CN106879611A - A kind of Pesticidal combination containing AVM and second azoles mite nitrile - Google Patents
A kind of Pesticidal combination containing AVM and second azoles mite nitrile Download PDFInfo
- Publication number
- CN106879611A CN106879611A CN201710084665.9A CN201710084665A CN106879611A CN 106879611 A CN106879611 A CN 106879611A CN 201710084665 A CN201710084665 A CN 201710084665A CN 106879611 A CN106879611 A CN 106879611A
- Authority
- CN
- China
- Prior art keywords
- avm
- azoles mite
- mite nitrile
- composition pesticide
- nitrile
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a kind of Synergistic insecticidal compositions containing AVM and second azoles mite nitrile, the weight ratio of the AVM and second azoles mite nitrile is 1:2‑1:100, composition pesticide of the invention is applied to preventing and treating citrus red mite, has synergistic function in the ratio range, is worth the popularization and application in production.
Description
Technical field
The present invention relates to composition pesticide field, and in particular to be a kind of desinsection comprising AVM and second azoles mite nitrile
Composition, the mite class of resistance is produced particularly for preventing and treating.
Background technology
Mite, also known as red spider, cause harm various crop, especially oranges and tangerines, cotton, apple etc., often results in explosive disaster, and
And the epoch overlap seriously, quantity is big, easily develops immunity to drugs.
AVM, English name Avermectins is by big village's intelligence of Japanese North university etc. and Merck companies of the U.S.
The class developed first has ten hexa-atomic Macrocyclic lactone compounds of desinsection, mite killing, eelworm-killing activity, action character and mode
Have：Tag, stomach toxicity, penetration is strong.It is a kind of f macrolide disaccharide compound.It is the natural of the separation from edaphon
Product, has to insect and mite class and tags and stomach poison function and have faint fumigation action, without systemic action.But it has to blade
Very strong osmosis, can kill subepidermal insect, and the longevity of residure is long.Its not ovicidal, its mechanism of action and general insecticide
The difference is that it disturbs nervous physiology activity, stimulate release r- aminobutyric acids, and r- aminobutyric acids are to the nerve biography of arthropod
Lead inhibitory action, mite class paralysis symptom occurs after being contacted with medicament with larva into, deutonymph and insect, and inertia does not take food,
It is dead after 2-4 days.Because not causing insect rapid dehydration, so its lethal effect is slower.But to predatism and parasite
Though there is direct killing effect, because plant surface residual is few therefore small to the damage of beneficial insect.
The new acaricide of second Zuo Manjingshi China independent intellectual property right, Shenyang Sciencreat Chemicals Co., Ltd. develops
30% second azoles mite nitrile suspending agent product.Second azoles mite nitrile quite tires out such as panonychus citri, oranges and tangerines to phytophagous and embroiders mite, apple tetranychus, cotton
Tetranychid, eggplant tetranychid etc. show high Mars, have preferable therapeutic effect to each period of acarid.
It is to prevent and treat the maximally efficient means of plant pest using chemical agent in the real process of agricultural production, but
It is easiest to generate the problem that the generation of pest resistance to insecticide by chemical prevention insect.And long-term continuous high dose ground applies single
One chemical insecticide, a series of problems, such as easily cause residual, the environmental pollution of medicament.Rational pest control with insecticide acaricide is answered
With or mixture with expansion prevent spectrum, improve prevention effect, extension the optimum period for applying fertilizer, reduce dosage, reduce poisoning, reduce it is residual
Stay, delay pest resistance and drug-fast generation and the positive feature such as development, insecticidal/acaricidal agent compounding or mixture are on solving
State one of maximally efficient method of problem.Develop new product insecticide price constantly rises, and by contrast, exploitation is high with research
Effect, low toxicity, the compounding of low-residual and mixture has small investment, the lead time is short and paid attention to both at home and abroad, it is numerous and confused to increase exploitation
Development dynamics.At present, there is no on AVM and second azoles mite nitrile compounding and the relevant report of application.
The content of the invention
The purpose of the present invention is to solve the shortcomings of the prior art, there is provided a kind of acaricidal activity is high, the lasting period long is contained
The mite killing synergistic composition of AVM and second azoles mite nitrile.
Application another object of the present invention is to provide the Synergistic mite killing composition.
To reach above-mentioned purpose, the present invention is adopted the following technical scheme that：
A kind of composition pesticide, it is characterised in that active component include AVM and second azoles mite nitrile, wherein, AVM and
The weight ratio of second azoles mite nitrile is 1:2-1:100.
Further, the weight ratio of AVM and second azoles mite nitrile is 1:1-1:20.
Further, the weight ratio of active component is 1-80%, preferably 3-40% in the composition pesticide.
Above-mentioned AVM and second azoles mite nitrile belong to acaricide well known in the art, can by various commercial channel or
Preparation method according to Patents is prepared.
Further, composition pesticide of the invention can be aided with auxiliary element conventional during the formulations of pesticide are processed and be prepared into
It is adapted to any one formulation for agriculturally using, including it is wettable powder, water dispersible granules, aqueous emulsion, microemulsion, missible oil, outstanding
Floating agent, suspension emulsion.
Further, described agricultural chemicals auxiliary element includes dispersant, wetting agent, emulsifying agent, antifreezing agent, defoamer, increasing
Thick dose, stabilizer, disintegrant, film forming agent, colouring agent, filler and solvent.
The frequency of administration and usage amount of the present composition change and small variations with crops, insect, weather condition,
The purpose of effective preventing and treating can be reached by using appropriate dosage.
Composition pesticide of the invention is mainly used in preventing and treating the sucking mouth parts on the crops such as paddy rice, cotton, vegetables, fruit tree
Insect, is particularly suited for preventing and treating red spider.
Compared with prior art, beneficial effects of the present invention are：
1st, substantially, the interaction between each component activity is not simple superposition for synergistic effect, but has obvious Synergistic to make
With.
2nd, the active component mechanism of action is different in composition pesticide of the invention, the mite killing combination of the different mechanisms of action
Thing is used in conjunction with delaying the generation of pest resistance to insecticide.
3rd, composition pesticide prevention effect of the invention is good, and the lasting period is long, and can reduce the use of pesticide active ingredient
Amount, meets the demand of " decrement synergy ".
Specific embodiment
In order to make the purpose , technical scheme and advantage of the present invention be clearer, present invention specific examples below
Illustrate, but the present invention is limited to absolutely not these examples.As described below is only the present invention preferably embodiment, is used only for explaining
The present invention, but can not be therefore understands that being the limitation to the scope of the claims of the present invention.It should be pointed out that it is all it is of the invention spirit and
Any modification, equivalent or improvement for being made within principle etc., should be included within the scope of the present invention, therefore,
The protection domain of patent of the present invention should be determined by the appended claims.
First, example of formulations
1st, embodiment 1:21% AVM second azoles mite nitrile suspending agent（1:20）
AVM 1%
Second azoles mite nitrile 20%
Phenethyl phenol polyethenoxy ether phosphate 4%
Xanthans 0.2%
Aluminium-magnesium silicate 0.2%
Propane diols 3%
Organic silicone 0.3%
Deionized water surplus
2nd, embodiment 2:20.5% AVM second azoles mite nitrile missible oil（1:40）
AVM 0.5%
Second azoles mite nitrile 20%
Emulsifying agent 1,601 10%
Agriculture breast 500# 8%
Dimethyl phosphate 20%
Toluene surplus
3rd, embodiment 3：12% AVM second azoles mite nitrile suspending agent（1：23）
AVM 0.5%
Second azoles mite nitrile 11.5%
APES sulfate 5%
Alkyl naphthalene formaldehyde condensate sulfonates 3%
Xanthans 0.3%
Polyvinyl alcohol 0.3%
Sodium Benzoate 0.2%
Ethylene glycol 4%
Organic silicone 0.3%
Deionized water surplus
4th, embodiment 4:20.2% AVM second azoles mite nitrile microemulsion（1:100）
AVM 0.2%
Second azoles mite nitrile 20%
1-METHYLPYRROLIDONE 20%
Calcium dodecyl benzene sulfonate 6%
Alkyl phenyl polyglycol ether 5%
Polyoxyethylene fatty alcohol 4%
Deionized water surplus
2nd, Toxicity Determination
In order to prevent and treat agriculturally produce resistance citrus red mite, present inventor with AVM, second azoles mite nitrile for test
Medicament has carried out the Toxicity Determination of the pesticide activity component to citrus red mite of different ratio.
Experiment uses infusion process, and AVM and second azoles mite nitrile mother liquor are made into different series concentrations, is right with clear water
According to.Interior will be taken back with the Citrus leaf of red spider, be cut into that 3cm is long to be attached to slide one end picking individual with two-sided tape
The basically identical red spider of size, viscose glue is pasted onto with small writing brush by its back, per slide 30, if 4 repetitions, first in moisturizing
Under the conditions of place 4 hours, dissect spectroscopy with the bitubular, dead red spider is chosen and is abandoned, then not enough.Then red spider will be stained with
Slide leaching it is into the liquid be shaken gently for, soak 5 seconds or so take out, the liquid of adhesive surface and surrounding is sucked with blotting paper, often locate
Reason is repeated 3 times.The survival number of each treatment red spider is checked within 24 hours after medicine, the death rate is calculated, virulence is calculated with least square method
Equation and lethal final concentration LC50, the toxicity index and mixed co-toxicity coefficient CTC values of medicament are calculated according to the abundant methods of Sun Yun.Experiment
Result is as follows.
From table 1 it follows that AVM and second azoles mite nitrile compounding, 1:5-1:In the range of 100, to citrus red mite
With certain synergistic function.
3rd, field control effectiveness test
In order to preferably verify practical application effect of the invention, preventing and treating oranges and tangerines are carried out using the preparation of the embodiment of the present invention 1 red
Spider field control effectiveness test, each cell is arranged using random district's groups, per three trees of cell, isolation is provided between each treatment cell
OK, it is repeated 4 times.
Reagent agent：（1）21% AVM second azoles mite nitrile suspending agent（1:20）；
（2）20.5% AVM second azoles mite nitrile missible oil（1:40）；
（3）12% AVM second azoles mite nitrile suspending agent（1：23）；
（4）20.2% AVM second azoles mite nitrile microemulsion（1:100）；
（5）Comparative example 1:1.8% AVM suspending agent；
（6）Comparative example 2：30% second azoles mite nitrile suspending agent.
Respectively at 7 days after medicine, 14 investigation insect population numbers and calculate preventive effect, result of the test is as shown in table 2.
By table 2 as can be seen that the preventing and treating of AVM and second azoles mite nitrile to citrus red mite has good lasting effect and quick-acting
Property, compared with single dose, 7 days after medicine, the preventive effect of 14 days be significantly improved, in addition, in scope of medication, not finding the present invention
Composition pesticide there is poisoning to produce oranges and tangerines crop, influence to beneficial natural enemy is not also observed.
In sum, Pesticide use amount, reduction drug cost, raising can be reduced after AVM and second azoles mite nitrile compounding
The advantages of efficiency, it is worth the popularization and application in production.
Claims (7)
1. a kind of composition pesticide, it is characterised in that active component includes AVM and second azoles mite nitrile.
2. composition pesticide according to claim 1, it is characterised in that the weight ratio of the AVM and second azoles mite nitrile is
1:2-1:100。
3. composition pesticide according to claim 2, it is characterised in that the weight ratio of the AVM and second azoles mite nitrile
It is 1:1-1:20.
4. the composition pesticide according to any one of claim 1-3 claim, it is characterised in that the pesticide combination
The weight ratio of active component is 1-80%, preferably 3-40% in thing.
5. the composition pesticide according to any one of claim 1-3 claim, it is characterised in that its formulation is for can
In WP, water dispersible granules, aqueous emulsion, microemulsion, missible oil, suspending agent, suspension emulsion any one.
6. the composition pesticide according to any one of claim 1-5 claim be used for prevent and treat paddy rice, cotton, vegetables,
The purposes of the sucking pest on the crops such as fruit tree.
7. purposes according to claim 6, it is characterised in that the insect is red spider.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710084665.9A CN106879611A (en) | 2017-02-16 | 2017-02-16 | A kind of Pesticidal combination containing AVM and second azoles mite nitrile |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710084665.9A CN106879611A (en) | 2017-02-16 | 2017-02-16 | A kind of Pesticidal combination containing AVM and second azoles mite nitrile |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106879611A true CN106879611A (en) | 2017-06-23 |
Family
ID=59179198
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710084665.9A Withdrawn CN106879611A (en) | 2017-02-16 | 2017-02-16 | A kind of Pesticidal combination containing AVM and second azoles mite nitrile |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106879611A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106889087A (en) * | 2017-03-20 | 2017-06-27 | 安徽省农业科学院植物保护与农产品质量安全研究所 | A kind of medicament composition and its application method |
| CN107751193A (en) * | 2017-10-17 | 2018-03-06 | 重庆市农业科学院 | Ultra low volume liquids of the mite nitrile of azoles containing second and Ivermectin HCL and preparation method thereof |
| CN111264531A (en) * | 2018-12-05 | 2020-06-12 | 浙江省化工研究院有限公司 | Composition containing abamectin |
Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101248786A (en) * | 2008-01-26 | 2008-08-27 | 益阳市润慷宝化工有限公司 | Avermectin . Propargite emulsifiable concentrate and method of preparing the same |
| CN101390519A (en) * | 2008-07-17 | 2009-03-25 | 张少武 | Acaricide composition containing bromopropylate and avermectin with synergistic action |
| CN101697728A (en) * | 2009-10-28 | 2010-04-28 | 陕西上格之路生物科学有限公司 | Acaricide compound containing biphenyl hydrazine ester |
| CN101856029A (en) * | 2010-07-07 | 2010-10-13 | 吴明龙 | Pesticide combination containing etoxazole and abamectin |
| CN102210312A (en) * | 2010-04-02 | 2011-10-12 | 青岛凯源祥化工有限公司 | Acaricidal composition containing abamectin and fenazaquin |
| CN102283216A (en) * | 2010-06-19 | 2011-12-21 | 海利尔药业集团股份有限公司 | Acaricidal composition containing abamectin and etoxazole |
| CN103340207A (en) * | 2013-07-30 | 2013-10-09 | 刘彦文 | Environmentally-friendly special effect agent for killing red spiders and production method thereof |
| CN106605654A (en) * | 2015-10-21 | 2017-05-03 | 陕西韦尔奇作物保护有限公司 | Insecticidal composition containing SYP-9625 |
| CN106614677A (en) * | 2015-10-30 | 2017-05-10 | 陕西韦尔奇作物保护有限公司 | Insecticidal pesticide composition containing SYP-9625 |
-
2017
- 2017-02-16 CN CN201710084665.9A patent/CN106879611A/en not_active Withdrawn
Patent Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101248786A (en) * | 2008-01-26 | 2008-08-27 | 益阳市润慷宝化工有限公司 | Avermectin . Propargite emulsifiable concentrate and method of preparing the same |
| CN101390519A (en) * | 2008-07-17 | 2009-03-25 | 张少武 | Acaricide composition containing bromopropylate and avermectin with synergistic action |
| CN101697728A (en) * | 2009-10-28 | 2010-04-28 | 陕西上格之路生物科学有限公司 | Acaricide compound containing biphenyl hydrazine ester |
| CN102210312A (en) * | 2010-04-02 | 2011-10-12 | 青岛凯源祥化工有限公司 | Acaricidal composition containing abamectin and fenazaquin |
| CN102283216A (en) * | 2010-06-19 | 2011-12-21 | 海利尔药业集团股份有限公司 | Acaricidal composition containing abamectin and etoxazole |
| CN101856029A (en) * | 2010-07-07 | 2010-10-13 | 吴明龙 | Pesticide combination containing etoxazole and abamectin |
| CN103340207A (en) * | 2013-07-30 | 2013-10-09 | 刘彦文 | Environmentally-friendly special effect agent for killing red spiders and production method thereof |
| CN106605654A (en) * | 2015-10-21 | 2017-05-03 | 陕西韦尔奇作物保护有限公司 | Insecticidal composition containing SYP-9625 |
| CN106614677A (en) * | 2015-10-30 | 2017-05-10 | 陕西韦尔奇作物保护有限公司 | Insecticidal pesticide composition containing SYP-9625 |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106889087A (en) * | 2017-03-20 | 2017-06-27 | 安徽省农业科学院植物保护与农产品质量安全研究所 | A kind of medicament composition and its application method |
| CN107751193A (en) * | 2017-10-17 | 2018-03-06 | 重庆市农业科学院 | Ultra low volume liquids of the mite nitrile of azoles containing second and Ivermectin HCL and preparation method thereof |
| CN111264531A (en) * | 2018-12-05 | 2020-06-12 | 浙江省化工研究院有限公司 | Composition containing abamectin |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103461353B (en) | A kind of composition pesticide containing chitosan oligosaccharide, insecticide and application thereof | |
| CN103250733A (en) | Chlorpyrifos-containing insect disinfestation composition | |
| CN106879611A (en) | A kind of Pesticidal combination containing AVM and second azoles mite nitrile | |
| CN101647463A (en) | Insecticidal and acaricidal composition containing spirodiclofen | |
| CN101984828B (en) | Compound pesticide | |
| CN104970038B (en) | A kind of composition pesticide | |
| CN103355326A (en) | High-efficiency pesticide composition | |
| CN102763664B (en) | Insecticide composite containing spirodiclofen and bifenazate | |
| CN103380783B (en) | A kind of high-efficient pesticide composition | |
| CN102657216A (en) | Use of pesticide mixed preparation containing chlorpyrifos and high-efficiency cypermethrin in control of Athetis lepigone Moschler | |
| CN101194621B (en) | Mixed pesticide preparation of tubatoxin and butyl ether urea | |
| CN108812707A (en) | One kind killing thrips plant essential oil composition, preparation and its application | |
| CN102657178B (en) | Synergistic acaricidal composition containing spiromesifen and pyridaben | |
| CN105028423A (en) | Insecticidal composition containing spinetoram and pyridaben and use of insecticidal composition | |
| CN103271081B (en) | Etoxazole-triazophospesticide pesticide composition | |
| CN103734168B (en) | Insecticidal pesticide formulation containing biopesticide-rotenone | |
| CN102626101A (en) | Efficient insecticidal composition containing cyflumetofen | |
| CN103355320A (en) | Efficient environment-friendly pesticide compound composition | |
| CN104472519A (en) | Anti-mite composition | |
| CN104285947A (en) | Granular pesticide containing abamectin | |
| CN110150329A (en) | The insecticide and its processing method of capsaicine and purple stem boneset extract compounding | |
| CN101406187A (en) | Composition for killing insects and mites containing tetranoic acid and organophosphorus | |
| CN106818806A (en) | A kind of farm killing mite composition containing doractin and Bifenazate | |
| CN106035367B (en) | A kind of composition pesticide containing azacyclotin and propargite | |
| CN106719687A (en) | A kind of composition pesticide of the mite nitrile of azoles containing second and cyflumetofen |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WW01 | Invention patent application withdrawn after publication |
Application publication date: 20170623 |
|
| WW01 | Invention patent application withdrawn after publication |