CN102084862B - Insecticidal composition containing ethiprole - Google Patents

Insecticidal composition containing ethiprole Download PDF

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Publication number
CN102084862B
CN102084862B CN201110066551.4A CN201110066551A CN102084862B CN 102084862 B CN102084862 B CN 102084862B CN 201110066551 A CN201110066551 A CN 201110066551A CN 102084862 B CN102084862 B CN 102084862B
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worm nitrile
active ingredient
rynaxypyr
rice
fipronil bisamide
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CN102084862A (en
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张伟
高超
曹巧利
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Shanxi Thompson Biological Technology Co Ltd
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Shanxi Thompson Biological Technology Co Ltd
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Abstract

The invention discloses an insecticidal composition containing ethiprole, which contains an active ingredient A and an active ingredient B, wherein the active ingredient A is selected from the ethiprole, the active ingredient B is selected from any one of following insecticides: fipronil bisamide and chlorantraniliprole, and the ratio of the active ingredient A to the active ingredient B by weight percent is 1-40%: 1-40%. The composition can be used for controlling a variety of insect pests, has obvious synergy, expands an insecticidal spectrum and has higher activity for rice fulgorid, rice-stem borer, yellow rice borer, rice leaf folder, beet armyworm, diamondback moth, apple peach fruit borer and asiatic apple leafminer; furthermore, the dosage of pesticide can be reduced, the residual quantity of the pesticide on crops can be reduced, and the environmental pollution can be also reduced; and the insecticidal composition is safe to people and animals, and good in environmental compatibility, and the insect pests are less prone to generating medicament resistance.

Description

A kind of Pesticidal combination that contains second worm nitrile
Technical field
The invention belongs to technical field of pesticide, relate to a kind of Pesticidal combination that contains second worm nitrile.
Background technology
Second worm nitrile, English common name (ethiprole), molecular formula: C 13h 9cl 2f 3n 4oS, sub-sulphur (sulphur) acyl group of chemical name: 5-amino-1-(2,6-dichloro-4-fluoromethylphenyl)-4-ethyl pyrazoles-3-itrile group.Second worm nitrile is novel pyrazole insecticides, and insecticidal spectrum is wide.Disturb chloride channel by γ-aminobutyric acid (GABA), make insect lethal thereby destroy central nervous system (CNS) normal activity.This medicine is tightr to the white clothing constraint comparison vertebrate of insect GABA chloride channel.Thereby provide very high selection toxicity.Its mechanism of action is different from the main insecticide families such as pyrethroid, organic phosphor, carbamate, does not almost produce the chance of interactivity with the existing insecticide of majority.Therefore, it is the desirable standby kind of resistance management, can be with the mixed pesticide of other chemical family, be used alternatingly.
But in the real process of agricultural production, the problem that pest control the most easily produces is the generation of pest resistance to insecticide.Insect important in agricultural is if lepidoptera pest is because its breeding cycle is short, and breeding amount is large, and mobility is little, and selfing degree is high, especially easily produces resistance.
Different cultivars composition carries out composite, is the very common method of control resistant insect.Heterogeneity is carried out composite, according to practical application effect, judge certain composite be synergy, add and or antagonism.In most cases, the composite effect of agricultural chemicals is all additive effect, really have a synergistic effect composite seldom, especially synergistic effect very obviously, co-toxicity coefficient very high composite just still less.Through inventor research, find after second worm nitrile and fipronil bisamide, Rynaxypyr is composite to produce good synergistic effect, and not yet open about the composite relevant report of second worm nitrile and fipronil bisamide, Rynaxypyr.
Summary of the invention
Resistance that the long-term use of second worm nitrile single dose may bring occurs, degradation problem under drug effect, and the Pesticidal combination that the present invention proposes contains A, two kinds of active components of B, and appropriate surfactant and carrier.
A kind of Pesticidal combination that contains second worm nitrile, comprise effective active component, auxiliary agent and filler, it is characterized in that: active components A, B percentage by weight are 1～40%: 1～40%, described active components A is selected from second worm nitrile, and active component B is selected from the one in fipronil bisamide, Rynaxypyr.
Described a kind of Pesticidal combination that contains second worm nitrile, is characterized in that: the percentage by weight of A, two kinds of active components of B is 1～30%: 1～30%.
The described Pesticidal combination that contains second worm nitrile, is characterized in that: the percentage by weight of second worm nitrile and fipronil bisamide is 5～20%: 5～20%;
The described Pesticidal combination that contains second worm nitrile, is characterized in that: the percentage by weight of second worm nitrile and Rynaxypyr is 5～20%: 5～20%.
The percentage by weight of A, two kinds of active components of B is 1～40%: 1～40%.Conventionally in composition, active weight percentage is gross weight 0.5～90%, is preferably 5%～85%.According to different preparation types, active component content scope is different.Conventionally, liquid preparation contains 1～70% active substance by weight, is preferably 5～50%; Solid pharmaceutical preparation contains 5～85% active substance by weight, is preferably 10～80%.
In Pesticidal combination of the present invention, at least contain a kind of surfactant, the dispersion of active component in water while being beneficial to use.Surface-active contents is 5～30% of total formulation weight amount, and surplus is solid or liquid diluent.
The selected surfactant of Pesticidal combination of the present invention is known in those skilled in the art: can be selected from one or more in dispersant, wetting agent, binding agent or defoamer.According to different dosage form, in preparation, can also contain disintegrant known in those skilled in the art, antifreeze etc.
Described dispersant is selected from alkylnaphthalene sulfonate, two (alkyl) naphthalenesulfonate formaldehyde condensation compound, naphthalene sulfonic acid-formaldehyde condensation product, aryl phenol polyoxyethylene succinate sulfonate, octylphenol polyethylene oxyethylene group ether sulfate, polycarboxylate, lignosulfonates, the phonetic formaldehyde condensation products sulphate of alkylphenol-polyethenoxy, alkyl benzene sulfonate calcium salt, naphthalene sulfonic acid-formaldehyde condensation product sodium salt, alkylphenol-polyethenoxy is phonetic, aliphatic amine polyoxyethylene is phonetic, polyoxyethylene carboxylate, one or more during ester polyoxyethylene is phonetic.
Described wetting agent is selected from: one or more in lauryl sodium sulfate, neopelex, Nekal BX, wetting and penetrating agent F, spaonin powder, silkworm excrement, soapberry powder.
Described disintegrant is selected from: one or more in bentonite, urea, ammonium sulfate, aluminium chloride.
Described binding agent is selected from: one or more in gum Arabic, xanthans, sodium phosphate trimer, phenolic resins, sodium alginate, white dextrin, methylcellulose, PAA, polyvinylpyrrolidone, crospolyvinylpyrrolidone, polyethylene glycol, polyvinyl alcohol.
Described antifreeze is selected from: one or more in ethylene glycol, propane diols, glycerine, polyethylene glycol.
Described defoamer is selected from: silicone, C 8～10aliphatic alcohols, C 10～20one or more in saturated fat acids (as capric acid) and acid amides, silicone oil, silicone compound.
Described filler is selected from: one or more in kaolin, diatomite, bentonite, attapulgite, white carbon, starch, precipitated calcium carbonate.
Composition of the present invention can be by user before use through dilution or directly use.Its preparation can be prepared by common processing method, after mixing, then adds surfactant as one or more in dispersant, stabilizing agent, wetting agent, adhesive, defoamer etc. by active substance with liquid flux or solid carrier.
Pesticidal combination of the present invention, can be processed into acceptable formulation on any agricultural chemicals on demand.Wherein preferred dosage form is wetting powder, water dispersible granules, suspending agent.
When making wetting powder, composition comprises following constituent content: second worm nitrile 1～40%, active component B 1～40%, dispersant 5～10%, wetting agent 2～10%, filler 8～91%.
Active component second worm nitrile, active component B, dispersant, wetting agent, filler are mixed, in mixed cylinder, mix, after airslide disintegrating mill is pulverized, mix again, can be made into the wetting powder product of the present composition.
When making water dispersible granules, composition comprises following constituent content: active component second worm nitrile 1～40%, active component B 1～40%, dispersant 3～12%, wetting agent 1～8%, disintegrant 1～10%, binding agent 1～8%, filler 10～92%.
Active component second worm nitrile, active component B, dispersant, wetting agent, disintegrant, filler etc. are obtained to the particle diameter needing through air-flow crushing together, then add other auxiliary agents such as binding agent, obtain the materials of granulating.By item quantitatively send in fluidized bed granulation dryer through granulation and dry after, make the water dispersible granules product of the present composition.
When making suspending agent, composition comprises following constituent content: active component second worm nitrile 1～25%, active component B 1～25%, dispersant 2～10%, wetting agent 2～10%, defoamer 0.1～1%, binding agent 0.1～2%, antifreeze 0.1～8%, deionized water add to 100%.
Dispersant, wetting agent, defoamer, thickener, antifreeze in above-mentioned formulation material are mixed through high speed shear, add active component second worm nitrile, active component B, ball milling 2～3 hours in ball mill, make diameter of particle all below 5 μ m, make the suspending agent product of the present composition.
The invention has the advantages that: after (1) second worm nitrile and active component B are composite, there is notable synergistic and lasting effect; (2) expanded insecticidal spectrum, rice fulgorid, rice-stem borer, paddy stem borer, rice leaf roller, beet armyworm, diamond-back moth, apple peach fruit borer, apple apple leaf miner have been had to greater activity; (3) reduce the dosage of agricultural chemicals, reduced the residual quantity of agricultural chemicals on crop, alleviated environmental pollution; (4), insect good to person poultry safety, Environmental compatibility is difficult for developing immunity to drugs.
Embodiment
Below in conjunction with embodiment, to further instruction of the present invention, the percentage in embodiment is all weight percentage, but the present invention is not limited thereto.
Application Example one
Example 1 48% second worm nitrile fipronil bisamide wetting powder
Second worm nitrile 8%, fipronil bisamide 40%, lignosulfonates 7%, soapberry powder 6%, bentonite add to 100%, and mixture carries out air-flow crushing, make 48% second worm nitrile fipronil bisamide wetting powder.
Example 2 50% second worm nitrile fipronil bisamide wetting powders
Second worm nitrile 25%, fipronil bisamide 25%, alkyl benzene sulfonate calcium salt 8%, wetting and penetrating agent F 6%, diatomite add to 100%, and mixture carries out air-flow crushing, make 50% second worm nitrile fipronil bisamide wetting powder.
Example 3 40% second worm nitrile fipronil bisamide water dispersible granules
Second worm nitrile 10%, fipronil bisamide 30%, two (alkyl) naphthalenesulfonate formaldehyde condensation compound 6%, spaonin powder 4%, urea 2%, kaolin add to 100%, mix and make 40% second worm nitrile fipronil bisamide water dispersible granules.
Example 4 60% second worm nitrile fipronil bisamide water dispersible granules
Second worm nitrile 20%, fipronil bisamide 40%, alkylphenol-polyethenoxy are phonetic 8%, lauryl sodium sulfate 7%, sodium carbonate 1.8%, attapulgite add to 100%, mix and make 60% second worm nitrile fipronil bisamide water dispersible granules.
Example 5 10% second worm nitrile fipronil bisamide suspension agents
Second worm nitrile 5%, fipronil bisamide 5%, aryl phenol polyoxyethylene succinate sulfonate 7%, soapberry powder 5%, silicone compound 0.1%, polyvinylpyrrolidone 1.5%, propane diols 1.8%, deionized water add to 100%, mix and make 10% second worm nitrile fipronil bisamide suspension agent.
Example 6 30% second worm nitrile fipronil bisamide suspension agents
Second worm nitrile 20%, fipronil bisamide 10%, the phonetic formaldehyde condensation products sulphate 8% of alkylphenol-polyethenoxy, Nekal BX 6%, C 10～20saturated fat acids 0.2%, gum Arabic 1.2%, triethylene glycol 1.6%, deionized water add to 100%, mix and make 30% second worm nitrile fipronil bisamide suspension agent.
Example 7 45% second worm nitrile Rynaxypyr wetting powders
Second worm nitrile 15%, Rynaxypyr 30%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 8%, tea are withered 7%, attapulgite adds to 100%, and mixture carries out air-flow crushing, makes 45% second worm nitrile Rynaxypyr wetting powder.
Example 8 46% second worm nitrile Rynaxypyr wetting powders
Second worm nitrile 40%, Rynaxypyr 6%, polyoxyethylene carboxylate 6%, spaonin powder 5%, kaolin add to 100%, and mixture carries out air-flow crushing, make 46% second worm nitrile Rynaxypyr wetting powder.
Example 9 40% second worm nitrile Rynaxypyr water dispersible granules
Second worm nitrile 20%, Rynaxypyr 20%, polycarboxylate 7%, lauryl sodium sulfate 6%, ammonium sulfate 2.2%, bentonite add to 100%, mix and make 40% second worm nitrile Rynaxypyr water dispersible granules.
Example 10 50% second worm nitrile Rynaxypyr water dispersible granules
Second worm nitrile 10%, Rynaxypyr 40%, aliphatic amine polyoxyethylene are phonetic 6%, silkworm excrement 4%, aluminium chloride 2.5%, diatomite add to 100%, mix and make 50% second worm nitrile Rynaxypyr water dispersible granules.
Example 11 20% second worm nitrile Rynaxypyr suspending agents
Second worm nitrile 10%, Rynaxypyr 10%, octylphenol polyethylene oxyethylene group ether sulfate 6%, DBSA 5%, C 8～10aliphatic alcohols 0.5%, methylcellulose 1.4%, ethylene glycol 1.3%, deionized water add to 100%, mix and make 20% second worm nitrile Rynaxypyr suspending agent.
Example 12 35% second worm nitrile Rynaxypyr suspending agents
Second worm nitrile 20%, Rynaxypyr 15%, two (alkyl) naphthalenesulfonate formaldehyde condensation compound 7%, wetting and penetrating agent F 6%, silicone compound 0.2%, sodium phosphate trimer 1.5%, glycerine 1.2%, deionized water add to 100%, mix and make 35% second worm nitrile Rynaxypyr suspending agent.
The embodiment of the present invention is the method that adopts Toxicity Determination and field trial to combine.First pass through Toxicity Determination, co-toxicity coefficient (CTC) after clear and definite two kinds of medicaments are composite by a certain percentage, CTC < 80 is antagonism, 80≤CTC≤120 are summation action, CTC > 120 is synergistic effect, on this basis, then carry out field trial.
Test method: respectively the mother liquor of the each mixed agent of second worm nitrile effective active composition B is diluted to five series concentration when test, is placed in respectively beaker for subsequent use.Adopt and first soak the method that connects worm after leaf, after the blade of the same size that does not contact any medicament is soaked to 5s in the liquid configuring, take out, naturally dry, put into insect box, then connect for examination 3 instar larvaes, under 25 ℃ of conditions, raise, every processing repeats for 3 times, every to repeat examination borer population used be 20, establishes blank simultaneously, checks dead borer population in 72h, calculate lethality and corrected mortality, try to achieve virulence regression equation and calculate LC 50value.If contrast lethality is greater than 10%, be considered as invalid test.Computing formula is as follows:
Insect corrected mortality is converted into probit value (y), and concentration for the treatment of (μ g/ml) converts logarithm value (x) to, draws virulence regression equation with method of least squares, and calculates thus the value of every kind of medicament.Calculate co-toxicity coefficient CTC according to the abundant equation of Sun Yun.Computing formula following (take second worm nitrile as standard medicament, its toxicity index is 100):
TI × the P of theoretical toxicity index (TTI)=second worm nitrile of M second worm nitriletI × P of+effective active composition B effective active composition B
In formula: the mixture that M is different proportionings
P effective active composition Bfor effective active composition B shared ratio in composition
P second worm nitrilefor second worm nitrile shared ratio in composition
A is selected from second worm nitrile;
B is selected from following any one insecticide: the one in fipronil bisamide, Rynaxypyr.
Application Example two:
For trying insect: Laphygma exigua Hubner.
Test medicine provides by Shanxi Thompson Biological Technology Co., Ltd..
Experimental scheme: effective lethal concentration scope of determining second worm nitrile, the former medicine of fipronil bisamide and the two different proportioning mixture through preliminary experiment.
Toxicity test result one
The toxicity test of table 1 second worm nitrile proportionings different from fipronil bisamide to Laphygma exigua Hubner
As shown in Table 1, the proportioning of the composite control Laphygma exigua Hubner of second worm nitrile and fipronil bisamide was at 40: 1 to 1: 40 o'clock, co-toxicity coefficient is all greater than 120, illustrate that both all show synergistic effect at mixture in 40: 1 to 1: 40 scopes, especially in the time that second worm nitrile and fipronil bisamide obtain proportioning at 5: 1 to 1: 5, synergistic effect is more obviously outstanding, wherein co-toxicity coefficient maximum in the time that second worm nitrile and fipronil bisamide weight ratio are 1: 1, and synergistic effect is the most obvious.
Application Example three:
For trying insect: rice hoppers.
Test medicine provides by Shanxi Thompson Biological Technology Co., Ltd..
Experimental scheme: effective lethal concentration scope of determining second worm nitrile, the former medicine of Rynaxypyr and the two different proportioning mixture through preliminary experiment.
Toxicity test result two
The toxicity test of table 2 second worm nitrile proportionings different from Rynaxypyr to rice hoppers
As shown in Table 2, the composite proportioning of preventing and treating rice hoppers of second worm nitrile and Rynaxypyr was at 40: 1 to 1: 40 o'clock, co-toxicity coefficient is all greater than 120, illustrate that both all show synergistic effect at mixture in 40: 1 to 1: 40 scopes, especially in the time that second worm nitrile and Rynaxypyr obtain proportioning at 5: 1 to 1: 5, synergistic effect is more obviously outstanding, wherein co-toxicity coefficient maximum in the time that second worm nitrile and Rynaxypyr weight ratio are 1: 1, and synergistic effect is the most obvious.Application Example tetrem worm nitrile and fipronil bisamide and the composite control Laphygma exigua Hubner test of pesticide effectiveness thereof
This experimental establishment is in Bozhou City Mengcheng County, Anhui Province, test medicine is researched and developed, is provided by Shanxi Thompson Biological Technology Co., Ltd., contrast medicament 10% second worm nitrile suspending agent (commercial), 20% fipronil bisamide water dispersible granules (commercial).
Investigation Laphygma exigua Hubner insect pest index before medicine, in their early stage dispenser, investigates insect pest indexes and calculates preventive effect for after dispenser 24 hours, 72 hours.Experimental result is as follows:
Table 3 second worm nitrile, fipronil bisamide and the composite control Laphygma exigua Hubner test of pesticide effectiveness thereof
As can be seen from Table 3, after second worm nitrile and fipronil bisamide are composite, can effectively prevent and treat Laphygma exigua Hubner, control efficiency is all better than the preventive effect of single dose.In test scope of medication, target crop is had no adverse effects.
Application Example five second worm nitriles and Rynaxypyr and the composite rice hoppers test of pesticide effectiveness of preventing and treating thereof
This experimental establishment is in Binyang County, Guangxi province Nanning City, test medicine is researched and developed, is provided by Shanxi Thompson Biological Technology Co., Ltd., contrast medicament 10% second worm nitrile suspending agent (commercial), 200 grams per liter Rynaxypyr suspending agents (commercial).
Investigation rice hoppers insect pest index before medicine, in their early stage dispenser, investigates insect pest indexes and calculates preventive effect for after dispenser 24 hours, 72 hours.Experimental result is as follows:
Table 4 second worm nitrile, Rynaxypyr and the composite rice hoppers test of pesticide effectiveness of preventing and treating thereof
As can be seen from Table 4, after second worm nitrile and Rynaxypyr are composite, can effectively prevent and treat rice hoppers, control efficiency is all better than the preventive effect of single dose.In test scope of medication, target crop is had no adverse effects.

Claims (5)

1. contain a Pesticidal combination for second worm nitrile, comprise effective active component, auxiliary agent, it is characterized in that: active components A, B percentage by weight are 1 ~ 40% ︰ 1 ~ 40%, and described active components A is selected from second worm nitrile, and active component B is selected from Rynaxypyr.
2. a kind of Pesticidal combination that contains second worm nitrile according to claim 1, is characterized in that: the percentage by weight of A, two kinds of active components of B is 1 ~ 30% ︰ 1 ~ 30%.
3. the Pesticidal combination that contains second worm nitrile according to claim 2, is characterized in that: the percentage by weight of second worm nitrile and Rynaxypyr is 5 ~ 20% ︰ 5 ~ 20%.
4. the Pesticidal combination that contains second worm nitrile according to claim 1, is characterized in that: composition is made wetting powder, water dispersible granules, suspending agent.
5. the ethiprole insecticidal composition that contains according to claim 1 is for preventing and treating the purposes of the various pests on Cereal, vegetables, ornamental plants, fruit tree.
CN201110066551.4A 2011-03-19 2011-03-19 Insecticidal composition containing ethiprole Active CN102084862B (en)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105941409B (en) * 2012-06-15 2018-09-07 陕西汤普森生物科技有限公司 A kind of Efficient insecticidal composition containing CGA 183893
US9549557B2 (en) 2013-04-19 2017-01-24 Bayer Cropscience Aktiengesellschaft Insecticidal synergistic combinations of phthaldiamide derivatives and fipronil or ethiprole
CN104115845B (en) * 2013-04-24 2017-11-21 陕西美邦农药有限公司 A kind of high-efficient pesticide composition containing fluorobenzene insect amide
CN105557697A (en) * 2014-10-15 2016-05-11 陕西美邦农药有限公司 Efficient pesticide composition containing N-(2-tert-butylamineformoxyl-4-chloro-6-methylphenyl)-1-(3-chloropyridine-2-pyridinyl)-3-fluoro-methoxy-1H-pyrazole-5-carboxamide
CN106804597A (en) * 2015-11-27 2017-06-09 陕西韦尔奇作物保护有限公司 A kind of Pesticidal combination of the nitrile of worm containing acetyl and fipronil bisamide
CN105454243A (en) * 2015-12-16 2016-04-06 济南昊泽环保科技有限公司 Insecticidal combination containing o-phenylenediamine insecticide and ethiprole

Citations (1)

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Publication number Priority date Publication date Assignee Title
CN1705437A (en) 2002-10-16 2005-12-07 拜尔农作物科学股份公司 Active substance combinations having insecticidal and acaricidal properties

Patent Citations (1)

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Publication number Priority date Publication date Assignee Title
CN1705437A (en) 2002-10-16 2005-12-07 拜尔农作物科学股份公司 Active substance combinations having insecticidal and acaricidal properties

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