CN107372522A - A kind of composition pesticide containing fenazaquin - Google Patents
A kind of composition pesticide containing fenazaquin Download PDFInfo
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- CN107372522A CN107372522A CN201710769151.7A CN201710769151A CN107372522A CN 107372522 A CN107372522 A CN 107372522A CN 201710769151 A CN201710769151 A CN 201710769151A CN 107372522 A CN107372522 A CN 107372522A
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- Prior art keywords
- fenazaquin
- active component
- composition pesticide
- amitraz
- lufenuron
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/54—1,3-Diazines; Hydrogenated 1,3-diazines
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/52—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing groups, e.g. carboxylic acid amidines
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
- A01N47/34—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the groups, e.g. biuret; Thio analogues thereof; Urea-aldehyde condensation products
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- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The present invention relates to a kind of composition pesticide containing fenazaquin and its application, active component composition A and active component B comprising effective dose, wherein active components A are fenazaquin, and active component B is any one in single carbonamidine, Amitraz or lufenuron.The ratio of weight and number of the active component composition A and active component B are 20:1‑1:60.Obvious synergistic effect is shown to evil mite after fenazaquin is mixed with any one in single carbonamidine, Amitraz or lufenuron, quick-acting is good, lasting period length, and can delay the drug-fast generation of evil mite, the improvement of the resistance that is particularly suitable for use in evil mite.
Description
Technical field
The present invention relates to a kind of miticide composition and its application, specially fenazaquin and another acaricidal activity composition compounding
Miticide composition with synergistic effect, said composition are applied to the preventing and treating of evil mite.
Background technology
Fenazaquin：English common name：Fenazaquin, chemical name：4- spy-butyl phenethyl quinazoline, molecular formula：
C20H22N20.Its structural formula is：
Fenazaquin be quinolines acaricide by action of contace poison in the mitochondria and genome I of insect, occupy ubiquinone
Binding site.There are preferable preventive effect, lasting period length, ovicidal to citrus, European red mite；To natural enemies security.With existing acaricide
No interactions resistance, it is particularly suitable for preventing and treating the evil mite that resistance is produced to existing acaricide.But single dose is for a long time largely using easily making evil mite
Produce resistance.
Single carbonamidine：English common name：Semiamitraz, chemical name：N- (2,4- xylyls)-N '-dimethyl cellosolve salt
Hydrochlorate, molecular formula：C10H14N2.Single carbonamidine is a kind of efficient, new organic nitrogen acaricide, has systemic activity, and mite killing is killed
Ovum activity is higher, and miticidal effect is more preferable when more than 25 DEG C.Single carbonamidine mite killing is quick, but the lasting period is short.Single carbonamidine simultaneously
Also there is higher killing aphids activity.
Amitraz：English common name：Amitraz, molecular formula：C19H23N3.Amitraz is wide property acaricide, by suppressing single
The activity of amine oxidase kills evil mite.With tag, food refusal, avoidance effect, also have certain interior suction, fumigation action.To same wing
Mesh insect also has preferable preventive effect.
Lufenuron：English common name：Lufenuron.Lufenuron substituted urea class insecticide, medicament is by acting on insect children
Worm prevents insect molting from killing off the insect pests, and has the insecticidal mechanism of uniqueness to rust mite, trialeurodes vaporariorum.Lasting medicine, resistance of rainwater washing against；To honey
Honeybee and hornet low toxicity, there is selectivity to the adult beneficial to arthropod.
Mite pest includes the insects such as Tetranychidae, Eriophyidae.Wherein cause harm maximum is Panonychus citri, Tetranychus urticae and cinnabar
Tetranychid.Evil mite, which is gathered in vacuum side of blade more and is pierced into lancet, sucks in the industry juice, causes plant leaf blade marennin to be damaged, influences light
Cooperation is used, and blade is withered when serious comes off, or even plant is dead caused by blade falls light.More, fertility from generation to generation occurs for evil mite
By force, the features such as degree is high is selfed, causes evil mite easily to be developed immunity to drugs to acaricide.Frequently medication has aggravated the negative of peasant simultaneously
Load, exacerbates the pollution of environment.The acaricide of different cultivars or the different mechanisms of action compounds or acaricide is with pesticide compositional
The effective way that the preventing and treating of solution resistance evil mite and evil mite develop immunity to drugs.
Compounded using the acaricide or insecticide of different mechanism, inventor has carried out substantial amounts of screening test.It was found that
Obvious synergistic effect is shown after fenazaquin is mixed with single carbonamidine, Amitraz or lufenuron to evil mite, and evil mite can be delayed to resist
The generation of the property of medicine, the improvement of the resistance that is particularly suitable for use in evil mite, spy propose the present invention.
The content of the invention
It is an object of the invention to provide a kind of acaricide composition containing fenazaquin, said composition has obvious increase
The advantages that wide, quick-acting is good and the lasting period is long, is composed in effect effect, preventing and treating, can reduce dosage, delay the drug-fast generation of evil mite.It can use
Evil mite in preventing and treating fruit tree, vegetables, cotton or flowers and other crops.Meanwhile it is a further object to provide the combination
The control and application of thing evil mite in fruit tree, vegetables, cotton or flowers and other crops.
The present invention is achieved by the following technical solutions：
A kind of composition pesticide containing fenazaquin, it includes the active components A of effective dose and active component B, wherein living
Property composition A be fenazaquin, active component B is any one in single carbonamidine, Amitraz or lufenuron.
Further, active components A and active component B ratio of weight and number are 20:1-1:60；It is highly preferred that activity into
The ratio of weight and number for dividing A and active component B is 20:1~1:20, in the range of the ratio of weight and number limited, active components A
The technique effect of Synergistic is obtained with active component B mixtures.
Further, active components A and active component B weight percentage are gross weight in described composition pesticide
1%~90%, preferably 10%-50%, remaining be agricultural chemicals in allow use and acceptable auxiliary element.
Further, described composition pesticide can be according to the needs of actual production, by the active components A of effective dose and work
Property composition B add auxiliary agent and agriculturally any one adaptable formulation is made in excipients；It is highly preferred that described formulation is
Missible oil, suspending agent, wettable powder, water dispersible granules, aqueous emulsion or microemulsion.
Composition pesticide provided by the invention can be used for the evil mite of preventing and treating crops.
Further, the evil mite is Panonychus citri, Tetranychus cinnabarinus or Tetranychus urticae.
Compared with prior art, beneficial effect is the composition pesticide of the present invention：
1st, the two kinds of active components in composition, which combines, has obvious synergistic effect, improves prevention effect, reduces
The dosage of active component, there is preferable preventive effect to the evil mite of each breeding time；
2nd, composition by the different mechanisms of action compound group into, effectively delayed the drug-fast generation of evil mite, extend
The service life of medicament, comprehensive regulation important in inhibiting to insect；
3rd, security is good, to beneficial insect safety, meets the security requirement of pesticidal preparations；Reduce the whole season of growth
Times for spraying, reduce the adverse effect of cost accounting and agricultural chemicals to ecological environment.
4th, evil mite can not only be preferably prevented and treated, also has to some insects and certain simultaneous controls effect.
Embodiment
In order that the objects, technical solutions and advantages of the present invention are more concise, with reference to embodiment to the present invention
Content be described further, but the present invention be only limitted to these examples absolutely not.Presented below is only that the present invention is relatively good
Case study on implementation, the description present invention is used only for, is not to be construed as limitation of the scope of the invention.
(1) formula and formulation examples.In embodiment active component using 99% fenazaquin active compound, 90% single carbonamidine active compound,
95% Amitraz active compound and 98% lufenuron active compound
Embodiment 1:31.5% fenazaquin list carbonamidine missible oil
By active component active compound, emulsifying agent and solvent etc., reactor is sequentially added by formula rate, is stirred, is produced
31.5% fenazaquin list carbonamidine missible oil.(mass ratio of fenazaquin and single carbonamidine is 20:1)
Single carbonamidine in the present embodiment can be replaced with Amitraz or lufenuron, form new embodiment.
Embodiment 2：18% fenazaquin Amitraz suspending agent
By active component active compound, dispersant, antifreeze, thickener and defoamer etc., reaction is sequentially added by formula rate
It is finely ground in kettle, mixed by high speed shear, produce 18% fenazaquin Amitraz suspending agent.(the matter of fenazaquin and Amitraz
Amount is than being 8:1)
Amitraz in this example can be replaced with single carbonamidine or lufenuron, form new embodiment.
Embodiment 3:24% fenazaquin list carbonamidine wettable powder
Fenazaquin 20g
Single carbonamidine 4g
Lauryl sodium sulfate (wetting agent) 3g
Alkylnaphthalene sulfonate formaldehyde condensation products (dispersant) 5g
Kaolin (filler) supplies 100g
Uniformly mix, active component active compound, wetting agent, dispersant and filler etc. through ultrafine crusher by formula rate
Crush, produce 24% fenazaquin list carbonamidine wettable powder.(mass ratio of fenazaquin and single carbonamidine is 5:1)
Single carbonamidine in this example can be replaced with Amitraz or lufenuron, form new embodiment.
Embodiment 4：24% fenazaquin lufenuron microemulsion
Active component active compound, auxiliary agent and solvent agent etc. are added together and are dissolved into homogeneous oil phase, water is slowly added under stirring
In, then the agitated rapid phase inversion of heating, room temperature is cooled to, produces 24% fenazaquin lufenuron microemulsion.(fenazaquin and Acarus tritici
The mass ratio of urea is 1:1)
Lufenuron in this example can be replaced with single carbonamidine or Amitraz, form new example.
Example 5：The 45% dispersible granula of fenazaquin Amitraz
Above-mentioned raw materials are well mixed, air-flow crushing, add suitable quantity of water and mediate, the mixture pelleting of gained, produce
The 45% dispersible granula of fenazaquin Amitraz.(mass ratio of fenazaquin and Amitraz is 1:4)
Amitraz in this example can be replaced with single carbonamidine or lufenuron, form new example.
Example 6：25% fenazaquin lufenuron aqueous emulsion
Active compound, cosolvent, emulsifying agent are added together, make to be dissolved into homogeneous oil phase, remainder water is as aqueous phase；In height
Under speed stirring, oil phase is mixed with water conjunction, 25% fenazaquin lufenuron aqueous emulsion is made.(the quality of fenazaquin and lufenuron
Than for 2:3)
Lufenuron in this example can be replaced with single carbonamidine or Amitraz, form new example.
Embodiment 7:10% fenazaquin list carbonamidine missible oil
By active component active compound, emulsifying agent and solvent etc., reactor is sequentially added by formula rate, is stirred, is produced
31.5% fenazaquin list carbonamidine missible oil.(mass ratio of fenazaquin and single carbonamidine is 1:1)
Single carbonamidine in the present embodiment can be replaced with Amitraz or lufenuron, form new embodiment.
Embodiment 3:80% fenazaquin list carbonamidine wettable powder
Fenazaquin 10g
Single carbonamidine 70g
Lauryl sodium sulfate (wetting agent) 3g
Alkylnaphthalene sulfonate formaldehyde condensation products (dispersant) 5g
Kaolin (filler) supplies 100g
Uniformly mix, active component active compound, wetting agent, dispersant and filler etc. through ultrafine crusher by formula rate
Crush, produce 24% fenazaquin list carbonamidine wettable powder.(mass ratio of fenazaquin and single carbonamidine is 1:7)
Single carbonamidine in this example can be replaced with Amitraz or lufenuron, form new embodiment.
(2) the indoor biological determination of activity of the present composition and field efficacy checking
1st, Toxicity Determination
1) using Tetranychus cinnabarinus into mite as subjects, using leaf butterfly spray-on process (see《In NY/T1154.13-2008 agricultural chemicals room
The parts of bioassay test criterion insecticide the 13rd：Leaf butterfly spray-on process》), determine fenazaquin and single carbonamidine compounds different proportion
Synergistic effect size.The co-toxicity coefficient (CTC values) of compound drug mixture is calculated according to the abundant methods of Sun Yun：
Survey toxicity index (ATI)=(standard agent LC50/ reagent agents) × 100
A percentage composition+B medicament toxicity index in theoretical toxicity index (TTI)=A medicament toxicity index × mixture × mixed
B percentage composition in agent
Co-toxicity coefficient (CTC)=ATI/TTI × 100
According to co-toxicity coefficient (CTC) criteria for classifying, CTC≤80 are antagonism, and 80 ＜ CTC ＜ 120 are summation action,
CTC >=120 are synergistic effect.
The fenazaquin of table 1 and single carbonamidine compound the Toxicity Determination on Tetranychus cinnabarinus
Fenazaquin and single carbonamidine compounding show that Tetranychus cinnabarinus indoor virulence test result fenazaquin and single carbonamidine compounding exist
Ratio range 8:1-1:Between 60, co-toxicity coefficient is all higher than 120, shows fenazaquin and single carbonamidine compounding 8:1-1:60 proportioning
In the range of can show synergistic effect, especially 8:1-1:Between 20, synergistic effect is obvious, and co-toxicity coefficient is shown in more than 130
Table 1.
2) using citrus red mite as subjects, using leaf butterfly spray-on process (see《It is raw in NY/T1154.13-2008 agricultural chemicals room
The parts of thing determination test criterion insecticide the 13rd：Leaf butterfly spray-on process》), determine the increasing of fenazaquin and Amitraz compounding different proportion
Effect acts on size.The co-toxicity coefficient (CTC values) of compound drug mixture is calculated according to the abundant methods of Sun Yun：
Survey toxicity index (ATI)=(standard agent LC50/ reagent agents) × 100
A percentage composition+B medicament toxicity index in theoretical toxicity index (TTI)=A medicament toxicity index × mixture × mixed
B percentage composition in agent
Co-toxicity coefficient (CTC)=ATI/TTI × 100
According to co-toxicity coefficient (CTC) criteria for classifying, CTC≤80 are antagonism, and 80 ＜ CTC ＜ 120 are summation action,
CTC >=120 are synergistic effect.
The fenazaquin of table 2 and Amitraz compound the Toxicity Determination on citrus red mite
Fenazaquin and Amitraz compounding show that citrus red mite indoor virulence test result fenazaquin and Amitraz compound
In ratio range 20:1-1:Between 60, synergistic effect, especially 20 can be shown:1-1:Between 20, synergistic effect is obvious,
Co-toxicity coefficient (table 2) more than 130.
3) using Tetranychus urticae as subjects, using leaf butterfly spray-on process (see《NY/T1154.13-2008 agricultural chemicals indoor biologicals
The parts of determination test criterion insecticide the 13rd：Leaf butterfly spray-on process》), determine the synergy of fenazaquin and lufenuron compounding different proportion
Act on size.The co-toxicity coefficient (CTC values) of compound drug mixture is calculated according to the abundant methods of Sun Yun：
Survey toxicity index (ATI)=(standard agent LC50/ reagent agents) × 100
A percentage composition+B medicament toxicity index in theoretical toxicity index (TTI)=A medicament toxicity index × mixture × mixed
B percentage composition in agent
Co-toxicity coefficient (CTC)=ATI/TTI × 100
According to co-toxicity coefficient (CTC) criteria for classifying, CTC≤80 are antagonism, and 80 ＜ CTC ＜ 120 are summation action,
CTC >=120 are synergistic effect.
The fenazaquin of table 3 and lufenuron compound the Toxicity Determination on Tetranychus urticae
Fenazaquin and lufenuron compounding show that Tetranychus urticae indoor virulence test result fenazaquin and lufenuron compounding exist
Ratio range 20:1-1:Between 60, synergistic effect, especially 20 can be shown:1-1:Between 20, synergistic effect is obvious, altogether
Spend coefficient (table 3) more than 130.
2nd, fenazaquin and the field test of single carbonamidine compounding preventing and treating citrus red mite
Experiment uses field spray method.In field, selection evil mite occurs than more uniform region, per 2-3 tree of cell, often
Group medicament sets 3 repetitions, repeats to select 2 trees every time and fixes a branch by five positionses in all directions are each and make investigation pair
As.Insect population investigation is first carried out, then carries out even spraying according to the extension rate and application method of experimental design.Respectively at
Check mite number living within 1 day, 7 days and 21 days after medicine, calculate preventive effect.
The fenazaquin of table 4 is compounded to citrus red mite field efficacy with single carbonamidine
Fenazaquin and single carbonamidine compounding table of field test results are bright, and fenazaquin and single carbonamidine compounding have synergistic effect, apply
After medicine 1 day each compound drug to the preventive effect of citrus red mite all more than 90%, higher than the preventive effect 78.18% of fenazaquin single dose,
Quick-acting improves after illustrating fenazaquin and single carbonamidine compounding；21 days after medicine, the preventive effect of each medicament is all more than 90%, up to
94.58%, the lasting effect that fenazaquin and single carbonamidine compound is better than the preventive effect 35.86% of single carbonamidine single dose, illustrates fenazaquin and list
The lasting effect of carbonamidine compounding significantly improves.Wherein when fenazaquin and single carbonamidine mass ratio are 20:When 1, to citrus red mite field
Preventive effect is optimal.
3rd, the field test of fenazaquin and Amitraz compounding preventing and treating citrus red mite
Experiment uses field spray method.In field, selection evil mite occurs than more uniform region, per 2-3 tree of cell, often
Group medicament sets 3 repetitions, repeats to select 2 trees every time and fixes a branch by five positionses in all directions are each and make investigation pair
As.Insect population investigation is first carried out, then carries out even spraying according to the extension rate and application method of experimental design.Respectively at
Check mite number living within 1 day, 7 days and 21 days after medicine, calculate preventive effect.
The fenazaquin of table 5 is compounded to citrus red mite field efficacy with Amitraz
Fenazaquin and Amitraz compounding table of field test results are bright, and fenazaquin and Amitraz compounding have synergistic effect, apply
After medicine 1 day each compound drug to the preventive effect of citrus red mite all more than 89%, higher than the preventive effect 78.18% of fenazaquin single dose,
Quick-acting improves after illustrating fenazaquin and Amitraz compounding；21 days after medicine, the preventive effect of each medicament is all more than 90%, up to
92.87%, fenazaquin and Amitraz compounding lasting effect be better than Amitraz single dose preventive effect 41.56%, illustrate fenazaquin and pair
The lasting effect of carbonamidine compounding significantly improves.Wherein fenazaquin and Amitraz mass ratio are 1:When 4, to the field to citrus red mite
Preventive effect is optimal.
4th, the field test of fenazaquin and lufenuron compounding preventing and treating cowpea red spider
Experiment uses field spray method, and in field, selection evil mite occurs to select 8 plants of cowpeas than more uniform region, every group of medicament
Beans first carry out insect population investigation, then carried out according to the extension rate and application method of experimental design equal as respondent
Even spraying.Check mite number living within 1 day, 7 days and 21 days after medicine, calculate preventive effect.
The fenazaquin of table 6 is compounded to cowpea red spider field efficacy with lufenuron
Fenazaquin and lufenuron compounding table of field test results are bright, and fenazaquin and lufenuron compounding have synergistic effect, apply
After medicine 1 day each compound drug to the preventive effect of citrus red mite all more than 84%, higher than the preventive effect 62.78% of fenazaquin single dose,
Quick-acting improves after illustrating fenazaquin and lufenuron compounding；21 days after medicine, the preventive effect of each medicament is all more than 89%, up to
90.77%, the lasting effect that fenazaquin and lufenuron compound is better than the preventive effect 52.91% of lufenuron single dose, illustrates fenazaquin and lice
The lasting effect of mite urea compounding significantly improves.Wherein fenazaquin and lufenuron mass ratio are 5:When 1, the field of cowpea red spider is prevented
Effect is optimal.
In summary, it is any during the present invention uses two kinds of active components as fenazaquin and single carbonamidine, Amitraz or lufenuron
A kind of composition pesticide, there is synergistic function, compared with existing unitary agent, the positive effect for preventing and treating evil mite carries
Height, and lasting period length, reduce dosage, to crop safety, are worth promoting the use of in agricultural production.
Claims (9)
1. a kind of composition pesticide containing fenazaquin, it is characterised in that described composition pesticide includes the activity of effective dose
Components Component A and active component B, wherein active components A are fenazaquin, and active component B is single carbonamidine, Amitraz or lufenuron
In any one.
A kind of 2. composition pesticide containing fenazaquin according to claim 1, it is characterised in that the active component into
The ratio of weight and number for dividing A and active component B is 20:1-1:60.
A kind of 3. composition pesticide containing fenazaquin according to claim 2, it is characterised in that the active component into
The ratio of weight and number for dividing A and active component B is 20:1-1:20.
A kind of 4. composition pesticide containing fenazaquin according to claim 1, it is characterised in that the active component into
The weight percentage for dividing A and active component B is the 1%~90% of gross weight, and remaining is to allow to use and can connect in agricultural chemicals
The auxiliary element received.
A kind of 5. composition pesticide containing fenazaquin according to claim 4, it is characterised in that the active component into
The weight percentage for dividing A and active component B is the 10%-50% of gross weight.
6. a kind of composition pesticide containing fenazaquin according to claim any one of 1-5, it is characterised in that described
Composition pesticide can be made into any one formulation on agricultural chemicals.
7. a kind of composition pesticide containing fenazaquin according to claim 6, it is characterised in that described formulation is breast
Oil, suspending agent, wettable powder, water dispersible granules, aqueous emulsion or microemulsion.
8. composition as claimed in claim 1 is applied to the evil mite of preventing and treating crops.
9. the application of composition pesticide according to claim 8, it is characterised in that preventing and treating Panonychus citri, Tetranychus cinnabarinus or two variegated leafs
Mite.
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| CN201710769151.7A CN107372522A (en) | 2017-08-31 | 2017-08-31 | A kind of composition pesticide containing fenazaquin |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109006827A (en) * | 2018-08-11 | 2018-12-18 | 江西正邦作物保护有限公司 | A kind of composition pesticide containing fluazinam and fenazaquin |
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| CN101653126A (en) * | 2009-08-12 | 2010-02-24 | 东莞市瑞德丰生物科技有限公司 | Mite-killing composition containing fenazaquin |
| CN101731250A (en) * | 2010-01-20 | 2010-06-16 | 东莞市瑞德丰生物科技有限公司 | Fenazaquin-containing acaricidal composition |
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2017
- 2017-08-31 CN CN201710769151.7A patent/CN107372522A/en active Pending
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101653126A (en) * | 2009-08-12 | 2010-02-24 | 东莞市瑞德丰生物科技有限公司 | Mite-killing composition containing fenazaquin |
| CN101731250A (en) * | 2010-01-20 | 2010-06-16 | 东莞市瑞德丰生物科技有限公司 | Fenazaquin-containing acaricidal composition |
Non-Patent Citations (1)
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109006827A (en) * | 2018-08-11 | 2018-12-18 | 江西正邦作物保护有限公司 | A kind of composition pesticide containing fluazinam and fenazaquin |
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