CN103250706A - Insecticidal composition containing tolfenpyrad - Google Patents

Insecticidal composition containing tolfenpyrad Download PDF

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CN103250706A
CN103250706A CN2012100352726A CN201210035272A CN103250706A CN 103250706 A CN103250706 A CN 103250706A CN 2012100352726 A CN2012100352726 A CN 2012100352726A CN 201210035272 A CN201210035272 A CN 201210035272A CN 103250706 A CN103250706 A CN 103250706A
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tolfenpyrad
mite
active component
pyridaben
pesticidal combination
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张伟
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Shaanxi Meibang Pesticide Co Ltd
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Shaanxi Meibang Pesticide Co Ltd
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Abstract

The invention discloses an insecticidal composition containing tolfenpyrad. The insecticidal composition comprises an active component A and an active component B, wherein the active component A is selected from the tolfenpyrad, the component B is selected from anyone of propargite, clofentezine, and pyridaben, and a weight ratio of the active component A and the active component B is 1 : 70 to 70 : 1. The composition can prevent and control a plurality of insects, is obvious in synergy effect, capable of expanding insecticidal spectrum and relatively high in activities on rice hopper, aphid, Bemisia tabaci, Trialeurodes vaporariorum, Empoasca pirisuga Matumura, Tetranychus cinnbarinus, Panonychus citri, and Phyllocoptes on vegetables, fruit trees, cottons, and paddy rice; the composition reduces pesticide dosage and residual quantity of the pesticide on crops, alleviates environment pollution, and is safe to human and animals and good in environmental compatibility. Pests are not easy to have drug resistance.

Description

A kind of Pesticidal combination that contains Tolfenpyrad
Technical field
The invention belongs to technical field of pesticide, relate to a kind of Pesticidal combination that contains Tolfenpyrad.
Background technology
Tolfenpyrad (Tolfenpyrad) chemical name: 4-chloro-3-ethyl-1-methyl-N-{[4-(4-methylphenoxy) phenyl]-methyl }-1H pyrazoles-5-carboxylic acid amides, molecular formula: C 21H 22ClN 2O 2, Tolfenpyrad is novel pyrazole heterocyclic insecticidal/acaricidal agent, its main mechanism is the oxidative phosphorylation that stops insect, also has the ovum of killing, presses down food, suppresses to lay eggs and bactericidal action.This medicine insecticidal spectrum is very wide, and various bony wing orders, Semiptera, beetle order, Hymenoptera, Diptera pest and mite class are had higher control efficiency, and this medicine also has good quick-acting, and one is treated, and insect is dead at once.Be widely used in the control of insect of crops such as vegetables, fruit tree, flowers, tealeaves.
Alkynes mite spy (Propargite) chemical name: 2-(4-tert-butyl benzene oxy)-cyclohexyl Propargyl sulfite, molecular formula: C 19H 26O 4S, the alkynes mite is specially for low toxicity broad spectrum activity organosulfur acaricide, have and tag and stomach poison function, inhale in not having and the infiltration conduction, effect is extensive, can kill multiple harmful mite, also can kill the harmful mite that other insecticide has been developed immunity to drugs, no matter kill into mite, all better as if mite, young mite and mite ovum effect, be used for three more than ten years in the world, do not see drug-fast problem so far.Can be used for preventing and treating cotton, vegetables, apple, citrus, tea, the harmful mite of various crop such as flowers, safer to most natural enemies, have selectivity, safer to honeybee and natural enemy, residual effect is lasting, and toxicity is very low, and is little to people and animals and natural environment harm, is the desirable miticide of integrated control.
Two (the 2-chlorphenyls)-1,2,4 of four mite piperazine (Clofentezine) chemical name: 3,6-, 5-tetrazine, molecular formula: C 14H 8C L2N 4, four mite piperazine special efficacy miticides, lasting medicine.To the ovum that occurs in panonychus ulmi on fruit tree, cotton, the ornamental plants, congo red spider with if mite is effective, this medicine is long to the lasting period, mainly is used as ovicide, and juvenile stage is had certain preventive effect, and predacious mite and beneficial insect are not had influence.
Pyridaben (Pyridaben) chemical name: 2-tertiary butyl-5-(4-tertiary butyl benzylthio-4-chloro-3 (H)-pyridazin-3-one, molecular formula: C 19H 25ClN 2OS, pyridaben are wide spectrum, tagging property miticide, can be used for preventing and treating multiple food vegetalitas evil mite.To whole growth phase of mite be ovum, young mite, if mite with becomes mite that good effect is arranged, have tangible speed to kill equally to the one-tenth mite of mobile phase and act on.This medicine is not acted upon by temperature changes, and no matter uses in early spring or autumn, all can reach promising result.
Yet in the real process of agricultural production, the problem that pest control is easy to generate most is the generation of pest resistance to insecticide.The different cultivars composition carries out composite, is the very common method of control resistant insect.Heterogeneity is carried out composite, according to practical application effect, judge certain composite be synergy, add and or antagonism.In most cases, the composite effect of agricultural chemicals all is additive effect, and the seldom composite of synergistic effect really arranged, especially synergistic effect very obviously, co-toxicity coefficient very high composite just still less.Through inventor research, find can produce good synergistic effect after Tolfenpyrad and alkynes mite spy, four mite piperazines, pyridaben is composite, and still unexposed about the composite relevant report of Tolfenpyrad and alkynes mite spy, four mite piperazines, pyridaben.
Summary of the invention
Degradation problem under the resistance generation that the long-term use of the single agent of Tolfenpyrad may bring, the drug effect, the Pesticidal combination that the present invention proposes contains active components A, active component B, and an amount of surfactant and carrier.
A kind of Pesticidal combination that contains Tolfenpyrad, comprise active component, auxiliary agent, it is characterized in that: active components A, active component B weight ratio are 1: 70~70: 1, and described active components A is selected from Tolfenpyrad, and active component B is selected from a kind of in alkynes mite spy, four mite piperazines, the pyridaben.
The described Tolfenpyrad Pesticidal combination that contains is characterized in that: the weight ratio of active components A, active component B is 1: 50~50: 1.
The described Pesticidal combination that contains Tolfenpyrad is characterized in that: Tolfenpyrad and alkynes mite spy's weight ratio is 5: 1~1: 25.
The described Pesticidal combination that contains Tolfenpyrad is characterized in that: the weight ratio of Tolfenpyrad and four mite piperazines is 5: 1~1: 15.
The described Pesticidal combination that contains Tolfenpyrad is characterized in that: the weight ratio of Tolfenpyrad and pyridaben is 10: 1~1: 10.
The described Pesticidal combination that contains Tolfenpyrad is characterized in that: composition is made wetting powder, water dispersible granules, suspending agent, suspension emulsion, aqueous emulsion, microemulsion.
The described Pesticidal combination that contains Tolfenpyrad is used for the purposes of insect on control vegetables, fruit tree, paddy rice, the cotton.
Described purposes is characterized in that, described insect comprises: rice fulgorid, aphid, Bemisia tabaci, trialeurodes vaporariorum, tea lesser leafhopper, two spotted spider mite, Panonychus citri, rust mite etc.
The weight ratio of active components A, active component B is 1: 70~70: 1.Usually the weight percentage of active component is 0.5%~90% of gross weight in the composition, and preferable is 5%~85%.According to different preparation types, the active component content scope is different.Usually, liquid preparation contains 1%~70% active substance by weight, preferably is 5%~50%; Solid pharmaceutical preparation contains 5%~85% active substance by weight, preferably is 10%~80%.
At least contain a kind of surfactant in the Pesticidal combination of the present invention, the dispersion of active component in water when being beneficial to use.Surface-active contents is 5%~30% of total formulation weight amount, and surplus is solid or liquid diluent.
The selected surfactant of Pesticidal combination of the present invention is known in those skilled in the art: can be selected from dispersant, wetting agent, binding agent or the defoamer one or more.According to different dosage form, can also contain disintegrant known in those skilled in the art, antifreeze etc. in the preparation.
Composition of the present invention can be by the user before use through dilution or directly use.Its preparation can be by common processing method preparation known in those skilled in the art, be about to active substance and after liquid flux or solid carrier mix, add in surfactant such as dispersant, stabilizing agent, wetting agent, binding agent, the defoamer etc. one or more again.
Pesticidal combination of the present invention, can be processed into acceptable forms on any agricultural chemicals on demand, wherein the excellent formulation of selecting is: wetting powder, water dispersible granules, suspending agent, suspension emulsion, aqueous emulsion, microemulsion, wherein wetting powder, water dispersible granules, suspending agent are known formulation, manufacturing process is routine techniques, does not do introduction at this.
Comprise following constituent content when composition is made suspension emulsion: active components A 1%~50%, active component B 1%~50%, emulsifier 2%~12%, dispersant 2%~10%, defoamer 0.1%~2%, thickener 0.1%~2%, antifreeze 0.1%~8%, stabilizing agent 0.05%~3%, water add to 100%.
Dispersant, defoamer, thickener, antifreeze, stabilizing agent in the above-mentioned formulation material are mixed through high speed shear, add active component B, ball milling is 2~3 hours in ball mill, make diameter of particle all below 5 μ m, make active component B suspending agent, then with active components A, emulsifier and various auxiliary agent with the direct emulsification of high speed agitator in suspending agent, make suspension emulsion product of the present invention.
Comprise following constituent content when composition is made aqueous emulsion: active components A 1%~50%, active component B 1%~50%, solvent 0%~30%, emulsifier 1%~15%, co-emulsifier 0%~8%, antifreeze 0%~10%, thickener 0.1%~2%, defoamer 0.01%~2%, deionized water are supplied surplus.
Above-mentioned formulation material is mixed, active ingredient, solvent, emulsifier, co-emulsifier are added together, make and be dissolved into even oil phase; Water, antifreeze, thickener, defoamer are mixed, become the homogeneous water.Under high-speed stirred, water is added oil phase, make aqueous emulsion product of the present invention.
Comprise following constituent content when composition is made microemulsion: active components A 1%~50%, active component B 1%~50%, solvent 0%~30%, emulsifier 3%~20%, co-emulsifier 0%~12%, antifreeze 0%~10%, thickener 0.1%~2%, defoamer 0.01%~2%, stabilizing agent 0%~4%, deionized water is supplied surplus.
Active components A and the former medicine of active component B are dissolved in the homogenizer that solvent and cosolvent are housed; Mix strongly after joining emulsifier, stabilizing agent and antifreeze, water in the homogenizer that above-mentioned solution is housed and homogenize, obtain the as clear as crystal microemulsion product of the present invention of outward appearance at last.
Wetting powder the key technical indexes of the present invention:
Figure BDA0000136206140000061
Water dispersible granules the key technical indexes of the present invention:
Figure BDA0000136206140000062
Suspending agent the key technical indexes of the present invention:
Figure BDA0000136206140000063
Suspension emulsion the key technical indexes of the present invention:
Figure BDA0000136206140000064
Aqueous emulsion the key technical indexes of the present invention:
Figure BDA0000136206140000065
Microemulsion the key technical indexes of the present invention:
Figure BDA0000136206140000066
The invention has the advantages that:
(1) Tolfenpyrad and alkynes mite spy, four mite piperazines, pyridaben composite after, have notable synergistic and lasting effect;
(2) enlarged insecticidal spectrum, the rice fulgorid on vegetables, fruit tree, paddy rice, the cotton, aphid, Bemisia tabaci, trialeurodes vaporariorum, tea lesser leafhopper, two spotted spider mite, Panonychus citri, rust mite etc. have all been had greater activity;
(3) reduce the dosage of agricultural chemicals, reduced the residual quantity of agricultural chemicals on crop, alleviated environmental pollution;
(4) to the person poultry safety, Environmental compatibility is good, and insect is difficult for developing immunity to drugs.
Embodiment
Below in conjunction with the further instruction of the present invention of embodiment, the percentage among the embodiment all is weight percentage, but the present invention is not limited thereto.
Application Example one
The special wetting powder of example 1 30% Tolfenpyrad alkynes mite
Tolfenpyrad 5%, alkynes mite spy 25%, ester polyoxyethylene are phonetic 8%, lauryl sodium sulfate 6%, kaolin add to 100%, and mixture carries out air-flow to be pulverized, and makes the special wetting powder of 30% Tolfenpyrad alkynes mite.
The special wetting powder of example 2 70% Tolfenpyrad alkynes mites
Tolfenpyrad 1%, alkynes mite spy 69%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 7%, Nekal BX 6%, white carbon 5%, kaolin add to 100%, and mixture carries out air-flow to be pulverized, and make the special wetting powder of 70% Tolfenpyrad alkynes mite.
The special water dispersible granules of example 3 50% Tolfenpyrad alkynes mites
Tolfenpyrad 45%, alkynes mite spy 5%, octylphenol polyethylene oxyethylene group ether sulfate 7%, sldium lauryl sulfate 5%, urea 4%, white carbon add to 100%, the mixed special water dispersible granules of 50% Tolfenpyrad alkynes mite that gets.
The special water dispersible granules of example 4 25% Tolfenpyrad alkynes mites
Tolfenpyrad 5%, alkynes mite spy 20%, two (alkyl) naphthalenesulfonate formaldehyde condensation compound 5%, wetting and penetrating agent F 5%, sodium bicarbonate 4%, precipitated calcium carbonate add to 100%, the mixed special water dispersible granules of 25% Tolfenpyrad alkynes mite that gets.
The special suspending agent of example 5 35% Tolfenpyrad alkynes mites
Withered 5%, the C of Tolfenpyrad 5%, alkynes mite spy 30%, polycarboxylate 8%, tea 8~10Aliphatic alcohols 1.2%, hydroxyethylcellulose 2%, deionized water add to 100%, the mixed special suspending agent of 35% Tolfenpyrad alkynes mite that gets.
The special suspending agent of example 6 45% Tolfenpyrad alkynes mites
Tolfenpyrad 15%, alkynes mite spy 30%, aryl phenol polyoxyethylene succinate sulfonate 5%, silkworm excrement 6%, C 10~20Saturated fat acids 0.4%, melon glue 1.5%, deionized water add to 100%, the mixed special suspending agent of 45% Tolfenpyrad alkynes mite that gets.
The special suspension emulsion of example 7 30% Tolfenpyrad alkynes mites
Tolfenpyrad 5%, alkynes mite spy 25%, the phonetic formaldehyde condensation products sulphate 4% of alkylphenol-polyethenoxy, lauryl sodium sulfate 7%, benzyl dimethyl phenol polyoxy ethyl ether 6%, C 8~10Aliphatic alcohols 0.4%, Magnesiumaluminumsilicate 3%, ethylene glycol 2.5%, deionized water add to 100%, the mixed special suspension emulsion of 30% Tolfenpyrad alkynes mite that gets.
The special suspension emulsion of example 8 20% Tolfenpyrad alkynes mites
Tolfenpyrad 10%, alkynes mite spy 10%, aliphatic alcohol polyethenoxy base ether 6%, spaonin powder 6%, castor oil polyoxyethylene ether 6%, silicone oil 0.2%, polyvinylpyrrolidone 1.6%, polyethylene glycol 1.7%, deionized water add to 100%, the mixed special suspension emulsion of 20% Tolfenpyrad alkynes mite that gets.
Example 9 40% Tolfenpyrad propargite microemulsions
Tolfenpyrad 5%, alkynes mite spy 35%, alkyl benzene calcium sulfonate 6%, alkylaryl APEO 5%, phenethyl fluosite polyoxy ethyl ether 5%, phenolic resins 4%, polyethylene glycol 5%, silicone oil 0.4%, deionized water supplies 100%, the mixed 40% Tolfenpyrad propargite microemulsion that gets.
Example 10 20% Tolfenpyrad propargite microemulsions
Tolfenpyrad 10%, alkynes mite spy 10%, 3-methyl cyclohexanol ketenes 5%, diethylene glycol (DEG) 6%, xanthans 3%, fatty alcohol-polyoxyethylene ether 5%, aryl phenol polyoxyethylene succinate sulfonate 4%, silicone 0.5%, deionized water supplies 100%, makes 20% Tolfenpyrad propargite microemulsion.
The special aqueous emulsion of example 11 35% Tolfenpyrad alkynes mites
Tolfenpyrad 5%, alkynes mite spy 30%, styrene polyoxyethylene ether ammonium sulfate salt 6%, alkylaryl APEO 5%, castor oil polyoxyethylene ether 6%, glycerine 5%, gum Arabic 1.5%, C 10~20Saturated fat acids 0.3%, deionized water supplies 100%, makes the special aqueous emulsion of 35% Tolfenpyrad alkynes mite.
The special aqueous emulsion of example 12 15% Tolfenpyrad alkynes mites
Tolfenpyrad 5%, alkynes mite spy 10%, sorbitan fatty acid ester APEO 6%, alkyl biphenyl ether disulfonic acid magnesium salts 5%, polyvinylpyrrolidone 1.3%, diethylene glycol (DEG) 5%, crospolyvinylpyrrolidone 4%, silicone 0.4%, deionized water supplies 100%, makes the special aqueous emulsion of 15% Tolfenpyrad alkynes mite.
Example 13 40% Tolfenpyrad clofentezine wettable powders
Tolfenpyrad 10%, four mite piperazines 30%, polycarboxylate 8%, neopelex 5%, diatomite add to 100%, and mixture carries out air-flow to be pulverized, and makes 40% Tolfenpyrad clofentezine wettable powder.
Example 14 55% Tolfenpyrad clofentezine wettable powders
Tolfenpyrad 5%, four mite piperazines 50%, lignosulfonates 5%, neopelex 6%, kaolin add to 100%, and mixture carries out air-flow and pulverizes 55% Tolfenpyrad clofentezine wettable powder.
Example 15 50% Tolfenpyrad clofentezine water dispersible granules
Tolfenpyrad 10%, four mite piperazines 40%, the phonetic formaldehyde condensation products sulphate 6% of alkylphenol-polyethenoxy, spaonin powder 5%, sodium carbonate 4%, white carbon add to 100%, the mixed 50% Tolfenpyrad clofentezine water dispersible granule that gets.
Example 16 45% Tolfenpyrad clofentezine water dispersible granules
Tolfenpyrad 40%, four mite piperazines 5%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 8%, neopelex 6%, aluminium chloride 3%, diatomite add to 100%, the mixed 45% Tolfenpyrad clofentezine water dispersible granule that gets.
Example 17 30% Tolfenpyrad clofentezine suspension agents
Tolfenpyrad 10%, four mite piperazines 20%, alkylphenol-polyethenoxy are phonetic 7%, soapberry powder 5%, silicone 0.3%, Magnesiumaluminumsilicate 2%, deionized water add to 100%, mixed 30% Tolfenpyrad clofentezine suspension agent.
Example 18 18% Tolfenpyrad clofentezine suspension agents
Tolfenpyrad 8%, four mite piperazines 10%, ester polyoxyethylene are phonetic 7%, wetting and penetrating agent F 6%, capric acid 0.7%, polyvinylpyrrolidone 2.1%, deionized water add to 100%, mixed 18% Tolfenpyrad clofentezine suspension agent.
Example 19 20% Tolfenpyrads four mite piperazine suspension emulsions
Tolfenpyrad 10%, four mite piperazines 10%, polyoxyethylene carboxylate 7%, silkworm excrement 3%, alkylaryl polyoxyethylene poly-oxygen propylene aether 4%, silicone compound 0.5%, PAA 1.4%, propane diols 2.5%, deionized water add to 100%, mixed 20% Tolfenpyrad, the four mite piperazine suspension emulsions that get.
Example 20 35% Tolfenpyrads four mite piperazine suspension emulsions
Tolfenpyrad 5%, four mite piperazines 30%, octylphenol polyethylene oxyethylene group ether sulfate 5%, Nekal BX 4.5%, phenyl phenol polyoxy ethyl ether phosphate 6%, C 8~10Aliphatic alcohols 0.8%, polyvinylpyrrolidone 1.2%, glycerine 3.5%, deionized water add to 100%, mixed 35% Tolfenpyrad, the four mite piperazine suspension emulsions that get.
Example 21 50% Tolfenpyrads four mite piperazine microemulsions
Tolfenpyrad 20%, four mite piperazines 30%, phenethyl fluosite polyoxy ethyl ether 6%, lignosulfonates 5%, castor oil polyoxyethylene ether 5%, crospolyvinylpyrrolidone 4%, diethylene glycol (DEG) 4%, C 8~10Aliphatic alcohols 0.3%, deionized water supplies 100%, mixed 50% Tolfenpyrad, the four mite piperazine microemulsions that get.
Example 22 30% Tolfenpyrads four mite piperazine microemulsions
Tolfenpyrad 10%, four mite piperazines 20%, sorbitan fatty acid ester APEO 4%, alkylaryl APEO 6%, fatty alcohol-polyoxyethylene ether 5%, sodium phosphate trimer 2.5%, glycerine 5%, C 10~20Saturated fat acids 0.5%, deionized water supplies 100%, mixed 30% Tolfenpyrad, the four mite piperazine microemulsions that get.
Example 23 20% Tolfenpyrads four mite piperazine aqueous emulsions
Tolfenpyrad 5%, four mite piperazines 15%, styrene polyoxyethylene ether ammonium sulfate salt 5%, polyoxyethylene carboxylate 6%, sorbitan monostearate 5%, triethylene glycol 4%, PAA 2%, capric acid 0.7%, deionized water supplies 100%, makes 20% Tolfenpyrad, four mite piperazine aqueous emulsions.
Example 24 33% Tolfenpyrads four mite piperazine aqueous emulsions
Tolfenpyrad 20%, four mite piperazines 13%, ethylene oxide-propylene oxide block copolymer 8%, naphthalene sulfonic acid-formaldehyde condensation product 5%, benzyl dimethyl phenol polyoxy ethyl ether 3%, xanthans 4%, Magnesiumaluminumsilicate 3%, silicone oil 0.2%, deionized water supplies 100%, makes 33% Tolfenpyrad, four mite piperazine aqueous emulsions.
Example 25 60% Tolfenpyrad pyridaben wetting powders
Tolfenpyrad 30%, pyridaben 30%, the phonetic formaldehyde condensation products sulphate 6% of alkylphenol-polyethenoxy, sldium lauryl sulfate 5%, bentonite add to 100%, and mixture carries out air-flow to be pulverized, and makes 60% Tolfenpyrad pyridaben wetting powder.
Example 26 40% Tolfenpyrad pyridaben wetting powders
Tolfenpyrad 10%, pyridaben 30%, the phonetic formaldehyde condensation products sulphate 4% of alkylphenol-polyethenoxy, spaonin powder 6%, attapulgite add to 100%, and mixture carries out air-flow to be pulverized, and makes 40% Tolfenpyrad pyridaben wetting powder.
Example 27 50% Tolfenpyrad pyridaben water dispersible granules
Tolfenpyrad 20%, pyridaben 30%, alkylaryl APEO 7%, wetting and penetrating agent F 6%, urea 3%, starch add to 100%, the mixed 50% Tolfenpyrad pyridaben water dispersible granules that gets.
Example 28 30% Tolfenpyrad pyridaben water dispersible granules
Tolfenpyrad 10%, pyridaben 20%, octylphenol polyethylene oxyethylene group ether sulfate 6%, sldium lauryl sulfate 4%, glucose 1.5%, white carbon add to 100%, the mixed 30% Tolfenpyrad pyridaben water dispersible granules that gets.
Example 29 40% Tolfenpyrad Damanling suspension agents
Tolfenpyrad 25%, pyridaben 15%, aliphatic amine polyoxyethylene are phonetic 6%, spaonin powder 5%, C 10~20Saturated fat acids 0.7%, gum Arabic 1.1%, deionized water add to 100%, the mixed 40% Tolfenpyrad Damanling suspension agent that gets.
Example 30 35% Tolfenpyrad Damanling suspension agents
Tolfenpyrad 5%, pyridaben 30%, alkylaryl APEO 7%, sldium lauryl sulfate 5%, C 8~10Aliphatic alcohols 0.8%, melon glue 1.3%, deionized water add to 100%, the mixed 35% Tolfenpyrad Damanling suspension agent that gets.
Example 31 40% Tolfenpyrad pyridaben suspension emulsions
Tolfenpyrad 10%, pyridaben 30%, lignosulfonates 4%, tea are withered 5%, benzyl dimethyl phenol polyoxy ethyl ether 6%, C 8~10Aliphatic alcohols 0.4%, melon glue 1.5%, glycerine 3%, deionized water add to 100%, the mixed 40% Tolfenpyrad pyridaben suspension emulsion that gets.
Example 32 15% Tolfenpyrad pyridaben suspension emulsions
Tolfenpyrad 10%, pyridaben 5%, alkylphenol-polyethenoxy are phonetic 4.5%, spaonin powder 6%, phenethyl fluosite polyoxy ethyl ether 4%, silicone oil 0.5%, gum Arabic 1.5%, polyethylene glycol 3%, deionized water add to 100%, mixed 15% Tolfenpyrad pyridaben suspension emulsion.
Example 33 20% Tolfenpyrad pyridaben micro-emulsions
Tolfenpyrad 10%, pyridaben 10%, alkylaryl polyoxyethylene poly-oxygen propylene aether 5%, polycarboxylate 4%, benzyl dimethyl phenol polyoxy ethyl ether 4%, polyvinyl alcohol 3%, glycerine 5%, silicone 0.5%, deionized water supplies 100%, the mixed 20% Tolfenpyrad pyridaben micro-emulsion that gets.
Example 34 35% Tolfenpyrad pyridaben micro-emulsions
Tolfenpyrad 15%, pyridaben 20%, fatty alcohol-polyoxyethylene ether 3%, the phonetic formaldehyde condensation products sulphate 4% of alkylphenol-polyethenoxy, benzyl dimethyl phenol polyoxy ethyl ether 6%, methylcellulose 3%, ethylene glycol 6%, C 8~10Aliphatic alcohols 0.3%, deionized water supplies 100%, the mixed 35% Tolfenpyrad pyridaben micro-emulsion that gets.
Example 35 30% Tolfenpyrad pyridaben aqueous emulsions
Tolfenpyrad 10%, pyridaben 20%, alkylphenol-formaldehyde resin polyoxy ethyl ether 6%, the phonetic formaldehyde condensation products sulphate 5% of alkylphenol-polyethenoxy, castor oil polyoxyethylene ether 4%, diethylene glycol (DEG) 5%, polyvinylpyrrolidone 3%, silicone 0.5%, deionized water supplies 100%, makes 30% Tolfenpyrad pyridaben aqueous emulsion.
Example 36 25% Tolfenpyrad pyridaben aqueous emulsions
Tolfenpyrad 15%, pyridaben 10%, sorbitan fatty acid ester APEO 7%, polyoxyethylene carboxylate 3%, fatty alcohol-polyoxyethylene ether 4%, polyethylene glycol 5%, white dextrin 4%, capric acid 0.5%, deionized water supplies 100%, makes 25% Tolfenpyrad pyridaben aqueous emulsion.
The embodiment of the invention is the method that adopts Toxicity Determination and field trial to combine.Earlier by Toxicity Determination, the co-toxicity coefficient (CTC) after clear and definite two kinds of medicaments are composite by a certain percentage, CTC<80 are antagonism, and 80≤CTC≤120 are summation action, and CTC>120 are synergistic effect, on this basis, carry out field trial again.
Test method: respectively the mother liquor of each mixed agent is diluted to five series concentration during test, places beaker standby respectively.Adopt and to soak the method that connects worm behind the leaf earlier, the blade of the same size that does not contact any medicament soaked in the soup that configures behind the 5s take out, dry naturally, put into insect box, connect then for the examination larva, under 25 ℃ of conditions, raise, every processing repeats for 3 times, every to repeat used examination borer population be 50, establishes blank simultaneously, checks dead borer population in 72h, calculate lethality and corrected mortality, try to achieve virulence regression equation and calculate LC 50Value.If the contrast lethality then is considered as invalid test greater than 10%.Computing formula is as follows:
Figure BDA0000136206140000151
The insect corrected mortality is converted into probit value (y), and concentration for the treatment of (μ g/ml) converts logarithm value (x) to, draws virulence regression equation with method of least squares, and calculates the value of every kind of medicament thus.Calculate co-toxicity coefficient CTC according to the abundant equation of Sun Yun.Computing formula following (be standard medicament with the Tolfenpyrad, its toxicity index is 100):
Figure BDA0000136206140000153
Figure BDA0000136206140000154
TI * the P of theoretical toxicity index (TTI)=Tolfenpyrad of M TolfenpyradTI * P of+effective active composition B Effective active composition B
Figure BDA0000136206140000161
In the formula: M is the mixture of different proportionings
P Effective active composition BBe effective active composition B shared ratio in composition
P TolfenpyradBe Tolfenpyrad shared ratio in composition
A is selected from Tolfenpyrad;
B is selected from a kind of in alkynes mite spy, four mite piperazines, the pyridaben.
Application Example two:
For trying insect: rice fulgorid.
Test medicine provides by Shaanxi agricultural chemicals Co., Ltd of U.S. nation.
Experimental scheme: effective lethal concentration scope of determining Tolfenpyrad, propargite medicine and the two different proportioning mixture through preliminary experiment.
Toxicity test result one
Table 1 Tolfenpyrad and the toxicity test of the special different proportionings of alkynes mite to rice fulgorid
As shown in Table 1, the proportioning of the special composite control of Tolfenpyrad and alkynes mite rice fulgorid was at 60: 1 to 1: 60 o'clock, co-toxicity coefficient is all greater than 120, illustrating that both were mixed in the scope at 60: 1 to 1: 60 all shows synergistic effect, especially when Tolfenpyrad and alkynes mite spy's proportioning during at 5: 1 to 1: 15, synergistic effect is more obviously outstanding, test through the applicant, the optimum ratio of finding Tolfenpyrad and alkynes mite spy is 5: 1,4: 1,3: 1,2: 1,1: 1,1: 2,1: 3,1: 4,1: 5,1: 6,1: 7,1: 8,1: 9,1: 10,1: 11,1: 12,1: 13,1: 14,1: 15, co-toxicity coefficient maximum when the special weight ratio of Tolfenpyrad and alkynes mite is 1: 5 wherein, synergistic effect is the most obvious.
Application Example three:
For trying insect: two spotted spider mite.
Test medicine provides by Shaanxi agricultural chemicals Co., Ltd of U.S. nation.
Experimental scheme: effective lethal concentration scope of determining Tolfenpyrad, the former medicine of four mite piperazines and the two different proportioning mixture through preliminary experiment.
Toxicity test result two
Table 2 Tolfenpyrad and the toxicity test of the different proportionings of four mite piperazines to two spotted spider mite
Figure BDA0000136206140000171
As shown in Table 2, the proportioning of the composite control of Tolfenpyrad and four mite piperazines two spotted spider mite was at 60: 1 to 1: 60 o'clock, co-toxicity coefficient is all greater than 120, illustrating that both were mixed in the scope at 60: 1 to 1: 60 all shows synergistic effect, especially when the proportioning of Tolfenpyrad and four mite piperazines during at 5: 1 to 1: 10, synergistic effect is more obviously outstanding, test through the applicant, the optimum ratio of finding Tolfenpyrad and four mite piperazines is 5: 1,4: 1,3: 1,2: 1,1: 1,1: 2,1: 3,1: 4,1: 5,1: 6,1: 7,1: 8,1: 9,1: 10, co-toxicity coefficient maximum when Tolfenpyrad and four mite piperazine weight ratios are 1: 3 wherein, synergistic effect is the most obvious.
Application Example four:
For trying insect: aphid.
Test medicine provides by Shaanxi agricultural chemicals Co., Ltd of U.S. nation.
Experimental scheme: effective lethal concentration scope of determining Tolfenpyrad, the former medicine of pyridaben and the two different proportioning mixture through preliminary experiment.
Toxicity test result three
The different proportionings with pyridaben of table 3 Tolfenpyrad are to the toxicity test of aphid
Figure BDA0000136206140000181
As shown in Table 3, the composite anti-proportioning that eliminates aphis of Tolfenpyrad and pyridaben was at 60: 1 to 1: 60 o'clock, co-toxicity coefficient is all greater than 120, illustrating that both were mixed in the scope at 60: 1 to 1: 60 all shows synergistic effect, especially when the proportioning of Tolfenpyrad and pyridaben during at 5: 1 to 1: 10, synergistic effect is more obviously outstanding, test through the applicant, the optimum ratio of finding Tolfenpyrad and pyridaben is 5: 1,4: 1,3: 1,2: 1,1: 1,1: 2,1: 3,1: 4,1: 5,1: 6,1: 7,1: 8,1: 9,1: 10, co-toxicity coefficient maximum when Tolfenpyrad and pyridaben weight ratio are 1: 1 wherein, synergistic effect is the most obvious.
Special and the composite control tomato trialeurodes vaporariorum test of pesticide effectiveness of Application Example pentazole insect amide and alkynes mite
This experimental establishment is at Baoji, Shaanxi province city Chencang District, and test medicine is researched and developed, provided by Shaanxi agricultural chemicals Co., Ltd of U.S. nation, contrast medicament 15% Tolfenpyrad missible oil (commercial), the special missible oil (commercial) of 40% alkynes mite.
Investigation tomato trialeurodes vaporariorum insect pest index in the dispenser of insect pest initial stage of origination, was investigated the insect pest indexes in 1 day, 3 days, 7 days after the dispenser and is calculated preventive effect before the medicine.Experimental result is as follows:
Table 4 Tolfenpyrad, alkynes mite spy and the composite control tomato trialeurodes vaporariorum test of pesticide effectiveness thereof
As can be seen from Table 4, can effectively prevent and treat the tomato trialeurodes vaporariorum after Tolfenpyrad and alkynes mite are special composite, control efficiency all is better than the preventive effect of single agent, and the preventive effect time is long.In the test scope of medication, the target crop is had no adverse effects.
Application Example six Tolfenpyrads and four mite piperazines and the composite rice hoppers test of pesticide effectiveness of preventing and treating thereof
This experimental establishment is in Gongan County, Jingzhou City, Hubei Province, and test medicine is researched and developed, provided by Shaanxi agricultural chemicals Co., Ltd of U.S. nation, contrast medicament 15% Tolfenpyrad missible oil (commercial), 400 grams per liter clofentezine suspension agents (commercial).
Investigation rice hoppers insect pest index before the medicine in the dispenser of insect pest initial stage of origination, was investigated the insect pest indexes in 1 day, 3 days, 7 days after the dispenser and is calculated preventive effect.Experimental result is as follows:
Table 5 Tolfenpyrad, four mite piperazines and the composite rice hoppers test of pesticide effectiveness of preventing and treating thereof
Figure BDA0000136206140000201
As can be seen from Table 5, can effectively prevent and treat rice hoppers after Tolfenpyrad and four mite piperazines are composite, control efficiency all is better than the preventive effect of single agent, and the preventive effect time is long.In the test scope of medication, the target crop is had no adverse effects.
Application Example seven Tolfenpyrads and pyridaben and the composite control apple tree two spotted spider mite test of pesticide effectiveness thereof
This experimental establishment is in Liquan County, Xianyang, Shanxi province city, and test medicine is researched and developed, provided by Shaanxi agricultural chemicals Co., Ltd of U.S. nation, contrast medicament 15% Tolfenpyrad missible oil (commercial), 20% pyridaben wetting powder (commercial).
Investigation apple tree two spotted spider mite insect pest index in the dispenser of insect pest initial stage of origination, was investigated the insect pest indexes in 1 day, 15 days, 30 days after the dispenser and is calculated preventive effect before the medicine.Experimental result is as follows:
Table 6 Tolfenpyrad, pyridaben and the composite control apple tree two spotted spider mite test of pesticide effectiveness thereof
Figure BDA0000136206140000211
As can be seen from Table 6, energy effectively preventing and treating apple-tree two spotted spider mite after Tolfenpyrad and pyridaben are composite, control efficiency all is better than the preventive effect of single agent, and the preventive effect time is long.In the test scope of medication, the target crop is had no adverse effects.
After draw through different local throughout the country tests, described contain the Pesticidal combination of Tolfenpyrad to the preventive effect of insect pests such as the rice fulgorids of various crops, aphid, Bemisia tabaci, trialeurodes vaporariorum, tea lesser leafhopper, two spotted spider mite, Panonychus citri, rust mite all more than 95%, be better than single agent preventive effect, synergistic effect is obvious.

Claims (9)

1. Pesticidal combination that contains Tolfenpyrad, comprise active component, auxiliary agent, it is characterized in that: active components A, active component B weight ratio are 1: 70~70: 1, and described active components A is selected from Tolfenpyrad, and active component B is selected from a kind of in alkynes mite spy, four mite piperazines, the pyridaben.
2. the Tolfenpyrad Pesticidal combination that contains according to claim 1, it is characterized in that: the weight ratio of active components A, active component B is 1: 50~50: 1.
3. the Pesticidal combination that contains Tolfenpyrad according to claim 2, it is characterized in that: Tolfenpyrad and alkynes mite spy's weight ratio is 5: 1~1: 25.
4. the Pesticidal combination that contains Tolfenpyrad according to claim 2, it is characterized in that: the weight ratio of Tolfenpyrad and four mite piperazines is 5: 1~1: 15.
5. the Pesticidal combination that contains Tolfenpyrad according to claim 2, it is characterized in that: the weight ratio of Tolfenpyrad and pyridaben is 10: 1~1: 10.
6. insecticides according to claim 1, its active ingredient total content is 0.5%~90%.
7. the Pesticidal combination that contains Tolfenpyrad according to claim 1, it is characterized in that: composition is made wetting powder, water dispersible granules, suspending agent, suspension emulsion, aqueous emulsion, microemulsion.
8. the purposes that is used for insect on control vegetables, fruit tree, paddy rice, the cotton according to each the described Pesticidal combination that contains Tolfenpyrad in the claim 1~7.
9. purposes according to claim 8 is characterized in that, described insect comprises: rice fulgorid, aphid, Bemisia tabaci, trialeurodes vaporariorum, tea lesser leafhopper, two spotted spider mite, Panonychus citri, rust mite.
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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104982442A (en) * 2015-07-08 2015-10-21 广东中迅农科股份有限公司 Pesticide composition containing tolfenpyrad and flutenzine
CN104996434A (en) * 2015-07-08 2015-10-28 广东中迅农科股份有限公司 Pesticide composition containing tolfenpxrad and etoxazole

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0365925A1 (en) * 1988-10-14 1990-05-02 Mitsubishi Chemical Corporation Pyrazole amides and insecticide and miticide containing them as active ingredient
JP2006131516A (en) * 2004-11-04 2006-05-25 Nippon Nohyaku Co Ltd Pest control agent composition and method for use thereof

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0365925A1 (en) * 1988-10-14 1990-05-02 Mitsubishi Chemical Corporation Pyrazole amides and insecticide and miticide containing them as active ingredient
JP2006131516A (en) * 2004-11-04 2006-05-25 Nippon Nohyaku Co Ltd Pest control agent composition and method for use thereof

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104982442A (en) * 2015-07-08 2015-10-21 广东中迅农科股份有限公司 Pesticide composition containing tolfenpyrad and flutenzine
CN104996434A (en) * 2015-07-08 2015-10-28 广东中迅农科股份有限公司 Pesticide composition containing tolfenpxrad and etoxazole
CN104982442B (en) * 2015-07-08 2018-08-14 广东中迅农科股份有限公司 Composition pesticide containing Tolfenpyrad and flufenzine

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