CN101543224B - Insecticidal composition containing triaguron and chlorpyrifos - Google Patents

Insecticidal composition containing triaguron and chlorpyrifos Download PDF

Info

Publication number
CN101543224B
CN101543224B CN 200910020861 CN200910020861A CN101543224B CN 101543224 B CN101543224 B CN 101543224B CN 200910020861 CN200910020861 CN 200910020861 CN 200910020861 A CN200910020861 A CN 200910020861A CN 101543224 B CN101543224 B CN 101543224B
Authority
CN
China
Prior art keywords
triaguron
chlorpyrifos
chlopyrifos
insecticidal composition
preventing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CN 200910020861
Other languages
Chinese (zh)
Other versions
CN101543224A (en
Inventor
张少武
弥华锋
曹巧利
李�瑞
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shaanxi Welch Crop Protection Co Ltd
Original Assignee
Shaanxi Welch Crop Protection Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shaanxi Welch Crop Protection Co Ltd filed Critical Shaanxi Welch Crop Protection Co Ltd
Priority to CN 200910020861 priority Critical patent/CN101543224B/en
Publication of CN101543224A publication Critical patent/CN101543224A/en
Application granted granted Critical
Publication of CN101543224B publication Critical patent/CN101543224B/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Landscapes

  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The invention relates to a high-efficiency and low-poison comosite insecticidal composition containing triaguron. The insecticidal composition comprises triaguron, chlorpyrifos, accessory ingredient and excipient and is prepared to water emulsion or microemulsion, and the weight ratio of the triaguron and the chlorpyrifos is 1:1 to 10. The insecticidal composition has higher synergy functions and fast insecticidal speed, stays pest resistance, enlarges the preventing spectrum,, and reduces drug costs and lightens toxicity. The invention is used for preventing and curing homopteran pests on fruit trees, vegetables, paddy, cotton and wheat and can be especially used for preventing and curing rice fulgorids, plant louses and white flies with the effect obviously higher than single dosage use.

Description

A kind of Pesticidal combination that contains triaguron and chlopyrifos
Technical field
The invention belongs to technical field of pesticide, being specifically related to a kind of is the Synergistic insecticidal compositions of main active with triaguron and chlopyrifos.
Background technology
Triaguron, english common name triazamate, outward appearance is a white powder, molecular formula C 13H 22N 4O 3S, chemical name is: (3-tertiary butyl-1-dimethylamino formyl-1H-1,2,4 ,-triazole-5-base sulphur) ethyl acetate.
Triaguron belongs to the high selectivity systemic insecticide, and cholinesterase is had rapid inhibitory effect, and is through the suction-operated and the contact action of aphid splanchnopleure, all effective to the various aphids on the various crop population.Dosage with the conventional control aphid is invalid to diptera and lepidoptera pest.To useful insect and honeybee safety.
Chlopyrifos: English name: (chlorpyrifos), molecular formula: C 9H 11C 13NO 3PS chemical name: O, O-diethyl-O-3,5,6-trichloro-2-pyridyl phosphorothionate.
Chlopyrifos have good tag, stomach toxicity and fumigation action.A dispenser can prevent and treat the various pests on the crop, insects such as leaf roller, coccid and leaf-roller is had outstanding especially preventive effect, and can be used for preventing and treating soil insect, domestic animal vermin and sanitary insect pest.To compare toxicity low, safe in utilization with conventional organophosphorous pesticide, little to the influence of natural enemy population, is difficult for producing resistance.
At present, the restriction increasingly stringent that both at home and abroad organic solvent is used, some national xylol has disabled trend, thereby the formulations of pesticide will be brought in constant renewal in and develop, and wherein Water-borne modification is exactly one of dominant direction of formulations of pesticide development.Therefore, just arise at the historic moment, make it become novel form and be developed and applied with aqueous emulsion, the microemulsion of organic solvent in water section or the replacing whole missible oil.
Do not see at present the relevant report of the composite product of triaguron and chlopyrifos as yet.
Summary of the invention
It is good to the purpose of this invention is to provide a kind of efficient, low-residual, low toxicity, environment compatibility, has synergistic function, the Pesticidal combination that the active ingredient that cost is low is made up of triaguron and chlopyrifos.
The present invention realizes through following technical scheme:
A kind of Pesticidal combination that contains triaguron and chlopyrifos, its effective active composition is made up of triaguron and chlopyrifos, and triaguron and chlopyrifos weight ratio are 1: 1~10.
The present invention relates to a kind of composition that contains triaguron and chlorpyrifos mixture, said composition effective active composition triaguron percentage by weight is 1%~30%, and the chlopyrifos percentage by weight is 1%~60%.
Described Pesticidal combination is characterized in that the optimum weight ratio through prescription screening triaguron and chlopyrifos is 1: 1~6.
Described Pesticidal combination active ingredient total content is 2%~60%.
The production technology that described Pesticidal combination adding auxiliary agent and excipients are all known according to those skilled in the art is processed aqueous emulsion or microemulsion.
Described auxiliary agent and excipients comprise: solvent, emulsifier, antifreeze, antifoaming agent, thickener, filler.
Described solvent is selected from N, one or more in dinethylformamide, cyclohexanone, toluene, xylol, dimethyl sulfoxide (DMSO), methyl alcohol, ethanol, 3-methyl cyclohexanol ketenes, N-octylpyrrolidone, N-pyrrolidones, propyl alcohol, butanols, ethylene glycol, diethylene glycol, EGME, butyl ether, ethyl acetate, vegetable oil, the acetonitrile.
Described emulsifier is selected from farming breast 500 #(alkyl benzene calcium sulfonate), OP series phosphate (NPE phosphate), 600 #Phosphate (phenyl phenol polyoxy ethyl ether phosphate), styrene polyoxyethylene ether ammonium sulfate salt, alkyl biphenyl ether disulfonic acid magnesium salts, triethanolamine salt, farming breast 400 #(benzyl dimethyl phenol polyoxy ethyl ether), farming breast 600 #(phenyl phenol polyoxy ethyl ether), Nongru-700 #(alkylphenol-formaldehyde resin polyoxy ethyl ether), peaceful breast 36 #(phenethyl fluosite polyoxy ethyl ether), farming breast 1600 #(phenethyl phenol polyoxy ethyl polypropylene-base ether), ethylene oxide-propylene oxide block copolymer, OP series (NPE), By series (castor oil polyoxyethylene ether), farming breast 33 #(alkylaryl polyoxyethylene polyoxypropylene ether), farming breast 34 #In (alkylaryl polyoxyethylene poly-oxygen propylene aether), sapn series (sorbitan monostearate), tween series (sorbitan fatty acid ester APEO), the AEO series (the pure APEO of fat) one or more.
Described antifreeze is selected from one or more in ethylene glycol, propane diols, glycerine, the urea.
Described antifoaming agent is selected from one or more in silicone oil, silicone compound, C10-20 saturated fat acid compounds, the C8-10 aliphatic alcohols compound.
Described thickener is selected from one or more in xanthans, CMC, hydroxyethylcellulose, methylcellulose, Magnesiumaluminumsilicate, the polyvinyl alcohol.
The Pesticidal combination that contains triaguron and chlorpyrifos mixture of the present invention is compared with single product, has the characteristics of binary Pesticidal combination; Enlarged effective active control spectrum, had obvious synergistic effect for the control of cereal, fruit tree and vegetables insect pest, and delayed the generation of pest resistance to insecticide; Lasting period is long, has reduced dosage and access times, practices thrift cost; Easy to use, saving of work and time, and reduce pollution to environment.
Embodiment
Below in conjunction with embodiment the present invention is further explained, but the present invention is not limited thereto.
Embodiment 1:20% triaguron chlorpyrifos aqueous emulsion
6g triaguron, 14g chlopyrifos, 8gN-methyl pyrrolidone, 5g xylol, 2g farming breast 500 #, the 4g Nongru-700 #, 2g farming breast 1600 #, 2g 600 #Phosphate, 4g ethylene glycol, 0.4g silicone compound, water are mended to 100g, make 20% triaguron chlorpyrifos aqueous emulsion.。
Embodiment 2:35% triaguron chlorpyrifos aqueous emulsion
5g triaguron, 30g chlopyrifos, 5gN-methyl pyrrolidone, 8g xylol, 4g farming breast 500 #, 2g farming breast 1600 #, 2gOP-10 phosphate, 4g ethylene glycol, 0.4g silicone compound, water mend to 100g, makes 35% triaguron chlorpyrifos aqueous emulsion.
Embodiment 3:45% triaguron chlorpyrifos aqueous emulsion
10g triaguron, 35g chlopyrifos, 6gN-methyl pyrrolidone, 8g xylol, 2g farming breast 600 #, 4g farming breast 500 #, 2g 600 #Phosphate, 4g ethylene glycol, 0.4g silicone compound, water are mended to 100g, make 45% triaguron chlorpyrifos aqueous emulsion.
Above-mentioned formulation material is mixed, active ingredient, solvent, emulsifier are added together, make and be dissolved into even oil phase; Water, antifreeze, thickener, antifoaming agent are mixed, become the homogeneous water.Under high-speed stirred, water is added oil phase, can make the triaguron chlorpyrifos aqueous emulsion.
Embodiment 4:30% triaguron chlorpyrifos micro emulsion
7g triaguron, 23g chlopyrifos, 5g vegetable oil, 5g N, N dimethyl pyrrolidone, 7g farming breast 600 #, 8g farming breast 500 #, 3g sorbester p17,4g 600 #Phosphate, 5g ethylene glycol, 0.4g silicone compound, water are mended to 100g, and emulsifier and water are mixed and made into water, and the former medicine that will be dissolved in then in the solvent under agitation adds water, process 30% triaguron chlorpyrifos micro emulsion.
Embodiment 5:40% triaguron chlorpyrifos micro emulsion
10g triaguron, 30g chlopyrifos, 4g vegetable oil, 6g N, N dimethyl pyrrolidone, 6g farming breast 500 #, 8g farming breast 400 #, 3gOP-10,4g OP series phosphate, 4g ethylene glycol, 0.2g silicone compound, water mend to 100g; Emulsifier and water are mixed and made into water; The former medicine that will be dissolved in then in the solvent under agitation adds water, processes 40% triaguron chlorpyrifos micro emulsion.
Embodiment 6:50% triaguron chlorpyrifos micro emulsion
15g triaguron, 35g chlopyrifos, 7g vegetable oil, 5g N, N dimethyl pyrrolidone, 5g vegetable oil, 9g farming breast 1600 #, 5g farming breast 500 #, 4g farming breast 600 #, 4g ethylene glycol, 0.4g silicone oil, water is supplied 100g, and emulsifier and water are mixed and made into water, the former medicine that will be dissolved in then in the solvent under agitation adds water, processes 50% triaguron chlorpyrifos micro emulsion.
Practice example one
Triaguron and the test of chlorpyrifos mixture pairing oranges and tangerines aphid Toxicity Determination
This EE designs 5 concentration with Pesticidal combination of the present invention respectively by active constituent content and handles in Shandong Agricultural University, adopts and soaks the worm leaf dipping method; Aphid is immersed 5s in the soup together with the oranges and tangerines blade, takes out the back and sop up the unnecessary soup on the leaf margin with blotting paper, reject have wing become aphid, if aphid; Only keep aptery one-tenth aphid; Put it into the raising of preserving moisture in the culture dish, put into 25 ℃ illumination box then, inspection survival borer population after 48 hours; Every concentration is handled repetition 3 times, the every repetition with 150 of examination worms.Calculate the insect population rate that goes down, proofread and correct the insect population rate that goes down, try to achieve virulence regression equation and calculate LC 50
The different proportionings with chlopyrifos of table 1 triaguron are used the toxicity test to the oranges and tangerines aphid with
Can know triaguron and chlorpyrifos mixture toxicity test by table 1 to the oranges and tangerines aphid; Removing proportioning is that 1: 10 o'clock co-toxicity coefficient is 114.04, and other proportionings show synergistic function all greater than 120; Triaguron wherein: chlopyrifos=co-toxicity coefficient was 159.82 in 1: 3 o'clock, and synergistic effect is particularly outstanding.
Practice example two
Handle the report of the chemical control rice hoppers test of pesticide effectiveness
Table 2 is handled chemical control rice hoppers field control effectiveness test
Can know that by table 2 triaguron and chlorpyrifos mixture have good control efficiency to rice hoppers; Preventive effect is superior to single agent preventive effect; And have quick-acting and lasting effect preferably; In this experimental drug scope, to rice safety, preparation of the present invention has good preventive effect to rice leaf roller, striped rice borer, paddy stem borer.
Practice example three
Handle the report of the chemical control oranges and tangerines aphid test of pesticide effectiveness
Table 3 is handled chemical control oranges and tangerines aphid field control effectiveness test
Figure G2009100208615D00071
Find out that by table 3 triaguron of the present invention and chlorpyrifos mixture composition have the better prevention effect to the oranges and tangerines aphid, control efficiency is that control efficiency is 83.5%~90.7% after 85.5%~93.7%, 15 days after 7 days, is superior to contrasting pharmacy control efficacy.Simultaneously, this medicament dosage is little, and to oranges and tangerines safety, Pesticidal combination of the present invention also has good control efficiency to oranges and tangerines aleyrodid, acarid in this test medicine scope.
In sum, behind triaguron and the chlorpyrifos mixture in practical application the single agent than single-activity composition show excellent more insecticidal activity, enlarged insecticidal spectrum; Control to homoptera pest has obvious role in synergism; One medicine is controlled more, has reduced the recruitment cost, has improved production efficiency; And to crop safety, environmental pollution is little.So R&D and promotion of the present invention has crucial meaning.

Claims (4)

1. a Pesticidal combination that contains triaguron and chlopyrifos is characterized in that the effective active composition is triaguron and chlopyrifos, and triaguron and chlopyrifos weight ratio are 1: 1~1: 6.
2. Pesticidal combination according to claim 1, the weight percentage that it is characterized in that triaguron and chlopyrifos is 1%~30% and 1%~60%.
3. Pesticidal combination according to claim 1 is characterized in that effective active composition total content is 2%~60%.
4. according to each described Pesticidal combination in the claim 1 to 3, it is characterized in that composition adds auxiliary agent and excipients is processed aqueous emulsion or microemulsion.
CN 200910020861 2009-01-09 2009-01-09 Insecticidal composition containing triaguron and chlorpyrifos Expired - Fee Related CN101543224B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN 200910020861 CN101543224B (en) 2009-01-09 2009-01-09 Insecticidal composition containing triaguron and chlorpyrifos

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN 200910020861 CN101543224B (en) 2009-01-09 2009-01-09 Insecticidal composition containing triaguron and chlorpyrifos

Publications (2)

Publication Number Publication Date
CN101543224A CN101543224A (en) 2009-09-30
CN101543224B true CN101543224B (en) 2012-09-26

Family

ID=41190806

Family Applications (1)

Application Number Title Priority Date Filing Date
CN 200910020861 Expired - Fee Related CN101543224B (en) 2009-01-09 2009-01-09 Insecticidal composition containing triaguron and chlorpyrifos

Country Status (1)

Country Link
CN (1) CN101543224B (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106106492A (en) * 2016-06-24 2016-11-16 叶松 A kind of compositions preventing and treating maize brown spot and preparation method thereof

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1183409A (en) * 1995-09-08 1998-06-03 化学工业部沈阳化工研究院 Insecticidal acaricidal pyrazoles compounds and preparation thereof

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1183409A (en) * 1995-09-08 1998-06-03 化学工业部沈阳化工研究院 Insecticidal acaricidal pyrazoles compounds and preparation thereof

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
徐善忠.水稻用药现状调查与思考.《安徽农学通报》.2008,(第2期),全文.
水稻用药现状调查与思考;徐善忠;《安徽农学通报》;20080131(第2期);全文 *

Also Published As

Publication number Publication date
CN101543224A (en) 2009-09-30

Similar Documents

Publication Publication Date Title
CN103355319A (en) Insecticidal composition containing pyridalyl and biological source
CN101637172B (en) Insecticidal/acaricidal composition having lufenuron and tebufenozide
CN102210321A (en) Pesticide composite containing etoxazole
CN103300020B (en) A kind of pesticide composition
CN103238613A (en) Insecticidal composition containing tolfenpyrad
CN103283762B (en) A kind of composition pesticide containing Prochloraz
CN101406197B (en) Compositional mite-killing composition containing spirodiclofen and ivermectin
CN103250716B (en) A kind of Pesticidal combination containing spiral shell worm ethyl ester and neires toxin
CN101406199A (en) Insecticidal composition containing emamectin-benzoate
CN103300036A (en) Insecticidal composition containing flonicamid
CN103355299B (en) A kind of Pesticidal combination containing pyridalyl Yu neires toxin
CN105994275B (en) A kind of composition pesticide of ring tebufenozide and biogenic substances
CN102228055A (en) Pesticide composite containing fenazaquin
CN101543224B (en) Insecticidal composition containing triaguron and chlorpyrifos
CN103828832B (en) Insecticidal composition containing spirotetramat and organic tin
CN103355320A (en) Efficient environment-friendly pesticide compound composition
CN110024803A (en) A kind of Pesticidal combination and its preparation of spirotetramat
CN101422158B (en) Insecticidal composition containing nitenpyram
CN109392909A (en) A kind of miticide composition containing fluorine pyrrole furanone and chlorfenapyr
CN102172242B (en) Insecticidal composition containing nitenpyram
CN102845459B (en) Insecticidal composition containing flubendiamide and dichlorvos
CN103651544A (en) Acaricidal composition of profenofos and etoxazole and formula instance
CN102687723B (en) Insecticidal composition and purpose of insecticidal composition
CN104430496B (en) For preventing and treating the Pesticidal combination of pear tree snout moth class pest
CN105638671B (en) A kind of high-efficient pesticide composition

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20120926

Termination date: 20170109

CF01 Termination of patent right due to non-payment of annual fee