive compound of using separately.
Table D
The insect of harm plant
The fall army worm test
| Reactive compound | Concentration (ppm) | Lethality after 6 days (%) | |
| Second worm nitrile | 4 | 0 | |
| Imidacloprid | 4 | 15 | |
| Second worm nitrile+Imidacloprid of the present invention (1: 1) | 4+4 | Measured value * | Calculated value ** |
| 40 | 15 | ||
*Measured value=measurement is active
*Calculated value=usefulness Colby formula activity calculated
Claims (10)
1. medicament comprises the following formula second worm nitrile with synergistic activity and the mixture of at least a anabasine compound
2. medicament comprises the second worm nitrile with synergistic activity and the mixture of Imidacloprid.
3. medicament comprises the second worm nitrile with synergistic activity and the mixture of Acetamiprid.
4. medicament comprises the second worm nitrile with synergistic activity and the mixture of Nitenpyram.
5. medicament comprises the second worm nitrile with synergistic activity and the mixture of thiophene worm piperazine.
6. medicament comprises the second worm nitrile with synergistic activity and the mixture of thiophene worm amine.
7. medicament comprises the second worm nitrile with synergistic activity and the mixture of thiophene worm quinoline.
8. medicament comprises the second worm nitrile with synergistic activity and the mixture of MTI-446.
9. the purposes that each described medicament is used to prevent and treat animal pest among the claim 1-8.
10. a method for preparing pest control agent is characterized in that each described mixture with synergistic activity among the claim 1-8 is mixed with thinner and/or surfactant.
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|---|---|---|---|
| DE102004028994.8 | 2004-06-16 | ||
| DE102004028994 | 2004-06-16 | ||
| DE102004038329.4 | 2004-08-06 |
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