CN104970038B - A kind of composition pesticide - Google Patents
A kind of composition pesticide Download PDFInfo
- Publication number
- CN104970038B CN104970038B CN201510334289.5A CN201510334289A CN104970038B CN 104970038 B CN104970038 B CN 104970038B CN 201510334289 A CN201510334289 A CN 201510334289A CN 104970038 B CN104970038 B CN 104970038B
- Authority
- CN
- China
- Prior art keywords
- flufenzine
- avm
- fenpropathrin
- composition
- etoxazole
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 82
- 239000000575 pesticide Substances 0.000 title claims abstract description 28
- SWBHWUYHHJCADA-UHFFFAOYSA-N 3-(2-chlorophenyl)-6-(2,6-difluorophenyl)-1,2,4,5-tetrazine Chemical compound FC1=CC=CC(F)=C1C1=NN=C(C=2C(=CC=CC=2)Cl)N=N1 SWBHWUYHHJCADA-UHFFFAOYSA-N 0.000 claims abstract description 142
- XQUXKZZNEFRCAW-UHFFFAOYSA-N fenpropathrin Chemical compound CC1(C)C(C)(C)C1C(=O)OC(C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 XQUXKZZNEFRCAW-UHFFFAOYSA-N 0.000 claims abstract description 70
- 239000000839 emulsion Substances 0.000 claims abstract description 29
- 239000000375 suspending agent Substances 0.000 claims abstract description 28
- 239000003094 microcapsule Substances 0.000 claims abstract description 24
- 239000000725 suspension Substances 0.000 claims abstract description 24
- 241000607479 Yersinia pestis Species 0.000 claims abstract description 17
- 239000004563 wettable powder Substances 0.000 claims abstract description 16
- 241000209140 Triticum Species 0.000 claims abstract description 14
- 239000004530 micro-emulsion Substances 0.000 claims abstract description 14
- 239000004562 water dispersible granule Substances 0.000 claims abstract description 14
- 235000021307 Triticum Nutrition 0.000 claims abstract description 10
- 229920000742 Cotton Polymers 0.000 claims abstract description 8
- 235000007164 Oryza sativa Nutrition 0.000 claims abstract description 5
- 235000009566 rice Nutrition 0.000 claims abstract description 5
- 235000009024 Ceanothus sanguineus Nutrition 0.000 claims abstract description 4
- 241000219146 Gossypium Species 0.000 claims abstract description 4
- 240000003553 Leptospermum scoparium Species 0.000 claims abstract description 4
- 235000015459 Lycium barbarum Nutrition 0.000 claims abstract description 4
- 235000013399 edible fruits Nutrition 0.000 claims abstract description 4
- 235000013311 vegetables Nutrition 0.000 claims abstract description 4
- 240000007594 Oryza sativa Species 0.000 claims abstract 2
- 239000003795 chemical substances by application Substances 0.000 claims description 21
- 241000488583 Panonychus ulmi Species 0.000 claims description 14
- 241000239290 Araneae Species 0.000 claims description 7
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims description 7
- 241001414720 Cicadellidae Species 0.000 claims description 5
- 241000368289 Lepidosaphes ulmi Species 0.000 claims description 5
- 241000952063 Polyphagotarsonemus latus Species 0.000 claims description 5
- 241001124076 Aphididae Species 0.000 claims description 3
- 241000426497 Chilo suppressalis Species 0.000 claims description 3
- 241000008892 Cnaphalocrocis patnalis Species 0.000 claims description 3
- 241000255969 Pieris brassicae Species 0.000 claims description 3
- 241000500437 Plutella xylostella Species 0.000 claims description 3
- 230000008859 change Effects 0.000 claims description 3
- 241001498622 Cixius wagneri Species 0.000 claims description 2
- 210000004894 snout Anatomy 0.000 claims description 2
- 241000131095 Oniscidea Species 0.000 claims 1
- 235000014443 Pyrus communis Nutrition 0.000 claims 1
- CGQCWMIAEPEHNQ-UHFFFAOYSA-N Vanillylmandelic acid Chemical compound COC1=CC(C(O)C(O)=O)=CC=C1O CGQCWMIAEPEHNQ-UHFFFAOYSA-N 0.000 abstract description 95
- IXSZQYVWNJNRAL-UHFFFAOYSA-N etoxazole Chemical compound CCOC1=CC(C(C)(C)C)=CC=C1C1N=C(C=2C(=CC=CC=2F)F)OC1 IXSZQYVWNJNRAL-UHFFFAOYSA-N 0.000 abstract description 74
- 239000005897 Etoxazole Substances 0.000 abstract description 71
- 230000002195 synergetic effect Effects 0.000 abstract description 17
- 230000007613 environmental effect Effects 0.000 abstract description 4
- 244000144977 poultry Species 0.000 abstract description 2
- 231100000572 poisoning Toxicity 0.000 abstract 1
- 230000000607 poisoning effect Effects 0.000 abstract 1
- 238000002360 preparation method Methods 0.000 abstract 1
- 238000005406 washing Methods 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 32
- 241000238631 Hexapoda Species 0.000 description 26
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 25
- 239000003814 drug Substances 0.000 description 25
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 22
- 239000008367 deionised water Substances 0.000 description 22
- 229910021641 deionized water Inorganic materials 0.000 description 22
- 238000013329 compounding Methods 0.000 description 19
- 239000005660 Abamectin Substances 0.000 description 16
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 15
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 15
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 15
- 241000344246 Tetranychus cinnabarinus Species 0.000 description 13
- 230000000694 effects Effects 0.000 description 13
- 238000012360 testing method Methods 0.000 description 13
- 229920003266 Leaf® Polymers 0.000 description 12
- 238000002474 experimental method Methods 0.000 description 12
- 239000007859 condensation product Substances 0.000 description 11
- 230000003449 preventive effect Effects 0.000 description 10
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 9
- -1 disaccharide compound Chemical class 0.000 description 9
- 238000000034 method Methods 0.000 description 9
- IBSREHMXUMOFBB-JFUDTMANSA-N 5u8924t11h Chemical compound O1[C@@H](C)[C@H](O)[C@@H](OC)C[C@@H]1O[C@@H]1[C@@H](OC)C[C@H](O[C@@H]2C(=C/C[C@@H]3C[C@@H](C[C@@]4(O3)C=C[C@H](C)[C@@H](C(C)C)O4)OC(=O)[C@@H]3C=C(C)[C@@H](O)[C@H]4OC\C([C@@]34O)=C/C=C/[C@@H]2C)/C)O[C@H]1C.C1=C[C@H](C)[C@@H]([C@@H](C)CC)O[C@]11O[C@H](C\C=C(C)\[C@@H](O[C@@H]2O[C@@H](C)[C@H](O[C@@H]3O[C@@H](C)[C@H](O)[C@@H](OC)C3)[C@@H](OC)C2)[C@@H](C)\C=C\C=C/2[C@]3([C@H](C(=O)O4)C=C(C)[C@@H](O)[C@H]3OC\2)O)C[C@H]4C1 IBSREHMXUMOFBB-JFUDTMANSA-N 0.000 description 8
- GLUUGHFHXGJENI-UHFFFAOYSA-N Piperazine Chemical compound C1CNCCN1 GLUUGHFHXGJENI-UHFFFAOYSA-N 0.000 description 8
- 229950008167 abamectin Drugs 0.000 description 8
- RRZXIRBKKLTSOM-XPNPUAGNSA-N avermectin B1a Chemical compound C1=C[C@H](C)[C@@H]([C@@H](C)CC)O[C@]11O[C@H](C\C=C(C)\[C@@H](O[C@@H]2O[C@@H](C)[C@H](O[C@@H]3O[C@@H](C)[C@H](O)[C@@H](OC)C3)[C@@H](OC)C2)[C@@H](C)\C=C\C=C/2[C@]3([C@H](C(=O)O4)C=C(C)[C@@H](O)[C@H]3OC\2)O)C[C@H]4C1 RRZXIRBKKLTSOM-XPNPUAGNSA-N 0.000 description 8
- 239000000470 constituent Substances 0.000 description 8
- 229920001296 polysiloxane Polymers 0.000 description 8
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 8
- 241001454293 Tetranychus urticae Species 0.000 description 7
- 241001122767 Theaceae Species 0.000 description 7
- 235000013616 tea Nutrition 0.000 description 7
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 6
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 6
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- 125000002877 alkyl aryl group Chemical group 0.000 description 6
- 229940079593 drug Drugs 0.000 description 6
- 230000002265 prevention Effects 0.000 description 6
- 230000008569 process Effects 0.000 description 6
- 239000004094 surface-active agent Substances 0.000 description 6
- 231100000820 toxicity test Toxicity 0.000 description 6
- 150000001266 acyl halides Chemical class 0.000 description 5
- 230000010165 autogamy Effects 0.000 description 5
- 150000001875 compounds Chemical class 0.000 description 5
- 239000013530 defoamer Substances 0.000 description 5
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 5
- 239000002270 dispersing agent Substances 0.000 description 5
- 239000003960 organic solvent Substances 0.000 description 5
- 159000000000 sodium salts Chemical class 0.000 description 5
- 239000002562 thickening agent Substances 0.000 description 5
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 description 4
- 241000255789 Bombyx mori Species 0.000 description 4
- 241001182720 Cacopsylla pyrisuga Species 0.000 description 4
- 241000207199 Citrus Species 0.000 description 4
- 102000002322 Egg Proteins Human genes 0.000 description 4
- 108010000912 Egg Proteins Proteins 0.000 description 4
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 4
- 206010067482 No adverse event Diseases 0.000 description 4
- 239000002253 acid Substances 0.000 description 4
- 230000009471 action Effects 0.000 description 4
- 150000001298 alcohols Chemical class 0.000 description 4
- 230000002528 anti-freeze Effects 0.000 description 4
- 235000020971 citrus fruits Nutrition 0.000 description 4
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 4
- MOTZDAYCYVMXPC-UHFFFAOYSA-N dodecyl hydrogen sulfate Chemical compound CCCCCCCCCCCCOS(O)(=O)=O MOTZDAYCYVMXPC-UHFFFAOYSA-N 0.000 description 4
- 229940043264 dodecyl sulfate Drugs 0.000 description 4
- 229910052731 fluorine Inorganic materials 0.000 description 4
- 239000011737 fluorine Substances 0.000 description 4
- NVVZQXQBYZPMLJ-UHFFFAOYSA-N formaldehyde;naphthalene-1-sulfonic acid Chemical compound O=C.C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 NVVZQXQBYZPMLJ-UHFFFAOYSA-N 0.000 description 4
- 210000004681 ovum Anatomy 0.000 description 4
- 229920001568 phenolic resin Polymers 0.000 description 4
- 229920002545 silicone oil Polymers 0.000 description 4
- 235000010413 sodium alginate Nutrition 0.000 description 4
- 239000000661 sodium alginate Substances 0.000 description 4
- 229940005550 sodium alginate Drugs 0.000 description 4
- 239000000080 wetting agent Substances 0.000 description 4
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- 241000209094 Oryza Species 0.000 description 3
- 229910019142 PO4 Inorganic materials 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- 150000007513 acids Chemical class 0.000 description 3
- 239000003905 agrochemical Substances 0.000 description 3
- LLEMOWNGBBNAJR-UHFFFAOYSA-N biphenyl-2-ol Chemical compound OC1=CC=CC=C1C1=CC=CC=C1 LLEMOWNGBBNAJR-UHFFFAOYSA-N 0.000 description 3
- 239000003995 emulsifying agent Substances 0.000 description 3
- 238000013401 experimental design Methods 0.000 description 3
- 235000011187 glycerol Nutrition 0.000 description 3
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 3
- 230000000149 penetrating effect Effects 0.000 description 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 3
- 239000010452 phosphate Substances 0.000 description 3
- 239000002574 poison Substances 0.000 description 3
- 231100000614 poison Toxicity 0.000 description 3
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 3
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 3
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 3
- 231100000419 toxicity Toxicity 0.000 description 3
- 230000001988 toxicity Effects 0.000 description 3
- 235000015112 vegetable and seed oil Nutrition 0.000 description 3
- 239000008158 vegetable oil Substances 0.000 description 3
- 230000001018 virulence Effects 0.000 description 3
- 238000009736 wetting Methods 0.000 description 3
- DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical compound CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 description 2
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 description 2
- JCUDAMKYTWVICI-UHFFFAOYSA-N 4-benzyl-2,3-dimethylphenol Chemical compound C1=C(O)C(C)=C(C)C(CC=2C=CC=CC=2)=C1 JCUDAMKYTWVICI-UHFFFAOYSA-N 0.000 description 2
- 239000005995 Aluminium silicate Substances 0.000 description 2
- 206010011732 Cyst Diseases 0.000 description 2
- QWCKQJZIFLGMSD-GSVOUGTGSA-N D-alpha-aminobutyric acid Chemical class CC[C@@H](N)C(O)=O QWCKQJZIFLGMSD-GSVOUGTGSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 2
- 241000382353 Pupa Species 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 2
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 150000001336 alkenes Chemical class 0.000 description 2
- 150000004996 alkyl benzenes Chemical class 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- 235000012211 aluminium silicate Nutrition 0.000 description 2
- 230000008485 antagonism Effects 0.000 description 2
- 150000003851 azoles Chemical class 0.000 description 2
- 239000000440 bentonite Substances 0.000 description 2
- 229910000278 bentonite Inorganic materials 0.000 description 2
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 2
- ZCILODAAHLISPY-UHFFFAOYSA-N biphenyl ether Natural products C1=C(CC=C)C(O)=CC(OC=2C(=CC(CC=C)=CC=2)O)=C1 ZCILODAAHLISPY-UHFFFAOYSA-N 0.000 description 2
- 210000000481 breast Anatomy 0.000 description 2
- 239000011575 calcium Substances 0.000 description 2
- 229910052791 calcium Inorganic materials 0.000 description 2
- 208000031513 cyst Diseases 0.000 description 2
- 239000004495 emulsifiable concentrate Substances 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- GQBJGCRYICJRII-UHFFFAOYSA-N formaldehyde 2-(2-phenylethyl)phenol Chemical compound C=O.C1(=CC=CC=C1)CCC1=C(C=CC=C1)O GQBJGCRYICJRII-UHFFFAOYSA-N 0.000 description 2
- 238000003958 fumigation Methods 0.000 description 2
- 239000002917 insecticide Substances 0.000 description 2
- 229920002521 macromolecule Polymers 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000008267 milk Substances 0.000 description 2
- 235000013336 milk Nutrition 0.000 description 2
- 210000004080 milk Anatomy 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 235000019198 oils Nutrition 0.000 description 2
- JMANVNJQNLATNU-UHFFFAOYSA-N oxalonitrile Chemical compound N#CC#N JMANVNJQNLATNU-UHFFFAOYSA-N 0.000 description 2
- AICOOMRHRUFYCM-ZRRPKQBOSA-N oxazine, 1 Chemical compound C([C@@H]1[C@H](C(C[C@]2(C)[C@@H]([C@H](C)N(C)C)[C@H](O)C[C@]21C)=O)CC1=CC2)C[C@H]1[C@@]1(C)[C@H]2N=C(C(C)C)OC1 AICOOMRHRUFYCM-ZRRPKQBOSA-N 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 239000003002 pH adjusting agent Substances 0.000 description 2
- 230000000361 pesticidal effect Effects 0.000 description 2
- 239000005011 phenolic resin Substances 0.000 description 2
- 229920002503 polyoxyethylene-polyoxypropylene Polymers 0.000 description 2
- 235000013809 polyvinylpolypyrrolidone Nutrition 0.000 description 2
- 229920000523 polyvinylpolypyrrolidone Polymers 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical class CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 235000019832 sodium triphosphate Nutrition 0.000 description 2
- 238000001228 spectrum Methods 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 1
- XGWIJUOSCAQSSV-XHDPSFHLSA-N (S,S)-hexythiazox Chemical compound S([C@H]([C@@H]1C)C=2C=CC(Cl)=CC=2)C(=O)N1C(=O)NC1CCCCC1 XGWIJUOSCAQSSV-XHDPSFHLSA-N 0.000 description 1
- OWEGMIWEEQEYGQ-UHFFFAOYSA-N 100676-05-9 Natural products OC1C(O)C(O)C(CO)OC1OCC1C(O)C(O)C(O)C(OC2C(OC(O)C(O)C2O)CO)O1 OWEGMIWEEQEYGQ-UHFFFAOYSA-N 0.000 description 1
- VUPXKQHLZATXTR-UHFFFAOYSA-N 2,4-diphenyl-1,3-oxazole Chemical class C=1OC(C=2C=CC=CC=2)=NC=1C1=CC=CC=C1 VUPXKQHLZATXTR-UHFFFAOYSA-N 0.000 description 1
- XNWFRZJHXBZDAG-UHFFFAOYSA-N 2-METHOXYETHANOL Chemical compound COCCO XNWFRZJHXBZDAG-UHFFFAOYSA-N 0.000 description 1
- 241000238421 Arthropoda Species 0.000 description 1
- GAWIXWVDTYZWAW-UHFFFAOYSA-N C[CH]O Chemical group C[CH]O GAWIXWVDTYZWAW-UHFFFAOYSA-N 0.000 description 1
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- 235000007516 Chrysanthemum Nutrition 0.000 description 1
- 240000005250 Chrysanthemum indicum Species 0.000 description 1
- 239000004375 Dextrin Substances 0.000 description 1
- 229920001353 Dextrin Polymers 0.000 description 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 241000488563 Eotetranychus carpini Species 0.000 description 1
- 239000005661 Hexythiazox Substances 0.000 description 1
- 239000005909 Kieselgur Substances 0.000 description 1
- 229920001732 Lignosulfonate Polymers 0.000 description 1
- GUBGYTABKSRVRQ-PICCSMPSSA-N Maltose Natural products O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@@H]1O[C@@H]1[C@@H](CO)OC(O)[C@H](O)[C@H]1O GUBGYTABKSRVRQ-PICCSMPSSA-N 0.000 description 1
- IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 description 1
- RCEAADKTGXTDOA-UHFFFAOYSA-N OS(O)(=O)=O.CCCCCCCCCCCC[Na] Chemical compound OS(O)(=O)=O.CCCCCCCCCCCC[Na] RCEAADKTGXTDOA-UHFFFAOYSA-N 0.000 description 1
- 206010033799 Paralysis Diseases 0.000 description 1
- 241001674048 Phthiraptera Species 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical group CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
- 241001249129 Scirpophaga incertulas Species 0.000 description 1
- 240000003377 Shepherdia canadensis Species 0.000 description 1
- 235000018324 Shepherdia canadensis Nutrition 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- HVUMOYIDDBPOLL-XWVZOOPGSA-N Sorbitan monostearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O HVUMOYIDDBPOLL-XWVZOOPGSA-N 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical class OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- VSLWUPHHCFQTDB-LJQANCHMSA-N [(3r)-3-(hydroxymethyl)piperidin-1-yl]-[4-[2-(4-methoxyphenyl)ethynyl]phenyl]methanone Chemical compound C1=CC(OC)=CC=C1C#CC1=CC=C(C(=O)N2C[C@H](CO)CCC2)C=C1 VSLWUPHHCFQTDB-LJQANCHMSA-N 0.000 description 1
- 230000000895 acaricidal effect Effects 0.000 description 1
- 239000000642 acaricide Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 238000012271 agricultural production Methods 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 229960000892 attapulgite Drugs 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 229940077388 benzenesulfonate Drugs 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 239000007957 coemulsifier Substances 0.000 description 1
- 230000002508 compound effect Effects 0.000 description 1
- 238000012937 correction Methods 0.000 description 1
- 125000004093 cyano group Chemical group *C#N 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 235000019425 dextrin Nutrition 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 239000007884 disintegrant Substances 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 210000002615 epidermis Anatomy 0.000 description 1
- BEFDCLMNVWHSGT-UHFFFAOYSA-N ethenylcyclopentane Chemical compound C=CC1CCCC1 BEFDCLMNVWHSGT-UHFFFAOYSA-N 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 238000001802 infusion Methods 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 230000000749 insecticidal effect Effects 0.000 description 1
- 229910052622 kaolinite Inorganic materials 0.000 description 1
- 230000002147 killing effect Effects 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 238000002386 leaching Methods 0.000 description 1
- 230000001665 lethal effect Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000003120 macrolide antibiotic agent Substances 0.000 description 1
- 159000000003 magnesium salts Chemical class 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 230000010534 mechanism of action Effects 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 239000012452 mother liquor Substances 0.000 description 1
- PSZYNBSKGUBXEH-UHFFFAOYSA-N naphthalene-1-sulfonic acid Chemical class C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 PSZYNBSKGUBXEH-UHFFFAOYSA-N 0.000 description 1
- 229930014626 natural product Natural products 0.000 description 1
- 230000007830 nerve conduction Effects 0.000 description 1
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 1
- 231100000194 ovacidal Toxicity 0.000 description 1
- 230000003151 ovacidal effect Effects 0.000 description 1
- 229910052625 palygorskite Inorganic materials 0.000 description 1
- 244000045947 parasite Species 0.000 description 1
- 230000035479 physiological effects, processes and functions Effects 0.000 description 1
- 229920000768 polyamine Polymers 0.000 description 1
- 229920005646 polycarboxylate Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229940051841 polyoxyethylene ether Drugs 0.000 description 1
- 229920000056 polyoxyethylene ether Polymers 0.000 description 1
- 229940088417 precipitated calcium carbonate Drugs 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 239000002728 pyrethroid Substances 0.000 description 1
- HNJBEVLQSNELDL-UHFFFAOYSA-N pyrrolidin-2-one Chemical compound O=C1CCCN1 HNJBEVLQSNELDL-UHFFFAOYSA-N 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 239000001488 sodium phosphate Substances 0.000 description 1
- 229910000162 sodium phosphate Inorganic materials 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- PYODKQIVQIVELM-UHFFFAOYSA-M sodium;2,3-bis(2-methylpropyl)naphthalene-1-sulfonate Chemical compound [Na+].C1=CC=C2C(S([O-])(=O)=O)=C(CC(C)C)C(CC(C)C)=CC2=C1 PYODKQIVQIVELM-UHFFFAOYSA-M 0.000 description 1
- PANBYUAFMMOFOV-UHFFFAOYSA-N sodium;sulfuric acid Chemical compound [Na].OS(O)(=O)=O PANBYUAFMMOFOV-UHFFFAOYSA-N 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000004334 sorbic acid Substances 0.000 description 1
- 235000010199 sorbic acid Nutrition 0.000 description 1
- 229940075582 sorbic acid Drugs 0.000 description 1
- 239000001587 sorbitan monostearate Substances 0.000 description 1
- 235000011076 sorbitan monostearate Nutrition 0.000 description 1
- 229940035048 sorbitan monostearate Drugs 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 210000002784 stomach Anatomy 0.000 description 1
- 208000024891 symptom Diseases 0.000 description 1
- 230000009885 systemic effect Effects 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- HTSABYAWKQAHBT-UHFFFAOYSA-N trans 3-methylcyclohexanol Natural products CC1CCCC(O)C1 HTSABYAWKQAHBT-UHFFFAOYSA-N 0.000 description 1
- 238000005829 trimerization reaction Methods 0.000 description 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a kind of composition pesticide, said composition is characterized mainly in that：Comprising active components A, active component B, wherein active components A is flufenzine, and active component B is arbitrarily one kind, and active components A and active component B weight ratio 1 in AVM, etoxazole, Fenpropathrin:80~80:1, wettable powder, water dispersible granules, suspending agent, suspension emulsion, aqueous emulsion, microemulsion, micro-capsule suspension, microcapsule suspension suspending agent is made in composition.The present composition can prevent and treat rice, wheat, cotton, fruit tree, vegetables, the various pests on tea tree, and have obvious synergistic effect, and reduce pesticide usage amount, and to person poultry safety, no poisoning, Environmental compatibility is good；Preparation adhesion strength strengthens, resistance of rainwater washing against.
Description
The application is divisional application, and original application is a kind of patent application " agriculture of Shaanxi Welch Crop Protection Co., Ltd.
Drug composition ", the application Wei ︰ 2012100636319 of original application, original application day 2012.03.12.
Technical field
The invention belongs to technical field of pesticide, is related to the application that a kind of composition pesticide is used to prevent and treat crop pest.
Background technology
Flufenzine (diflovidazin), molecular formula：C14H7CLF2N4, flufenzine contact goes out ovum and percutaneous activity, attracts mite
Adult carrys out feeding, also prevents and treats the acarid in pupa stage.The compound effects mechanism is unique, not only there is excellent work to ovum and into mite
Property, and female mite is produced unsound ovum, cause destroying the evidence for mite, while also have very well to pear sucker, oystershell scale, leafhopper etc.
Effect, and to natural enemy and Environmental security.
AVM (abamectin), chemical molecular formula：C48H72O14(B1a)·C47H70O14(B1b).AVM is
A kind of f macrolide disaccharide compound.It is the natural products separated from edaphon, has to insect and mite class and tag
With stomach poison function and have faint fumigation action, no systemic action.But it has very strong osmosis to blade, epidermis can be killed
Under insect, and the longevity of residure grow.Its not ovicidal.Its mechanism of action its interference nervous physiology unlike general insecticide is lived
It is dynamic, stimulate release r- aminobutyric acids, and r- aminobutyric acids have inhibitory action to the nerve conduction of arthropod, if mite class into,
There is paralysis symptom in mite and insect after being contacted with larva with medicament, inactive not feeding is dead after 2-4 days.Because not causing elder brother
Worm rapid dehydration, so its lethal effect is slower.Though but have direct killing effect to predatism and parasite, because planting
Thing remained on surface is few, therefore the damage to beneficial insect is small.
Etoxazole (etoxazole), chemical molecular formula：C21H23F2NO2.Etoxazole belongs to 2,4- diphenyl-oxazole derivatives
Class compound, it is a kind of selective acaricide.Mainly suppress mite class molting process, so as to mite from ovum, larva to pupa not
Have with the stage excellent contact.But the prevention effect to adult is not fine.The mite class that resistance has been produced to Hexythiazox has
Good prevention effect.
Fenpropathrin (fenpropathrin), chemical molecular formula：C22H23NO3, Fenpropathrin is a kind of pyrethroid
Insecticide, insecticidal spectrum is wide, and longevity of residure length, it is its maximum feature to have good result to a variety of tetranychids, but without interior suction, fumigation action.
In the real process of agricultural production, pest control, evil mite are easiest to generate the problem that drug-fast generation.No
Compounded with kind composition, be to prevent and treat the very common method of resistant insect, evil mite.Heterogeneity is compounded, according to reality
Application effect, to judge that certain compounding is synergy plus and or antagonism.In most cases, the compounding effect of agricultural chemicals
All it is additive effect, really there is that the compounding of synergistic effect is seldom, especially synergistic effect is clearly, co-toxicity coefficient is very high answers
With just less.Found through inventor's lot of experiments, after flufenzine and AVM, etoxazole, Fenpropathrin compounding, synergy is made
With notable, Environmental compatibility is fabulous, considerably reduces pesticide usage amount.
The content of the invention
Composition pesticide proposed by the present invention is except comprising any in flufenzine and AVM, etoxazole, Fenpropathrin
Outside two kinds of a kind of active components, also comprising appropriate surfactant and carrier.
A kind of composition pesticide, include active components A, active component B, it is characterised in that：Active components A is flufenzine,
Active component B is arbitrarily one kind, and active components A and active component B weight in AVM, etoxazole, Fenpropathrin
Than for 1:80~80:1.
Described composition pesticide, it is characterised in that：Active components A and active component B weight ratio are 1:40~60:1.
Described composition pesticide, it is characterised in that：Flufenzine and the weight of AVM ratio are 1:5~40:1, preferably
For 1:1~8:1.
Described composition pesticide, it is characterised in that：The weight of flufenzine and etoxazole ratio is 1:5~25:1, be preferably
1:1~5:1.
Described composition pesticide, it is characterised in that：Flufenzine and the weight of Fenpropathrin ratio are 1:20~20:1, preferably
For 1:10~10:1.
Described composition pesticide, it is characterised in that：Wettable powder, water dispersible granules, suspending agent, outstanding is made in composition
Emulsion, aqueous emulsion, microemulsion, microcapsule suspending agent, microcapsule suspension-suspendinagent agent.
Described composition pesticide be used to preventing and treating rice, wheat, cotton, fruit tree, vegetables, on tea tree insect application.
Described application, pest control include：Rice leaf roller, striped rice borer, yellow rice borer, diamondback moth, cabbage caterpillar, rice fly
Lice, aphid, red spider, yellow spider, blister mite, rust mite, yellow tea mite, Tetranychus cinnabarinus, Tetranychus urticae, wheat leaf pawl mite, pear sucker,
Oystershell scale, leafhopper.
The present invention composition pesticide in comprise at least a kind of surfactant, in favor of administration when active component in water
It is scattered.Surface-active contents are the 5%~30% of total formulation weight, and surplus is solid or liquid diluent.The present invention's
Surfactant selected by composition pesticide is known in those skilled in the art：Dispersant, wetting agent, breast can be selected from
One or more in agent or defoamer.
Following constituent content is included when wettable powder is made：Active components A 1%~80%, active component B 1%~
80%th, dispersant 5%~10%, wetting agent 2%~10%, filler surplus.
Composition includes following constituent content when water dispersible granules are made：Active components A 1%~80%, active component B
1%~80%, dispersant 3%~12%, wetting agent 1%~8%, disintegrant 1%~10%, binding agent 0%~8%, filler
Surplus.
Composition includes following constituent content when suspending agent is made：Active components A 1%~60%, active component B 1%~
60%th, dispersant 2~10%, wetting agent 2~10%, defoamer 0.1~2%, thickener 0.05~1%, antifreeze 1~8%,
Deionized water adds to 100%.
Composition includes following constituent content when suspension emulsion is made：Active components A 1%~60%, active component B 1%~
60%th, organic solvent 0~15%, emulsifying agent 2%~12%, dispersant 2%~10%, defoamer 1%~2%, thickener
0.05%~1%, antifreeze 1%~8%, stabilizer 0.05%~3%, deionized water add to 100%.
Composition includes following constituent content when aqueous emulsion is made：Activity composition A1%~60%, active component B 1%
~60%, organic solvent 0%~15%, emulsifying agent 1%~15%, antifreeze 0%~10%, thickener 0.05%~1%, disappear
Infusion 0.01%~2%, deionized water supply surplus.
When composition is made microemulsion comprising following constituent content active components A 1%~60%, active component B 1%~
60%th, organic solvent 0%~15%, emulsifying agent 3%~15%, co-emulsifier 0%~12%, antifreeze 0%~10%, thickening
Agent 0.05%~1%, defoamer 0.01%~2%, stabilizer 0%~4%, deionized water supplies surplus.
Micro-capsule suspension, which is made, in composition includes following constituent content：Active components A 1%~60%, active component B
1%~60%, macromolecule cyst material 1%~12%, surfactant 2%~10%, organic solvent 1%~15%, emulsification
Agent 1%~8%, pH adjusting agent 1%~5%, deionized water adds to 100%.
Composition includes following constituent content when microcapsule suspension-suspendinagent agent is made：Active components A 1%~60%, activity into
Divide B 1%~60%, macromolecule cyst material 2%~12%, surfactant 3%~15%, organic solvent 1%~5%, breast
Agent 1%~6%, defoamer 0.2%~5%, thickener 0.05%~1%, pH adjusting agent 1%~5%, water add to 100%.
The wettable powder the key technical indexes of the present invention：
The water dispersible granules the key technical indexes of the present invention：
The suspending agent the key technical indexes of the present invention：
The suspension emulsion the key technical indexes of the present invention：
The aqueous emulsion the key technical indexes of the present invention：
The microemulsion the key technical indexes of the present invention：
The microcapsule suspending agent the key technical indexes of the present invention：
The microcapsule suspension-suspendinagent agent the key technical indexes of the present invention：
The advantage of the invention is that：
(1) after flufenzine and AVM, etoxazole, Fenpropathrin compound, there is notable synergistic and lasting effect；
(2) preventing and treating spectrum is expanded, to rice, wheat, cotton, fruit tree, vegetables, the rice leaf roller of tea tree, striped rice borer, three
Change snout moth's larva, diamondback moth, cabbage caterpillar, planthopper, aphid, red spider, yellow spider, blister mite, rust mite, yellow tea mite, Tetranychus cinnabarinus, two
Variegated leaf mite, wheat leaf pawl mite, pear sucker, oystershell scale, leafhopper etc. have greater activity；
(3) reduce the dosage of agricultural chemicals, reduce residual quantity of the agricultural chemicals on crop, alleviate environmental pollution；
(4) to person poultry safety, Environmental compatibility is good, is not likely to produce the resistance to the action of a drug.
Embodiment
With reference to embodiment to further instruction of the present invention, the percentage in embodiment is weight percentage, but
The invention is not limited in this.
Application Example one
The flufenzine AVM wettable powder of embodiment 1 81%
Flufenzine 80%, AVM 1%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 5%, sldium lauryl sulfate 3%, kaolin
100% is added to, mixture carries out air-flow crushing, and 81% flufenzine AVM wettable powder is made.
Effective active composition AVM is changed to etoxazole, Fenpropathrin forms new embodiment.
The flufenzine AVM wettable powder of embodiment 2 45%
Flufenzine 40%, AVM 5%, alkylnaphthalene sulfonate 6%, wetting and penetrating agent F 4%, precipitated calcium carbonate add to
100%, mixture carries out air-flow crushing, and 45% flufenzine AVM wettable powder is made.
Effective active composition AVM is changed to etoxazole, Fenpropathrin forms new embodiment.
The flufenzine AVM wettable powder of embodiment 3 40%
Flufenzine 30%, AVM 10%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 8%, tea seed cake 3%, kaolin add to
100%, mixture carries out air-flow crushing, and 40% flufenzine AVM wettable powder is made.
Effective active composition AVM is changed to etoxazole, Fenpropathrin forms new embodiment.
The flufenzine AVM water dispersible granules of embodiment 4 61%
The phonetic formaldehyde condensation products sulfate 6% of flufenzine 60%, AVM 1%, alkylphenol-polyethenoxy, laruyl alcohol sulfuric acid
Sodium 5%, sodium carbonate 2%, white carbon add to 100%, are mixed to prepare 61% flufenzine AVM water dispersible granules.
Effective active composition AVM is changed to etoxazole, Fenpropathrin forms new embodiment.
The flufenzine AVM water dispersible granules of embodiment 5 55%
Flufenzine 50%, AVM 5%, silkworm excrement 4%, alkylaryl APEO 7%, sodium acid carbonate 2%, kaolinite
Soil adds to 100%, is mixed to prepare 55% flufenzine AVM water dispersible granules.
Effective active composition AVM is changed to etoxazole, Fenpropathrin forms new embodiment.
The flufenzine AVM water dispersible granules of embodiment 6 30%
Flufenzine 20%, AVM 10%, polycarboxylate 6%, neopelex 5%, bentonite 2%, silicon
Diatomaceous earth adds to 100%, is mixed to prepare 30% flufenzine AVM water dispersible granules.
Effective active composition AVM is changed to etoxazole, Fenpropathrin forms new embodiment.
The flufenzine AVM suspending agent of embodiment 7 41%
Flufenzine 1%, AVM 40%, alkylaryl APEO 5%, sldium lauryl sulfate 4%, silicone
1.6%th, sodium alginate 0.12%, propane diols 1.2%, deionized water add to 100%, are mixed to prepare 41% flufenzine Avermectin
Plain suspending agent.
Effective active composition AVM is changed to etoxazole, Fenpropathrin forms new embodiment.
The flufenzine AVM suspending agent of embodiment 8 35%
Flufenzine 25%, AVM 5%, ester polyoxyethylene are phonetic 6%, silkworm excrement 4%, silicone compound 1.2%, trimerization
Sodium phosphate 0.14%, polyethylene glycol 0.8%, deionized water add to 100%, are mixed to prepare the suspension of 30% flufenzine AVM
Agent.
Effective active composition AVM is changed to etoxazole, Fenpropathrin forms new embodiment.
The flufenzine AVM suspending agent of embodiment 9 25%
Flufenzine 20%, AVM 5%, lignosulfonates 6%, tea seed cake 3%, silicone 2.5%, sodium tripolyphosphate
0.09%th, diethylene glycol (DEG) 1%, deionized water add to 100%, are mixed to prepare 25% flufenzine AVM suspending agent.
Effective active composition AVM is changed to etoxazole, Fenpropathrin forms new embodiment.
The flufenzine AVM suspension emulsion of embodiment 10 41%
Flufenzine 40%, AVM 1%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 5%, sldium lauryl sulfate 5%, nonyl phenol
Polyoxyethylene ether phosphate 6%, acetone 5%, C8~10Aliphatic alcohols 1%, methylcellulose 0.08%, glycerine 1.8%, go from
Sub- water adds to 100%, is mixed to prepare 41% flufenzine AVM suspension emulsion.
Effective active composition AVM is changed to etoxazole, Fenpropathrin forms new embodiment.
The flufenzine AVM suspension emulsion of embodiment 11 30%
Flufenzine 15%, AVM 15%, alkane naphthalene sulfonic acid-formaldehyde condensation product sodium salt 5%, silkworm excrement 4%, alkylaryl gather
Oxypropylene APEO 6%, butyl ether 5%, silicone oil 1.2%, xanthans 0.15%, glycerine 1.6%, deionized water add to
100%, it is mixed to prepare 30% flufenzine AVM suspension emulsion.
Effective active composition AVM is changed to etoxazole, Fenpropathrin forms new embodiment.
The flufenzine AVM suspension emulsion of embodiment 12 20%
The phonetic formaldehyde condensation products sulfate 6.5% of flufenzine 15%, AVM 5%, alkylphenol-polyethenoxy, dodecyl
Sodium sulphate 4%, AEO 5%, propyl alcohol 4%, C10~20Saturated fat acids 0.9%, glycerine 1.5%, poly- second
Alkene pyrrolidone 0.19%, deionized water add to 100%, are mixed to prepare 20% flufenzine AVM suspension emulsion.
Effective active composition AVM is changed to etoxazole, Fenpropathrin forms new embodiment.
The flufenzine avermectin micro-emulsion of embodiment 13 35%
Flufenzine 30%, AVM 5%, phenethyl phenol formaldehyde resin polyoxyethyl ether 7%, propyl alcohol 4%, diethylene glycol (DEG)
1%th, phenolic resin 0.18%, silicone 1.2%, deionized water supplies 100%, is mixed to prepare 35% flufenzine AVM
Microemulsion.
Effective active composition AVM is changed to etoxazole, Fenpropathrin forms new embodiment.
The flufenzine avermectin micro-emulsion of embodiment 14 15%
Flufenzine 13%, AVM 2%, cyclohexanone 6%, PVPP 0.2%, alkyl biphenyl ether two
Sulfonic acid magnesium salts 7%, C10~20Saturated fat acids 1.4%, deionized water supplies 100%, and 15% flufenzine AVM is made
Microemulsion.
Effective active composition AVM is changed to etoxazole, Fenpropathrin forms new embodiment.
The flufenzine abamectin aqueous emulsion of embodiment 15 30%
Flufenzine 5%, AVM 25%, toluene 3%, ethyl acetate 4%, alkyl benzene calcium sulfonate 6%, hydroxy ethyl fiber
Element 0.18%, silicone compound 0.8%, deionized water adds to 100%, is mixed to prepare 30% flufenzine AVM water and milk
Agent.
Effective active composition AVM is changed to etoxazole, Fenpropathrin forms new embodiment.
The flufenzine abamectin aqueous emulsion of embodiment 16 25%
Flufenzine 15%, AVM 10%, vegetable oil 3.5%, propyl alcohol 5.5%, phenyl phenol polyoxyethanyl ether phosphate
7%th, sodium alginate 0.12%, C8~10Aliphatic alcohols 1%, deionized water add to 100%, it is blended be made 25% flufenzine Ah
Tie up rhzomorph aqueous emulsion.
Effective active composition AVM is changed to etoxazole, Fenpropathrin forms new embodiment.
The flufenzine avermectin microcapsule suspending agent of embodiment 17 20%
Flufenzine 10%, AVM 10%, sodium alginate 3%, polyfunctional group acyl halide polyamines 2%, wetting and penetrating agent F
5%th, aliphatic alcohol polyethenoxy base ether 2.8%, cyclohexanone 4%, sorbitan monostearate 5%, citric acid 0.5%, hydrogen-oxygen
Change sodium 0.6%, deionized water adds to 100% parts by weight, obtained 20% flufenzine avermectin microcapsule suspending agent.
Effective active composition AVM is changed to etoxazole, Fenpropathrin forms new embodiment.
The flufenzine avermectin microcapsule suspension of embodiment 18 25%-suspending agent
Flufenzine 20%, AVM 5%, carboxymethyl cellulose 5%, polyfunctional group acyl halide dihydric alcohol 2%, laruyl alcohol
Sodium sulphate 2.5%, vegetable oil 7%, phenyl phenol polyoxyethyl ether 5%, alkylaryl polyoxyethylene poly-oxygen propylene aether 3%, silicone oil
1.6%th, sodium tripolyphosphate 1.2%, sodium hydroxide 0.4%, citric acid 0.8%, water add to 100% parts by weight, and 25% fluorine is made
Mite piperazine avermectin microcapsule suspension-suspending agent.
Effective active composition AVM is changed to etoxazole, Fenpropathrin forms new embodiment.
The flufenzine Fenpropathrin wettable powder of embodiment 19 60%
Flufenzine 30%, Fenpropathrin 30%, arylphenol polyoxyethylene succinate sulfonate 6%, detergent alkylate sulphur
Sour sodium 5%, attapulgite add to 100%, and mixture carries out air-flow crushing, and 60% flufenzine Fenpropathrin wettable powder is made
Agent.
Effective active composition Fenpropathrin is changed to etoxazole, AVM forms new embodiment.
The flufenzine Fenpropathrin suspension emulsion of embodiment 20 20%
The phonetic formaldehyde condensation products sulfate 6% of flufenzine 5%, Fenpropathrin 15%, alkylphenol-polyethenoxy, Nekal BX
4%th, phenyl phenol polyoxyethanyl ether phosphate 6%, ethanol 5%, C8~10Aliphatic alcohols 1%, polyvinylpyrrolidone 0.12%, gather
Ethylene glycol 1.5%, deionized water add to 100%, are mixed to prepare 20% flufenzine Fenpropathrin suspension emulsion.
Effective active composition Fenpropathrin is changed to AVM, etoxazole forms new embodiment.
The flufenzine fenpropathrin microemulsion of embodiment 21 20%
Flufenzine 10%, Fenpropathrin 10%, 3-methyl cyclohexanol ketenes 6%, PAA 0.2%, fatty alcohol polyoxy second
Alkene ether 7%, silicone oil 1.4%, antioxidant 1.5%, deionized water supplies 100%, and 20% flufenzine Fenpropathrin micro emulsion is made
Agent.
Effective active composition Fenpropathrin is changed to AVM, etoxazole forms new embodiment.
The flufenzine Fenpropathrin aqueous emulsion of embodiment 22 25%
Flufenzine 10%, Fenpropathrin 15%, vegetable oil 5%, ethyl acetate 5%, benzyl dimethyl phenol polyoxyethyl ether
6%th, white dextrin 0.18%, silicone 0.8%, deionized water adds to 100%, is mixed to prepare 25% flufenzine Fenpropathrin water
Emulsion.
Effective active composition Fenpropathrin is changed to AVM, etoxazole forms new embodiment.
The flufenzine Fenpropathrin micro-capsule suspension of embodiment 23 30%
Flufenzine 10%, Fenpropathrin 20%, PIC 3%, polyfunctional group acyl halide dihydric alcohol 2%, soapberry
The phonetic formaldehyde condensation products sulfate 2.8% of powder 5%, alkylphenol-polyethenoxy, ethyl acetate 4%, benzyl dimethyl phenol polyoxyethanyl
Ether 5%, sorbic acid 0.5%, sodium hydroxide 0.6%, deionized water add to 100% parts by weight, and 30% flufenzine first cyanogen is made
Chrysanthemum ester micro-capsule suspension.
Effective active composition Fenpropathrin is changed to etoxazole, AVM forms new embodiment.
The flufenzine Fenpropathrin microcapsule suspension-suspendinagent agent of embodiment 24 25%
Flufenzine 15%, Fenpropathrin 10%, polyfunctional group acyl halide dihydric alcohol 5%, sodium alginate 2%, spaonin powder
2.5%th, ethyl acetate 7%, alkylphenol-formaldehyde resin polyoxyethyl ether 5%, NPE 3%, silicone oil 1.6%,
PVPP 1.2%, sodium hydroxide 0.4%, citric acid 0.8%, water add to 100% parts by weight, are made 25%
Flufenzine Fenpropathrin microcapsule suspension-suspendinagent agent.
Effective active composition Fenpropathrin is changed to etoxazole, AVM forms new embodiment.
The flufenzine etoxazole wettable powder of embodiment 25 60%
The phonetic formaldehyde condensation products sulfate 6% of flufenzine 10%, etoxazole 50%, alkylphenol-polyethenoxy, wetting and penetrating agent F
5%th, bentonite adds to 100%, and mixture carries out air-flow crushing, and 60% flufenzine etoxazole wettable powder is made.
Effective active composition etoxazole is changed to Fenpropathrin, AVM forms new embodiment.
The flufenzine etoxazole water dispersible granules of embodiment 26 81%
Flufenzine 1%, etoxazole 80%, alkyl benzene sulfonate calcium salt 6%, silkworm excrement 4%, sodium acid carbonate 3%, white carbon adds to
100%, it is mixed to prepare 81% flufenzine etoxazole water dispersible granules.
Effective active composition etoxazole is changed to Fenpropathrin, AVM forms new embodiment.
The flufenzine etoxazole suspending agent of embodiment 27 35%
The phonetic formaldehyde condensation products sulfate 5% of flufenzine 5%, etoxazole 30%, alkylphenol-polyethenoxy, tea seed cake 4%, C8~10
Aliphatic alcohols 1.6%, PAA 0.12%, propane diols 1.2%, deionized water add to 100%, are mixed to prepare 35% fluorine mite
Piperazine etoxazole suspending agent.
Effective active composition etoxazole is changed to AVM, Fenpropathrin forms new embodiment.
The flufenzine etoxazole suspension emulsion of embodiment 28 40%
Flufenzine 5%, etoxazole 35%, alkylphenol-polyethenoxy are phonetic 6%, tea seed cake 4%, styrene APEO sulfuric acid
Ammonium salt 6%, butyl ether 5%, C10~20Saturated fat acids 1%, polyvinylpyrrolidone 0.12%, PAA 1.5%, go from
Sub- water adds to 100%, is mixed to prepare 40% flufenzine etoxazole suspension emulsion.
Effective active composition etoxazole is changed to AVM, Fenpropathrin forms new embodiment.
The flufenzine etoxazole microemulsion of embodiment 29 30%
Flufenzine 10%, etoxazole 20%, toluene 6%, phenolic resin 0.2%, alkylaryl polyoxyethylene polyoxypropylene
Ether 7%, silicone compound 1.4%, surface-active substance 1%, deionized water supplies 100%, and 30% flufenzine second mite is made
Azoles microemulsion.
Effective active composition etoxazole is changed to AVM, Fenpropathrin forms new embodiment.
The flufenzine etoxazole aqueous emulsion of embodiment 30 25%
Flufenzine 10%, etoxazole 15%, ethyl acetate 5%, propyl alcohol 5%, alkyl biphenyl ether disulfonic acid magnesium salts 6%, friendship
Join polyvinylpyrrolidone 0.18%, C8~10Aliphatic alcohols 0.8%, deionized water adds to 100%, is mixed to prepare 25% fluorine mite
Piperazine etoxazole aqueous emulsion.
Effective active composition etoxazole is changed to AVM, Fenpropathrin forms new embodiment.
The flufenzine etoxazole micro-capsule suspension of embodiment 31 30%
Flufenzine 5%, etoxazole 25%, polyfunctional group acyl halide dihydric alcohol 3%, maltose 2%, tea seed cake 5%, naphthalene sulfonic acids
Formaldehyde condensation products sodium salt 2.8%, ethylene glycol monomethyl ether 4%, triethanolamine salt 5%, citric acid 0.5%, sodium hydroxide 0.6%, go
Ionized water adds to 100% parts by weight, and 30% flufenzine etoxazole micro-capsule suspension is made.
Effective active composition etoxazole is changed to Fenpropathrin, AVM forms new embodiment.
The flufenzine etoxazole microcapsule suspension-suspendinagent agent of embodiment 32 20%
Flufenzine 10%, etoxazole 10%, PIC 5%, converted starch 2%, sldium lauryl sulfate 2.5%, plant
Thing oil 7%, phenethyl phenol formaldehyde resin polyoxyethyl ether 5%, alkylaryl polyoxyethylene polyoxypropylene ether again 3%, silicone
1.6%th, PAA 1.2%, sodium hydroxide 0.4%, citric acid 0.8%, water add to 100% parts by weight, and 20% fluorine mite is made
Piperazine etoxazole microcapsule suspension-suspendinagent agent.
Effective active composition etoxazole is changed to Fenpropathrin, AVM forms new embodiment.
The embodiment of the present invention is the method being combined using Toxicity Determination and field test.First pass through indoor virulence survey
It is fixed, clear and definite two kinds of medicaments compound by a certain percentage after co-toxicity coefficient (CTC), CTC ＜ 80 are antagonism, 80≤CTC≤120
For summation action, CTC ＞ 120 are synergistic effect, on this basis, then carry out field test.
Test method：The mother liquor of each mixed agent is diluted to five series concentrations respectively during experiment, is respectively placed in beaker
It is standby.Using the first leaching leaf method that is followed by worm, by not in contact with the blade of the same size of any medicament in the decoction configured
Take out, naturally dry, be put into insect box after immersion 5s, then connect for examination larva, raised under the conditions of 25 DEG C, often handle 3
Secondary repetition, it is 50 often to repeat test worm number used, while sets blank control, checks dead borer population in 72h, calculates the death rate and correction
The death rate, try to achieve virulence regression equation and calculate LC50Value.If compareing the death rate is more than 10%, it is considered as invalid experiment.Calculate public
Formula is as follows：
Insect corrected mortality is converted into probit value (y), concentration for the treatment of (μ g/ml) is converted into logarithm value (x), with minimum
Square law draws virulence regression equation, and thus calculates the value of every kind of medicament.Common poison system is calculated according to the abundant equations of Sun Yun
Number CTC.Calculation formula is following, and (using flufenzine as standard agent, 100) its toxicity index is：
TI × P of M theoretical toxicity index (TTI)=flufenzineFlufenzine+ active component B TI × PActive component B
In formula：M is the mixture of different ratio；
PActive component BFor active component B shared ratios in the composition；
PFlufenzineFor flufenzine shared ratio in the composition.
Note：Active component B is arbitrary a kind of in etoxazole, AVM, Fenpropathrin.
Application Example two：
For trying insect：Red spider.
Experimental design：The effective of flufenzine, the former medicine of AVM and the two different ratio mixture is determined by pilot study
Lethasl concentration scope.
Toxicity test result one
Toxicity test of the flufenzine of table 1 with AVM different ratio to red spider
As shown in Table 1, flufenzine fits over 80 with abamectin compounded preventing and treating red spider:1 to 1:When 80, co-toxicity coefficient is equal
More than 120, illustrate both 80:1 to 1:Mixture shows synergistic effect in the range of 80, especially when flufenzine and Avermectin
It is plain to match 40:1 to 1:When 5, synergistic effect becomes apparent protruding, wherein when flufenzine and AVM weight ratio are 8:1
When co-toxicity coefficient it is maximum, synergistic effect is the most obvious.Find simultaneously, flufenzine is matched 40 with AVM:1、39:1、38:
1、37:1、36:1、35:1、34:1、33:1、32:1、31:1、30:1、29:1、28:1、27:1、26:1、25:1、24:1、23:1、
22:1、21:1、20:1、19:1、18:1、17:1、16:1、15:1、14:1、13:1、12:1、11:1、10:1、9:1、8:1、7:1、
6:1、5:1、4:1、3:1、2:1、1:1、1:2、1:3、1:4、1:Compounding is to red spider, yellow spider, blister mite, rust mite, tea when 5
The insects such as yellow mite, Tetranychus cinnabarinus, Tetranychus urticae, wheat leaf pawl mite, pear sucker, oystershell scale, leafhopper also there is preferable synergy to make
With co-toxicity coefficient is all higher than 120.
Application Example three：
For trying insect：Tetranychus urticae.
Experimental design：Effective cause of flufenzine, etoxazole active compound and the two different ratio mixture is determined by pilot study
Dead concentration range.
Toxicity test result two
Toxicity test of the flufenzine of table 2 with etoxazole different ratio to Tetranychus urticae
As shown in Table 2, flufenzine prevents and treats the proportioning of Tetranychus urticae 80 with etoxazole compounding:1 to 1:When 80, co-toxicity coefficient
120 are all higher than, illustrates both 80:1 to 1:Mixture shows synergistic effect in the range of 80, especially when flufenzine and second mite
The proportioning of azoles is 25:1 to 1:When 5, synergistic effect becomes apparent protruding, wherein when flufenzine and etoxazole weight ratio are 5:When 1
Co-toxicity coefficient is maximum, and synergistic effect is the most obvious, finds simultaneously, and flufenzine is matched 25 with etoxazole:1、24:1、23:1、22:
1、21:1、20:1、19:1、18:1、17:1、16:1、15:1、14:1、13:1、12:1、11:1、10:1、9:1、8:1、7:1、6:
1、5:1、4:1、3:1、2:1、1:1、1:2、1:3、1:4、1:Compounding is yellow to red spider, yellow spider, blister mite, rust mite, tea when 5
The insects such as mite, Tetranychus cinnabarinus, Tetranychus urticae, wheat leaf pawl mite also have preferable synergistic effect, and co-toxicity coefficient is all higher than 120.
Application Example four：
For trying insect：Tetranychus cinnabarinus.
Experimental design：The effective of flufenzine, Fenpropathrin active compound and the two different ratio mixture is determined by pilot study
Lethasl concentration scope.
Toxicity test result three
Toxicity test of the flufenzine of table 3 with Fenpropathrin different ratio to Tetranychus cinnabarinus
As shown in Table 3, flufenzine prevents and treats the proportioning of Tetranychus cinnabarinus 80 with Fenpropathrin compounding:1 to 1:When 80, poison is altogether
Number is all higher than 120, illustrates both 80:1 to 1:Mixture shows synergistic effect in the range of 80, especially when flufenzine and first
The proportioning of Cyano chrysanthemate is 20:1 to 1:When 20, synergistic effect becomes apparent protruding, wherein when flufenzine and Fenpropathrin weight ratio
For 1:Co-toxicity coefficient is maximum when 1, and synergistic effect is the most obvious, finds simultaneously, and flufenzine is matched 20 with Fenpropathrin:1、19:
1、18:1、17:1、16:1、15:1、14:1、13:1、12:1、11:1、10:1、9:1、8:1、7:1、6:1、5:1、4:1、3:1、2:
1、1:1、1:2、1:3、1:4、1:5、1:6、1:7、1:8、1:9、1:10、1:11、1:12、1:13、1:14、1:15、1:16、1:
17、1:18、1:19、1:Compounding is to red spider, yellow spider, blister mite, rust mite, yellow tea mite, Tetranychus cinnabarinus, two variegated leafs when 20
The insects such as mite, wheat leaf pawl mite also have preferable synergistic effect, and co-toxicity coefficient is all higher than 120.
The flufenzine of Application Example five and AVM and its compounding preventing and treating cotton Tetranychus cinnabarinus test of pesticide effectiveness
This experimental arrangement is carried in Shaanxi Province Weinan City Dali County, test medicine by Shaanxi Welch Crop Protection Co., Ltd.
For, the flufenzine suspending agent (autogamy) of comparison medicament 10%, 2% abamectin emulsifiable concentrate (purchased in market).
Experiment uses conventional spray-on process, investigates cotton Tetranychus cinnabarinus insect pest index before medicine, in insect pest early period of origination dispenser, applies
10 days after medicine, investigate insect pest indexes and calculate preventive effect within 30 days, 45 days.Experimental result is as follows：
The flufenzine of table 4, AVM and its compounding preventing and treating cotton Tetranychus cinnabarinus test of pesticide effectiveness
As can be seen from Table 4, flufenzine with it is abamectin compounded after can effectively prevent and treat cotton Tetranychus cinnabarinus, prevention effect is equal
Better than the preventive effect of single dose, and efficiency time is grown.Target crop is had no adverse effects in experiment scope of medication.
The flufenzine of Application Example six and AVM and its compounding preventing and treating Pesticide Effect for Apple Red Spiders
This experimental arrangement is carried in Shaanxi Province Weinan city Linwei district, test medicine by Shaanxi Welch Crop Protection Co., Ltd.
For, the flufenzine suspending agent (autogamy) of comparison medicament 10%, 2% abamectin emulsifiable concentrate (purchased in market).
Experiment uses conventional spray-on process, European red mite insect pest index is investigated before medicine, in insect pest early period of origination dispenser, dispenser
Investigate insect pest indexes and calculate preventive effect within 10 days afterwards, 30 days, 45 days.Experimental result is as follows：
The flufenzine of table 5, AVM and its compounding preventing and treating Pesticide Effect for Apple Red Spiders
As can be seen from Table 5, flufenzine with it is abamectin compounded after can effectively prevent and treat European red mite, prevention effect is excellent
In the preventive effect of single dose, and efficiency time is grown.Target crop is had no adverse effects in experiment scope of medication.
The flufenzine of Application Example seven and Fenpropathrin and its compounding preventing and treating citrus blister mite test of pesticide effectiveness
This experimental arrangement is carried in Jiaxing City, Zhejiang Province Haiyan County, test medicine by Shaanxi Welch Crop Protection Co., Ltd.
For, the flufenzine suspending agent (autogamy) of comparison medicament 10%, 20% fenpropathrin milk oil (purchased in market).
Experiment uses conventional spray-on process, citrus blister mite insect pest index is investigated before medicine, in insect pest early period of origination dispenser, dispenser
Investigate insect pest indexes and calculate preventive effect within 10 days afterwards, 30 days, 45 days.Experimental result is as follows：
The flufenzine of table 6, Fenpropathrin and its compounding preventing and treating citrus blister mite test of pesticide effectiveness
As can be seen from Table 6, for flufenzine with can effectively prevent and treat citrus blister mite after Fenpropathrin compounding, prevention effect is excellent
In the preventive effect of single dose, and efficiency time is grown.Target crop is had no adverse effects in experiment scope of medication.
The flufenzine of Application Example eight and etoxazole and its compounding preventing and treating wheat wheat leaf pawl mite test of pesticide effectiveness
This experimental arrangement is carried in Xianyang, Shanxi province city Liquan County, test medicine by Shaanxi Welch Crop Protection Co., Ltd.
For, the flufenzine suspending agent (autogamy) of comparison medicament 10%, 10% etoxazole suspending agent (autogamy).
Experiment uses conventional spray-on process, and wheat wheat leaf pawl acarid evil index is investigated before medicine, in insect pest early period of origination dispenser, is applied
10 days after medicine, investigate insect pest indexes and calculate preventive effect within 30 days, 45 days.Experimental result is as follows：
The flufenzine of table 7, AVM and its compounding preventing and treating wheat wheat leaf pawl mite test of pesticide effectiveness
As can be seen from Table 7, for flufenzine with can effectively prevent and treat wheat wheat leaf pawl mite after etoxazole compounding, prevention effect is excellent
In the preventive effect of single dose, and efficiency time is grown.Target crop is had no adverse effects in experiment scope of medication.
The experiment by different places throughout the country is drawn afterwards, and flufenzine and AVM, etoxazole, Fenpropathrin are multiple
Be configured to wettable powder, water dispersible granules, suspending agent, suspension emulsion, aqueous emulsion, microemulsion, microcapsule suspending agent, microcapsule suspension-
To the red spider of all kinds of crops, yellow spider, blister mite, rust mite, yellow tea mite, Tetranychus cinnabarinus, Tetranychus urticae, Mai Ye after suspending agent
The preventive effect of the common insect pests such as pawl mite is obvious better than single dose preventive effect, synergistic effect more than 95%.
Claims (6)
1. a kind of composition pesticide, include active components A, active component B, it is characterised in that：Active components A is flufenzine, living
Property composition B is Fenpropathrin, and active components A and active component B weight ratio 1:80~80:1.
2. composition pesticide according to claim 1, it is characterised in that：Active components A and active component B weight ratio are
1:40~60:1。
3. composition pesticide according to claim 1, it is characterised in that：Flufenzine and the weight of Fenpropathrin ratio are 1:20
~20:1。
4. the composition pesticide according to any one in claim 1 ~ 3, it is characterised in that：Wettable powder is made in composition
Agent, water dispersible granules, suspending agent, suspension emulsion, aqueous emulsion, microemulsion, microcapsule suspending agent, microcapsule suspension-suspendinagent agent.
5. composition pesticide according to claim 4 is used to prevent and treat rice, wheat, cotton, fruit tree, vegetables, evil on tea tree
The application of worm.
6. application according to claim 5, it is characterised in that institute's pest control includes：Rice leaf roller, striped rice borer, three change
Snout moth's larva, diamondback moth, cabbage caterpillar, planthopper, aphid, red spider, yellow spider, blister mite, rust mite, yellow tea mite, wheat leaf pawl mite, pear wood
Lice, oystershell scale, leafhopper.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510334289.5A CN104970038B (en) | 2012-03-12 | 2012-03-12 | A kind of composition pesticide |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510334289.5A CN104970038B (en) | 2012-03-12 | 2012-03-12 | A kind of composition pesticide |
| CN201210063631.9A CN103300020B (en) | 2012-03-12 | 2012-03-12 | A kind of pesticide composition |
Related Parent Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201210063631.9A Division CN103300020B (en) | 2012-03-12 | 2012-03-12 | A kind of pesticide composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104970038A CN104970038A (en) | 2015-10-14 |
| CN104970038B true CN104970038B (en) | 2018-03-23 |
Family
ID=49126087
Family Applications (3)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510611078.1A Active CN105230632B (en) | 2012-03-12 | 2012-03-12 | A kind of composition pesticide |
| CN201510334289.5A Active CN104970038B (en) | 2012-03-12 | 2012-03-12 | A kind of composition pesticide |
| CN201210063631.9A Active CN103300020B (en) | 2012-03-12 | 2012-03-12 | A kind of pesticide composition |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510611078.1A Active CN105230632B (en) | 2012-03-12 | 2012-03-12 | A kind of composition pesticide |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201210063631.9A Active CN103300020B (en) | 2012-03-12 | 2012-03-12 | A kind of pesticide composition |
Country Status (1)
| Country | Link |
|---|---|
| CN (3) | CN105230632B (en) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103461356B (en) * | 2013-09-06 | 2015-12-23 | 刘波 | The composition pesticide of a kind of fluorine-containing mite piperazine and Avermectin |
| CN103688954A (en) * | 2013-12-10 | 2014-04-02 | 济南凯因生物科技有限公司 | Composition for controlling tangerine pest mites |
| CN104285971A (en) * | 2014-09-10 | 2015-01-21 | 广东中迅农科股份有限公司 | Acaricidal composition containing etoxazole and flutenzine |
| CN106305732B (en) * | 2015-06-18 | 2019-03-19 | 沈阳中化农药化工研发有限公司 | A kind of insecticide acaricide composition containing flufenzine |
| CR20220623A (en) | 2020-06-10 | 2023-06-14 | Valent Biosciences Llc | A mixture of pyrethroids and mectins and uses thereof |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| HU212613B (en) * | 1993-07-21 | 1996-09-30 | Chinoin Gyogyszer Es Vegyeszet | Tetrazine-derivatives, process for production of the compounds, acaricidal,larvicidal and ovicidal compositions containing the compounds as active ingredient and process for their production and their use |
| CN1166295C (en) * | 2002-07-04 | 2004-09-15 | 胡凡 | Insecticide and acaricide composition containing abamectin |
-
2012
- 2012-03-12 CN CN201510611078.1A patent/CN105230632B/en active Active
- 2012-03-12 CN CN201510334289.5A patent/CN104970038B/en active Active
- 2012-03-12 CN CN201210063631.9A patent/CN103300020B/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| CN105230632A (en) | 2016-01-13 |
| CN104970038A (en) | 2015-10-14 |
| CN103300020B (en) | 2016-06-08 |
| CN105230632B (en) | 2017-10-24 |
| CN103300020A (en) | 2013-09-18 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102349539B (en) | Insecticidal composition containing lythidathion and antibiotic compound | |
| CN101380008A (en) | Disinsection composition with synergistic action | |
| CN104970038B (en) | A kind of composition pesticide | |
| CN103355319A (en) | Insecticidal composition containing pyridalyl and biological source | |
| CN101406197B (en) | Compositional mite-killing composition containing spirodiclofen and ivermectin | |
| CN103238630A (en) | Bifenazate-bearing insecticidal composition | |
| CN103250716B (en) | A kind of Pesticidal combination containing spiral shell worm ethyl ester and neires toxin | |
| CN102228056B (en) | Pesticide composition containing sulfur-fluorine oxime ether and part of organophosphorus pesticides | |
| CN101849549B (en) | Pesticide preparation for preventing and treating rice hoppers and other rice pests | |
| CN105994275B (en) | A kind of composition pesticide of ring tebufenozide and biogenic substances | |
| CN103300036A (en) | Insecticidal composition containing flonicamid | |
| CN102487954A (en) | Insecticidal composition containing cycloxaprid and biogenic substances | |
| CN102626101B (en) | A kind of Efficient insecticidal composition containing cyflumetofen | |
| CN103355299B (en) | A kind of Pesticidal combination containing pyridalyl Yu neires toxin | |
| CN103828832B (en) | Insecticidal composition containing spirotetramat and organic tin | |
| CN103283738B (en) | A kind of Pesticidal combination containing spiral shell worm ethyl ester | |
| CN105746521B (en) | A kind of composition pesticide of fluorine-containing lice sulfanilamide (SN) and biogenic substances | |
| CN103250706A (en) | Insecticidal composition containing tolfenpyrad | |
| CN103371154B (en) | The composition pesticide of a kind of fluorine-containing lice sulfanilamide (SN) and biogenic substances | |
| CN107372522A (en) | A kind of composition pesticide containing fenazaquin | |
| CN103749530B (en) | A kind of Pesticidal combination containing Avermectin | |
| CN105475339A (en) | Synergistic insecticidal composition containing propargite and cycloprothrin and application thereof | |
| CN105557707B (en) | A kind of Pesticidal combination containing flufenzine | |
| CN103238609A (en) | Cycloxaprid-containing insecticidal composition | |
| CN101543224B (en) | Insecticidal composition containing triaguron and chlorpyrifos |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| TA01 | Transfer of patent application right | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20180208 Address after: 18 No. 448000 Jingmen city of Hubei province Duodao District chemical recycling industrial park and road. Applicant after: JINGMEN JINXIADA BIOLOGICAL TECHNOLOGY CO.,LTD. Address before: 715500 Shaanxi city of Weinan province Shaanxi Pucheng agricultural base industrial park Applicant before: Shaanxi Welch Crop Protection Co.,Ltd. |
|
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: A pesticide combination Effective date of registration: 20231124 Granted publication date: 20180323 Pledgee: Hengfeng Bank Co.,Ltd. Wuhan Branch Pledgor: JINGMEN JINXIADA BIOLOGICAL TECHNOLOGY CO.,LTD. Registration number: Y2023980067373 |