CN106605654A - Insecticidal composition containing SYP-9625 - Google Patents

Insecticidal composition containing SYP-9625 Download PDF

Info

Publication number
CN106605654A
CN106605654A CN201510688423.1A CN201510688423A CN106605654A CN 106605654 A CN106605654 A CN 106605654A CN 201510688423 A CN201510688423 A CN 201510688423A CN 106605654 A CN106605654 A CN 106605654A
Authority
CN
China
Prior art keywords
azoles
demodicid mite
nitrile
weight ratio
jing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201510688423.1A
Other languages
Chinese (zh)
Inventor
张伟
高云
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shaanxi Welch Crop Protection Co Ltd
Original Assignee
Shaanxi Welch Crop Protection Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shaanxi Welch Crop Protection Co Ltd filed Critical Shaanxi Welch Crop Protection Co Ltd
Priority to CN201510688423.1A priority Critical patent/CN106605654A/en
Publication of CN106605654A publication Critical patent/CN106605654A/en
Pending legal-status Critical Current

Links

Classifications

    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N31/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic oxygen or sulfur compounds
    • A01N31/08—Oxygen or sulfur directly attached to an aromatic ring system
    • A01N31/14—Ethers
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/02—Saturated carboxylic acids or thio analogues thereof; Derivatives thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N41/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom
    • A01N41/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom containing a sulfur-to-oxygen double bond
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/58—1,2-Diazines; Hydrogenated 1,2-diazines
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
    • A01N47/24—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing the groups, or; Thio analogues thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N53/00—Biocides, pest repellants or attractants, or plant growth regulators containing cyclopropane carboxylic acids or derivatives thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N55/00—Biocides, pest repellants or attractants, or plant growth regulators, containing organic compounds containing elements other than carbon, hydrogen, halogen, oxygen, nitrogen and sulfur
    • A01N55/02—Biocides, pest repellants or attractants, or plant growth regulators, containing organic compounds containing elements other than carbon, hydrogen, halogen, oxygen, nitrogen and sulfur containing metal atoms
    • A01N55/04—Tin

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The invention discloses an insecticidal composition containing SYP-9625. The insecticidal composition contains effective active components of an active component A and an active component B, wherein the active component A is SYP-9625, and the active component B is selected from any one of the following compounds, pyridaben, azocyclotin, bifenazate, avermectin, propargite, fenpropathrin, tebufenpyrad, fenpyroximate, acequinocyl, halfenprox, and cyenopyrafen. The weight ratio of the active component A to the active component B is 1:80-80:1. The composition is synergistic to multiple insects which are harmful to the agricultural production. The pesticide consumption is lowered, the residual quantity on crops of a pesticide is reduced, and the environmental pollution is eliminated. The composition is safe to people and animals, good to environmental compatibility, and not prone to cause insects to generate pesticide resistance.

Description

A kind of Pesticidal combination of the demodicid mite of azoles containing second nitrile
Technical field
The invention belongs to technical field of pesticide, is related to a kind of Pesticidal combination of the demodicid mite of azoles containing second nitrile and exists Application on crop pests.
Background technology
Second azoles demodicid mite nitrile is Shenyang Sciencreat Chemicals Co., Ltd.'s product, is had to apple tree red spider Good preventive effect, 7d preventive effects are 82.17%～100% after medicine, and quick-acting is preferable, holding effect Phase 14d or so, recommends to start dispenser in red spider generation Sheng phase beginning.
Pyridaben, azacyclotin, Bifenazate, avilamycin, propargite, Fenpropathrin, pyrrole Demodicid mite amine, fenpyroximate, acequinocyl, halfenprox, nitrile pyrrole demodicid mite ester belong to conventional anabasine Insecticide, is widely used in preventing and treating the insect pest on crops, and prevention effect is preferable.
But in the real process of agricultural production, pest control is easiest to generate the problem that The generation of pest resistance to insecticide.Different cultivars composition is compounded, and is that preventing and treating resistant insect is very normal The method seen.Heterogeneity is compounded, and judges that certain is answered according to practical application effect Be potentiation, plus and or antagonism.In most cases, the compounding effect of pesticide All it is additive effect, really has the compounding of potentiation seldom, especially potentiation is very Substantially, the very high compounding of co-toxicity coefficient is just less.Through inventor's research, find second Azoles demodicid mite nitrile and pyridaben, azacyclotin, Bifenazate, avilamycin, propargite, Fenpropathrin, Increasing well can be produced after tebufenpyrad, fenpyroximate, acequinocyl, halfenprox, nitrile pyrrole demodicid mite ester compounding Effect is acted on, and with regard to second azoles demodicid mite nitrile and pyridaben, azacyclotin, Bifenazate, avilamycin, Propargite, Fenpropathrin, tebufenpyrad, fenpyroximate, acequinocyl, halfenprox, nitrile pyrrole demodicid mite ester are answered The relevant report matched somebody with somebody not yet is disclosed.
The content of the invention
Have that synergistic function, use cost be low, preventive effect the purpose of the present invention is to propose to a kind of The Pesticidal combination of the good demodicid mite nitrile of azoles containing second.
The Pesticidal combination of the demodicid mite of azoles containing second nitrile proposed by the present invention by active components A with activity into Divide B compositions, active components A is the ︰ 1 of 1 ︰ 80～80 with active component B weight ratio, described Active components A be second azoles demodicid mite nitrile, active component B be selected from pyridaben, azacyclotin, biphenyl Hydrazine ester, avilamycin, propargite, Fenpropathrin, tebufenpyrad, fenpyroximate, acequinocyl, benzyl One of demodicid mite ether, nitrile pyrrole demodicid mite ester kind, active components A and the preferred weight ratios of active component B For the ︰ 1 of 1 ︰ 40～40；More preferably the weight ratio of second azoles demodicid mite nitrile and pyridaben is 20:1～1:20； The weight ratio of second azoles demodicid mite nitrile and azacyclotin is 20:1～1:20；The weight of second azoles demodicid mite nitrile and Bifenazate Amount is than being 15:1～1:25；The weight ratio of second azoles demodicid mite nitrile and avilamycin is 25:1～1:15；Second azoles The weight ratio of demodicid mite nitrile and propargite is 15:1～1:25；The weight ratio of second azoles demodicid mite nitrile and Fenpropathrin For 20:1～1:20；The weight ratio of second azoles demodicid mite nitrile and tebufenpyrad is 15:1～1:25；Second azoles demodicid mite nitrile and The weight ratio of fenpyroximate is 20:1～1:20；The weight ratio of second azoles demodicid mite nitrile and acequinocyl is 20:1～1:20；The weight ratio of second azoles demodicid mite nitrile and halfenprox is 20:1～1:20；Second azoles demodicid mite nitrile and nitrile The weight ratio of pyrrole demodicid mite ester is 20:1～1:20.
The Pesticidal combination of the demodicid mite of azoles containing second nitrile proposed by the present invention is used to prevent and treat insect on crops Purposes, described crops include that cereal crops, legume crop, fibre crops, sugar material are made Thing, melon crop, fruits crop, dry fruit crop, hobby crop, root crop, Oil crop, flower crop, medicinal crop, crop, green manure pasture crop；Described Insect be red spider, rust mite, tetranychid, planthopper, rice leaf roller, striped rice borer, Yellow rice borer, diamondback moth, Pieris rapae, bollworm, leaf miner, blister mite, America speckle are dived Fly, pear sucker or small heart-eating peach worm.
Active components A, the weight ratio of active component B are the ︰ 1 of 1 ︰ 80～80.Usual compositionss The weight percentage of middle active component for gross weight 0.5%～90%, preferably 5%～ 80%.According to different preparation types, active component content scope is different.Generally, liquid Body preparation contains by weight 1%～70% active substance, and preferably 5%～50%；Gu Body preparation contains by weight 5%～80% active substance, and preferably 10%～80%.
At least contain a kind of surfactant in the Pesticidal combination of the present invention, when being beneficial to administration Dispersion of the active component in water.Surface-active contents are the 5%～30% of total formulation weight, Balance of solid or liquid diluent.
The Pesticidal combination of the present invention can diluted using front Jing or directly used by user. It is prepared can be prepared by common processing method known in those skilled in the art, will activity After material mixes with liquid flux or solid carrier, surfactant such as dispersant, steady is added Determine one or more in agent, wetting agent, binding agent, defoamer, disintegrating agent, antifreeze etc..
The Pesticidal combination of the present invention, can be processed on demand acceptable dose on any pesticide Type, wherein more preferably dosage form be wettable powder, water dispersible granules, suspending agent, suspension emulsion, Aqueous emulsion, microemulsion, microcapsule suspending agent, microcapsule suspension-suspendinagent agent, can also make effervescent Tablet, seed coat agent, ultra-low-volume formulation, water preparation, soluble liquid, soluble powder, hot mist Agent.
Compositionss include following constituent content when making wettable powder：Active components A 0.1%～ 80%th, active component B0.1%～80 dispersant 2%～10%, wetting agent 2%～10%, filler Surplus.
Compositionss include following constituent content when making water dispersible granules：Active components A 0.1%～ 80%th, active component B0.1%～80 dispersant 3%～12%, wetting agent 1%～8%, disintegrating agent 1%～10%, binding agent 0～8%, filler surplus.
Compositionss include following constituent content when making suspending agent：Active components A 0.1%～50%, Active component B0.1%～50%, dispersant 2%～10%, wetting agent 2%～10%, defoamer 0.01%～2%, thickening agent 0～2%, antifreeze 0～8%, deionized water add to 100%.
Compositionss include following constituent content when making suspension emulsion：Active components A 0.1%～50%, Active component B0.1%～50%, dispersant 2%～10%, defoamer 0.01%～2%, solvent 1%～15%, thickening agent 0～2%, emulsifying agent 2%～12%, antifreeze 0～8%, deionized water Add to 100%.
Compositionss include following constituent content when making aqueous emulsion：Active components A 0.1%～50%, Active component B0.1%～50%, solvent 1%～30%, emulsifying agent 1%～15%, antifreeze 0～8%, Thickening agent 0～2%, defoamer 0.01%～2%, deionized water supply surplus.
Compositionss include following constituent content when making microcapsule suspending agent：Active components A 0.1%～50%, active component B0.1%～50%, macromolecule cyst material 2%～10%, dispersion Agent 1%～10%, organic solvent 1%～10%, defoamer 0.01%～2%, emulsifying agent 1%～7%, PH adjusting agent 0.01%～5%, deionized water adds to 100%.
Compositionss include following constituent content when making microcapsule suspension-suspendinagent agent：Active components A 0.1%～50%, active component B0.1%～50%, macromolecule cyst material 2%～10%, dispersion Agent 1%～12%, wetting agent 1%～8%, organic solvent 1%～15%, emulsifying agent 1%～6%, Defoamer 0.01%～2%, thickening agent 0～2%, pH adjusting agent 0.01%～5%, deionized water Add to 100%.
The wettable powder the key technical indexes of the present invention：
The water dispersible granules the key technical indexes of the present invention：
The suspending agent the key technical indexes of the present invention：
The suspension emulsion the key technical indexes of the present invention：
The aqueous emulsion the key technical indexes of the present invention：
The microcapsule suspending agent the key technical indexes of the present invention：
The microcapsule suspension-suspendinagent agent the key technical indexes of the present invention：
It is an advantage of the current invention that：
(1) second azoles demodicid mite nitrile and pyridaben, azacyclotin, Bifenazate, avilamycin, propargite, After Fenpropathrin, tebufenpyrad, fenpyroximate, acequinocyl, halfenprox, nitrile pyrrole demodicid mite ester compounding, tool There are obvious potentiation and lasting effect；(2) to cereal crops, legume crop, fibre crops, Sugar crop, melon crop, fruits crop, dry fruit crop, hobby crop, tuberses Crop, oil crop, flower crop, medicinal crop, crop, green manure pasture crop evil Worm has greater activity；(3) pesticide usage amount is reduced, reduces pesticide residual on crop Allowance, alleviates environmental pollution；(4) to person poultry safety, Environmental compatibility is good；And preparation Adhesion strength strengthens, resistance of rainwater washing against.
Specific embodiment
With reference to embodiment to further instruction of the present invention, the percentage ratio in embodiment is Percentage by weight, but the invention is not limited in this.
Application Example one
The wettable powder of embodiment 1～8
Second azoles demodicid mite nitrile, active component B, dispersant, wetting agent, filler are mixed in mixed cylinder Close uniform, remix Jing after jet mill is crushed uniform, you can be obtained it is of the present invention can WP product, is specifically shown in Table 1.
The each component of 1 embodiment of table 1～8 and weight portion
The water dispersible granules of embodiment 9～16
By second azoles demodicid mite nitrile, active component B, dispersant, wetting agent, disintegrating agent, filler etc. Rise Jing comminution by gas stream obtain need particle diameter, add binding agent (can add to be not added with) etc. other Auxiliary agent, obtains materials of pelletizing.Item is quantitatively sent in fluidized bed granulating dryer through granulation And after being dried, you can water dispersible granules product of the present invention is obtained, 2 are specifically shown in Table.
The each component of 2 embodiment of table 9～16 and weight portion
The suspending agent of embodiment 17～24
By dispersant, wetting agent, defoamer, thickening agent (can add to be not added with), antifreeze (can Plus can be not added with), through high speed shear mix homogeneously, second azoles demodicid mite nitrile, active component B are added, Ball milling 2～3 hours in ball mill, make diameter of particle all below 5 μm, and surplus spends Ionized water is supplied, you can suspending agent product of the present invention is obtained, 3 are specifically shown in Table.
The each component of 3 embodiment of table 17～24 and weight portion
The suspension emulsion of embodiment 25～28
By dispersant, defoamer, thickening agent (can add to be not added with), (can add can for antifreeze It is not added with) through high speed shear mix homogeneously, add active component B, the ball milling in ball mill 2～3 hours, make diameter of particle all below 5 μm, active component B suspending agents are obtained, so Afterwards by second azoles demodicid mite nitrile, solvent (can add to be not added with), emulsifying agent and various auxiliary agent high-speed stirrings The direct emulsifying of device is mixed in suspending agent, surplus deionized water is supplied, be obtained of the present invention Suspension emulsion product, be specifically shown in Table 4.
The each component of 4 embodiment of table 25～28 and weight portion
The aqueous emulsion of embodiment 29～32
Second azoles demodicid mite nitrile, active component B, solvent, emulsifying agent are added together, make to be dissolved into Even oil phase；By deionized water, antifreeze (can add to be not added with), thickening agent (can add to be not added with), Defoamer is mixed, into homogeneous water phase.Under high velocity agitation, water is added to into oil phase, Surplus deionized water is supplied；Aqueous emulsion product of the present invention is can be prepared by, is specifically shown in Table 5。
The each component of 5 embodiment of table 29～32 and weight portion
Pyridaben, azacyclotin, Bifenazate, avilamycin in table 1～5 are exchanged or replaced For propargite, Fenpropathrin, tebufenpyrad, fenpyroximate, acequinocyl, halfenprox, nitrile pyrrole demodicid mite ester , novel formulation can be obtained.
The microemulsion of embodiment 33～35
Second azoles demodicid mite nitrile, active component B are dissolved in the homogenizer equipped with solvent, by emulsifying Agent, antifreeze (can add to be not added with), defoamer are added in the homogenizer equipped with above-mentioned solution, Surplus deionized water mixes and homogenizes strongly after supplying, and finally obtains clear appearance transparent Microemulsion product of the present invention, be specifically shown in Table 6.
The each component of 6 embodiment of table 33～35 and content
Embodiment 36,37 microcapsule suspending agents
By second azoles demodicid mite nitrile, active component B, macromolecule cyst material, solvent, defoamer mixing, Make to be dissolved into homogeneous oil phase, in a shear condition, oil phase is added to containing emulsifying agent, pH In regulator, the aqueous phase solution of dispersant, surplus deionized water is supplied, and bi-material is in oil Water termination reacts, and forms high score ascus wall, makes well dispersed micro- of the present composition Capsule suspending agent product, is specifically shown in Table 7.
The embodiment 36 of table 7,37 each components and weight portion
Embodiment 38,39 microcapsule suspension-suspendinagent agents
By second azoles demodicid mite nitrile, macromolecule cyst material, solvent mixing, make to be dissolved into homogeneous oil phase, During oil phase is added in a shear condition containing emulsifying agent, the aqueous phase solution of pH adjusting agent, Make well dispersed microcapsule suspending agent.By dispersant, wetting agent, defoamer, thickening agent (can Plus can be not added with) through high speed shear mix homogeneously, add active component B, the ball in ball mill Mill 2～3 hours, makes diameter of particle all below 5 μm, and suspending agent is obtained, then will be outstanding Floating agent is added in the aqueous phase solution of micro-capsule suspension, and deionized water supplies surplus, makes this The well dispersed microcapsule suspension-suspendinagent agent product of inventive composition, is specifically shown in Table 8.
The embodiment 38 of table 8,39 each components and weight portion
The embodiment of the present invention is the method combined using Toxicity Determination and field test.First pass through Toxicity Determination, clear and definite two kinds of medicaments compound by a certain percentage after co-toxicity coefficient (CTC), CTC ＜ 80 are antagonism, and 80≤CTC≤120 are summation action, and CTC ＞ 120 are increasing Effect is acted on, and on this basis, then carries out field test.
Test method：Respectively the mother solution of each mixed agent is diluted to into five series concentrations during test, It is respectively placed in standby in beaker.Using the method that leaf is followed by worm is first soaked, will be not in contact with any medicament Blade of the same size soak in the medicinal liquid for having configured after 5s take out, dry naturally, put In entering insect box, then connect for examination larva, raise under the conditions of 25 DEG C, often process 3 times Repeat, often repeat test worm number used for 50, while setting blank, check dead in 72h Borer population, calculates mortality rate and corrected mortality, tries to achieve virulence regression equation and calculates LC50Value. If control mortality rate is more than 10%, it is considered as invalid test.Computing formula is as follows：
Insect corrected mortality is converted into into probit value (y), concentration for the treatment of (μ g/ml) is converted into Logarithm value (x), with method of least square virulence regression equation is drawn, and thus calculates every kind of medicine The value of agent, according to the abundant equations of Sun Yun co-toxicity coefficient CTC is calculated.Computing formula it is following (with Second azoles demodicid mite nitrile is standard agent, and its toxicity index is for 100)：
TI × the P of the theoretical toxicity index (TTI) of M=second azoles demodicid mite nitrileSecond azoles demodicid mite nitrile+Effective active into Divide the TI × P of BEffective active composition B
In formula：M is the mixture of different ratio
PEffective active composition BFor effective active composition B ratio shared in the composition
PSecond azoles demodicid mite nitrileFor second azoles demodicid mite nitrile ratio shared in the composition
B is selected from pyridaben, azacyclotin, Bifenazate, avilamycin, propargite, first cyanogen chrysanthemum One of ester, tebufenpyrad, fenpyroximate, acequinocyl, halfenprox, nitrile pyrrole demodicid mite ester are planted.
Application Example two：
For trying insect：Cotton red spider
Test medicine is provided by Shaanxi Welch Crop Protection Co., Ltd..
EXPERIMENTAL DESIGN：Determine second azoles demodicid mite nitrile and pyridaben active compound through pilot study and the two is different Effective lethasl concentration scope of proportioning mixture.
Toxicity test result
The second azoles demodicid mite nitrile of table 9 compounds the toxicity test analysis of results table to cotton red spider with pyridaben
Reagent agent Proportioning LC50(ug/mL) Co-toxicity coefficient (CTC)
Second azoles demodicid mite nitrile — 1.85 —
Pyridaben — 1.43 —
Second azoles Man Jing ︰ pyridabens 80:1 1.01 182.51
Second azoles Man Jing ︰ pyridabens 60:1 0.95 193.80
Second azoles Man Jing ︰ pyridabens 40:1 0.89 206.39
Second azoles Man Jing ︰ pyridabens 20:1 0.81 225.24
Second azoles Man Jing ︰ pyridabens 10:1 0.75 239.63
Second azoles Man Jing ︰ pyridabens 4:1 0.71 246.11
Second azoles Man Jing ︰ pyridabens 1:1 0.63 256.05
Second azoles Man Jing ︰ pyridabens 1:4 0.61 245.58
Second azoles Man Jing ︰ pyridabens 1:9 0.63 232.26
Second azoles Man Jing ︰ pyridabens 1:20 0.64 225.88
Second azoles Man Jing ︰ pyridabens 1:40 0.71 202.53
Second azoles Man Jing ︰ pyridabens 1:60 0.75 191.38
Second azoles Man Jing ︰ pyridabens 1:80 0.78 183.85
As shown in Table 9, second azoles demodicid mite nitrile and pyridaben to cotton red spider proportioning in 1 ︰ 80～80 During ︰ 1, co-toxicity coefficient is all higher than 120, illustrates both mixtures in the range of the ︰ 1 of 1 ︰ 80～80 Potentiation is shown, when the proportioning of second azoles demodicid mite nitrile and pyridaben is 1：20～20：When 1, Potentiation becomes apparent from projecting, and co-toxicity coefficient is all higher than 225.Jing applicant's test finds second The optimum ratio of azoles demodicid mite nitrile and pyridaben be 20 ︰ 1,19 ︰ 1,18 ︰ 1,17 ︰ 1,16 ︰ 1, 15 ︰ 1,14 ︰ 1,13 ︰ 1,12 ︰ 1,11 ︰ 1,10 ︰ 1,9 ︰ 1,8 ︰ 1,7 ︰ 1, 6 ︰ 1,5 ︰ 1,4 ︰ 1,3 ︰ 1,2 ︰ 1,1 ︰ 1,1 ︰ 2,1 ︰ 3,1 ︰ 4,1 ︰ 5, 1 ︰ 6,1 ︰ 7,1 ︰ 8,1 ︰ 9,1 ︰ 10,1 ︰ 11,1 ︰ 12,1 ︰ 13,1 ︰ 14,1 ︰ 15,1 ︰ 16,1 ︰ 17,1 ︰ 18,1 ︰ 19,1 ︰ 20, wherein when second azoles demodicid mite nitrile with rattle away Demodicid mite spirit weight ratio is 1：Co-toxicity coefficient is maximum when 1, and potentiation is the most obvious.
Application Example three：
For trying insect：Citrus red mite
Test medicine is provided by Shaanxi Welch Crop Protection Co., Ltd..
EXPERIMENTAL DESIGN：Determine second azoles demodicid mite nitrile and azacyclotin active compound through pilot study and the two is different Effective lethasl concentration scope of proportioning mixture.
Toxicity test result
The second azoles demodicid mite nitrile of table 10 compounds the toxicity test analysis of results table to citrus red mite with azacyclotin
Reagent agent Proportioning LC50(ug/mL) Co-toxicity coefficient (CTC)
Second azoles demodicid mite nitrile — 1.89 —
Azacyclotin — 2.81 —
Second azoles Man Jing ︰ azacyclotins 80:1 0.98 193.64
Second azoles Man Jing ︰ azacyclotins 60:1 0.95 200.02
Second azoles Man Jing ︰ azacyclotins 40:1 0.89 214.07
Second azoles Man Jing ︰ azacyclotins 20:1 0.81 237.03
Second azoles Man Jing ︰ azacyclotins 10:1 0.79 247.34
Second azoles Man Jing ︰ azacyclotins 4:1 0.80 252.80
Second azoles Man Jing ︰ azacyclotins 1:1 0.85 265.88
Second azoles Man Jing ︰ azacyclotins 1:2 0.89 271.65
Second azoles Man Jing ︰ azacyclotins 1:4 0.99 258.66
Second azoles Man Jing ︰ azacyclotins 1:9 1.08 248.11
Second azoles Man Jing ︰ azacyclotins 1:20 1.18 232.74
Second azoles Man Jing ︰ azacyclotins 1:40 1.28 216.95
Second azoles Man Jing ︰ azacyclotins 1:60 1.38 202.01
Second azoles Man Jing ︰ azacyclotins 1:80 1.45 192.63
As shown in Table 10, second azoles demodicid mite nitrile and azacyclotin to citrus red mite proportioning in 1 ︰ 80～80 During ︰ 1, co-toxicity coefficient is all higher than 120, illustrates both mixtures in the range of the ︰ 1 of 1 ︰ 80～80 Potentiation is shown, when the proportioning of second azoles demodicid mite nitrile and azacyclotin is 1：20～20：When 1, Potentiation becomes apparent from projecting, and co-toxicity coefficient is all higher than 230.Jing applicant's test finds second The optimum ratio of azoles demodicid mite nitrile and azacyclotin be 20 ︰ 1,19 ︰ 1,18 ︰ 1,17 ︰ 1,16 ︰ 1, 15 ︰ 1,14 ︰ 1,13 ︰ 1,12 ︰ 1,11 ︰ 1,10 ︰ 1,9 ︰ 1,8 ︰ 1,7 ︰ 1, 6 ︰ 1,5 ︰ 1,4 ︰ 1,3 ︰ 1,2 ︰ 1,1 ︰ 1,1 ︰ 2,1 ︰ 3,1 ︰ 4,1 ︰ 5, 1 ︰ 6,1 ︰ 7,1 ︰ 8,1 ︰ 9,1 ︰ 10,1 ︰ 11,1 ︰ 12,1 ︰ 13,1 ︰ 14,1 ︰ 15,1 ︰ 16,1 ︰ 17,1 ︰ 18,1 ︰ 19,1 ︰ 20, wherein when second azoles demodicid mite nitrile and three Azoles stannum weight ratio is 1：Co-toxicity coefficient is maximum when 2, and potentiation is the most obvious.
Application Example four：
For trying insect：European red mite
Test medicine is provided by Shaanxi Welch Crop Protection Co., Ltd..
EXPERIMENTAL DESIGN：Through pilot study determine second azoles demodicid mite nitrile and Bifenazate active compound and the two not With effective lethasl concentration scope of proportioning mixture.
Toxicity test result
The second azoles demodicid mite nitrile of table 11 compounds the toxicity test analysis of results table to European red mite with Bifenazate
Reagent agent Proportioning LC50(ug/mL) Co-toxicity coefficient (CTC)
Second azoles demodicid mite nitrile — 1.75 —
Bifenazate — 3.75 —
Second azoles Man Jing ︰ Bifenazates 80:1 0.95 185.43
Second azoles Man Jing ︰ Bifenazates 60:1 0.91 194.00
Second azoles Man Jing ︰ Bifenazates 40:1 0.85 208.60
Second azoles Man Jing ︰ Bifenazates 30:1 0.83 214.53
Second azoles Man Jing ︰ Bifenazates 15:1 0.76 238.20
Second azoles Man Jing ︰ Bifenazates 4:1 0.80 244.87
Second azoles Man Jing ︰ Bifenazates 1:1 0.95 251.19
Second azoles Man Jing ︰ Bifenazates 1:3 1.08 270.05
Second azoles Man Jing ︰ Bifenazates 1:4 1.15 265.41
Second azoles Man Jing ︰ Bifenazates 1:9 1.31 256.88
Second azoles Man Jing ︰ Bifenazates 1:14 1.42 245.37
Second azoles Man Jing ︰ Bifenazates 1:25 1.51 237.87
Second azoles Man Jing ︰ Bifenazates 1:40 1.67 218.45
Second azoles Man Jing ︰ Bifenazates 1:60 1.78 206.79
Second azoles Man Jing ︰ Bifenazates 1:80 1.87 197.73
As shown in Table 11, second azoles demodicid mite nitrile and Bifenazate to European red mite proportioning in 1 ︰ During 80～80 ︰ 1, co-toxicity coefficient is all higher than 120, illustrates both in the range of the ︰ 1 of 1 ︰ 80～80 Mixture shows potentiation, when the proportioning of second azoles demodicid mite nitrile and Bifenazate is 1：25～15： When 1, potentiation becomes apparent from projecting, and co-toxicity coefficient is all higher than 235.Jing applicant tests It was found that second azoles demodicid mite nitrile is 15 ︰ 1,14 ︰ 1,13 ︰ 1,12 ︰ with the optimum ratio of Bifenazate 1st, 11 ︰ 1,10 ︰ 1,9 ︰ 1,8 ︰ 1,7 ︰ 1,6 ︰ 1,5 ︰ 1,4 ︰ 1,3 ︰ 1,2 ︰ 1,1 ︰ 1,1 ︰ 2,1 ︰ 3,1 ︰ 4,1 ︰ 5,1 ︰ 6,1 ︰ 7,1 ︰ 8,1 ︰ 9,1 ︰ 10,1 ︰ 11,1 ︰ 12,1 ︰ 13,1 ︰ 14,1 ︰ 15,1 ︰ 16,1 ︰ 17,1 ︰ 18, 1 ︰ 19,1 ︰ 20,1 ︰ 21,1 ︰ 22,1 ︰ 23,1 ︰ 24,1 ︰ 25, wherein when second azoles Demodicid mite nitrile is 1 with Bifenazate weight ratio：Co-toxicity coefficient is maximum when 3, and potentiation is the most obvious.
Application Example five：
For trying insect：Brassicaceous vegetable diamondback moth
Test medicine is provided by Shaanxi Welch Crop Protection Co., Ltd..
EXPERIMENTAL DESIGN：Through pilot study determine second azoles demodicid mite nitrile and the former medicine of AVM and the two not With effective lethasl concentration scope of proportioning mixture.
Toxicity test result
The second azoles demodicid mite nitrile of table 12 and the abamectin compounded toxicity test analysis of results table to brassicaceous vegetable diamondback moth
Reagent agent Proportioning LC50(ug/mL) Co-toxicity coefficient (CTC)
Second azoles demodicid mite nitrile — 1.91 —
Avilamycin — 0.45 —
Second azoles Man Jing ︰ avilamycin 80:1 0.98 187.39
Second azoles Man Jing ︰ avilamycin 60:1 0.91 199.29
Second azoles Man Jing ︰ avilamycin 40:1 0.85 208.23
Second azoles Man Jing ︰ avilamycin 25:1 0.74 229.48
Second azoles Man Jing ︰ avilamycin 14:1 0.66 237.94
Second azoles Man Jing ︰ avilamycin 9:1 0.58 248.65
Second azoles Man Jing ︰ avilamycin 4:1 0.45 257.43
Second azoles Man Jing ︰ avilamycin 3:1 0.40 263.67
Second azoles Man Jing ︰ avilamycin 1:1 0.30 242.82
Second azoles Man Jing ︰ avilamycin 1:4 0.23 230.98
Second azoles Man Jing ︰ avilamycin 1:15 0.21 225.06
Second azoles Man Jing ︰ avilamycin 1:30 0.22 209.74
Second azoles Man Jing ︰ avilamycin 1:40 0.23 199.39
Second azoles Man Jing ︰ avilamycin 1:60 0.24 189.90
Second azoles Man Jing ︰ avilamycin 1:80 0.25 181.73
As shown in Table 12, second azoles demodicid mite nitrile and avilamycin are to brassicaceous vegetable diamondback moth proportioning In 1 80～80 ︰ 1 of ︰, co-toxicity coefficient is all higher than 120, illustrates both in the ︰ 1 of 1 ︰ 80～80 In the range of mixture show potentiation, when the proportioning of second azoles demodicid mite nitrile and avilamycin is 1： 15～25：When 1, potentiation becomes apparent from projecting, and co-toxicity coefficient is all higher than 225.Jing applies People's test find the optimum ratio of second azoles demodicid mite nitrile and avilamycin be 25 ︰ 1,24 ︰ 1,23 ︰ 1, 22 ︰ 1,21 ︰ 1,20 ︰ 1,19 ︰ 1,18 ︰ 1,17 ︰ 1,16 ︰ 1,15 ︰ 1,14 ︰ 1,13 ︰ 1,12 ︰ 1,11 ︰ 1,10 ︰ 1,9 ︰ 1,8 ︰ 1,7 ︰ 1,6 ︰ 1,5 ︰ 1,4 ︰ 1,3 ︰ 1,2 ︰ 1,1 ︰ 1,1 ︰ 2,1 ︰ 3,1 ︰ 4,1 ︰ 5,1 ︰ 6,1 ︰ 7,1 ︰ 8,1 ︰ 9,1 ︰ 10,1 ︰ 11,1 ︰ 12,1 ︰ 13,1 ︰ 14,1 ︰ 15, Wherein when second azoles demodicid mite nitrile and avilamycin weight ratio are 3：Co-toxicity coefficient is maximum when 1, and potentiation is made With the most obvious.
Application Example six：
For trying insect：Citrus red mite
Test medicine is provided by Shaanxi Welch Crop Protection Co., Ltd..
EXPERIMENTAL DESIGN：Determine second azoles demodicid mite nitrile and propargite active compound through pilot study and the two is different Effective lethasl concentration scope of proportioning mixture.
Toxicity test result
The second azoles demodicid mite nitrile of table 13 compounds the toxicity test analysis of results table to citrus red mite with propargite
Reagent agent Proportioning LC50(ug/mL) Co-toxicity coefficient (CTC)
Second azoles demodicid mite nitrile — 1.95 —
Propargite — 7.5 —
Second azoles Man Jing ︰ propargites 80:1 1.05 187.43
Second azoles Man Jing ︰ propargites 60:1 1.02 193.52
Second azoles Man Jing ︰ propargites 40:1 0.98 202.64
Second azoles Man Jing ︰ propargites 30:1 0.92 217.14
Second azoles Man Jing ︰ propargites 15:1 0.91 224.68
Second azoles Man Jing ︰ propargites 4:1 0.96 238.41
Second azoles Man Jing ︰ propargites 1:1 1.25 247.62
Second azoles Man Jing ︰ propargites 1:4 1.86 256.96
Second azoles Man Jing ︰ propargites 1:6 2.04 261.37
Second azoles Man Jing ︰ propargites 1:9 2.38 245.31
Second azoles Man Jing ︰ propargites 1:14 2.64 238.78
Second azoles Man Jing ︰ propargites 1:25 2.97 227.61
Second azoles Man Jing ︰ propargites 1:40 3.33 210.61
Second azoles Man Jing ︰ propargites 1:60 3.45 207.70
Second azoles Man Jing ︰ propargites 1:80 3.78 191.68
As shown in Table 13, second azoles demodicid mite nitrile and propargite to citrus red mite proportioning in 1 ︰ 80～80 During ︰ 1, co-toxicity coefficient is all higher than 120, illustrates both mixtures in the range of the ︰ 1 of 1 ︰ 80～80 Potentiation is shown, when the proportioning of second azoles demodicid mite nitrile and propargite is 15：1～1：When 25, Potentiation becomes apparent from projecting, and co-toxicity coefficient is all higher than 225.Jing applicant's test finds second The optimum ratio of azoles demodicid mite nitrile and propargite be 15 ︰ 1,14 ︰ 1,13 ︰ 1,12 ︰ 1,11 ︰ 1, 10 ︰ 1,9 ︰ 1,8 ︰ 1,7 ︰ 1,6 ︰ 1,5 ︰ 1,4 ︰ 1,3 ︰ 1,2 ︰ 1,1 ︰ 1, 1 ︰ 2,1 ︰ 3,1 ︰ 4,1 ︰ 5,1 ︰ 6,1 ︰ 7,1 ︰ 8,1 ︰ 9,1 ︰ 10,1 ︰ 11, 1 ︰ 12,1 ︰ 13,1 ︰ 14,1 ︰ 15,1 ︰ 16,1 ︰ 17,1 ︰ 18,1 ︰ 19,1 ︰ 20th, 1 ︰ 21,1 ︰ 22,1 ︰ 23,1 ︰ 24,1 ︰ 25, wherein when second azoles demodicid mite nitrile and alkynes demodicid mite Extra heavy amount ratio is 1：Co-toxicity coefficient is maximum when 6, and potentiation is the most obvious.
Application Example seven：
For trying insect：Citrus red mite
Test medicine is provided by Shaanxi Welch Crop Protection Co., Ltd..
EXPERIMENTAL DESIGN：Through pilot study determine second azoles demodicid mite nitrile and Fenpropathrin active compound and the two not With effective lethasl concentration scope of proportioning mixture.
Toxicity test result
The second azoles demodicid mite nitrile of table 14 compounds the toxicity test analysis of results table to citrus red mite with Fenpropathrin
Reagent agent Proportioning LC50(ug/mL) Co-toxicity coefficient (CTC)
Second azoles demodicid mite nitrile — 1.64 —
Fenpropathrin — 2.5 —
Second azoles Man Jing ︰ Fenpropathrins 80:1 0.87 189.31
Second azoles Man Jing ︰ Fenpropathrins 60:1 0.85 194.04
Second azoles Man Jing ︰ Fenpropathrins 40:1 0.81 204.18
Second azoles Man Jing ︰ Fenpropathrins 20:1 0.75 222.31
Second azoles Man Jing ︰ Fenpropathrins 9:1 0.73 232.66
Second azoles Man Jing ︰ Fenpropathrins 4:1 0.72 244.61
Second azoles Man Jing ︰ Fenpropathrins 1:1 0.78 253.93
Second azoles Man Jing ︰ Fenpropathrins 1:2 0.81 262.72
Second azoles Man Jing ︰ Fenpropathrins 1:4 0.91 248.65
Second azoles Man Jing ︰ Fenpropathrins 1:9 1.02 232.89
Second azoles Man Jing ︰ Fenpropathrins 1:20 1.08 225.84
Second azoles Man Jing ︰ Fenpropathrins 1:40 1.18 209.19
Second azoles Man Jing ︰ Fenpropathrins 1:60 1.28 193.65
Second azoles Man Jing ︰ Fenpropathrins 1:80 1.35 183.99
As shown in Table 14, second azoles demodicid mite nitrile and Fenpropathrin to citrus red mite proportioning in 1 ︰ During 80～80 ︰ 1, co-toxicity coefficient is all higher than 120, illustrates both in the range of the ︰ 1 of 1 ︰ 80～80 Mixture shows potentiation, when the proportioning of second azoles demodicid mite nitrile and Fenpropathrin is 20：1～1： When 20, potentiation becomes apparent from projecting, and co-toxicity coefficient is all higher than 220.Jing applicant tests It was found that second azoles demodicid mite nitrile is 20 ︰ 1,19 ︰ 1,18 ︰ 1,17 ︰ with the optimum ratio of Fenpropathrin 1st, 16 ︰ 1,15 ︰ 1,14 ︰ 1,13 ︰ 1,12 ︰ 1,11 ︰ 1,10 ︰ 1,9 ︰ 1,8 ︰ 1,7 ︰ 1,6 ︰ 1,5 ︰ 1,4 ︰ 1,3 ︰ 1,2 ︰ 1,1 ︰ 1,1 ︰ 2,1 ︰ 3,1 ︰ 4,1 ︰ 5,1 ︰ 6,1 ︰ 7,1 ︰ 8,1 ︰ 9,1 ︰ 10,1 ︰ 11,1 ︰ 12,1 ︰ 13rd, 1 ︰ 14,1 ︰ 15,1 ︰ 16,1 ︰ 17,1 ︰ 18,1 ︰ 19,1 ︰ 20, wherein when Second azoles demodicid mite nitrile is 1 with Fenpropathrin weight ratio：Co-toxicity coefficient is maximum when 2, and potentiation is the most Substantially.
Application Example eight：
For trying insect：Citrus red mite
Test medicine is provided by Shaanxi Welch Crop Protection Co., Ltd..
EXPERIMENTAL DESIGN：Determine second azoles demodicid mite nitrile and tebufenpyrad active compound through pilot study and the two is different Effective lethasl concentration scope of proportioning mixture.
Toxicity test result
The second azoles demodicid mite nitrile of table 15 compounds the toxicity test analysis of results table to citrus red mite with tebufenpyrad
Reagent agent Proportioning LC50(ug/mL) Co-toxicity coefficient (CTC)
Second azoles demodicid mite nitrile — 1.75 —
Tebufenpyrad — 7.5 —
Second azoles Man Jing ︰ tebufenpyrads 80:1 0.95 185.97
Second azoles Man Jing ︰ tebufenpyrads 60:1 0.91 194.76
Second azoles Man Jing ︰ tebufenpyrads 40:1 0.89 200.38
Second azoles Man Jing ︰ tebufenpyrads 30:1 0.82 218.83
Second azoles Man Jing ︰ tebufenpyrads 15:1 0.78 235.65
Second azoles Man Jing ︰ tebufenpyrads 4:1 0.85 243.17
Second azoles Man Jing ︰ tebufenpyrads 1:1 1.12 253.39
Second azoles Man Jing ︰ tebufenpyrads 1:4 1.68 269.42
Second azoles Man Jing ︰ tebufenpyrads 1:6 1.87 272.97
Second azoles Man Jing ︰ tebufenpyrads 1:9 2.21 255.46
Second azoles Man Jing ︰ tebufenpyrads 1:14 2.51 245.14
Second azoles Man Jing ︰ tebufenpyrads 1:25 2.87 232.03
Second azoles Man Jing ︰ tebufenpyrads 1:40 3.28 211.72
Second azoles Man Jing ︰ tebufenpyrads 1:60 3.54 201.06
Second azoles Man Jing ︰ tebufenpyrads 1:80 3.78 190.70
As shown in Table 15, second azoles demodicid mite nitrile and tebufenpyrad to citrus red mite proportioning in 1 ︰ 80～80 During ︰ 1, co-toxicity coefficient is all higher than 120, illustrates both mixtures in the range of the ︰ 1 of 1 ︰ 80～80 Potentiation is shown, when the proportioning of second azoles demodicid mite nitrile and tebufenpyrad is 15：1～1：When 25, Potentiation becomes apparent from projecting, and co-toxicity coefficient is all higher than 230.Jing applicant's test finds second The optimum ratio of azoles demodicid mite nitrile and tebufenpyrad be 15 ︰ 1,14 ︰ 1,13 ︰ 1,12 ︰ 1,11 ︰ 1, 10 ︰ 1,9 ︰ 1,8 ︰ 1,7 ︰ 1,6 ︰ 1,5 ︰ 1,4 ︰ 1,3 ︰ 1,2 ︰ 1,1 ︰ 1, 1 ︰ 2,1 ︰ 3,1 ︰ 4,1 ︰ 5,1 ︰ 6,1 ︰ 7,1 ︰ 8,1 ︰ 9,1 ︰ 10,1 ︰ 11, 1 ︰ 12,1 ︰ 13,1 ︰ 14,1 ︰ 15,1 ︰ 16,1 ︰ 17,1 ︰ 18,1 ︰ 19,1 ︰ 20th, 1 ︰ 21,1 ︰ 22,1 ︰ 23,1 ︰ 24,1 ︰ 25, wherein when second azoles demodicid mite nitrile and pyrrole demodicid mite Amine weight ratio is 1：Co-toxicity coefficient is maximum when 6, and potentiation is the most obvious.
Application Example nine：
For trying insect：Citrus red mite
Test medicine is provided by Shaanxi Welch Crop Protection Co., Ltd..
EXPERIMENTAL DESIGN：Determine second azoles demodicid mite nitrile and fenpyroximate active compound through pilot study and the two is different Effective lethasl concentration scope of proportioning mixture.
Toxicity test result
The second azoles demodicid mite nitrile of table 16 compounds the toxicity test analysis of results table to citrus red mite with fenpyroximate
Reagent agent Proportioning LC50(ug/mL) Co-toxicity coefficient (CTC)
Second azoles demodicid mite nitrile — 1.84 —
Fenpyroximate — 0.65 —
Second azoles Man Jing ︰ fenpyroximates 80:1 0.95 189.40
Second azoles Man Jing ︰ fenpyroximates 60:1 0.91 196.31
Second azoles Man Jing ︰ fenpyroximates 40:1 0.88 200.15
Second azoles Man Jing ︰ fenpyroximates 20:1 0.75 225.66
Second azoles Man Jing ︰ fenpyroximates 9:1 0.65 239.27
Second azoles Man Jing ︰ fenpyroximates 4:1 0.55 244.88
Second azoles Man Jing ︰ fenpyroximates 2:1 0.45 253.93
Second azoles Man Jing ︰ fenpyroximates 1:1 0.38 252.80
Second azoles Man Jing ︰ fenpyroximates 1:4 0.30 248.85
Second azoles Man Jing ︰ fenpyroximates 1:9 0.30 231.65
Second azoles Man Jing ︰ fenpyroximates 1:20 0.30 223.55
Second azoles Man Jing ︰ fenpyroximates 1:40 0.31 213.04
Second azoles Man Jing ︰ fenpyroximates 1:60 0.32 205.30
Second azoles Man Jing ︰ fenpyroximates 1:80 0.33 198.55
As shown in Table 16, second azoles demodicid mite nitrile and fenpyroximate to citrus red mite proportioning in 1 ︰ 80～80 During ︰ 1, co-toxicity coefficient is all higher than 120, illustrates both mixtures in the range of the ︰ 1 of 1 ︰ 80～80 Potentiation is shown, when the proportioning of second azoles demodicid mite nitrile and fenpyroximate is 20：1～1：When 20, Potentiation becomes apparent from projecting, and co-toxicity coefficient is all higher than 220.Jing applicant's test finds second The optimum ratio of azoles demodicid mite nitrile and fenpyroximate be 20 ︰ 1,19 ︰ 1,18 ︰ 1,17 ︰ 1,16 ︰ 1, 15 ︰ 1,14 ︰ 1,13 ︰ 1,12 ︰ 1,11 ︰ 1,10 ︰ 1,9 ︰ 1,8 ︰ 1,7 ︰ 1, 6 ︰ 1,5 ︰ 1,4 ︰ 1,3 ︰ 1,2 ︰ 1,1 ︰ 1,1 ︰ 2,1 ︰ 3,1 ︰ 4,1 ︰ 5, 1 ︰ 6,1 ︰ 7,1 ︰ 8,1 ︰ 9,1 ︰ 10,1 ︰ 11,1 ︰ 12,1 ︰ 13,1 ︰ 14,1 ︰ 15,1 ︰ 16,1 ︰ 17,1 ︰ 18,1 ︰ 19,1 ︰ 20, wherein when second azoles demodicid mite nitrile and azoles Demodicid mite ester weight ratio is 2：Co-toxicity coefficient is maximum when 1, and potentiation is the most obvious.
Application Example ten：
For trying insect：European red mite
Test medicine is provided by Shaanxi Welch Crop Protection Co., Ltd..
EXPERIMENTAL DESIGN：Determine second azoles demodicid mite nitrile and acequinocyl active compound through pilot study and the two is different Effective lethasl concentration scope of proportioning mixture.
Toxicity test result
The second azoles demodicid mite nitrile of table 17 compounds the toxicity test analysis of results table to European red mite with acequinocyl
Reagent agent Proportioning LC50(ug/mL) Co-toxicity coefficient (CTC)
Second azoles demodicid mite nitrile — 1.79 —
Acequinocyl — 1.88 —
Second azoles Man Jing ︰ acequinocyls 80:1 0.95 188.53
Second azoles Man Jing ︰ acequinocyls 60:1 0.91 196.86
Second azoles Man Jing ︰ acequinocyls 40:1 0.88 203.65
Second azoles Man Jing ︰ acequinocyls 20:1 0.79 227.10
Second azoles Man Jing ︰ acequinocyls 9:1 0.75 239.82
Second azoles Man Jing ︰ acequinocyls 4:1 0.74 244.23
Second azoles Man Jing ︰ acequinocyls 1:1 0.73 251.22
Second azoles Man Jing ︰ acequinocyls 2:3 0.71 259.57
Second azoles Man Jing ︰ acequinocyls 1:4 0.75 248.18
Second azoles Man Jing ︰ acequinocyls 1:9 0.78 239.83
Second azoles Man Jing ︰ acequinocyls 1:20 0.82 228.73
Second azoles Man Jing ︰ acequinocyls 1:40 0.89 210.98
Second azoles Man Jing ︰ acequinocyls 1:60 0.91 206.43
Second azoles Man Jing ︰ acequinocyls 1:80 0.95 197.78
As shown in Table 17, second azoles demodicid mite nitrile and acequinocyl to European red mite proportioning in 1 ︰ 80～80 During ︰ 1, co-toxicity coefficient is all higher than 120, illustrates both mixtures in the range of the ︰ 1 of 1 ︰ 80～80 Potentiation is shown, when the proportioning of second azoles demodicid mite nitrile and acequinocyl is 20：1～1：When 20, Potentiation becomes apparent from projecting, and co-toxicity coefficient is all higher than 225.Jing applicant's test finds second The optimum ratio of azoles demodicid mite nitrile and acequinocyl be 20 ︰ 1,19 ︰ 1,18 ︰ 1,17 ︰ 1,16 ︰ 1, 15 ︰ 1,14 ︰ 1,13 ︰ 1,12 ︰ 1,11 ︰ 1,10 ︰ 1,9 ︰ 1,8 ︰ 1,7 ︰ 1, 6 ︰ 1,5 ︰ 1,4 ︰ 1,3 ︰ 1,2 ︰ 1,1 ︰ 1,1 ︰ 2,1 ︰ 3,1 ︰ 4,1 ︰ 5, 1 ︰ 6,1 ︰ 7,1 ︰ 8,1 ︰ 9,1 ︰ 10,1 ︰ 11,1 ︰ 12,1 ︰ 13,1 ︰ 14,1 ︰ 15,1 ︰ 16,1 ︰ 17,1 ︰ 18,1 ︰ 19,1 ︰ 20, wherein when second azoles demodicid mite nitrile with go out Demodicid mite quinone weight ratio is 2：Co-toxicity coefficient is maximum when 3, and potentiation is the most obvious.
Application Example 11：
For trying insect：European red mite
Test medicine is provided by Shaanxi Welch Crop Protection Co., Ltd..
EXPERIMENTAL DESIGN：Determine second azoles demodicid mite nitrile and halfenprox active compound through pilot study and the two is different Effective lethasl concentration scope of proportioning mixture.
Toxicity test result
The second azoles demodicid mite nitrile of table 18 compounds the toxicity test analysis of results table to European red mite with halfenprox
Reagent agent Proportioning LC50(ug/mL) Co-toxicity coefficient (CTC)
Second azoles demodicid mite nitrile — 1.93 —
Halfenprox — 0.75 —
Second azoles Man Jing ︰ halfenprox 80:1 0.95 199.29
Second azoles Man Jing ︰ halfenprox 60:1 0.91 206.76
Second azoles Man Jing ︰ halfenprox 40:1 0.88 211.21
Second azoles Man Jing ︰ halfenprox 20:1 0.75 239.40
Second azoles Man Jing ︰ halfenprox 9:1 0.68 245.24
Second azoles Man Jing ︰ halfenprox 4:1 0.58 253.11
Second azoles Man Jing ︰ halfenprox 2:1 0.48 263.76
Second azoles Man Jing ︰ halfenprox 1:1 0.41 263.47
Second azoles Man Jing ︰ halfenprox 1:4 0.33 258.94
Second azoles Man Jing ︰ halfenprox 1:9 0.33 242.08
Second azoles Man Jing ︰ halfenprox 1:20 0.33 234.09
Second azoles Man Jing ︰ halfenprox 1:40 0.35 217.53
Second azoles Man Jing ︰ halfenprox 1:60 0.37 204.76
Second azoles Man Jing ︰ halfenprox 1:80 0.38 198.87
As shown in Table 18, second azoles demodicid mite nitrile and halfenprox to European red mite proportioning in 1 ︰ 80～80 During ︰ 1, co-toxicity coefficient is all higher than 120, illustrates both mixtures in the range of the ︰ 1 of 1 ︰ 80～80 Potentiation is shown, when the proportioning of second azoles demodicid mite nitrile and halfenprox is 20：1～1：When 20, Potentiation becomes apparent from projecting, and co-toxicity coefficient is all higher than 230.Jing applicant's test finds second The optimum ratio of azoles demodicid mite nitrile and halfenprox be 20 ︰ 1,19 ︰ 1,18 ︰ 1,17 ︰ 1,16 ︰ 1, 15 ︰ 1,14 ︰ 1,13 ︰ 1,12 ︰ 1,11 ︰ 1,10 ︰ 1,9 ︰ 1,8 ︰ 1,7 ︰ 1, 6 ︰ 1,5 ︰ 1,4 ︰ 1,3 ︰ 1,2 ︰ 1,1 ︰ 1,1 ︰ 2,1 ︰ 3,1 ︰ 4,1 ︰ 5, 1 ︰ 6,1 ︰ 7,1 ︰ 8,1 ︰ 9,1 ︰ 10,1 ︰ 11,1 ︰ 12,1 ︰ 13,1 ︰ 14,1 ︰ 15,1 ︰ 16,1 ︰ 17,1 ︰ 18,1 ︰ 19,1 ︰ 20, wherein when second azoles demodicid mite nitrile and benzyl Demodicid mite ether weight ratio is 2：Co-toxicity coefficient is maximum when 1, and potentiation is the most obvious.
Application Example 12：
For trying insect：European red mite
Test medicine is provided by Shaanxi Welch Crop Protection Co., Ltd..
EXPERIMENTAL DESIGN：Through pilot study determine second azoles demodicid mite nitrile and nitrile pyrrole demodicid mite ester active compound and the two not With effective lethasl concentration scope of proportioning mixture.
Toxicity test result
The second azoles demodicid mite nitrile of table 19 compounds the toxicity test analysis of results table to European red mite with nitrile pyrrole demodicid mite ester
Reagent agent Proportioning LC50(ug/mL) Co-toxicity coefficient (CTC)
Second azoles demodicid mite nitrile — 1.88 —
Nitrile pyrrole demodicid mite ester — 1.43 —
Second azoles Man Jing ︰ nitrile pyrrole demodicid mite esters 80:1 0.95 197.13
Second azoles Man Jing ︰ nitrile pyrrole demodicid mite esters 60:1 0.91 205.53
Second azoles Man Jing ︰ nitrile pyrrole demodicid mite esters 40:1 0.88 212.01
Second azoles Man Jing ︰ nitrile pyrrole demodicid mite esters 20:1 0.78 237.47
Second azoles Man Jing ︰ nitrile pyrrole demodicid mite esters 9:1 0.75 243.02
Second azoles Man Jing ︰ nitrile pyrrole demodicid mite esters 4:1 0.69 256.33
Second azoles Man Jing ︰ nitrile pyrrole demodicid mite esters 1:1 0.61 266.30
Second azoles Man Jing ︰ nitrile pyrrole demodicid mite esters 1:4 0.58 258.95
Second azoles Man Jing ︰ nitrile pyrrole demodicid mite esters 1:9 0.59 248.31
Second azoles Man Jing ︰ nitrile pyrrole demodicid mite esters 1:20 0.61 237.13
Second azoles Man Jing ︰ nitrile pyrrole demodicid mite esters 1:40 0.68 211.53
Second azoles Man Jing ︰ nitrile pyrrole demodicid mite esters 1:60 0.71 202.20
Second azoles Man Jing ︰ nitrile pyrrole demodicid mite esters 1:80 0.75 191.23
As shown in Table 19, second azoles demodicid mite nitrile and nitrile pyrrole demodicid mite ester to European red mite proportioning in 1 ︰ During 80～80 ︰ 1, co-toxicity coefficient is all higher than 120, illustrates both in the range of the ︰ 1 of 1 ︰ 80～80 Mixture shows potentiation, when the proportioning of second azoles demodicid mite nitrile and nitrile pyrrole demodicid mite ester is 20：1～1： When 20, potentiation becomes apparent from projecting, and co-toxicity coefficient is all higher than 235.Jing applicant tests It was found that second azoles demodicid mite nitrile is 20 ︰ 1,19 ︰ 1,18 ︰ 1,17 ︰ with the optimum ratio of nitrile pyrrole demodicid mite ester 1st, 16 ︰ 1,15 ︰ 1,14 ︰ 1,13 ︰ 1,12 ︰ 1,11 ︰ 1,10 ︰ 1,9 ︰ 1,8 ︰ 1,7 ︰ 1,6 ︰ 1,5 ︰ 1,4 ︰ 1,3 ︰ 1,2 ︰ 1,1 ︰ 1,1 ︰ 2,1 ︰ 3,1 ︰ 4,1 ︰ 5,1 ︰ 6,1 ︰ 7,1 ︰ 8,1 ︰ 9,1 ︰ 10,1 ︰ 11,1 ︰ 12,1 ︰ 13rd, 1 ︰ 14,1 ︰ 15,1 ︰ 16,1 ︰ 17,1 ︰ 18,1 ︰ 19,1 ︰ 20, wherein when Second azoles demodicid mite nitrile is 1 with nitrile pyrrole demodicid mite ester weight ratio：Co-toxicity coefficient is maximum when 1, and potentiation is the most Substantially.
Jing tests find：To red in various crop after second azoles demodicid mite nitrile and active component B compounding Aranea, rust mite, tetranychid, planthopper, rice leaf roller, striped rice borer, yellow rice borer, Diamondback moth, Pieris rapae, bollworm, leaf miner, blister mite, Americal rice leaf miner, pear wood The preventing and treating of louse or small heart-eating peach worm has obvious potentiation, and co-toxicity coefficient is 120 More than.
Effect experiment part：Test medicine is researched and developed, carried by Shaanxi Welch Crop Protection Co., Ltd. For, second azoles demodicid mite nitrile suspending agent (autogamy) of comparison medicament 30%, 15% pyridaben cream (commercial), 25% azacyclotin wettable powder (commercial), 43% Bifenazate suspending agent (commercial), 1% Ah Dimension rhzomorph cream (commercial), 40% propargite cream (commercial), 20% Fenpropathrin wettability Powder (commercial), 30% tebufenpyrad suspending agent (autogamy), 5% Enpyfoximate dispersant (commercial), 10% acequinocyl suspending agent (autogamy), 20% halfenprox cream (autogamy), 30% nitrile pyrrole demodicid mite ester Suspending agent (autogamy).
The second azoles demodicid mite nitrile of Application Example 13 and active component B and its compounding preventing and treating cotton red spider The test of pesticide effectiveness
This test arrangement investigates cotton red spider insect pest in Shaanxi Province Weinan City Dali County, before medicine Index, in insect pest early period of origination dispenser, 3 days after dispenser, investigates insect pest and refers to for 10 days, 20 days Count and calculate preventive effect.Result of the test is as follows：
The second azoles demodicid mite nitrile of table 20 and active component B and its compounding preventing and treating cotton red spider test of pesticide effectiveness
As can be seen from Table 20, cotton can effectively be prevented and treated after second azoles demodicid mite nitrile and active component B compoundings Premium Aranea, can also Jing after inventor's test proves second azoles demodicid mite nitrile and active component B compoundings Cotton boll worm is effectively prevented and treated, prevention effect is above 96%, it is better than the preventive effect of single dose and anti- The effect phase is long.Target crop is had no adverse effects in test scope of medication.
The tetrem azoles demodicid mite nitrile of Application Example ten and active component B and its compounding preventing and treating rice-stem borer The test of pesticide effectiveness
This test arrangement is investigated rice-stem borer insect pest and is referred in Shaanxi Province Hanzhong suburban area, before medicine Number, in insect pest early period of origination dispenser, 3 days after dispenser, investigates insect pest index in 10 days, 20 days And calculate preventive effect.Result of the test is as follows：
The second azoles demodicid mite nitrile of table 21 and active component B and its compounding preventing and treating rice-stem borer test of pesticide effectiveness
As can be seen from Table 21, can effectively prevent harnessing the river after second azoles demodicid mite nitrile and active component B compoundings Chilo suppressalis, can also Jing after inventor's test proves second azoles demodicid mite nitrile and active component B compoundings Paddy rice rice leaf roller, yellow rice borer, planthopper are effectively prevented and treated, prevention effect is above 96%, Better than the preventive effect of single dose, and preventive effect phase is long.To target crop without bad in test scope of medication Affect.
The second azoles demodicid mite nitrile of Application Example 15 and active component B and its compounding preventing and treating Cruciferae vegetable The dish diamondback moth test of pesticide effectiveness
This test arrangement investigates brassicaceous vegetable pickles in Shaanxi Province Hanzhong suburban area, before medicine Moth insect pest index, in insect pest early period of origination dispenser, 3 days after dispenser, investigates for 10 days, 20 days Insect pest index simultaneously calculates preventive effect.Result of the test is as follows：
The second azoles demodicid mite nitrile of table 22 and active component B and its compounding preventing and treating brassicaceous vegetable diamondback moth test of pesticide effectiveness
As can be seen from Table 22, ten can effectively be prevented and treated after second azoles demodicid mite nitrile and active component B compoundings Zi Hua sections vegetable diamondback moth, Jing inventor's test proves that second azoles demodicid mite nitrile is compounded with active component B After can also effectively prevent and treat brassicaceous vegetable Pieris rapae, prevention effect is above 96%, is better than The preventive effect of single dose, and preventive effect phase is long.Target crop is had no adverse effects in test scope of medication.
The second azoles demodicid mite nitrile of Application Example 16 and active component B and its compounding preventing and treating citrus red mite The test of pesticide effectiveness
This test arrangement is investigated citrus red mite insect pest and is referred in Shaanxi Province Hanzhong suburban area, before medicine Number, in insect pest early period of origination dispenser, 3 days after dispenser, investigates insect pest index in 10 days, 20 days And calculate preventive effect.Result of the test is as follows：
The second azoles demodicid mite nitrile of table 23 and active component B and its compounding preventing and treating citrus red mite test of pesticide effectiveness
As can be seen from Table 23, Citrus chachiensis Hort. can effectively be prevented and treated after second azoles demodicid mite nitrile and active component B compoundings Exocarpium Citri Rubrum Aranea, can also Jing after inventor's test proves second azoles demodicid mite nitrile and active component B compoundings Citrus blister mite, leaf miner are effectively prevented and treated, prevention effect is above 96%, anti-better than single dose Effect, and preventive effect phase is long.Target crop is had no adverse effects in test scope of medication.
The second azoles demodicid mite nitrile of Application Example 17 and active component B and its compounding preventing and treating European red mite The test of pesticide effectiveness
This test arrangement investigates European red mite insect pest in Shaanxi Province Weinan City Dali County, before medicine Index, in insect pest early period of origination dispenser, 3 days after dispenser, investigates insect pest and refers to for 10 days, 20 days Count and calculate preventive effect.Result of the test is as follows：
The second azoles demodicid mite nitrile of table 24 and active component B and its compounding preventing and treating Pesticide Effect for Apple Red Spiders
As can be seen from Table 24, Herba Marsileae Quadrifoliae can effectively be prevented and treated after second azoles demodicid mite nitrile and active component B compoundings Arnotto Aranea, can also Jing after inventor's test proves second azoles demodicid mite nitrile and active component B compoundings Fructus Mali pumilae small heart-eating peach worm is effectively prevented and treated, prevention effect is above 96%, better than the preventive effect of single dose, And preventive effect phase is long.Target crop is had no adverse effects in test scope of medication.
Test through different places throughout the country afterwards draws, second azoles demodicid mite nitrile and pyridaben, three Azoles stannum, Bifenazate, avilamycin, propargite, Fenpropathrin, tebufenpyrad, fenpyroximate, Acequinocyl, halfenprox, nitrile pyrrole demodicid mite ester compounding after to the red spider in various crop, rust mite, Tetranychid, planthopper, rice leaf roller, striped rice borer, yellow rice borer, diamondback moth, Pieris rapae, Bollworm, leaf miner, blister mite, Americal rice leaf miner, pear sucker or small heart-eating peach worm etc. More than 96%, better than single dose preventive effect, potentiation is obvious for the preventive effect of common insect pests.

Claims (6)

1. a kind of Pesticidal combination of the demodicid mite of azoles containing second nitrile, effective active composition is active components A With active component B, it is characterised in that：Active components A is 1 with the weight ratio of active component B The ︰ 1 of ︰ 80～80, described active components A is second azoles demodicid mite nitrile, and active component B is selected from demodicid mite of rattling away Spirit, azacyclotin, Bifenazate, avilamycin, propargite, Fenpropathrin, tebufenpyrad, azoles One of demodicid mite ester, acequinocyl, halfenprox, nitrile pyrrole demodicid mite ester are planted.
2. the Pesticidal combination of the demodicid mite of azoles containing second nitrile according to claim 1, its feature exists In：Active components A is the ︰ 1 of 1 ︰ 40～40 with the weight ratio of active component B.
3. the Pesticidal combination of the demodicid mite of azoles containing second nitrile according to claim 2, its feature exists In：
The weight ratio of second azoles demodicid mite nitrile and pyridaben is 20:1～1:20；
The weight ratio of second azoles demodicid mite nitrile and azacyclotin is 20:1～1:20；
The weight ratio of second azoles demodicid mite nitrile and Bifenazate is 15:1～1:25；
The weight ratio of second azoles demodicid mite nitrile and avilamycin is 25:1～1:15；
The weight ratio of second azoles demodicid mite nitrile and propargite is 15:1～1:25；
The weight ratio of second azoles demodicid mite nitrile and Fenpropathrin is 20:1～1:20；
The weight ratio of second azoles demodicid mite nitrile and tebufenpyrad is 15:1～1:25；
The weight ratio of second azoles demodicid mite nitrile and fenpyroximate is 20:1～1:20；
The weight ratio of second azoles demodicid mite nitrile and acequinocyl is 20:1～1:20；
The weight ratio of second azoles demodicid mite nitrile and halfenprox is 20:1～1:20；
The weight ratio of second azoles demodicid mite nitrile and nitrile pyrrole demodicid mite ester is 20:1～1:20.
4. Insecticidal combinations of the demodicid mite of azoles containing second nitrile according to any one of claim 1 to 3 Thing, it is characterised in that：Compositionss make wettable powder, water dispersible granules, suspending agent, outstanding Emulsion, aqueous emulsion, microemulsion, microcapsule suspending agent or microcapsule suspension-suspendinagent agent.
5. the Pesticidal combination of the demodicid mite of azoles containing second nitrile according to claim 4 is used to prevent and treat agriculture The purposes of pest on crop.
6. purposes according to claim 5, it is characterised in that：Described insect is red Aranea, rust mite, tetranychid, planthopper, rice leaf roller, striped rice borer, yellow rice borer, Diamondback moth, Pieris rapae, bollworm, leaf miner, blister mite, Americal rice leaf miner, pear wood Louse or small heart-eating peach worm.
CN201510688423.1A 2015-10-21 2015-10-21 Insecticidal composition containing SYP-9625 Pending CN106605654A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201510688423.1A CN106605654A (en) 2015-10-21 2015-10-21 Insecticidal composition containing SYP-9625

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201510688423.1A CN106605654A (en) 2015-10-21 2015-10-21 Insecticidal composition containing SYP-9625

Publications (1)

Publication Number Publication Date
CN106605654A true CN106605654A (en) 2017-05-03

Family

ID=58610768

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201510688423.1A Pending CN106605654A (en) 2015-10-21 2015-10-21 Insecticidal composition containing SYP-9625

Country Status (1)

Country Link
CN (1) CN106605654A (en)

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106689137A (en) * 2017-02-16 2017-05-24 佛山市瑞生通科技有限公司 Pesticide composition containing ethyl cyanide and propargite
CN106818766A (en) * 2017-02-18 2017-06-13 佛山市瑞生通科技有限公司 A kind of composition pesticide of the mite nitrile of azoles containing second and spirodiclofen
CN106879611A (en) * 2017-02-16 2017-06-23 佛山市瑞生通科技有限公司 A kind of Pesticidal combination containing AVM and second azoles mite nitrile
CN106889087A (en) * 2017-03-20 2017-06-27 安徽省农业科学院植物保护与农产品质量安全研究所 A kind of medicament composition and its application method
CN108902158A (en) * 2018-08-17 2018-11-30 沈阳中化农药化工研发有限公司 A kind of suspending agent containing second azoles mite cyanide composition and its application
CN111226945A (en) * 2018-11-29 2020-06-05 沈阳中化农药化工研发有限公司 Synergistic insecticidal and acaricidal composition
CN113016812A (en) * 2019-12-24 2021-06-25 沈阳中化农药化工研发有限公司 Insecticidal and acaricidal synergistic composition and application thereof
CN115530025A (en) * 2022-11-09 2022-12-30 四川超易宏科技有限公司 Green and environment-friendly tomato planting method
CN115806512A (en) * 2021-09-15 2023-03-17 张建勋 Fluorine-containing acaricide and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104663666A (en) * 2013-11-26 2015-06-03 中国中化股份有限公司 Insecticidal and acaricidal composition containing mitochondrial electron transfer inhibitor acaricide
CN104663670A (en) * 2013-11-26 2015-06-03 中国中化股份有限公司 Synergistic miticidal composition
CN104663704A (en) * 2013-11-26 2015-06-03 中国中化股份有限公司 Insecticidal and acaricidal composition containing ATP synthetase inhibitor acaricide
CN104663702A (en) * 2013-11-26 2015-06-03 中国中化股份有限公司 Insecticidal and acaricidal composition containing esbiothrin insecticide

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104663666A (en) * 2013-11-26 2015-06-03 中国中化股份有限公司 Insecticidal and acaricidal composition containing mitochondrial electron transfer inhibitor acaricide
CN104663670A (en) * 2013-11-26 2015-06-03 中国中化股份有限公司 Synergistic miticidal composition
CN104663704A (en) * 2013-11-26 2015-06-03 中国中化股份有限公司 Insecticidal and acaricidal composition containing ATP synthetase inhibitor acaricide
CN104663702A (en) * 2013-11-26 2015-06-03 中国中化股份有限公司 Insecticidal and acaricidal composition containing esbiothrin insecticide

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106689137A (en) * 2017-02-16 2017-05-24 佛山市瑞生通科技有限公司 Pesticide composition containing ethyl cyanide and propargite
CN106879611A (en) * 2017-02-16 2017-06-23 佛山市瑞生通科技有限公司 A kind of Pesticidal combination containing AVM and second azoles mite nitrile
CN106818766A (en) * 2017-02-18 2017-06-13 佛山市瑞生通科技有限公司 A kind of composition pesticide of the mite nitrile of azoles containing second and spirodiclofen
CN106889087A (en) * 2017-03-20 2017-06-27 安徽省农业科学院植物保护与农产品质量安全研究所 A kind of medicament composition and its application method
CN108902158A (en) * 2018-08-17 2018-11-30 沈阳中化农药化工研发有限公司 A kind of suspending agent containing second azoles mite cyanide composition and its application
CN111226945A (en) * 2018-11-29 2020-06-05 沈阳中化农药化工研发有限公司 Synergistic insecticidal and acaricidal composition
CN111226945B (en) * 2018-11-29 2021-11-23 沈阳中化农药化工研发有限公司 Synergistic insecticidal and acaricidal composition
CN113016812A (en) * 2019-12-24 2021-06-25 沈阳中化农药化工研发有限公司 Insecticidal and acaricidal synergistic composition and application thereof
CN113016812B (en) * 2019-12-24 2022-02-11 沈阳中化农药化工研发有限公司 Insecticidal and acaricidal synergistic composition and application thereof
CN115806512A (en) * 2021-09-15 2023-03-17 张建勋 Fluorine-containing acaricide and preparation method thereof
CN115530025A (en) * 2022-11-09 2022-12-30 四川超易宏科技有限公司 Green and environment-friendly tomato planting method

Similar Documents

Publication Publication Date Title
CN106605654A (en) Insecticidal composition containing SYP-9625
CN106605657A (en) Pesticide combination containing SYP-9625
CN104430473A (en) Compounded insecticidal composition containing trifluorobenzene pyrimidine
CN104430369A (en) Insecticidal composition containing trifluoro-phenylpyridine and amides
CN106614677A (en) Insecticidal pesticide composition containing SYP-9625
CN104738045B (en) A kind of Pesticidal combination containing propylene glycol alginate
CN106614697A (en) SYP-9625-containing insecticidal pesticide composition
CN106804597A (en) A kind of Pesticidal combination of the nitrile of worm containing acetyl and fipronil bisamide
CN106804612A (en) A kind of Pesticidal combination of the nitrile of worm containing acetyl and thiacloprid
CN106804600A (en) A kind of Pesticidal combination of the nitrile of worm containing acetyl and pymetrozine
CN105594724A (en) High-efficient pesticide composition containing flumizone pentafluoride
CN105580830A (en) Insecticidal composition containing ZJ3757
CN104509534A (en) Insect disinfestation composition containing trifluorobenzene pyrimidine and nereistoxin
CN104585176B (en) A kind of Pesticidal combination of containing pyriminostrobin
CN106852338A (en) A kind of Pesticidal combination of the nitrile of worm containing acetyl and clothianidin
CN106804596A (en) A kind of Pesticidal combination of the nitrile of worm containing acetyl and Rynaxypyr
CN106804613A (en) A kind of Pesticidal combination of the nitrile of worm containing acetyl and Diacloden
CN106852328A (en) A kind of Pesticidal combination of the nitrile of worm containing acetyl and multiple killing teichomycin
CN104430484A (en) Insecticidal composition containing trifluoro-phenylpyridine and pyrethroids
CN105580815A (en) Pesticide composition containing ZJ3757
CN104585177B (en) A kind of High-efficiency miticidal composition of containing pyriminostrobin
CN103563977B (en) Pesticide pest-killing composition containing propylene glycol alginate
CN106852337A (en) A kind of Pesticidal combination of the nitrile of worm containing acetyl and sulfoxaflor
CN105746523A (en) Pyriproxyfen-containing insecticidal composition
CN106719773A (en) A kind of high-efficient pesticide composition of the nitrile of worm containing acetyl

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
WD01 Invention patent application deemed withdrawn after publication

Application publication date: 20170503

WD01 Invention patent application deemed withdrawn after publication