CN103416407B - A kind of composition pesticide - Google Patents
A kind of composition pesticide Download PDFInfo
- Publication number
- CN103416407B CN103416407B CN201210150747.6A CN201210150747A CN103416407B CN 103416407 B CN103416407 B CN 103416407B CN 201210150747 A CN201210150747 A CN 201210150747A CN 103416407 B CN103416407 B CN 103416407B
- Authority
- CN
- China
- Prior art keywords
- fluacrypyrim
- mite
- active component
- composition pesticide
- weight ratio
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 52
- 239000000575 pesticide Substances 0.000 title claims abstract description 34
- MXWAGQASUDSFBG-RVDMUPIBSA-N fluacrypyrim Chemical compound CO\C=C(\C(=O)OC)C1=CC=CC=C1COC1=CC(C(F)(F)F)=NC(OC(C)C)=N1 MXWAGQASUDSFBG-RVDMUPIBSA-N 0.000 claims abstract description 85
- 241000607479 Yersinia pestis Species 0.000 claims abstract description 29
- ZYHMJXZULPZUED-UHFFFAOYSA-N propargite Chemical compound C1=CC(C(C)(C)C)=CC=C1OC1C(OS(=O)OCC#C)CCCC1 ZYHMJXZULPZUED-UHFFFAOYSA-N 0.000 claims abstract description 27
- 239000005656 Fenazaquin Substances 0.000 claims abstract description 26
- 239000005658 Tebufenpyrad Substances 0.000 claims abstract description 26
- DMYHGDXADUDKCQ-UHFFFAOYSA-N fenazaquin Chemical compound C1=CC(C(C)(C)C)=CC=C1CCOC1=NC=NC2=CC=CC=C12 DMYHGDXADUDKCQ-UHFFFAOYSA-N 0.000 claims abstract description 26
- WIFXJBMOTMKRMM-UHFFFAOYSA-N halfenprox Chemical compound C=1C=C(OC(F)(F)Br)C=CC=1C(C)(C)COCC(C=1)=CC=CC=1OC1=CC=CC=C1 WIFXJBMOTMKRMM-UHFFFAOYSA-N 0.000 claims abstract description 26
- ZZYSLNWGKKDOML-UHFFFAOYSA-N tebufenpyrad Chemical compound CCC1=NN(C)C(C(=O)NCC=2C=CC(=CC=2)C(C)(C)C)=C1Cl ZZYSLNWGKKDOML-UHFFFAOYSA-N 0.000 claims abstract description 26
- 241001454293 Tetranychus urticae Species 0.000 claims description 33
- 241000238631 Hexapoda Species 0.000 claims description 32
- 239000000375 suspending agent Substances 0.000 claims description 31
- 241000488581 Panonychus citri Species 0.000 claims description 15
- 241000488533 Tetranychus viennensis Species 0.000 claims description 15
- 239000003094 microcapsule Substances 0.000 claims description 14
- 239000000839 emulsion Substances 0.000 claims description 12
- 229920000742 Cotton Polymers 0.000 claims description 9
- 241000239290 Araneae Species 0.000 claims description 8
- 206010018498 Goitre Diseases 0.000 claims description 8
- 235000007688 Lycopersicon esculentum Nutrition 0.000 claims description 8
- 240000003768 Solanum lycopersicum Species 0.000 claims description 8
- 241001454295 Tetranychidae Species 0.000 claims description 8
- 241000344246 Tetranychus cinnabarinus Species 0.000 claims description 8
- 239000003795 chemical substances by application Substances 0.000 claims description 8
- 201000003872 goiter Diseases 0.000 claims description 8
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims description 8
- 239000000725 suspension Substances 0.000 claims description 7
- 239000004530 micro-emulsion Substances 0.000 claims description 6
- 239000000843 powder Substances 0.000 claims description 6
- 239000004562 water dispersible granule Substances 0.000 claims description 6
- 238000009736 wetting Methods 0.000 claims description 6
- 230000002195 synergetic effect Effects 0.000 abstract description 24
- 239000003905 agrochemical Substances 0.000 abstract description 3
- 150000001875 compounds Chemical class 0.000 abstract description 3
- 238000003912 environmental pollution Methods 0.000 abstract description 2
- 230000000749 insecticidal effect Effects 0.000 abstract description 2
- 238000001228 spectrum Methods 0.000 abstract description 2
- 238000012360 testing method Methods 0.000 description 46
- 239000002131 composite material Substances 0.000 description 43
- 239000003814 drug Substances 0.000 description 42
- 230000003449 preventive effect Effects 0.000 description 25
- 230000010165 autogamy Effects 0.000 description 21
- 241000488583 Panonychus ulmi Species 0.000 description 14
- 239000013530 defoamer Substances 0.000 description 14
- 239000002270 dispersing agent Substances 0.000 description 14
- 238000011835 investigation Methods 0.000 description 14
- 239000012071 phase Substances 0.000 description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 13
- 239000008367 deionised water Substances 0.000 description 11
- 229910021641 deionized water Inorganic materials 0.000 description 11
- 239000003995 emulsifying agent Substances 0.000 description 10
- 239000002904 solvent Substances 0.000 description 10
- 239000000080 wetting agent Substances 0.000 description 10
- 230000002528 anti-freeze Effects 0.000 description 9
- 230000000694 effects Effects 0.000 description 9
- 239000002562 thickening agent Substances 0.000 description 9
- 229940079593 drug Drugs 0.000 description 8
- 231100000820 toxicity test Toxicity 0.000 description 8
- 206010067482 No adverse event Diseases 0.000 description 7
- 240000001987 Pyrus communis Species 0.000 description 7
- 235000014443 Pyrus communis Nutrition 0.000 description 7
- OARRHUQTFTUEOS-UHFFFAOYSA-N safranin Chemical compound [Cl-].C=12C=C(N)C(C)=CC2=NC2=CC(C)=C(N)C=C2[N+]=1C1=CC=CC=C1 OARRHUQTFTUEOS-UHFFFAOYSA-N 0.000 description 7
- 244000141359 Malus pumila Species 0.000 description 6
- 235000011430 Malus pumila Nutrition 0.000 description 6
- 235000015103 Malus silvestris Nutrition 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- 239000003381 stabilizer Substances 0.000 description 6
- 241001672694 Citrus reticulata Species 0.000 description 5
- 206010011732 Cyst Diseases 0.000 description 5
- 239000008346 aqueous phase Substances 0.000 description 5
- 208000031513 cyst Diseases 0.000 description 5
- 229920002521 macromolecule Polymers 0.000 description 5
- 238000002360 preparation method Methods 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- 239000000642 acaricide Substances 0.000 description 4
- 238000004458 analytical method Methods 0.000 description 4
- 235000013399 edible fruits Nutrition 0.000 description 4
- 238000002474 experimental method Methods 0.000 description 4
- 239000000945 filler Substances 0.000 description 4
- 230000002045 lasting effect Effects 0.000 description 4
- 231100000636 lethal dose Toxicity 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 239000003002 pH adjusting agent Substances 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- 231100000419 toxicity Toxicity 0.000 description 4
- 230000001988 toxicity Effects 0.000 description 4
- 235000013311 vegetables Nutrition 0.000 description 4
- 241000196324 Embryophyta Species 0.000 description 3
- 238000000498 ball milling Methods 0.000 description 3
- 239000011230 binding agent Substances 0.000 description 3
- 235000013339 cereals Nutrition 0.000 description 3
- 239000000835 fiber Substances 0.000 description 3
- 235000021374 legumes Nutrition 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 230000000361 pesticidal effect Effects 0.000 description 3
- 239000002574 poison Substances 0.000 description 3
- 231100000614 poison Toxicity 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 239000004094 surface-active agent Substances 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 102000002322 Egg Proteins Human genes 0.000 description 2
- 108010000912 Egg Proteins Proteins 0.000 description 2
- ZHNUHDYFZUAESO-UHFFFAOYSA-N Formamide Chemical compound NC=O ZHNUHDYFZUAESO-UHFFFAOYSA-N 0.000 description 2
- 239000013543 active substance Substances 0.000 description 2
- 230000008485 antagonism Effects 0.000 description 2
- 239000007884 disintegrant Substances 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 231100000225 lethality Toxicity 0.000 description 2
- 210000004681 ovum Anatomy 0.000 description 2
- 231100000572 poisoning Toxicity 0.000 description 2
- 230000000607 poisoning effect Effects 0.000 description 2
- 239000002728 pyrethroid Substances 0.000 description 2
- 210000002784 stomach Anatomy 0.000 description 2
- 230000001018 virulence Effects 0.000 description 2
- -1 2-(4-tert-butyl benzene oxy) cyclohexyl Propargyl sulfite Chemical compound 0.000 description 1
- 241000207199 Citrus Species 0.000 description 1
- ACTIUHUUMQJHFO-UHFFFAOYSA-N Coenzym Q10 Natural products COC1=C(OC)C(=O)C(CC=C(C)CCC=C(C)CCC=C(C)CCC=C(C)CCC=C(C)CCC=C(C)CCC=C(C)CCC=C(C)CCC=C(C)CCC=C(C)C)=C(C)C1=O ACTIUHUUMQJHFO-UHFFFAOYSA-N 0.000 description 1
- 241000258937 Hemiptera Species 0.000 description 1
- 244000269722 Thea sinensis Species 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000000895 acaricidal effect Effects 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 238000012271 agricultural production Methods 0.000 description 1
- 229940111121 antirheumatic drug quinolines Drugs 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 210000004027 cell Anatomy 0.000 description 1
- 210000000349 chromosome Anatomy 0.000 description 1
- 235000020971 citrus fruits Nutrition 0.000 description 1
- ACTIUHUUMQJHFO-UPTCCGCDSA-N coenzyme Q10 Chemical compound COC1=C(OC)C(=O)C(C\C=C(/C)CC\C=C(/C)CC\C=C(/C)CC\C=C(/C)CC\C=C(/C)CC\C=C(/C)CC\C=C(/C)CC\C=C(/C)CC\C=C(/C)CCC=C(C)C)=C(C)C1=O ACTIUHUUMQJHFO-UPTCCGCDSA-N 0.000 description 1
- 235000017471 coenzyme Q10 Nutrition 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000002552 dosage form Substances 0.000 description 1
- 230000000857 drug effect Effects 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 230000004907 flux Effects 0.000 description 1
- 238000005469 granulation Methods 0.000 description 1
- 230000003179 granulation Effects 0.000 description 1
- 230000012447 hatching Effects 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 239000002917 insecticide Substances 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 210000003470 mitochondria Anatomy 0.000 description 1
- 239000012452 mother liquor Substances 0.000 description 1
- 231100000194 ovacidal Toxicity 0.000 description 1
- 230000003151 ovacidal effect Effects 0.000 description 1
- 239000000825 pharmaceutical preparation Substances 0.000 description 1
- 244000144977 poultry Species 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 150000003248 quinolines Chemical class 0.000 description 1
- NPCOQXAVBJJZBQ-UHFFFAOYSA-N reduced coenzyme Q9 Natural products COC1=C(O)C(C)=C(CC=C(C)CCC=C(C)CCC=C(C)CCC=C(C)CCC=C(C)CCC=C(C)CCC=C(C)CCC=C(C)CCC=C(C)C)C(O)=C1OC NPCOQXAVBJJZBQ-UHFFFAOYSA-N 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 238000000967 suction filtration Methods 0.000 description 1
- 235000013616 tea Nutrition 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 229940035936 ubiquinone Drugs 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a kind of composition pesticide, composition pesticide containing active components A and active component B, active components A is selected from fluacrypyrim, active component B is selected from any one compound following: tebufenpyrad, propargite, fenazaquin, halfenprox, and the weight ratio of active components A and active component B is 1 ︰ 70 ~ 70 ︰ 1.The present composition can prevent and treat various pests, and has obvious synergistic effect, expands insecticidal spectrum, and can reduce pesticide usage amount, reduces the residual quantity of agricultural chemicals on crop, alleviates environmental pollution.<!--1-->
Description
Technical field
The invention belongs to technical field of pesticide, relate to the application of a kind of composition pesticide on crop pest.
Technical background
Fluacrypyrim (Fluacrypyrim) chemical name: methyl (E)-2-{ α-[2-isopropoxy-6-(trifluoromethyl) pyrimidine-4-phenoxy group]-0-tolyl }-3-methoxy acrylate, molecular formula: C
20h
21f
3n
2o
5.Fluacrypyrim is first methoxy acrylic miticide.Have and well tag and stomach poison function, to each feature of evil mite, if comprise ovum mite, one-tenth mite all effectively, and quick-acting is good, and the lasting period reaches more than 30 days.
Tebufenpyrad (Tebufenpyrad) chemical name: N-(4-tertiary butyl benzyl) the chloro-3-ethyl of-4--1-methylpyrazole-5-base formamide, molecular formula: C
18h
24cLN
3o.Belong to amide-type miticide.To various mite class and Semiptera, homoptera pest, there is tall and erect effect, and the dawn all to have immediate effect each vegetative period to mite class and efficiently, the lasting period is long.Without interior absorption, but there is osmotically active, have splendid selectivity to target crop.
Propargite (Propargite) chemical name: 2-(4-tert-butyl benzene oxy) cyclohexyl Propargyl sulfite, molecular formula: C
19h
26o
4s.Low toxicity broad spectrum activity organosulfur acaricide, has and tags and stomach poison function, without interior suction and infiltration conduction, if effective to one-tenth mite mite, the weak effect of ovicidal, this medicine drug effect under temperature more than 20 DEG C conditions can improve, but fall progressively with low temperature below 20 DEG C, propargite can be used for preventing and treating cotton, vegetables, apple, citrus, tea, the harmful mite of the various crop such as flowers, safer to most natural enemy, but want strict controlled concentration when using on tender little crop, too high easy generation poisoning.
Fenazaquin (Fenazaquin) chemical name: 4-spy-butyl benzene ethyl quinazoline-4-base ether, molecular formula: C
20h
22n
2o.It belongs to quinolines miticide, and by action of contace poison in the mitochondria of insect cell and chromosome set I, there is good control efficiency at the abutment occupying ubiquinone to mandarin tree, apple tree two spotted spider mite, and the lasting period is long, to natural enemies security.
Halfenprox (Halfenprox) chemical name: 2-(4-bromine difluoro-methoxy phenyl)-2-methyl-propyl-3-phenoxy benzyl ether, belong to non-pyrethroid medicament, but its space structure and pyrethroid there is similarity.This product is a kind of broad spectrum activity, if to young mite mite with to become mite down effect good, the hatching of ovum can also be suppressed, to evil mite resistant strain and sensitive strain all effective, under normal using dosage to fruit tree without poisoning.
But in the real process of agricultural production, the problem that pest control the most easily produces is the generation of pest resistance to insecticide.Different cultivars composition carries out composite, is to prevent and treat the very common method of resistant insect.Heterogeneity is carried out composite, according to practical application effect, judge certain composite be synergy, add and or antagonism.In most cases, the composite effect of agricultural chemicals is all additive effect, really has the seldom composite of synergistic effect, especially synergistic effect clearly, very high composite just less of co-toxicity coefficient.Through inventor's research, find fluacrypyrim and tebufenpyrad, propargite, fenazaquin, halfenprox is composite after can produce good synergistic effect, and not yet open about the relevant report that fluacrypyrim and tebufenpyrad, propargite, fenazaquin, halfenprox are composite.
Summary of the invention
The object of the invention is to propose a kind of to there is synergistic function, use cost is low, preventive effect is good composition pesticide.
A kind of composition pesticide, containing active components A and active component B, active components A and active component B weight ratio are 1 ︰ 70 ~ 70 ︰ 1, and described active components A is selected from fluacrypyrim, and active component B is selected from the one in tebufenpyrad, propargite, fenazaquin, halfenprox; Active components A and the preferred weight ratio of active component B are 1 ︰ 50 ~ 50 ︰ 1; The weight ratio being more preferably fluacrypyrim and tebufenpyrad is 1 ︰ 20 ~ 20 ︰ 1; The weight ratio of fluacrypyrim and propargite is 1 ︰ 25 ~ 5 ︰ 1; The weight ratio of fluacrypyrim and fenazaquin is 1 ︰ 20 ~ 30 ︰ 1; The weight ratio of fluacrypyrim and halfenprox is 1 ︰ 10 ~ 20 ︰ 1.
Described composition pesticide can be made into wetting powder, water dispersible granules, suspending agent, suspension emulsion, aqueous emulsion, microemulsion, microcapsule suspending agent, microcapsule suspension-suspendinagent agent.
Described composition pesticide is for preventing and treating the application of insect on cereal crop, fruit tree, vegetables, fiber crop, ornamental plants, legume crop.
Described insect comprises two spotted spider mite, Panonychus citri, tetranychus viennensis, Tetranychus urticae, yellow spider, knurl tick, blister mite, Shenmu-Yanan railway, Tetranychus cinnabarinus, tealeaves mite, tomato goitre mite, rust mite, cotton spider mites, tetranychus telarius.
In the present composition, the content of active component depends on amount of application when being used alone, and also depends on mixed ratio and the synergistic effect degree of a kind of compound and another kind of compound, simultaneously also relevant with target pest.In usual composition, the weight percentage of active component is 2% ~ 90% of gross weight, is preferably 5% ~ 80%.According to different preparation types, active component content scope is different.Usually, liquid preparation contains the active substance of by weight 1% ~ 60%, is preferably 5% ~ 50%; Solid pharmaceutical preparation contains the active substance of by weight 5% ~ 80%, is preferably 10% ~ 80%.
At least containing a kind of surfactant in Pesticidal combination of the present invention, the dispersion of active component in water when being beneficial to use.Surface-active contents is 2% ~ 30% of total formulation weight amount, and surplus is solid or liquid diluent.
Surfactant selected by Pesticidal combination of the present invention is known in those skilled in the art: can be selected from one or more in dispersant, wetting agent, thickener or defoamer.According to different dosage form, in preparation, stabilizing agent known in those skilled in the art, antifreeze etc. can also be contained.
Pesticidal combination of the present invention can by user before use through diluting or directly using.Its preparation can be prepared by processing method known in those skilled in the art, after mixing, then adds surfactant as one or more in dispersant, stabilizing agent, wetting agent, binding agent, defoamer etc. by active component with liquid flux or solid carrier.
Composition comprises following component and content when making wetting powder: active components A 1% ~ 70%, active component B1% ~ 70%, dispersant 1% ~ 12%, wetting agent 1% ~ 8%, filler surplus.
Composition comprises following component and content when making water dispersible granules: active components A 1% ~ 70%, active component B1% ~ 70%, dispersant 1% ~ 12%, wetting agent 1% ~ 8%, disintegrant 1% ~ 10%, binding agent 0 ~ 8%, filler surplus.
Composition comprises following component and content when making suspending agent: active components A 1% ~ 50%, active component B1% ~ 50%, dispersant 1% ~ 10%, wetting agent 1% ~ 10%, defoamer 0.01% ~ 2%, thickener 0 ~ 2%, antifreeze 0 ~ 8%, deionized water add to 100%.
Composition comprises following component and content when making suspension emulsion: active components A 1% ~ 50%, active component B1% ~ 50%, emulsifier 1% ~ 10%, dispersant 1% ~ 10%, solvent 0 ~ 20%, defoamer 0.01% ~ 2%, thickener 0 ~ 2%, antifreeze 0 ~ 8%, stabilizing agent 0 ~ 3%, deionized water add to 100%.
Composition comprises following component and content when making microemulsion: active components A 1% ~ 50%, active component B1% ~ 50%, emulsifier 3% ~ 25%, solvent 1% ~ 10%, antifreeze 0 ~ 8%, stabilizing agent 0 ~ 3%, defoamer 0.01% ~ 2%, deionized water add to 100%.
Composition comprises following component and content when making aqueous emulsion: active components A 1% ~ 50%, active component B1% ~ 50%, solvent 1% ~ 20%, emulsifier 1% ~ 12%, antifreeze 0 ~ 8%, defoamer 0.01% ~ 2%, thickener 0 ~ 2%, deionized water add to 100%.
Composition comprises following component and content when making microcapsule suspending agent: active components A 1% ~ 50%, active component B1% ~ 50%, macromolecule cyst material 1% ~ 10%, dispersant 2% ~ 10%, solvent 1% ~ 10%, emulsifier 1% ~ 7%, pH adjusting agent 0.01% ~ 5%, defoamer 0.01% ~ 2%, deionized water add to 100%.
Composition comprises following component and content when making microcapsule suspension-suspendinagent agent: active components A 1% ~ 50%, active component B1% ~ 50%, macromolecule cyst material 1% ~ 12%, dispersant 1%-12%, wetting agent 1%-8%, solvent 1% ~ 15%, emulsifier 1% ~ 8%, defoamer 0.01% ~ 2%, thickener 0 ~ 2%, pH adjusting agent 0.01% ~ 5%, deionized water add to 100%.
Wetting powder the key technical indexes of the present invention:
Water dispersible granules the key technical indexes of the present invention:
Suspending agent the key technical indexes of the present invention:
Suspension emulsion the key technical indexes of the present invention:
Microemulsion the key technical indexes of the present invention:
Aqueous emulsion the key technical indexes of the present invention:
Microcapsule suspending agent the key technical indexes of the present invention:
Microcapsule suspension-suspendinagent agent the key technical indexes of the present invention:
The invention has the advantages that:
(1) present composition has good synergy and lasting effect within the specific limits, and preventive effect higher than single dose, thus reduces pesticide usage amount, while minimizing peasant drug cost, reduces the residual quantity of agricultural chemicals on crop, alleviates environmental pollution; (2) between kind, structure difference is comparatively large, thus the resistance that can delay single dose occurs and development; (3) expand insecticidal spectrum, have greater activity to the two spotted spider mite on cereal crop, fruit tree, vegetables, fiber crop, ornamental plants, legume crop, Panonychus citri, tetranychus viennensis, Tetranychus urticae, yellow spider, knurl tick, blister mite, Shenmu-Yanan railway, Tetranychus cinnabarinus, tealeaves mite, tomato goitre mite, rust mite, cotton spider mites, tetranychus telarius; (4) to person poultry safety, Environmental compatibility is good; And preparation adhesion strength strengthens, resistance of rainwater washing against.
Embodiment
Below in conjunction with embodiment to further instruction of the present invention, the percentage in embodiment is all weight percentage, but the present invention is not limited thereto.
Application Example one
Example 1 ~ 12 wetting powder
By fluacrypyrim, active component B, dispersant, wetting agent, filler mixing, mix in mixed cylinder, mix again after airslide disintegrating mill is pulverized, namely can be made into wetting powder product of the present invention.Specifically in table 1.
The each component of table 1 example 1 ~ 12 and content
Example 13 ~ 24 water dispersible granules
Fluacrypyrim, active component B, dispersant, wetting agent, binding agent (can add and can not add), disintegrant, filler are obtained together the particle diameter of needs through air-flow crushing, obtain granulation materials.Item is quantitatively sent in fluidized bed granulating dryer through granulating and after drying, obtaining water dispersible granules product of the present invention.Specifically in table 2.
The each component of table 2 example 13 ~ 24 and content
Example 25 ~ 34 suspending agent
Dispersant, wetting agent, defoamer, thickener (can add and can not add), antifreeze (can add and can not add) are mixed through high speed shear, add fluacrypyrim, active component B, surplus deionized water is supplied, ball milling 2 ~ 3 hours in ball mill, make diameter of particle all below 5 μm, obtained suspending agent product of the present invention.Specifically in table 3.
The each component of table 3 example 25 ~ 34 and content
Example 35 ~ 46 suspension emulsion
By dispersant, defoamer, thickener (can add and can not add), antifreeze (can add and can not add), stabilizing agent (can add and can not add), mix through high speed shear, add fluacrypyrim, ball milling 2 ~ 3 hours in ball mill, make diameter of particle all below 5 μm, obtained fluacrypyrim suspending agent, then by active component B, solvent (can add and can not add), emulsifier and the direct emulsification of various auxiliary agent high speed agitators in suspending agent, obtained suspension emulsion product of the present invention.Specifically in table 4,5.
The each component of table 4 example 35 ~ 40 and content
The each component of table 5 example 41 ~ 46 and content
Example 47 ~ 58 aqueous emulsion
Fluacrypyrim, active component B, solvent, emulsifier are added together, make to be dissolved into homogeneous oil phase; Deionized water, antifreeze (can add and can not add), thickener (can add and can not add), defoamer are mixed, becomes homogeneous aqueous phase.Under high velocity agitation, aqueous phase is added oil phase, obtained aqueous emulsion product of the present invention.Specifically in table 6,7.
The each component of table 6 example 47 ~ 52 and content
The each component of table 7 example 53 ~ 58 and content
Example 59 ~ 62 microemulsion
Fluacrypyrim, active component B are dissolved in and are equipped with in the homogenizer of solvent, emulsifier, antifreeze (can add and can not add), defoamer, stabilizing agent (can add and can not add) are joined in the homogenizer that above-mentioned solution is housed, surplus deionized water gives strong mixing and homogenize after supplying, finally obtain the microemulsion product of the present invention that clear appearance is transparent.Specifically in table 8.
The each component of table 8 example 59 ~ 62 and content
Tebufenpyrad, propargite, fenazaquin, halfenprox in table 1 to table 8 are exchanged, can novel formulation be obtained.
Example 63 ~ 65 microcapsule suspending agent
By fluacrypyrim, active component B, macromolecule cyst material, solvent, make to be dissolved into homogeneous oil phase, in a shear condition, oil phase is joined in the aqueous phase solution containing emulsifier, pH adjusting agent, dispersant, defoamer, surplus deionized water is supplied, bi-material reacts at oil-water interfaces, forms macromolecule cyst wall, makes the finely disseminated microcapsule suspending agent product of the present composition.Specifically in table 9.
The each component of table 9 example 63 ~ 65 and content
Example 66 ~ 68 microcapsule suspension-suspendinagent agent
By active component B, macromolecule cyst material, solvent, make to be dissolved into homogeneous oil phase, oil phase is joined in a shear condition in the aqueous phase solution containing emulsifier, pH adjusting agent, make finely disseminated microcapsule suspending agent.Dispersant, wetting agent, defoamer, thickener (can add and can not add) are mixed through high speed shear, add fluacrypyrim, ball milling 2 ~ 3 hours in ball mill, make diameter of particle all below 5 μm, obtained suspending agent, then join in the aqueous phase solution of micro-capsule suspension by suspending agent, deionized water supplies surplus, makes the finely disseminated microcapsule suspension-suspendinagent agent product of the present composition.Specifically in table 10.
The each component of table 10 example 66 ~ 68 and content
The embodiment of the present invention is the method adopting Toxicity Determination and field trial to combine.First pass through Toxicity Determination, co-toxicity coefficient (CTC) after clear and definite two kinds of medicaments are composite by a certain percentage, CTC < 80 is antagonism, 80≤CTC≤120 are summation action, CTC > 120 is synergistic effect, on this basis, then carry out field trial.
Test method: respectively the mother liquor of each mixed agent is diluted to five series concentration during test, is placed in beaker respectively for subsequent use.Adopt the method connecing worm after first soaking leaf, take out after the blade of the same size not contacting any medicament is soaked 5s in the liquid configured, naturally dry, put into insect box, then connect for examination larva, raise under 25 DEG C of conditions, often process and repeat for 3 times, often repeating examination borer population used is 50, establishes blank simultaneously, checks dead borer population in 72h, calculate lethality and corrected mortality, try to achieve virulence regression equation and calculate LC
50value.If contrast lethality is greater than 10%, be then considered as invalid test.Computing formula is as follows:
Insect corrected mortality is converted into probit value (y), and concentration for the treatment of (μ g/ml) converts logarithm value to (x), draws virulence regression equation, and calculate the value of often kind of medicament thus with method of least squares.Co-toxicity coefficient CTC is calculated according to the abundant equation of Sun Yun.Computing formula following (take fluacrypyrim as standard agent, its toxicity index is 100):
TI × the P of theoretical toxicity index (the TTI)=fluacrypyrim of M
fluacrypyrimtI × the P of+active component B
effective active composition B
In formula: M is the mixture of different ratio
P
effective active composition Bfor the ratio that effective active composition B is shared in the composition
P
fluacrypyrimfor the ratio that fluacrypyrim is shared in the composition
B is selected from the one in tebufenpyrad, propargite, fenazaquin, halfenprox.
Application Example two:
For examination insect: panonychus ulmi.
Test medicine provides by Shaanxi Meibang Pesticide Co., Ltd..
Experimental scheme: through effective lethal concentration scope of preliminary experiment determination fluacrypyrim and the former medicine of tebufenpyrad and the two different ratio mixture.
Toxicity test result
Table 11 fluacrypyrim and the composite toxicity test analysis of results table to panonychus ulmi of tebufenpyrad
As shown in Table 11, the proportioning of fluacrypyrim and the composite control panonychus ulmi of tebufenpyrad is when 1 ︰ 70 ~ 70 ︰ 1, co-toxicity coefficient is all greater than 120, both explanations mixture in 1 ︰ 70 ~ 70 ︰ 1 scope all shows synergistic effect, when the proportioning of fluacrypyrim and tebufenpyrad is at 1 ︰ 20 ~ 20 ︰ 1, synergistic effect is more outstanding, and co-toxicity coefficient is all greater than 220, wherein when fluacrypyrim and tebufenpyrad weight ratio are 1 ︰ 1, co-toxicity coefficient is maximum, and synergistic effect is the most obvious.Testing through applicant the proportioning finding fluacrypyrim and tebufenpyrad is 20:1, 15:1, 10:1, 9:1, 8:1, 7:1, 6:1, 5:1, 4:1, 3:1, 2:1, 1:1, 1:2, 1:3, 1:4, 1:5, 1:6, 1:7, 1:8, 1:9, 1:10, 1:15, during 1:20, fluacrypyrim and tebufenpyrad composite to two spotted spider mite, Panonychus citri, tetranychus viennensis, Tetranychus urticae, yellow spider, knurl tick, blister mite, Shenmu-Yanan railway, Tetranychus cinnabarinus, tealeaves mite, tomato goitre mite, rust mite, cotton spider mites, the control of tetranychus telarius has obvious synergistic effect, co-toxicity coefficient is all greater than 120.
Application Example three:
For examination insect: cotton red spider.
Test medicine provides by Shaanxi Meibang Pesticide Co., Ltd..
Experimental scheme: through effective lethal concentration scope of preliminary experiment determination fluacrypyrim and propargite medicine and the two different ratio mixture.
Toxicity test result
Table 12 fluacrypyrim and the composite toxicity test analysis of results table to cotton red spider of propargite
As shown in Table 12, the proportioning of fluacrypyrim and the composite control cotton red spider of propargite is when 1 ︰ 70 ~ 70 ︰ 1, co-toxicity coefficient is all greater than 120, both explanations mixture in 1 ︰ 70 ~ 70 ︰ 1 scope all shows synergistic effect, when the proportioning of fluacrypyrim and propargite is at 1 ︰ 25 ~ 5 ︰ 1, synergistic effect is more outstanding, and co-toxicity coefficient is all greater than 220, wherein when fluacrypyrim and propargite weight ratio are 1 ︰ 5, co-toxicity coefficient is maximum, and synergistic effect is the most obvious.Testing through applicant the proportioning finding fluacrypyrim and propargite is 5:1, 4:1, 3:1, 2:1, 1:1, 1:2, 2:5, 1:3, 1:4, 1:5, 1:6, 1:7, 1:8, 1:9, 1:10, 1:11, 1:12, 1:13, 1:14, 1:15, 1:20, during 1:25, fluacrypyrim and propargite composite to two spotted spider mite, Panonychus citri, tetranychus viennensis, Tetranychus urticae, yellow spider, knurl tick, blister mite, Shenmu-Yanan railway, Tetranychus cinnabarinus, tealeaves mite, tomato goitre mite, rust mite, cotton spider mites, the control of tetranychus telarius has obvious synergistic effect, co-toxicity coefficient is all greater than 120.
Application Example four:
For examination insect: citrus red mite.
Test medicine provides by Shaanxi Meibang Pesticide Co., Ltd..
Experimental scheme: through effective lethal concentration scope of preliminary experiment determination fluacrypyrim and the former medicine of fenazaquin and the two different ratio mixture.
Toxicity test result
Table 13 fluacrypyrim and the composite toxicity test analysis of results table to citrus red mite of fenazaquin
As shown in Table 13, fluacrypyrim and the composite proportioning of preventing and treating citrus red mite of fenazaquin are when 1 ︰ 70 ~ 70 ︰ 1, co-toxicity coefficient is all greater than 120, both explanations mixture in 1 ︰ 70 ~ 70 ︰ 1 scope all shows synergistic effect, when the proportioning of fluacrypyrim and fenazaquin is at 1 ︰ 20 ~ 30 ︰ 1, synergistic effect is more outstanding, and co-toxicity coefficient is all greater than 220, wherein when fluacrypyrim and fenazaquin weight ratio are 3 ︰ 2, co-toxicity coefficient is maximum, and synergistic effect is the most obvious.Testing through applicant the proportioning finding fluacrypyrim and fenazaquin is 30:1, 25:1, 20:1, 15:1, 10:1, 9:1, 8:1, 7:1, 6:1, 5:1, 4:1, 3:1, 2:1, 3:2, 1:1, 1:2, 1:3, 1:4, 1:5, 1:10, 1:15, during 1:20, fluacrypyrim and fenazaquin composite to two spotted spider mite, Panonychus citri, tetranychus viennensis, Tetranychus urticae, yellow spider, knurl tick, blister mite, Shenmu-Yanan railway, Tetranychus cinnabarinus, tealeaves mite, tomato goitre mite, rust mite, cotton spider mites, the control of tetranychus telarius has obvious synergistic effect, co-toxicity coefficient is all greater than 120.
Application Example five:
For examination insect: pear tree tetranychus viennensis.
Test medicine provides by Shaanxi Meibang Pesticide Co., Ltd..
Experimental scheme: through effective lethal concentration scope of preliminary experiment determination fluacrypyrim and the former medicine of halfenprox and the two different ratio mixture.
Toxicity test result
Table 14 fluacrypyrim and the composite toxicity test analysis of results table to pear tree tetranychus viennensis of halfenprox
As shown in Table 14, fluacrypyrim and the composite proportioning of preventing and treating pear tree tetranychus viennensis of halfenprox are when 1 ︰ 70 ~ 70 ︰ 1, co-toxicity coefficient is all greater than 120, both explanations mixture in 1 ︰ 70 ~ 70 ︰ 1 scope all shows synergistic effect, when the proportioning of fluacrypyrim and halfenprox is at 1 ︰ 10 ~ 20 ︰ 1, synergistic effect is more outstanding, and co-toxicity coefficient is all greater than 225, wherein when fluacrypyrim and halfenprox weight ratio are 2 ︰ 1, co-toxicity coefficient is maximum, and synergistic effect is the most obvious.Testing through applicant the proportioning finding fluacrypyrim and halfenprox is 20:1, 15:1, 10:1, 9:1, 8:1, 7:1, 6:1, 5:1, 4:1, 3:1, 2:1, 1:1, 1:2, 1:3, 1:4, 1:5, 1:6, 1:7, 1:8, 1:9, during 1:10, fluacrypyrim and halfenprox composite to two spotted spider mite, Panonychus citri, tetranychus viennensis, Tetranychus urticae, yellow spider, knurl tick, blister mite, Shenmu-Yanan railway, Tetranychus cinnabarinus, tealeaves mite, tomato goitre mite, rust mite, cotton spider mites, the control of tetranychus telarius has obvious synergistic effect, co-toxicity coefficient is all greater than 120.
Application Example six fluacrypyrim and active component B and the composite control citrus red mite test of pesticide effectiveness thereof
This experimental establishment is at Shaanxi Province's Hanzhong City, test medicine is researched and developed by Shaanxi Meibang Pesticide Co., Ltd., is provided, contrast medicament 30% fluacrypyrim suspending agent (autogamy), 30% tebufenpyrad suspending agent (autogamy), 40% propargite missible oil (commercial), 95g/L fenazaquin missible oil (commercial), 20% halfenprox missible oil (autogamy).
Investigation citrus red mite insect pest index before medicine, in the dispenser of insect pest initial stage of origination, 10 days, 30 days, 45 days investigation insect pest indexes after dispenser also calculate preventive effect.Result of the test is as follows:
Table 15 fluacrypyrim and active component B and the composite control citrus red mite test of pesticide effectiveness thereof
As can be seen from Table 15, fluacrypyrim and active component B composite after effectively can prevent and treat citrus red mite, control efficiency is all better than the preventive effect of single dose, and the preventive effect phase is long.In test scope of medication, target crop is had no adverse effects.
Application Example seven fluacrypyrim and active component B and the composite control panonychus ulmi test of pesticide effectiveness thereof
This experimental establishment is in Xianyang, Shanxi province city, test medicine is researched and developed by Shaanxi Meibang Pesticide Co., Ltd., is provided, contrast medicament 30% fluacrypyrim suspending agent (autogamy), 30% tebufenpyrad suspending agent (autogamy), 40% propargite missible oil (commercial), 95g/L fenazaquin missible oil (commercial), 20% halfenprox missible oil (autogamy).
Investigation panonychus ulmi insect pest index before medicine, in the dispenser of insect pest initial stage of origination, 10 days, 30 days, 45 days investigation insect pest indexes after dispenser also calculate preventive effect.Result of the test is as follows:
Table 16 fluacrypyrim and active component B and the composite control panonychus ulmi test of pesticide effectiveness thereof
As can be seen from Table 16, fluacrypyrim and active component B composite after effectively can prevent and treat panonychus ulmi, control efficiency is all better than the preventive effect of single dose, and the preventive effect phase is long.In test scope of medication, target crop is had no adverse effects.
Application Example eight fluacrypyrim and active component B and the composite control flowers two spotted spider mite test of pesticide effectiveness thereof
This experimental establishment is in Changan District, Xi'an City, Shanxi Province, test medicine is researched and developed by Shaanxi Meibang Pesticide Co., Ltd., is provided, contrast medicament 30% fluacrypyrim suspending agent (autogamy), 30% tebufenpyrad suspending agent (autogamy), 40% propargite missible oil (commercial), 95g/L fenazaquin missible oil (commercial), 20% halfenprox missible oil (autogamy).
Investigation flowers two spotted spider mite insect pest index before medicine, in the dispenser of insect pest initial stage of origination, 10 days, 30 days, 45 days investigation insect pest indexes after dispenser also calculate preventive effect.Result of the test is as follows:
Table 17 fluacrypyrim and active component B and the composite control flowers two spotted spider mite test of pesticide effectiveness thereof
As can be seen from Table 17, fluacrypyrim and active component B composite after can effectively prevent and treat flowers two spotted spider mite, control efficiency is all better than the preventive effect of single dose, and the preventive effect phase is long.In test scope of medication, target crop is had no adverse effects.
Application Example nine fluacrypyrim and active component B and the composite control pear tree tetranychus viennensis test of pesticide effectiveness thereof
This experimental establishment is in Xianyang, Shanxi province city, test medicine is researched and developed by Shaanxi Meibang Pesticide Co., Ltd., is provided, contrast medicament 30% fluacrypyrim suspending agent (autogamy), 30% tebufenpyrad suspending agent (autogamy), 40% propargite missible oil (commercial), 95g/L fenazaquin missible oil (commercial), 20% halfenprox missible oil (autogamy).
Investigation pear tree tetranychus viennensis insect pest index before medicine, in the dispenser of insect pest initial stage of origination, 10 days, 30 days, 45 days investigation insect pest indexes after dispenser also calculate preventive effect.Result of the test is as follows:
Table 18 fluacrypyrim and active component B and the composite control pear tree tetranychus viennensis test of pesticide effectiveness thereof
As can be seen from Table 18, fluacrypyrim and active component B composite after can effectively prevent and treat pear tree tetranychus viennensis, control efficiency is all better than the preventive effect of single dose, and the preventive effect phase is long.In test scope of medication, target crop is had no adverse effects.
Application Example ten fluacrypyrim and active component B and the composite control cotton red spider test of pesticide effectiveness thereof
This experimental establishment is in Weinan City Dali County, Shaanxi Province, test medicine is researched and developed by Shaanxi Meibang Pesticide Co., Ltd., is provided, contrast medicament 30% fluacrypyrim suspending agent (autogamy), 30% tebufenpyrad suspending agent (autogamy), 40% propargite missible oil (commercial), 95g/L fenazaquin missible oil (commercial), 20% halfenprox missible oil (autogamy).
Insect pest index before medicine, in the dispenser of insect pest initial stage of origination, 10 days, 30 days, 45 days investigation insect pest indexes after dispenser also count investigation cotton red spider calculation preventive effect.Result of the test is as follows:
Table 19 fluacrypyrim and active component B and the composite control cotton red spider test of pesticide effectiveness thereof
As can be seen from Table 19, fluacrypyrim and active component B composite after effectively can prevent and treat cotton red spider, control efficiency is all better than the preventive effect of single dose, and the preventive effect phase is long.In test scope of medication, target crop is had no adverse effects.
Application Example 11 fluacrypyrim and active component B and the composite control oranges and tangerines blister mite test of pesticide effectiveness thereof
This experimental establishment is at Shaanxi Province's Hanzhong City, test medicine is researched and developed by Shaanxi Meibang Pesticide Co., Ltd., is provided, contrast medicament 30% fluacrypyrim suspending agent (autogamy), 30% tebufenpyrad suspending agent (autogamy), 40% propargite missible oil (commercial), 95g/L fenazaquin missible oil (commercial), 20% halfenprox missible oil (autogamy).
Investigation oranges and tangerines blister mite insect pest index before medicine, in the dispenser of insect pest initial stage of origination, 10 days, 30 days, 45 days investigation insect pest indexes after dispenser also calculate preventive effect.Result of the test is as follows:
Table 20 fluacrypyrim and active component B and the composite control oranges and tangerines blister mite test of pesticide effectiveness thereof
As can be seen from Table 20, fluacrypyrim and active component B composite after can effectively prevent and treat oranges and tangerines blister mite, control efficiency is all better than the preventive effect of single dose, and the preventive effect phase is long.In test scope of medication, target crop is had no adverse effects.
Application Example 12 fluacrypyrim and active component B and the composite control apple Tetranychus urticae test of pesticide effectiveness thereof
This experimental establishment is in Xianyang, Shanxi province city, test medicine is researched and developed by Shaanxi Meibang Pesticide Co., Ltd., is provided, contrast medicament 30% fluacrypyrim suspending agent (autogamy), 30% tebufenpyrad suspending agent (autogamy), 40% propargite missible oil (commercial), 95g/L fenazaquin missible oil (commercial), 20% halfenprox missible oil (autogamy).
Investigation apple Tetranychus urticae insect pest index before medicine, in the dispenser of insect pest initial stage of origination, 10 days, 30 days, 45 days investigation insect pest indexes after dispenser also calculate preventive effect.Result of the test is as follows:
Table 21 fluacrypyrim and active component B and the composite control apple Tetranychus urticae test of pesticide effectiveness thereof
As can be seen from Table 21, fluacrypyrim and active component B composite after can effectively prevent and treat apple Tetranychus urticae, control efficiency is all better than the preventive effect of single dose, and the preventive effect phase is long.In test scope of medication, target crop is had no adverse effects.
After draw through tests different local throughout the country, fluacrypyrim and tebufenpyrad, propargite, fenazaquin, the composite rear preventive effect to common pests such as the two spotted spider mite on cereal crop, fruit tree, vegetables, fiber crop, ornamental plants, legume crop, Panonychus citri, tetranychus viennensis, Tetranychus urticae, yellow spider, knurl tick, blister mite, Shenmu-Yanan railway, Tetranychus cinnabarinus, tealeaves mite, tomato goitre mite, rust mite, cotton spider mites, tetranychus telariuses of halfenprox are all more than 95%, be better than single dose preventive effect, synergistic effect is obvious.
Claims (9)
1. a composition pesticide, it is characterized in that containing active components A and active component B, active components A and active component B weight ratio are 1 ︰ 70 ~ 70 ︰ 1, and described active components A is selected from fluacrypyrim, and active component B is selected from the one in tebufenpyrad, propargite, fenazaquin, halfenprox.
2. composition pesticide according to claim 1, is characterized in that: the weight ratio of active components A and active component B is 1 ︰ 50 ~ 50 ︰ 1.
3. composition pesticide according to claim 2, is characterized in that: the weight ratio of fluacrypyrim and tebufenpyrad is 1 ︰ 20 ~ 20 ︰ 1.
4. composition pesticide according to claim 2, is characterized in that: the weight ratio of fluacrypyrim and propargite is 1 ︰ 25 ~ 5 ︰ 1.
5. composition pesticide according to claim 2, is characterized in that: the weight ratio of fluacrypyrim and fenazaquin is 1 ︰ 20 ~ 30 ︰ 1.
6. composition pesticide according to claim 2, is characterized in that: the weight ratio of fluacrypyrim and halfenprox is 1 ︰ 10 ~ 20 ︰ 1.
7. according to the composition pesticide in claim 3 to 6 described in any one, it is characterized in that: composition makes wetting powder, water dispersible granules, suspending agent, suspension emulsion, aqueous emulsion, microemulsion, microcapsule suspending agent and microcapsule suspension-suspendinagent agent.
8. composition pesticide according to claim 7 is for preventing and treating the application of crop pests.
9. application according to claim 8, is characterized in that: described insect is two spotted spider mite, Panonychus citri, tetranychus viennensis, Tetranychus urticae, yellow spider, knurl tick, blister mite, Shenmu-Yanan railway, Tetranychus cinnabarinus, tealeaves mite, tomato goitre mite, rust mite, cotton spider mites, tetranychus telarius.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210150747.6A CN103416407B (en) | 2012-05-16 | 2012-05-16 | A kind of composition pesticide |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210150747.6A CN103416407B (en) | 2012-05-16 | 2012-05-16 | A kind of composition pesticide |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103416407A CN103416407A (en) | 2013-12-04 |
| CN103416407B true CN103416407B (en) | 2015-12-16 |
Family
ID=49642214
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201210150747.6A Expired - Fee Related CN103416407B (en) | 2012-05-16 | 2012-05-16 | A kind of composition pesticide |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103416407B (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107094805A (en) * | 2017-05-02 | 2017-08-29 | 南宁为辰科技有限公司 | A kind of plant pesticide composition comprising camphor tree leaf essential oil and its application |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1911032A (en) * | 2005-08-12 | 2007-02-14 | 南京第一农药有限公司 | Synergistic compound pesticide contg. pyrimidifen and high efficiency cyfluthrin, and its application |
-
2012
- 2012-05-16 CN CN201210150747.6A patent/CN103416407B/en not_active Expired - Fee Related
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1911032A (en) * | 2005-08-12 | 2007-02-14 | 南京第一农药有限公司 | Synergistic compound pesticide contg. pyrimidifen and high efficiency cyfluthrin, and its application |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103416407A (en) | 2013-12-04 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103563901A (en) | High-efficient insecticide composition containing propylene glycol alginate | |
| CN103563899B (en) | High-efficient pesticide composition | |
| CN103907612A (en) | Pyriminostrobin-containing insecticidal composition | |
| CN103380783B (en) | A kind of high-efficient pesticide composition | |
| CN103621524B (en) | Pesticide composition | |
| CN103416407B (en) | A kind of composition pesticide | |
| CN103907624A (en) | Pyriminostrobin-containing acaricidal composition | |
| CN103651363A (en) | Pesticidal composition containing spiromesifen and nereistoxin | |
| CN103416408B (en) | A kind of insect-killing composition containing Fluacrypyrim | |
| CN103907623B (en) | A kind of High-efficiency miticidal composition containing phonetic mite amine | |
| CN103828823B (en) | A kind of composition pesticide | |
| CN103503874A (en) | Pesticide combination containing acequinocyl | |
| CN103621509B (en) | A kind of composition pesticide containing Spiromesifen | |
| CN104115830A (en) | Insecticidal composition containing flubendiamide and nereistoxin | |
| CN103907630A (en) | Pyriminostrobin-containing acaricidal composition | |
| CN103891761B (en) | A kind of compound acaricide composition containing phonetic mite amine | |
| CN103478157B (en) | A kind of Efficient insecticidal composition | |
| CN103503877B (en) | A kind of composition pesticide | |
| CN103503902B (en) | A kind of High-efficiency miticidal composition | |
| CN103621528B (en) | High efficient mite-killing composition | |
| CN103385252A (en) | Pesticide composition comprising fluacrypyrim | |
| CN103503911B (en) | A kind of miticide composition containing acequinocyl | |
| CN103416420B (en) | A kind of Pesticidal combination containing CGA 183893 | |
| CN105638671B (en) | A kind of high-efficient pesticide composition | |
| CN103798280A (en) | Compound insecticidal composition containing bifenthrin and chlorpyrifos |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CP03 | Change of name, title or address | ||
| CP03 | Change of name, title or address |
Address after: 715500 Pucheng high tech Industrial Development Zone, Weinan, Shaanxi Patentee after: SHAANXI MEIBANG PHARMACEUTICAL GROUP Co.,Ltd. Address before: 715500 Shaanxi Pucheng Weinan County agricultural base industrial park Patentee before: Shaanxi Meibang pesticide Co.,Ltd. |
|
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20151216 |