CN101485329B - Agricultural chemical composition for disinsection and use thereof - Google Patents
Agricultural chemical composition for disinsection and use thereof Download PDFInfo
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- CN101485329B CN101485329B CN2009101054493A CN200910105449A CN101485329B CN 101485329 B CN101485329 B CN 101485329B CN 2009101054493 A CN2009101054493 A CN 2009101054493A CN 200910105449 A CN200910105449 A CN 200910105449A CN 101485329 B CN101485329 B CN 101485329B
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- worm prestige
- indenes worm
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- urea
- disinsection
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- 239000000203 mixture Substances 0.000 title claims abstract description 52
- 239000003905 agrochemical Substances 0.000 title claims description 19
- 241000607479 Yersinia pestis Species 0.000 claims abstract description 15
- 150000002469 indenes Chemical class 0.000 claims description 97
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 80
- KDGQGEKLPWYCGO-UHFFFAOYSA-N 1-butoxybutane;urea Chemical compound NC(N)=O.CCCCOCCCC KDGQGEKLPWYCGO-UHFFFAOYSA-N 0.000 claims description 54
- 241000934067 Acarus Species 0.000 claims description 42
- 239000004202 carbamide Substances 0.000 claims description 41
- 239000003921 oil Substances 0.000 claims description 25
- 239000000375 suspending agent Substances 0.000 claims description 19
- 239000004480 active ingredient Substances 0.000 claims description 11
- 239000000843 powder Substances 0.000 claims description 10
- 238000009736 wetting Methods 0.000 claims description 10
- 239000004530 micro-emulsion Substances 0.000 claims description 8
- 239000004562 water dispersible granule Substances 0.000 claims description 7
- 239000000839 emulsion Substances 0.000 claims description 5
- 238000009472 formulation Methods 0.000 claims description 5
- 239000003814 drug Substances 0.000 abstract description 37
- 239000003795 chemical substances by application Substances 0.000 abstract description 20
- 230000000694 effects Effects 0.000 abstract description 8
- 239000002917 insecticide Substances 0.000 abstract description 8
- 239000005912 Lufenuron Substances 0.000 abstract description 6
- PWPJGUXAGUPAHP-UHFFFAOYSA-N lufenuron Chemical compound C1=C(Cl)C(OC(F)(F)C(C(F)(F)F)F)=CC(Cl)=C1NC(=O)NC(=O)C1=C(F)C=CC=C1F PWPJGUXAGUPAHP-UHFFFAOYSA-N 0.000 abstract description 6
- 229960000521 lufenuron Drugs 0.000 abstract description 6
- 230000009471 action Effects 0.000 abstract description 5
- 241000255777 Lepidoptera Species 0.000 abstract description 4
- WOWBFOBYOAGEEA-UHFFFAOYSA-N diafenthiuron Chemical compound CC(C)C1=C(NC(=S)NC(C)(C)C)C(C(C)C)=CC(OC=2C=CC=CC=2)=C1 WOWBFOBYOAGEEA-UHFFFAOYSA-N 0.000 abstract description 4
- 230000000749 insecticidal effect Effects 0.000 abstract description 4
- 230000007246 mechanism Effects 0.000 abstract description 4
- 206010034133 Pathogen resistance Diseases 0.000 abstract description 3
- 229940079593 drug Drugs 0.000 abstract description 3
- 238000001228 spectrum Methods 0.000 abstract description 3
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- 230000008901 benefit Effects 0.000 abstract description 2
- VBCVPMMZEGZULK-NRFANRHFSA-N indoxacarb Chemical compound C([C@@]1(OC2)C(=O)OC)C3=CC(Cl)=CC=C3C1=NN2C(=O)N(C(=O)OC)C1=CC=C(OC(F)(F)F)C=C1 VBCVPMMZEGZULK-NRFANRHFSA-N 0.000 abstract description 2
- 239000002728 pyrethroid Substances 0.000 abstract description 2
- 239000005660 Abamectin Substances 0.000 abstract 1
- 206010059866 Drug resistance Diseases 0.000 abstract 1
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- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 abstract 1
- 125000000250 methylamino group Chemical group [H]N(*)C([H])([H])[H] 0.000 abstract 1
- 239000011574 phosphorus Substances 0.000 abstract 1
- 229910052698 phosphorus Inorganic materials 0.000 abstract 1
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- 230000003449 preventive effect Effects 0.000 description 22
- 238000000034 method Methods 0.000 description 17
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- 238000002360 preparation method Methods 0.000 description 6
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 5
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- 239000002270 dispersing agent Substances 0.000 description 5
- 239000000080 wetting agent Substances 0.000 description 5
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 4
- RCEAADKTGXTDOA-UHFFFAOYSA-N OS(O)(=O)=O.CCCCCCCCCCCC[Na] Chemical compound OS(O)(=O)=O.CCCCCCCCCCCC[Na] RCEAADKTGXTDOA-UHFFFAOYSA-N 0.000 description 4
- 239000012752 auxiliary agent Substances 0.000 description 4
- YDEXUEFDPVHGHE-GGMCWBHBSA-L disodium;(2r)-3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Na+].[Na+].COC1=CC=CC(C[C@H](CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O YDEXUEFDPVHGHE-GGMCWBHBSA-L 0.000 description 4
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- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
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- 241000499436 Brassica rapa subsp. pekinensis Species 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 241001674939 Caulanthus Species 0.000 description 2
- 241000008892 Cnaphalocrocis patnalis Species 0.000 description 2
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- 241001046947 Ectropis obliqua Species 0.000 description 2
- 241001325860 Lacanobia oleracea Species 0.000 description 2
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- 241001525802 Phyllonorycter pomonella Species 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 239000000642 acaricide Substances 0.000 description 2
- 235000012211 aluminium silicate Nutrition 0.000 description 2
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 2
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 2
- 235000011130 ammonium sulphate Nutrition 0.000 description 2
- 230000008485 antagonism Effects 0.000 description 2
- 239000000440 bentonite Substances 0.000 description 2
- 229910000278 bentonite Inorganic materials 0.000 description 2
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 2
- 239000006229 carbon black Substances 0.000 description 2
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- 235000013399 edible fruits Nutrition 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
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- XUZHLZDRCCUWEV-UHFFFAOYSA-N formaldehyde;methyl naphthalene-1-sulfonate Chemical compound O=C.C1=CC=C2C(S(=O)(=O)OC)=CC=CC2=C1 XUZHLZDRCCUWEV-UHFFFAOYSA-N 0.000 description 2
- 235000011187 glycerol Nutrition 0.000 description 2
- 238000000227 grinding Methods 0.000 description 2
- 238000005286 illumination Methods 0.000 description 2
- 238000007689 inspection Methods 0.000 description 2
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 2
- 231100000225 lethality Toxicity 0.000 description 2
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- 229940088417 precipitated calcium carbonate Drugs 0.000 description 2
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- 238000007619 statistical method Methods 0.000 description 2
- 210000002784 stomach Anatomy 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- UMGDCJDMYOKAJW-UHFFFAOYSA-N thiourea Chemical compound NC(N)=S UMGDCJDMYOKAJW-UHFFFAOYSA-N 0.000 description 2
- 235000013311 vegetables Nutrition 0.000 description 2
- 229920001285 xanthan gum Polymers 0.000 description 2
- QMEQBOSUJUOXMX-UHFFFAOYSA-N 2h-oxadiazine Chemical compound N1OC=CC=N1 QMEQBOSUJUOXMX-UHFFFAOYSA-N 0.000 description 1
- 241000238876 Acari Species 0.000 description 1
- 241001124076 Aphididae Species 0.000 description 1
- 235000016068 Berberis vulgaris Nutrition 0.000 description 1
- 241000335053 Beta vulgaris Species 0.000 description 1
- 235000009024 Ceanothus sanguineus Nutrition 0.000 description 1
- 229920002101 Chitin Polymers 0.000 description 1
- 241001414720 Cicadellidae Species 0.000 description 1
- 241000675108 Citrus tangerina Species 0.000 description 1
- 241001498622 Cixius wagneri Species 0.000 description 1
- 244000241257 Cucumis melo Species 0.000 description 1
- 235000015510 Cucumis melo subsp melo Nutrition 0.000 description 1
- 102000002322 Egg Proteins Human genes 0.000 description 1
- 108010000912 Egg Proteins Proteins 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 241001486250 Etiella zinckenella Species 0.000 description 1
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- 240000003553 Leptospermum scoparium Species 0.000 description 1
- 235000015459 Lycium barbarum Nutrition 0.000 description 1
- 241000907661 Pieris rapae Species 0.000 description 1
- 108010052164 Sodium Channels Proteins 0.000 description 1
- 102000018674 Sodium Channels Human genes 0.000 description 1
- 244000061456 Solanum tuberosum Species 0.000 description 1
- 235000002595 Solanum tuberosum Nutrition 0.000 description 1
- 241000916145 Tarsonemidae Species 0.000 description 1
- 241001454295 Tetranychidae Species 0.000 description 1
- 241001414989 Thysanoptera Species 0.000 description 1
- FJJCIZWZNKZHII-UHFFFAOYSA-N [4,6-bis(cyanoamino)-1,3,5-triazin-2-yl]cyanamide Chemical compound N#CNC1=NC(NC#N)=NC(NC#N)=N1 FJJCIZWZNKZHII-UHFFFAOYSA-N 0.000 description 1
- 239000002671 adjuvant Substances 0.000 description 1
- 238000012271 agricultural production Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 125000003236 benzoyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C(*)=O 0.000 description 1
- 230000004071 biological effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000000740 bleeding effect Effects 0.000 description 1
- OOCMUZJPDXYRFD-UHFFFAOYSA-L calcium;2-dodecylbenzenesulfonate Chemical compound [Ca+2].CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O.CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O OOCMUZJPDXYRFD-UHFFFAOYSA-L 0.000 description 1
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- CXEGAUYXQAKHKJ-NSBHKLITSA-N emamectin B1a Chemical compound C1=C[C@H](C)[C@@H]([C@@H](C)CC)O[C@]11O[C@H](C\C=C(C)\[C@@H](O[C@@H]2O[C@@H](C)[C@H](O[C@@H]3O[C@@H](C)[C@H](NC)[C@@H](OC)C3)[C@@H](OC)C2)[C@@H](C)\C=C\C=C/2[C@]3([C@H](C(=O)O4)C=C(C)[C@@H](O)[C@H]3OC\2)O)C[C@H]4C1 CXEGAUYXQAKHKJ-NSBHKLITSA-N 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
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- 238000010438 heat treatment Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 238000004920 integrated pest control Methods 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000000422 nocturnal effect Effects 0.000 description 1
- 210000004681 ovum Anatomy 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 230000000361 pesticidal effect Effects 0.000 description 1
- 239000000575 pesticide Substances 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 238000012216 screening Methods 0.000 description 1
- 210000004894 snout Anatomy 0.000 description 1
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- WTHDKMILWLGDKL-UHFFFAOYSA-N urea;hydrate Chemical compound O.NC(N)=O WTHDKMILWLGDKL-UHFFFAOYSA-N 0.000 description 1
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Abstract
The invention provides an insecticidal farm chemical composition and application thereof. The composition adopts one of diafenthiuron or lufenuron, and indoxacarb as active components. The composition has the advantages that: (1) compared with a mono agent, the composition has obvious synergism to lepidoptera pests and improves the control effect; (2) the action mechanisms of the active components and the conventional insecticides of organic phosphorus, pyrethroid and the like are different without cross resistance, and are different from using more methylamino avermectin benzoate, so that the field drug dosage is reduced greatly and the cost is reduced; (3) the difference of the action mechanisms of the active components in the composition is advantageous to overcome and retard the generation of pest drug resistance; and (4) the composition enlarges the controlling spectrum, and has double effects on treating various pests appearing simultaneously.
Description
Technical field
The present invention relates to a kind of agricultural chemical composition for disinsection and application thereof, be used to prevent and treat insect and mite on the agricultural.
Background technology
In the real process of agricultural production, chemical control is the main effective means of pest control.Yet,, like pesticide resistance such as diamond-back moth, beet armyworm, cotton bollworms very generally, become a great problem of chemical control in recent years because single drug and the medication of non-science have caused many kinds of insects that the agricultural chemicals of current use has been produced resistance.Because insect produces resistance, frequent dispenser causes peasant burden to increase the weight of and increasing environmental pollution again.Therefore, in pest resistance treatment and integrated control system, press for efficient, low toxicity, low-residual, the novel insecticide of mechanism of action.
Indenes worm prestige (indoxacarb) is a kind of Xin Xing oxadiazine insecticides, and its insecticidal mechanism is through the sodium-ion channel in the blocking-up insect nerve cell, makes the nerve cell loss of function, and insect is benumbed, and the coordination ability descends, and is final dead.Medicament works through contacting or get in the food entering polypide, does not have cross resistance with other insecticide.Active high to lepidoptera pests such as agriculture and garden crop pest such as vegetables, beet, cotton, fruit tree, tea tree, potato, gardening, flowers such as beet armyworm, tomato moth, imported cabbageworm, cotton bollworms, and each instar larvae all had good control efficiency.Simultaneously, as safe as a house to natural enemy insect, residual low in crop, be the desirable medicament that can be used for integrated pest control and resistance management.But indenes worm prestige insecticidal spectrum is narrower, does not kill mite, and use cost is high, has therefore limited it to a certain extent and has applied.
Butyl ether urea (diafenthiuron) is a kind of novel Thiourea efficient insecticide, miticide; Have tag, stomach toxicity, interior suction and fumigation action; Low toxicity is effective insecticide and the miticide of insects such as phytophagous mites (Tetranychidae, Tarsonemidae), aleyrodid, aphid and leafhopper on control cotton etc. multiple field crops, fruit tree, vegetables and the ornamental plants.To natural enemy insect safety.But in practical application, find that the butyl ether urea is on the low side to nocturnal moth class insect activity, control efficiency is not ideal enough.
Acarus tritici urea (lufenuron) belongs to the benzoyl area kind agent for killing mite and pest, is chitin synthesis inhibitor.Be mainly used in control beet armyworm, prodenia litura, tomato moth, diamond-back moth, cotton bollworm, lima bean pod borer, melon thin,tough silk snout moth's larva, oriental tobacco budworm, thrips, rust mite, phyllocnistis citrella stainton, plant hopper etc.Have stomach toxicity and action of contace poison, insecticidal mechanism is unique, low toxicity, and desinsection kills ovum, and permeability is strong, resistance of rainwater washing against.
Summary of the invention
The purpose of the embodiment of the invention is to provide a kind of synergistic effect that has, the agricultural chemical composition for disinsection of good disinsection effect.
The agricultural chemical composition for disinsection that the embodiment of the invention provides, active ingredient wherein is:
Indenes worm prestige; With
Butyl ether urea or Acarus tritici urea.
Another purpose of the embodiment of the invention is above-mentioned agricultural chemical composition for disinsection to be applied to prepare the agricultural chemicals of pest control, evil mite.
Above-mentioned agricultural chemical composition for disinsection is used to prepare the agricultural chemicals of control crop pests, evil mite.
Different with prior art, technique scheme one of adopts in butyl ether urea and the Acarus tritici urea, with indenes worm prestige as active ingredient, the interpolation auxiliary material is re-dubbed the composition of a customization agent with certain proportion.The beneficial effect that produces is: (1) is compared with single agent, and said composition has tangible synergy to lepidoptera pest, has improved control efficiency; (2) active ingredient is different with the mechanism of action of insecticides such as conventional organic phosphor, pyrethroid, and no cross resistance also is different from and uses more emamectin-benzoate, can significantly reduce the field dosage, has reduced cost; (3) mechanism of action of active ingredient is different in the composition, helps overcoming and delaying the generation of pest resistance to insecticide; (4) enlarged control spectrum, simultaneous various pests has been had the good double effect of controlling.
Embodiment
In order to make the object of the invention, technical scheme and advantage clearer,, the present invention is further elaborated below in conjunction with embodiment.Should be appreciated that specific embodiment described herein only in order to explanation the present invention, and be not used in qualification the present invention.
The inventor is through a large amount of biologicall test screenings; One of in discovery butyl ether urea and the Acarus tritici urea; With indenes worm prestige as active ingredient; Add auxiliary material and be re-dubbed the composition of a customization agent with certain proportion, antagonism property of medicine insect, evil mite have remarkable synergistic effect, especially resist lepidoptera pests such as property of medicine prodenia litura, diamond-back moth, cotton bollworm and have remarkable synergistic effect.
The characteristic of the present composition is that active ingredient has two kinds of combinations, and a kind of is indenes worm prestige and butyl ether urea, and both part by weight are 1: 0.1～20, be preferably 1: 1～and 10; Another kind is indenes worm prestige and Acarus tritici urea, and both part by weight are 1: 0.05～10, be preferably 1: 0.1～and 5.
The present composition can be processed into agriculture any one formulation that allows that goes up and be applied; Preferred dosage form comprises wetting powder, aqueous emulsion, missible oil, microemulsion, water dispersible granules and suspending agent; The total content of active ingredient is 5～80% of a total composition in the preparation, is preferably 16～40%.
The adjuvant that uses in the composition of the present invention comprises that solvent, emulsifier, dispersant, wetting agent, stabilizing agent, antifreezing agent, thickener, pH regulator agent, bleeding agent etc. and other are of value to the existing material that active ingredient is stablized and drug effect is brought into play in storing and using, select different auxiliary material to be mixed with corresponding formulation as required.Above-mentioned auxiliary material all is the various compositions that permission commonly used in the pesticidal preparations is used, and does not have special qualification, and concrete composition and consumption require to confirm through simple experiment according to prescription.
Product described in the invention can the finished product preparation form provide, and promptly each material mixes in the composition, and the composition of composition also can provide with single agent form, directly in bucket or jar, directly mixes before the use, is diluted to required concentration then.
Percentage all is weight percentage in following all Example formulations.The processing technology of the various preparations of the present composition is prior art, can change to some extent according to different situations.
Embodiment 1:20% indenes worm prestige butyl ether urea wetting powder
Indenes worm prestige 15%
Butyl ether urea 5%
Lauryl sodium sulfate 2%
Sodium lignin sulfonate 5%
White carbon black 10%
Kaolin complements to 100%.
Active component, various auxiliary agent and filler etc. are fully mixed in the ratio of prescription, after ultrafine crusher is pulverized, promptly get 20% indenes worm prestige butyl ether urea wetting powder.
This embodiment is applied to prevent and treat the prodenia litura on the wild cabbage.By 4000 extraordinarily water dilution sprayings, the control efficiency of 7 days and 15 days is respectively 93.5%, 90.4% behind the medicine with 20% indenes worm prestige butyl ether urea wetting powder.15% indenes worm prestige suspending agent by 3500 times with 25% butyl ether urea missible oil by 2000 times, use with the quadrat method use, the preventive effect of 7 days and 15 days is respectively 87.2%, 80.2% and 76.9%, 73.6% behind the medicine.The synergistic effect of the composite back of indenes worm prestige and butyl ether urea is obvious, and the preventive effect of prodenia litura obviously is better than single agent.
Embodiment 2:18% indenes worm prestige butyl ether urea aqueous emulsion
Indenes worm prestige 3%
Butyl ether urea 15%
N-Methyl pyrrolidone 10%
Calcium dodecyl benzene sulfonate 5%
The newborn 600# 5% of farming
Water complements to 100%.
Former medicine, solvent, emulsifier are added together, make and be dissolved into even oil phase; With water-soluble component and the mixed water that gets of water; Under high-speed stirred, oil phase is mixed with water, make 18% indenes worm prestige butyl ether urea aqueous emulsion.
This embodiment is applied to prevent and treat the wild cabbage beet armyworm.By 3000 extraordinarily water dilution sprayings, the control efficiency of 7 days and 15 days is respectively 92.7%, 87.6% behind the medicine with 18% indenes worm prestige butyl ether urea aqueous emulsion.15% indenes worm prestige suspending agent by 3500 times with 25% butyl ether urea missible oil by 2000 times, use with the quadrat method use, the preventive effect of 7 days and 15 days is respectively 85.3%, 80.2% and 77.8%, 75.8% behind the medicine.The synergistic effect of the composite back of indenes worm prestige and butyl ether urea is obvious, and the preventive effect of beet armyworm obviously is better than single agent.
Embodiment 3:20% indenes worm prestige butyl ether urea suspending agent
Indenes worm prestige 18%
Butyl ether urea 2%
Methyl naphthalene sulfonate formaldehyde condensate 10%
Xanthans 1%
Bentonite 1%
Glycerine 5%
Water complements to 100%.
Each component such as active component, dispersant, wetting agent and water is even by the mixed of prescription, after grinding and/or high speed shear, obtain 20% indenes worm prestige butyl ether urea suspending agent.
This embodiment is applied to prevent and treat cotton bollworm.By 4000 extraordinarily water dilution sprayings, the control efficiency of 7 days and 15 days is respectively 93.5%, 89.1% behind the medicine with 20% indenes worm prestige butyl ether urea suspending agent.15% indenes worm prestige suspending agent by 3500 times with 25% butyl ether urea missible oil by 2000 times, use with the quadrat method use, the preventive effect of 7 days and 15 days is respectively 87.3%, 81.5% and 80.8%, 75.8% behind the medicine.The synergistic effect of the composite back of indenes worm prestige and butyl ether urea is obvious, and the preventive effect of cotton bollworm obviously is better than single agent.
Embodiment 4:16.5% indenes worm prestige butyl ether urea microemulsion
Indenes worm prestige 1.5%
Butyl ether urea 15%
N-Methyl pyrrolidone 10%
Isopropyl alcohol 15%
The newborn 500# 5% of farming
The newborn 1601# 5% of farming
Water complements to 100%.
Former medicine, solvent, emulsifier are added together, make and be dissolved into even oil phase, slowly add in the entry under stirring,, be chilled to room temperature and make 16.5% indenes worm prestige butyl ether urea microemulsion again through the rapid phase inversion of agitating heating.
This embodiment is applied to prevent and treat the cauliflower diamond-back moth.By 2000 extraordinarily water dilution sprayings, the control efficiency of 7 days and 15 days is respectively 91.9%, 87.3% behind the medicine with 16.5% indenes worm prestige butyl ether urea microemulsion.15% indenes worm prestige suspending agent by 2000 times with 25% butyl ether urea missible oil by 2000 times, use with the quadrat method use, the preventive effect of 7 days and 15 days is respectively 86.4%, 78.8% and 76.1%, 72.9% behind the medicine.The synergistic effect of the composite back of indenes worm prestige and butyl ether urea is obvious, and the preventive effect of cauliflower diamond-back moth obviously is better than single agent.
Embodiment 5:20% indenes worm prestige butyl ether urea missible oil
Indenes worm prestige 10%
Butyl ether urea 10%
N-Methyl pyrrolidone 10%
The newborn 1601# 5% of farming
The newborn 500# 5% of farming
Xylol complements to 100%.
Active component, emulsifier and the auxiliary agent ratio in prescription is added in the mixing kettle successively, stir, make 20% indenes worm prestige butyl ether urea missible oil.
This embodiment is applied to prevent and treat the apple apple leaf miner.By 5000 extraordinarily water dilution sprayings, the control efficiency of 7 days and 15 days is respectively 93.3%, 90.8% behind the medicine with 20% indenes worm prestige butyl ether urea missible oil.15% indenes worm prestige suspending agent by 3500 times with 25% butyl ether urea missible oil by 2000 times, use with the quadrat method use, the preventive effect of 7 days and 15 days is respectively 88.5%, 78.5% and 83.8%, 59.7% behind the medicine.The synergistic effect of the composite back of indenes worm prestige and butyl ether urea is obvious, and the preventive effect of apple apple leaf miner obviously is better than single agent.In addition, find also that in process of the test 20% indenes worm prestige butyl ether urea missible oil has the double effect of controlling to European red mite, preventive effect reaches more than 70%.
Embodiment 6:60% indenes worm prestige diafenthiuron water dispersible granule
Indenes worm prestige 15%
Butyl ether urea 45%
Negel 5%
Sodium lignin sulfonate 7%
Lauryl sodium sulfate 2%
Ammonium sulfate 5%
Precipitated calcium carbonate complements to 100%.
Active component, dispersant, wetting agent, disintegrant and filler is even by the mixed of prescription, become wetting powder through comminution by gas stream, add a certain amount of water extrusion again and make material, after dry screened, obtain 60% indenes worm prestige butyl ether urea water-dispersible granules.
This embodiment is applied to prevent and treat tea geometrid.By 8000 extraordinarily water dilution sprayings, the control efficiency of 7 days and 20 days is respectively 97.4%, 93.6% behind the medicine with 60% indenes worm prestige diafenthiuron water dispersible granule.15% indenes worm prestige suspending agent by 3500 times with 25% butyl ether urea missible oil by 2000 times, use with the quadrat method use, the preventive effect of 7 days and 20 days is respectively 81.7%, 89.2% and 61.8%, 85.1% behind the medicine.The synergistic effect of the composite back of indenes worm prestige and butyl ether urea is obvious, and the preventive effect of tea geometrid obviously is better than single agent.
Embodiment 7:21% indenes worm prestige Acarus tritici urea wetting powder
Indenes worm prestige 20%
Acarus tritici urea 1%
Lauryl sodium sulfate 2%
Sodium lignin sulfonate 5%
White carbon black 10%
Kaolin complements to 100%.
Active component, various auxiliary agent and filler etc. are fully mixed in the ratio of prescription, after ultrafine crusher is pulverized, promptly get 21% indenes worm prestige Acarus tritici urea wetting powder.
This embodiment is applied to prevent and treat rice leaf roller.By 2000 extraordinarily water dilution sprayings, the control efficiency of 7 days and 15 days is respectively 97.7%, 94.6% behind the medicine with 21% indenes worm prestige Acarus tritici urea wetting powder.15% indenes worm prestige suspending agent by 2000 times with 5% Acarus tritici urea missible oil by 1000 times, use with the quadrat method use, the preventive effect of 7 days and 15 days is respectively 93.5%, 84.1% and 90.9%, 77.6% behind the medicine.The synergistic effect of the composite back of indenes worm prestige and Acarus tritici urea is obvious, and the preventive effect of rice leaf roller obviously is better than single agent.
Embodiment 8:30% indenes worm prestige Acarus tritici urea missible oil
Indenes worm prestige 5%
Acarus tritici urea 25%
N-Methyl pyrrolidone 10%
The newborn 1601# 5% of farming
The newborn 500# 5% of farming
Xylol complements to 100%.
Active component, emulsifier and the auxiliary agent ratio in prescription is added in the mixing kettle successively, stir, make 30% indenes worm prestige Acarus tritici urea missible oil.
This embodiment is applied to prevent and treat phyllocnistis citrella stainton.By 5000 extraordinarily water dilution sprayings, the control efficiency of 7 days and 15 days is respectively 93.8%, 91.4% behind the medicine with 30% indenes worm prestige Acarus tritici urea missible oil.15% indenes worm prestige suspending agent by 3500 times with 5% Acarus tritici urea missible oil by 1000 times, use with the quadrat method use, the preventive effect of 7 days and 15 days is respectively 88.7%, 85.5% and 80.1%, 83.4% behind the medicine.The synergistic effect of the composite back of indenes worm prestige and Acarus tritici urea is obvious, and the preventive effect of phyllocnistis citrella stainton obviously is better than single agent.Simultaneously, find also that in process of the test 30% indenes worm prestige Acarus tritici urea missible oil has the double effect of controlling to the oranges and tangerines blister mite, preventive effect reaches more than 80%.
Embodiment 9:20% indenes worm prestige Acarus tritici urea microemulsion
Indenes worm prestige 10%
Acarus tritici urea 10%
N-Methyl pyrrolidone 10%
The newborn 500# 5% of farming
The newborn 1601# 5% of farming
Water complements to 100%.
Former medicine, solvent, emulsifier are added together, make and be dissolved into even oil phase; With water-soluble component and the mixed water that gets of water; Under high-speed stirred, oil phase is mixed with water, make 20% indenes worm prestige Acarus tritici urea microemulsion.
This embodiment is applied to prevent and treat cotton bollworm.By 4000 extraordinarily water dilution sprayings, the control efficiency of 7 days and 15 days is respectively 92.9%, 88.3% behind the medicine with 20% indenes worm prestige Acarus tritici urea microemulsion.15% indenes worm prestige suspending agent by 2000 times with 5% Acarus tritici urea missible oil by 1000 times, use with the quadrat method use, the preventive effect of 7 days and 15 days is respectively 87.4%, 85.8% and 79.7%, 80.4% behind the medicine.The synergistic effect of the composite back of indenes worm prestige and Acarus tritici urea is obvious, and the preventive effect of cotton bollworm obviously is better than single agent.
Embodiment 10:40% indenes worm prestige Acarus tritici urea water dispersible granules
Indenes worm prestige 30%
Acarus tritici urea 10%
Negel 5%
Sodium lignin sulfonate 5%
Lauryl sodium sulfate 2%
Ammonium sulfate 5%
Precipitated calcium carbonate complements to 100%.
Active component, dispersant, wetting agent, disintegrant and filler is even by the mixed of prescription, become wetting powder through comminution by gas stream, add a certain amount of water extrusion again and make material, after dry screened, obtain 40% indenes worm prestige Acarus tritici urea water-dispersible granules.
Embodiment 11:22% indenes worm prestige lufenuron suspension agent
Indenes worm prestige 2%
Acarus tritici urea 20%
Methyl naphthalene sulfonate formaldehyde condensate 10%
Xanthans 1%
Bentonite 1%
Glycerine 5%
Water complements to 100%.
Each component such as active component, dispersant, wetting agent and water is even by the mixed of prescription, after grinding and/or high speed shear, obtain 22% indenes worm prestige lufenuron suspension agent.
This embodiment is applied to prevent and treat the apple olethreutid.By 4000 extraordinarily water dilution sprayings, the control efficiency of 7 days and 15 days is respectively 92.5%, 88.7% behind the medicine with 22% indenes worm prestige lufenuron suspension agent.15% indenes worm prestige suspending agent by 3500 times with 5% Acarus tritici urea missible oil by 1000 times, use with the quadrat method use, the preventive effect of 7 days and 15 days is respectively 89.3%, 86.5% and 77.8%, 79.8% behind the medicine.The synergistic effect of the composite back of indenes worm prestige and Acarus tritici urea is obvious, and the preventive effect of apple olethreutid obviously is better than single agent.Simultaneously, find also that in process of the test 22% indenes worm prestige lufenuron suspension agent has the double effect of controlling to European red mite.
Biological activity determination
Instance 1: the composite toxicity test of indenes worm prestige and butyl ether urea to diamond-back moth
Subjects: diamond-back moth 3 instar larvaes
The experiment soup is in component in the table 1 and ratio preparation.
Test method: with reference to " the agricultural industry criteria NY/T1154.7-2006 of the People's Republic of China (PRC) ".The examination worm is a diamond-back moth worm kind of picking up from the field through 5 generations of indoor feeding; Select the consistent third-instar larvae of growing, the culture dish that the diameter of access storing a variety of Chinese cabbage blade (Shanghai is blue or green) is 9 centimetres, every ware connect 10 and also do to anaesthetize preliminary treatment; Spray under 50PSI pressure with the potter spray tower; Ware of each spray, 1 milliliter of every ware spraying liquid, blank spray equivalent clear water.Each processing is provided with 6 concentration gradients, repeats 4 times.The culture dish of handling is put into 25 ℃, cultivate in the 12H/12H illumination box, inspection in 72 hours is borer population anyway, calculates lethality.Carry out statistical analysis with the DPS data processing software, calculate the LC of each medicament
50, press the abundant method of Sun Yun then and calculate co-toxicity coefficient (CTC).
When CTC≤80, then the composition performance is for antagonism, and when 80＜CTC＜120, then the composition performance is for for summation action, and when CTC>=120, then the composition performance is synergistic effect.
Actual measurement toxicity index (ATI)=standard medicament LC
50/ confession reagent agent LC
50* 100
The percentage composition of B in percentage composition+B medicament toxicity index * mixture of A in theoretical toxicity index (TTI)=A medicament toxicity index * mixture
Co-toxicity coefficient (CTC)=mixture actual measurement toxicity index (the ATI)/theoretical toxicity index (TTI) * 100 of mixture
The result shows that indenes worm prestige and butyl ether urea have obvious synergistic effect between proportioning 1: 0.1～20, especially 1: 1～10, and synergy is more obvious, and co-toxicity coefficient is more than 180, and specifically referring to table 2, proportioning is a weight ratio in the table 2.
Table 1 different disposal is to the toxicity test result of diamond-back moth
| Medicament and proportioning | LC 50(mg/L) | ATI | TTI | Co-toxicity coefficient CTC |
| The butyl ether urea | 45.23 | 100 | ||
| Indenes worm prestige | 10.36 | 436.6 | ||
| Indenes worm prestige: butyl ether urea=10: 1 | 25.36 | 178.4 | 130.6 | ?136.7 |
| Indenes worm prestige: butyl ether urea=5: 1 | 16.58 | 272.8 | 156.1 | ?174.8 |
| Indenes worm prestige: butyl ether urea=1: 1 | 7.61 | 594.3 | 268.3 | ?221.5 |
| Indenes worm prestige: butyl ether urea=1: 3 | 6.95 | 650.8 | 352.4 | ?184.7 |
| Indenes worm prestige: butyl ether urea=1: 5 | 6.24 | 724.8 | 380.5 | ?190.5 |
| Indenes worm prestige: butyl ether urea=1: 10 | 6.01 | 752.6 | 406.0 | ?185.4 |
| Indenes worm prestige: butyl ether urea=1: 20 | 6.82 | 663.2 | 420.6 | ?157.7 |
Instance 2: the composite toxicity test of indenes worm prestige and Acarus tritici urea to prodenia litura
Subjects: prodenia litura 3 instar larvaes
The experiment soup is in component in the table 2 and ratio preparation.
Test method: with reference to " the agricultural industry criteria NY/T1154.7-2006 of the People's Republic of China (PRC) ".With prodenia litura 3 instar larvaes, the culture dish that the diameter of access storing a variety of Chinese cabbage blade (Shanghai is blue or green) is 9 centimetres, every ware connect 10 and also do to anaesthetize preliminary treatment; Spray under 50PSI pressure with the potter spray tower; Ware of each spray, 1 milliliter of every ware spraying liquid, blank spray equivalent clear water.Each processing is provided with 6 concentration gradients, repeats 4 times.The culture dish of handling is put into 25 ℃, cultivate in the 12H/12H illumination box, inspection in 72 hours is borer population anyway, calculates lethality.Carry out statistical analysis with the DPS data processing software, calculate the LC of each medicament
50, press the abundant method of Sun Yun then and calculate co-toxicity coefficient (CTC).
The result shows that indenes worm prestige and Acarus tritici urea have obvious synergistic effect between proportioning 1: 0.05～10, and especially 1: 0.1～5 synergy are more obvious, and co-toxicity coefficient is more than 180, and specifically referring to table 2, proportioning is a weight ratio in the table 2.
Table 2 different disposal is to the toxicity test result of prodenia litura
| Medicament and proportioning | LC 50(mg/L) | ATI | TTI | Co-toxicity coefficient CTC |
| Indenes worm prestige | 25.19 | 100 | ||
| The Acarus tritici urea | 7.65 | 329.3 | ||
| Indenes worm prestige: Acarus tritici urea=20: 1 | 15.74 | 160.0 | 110.9 | ?144.3 |
| Indenes worm prestige: Acarus tritici urea=10: 1 | 11.38 | 221.4 | 120.8 | ?183.2 |
| Indenes worm prestige: Acarus tritici urea=3: 1 | 7.74 | 325.5 | 157.3 | ?206.9 |
| Indenes worm prestige: Acarus tritici urea=1: 1 | 5.33 | 472.6 | 214.6 | ?220.2 |
| Indenes worm prestige: Acarus tritici urea=1: 5 | 3.88 | 649.2 | 291.1 | ?223.1 |
| Indenes worm prestige: Acarus tritici urea=1: 10 | 4.71 | 534.8 | 308.4 | ?173.4 |
The above is merely preferred embodiment of the present invention, not in order to restriction the present invention, all any modifications of within spirit of the present invention and principle, being done, is equal to and replaces and improvement etc., all should be included within protection scope of the present invention.
Claims (8)
1. agricultural chemical composition for disinsection, active ingredient wherein is:
Indenes worm prestige; With
Butyl ether urea or Acarus tritici urea, the ratio of weight and number of said indenes worm prestige and butyl ether urea is 1: 0.1～20, the ratio of weight and number of said indenes worm prestige and Acarus tritici urea is 1: 0.05～10.
2. agricultural chemical composition for disinsection according to claim 1 is characterized in that, the ratio of weight and number of indenes worm prestige and butyl ether urea is 1: 1～10.
3. agricultural chemical composition for disinsection according to claim 1 is characterized in that, the ratio of weight and number of indenes worm prestige and Acarus tritici urea is 1: 0.1～5.
4. agricultural chemical composition for disinsection according to claim 1 is characterized in that, is mixed with agricultural during said composition practical application and goes up any one formulation that allows.
5. composition according to claim 4 is characterized in that, said formulation is wetting powder, missible oil, water dispersible granules, microemulsion, aqueous emulsion or suspending agent.
6. according to the arbitrary described agricultural chemical composition for disinsection of claim 1～5, it is characterized in that the total content of said active ingredient is 5～80% of a said agricultural chemical composition for disinsection total amount.
7. agricultural chemical composition for disinsection according to claim 6 is characterized in that, the total content of said active ingredient is 16～40% of a said agricultural chemical composition for disinsection total amount.
8. agricultural chemical composition for disinsection as claimed in claim 1 is used to prevent and treat crop pests, evil mite.
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| CN115211435A (en) * | 2021-09-13 | 2022-10-21 | 山东统防生物科技有限公司 | Efficient plant insect-resistant composition and preparation method thereof |
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Non-Patent Citations (3)
| Title |
|---|
| 刘刚.新型果蔬杀虫杀螨剂——丁醚脲.《西北园艺》.2006,(第4期),53. * |
| 刘长令.新型高效杀虫剂茚虫威.《农药》.2003,第10卷(第2期),42-44. * |
| 夏广安.新型高效杀虫剂——美除的应用.《农药市场信息》.2007,(第8期),32. * |
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