CN103380783B - A kind of high-efficient pesticide composition - Google Patents
A kind of high-efficient pesticide composition Download PDFInfo
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- CN103380783B CN103380783B CN201210138455.0A CN201210138455A CN103380783B CN 103380783 B CN103380783 B CN 103380783B CN 201210138455 A CN201210138455 A CN 201210138455A CN 103380783 B CN103380783 B CN 103380783B
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- 239000000203 mixture Substances 0.000 title claims abstract description 50
- 239000000575 pesticide Substances 0.000 title claims abstract description 31
- MXWAGQASUDSFBG-RVDMUPIBSA-N fluacrypyrim Chemical compound CO\C=C(\C(=O)OC)C1=CC=CC=C1COC1=CC(C(F)(F)F)=NC(OC(C)C)=N1 MXWAGQASUDSFBG-RVDMUPIBSA-N 0.000 claims abstract description 81
- 239000005653 Bifenazate Substances 0.000 claims abstract description 26
- VHLKTXFWDRXILV-UHFFFAOYSA-N bifenazate Chemical compound C1=C(NNC(=O)OC(C)C)C(OC)=CC=C1C1=CC=CC=C1 VHLKTXFWDRXILV-UHFFFAOYSA-N 0.000 claims abstract description 26
- 241000607479 Yersinia pestis Species 0.000 claims abstract description 25
- 239000000375 suspending agent Substances 0.000 claims description 38
- 241000238631 Hexapoda Species 0.000 claims description 27
- 241001454293 Tetranychus urticae Species 0.000 claims description 23
- 239000000843 powder Substances 0.000 claims description 20
- 238000009736 wetting Methods 0.000 claims description 20
- 241000255967 Helicoverpa zea Species 0.000 claims description 15
- 241000488581 Panonychus citri Species 0.000 claims description 15
- 239000003094 microcapsule Substances 0.000 claims description 14
- 241001347511 Carposina sasakii Species 0.000 claims description 12
- 206010018498 Goitre Diseases 0.000 claims description 12
- 235000007688 Lycopersicon esculentum Nutrition 0.000 claims description 12
- 240000003768 Solanum lycopersicum Species 0.000 claims description 12
- 239000000839 emulsion Substances 0.000 claims description 12
- 201000003872 goiter Diseases 0.000 claims description 12
- 241001619980 Acaphylla theae Species 0.000 claims description 8
- 241001517923 Douglasiidae Species 0.000 claims description 8
- 241000255969 Pieris brassicae Species 0.000 claims description 8
- 241000488533 Tetranychus viennensis Species 0.000 claims description 8
- 239000003795 chemical substances by application Substances 0.000 claims description 8
- 239000000725 suspension Substances 0.000 claims description 7
- 239000004530 micro-emulsion Substances 0.000 claims description 6
- 239000004562 water dispersible granule Substances 0.000 claims description 6
- BOTNFCTYKJBUMU-UHFFFAOYSA-N 2-[4-(2-methylpropyl)piperazin-4-ium-1-yl]-2-oxoacetate Chemical compound CC(C)C[NH+]1CCN(C(=O)C([O-])=O)CC1 BOTNFCTYKJBUMU-UHFFFAOYSA-N 0.000 abstract description 24
- XQUXKZZNEFRCAW-UHFFFAOYSA-N fenpropathrin Chemical compound CC1(C)C(C)(C)C1C(=O)OC(C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 XQUXKZZNEFRCAW-UHFFFAOYSA-N 0.000 abstract description 24
- 230000002195 synergetic effect Effects 0.000 abstract description 20
- 150000001875 compounds Chemical class 0.000 abstract description 3
- 230000000749 insecticidal effect Effects 0.000 abstract description 3
- 238000001228 spectrum Methods 0.000 abstract description 3
- 239000003905 agrochemical Substances 0.000 abstract description 2
- 238000003912 environmental pollution Methods 0.000 abstract description 2
- 238000012360 testing method Methods 0.000 description 46
- 239000003814 drug Substances 0.000 description 41
- 239000002131 composite material Substances 0.000 description 35
- 230000003449 preventive effect Effects 0.000 description 24
- 239000013530 defoamer Substances 0.000 description 14
- 239000002270 dispersing agent Substances 0.000 description 14
- 238000011835 investigation Methods 0.000 description 14
- 239000012071 phase Substances 0.000 description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 13
- 239000008367 deionised water Substances 0.000 description 11
- 229910021641 deionized water Inorganic materials 0.000 description 11
- 239000003995 emulsifying agent Substances 0.000 description 10
- 239000002904 solvent Substances 0.000 description 10
- 239000000080 wetting agent Substances 0.000 description 10
- 230000002528 anti-freeze Effects 0.000 description 9
- 239000002562 thickening agent Substances 0.000 description 9
- 231100000820 toxicity test Toxicity 0.000 description 8
- 241000675108 Citrus tangerina Species 0.000 description 7
- 229920000742 Cotton Polymers 0.000 description 7
- 206010067482 No adverse event Diseases 0.000 description 7
- 241000344246 Tetranychus cinnabarinus Species 0.000 description 7
- 230000010165 autogamy Effects 0.000 description 7
- 229940079593 drug Drugs 0.000 description 7
- 239000000463 material Substances 0.000 description 7
- -1 carbazic acid isopropyl ester Chemical class 0.000 description 6
- 239000003381 stabilizer Substances 0.000 description 6
- 206010011732 Cyst Diseases 0.000 description 5
- 239000000642 acaricide Substances 0.000 description 5
- 239000008346 aqueous phase Substances 0.000 description 5
- 208000031513 cyst Diseases 0.000 description 5
- 229920002521 macromolecule Polymers 0.000 description 5
- 238000002360 preparation method Methods 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- 238000004458 analytical method Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 238000002474 experimental method Methods 0.000 description 4
- 239000000945 filler Substances 0.000 description 4
- 231100000636 lethal dose Toxicity 0.000 description 4
- 231100000225 lethality Toxicity 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 239000003002 pH adjusting agent Substances 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- 239000004094 surface-active agent Substances 0.000 description 4
- 231100000419 toxicity Toxicity 0.000 description 4
- 230000001988 toxicity Effects 0.000 description 4
- 241000196324 Embryophyta Species 0.000 description 3
- 238000000498 ball milling Methods 0.000 description 3
- 239000011230 binding agent Substances 0.000 description 3
- 235000013339 cereals Nutrition 0.000 description 3
- 235000013399 edible fruits Nutrition 0.000 description 3
- 239000000835 fiber Substances 0.000 description 3
- 238000009472 formulation Methods 0.000 description 3
- 235000021374 legumes Nutrition 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 230000000361 pesticidal effect Effects 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 235000013311 vegetables Nutrition 0.000 description 3
- 230000001018 virulence Effects 0.000 description 3
- 102000002322 Egg Proteins Human genes 0.000 description 2
- 108010000912 Egg Proteins Proteins 0.000 description 2
- 239000013543 active substance Substances 0.000 description 2
- 239000007884 disintegrant Substances 0.000 description 2
- 230000002045 lasting effect Effects 0.000 description 2
- 210000004681 ovum Anatomy 0.000 description 2
- 239000002574 poison Substances 0.000 description 2
- 231100000614 poison Toxicity 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 241000238876 Acari Species 0.000 description 1
- 241001292007 Chrysopa Species 0.000 description 1
- 206010034133 Pathogen resistance Diseases 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 230000008485 antagonism Effects 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- ONHBDDJJTDTLIR-UHFFFAOYSA-N azocyclotin Chemical compound C1CCCCC1[Sn](N1N=CN=C1)(C1CCCCC1)C1CCCCC1 ONHBDDJJTDTLIR-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N dimethylmethane Natural products CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000002552 dosage form Substances 0.000 description 1
- 230000000857 drug effect Effects 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 230000004907 flux Effects 0.000 description 1
- 238000003958 fumigation Methods 0.000 description 1
- 238000003197 gene knockdown Methods 0.000 description 1
- 238000005469 granulation Methods 0.000 description 1
- 230000003179 granulation Effects 0.000 description 1
- 239000002917 insecticide Substances 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000012452 mother liquor Substances 0.000 description 1
- 230000003151 ovacidal effect Effects 0.000 description 1
- 239000000825 pharmaceutical preparation Substances 0.000 description 1
- 231100000572 poisoning Toxicity 0.000 description 1
- 230000000607 poisoning effect Effects 0.000 description 1
- 244000144977 poultry Species 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 239000002728 pyrethroid Substances 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 210000002784 stomach Anatomy 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
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- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a kind of high-efficient pesticide composition, composition pesticide containing active components A and active component B, active components A is selected from fluacrypyrim, active component B is selected from any one compound following: azacyclotin, Bifenazate, fenbutatin oxide, fenpropathrin, and the weight ratio of active components A and active component B is 1 ︰ 80 ~ 60 ︰ 1.The present composition can prevent and treat various pests, and has obvious synergistic effect, expands insecticidal spectrum, and can reduce pesticide usage amount, reduces the residual quantity of agricultural chemicals on crop, alleviates environmental pollution.<!--1-->
Description
Technical field
The invention belongs to technical field of pesticide, relate to the application of a kind of high-efficient pesticide composition on crop pest.
Technical background
Fluacrypyrim (Fluacrypyrim) chemical name: methyl (E)-2-{ α-[2-isopropoxy-6-(trifluoromethyl) pyrimidine-4-phenoxy group]-0-tolyl }-3-methoxy acrylate, molecular formula: C
20h
21f
3n
2o
5.Fluacrypyrim is first methoxy acrylic miticide.Have and well tag and stomach poison function, to each feature of evil mite, if comprise ovum mite, one-tenth mite all effectively, and quick-acting is good, and the lasting period reaches more than 30 days.
Azacyclotin (Azocyclotin) chemical name: 1-(three cyclohexyl stannyls)-1-hydrogen-1,2,4-triazole, molecular formula: C
20h
35n
3sn.Azacyclotin is the stronger broad spectrum activity miticide of action of contace poison.If mite can be killed, become mite and summer egg, invalid to winter egg.Have good stability to light and rainwater, the longevity of residure is longer.To crop safety under typical concentrations.
Bifenazate (Bifenazate) chemical name: 3-(4-methoxyl biphenyl base-3-base) carbazic acid isopropyl ester, molecular formula: C
17h
20n
2o
3.Bifenazate is a kind of new selective foliar spray miticide, effective to each life stage of mite.There is ovicidal activity and knock down activity rapidly with to what become mite, minimum on predacious mite impact, be very suitable for the comprehensive regulation of insect.Plant is not poisoned.
Fenbutatin oxide (Fenbutatinoxide) chemical name: two [three 2-methylphenyl propyl group) tin] oxide, molecular formula: C
60h
78oSn
2.Fenbutatin oxide is a kind of non-interior suction miticide, has the harmful mite of resistance not produce cross resistance to it to organic phosphor and organochlorine.To evil mite to tag, after spray medicine, initial virulence is slow, and after 3 days, activity starts to increase, and peaks by 14 days.This medicine longevity of residure is one longer in miticide, 2-5 month can be reached, to young mite with to become the lethality of mite stronger, but it is little to the lethality of ovum, use all very safe each vegetative period crop, use exceedes effectively kills mite concentration one and has doubly been showed no poisoning and occurs, as very little in impacts such as Predatory Mites, wooden dipper first and Chrysopas on evil mite natural enemy.
Fenpropathrin (Fenpropathrin) chemical name: alpha-cyano-3-phenoxy benzyl-2,2,3,3-tetramethyl-ring propane carbonyl acid ester, molecular formula: C
22h
23nO
3.Fenpropathrin is a kind of pyrethroid insecticides, and insecticidal spectrum is wide, and the longevity of residure is long, have good result to be its maximum feature, but this product is without interior suction, fumigation action to multiple tetranychid.
Summary of the invention
Fluacrypyrim, azacyclotin, Bifenazate, fenbutatin oxide, fenpropathrin single dose Long-Time Service may bring resistance to occur, degradation problem under drug effect, the composition pesticide that the present invention proposes contains active components A and active component B, and appropriate surfactant and carrier.
A kind of high-efficient pesticide composition, containing active components A and active component B, active components A and active component B weight ratio are 1 ︰ 80 ~ 60 ︰ 1, and described active components A is selected from fluacrypyrim, and active component B is selected from the one in azacyclotin, Bifenazate, fenbutatin oxide, fenpropathrin; Active components A and the preferred weight ratio of active component B are 1 ︰ 60 ~ 40 ︰ 1; The weight ratio being more preferably fluacrypyrim and azacyclotin is 1 ︰ 25 ~ 10 ︰ 1; The weight ratio of fluacrypyrim and Bifenazate is 1 ︰ 30 ~ 10 ︰ 1; The weight ratio of fluacrypyrim and fenbutatin oxide is 1 ︰ 30 ~ 10 ︰ 1; The weight ratio of fluacrypyrim and fenpropathrin is 1 ︰ 20 ~ 10 ︰ 1.
Described composition pesticide can be made into wetting powder, water dispersible granules, suspending agent, suspension emulsion, microemulsion, aqueous emulsion, microcapsule suspending agent, microcapsule suspension-suspendinagent agent.
Described composition pesticide is for preventing and treating the application of insect pest on cereal crop, fruit tree, vegetables, fiber crop, ornamental plants, legume crop.
Described insect comprises Tetranychus urticae, two spotted spider mite, Panonychus citri, peach fruit borer, tetranychus viennensis, tetranychid, knurl tick, blister mite, leaf miner, cotton bollworm, Shenmu-Yanan railway, Tetranychus cinnabarinus, cuts type tetranychid, acaphylla theae, tealeaves mite, tomato goitre mite, cabbage caterpillar.
In the present composition, the content of active component depends on amount of application when being used alone, and also depends on mixed ratio and the synergistic effect degree of a kind of compound and another kind of compound, simultaneously also relevant with target pest.In usual composition, the weight percentage of active component is 2% ~ 90% of gross weight, is preferably 5% ~ 80%.According to different preparation types, active component content scope is different.Usually, liquid preparation contains the active substance of by weight 1% ~ 60%, is preferably 5% ~ 50%; Solid pharmaceutical preparation contains the active substance of by weight 5% ~ 80%, is preferably 10% ~ 80%.
At least containing a kind of surfactant in Pesticidal combination of the present invention, the dispersion of active component in water when being beneficial to use.Surface-active contents is 2% ~ 30% of total formulation weight amount, and surplus is solid or liquid diluent.
Surfactant selected by Pesticidal combination of the present invention is known in those skilled in the art: can be selected from one or more in dispersant, wetting agent, thickener or defoamer.According to different dosage form, in preparation, stabilizing agent known in those skilled in the art, antifreeze etc. can also be contained.
Pesticidal combination of the present invention can by user before use through diluting or directly using.Its preparation can be prepared by processing method known in those skilled in the art, after mixing, then adds surfactant as one or more in dispersant, stabilizing agent, wetting agent, binding agent, defoamer etc. by active component with liquid flux or solid carrier.
Composition comprises following component and content when making wetting powder: active components A 1% ~ 60%, active component B1% ~ 80%, dispersant 1% ~ 12%, wetting agent 1% ~ 8%, filler surplus.
Composition comprises following component and content when making water dispersible granules: active components A 1% ~ 60%, active component B1% ~ 80%, dispersant 1% ~ 12%, wetting agent 1% ~ 8%, disintegrant 1% ~ 10%, binding agent 0 ~ 8%, filler surplus.
Composition comprises following component and content when making suspending agent: active components A 1% ~ 50%, active component B1% ~ 50%, dispersant 1% ~ 10%, wetting agent 1% ~ 10%, defoamer 0.01% ~ 2%, thickener 0 ~ 2%, antifreeze 0 ~ 8%, deionized water add to 100%.
Composition comprises following component and content when making suspension emulsion: active components A 1% ~ 50%, active component B1% ~ 50%, emulsifier 1% ~ 10%, dispersant 1% ~ 10%, solvent 0 ~ 20%, defoamer 0.01% ~ 2%, thickener 0 ~ 2%, antifreeze 0 ~ 8%, stabilizing agent 0 ~ 3%, deionized water add to 100%.
Composition comprises following component and content when making microemulsion: active components A 1% ~ 50%, active component B1% ~ 50%, emulsifier 3% ~ 25%, solvent 1% ~ 10%, antifreeze 0 ~ 8%, stabilizing agent 0 ~ 3%, defoamer 0.01% ~ 2%, deionized water add to 100%.
Composition comprises following component and content when making aqueous emulsion: active components A 1% ~ 50%, active component B1% ~ 50%, solvent 1% ~ 20%, emulsifier 1% ~ 12%, antifreeze 0 ~ 8%, defoamer 0.01% ~ 2%, thickener 0 ~ 2%, deionized water add to 100%.
Composition comprises following component and content when making microcapsule suspending agent: active components A
1% ~ 50%, active component B1% ~ 50%, macromolecule cyst material 1% ~ 10%, dispersant 2% ~ 10%, solvent 1% ~ 10%, emulsifier 1% ~ 7%, pH adjusting agent 0.01% ~ 5%, defoamer 0.01% ~ 2%, deionized water add to 100%.
Composition comprises following component and content when making microcapsule suspension-suspendinagent agent: active components A 1% ~ 50%, active component B1% ~ 50%, macromolecule cyst material 1% ~ 12%, dispersant 1%-12%, wetting agent 1%-8%, solvent 1% ~ 15%, emulsifier 1% ~ 8%, defoamer 0.01% ~ 2%, thickener 0 ~ 2%, pH adjusting agent 0.01% ~ 5%, deionized water add to 100%.
wetting powder the key technical indexes of the present invention:
Water dispersible granules the key technical indexes of the present invention:
Suspending agent the key technical indexes of the present invention:
Suspension emulsion the key technical indexes of the present invention:
Microemulsion the key technical indexes of the present invention:
Aqueous emulsion the key technical indexes of the present invention:
Microcapsule suspending agent the key technical indexes of the present invention:
Microcapsule suspension-suspendinagent agent the key technical indexes of the present invention:
The invention has the advantages that:
(1) present composition has good synergy and lasting effect within the specific limits, and preventive effect is higher than single dose; (2) pesticide usage amount reduces, and reduces the residual quantity of agricultural chemicals on crop, alleviates environmental pollution; (3) expand insecticidal spectrum, have greater activity to the Tetranychus urticae on cereal crop, fruit tree, vegetables, fiber crop, ornamental plants, legume crop, two spotted spider mite, Panonychus citri, peach fruit borer, tetranychus viennensis, tetranychid, knurl tick, blister mite, leaf miner, cotton bollworm, Shenmu-Yanan railway, Tetranychus cinnabarinus, section type tetranychid, acaphylla theae, tealeaves mite, tomato goitre mite, cabbage caterpillar; (4) to person poultry safety, Environmental compatibility is good; And preparation adhesion strength strengthens, resistance of rainwater washing against.
Embodiment
Below in conjunction with embodiment to further instruction of the present invention, the percentage in embodiment is all weight percentage, but the present invention is not limited thereto.
Application Example one
Example 1 ~ 12 wetting powder
By fluacrypyrim, active component B, dispersant, wetting agent, filler mixing, mix in mixed cylinder, mix again after airslide disintegrating mill is pulverized, namely can be made into wetting powder product of the present invention.Specifically in table 1.
The each component of table 1 example 1 ~ 12 and content
Example 13 ~ 24 water dispersible granules
Fluacrypyrim, active component B, dispersant, wetting agent, binding agent, disintegrant, filler are obtained together the particle diameter needed through air-flow crushing, obtain granulation materials.Item is quantitatively sent in fluidized bed granulating dryer through granulating and after drying, obtaining water dispersible granules product of the present invention.Specifically in table 2.
The each component of table 2 example 13 ~ 24 and content
Example 25 ~ 36 suspending agent
Dispersant, wetting agent, defoamer, thickener, antifreeze are mixed through high speed shear, add fluacrypyrim, active component B, surplus deionized water is supplied, ball milling 2 ~ 3 hours in ball mill, make diameter of particle all below 5 μm, obtained suspending agent product of the present invention.Specifically in table 3.
The each component of table 3 example 25 ~ 36 and content
Example 37 ~ 48 suspension emulsion
By dispersant, defoamer, thickener, antifreeze, stabilizing agent in above-mentioned formulation material, mix through high speed shear, add fluacrypyrim, ball milling 2 ~ 3 hours in ball mill, make diameter of particle all below 5 μm, obtained fluacrypyrim suspending agent, then by active component B, solvent, emulsifier and the direct emulsification of various auxiliary agent high speed agitators in suspending agent, obtained suspension emulsion product of the present invention.Specifically in table 4,5.
The each component of table 4 example 37 ~ 42 and content
The each component of table 5 example 43 ~ 48 and content
Example 49 ~ 53 microemulsion
Fluacrypyrim, active component B are dissolved in and are equipped with in the homogenizer of solvent, emulsifier, antifreeze, defoamer, stabilizing agent are joined in the homogenizer that above-mentioned solution is housed, surplus deionized water gives strong mixing and homogenize after supplying, finally obtain the microemulsion product of the present invention that clear appearance is transparent.Specifically in table 6.
The each component of table 6 example 49 ~ 53 and content
Example 54 ~ 65 aqueous emulsion
Fluacrypyrim, active component B, solvent, emulsifier are added together, make to be dissolved into homogeneous oil phase; Deionized water, antifreeze, thickener, defoamer are mixed, becomes homogeneous aqueous phase.Under high velocity agitation, aqueous phase is added oil phase, obtained aqueous emulsion product of the present invention.Specifically in table 7,8.
The each component of table 7 example 54 ~ 59 and content
The each component of table 8 example 60 ~ 65 and content
Azacyclotin in 1-table 8, Bifenazate, fenbutatin oxide, fenpropathrin exchange will be shown, can novel formulation be obtained.
Example 66 ~ 68 microcapsule suspending agent
By fluacrypyrim, active component B, macromolecule cyst material, solvent, make to be dissolved into homogeneous oil phase, in a shear condition, oil phase is joined in the aqueous phase solution containing emulsifier, pH adjusting agent, dispersant, defoamer, surplus deionized water is supplied, bi-material reacts at oil-water interfaces, forms macromolecule cyst wall, makes the finely disseminated microcapsule suspending agent product of the present composition.Specifically in table 9.
The each component of table 9 example 66 ~ 68 and content
Example 69 ~ 71 microcapsule suspension-suspendinagent agent
By active component B, macromolecule cyst material, solvent, make to be dissolved into homogeneous oil phase, oil phase is joined in a shear condition in the aqueous phase solution containing emulsifier, pH adjusting agent, make finely disseminated microcapsule suspending agent.Dispersant, wetting agent, defoamer, thickener are mixed through high speed shear, add fluacrypyrim, ball milling 2 ~ 3 hours in ball mill, make diameter of particle all below 5 μm, obtained suspending agent, then join in the aqueous phase solution of micro-capsule suspension by suspending agent, deionized water supplies surplus, makes the finely disseminated microcapsule suspension-suspendinagent agent product of the present composition.Specifically in table 10.
The each component of table 10 example 69 ~ 71 and content
The embodiment of the present invention is the method adopting Toxicity Determination and field trial to combine.First pass through Toxicity Determination, co-toxicity coefficient (CTC) after clear and definite two kinds of medicaments are composite by a certain percentage, CTC < 80 is antagonism, 80≤CTC≤120 are summation action, CTC > 120 is synergistic effect, on this basis, then carry out field trial.
Test method: respectively the mother liquor of each mixed agent is diluted to five series concentration during test, is placed in beaker respectively for subsequent use.Adopt the method connecing worm after first soaking leaf, take out after the blade of the same size not contacting any medicament is soaked 5s in the liquid configured, naturally dry, put into insect box, then connect for examination larva, raise under 25 DEG C of conditions, often process and repeat for 3 times, often repeating examination borer population used is 50, establishes blank simultaneously, checks dead borer population in 72h, calculate lethality and corrected mortality, try to achieve virulence regression equation and calculate LC
50value.If contrast lethality is greater than 10%, be then considered as invalid test.Computing formula is as follows:
Insect corrected mortality is converted into probit value (y), and concentration for the treatment of (μ g/ml) converts logarithm value to (x), draws virulence regression equation, and calculate the value of often kind of medicament thus with method of least squares.Co-toxicity coefficient CTC is calculated according to the abundant equation of Sun Yun.Computing formula following (take fluacrypyrim as standard agent, its toxicity index is 100):
TI × the P of theoretical toxicity index (the TTI)=fluacrypyrim of M
fluacrypyrimtI × the P of+active component B
effective active composition B
In formula: M is the mixture of different ratio
P
effective active composition Bfor the ratio that effective active composition B is shared in the composition
P
fluacrypyrimfor the ratio that fluacrypyrim is shared in the composition
B is selected from the one in azacyclotin, Bifenazate, fenbutatin oxide, fenpropathrin.
Application Example two:
For examination insect: citrus red mite.
Test medicine provides by Shaanxi Meibang Pesticide Co., Ltd..
Experimental scheme: through effective lethal concentration scope of preliminary experiment determination fluacrypyrim and the former medicine of azacyclotin and the two different ratio mixture.
Toxicity test result
Table 11 fluacrypyrim and the composite toxicity test analysis of results table to citrus red mite of azacyclotin
As shown in Table 11, fluacrypyrim and the composite proportioning of preventing and treating citrus red mite of azacyclotin are when 1 ︰ 80 ~ 60 ︰ 1, co-toxicity coefficient is all greater than 120, both explanations mixture in 1 ︰ 80 ~ 60 ︰ 1 scope all shows synergistic effect, when the proportioning of fluacrypyrim and azacyclotin is at 1 ︰ 25 ~ 10 ︰ 1, synergistic effect is more outstanding, and co-toxicity coefficient is all greater than 210.Wherein when fluacrypyrim and azacyclotin weight ratio are 2 ︰ 5, co-toxicity coefficient is maximum, and synergistic effect is the most obvious.Testing through applicant the proportioning finding fluacrypyrim and azacyclotin is 10:1, 5:1, 4:1, 3:1, 2:1, 1:1, 1:2, 2:5, 1:3, 1:4, 1:5, 1:6, 1:7, 1:8, 1:9, 1:10, 1:15, 1:20, during 1:25, fluacrypyrim and azacyclotin composite to Tetranychus urticae, two spotted spider mite, Panonychus citri, peach fruit borer, tetranychus viennensis, tetranychid, knurl tick, blister mite, leaf miner, cotton bollworm, Shenmu-Yanan railway, Tetranychus cinnabarinus, cut type tetranychid, acaphylla theae, tealeaves mite, tomato goitre mite, the control of cabbage caterpillar has obvious synergistic effect, co-toxicity coefficient is all greater than 120.
Application Example three:
For examination insect: apple Tetranychus urticae.
Test medicine provides by Shaanxi Meibang Pesticide Co., Ltd..
Experimental scheme: through effective lethal concentration scope of preliminary experiment determination fluacrypyrim and the former medicine of Bifenazate and the two different ratio mixture.
Toxicity test result
Table 12 fluacrypyrim and the composite toxicity test analysis of results table to apple Tetranychus urticae of Bifenazate
As shown in Table 12, the proportioning of fluacrypyrim and Bifenazate composite control apple Tetranychus urticae is when 1 ︰ 80 ~ 60 ︰ 1, co-toxicity coefficient is all greater than 120, both explanations mixture in 1 ︰ 80 ~ 60 ︰ 1 scope all shows synergistic effect, when the proportioning of fluacrypyrim and Bifenazate is at 1 ︰ 30 ~ 10 ︰ 1, synergistic effect is more outstanding, and co-toxicity coefficient is all greater than 220.Wherein when fluacrypyrim and Bifenazate weight ratio are 1 ︰ 3, co-toxicity coefficient is maximum, and synergistic effect is the most obvious.Testing through applicant the proportioning finding fluacrypyrim and Bifenazate is 10:1, 5:1, 4:1, 3:1, 2:1, 1:1, 1:2, 1:3, 1:4, 1:5, 1:6, 1:7, 1:8, 1:9, 1:10, 1:15, 1:20, 1:25, during 1:30, fluacrypyrim and Bifenazate composite to Tetranychus urticae, two spotted spider mite, Panonychus citri, peach fruit borer, tetranychus viennensis, tetranychid, knurl tick, blister mite, leaf miner, cotton bollworm, Shenmu-Yanan railway, Tetranychus cinnabarinus, cut type tetranychid, acaphylla theae, tealeaves mite, tomato goitre mite, the control of cabbage caterpillar has obvious synergistic effect, co-toxicity coefficient is all greater than 120.
Application Example four:
For examination insect: oranges and tangerines blister mite.
Test medicine provides by Shaanxi Meibang Pesticide Co., Ltd..
Experimental scheme: through effective lethal concentration scope of preliminary experiment determination fluacrypyrim and the former medicine of fenbutatin oxide and the two different ratio mixture.
Toxicity test result
Table 13 fluacrypyrim and the composite toxicity test analysis of results table to oranges and tangerines blister mite of fenbutatin oxide
As shown in Table 13, the proportioning of fluacrypyrim and fenbutatin oxide composite control oranges and tangerines blister mite is when 1 ︰ 80 ~ 60 ︰ 1, co-toxicity coefficient is all greater than 120, both explanations mixture in 1 ︰ 80 ~ 60 ︰ 1 scope all shows synergistic effect, when the proportioning of fluacrypyrim and fenbutatin oxide is at 1 ︰ 30 ~ 10 ︰ 1, synergistic effect is more outstanding, and co-toxicity coefficient is all greater than 220.Wherein when fluacrypyrim and fenbutatin oxide weight ratio are 1 ︰ 3, co-toxicity coefficient is maximum, and synergistic effect is the most obvious.Testing through applicant the proportioning finding fluacrypyrim and fenbutatin oxide is 10:1, 5:1, 4:1, 3:1, 2:1, 1:1, 1:2, 1:3, 1:4, 1:5, 1:6, 1:7, 1:8, 1:9, 1:10, 1:15, 1:20, 1:25, during 1:30, fluacrypyrim and fenbutatin oxide composite to Tetranychus urticae, two spotted spider mite, Panonychus citri, peach fruit borer, tetranychus viennensis, tetranychid, knurl tick, blister mite, leaf miner, cotton bollworm, Shenmu-Yanan railway, Tetranychus cinnabarinus, cut type tetranychid, acaphylla theae, tealeaves mite, tomato goitre mite, the control of cabbage caterpillar has obvious synergistic effect, co-toxicity coefficient is all greater than 120.
Application Example five:
For examination insect: cotton cotton bollworm.
Test medicine provides by Shaanxi Meibang Pesticide Co., Ltd..
Experimental scheme: through effective lethal concentration scope of preliminary experiment determination fluacrypyrim and the former medicine of fenpropathrin and the two different ratio mixture.
Toxicity test result
Table 14 fluacrypyrim and the composite toxicity test analysis of results table to cotton cotton bollworm of fenpropathrin
As shown in Table 14, fluacrypyrim and the composite proportioning of preventing and treating cotton cotton bollworm of fenpropathrin are when 1 ︰ 80 ~ 60 ︰ 1, co-toxicity coefficient is all greater than 120, both explanations mixture in 1 ︰ 80 ~ 60 ︰ 1 scope all shows synergistic effect, when the proportioning of fluacrypyrim and fenpropathrin is at 1 ︰ 20 ~ 10 ︰ 1, synergistic effect is more outstanding, and co-toxicity coefficient is all greater than 210.Wherein when fluacrypyrim and fenpropathrin weight ratio are 1 ︰ 2, co-toxicity coefficient is maximum, and synergistic effect is the most obvious.Testing through applicant the proportioning finding fluacrypyrim and fenpropathrin is 10:1, 5:1, 4:1, 3:1, 2:1, 1:1, 1:2, 1:3, 1:4, 1:5, 1:6, 1:7, 1:8, 1:9, 1:10, 1:15, during 1:20, fluacrypyrim and fenpropathrin composite to Tetranychus urticae, two spotted spider mite, Panonychus citri, peach fruit borer, tetranychus viennensis, tetranychid, knurl tick, blister mite, leaf miner, cotton bollworm, Shenmu-Yanan railway, Tetranychus cinnabarinus, cut type tetranychid, acaphylla theae, tealeaves mite, tomato goitre mite, the control of cabbage caterpillar has obvious synergistic effect, co-toxicity coefficient is all greater than 120.
Application Example six fluacrypyrim and active component B and the composite control tomato goitre mite test of pesticide effectiveness thereof
This experimental establishment is at Xian District, Shanxi Province suburban area, test medicine is researched and developed by Shaanxi Meibang Pesticide Co., Ltd., is provided, contrast medicament 30% fluacrypyrim suspending agent (autogamy), 25% azacyclotin wetting powder (commercial), 43% Bifenazate suspending agent (commercial), 50% fenbutatin oxide suspending agent (commercial), 20% fenpropathrin wetting powder (commercial).
Investigation tomato goitre acarid evil index before medicine, in the dispenser of insect pest initial stage of origination, 1 day, 3 days, 7 days investigation insect pest indexes after dispenser also calculate preventive effect.Result of the test is as follows:
Table 15 fluacrypyrim and active component B and the composite control tomato goitre mite test of pesticide effectiveness thereof
As can be seen from Table 15, fluacrypyrim and active component B composite after effectively can prevent and treat tomato goitre mite, control efficiency is all better than the preventive effect of single dose, and the preventive effect phase is long.In test scope of medication, target crop is had no adverse effects.
Application Example seven fluacrypyrim and active component B and the composite control cotton cotton bollworm test of pesticide effectiveness thereof
This experimental establishment is in Weinan City Dali County, Shaanxi Province, test medicine is researched and developed by Shaanxi Meibang Pesticide Co., Ltd., is provided, contrast medicament 30% fluacrypyrim suspending agent (autogamy), 25% azacyclotin wetting powder (commercial), 43% Bifenazate suspending agent (commercial), 50% fenbutatin oxide suspending agent (commercial), 20% fenpropathrin wetting powder (commercial).
Investigation cotton cotton bollworm insect pest index before medicine, in the dispenser of insect pest initial stage of origination, 1 day, 3 days, 7 days investigation insect pest indexes after dispenser also calculate preventive effect.Result of the test is as follows:
Table 16 fluacrypyrim and active component B and the composite control cotton cotton bollworm test of pesticide effectiveness thereof
As can be seen from Table 16, fluacrypyrim and active component B composite after can effectively prevent and treat cotton cotton bollworm, control efficiency is all better than the preventive effect of single dose, and the preventive effect phase is long.In test scope of medication, target crop is had no adverse effects.
Application Example eight fluacrypyrim and active component B and the composite control apple Tetranychus urticae test of pesticide effectiveness thereof
This experimental establishment is in Xianyang, Shanxi province city, test medicine is researched and developed by Shaanxi Meibang Pesticide Co., Ltd., is provided, contrast medicament 30% fluacrypyrim suspending agent (autogamy), 25% azacyclotin wetting powder (commercial), 43% Bifenazate suspending agent (commercial), 50% fenbutatin oxide suspending agent (commercial), 20% fenpropathrin wetting powder (commercial).
Investigation apple Tetranychus urticae insect pest index before medicine, in the dispenser of insect pest initial stage of origination, 1 day, 3 days, 7 days investigation insect pest indexes after dispenser also calculate preventive effect.Result of the test is as follows:
Table 17 fluacrypyrim and active component B and the composite control apple Tetranychus urticae test of pesticide effectiveness thereof
As can be seen from Table 17, fluacrypyrim and active component B composite after can effectively prevent and treat apple Tetranychus urticae, control efficiency is all better than the preventive effect of single dose, and the preventive effect phase is long.In test scope of medication, target crop is had no adverse effects.
Application Example nine fluacrypyrim and active component B and the composite control citrus red mite test of pesticide effectiveness thereof
This experimental establishment is in Hanzhong city, test medicine is researched and developed by Shaanxi Meibang Pesticide Co., Ltd., is provided, contrast medicament 30% fluacrypyrim suspending agent (autogamy), 25% azacyclotin wetting powder (commercial), 43% Bifenazate suspending agent (commercial), 50% fenbutatin oxide suspending agent (commercial), 20% fenpropathrin wetting powder (commercial).
Investigation citrus red mite insect pest index before medicine, in the dispenser of insect pest initial stage of origination, 1 day, 3 days, 7 days investigation insect pest indexes after dispenser also calculate preventive effect.Result of the test is as follows:
Table 18 fluacrypyrim and active component B and the composite control citrus red mite test of pesticide effectiveness thereof
As can be seen from Table 18, fluacrypyrim and active component B composite after effectively can prevent and treat citrus red mite, control efficiency is all better than the preventive effect of single dose, and the preventive effect phase is long.In test scope of medication, target crop is had no adverse effects.
Application Example ten fluacrypyrim and active component B and the composite control apple peach fruit borer test of pesticide effectiveness thereof
This experimental establishment is in Xianyang, Shanxi province city, test medicine is researched and developed by Shaanxi Meibang Pesticide Co., Ltd., is provided, contrast medicament 30% fluacrypyrim suspending agent (autogamy), 25% azacyclotin wetting powder (commercial), 43% Bifenazate suspending agent (commercial), 50% fenbutatin oxide suspending agent (commercial), 20% fenpropathrin wetting powder (commercial).
Investigation apple peach fruit borer insect pest index before medicine, in the dispenser of insect pest initial stage of origination, 1 day, 3 days, 7 days investigation insect pest indexes after dispenser also calculate preventive effect.Result of the test is as follows:
Table 19 fluacrypyrim and active component B and the composite control apple peach fruit borer test of pesticide effectiveness thereof
As can be seen from Table 19, fluacrypyrim and active component B composite after can effectively prevent and treat apple peach fruit borer, control efficiency is all better than the preventive effect of single dose, and the preventive effect phase is long.In test scope of medication, target crop is had no adverse effects.
Application Example 11 fluacrypyrim and active component B and the composite control oranges and tangerines blister mite test of pesticide effectiveness thereof
This experimental establishment is at Shaanxi Province's Hanzhong City, test medicine is researched and developed by Shaanxi Meibang Pesticide Co., Ltd., is provided, contrast medicament 30% fluacrypyrim suspending agent (autogamy), 25% azacyclotin wetting powder (commercial), 43% Bifenazate suspending agent (commercial), 50% fenbutatin oxide suspending agent (commercial), 20% fenpropathrin wetting powder (commercial).
Investigation oranges and tangerines blister mite insect pest index before medicine, in the dispenser of insect pest initial stage of origination, 3 days, 7 days, 15 days investigation insect pest indexes after dispenser also calculate preventive effect.Result of the test is as follows:
Table 20 fluacrypyrim and active component B and the composite control oranges and tangerines blister mite test of pesticide effectiveness thereof
As can be seen from Table 20, fluacrypyrim and active component B composite after can effectively prevent and treat oranges and tangerines blister mite, control efficiency is all better than the preventive effect of single dose, and the preventive effect phase is long.In test scope of medication, target crop is had no adverse effects.
Application Example 12 fluacrypyrim and active component B and the composite control tealeaves mite test of pesticide effectiveness thereof
This experimental establishment is in Ya'an, Sichuan Province, test medicine is researched and developed by Shaanxi Meibang Pesticide Co., Ltd., is provided, contrast medicament 30% fluacrypyrim suspending agent (autogamy), 25% azacyclotin wetting powder (commercial), 43% Bifenazate suspending agent (commercial), 50% fenbutatin oxide suspending agent (commercial), 20% fenpropathrin wetting powder (commercial).
Investigation tealeaves acarid evil index before medicine, in the dispenser of insect pest initial stage of origination, 1 day, 3 days, 7 days investigation insect pest indexes after dispenser also calculate preventive effect.Result of the test is as follows:
Table 21 fluacrypyrim and active component B and the composite control tealeaves mite test of pesticide effectiveness thereof
As can be seen from Table 21, fluacrypyrim and active component B composite after can effectively prevent and treat tealeaves mite, control efficiency is all better than the preventive effect of single dose, and the preventive effect phase is long.In test scope of medication, target crop is had no adverse effects.
After draw through tests different local throughout the country, fluacrypyrim and azacyclotin, Bifenazate, fenbutatin oxide, fenpropathrin composite rear to the Tetranychus urticae on cereal crops, fruit tree, vegetables, flowers, fiber crop, legume crop, two spotted spider mite, Panonychus citri, peach fruit borer, tetranychus viennensis, tetranychid, knurl tick, blister mite, leaf miner, cotton bollworm, Shenmu-Yanan railway, Tetranychus cinnabarinus, cut the preventive effect of the common pests such as type tetranychid, acaphylla theae, tealeaves mite, tomato goitre mite, cabbage caterpillar all more than 95%, be better than single dose preventive effect, synergistic effect is obvious.
Claims (6)
1. a high-efficient pesticide composition, is characterized in that: effective active composition is active components A and active component B, and active components A and active component B weight ratio are 1 ︰ 80 ~ 60 ︰ 1, and described active components A is fluacrypyrim, and active component B is Bifenazate.
2. high-efficient pesticide composition according to claim 1, is characterized in that: the weight ratio of active components A and active component B is 1 ︰ 60 ~ 40 ︰ 1.
3. high-efficient pesticide composition according to claim 2, is characterized in that: the weight ratio of fluacrypyrim and Bifenazate is 1 ︰ 30 ~ 10 ︰ 1.
4. high-efficient pesticide composition as claimed in any of claims 1 to 3, is characterized in that: composition makes wetting powder, water dispersible granules, suspending agent, suspension emulsion, microemulsion, aqueous emulsion, microcapsule suspending agent, microcapsule suspension-suspendinagent agent.
5. high-efficient pesticide composition according to claim 4 is for preventing and treating the application of crop pests.
6. application according to claim 5, is characterized in that: described insect is Tetranychus urticae, two spotted spider mite, Panonychus citri, peach fruit borer, tetranychus viennensis, knurl tick, blister mite, leaf miner, cotton bollworm, Shenmu-Yanan railway, section type tetranychid, acaphylla theae, tealeaves mite, tomato goitre mite, cabbage caterpillar.
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| CN103651534A (en) * | 2013-12-30 | 2014-03-26 | 青岛崂乡茶制品有限公司 | Novel tea planting insecticide |
| CN104686542A (en) * | 2015-03-18 | 2015-06-10 | 山西绿海农药科技有限公司 | Fluacrypyrim composition containing ultralow-capacity liquid and preparation method thereof |
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5367093A (en) * | 1991-11-22 | 1994-11-22 | Uniroyal Chemical Company, Inc. | Insecticidal phenylhydrazine derivatives |
| CN1911033A (en) * | 2005-08-12 | 2007-02-14 | 南京第一农药有限公司 | Synergistic compound pesticide contg. high efficiency cypermethrin and pyrimidifen and its application |
| CN101228876A (en) * | 2007-12-27 | 2008-07-30 | 华南农业大学 | Nicouline and fluacrypyrim blending agrochemical |
-
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Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5367093A (en) * | 1991-11-22 | 1994-11-22 | Uniroyal Chemical Company, Inc. | Insecticidal phenylhydrazine derivatives |
| CN1911033A (en) * | 2005-08-12 | 2007-02-14 | 南京第一农药有限公司 | Synergistic compound pesticide contg. high efficiency cypermethrin and pyrimidifen and its application |
| CN101228876A (en) * | 2007-12-27 | 2008-07-30 | 华南农业大学 | Nicouline and fluacrypyrim blending agrochemical |
Non-Patent Citations (1)
| Title |
|---|
| "具有不同作用机理的杀螨剂";柏亚罗;《现代农药》;20050630;第4卷(第3期);第27-29页 * |
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