CN105707107A - Insecticide composition, preparation and applications thereof - Google Patents
Insecticide composition, preparation and applications thereof Download PDFInfo
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- CN105707107A CN105707107A CN201610196464.3A CN201610196464A CN105707107A CN 105707107 A CN105707107 A CN 105707107A CN 201610196464 A CN201610196464 A CN 201610196464A CN 105707107 A CN105707107 A CN 105707107A
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- China
- Prior art keywords
- insecticides
- agent
- indoxacarb
- preparation
- lufenuron
- Prior art date
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
- A01N47/38—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the group >N—CO—N< where at least one nitrogen atom is part of a heterocyclic ring; Thio analogues thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
- A01N47/34—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the groups, e.g. biuret; Thio analogues thereof; Urea-aldehyde condensation products
Abstract
The invention relates to the field of agricultural insecticides, in particular to insecticide composition, a preparation prepared from the insecticide composition and applications thereof. Active ingredients of the insecticide composition contain indoxacarb and lufenuron in the weight ratio being 1:(0.001-1,000). With the adoption of the insecticide composition, the insecticidal spectrum of the single ingredient of indoxacarb and lufenuron can be expanded, the control efficacy of indoxacarb and lufenuron on beet armyworms, Plutella xylostella and the like can be improved to a larger extent, meanwhile, the dosage can be reduced, and environmental pollution can be reduced. Besides, according to the insecticide composition, the two active ingredients have the obvious synergistic effect due to the ratio and have the significant control effect on plant pests, in particular to the beet armyworms, cabbage moths, cotton bollworms and/or cabbage worms.
Description
Technical field
The present invention relates to agricultural insecticide field, in particular it relates to a kind of insecticides, described in kill
Preparation that worm agent compositions is made and application thereof.
Background technology
Indoxacarb (indoxacarb) is that the diazines succeeded in developing by du pont company is new and effective
Insecticide, chemical name is (S)-N-[7-chloro-2,3,4a, 5-tetrahydrochysene-4a-(methoxycarbonyl) indeno
[1,2-e]-[1,3,4] diazine-2-carbonyl]-4 '-(trifluoromethoxy) methyl phenyl carbamate, molecular formula is
C22H17ClF3N3O7, relative molecular weight is 527.83, and its structure is:
Indoxacarb has the mechanism of action of uniqueness, for sodium-ion channel inhibitor, mainly blocks insect god
Sodium-ion channel in cell, causes target pest movement disorder, aphagia, paralysis final
Dead.Medicament, by contact and the entrance polypide that ingests, causes insect behavior to produce rapidly change, causes evil
Worm terminates rapidly ingesting, thus protects Target crops admirably.
The chemical name of lufenuron is (RS)-1-[the chloro-4-of 2,5-bis-(1,1,2,3,3,3-hexafluoro propoxyl group) benzene
Base]-3-(2,6-difluoro benzoyl) urea, its molecular formula is C17H8Cl2F8N2O3, relative molecular weight is
511.15, structural formula is:
Lufenuron (Lufenuron) is the latest generation substituted urea class insecticide that Syngenta Co., Ltd produces, mainly
By suppression biosynthetic to chitin, the formation of insect cuticle is stoped to play insecticidal action, to evil
Worm has stomach toxicity and action of contace poison concurrently, has preferable ovicidal action simultaneously.Especially to food leaf caterpillars such as fruit trees
There is outstanding preventive effect, have uniqueness to kill mechanism thrips, rust mite, trialeurodes vaporariorum, be suitable to preventing and treating to synthesis
Pyrethrin and organophosphorus pesticide produce the insect of resistance.The lasting period of medicament is long, advantageously reduces medication
Number of times;Good to crop safety, can be applicable to Semen Maydis, vegetable, Citrus, Cotton Gossypii, Rhizoma Solani tuber osi, Fructus Vitis viniferae,
Soybean and Other Crops.
Summary of the invention
It is an object of the invention to provide a kind of insecticide composition the newest to insect pest of the plant prevention effect
Thing and preparation and application thereof, particularly provide a kind of to beet armyworm, lopper worm, bollworm and dark greyish green
Insecticides that worm prevention effect is the newest and preparation and application thereof.
According to the first aspect of the invention, the invention provides a kind of insecticides, wherein, this kills
The active component of worm agent compositions contains indoxacarb and lufenuron, described indoxacarb and the weight of described lufenuron
Amount ratio is 1:0.001-1000.
According to the second aspect of the invention, the invention provides prepared by a kind of above-mentioned insecticides
Preparation, wherein, the dosage form of described preparation be cream, aqueous emulsion, microemulsion, soluble liquid, water hang
Floating agent, suspension emulsion, ultra-low volume spray agent, oil-suspending agent, microcapsule suspending agent, water surface film-spreading oil solution,
Wettable powder, water dispersible granules, dry suspending agent, soluble powder, soluble granula, emulsifiable powder
Agent, emulsifiable granule, granule, solid microcapsule formulation, effervescent tablet, effervescent granule, water
Floating dispersible granule or seed coat agent.
According to the third aspect of the present invention, the invention provides above-mentioned insecticides and preparation anti-
Control beet armyworm, diamondback moth, Pieris rapae, Prodenia litura, lopper worm, bollworm, oriental tobacco budworm, volume
The application of one or more in leaf moth class, carpocapsa pononella, leafhopper, diamond and colorado potato bug.
The present inventor it has been investigated that, the insecticides of the present invention can expand indoxacarb, lufenuron list
The insecticidal spectrum of one composition, it is possible to improve indoxacarb, lufenuron to a greater degree to beet armyworm, diamondback moth
Deng prevention effect, using dosage can be reduced simultaneously, reduce the pollution to environment.Further, the present invention carries
The insecticides of confession, the proportioning of two kinds of active component has obvious potentiation, to insect pest of the plant
Prevention effect is notable, and the particularly preventing and treating to beet armyworm, lopper worm, bollworm and/or Pieris rapae is imitated
Fruit is notable.
Additionally, the insecticides of the present invention can have the change of weeding, parasite killing or bactericidal property with other
Compound, particularly tags and stomach toxicity type insecticide is used in mixed way, it is possible to nematicide, protective agent, life
Long regulator, nutrient for plants or soil conditioner etc. are used in mixed way.
Specifically, the having the beneficial effect that of insecticides of the present invention:
1), in the insecticides of the present invention, each active component is compounding in certain ratio range, performance
Going out fabulous potentiation, mixed compositions relatively its single dose significantly improves insecticidal effect, and then fall
Low using dosage, while reducing peasant's drug cost, decreases the degree of effect on environment;
2) insecticidal spectrum is expanded so that a kind of medicament can prevent and treat multiple insects simultaneously, it is provided that one is extremely
Means of prevention easily and effectively, to Caulis et Folium Brassicae capitatae, flower coconut palm class, cabbage mustard, Fructus Lycopersici esculenti, Fructus Capsici, Fructus Cucumidis sativi, little cucumber,
Beet armyworm on the crops such as Fructus Solani melongenae, Caulis et Folium Lactucae sativae, Fructus Mali pumilae, pears, Fructus Persicae, Fructus Pruni, Cotton Gossypii, Rhizoma Solani tuber osi, Fructus Vitis viniferae,
Diamondback moth, Pieris rapae, Prodenia litura, lopper worm, bollworm, oriental tobacco budworm, leaf rollers, Fructus Mali pumilae
Moth-eaten moth, leafhopper, diamond, colorado potato bug have good prevention effect;
3) said composition has and tags and stomach poison function, the most effective to each instar larvae.Medicament is by contact
Entering in insect bodies with taking food, in 0-4 hour, insecticide i.e. stops taking food, and is benumbed immediately, the association of insecticide
Tune ability can decline (may result in larva to fall from crop), typically dead in 24-60 hour after medicine.
Medicament difference action characteristic makes to produce extremely strong mutual supplement with each other's advantages between two kinds of active component, can effectively delay
The generation of single dose resistance and development.
Other features and advantages of the present invention will be described in detail in detailed description of the invention part subsequently.
Detailed description of the invention
Hereinafter the detailed description of the invention of the present invention is described in detail.It should be appreciated that this place is retouched
The detailed description of the invention stated is merely to illustrate and explains the present invention, is not limited to the present invention.
The insecticides that the present invention provides, wherein, the active component of described insecticides contains
Indoxacarb and lufenuron, the weight ratio of described indoxacarb and described lufenuron is 1:0.001-1000.
According to the present invention, in order to improve the insecticidal activity of insecticides further, it is preferable that described
Insecticides in, the weight ratio of described indoxacarb and described lufenuron is 1:0.01-600;More
Preferably, the weight ratio of described indoxacarb and described lufenuron is 1:0.2-100;It is further preferred that
The weight ratio of described indoxacarb and described lufenuron is 1:0.3-50;It is further preferred that described indenes worm
The weight ratio of prestige and described lufenuron is 1:0.4-15;It is further preferred that described indoxacarb and described
The weight ratio of lufenuron is 1:0.5-8;It is further preferred that described indoxacarb and described lufenuron
Weight ratio is 1:2-8.
Insecticides according to the present invention, it is preferable that described active component is at described insecticide composition
Content in thing is 0.1-96 weight %;It is highly preferred that described active component is at described insecticides
In content be 0.2-80 weight %;It is further preferred that described active component is at described insecticide composition
Content in thing is 0.5-60 weight %.
According to the insecticides of the present invention, this insecticides also comprises surfactant, described
Surfactant is one or more in emulsifying agent, dispersant and wetting agent.
Described emulsifying agent can various emulsifying agents well known to formulations of pesticide field, specifically, this emulsifying
Agent can be phenethyl phenol polyethenoxy polyoxy propylene ether, styrylphenol formaldehyde resin polyoxyethylene-
Oxypropylene block type polyethers, aliphatic acid polyethenoxy ether, polyoxyethylene aliphatic alcohol ether, glycerol three Laurel
Acid ester polyoxyethylene ether, two Bian xenyl polyoxyethylene ether, glyceryl monolaurate polyoxyethylene ether, benzene
Vinyl benzene phenol polyethenoxy ether, castor oil polyoxyethylene ether, ethoxy castor oil polyoxyethylene ether, alkane
Base phenol polyoxyethylene polyoxypropylene ether, styryl phenyl polyoxyethylene ether, secondary octyl phenol polyethenoxy ether,
NPE, alkylaryl polyoxyethylene poly-oxygen propylene aether, alkylphenol polyoxyethylene, mistake
Water Span polyoxyethylene ether, aliphatic alcohol polyoxyethylene sulfonate, polyxyethylated
Phenol formaldehyde condensate, dodecyl sodium sulfonate calcium, decanol polyoxyethylene ether sulfosuccinic acid sodium, alkyl phenol are poly-
Oxygen vinyl Ether formaldehyde condensation products sodium sulfate, alkylphenol polyoxyethylene succinate monoester sulfonate, alkyl phenol
Polyoxyethylene phosphate, alkylphenol polyoxyethylene sulfosuccinates, polyoxyethylene fatty acid fat, poly-
Acrylic acid methyl ester., Polyoxyethylene fatty ammonia, ethoxy castor oil, alkyl-diethylene glycol ether-sodium sulfonate,
In fatty acid polyethylene glycol ester, fast penetration enhancer T, oleic acid PEG400 ester and fatty alcohol-polyoxyethylene ether
One or more.
Described dispersant can various dispersants well known to field of pesticide preparation, specifically, this dispersion
Agent can be sodium lignin sulfonate, sodium metnylene bis-naphthalene sulfonate (dispersant NNO), calcium lignosulfonate,
Sodium polyacrylate, sodium methylene bis-naphthalene sulfonate, dispersing agent MF, polyvinylpyrrolidone,
Alkyl amide taurate, the sodium salt of alkyl naphthalene sulfonic acid condensation polymer and sodium methylene bis-naphthalene sulfonate formaldehyde condensation
One or more in thing.
Described wetting agent can various wetting agent well known to field of pesticide preparation, specifically, this moistening
Agent can be Negel, sodium lauryl sulphate, Teepol, DBSA
Sodium, fatty alcohol polyglycol ether sulfate, fatty alcohol-polyoxyethylene ether, NPE, mistake
Water Span polyoxyethylene ether, alkyl naphthalene formaldehyde condensation substance, alkylnaphthalene sulfonate and other profits
One or more in humectant.
According to the insecticides of the present invention, wherein, described insecticides possibly together with preparation with helping
Agent and/or carrier;
Described auxiliary agent is one or more in solvent, thickening agent, antifreezing agent and defoamer;
Described solvent can various solvents well known to field of pesticide preparation, specifically, this solvent is permissible
For water, N-Methyl pyrrolidone, N,N-dimethylformamide, tributyl phosphate, tetrahydrofurfuryl alcohol, toluene,
Dimethylbenzene, dimethyl sulfoxide, oxolane, 1,4 dioxane, Hexalin, Ketohexamethylene, epoxy are big
Oleum Glycines, plant soybean oil, liquid wax, lubricating oil and solvent naphtha 100, No. 150, No. 180,200
One or more in number.
Described thickening agent can various thickening agents well known to field of pesticide preparation, specifically, this thickening
Agent can be xanthan gum, polyvinyl alcohol, sodium alginate, kieselguhr, starch, Kaolin and organic swelling
One or more in soil.
Described antifreezing agent can various antifreezing agents well known to field of pesticide preparation, specifically, this is antifreeze
Agent can be one or more in propylene glycol, ethylene glycol, glycerol and carbamide.
Described defoamer can various defoamer well known to field of pesticide preparation, specifically, this froth breaking
Agent can be tributyl phosphate and/or silicone.
Described carrier can various carriers well known to field of pesticide preparation, can be solid or liquid,
Including various silicates, carbonate, Sulfates, oxide-based, phosphoric acid salt, plant vector
Class, synthetic vectors class.Specifically, this carrier can be white carbon, Kaolin, kieselguhr, bentonite,
Fertile the mixing of precipitated calcium carbonate, Gypsum Fibrosum, attapulgite, soluble starch, carbamide, amine fertilizer, carbamide and amine
Compound, glucose, maltose, sucrose, citric acid, Anhydrous potassium carbonate, natrium carbonicum calcinatum, anhydrous carbon
One or more in potassium hydrogen phthalate, anhydrous sodium sulfate and anhydrous sodium bicarbonate.
The present invention also provides for the preparation prepared by above-mentioned insecticides, and the dosage form of described preparation is breast
Oil, aqueous emulsion, microemulsion, soluble liquid, aqueous suspension agent, suspension emulsion, ultra-low volume spray agent,
Oil-suspending agent, microcapsule suspending agent, water surface film-spreading oil solution, wettable powder, water dispersible granules, dry suspension
Agent, soluble powder, soluble granula, emulsifiable powder, emulsifiable granule, granule, solid
The floating dispersible granule of microcapsule formulation, effervescent tablet, effervescent granule, water or seed coat agent;Preferably,
The dosage form of described preparation is cream, aqueous emulsion, aqueous suspension agent, oil-suspending agent, wettable powder, moisture
Shot agent, soluble powder or soluble granula.Above-mentioned dosage form all can be by the conventional method system of this area
Standby.
Under preferable case, consisting of of described cream weight percent: active component 0.1-96%, table
Face activating agent 1-30%, solvent complement to 100%, and wherein, described solvent is aromatic hydrocarbon solvent or alcohols
Solvent;Preparation method: by active component, surfactant and solvent mixed dissolution so that it is uniformly oil
Phase.
Under preferable case, consisting of of described aqueous emulsion or microemulsion weight percent: active component
0.1-96%, emulsifying agent 1-30%, thickening agent 0.1-5%, antifreezing agent 1-20%, organic solvent 1-30%,
Water complements to 100%, and described organic solvent is aromatic hydrocarbon solvent or alcohols solvent;
Under preferable case, the preparation method of described aqueous emulsion is by active component, emulsifying agent and organic solvent
Mixed dissolution so that it is become homogeneous oil phase;By water, antifreezing agent, thickening agent mixing so that it is uniformly water
Phase.Under high velocity agitation, aqueous phase joined oil phase or oil phase is joined aqueous phase, forming dispersibility good
Good aqueous emulsion.
Under preferable case, the preparation method of described microemulsion is by active component, emulsifying agent and organic solvent
Mixed dissolution so that it is become homogeneous oil phase;By water, antifreezing agent, thickening agent mixing so that it is uniformly water
Phase.Under conditions of stirring, oil phase gradually adds water so that it is form the microemulsion of transparent and homogeneous.
Under preferable case, consisting of of described aqueous suspension agent weight percent: active component 0.1-96%,
Dispersant 1-30%, wetting agent 1-30%, antifreezing agent 1-20%, thickening agent 0.1-5%, defoamer 0.1-5%,
Emulsifying agent 1-30%, water complement to 100%.
Under preferable case, the preparation method of described aqueous suspension agent is with water as medium, by active component, table
Face activating agent, thickening agent, defoamer, antifreezing agent add in sand milling still finely ground, make aqueous suspension agent.
Under preferable case, consisting of of described oil-suspending agent weight percent: active component 0.1-96%,
Dispersant 1-30%, wetting agent 0.1-30%, thickening agent 0.1-10%, defoamer 0.1-5%, emulsifying agent
1-30%, oil complement to 100%, and described oil is selected from plant soybean oil, plant Zea mays oil, plant Semen arachidis hypogaeae
One or more of oil, methyl oleate, paraffin oil, Oleum Ricini, paraffin oil, solvent naphtha etc..Preferably
In the case of, the preparation method of described oil-suspending agent is with oil as medium, by active component, surfactant,
Thickening agent, defoamer add in sand milling still finely ground, make oil-suspending agent.
Under preferable case, described wettable powder, soluble powder, water dispersible granules, soluble granula
The composition of weight percent is: active component 0.1-96%, wetting agent 1-20%, dispersant 1-20%,
Other carriers complement to 100%;
The preparation method of wettable powder or soluble powder be by each active component, surfactant and
His carrier etc. is sufficiently mixed, through ultra-fine pulverizer disintegrating and get final product.
The preparation method of water dispersible granules or soluble granula is by each active component and powder carrier, moistening
Agent and dispersant etc. carry out co-grinding, spray-dried or airpillow-dry and get final product;Or after adding water kneading,
Adding in comminutor and carry out pelletize, drying, screening, to obtain final product the most again.
In addition to above-mentioned dosage form, the insecticides of the present invention can also make what field of pesticide preparation was commonly used
Other dosage forms, such as liquor, water preparation, emulsifiable concentrate, microemulsion, suspension emulsion, microcapsule etc., its
Prepared by the conventional method of this area.
According to the present invention, described insecticides can provide with the form of above-mentioned preparation, i.e. compositions
In each material the most by evenly mixing, can directly apply;Can also the independent preparation of each material form provide,
Mix voluntarily in the container such as bucket or tank before using, such as, active component in the present invention made concentrate,
Before using, by this concentrate, directly and water is mixed to get the concentration of required active substance.
Present invention also offers described insecticides and preparation thereof at the preventing and treating cruciate flower such as Caulis et Folium Brassicae capitatae, cabbage mustard
Section vegetable and Fructus Lycopersici esculenti, Fructus Capsici, Fructus Cucumidis sativi, little cucumber, Fructus Solani melongenae, Caulis et Folium Lactucae sativae, Fructus Mali pumilae, pears, Fructus Persicae, Fructus Pruni,
Beet armyworm on the crops such as Cotton Gossypii, Rhizoma Solani tuber osi, Fructus Vitis viniferae, diamondback moth, Pieris rapae, Prodenia litura, sweet
Blue noctuid, bollworm, oriental tobacco budworm, leaf rollers, carpocapsa pononella, leafhopper, diamond and Rhizoma Solani tuber osi first
The application of one or more in worm;Preferably, the invention provides insecticides and preparation exists
The application of one or more in preventing and treating beet armyworm, lopper worm, bollworm and Pieris rapae.
The compositions of the present invention also can have the compound of sterilization, parasite killing or herbicidal performance and mix and make with other
With, it is possible to mix with nematicide, protective agent, growth regulator, nutrient for plants or soil conditioner
Use.
The application process of the insecticides of the present invention is simple, in larva 2-3 age, to crop and work
The place of thing growth is used according to a conventional method, as mix soil, spray, spray, cast etc..Its amount of application root
Depending on weather conditions or crop condition, usually, consumption is 5-300g a.i./hm2, preferably 10-50g
a.i./hm2。
The insecticides of the present invention, its insecticidal effect is the most relevant with extraneous factor such as weather, but logical
Cross the impact using suitable dosage form can slow down weather.
Hereinafter by embodiment, the present invention will be conducted further description, but the present invention will be not limited in down
State embodiment.
In following embodiment, indoxacarb is purchased from Shangyu Nutrichem Co., Ltd, registration card number:
PD20122031, lufenuron is purchased from Shangyu Nutrichem Co., Ltd, registration card number:
PD20151795。
Test example 1
The purpose of this test example is to study the potentiation that indoxacarb is mixed with lufenuron.
(1) worm kind is measured
Diamondback moth (Plutella xylostella) is raised in indoor Vermiculitum Turnip Sprouts method.
(2) assay method
Assay method uses blade infusion process.By the cabbage leaves without pollution by pesticides with after dish detergent wash clean
Dry.After indoxacarb and the former medicinal acetone of lufenuron are made into mother solution, with the Triton X-100 of 0.01%
It is diluted to required concentration, is made into the mixture of different ratio simultaneously on demand.Ready blade is soaked
In medicinal liquid 10 seconds, after taking-up, vertically it is hung on iron wire and dries in the shade.The blade dried in the shade is placed on cultivation
In ware, access three age primary larva.Keep 25 DEG C, check mortality rate at 24 and 48 hours respectively.
Each medicament or be diluted to 5-7 concentration by proportioning (weight ratio), each concentration 3-5 repeats,
Each repetition 15-20 head diamondback moth larvae.
(3) statistical analysis
With Polo software, the data obtained carried out machine value analysis, the invalid mensuration of automatic rejection.According to Sun
The program calculating co-toxicity coefficient (CTC), co-toxicity coefficient=actual measurement is write etc. method Excel 9.0 platform
Toxicity index/theory toxicity index × 100, the LC calculated according to Polo50Or LC90CTC is calculated with proportioning
Value.When CTC >=120, show as potentiation;When CTC≤80, show as antagonism;80 < CTC
< 120, shows as summation action.
(4) result and discussion
Indoxacarb is quickly converted to DCJW (N-removes methoxycarbonyl group metabolite) in insect bodies, by
DCJW acts on insecticide neurocyte inactivation state Voltage-gated sodium channels, acts on elder brother with lufenuron
Worm larva, stoping exfoliating process and the difference that kills off the insect pests, the two is mixed in certain proportion has significantly
Potentiation, the results are shown in Table 1 with table 2 (table 1 is indoxacarb toxicity test result mixed with lufenuron,
Table 2 is indoxacarb toxicity test co-toxicity coefficient mixed with lufenuron (CTC) statistical table (LC50))。
Table 1
Insecticide | Examination borer population | LC50(mg/L) 95% confidence limit | Slope±SE | CTC |
Indoxacarb | 178 | 0.054(0.044-0.068) | 2.764±0.332 | |
Lufenuron | 168 | 0.100(0.077-0.135) | 2.030±0.275 | |
Indoxacarb: lufenuron=2:1 | 174 | 0.049(0.025-0.085) | 1.381±0.229 | 130.157 |
Indoxacarb: lufenuron=1:1 | 172 | 0.051(0.028-0.063) | 1.684±0.247 | 137.532 |
Indoxacarb: lufenuron=1:2 | 135 | 0.035(0.026-0.046) | 2.295±0.349 | 222.528 |
Indoxacarb: lufenuron=1:4 | 180 | 0.039(0.009-0.085) | 2.833±0.385 | 219.085 |
Indoxacarb: lufenuron=1:8 | 173 | 0.043(0.013-0.093) | 1.535±0.228 | 212.449 |
LC50Unit be mg/L (being equivalent to ppm)
Table 2
Insecticide | LC50Or proportioning (mg/L) | Toxicity index | Co-toxicity coefficient | |
Indoxacarb (A) | 0.054 | TIa | 100 | 130.157 |
Lufenuron (B) | 0.100 | TIb | 54 | |
A+B | 0.049 | ATI | 110.200 | |
Proportioning 2:1 | 0.67 | TTI | 84.667 | |
0.33 | ||||
Indoxacarb (A) | 0.054 | TIa | 100 | 137.532 |
Lufenuron (B) | 0.100 | TIb | 54 | |
A+B | 0.051 | ATI | 105.900 | |
Proportioning 1:1 | 0.5 | TTI | 77.000 | |
0.5 | ||||
Indoxacarb (A) | 0.054 | TIa | 100 | 222.528 |
Lufenuron (B) | 0.100 | TIb | 54 | |
A+B | 0.035 | ATI | 154.286 | |
Proportioning 1:2 | 0.33 | TTI | 69.333 | |
0.67 | ||||
Indoxacarb (A) | 0.054 | TIa | 100 | 219.05 |
Lufenuron (B) | 0.100 | TIb | 54 | |
A+B | 0.039 | ATI | 138.462 | |
Proportioning 1:4 | 0.2 | TTI | 63.200 | |
0.8 | ||||
Indoxacarb (A) | 0.054 | TIa | 100 | 212.449 |
Lufenuron (B) | 0.100 | TIb | 54 | |
A+B | 0.043 | ATI | 125.581 | |
Proportioning 1:8 | 0.11 | TTI | 59.111 | |
0.89 |
When indoxacarb and lufenuron proportioning are 2:1,1:1,1:2,1:4 and 1:8 as can be seen from Table 2,
Based on LC50CTC value be respectively 130,137,222,219 and 212 all much larger than 100, explanation
It has obvious potentiation.
Preparation example 1
This preparation example is in order to illustrate the preparation method of the cream containing 0.5% active component.
By indoxacarb 1g, lufenuron 4g, NPE (7) 50g, fatty alcohol polyoxy second
Alkene ether 50g, dimethylbenzene are mended to 1kg, and mixed dissolution uniformly oil phase obtains cream A1.
Preparation example 2
This preparation example is in order to illustrate the preparation method of the cream containing 0.5% active component.
By indoxacarb 4g, lufenuron 1g, aliphatic amine polyoxyethylene ether 40g, laurate polyoxyethylene ether
40g, solvent naphtha 180 are mended to 1kg, and mixed dissolution uniformly oil phase obtains cream A2.
Preparation example 3
This preparation example is in order to illustrate the preparation method of the cream containing 80% active component.
By indoxacarb 1g, lufenuron 799g, calcium dodecyl benzene sulfonate 50g, fatty alcohol-polyoxyethylene ether
(40) 50g, single oleamide polyoxyethylene groups disodium sulfosuccinate 50g, oleic acid 10g, N-methyl pyrrole
Pyrrolidone is mended to 1kg, and mixed dissolution uniformly oil phase obtains cream A3.
Preparation example 4
This preparation example is in order to illustrate the preparation method of the cream containing 80% active component.
Indoxacarb 799g, lufenuron 1g, calcium dodecyl benzene sulfonate 30g, emulsifying agent 0203B 40g,
N-Methyl pyrrolidone is mended to 1kg mixed dissolution uniformly oil phase, obtains cream A4.
Preparation example 5
This preparation example is in order to illustrate the preparation method of the aqueous emulsion containing 1% active component.
Indoxacarb 0.1g, lufenuron 9.9g, Ketohexamethylene 50g, fatty alcohol-polyoxyethylene ether (5) 20g,
Fatty alcohol-polyoxyethylene ether (80) 20g, carbamide 80g, Kaolin 30g, silicone 20g, water complement to
1kg。
Preparation method: by indoxacarb, lufenuron, Ketohexamethylene, fatty alcohol-polyoxyethylene ether (5) and fat
Fat polyoxyethylenated alcohol (80) mixed dissolution so that it is become homogeneous oil phase;By water, carbamide, Kaolin,
Silicone mixed dissolution so that it is become homogeneous aqueous phase;Under (3000 revs/min) stirring at a high speed, by water
It is added to oil phase, forms the aqueous emulsion A5 of favorable dispersibility.
Preparation example 6
This preparation example is in order to illustrate the preparation method of the aqueous emulsion containing 1% active component.
Indoxacarb 9.9g, lufenuron 0.1g, N-Methyl pyrrolidone 30g, polyvinyl alcohol 20g, 12
Alkyl benzene calcium sulfonate 40g, phenethyl phenol polyethenoxy polyethenoxy ether 60g, ethylene glycol 50g, alginic acid
Sodium 10g, silicone 20g, water complement to 1kg.
Preparation method: by indoxacarb, lufenuron, N-Methyl pyrrolidone, polyvinyl alcohol, dodecyl
Benzenesulfonic acid calcium and phenethyl phenol polyethenoxy polyethenoxy ether mixed dissolution so that it is become homogeneous oil phase;Will
Water, ethylene glycol, sodium alginate, silicone mixed dissolution so that it is become homogeneous aqueous phase;At a high speed (3000
Rev/min) under stirring, aqueous phase is joined oil phase, forms the aqueous emulsion A6 of favorable dispersibility.
Preparation example 7
This preparation example is in order to illustrate the preparation method of the aqueous emulsion containing 40% active component.
Indoxacarb 1g, lufenuron 399g, tributyl phosphate 100g, dodecylbenzene sodium sulfonate 50g,
Castor oil polyoxyethylene ether 50g, xanthan gum 3g, carbamide 50g, water complement to 1kg.
Preparation method: by indoxacarb, lufenuron, tributyl phosphate, dodecylbenzene sodium sulfonate and Semen Ricini
Oil polyoxyethylene ether mixed dissolution so that it is become homogeneous oil phase;By water, xanthan gum, carbamide mixed dissolution,
Become homogeneous aqueous phase;Under (3000 revs/min) stirring at a high speed, aqueous phase is joined oil phase,
Form the aqueous emulsion A7 of favorable dispersibility.
Preparation example 8
This preparation example is in order to illustrate the preparation method of the aqueous emulsion containing 40% active component.
Indoxacarb 399g, lufenuron 1g, N-Methyl pyrrolidone 50g, polymethyl acrylate 30g, alkane
Base-diethylene glycol ether-sodium sulfonate 35g, calcium dodecyl benzene sulfonate 20g, propylene glycol alginate 10g,
Ethylene glycol 40g, tributyl phosphate 20g, water complement to 1kg.
Preparation method: by indoxacarb, lufenuron, N-Methyl pyrrolidone, polymethyl acrylate, alkyl
-diethylene glycol ether-sodium sulfonate, calcium dodecyl benzene sulfonate and propylene glycol alginate mixed dissolution so that it is
Become homogeneous oil phase;By water, ethylene glycol, tributyl phosphate mixed dissolution so that it is become homogeneous aqueous phase;
Under (3000 revs/min) stirring at a high speed, oil phase is joined aqueous phase, forms the water of favorable dispersibility
Emulsion A8.
Preparation example 9
This preparation example is in order to illustrate the preparation method of the aqueous emulsion containing 60% active component.
Indoxacarb 200g, lufenuron 400g, N,N-dimethylformamide 20g, alkylphenol-polyethenoxy
Ether formaldehyde condensation products sodium sulfate 10g, agriculture breast 1601 10g, propylene glycol 40g, silicone 5g, water complement to
1kg。
Preparation method: by indoxacarb, lufenuron, N,N-dimethylformamide, alkylphenol polyoxyethylene
Formaldehyde condensation products sodium sulfate, agriculture breast 1601 mixed dissolutions so that it is become homogeneous oil phase;Jiang Shui, the third two
Alcohol, silicone, mixed dissolution so that it is become homogeneous aqueous phase;Under high velocity agitation, oil phase is joined water
Phase, forms the aqueous emulsion A9 of favorable dispersibility.
Preparation example 10
This preparation example is in order to illustrate the preparation method of the aqueous suspension agent containing 0.1% active component.
Indoxacarb 0.04g, lufenuron 0.96g, fatty alcohol-polyoxyethylene ether 50g, kieselguhr 30g, sweet
Oil 40g, tributyl phosphate 20g, water complement to 1kg.
Preparation method: with water as medium, by indoxacarb, lufenuron, fatty alcohol-polyoxyethylene ether, diatom
Soil, glycerol, tributyl phosphate add in sand milling still finely ground, make aqueous suspension agent A10.
Preparation example 11
This preparation example is in order to illustrate the preparation method of the aqueous suspension agent containing 0.1% active component.
Indoxacarb 0.96g, lufenuron 0.04g, styrylphenol polyoxyethylene ether 50g, Kaolin 12g,
Sodium lauryl sulphate 10g, glycerol 80g, silicone 50g water complement to 1kg.
Preparation method: with water as medium, by indoxacarb, lufenuron, styrylphenol polyoxyethylene ether,
Kaolin, sodium lauryl sulphate, glycerol, silicone add in sand milling still finely ground, make aqueous suspension agent
A11。
Preparation example 12
This preparation example is in order to illustrate the preparation method of the aqueous suspension agent containing 35% active component.
Indoxacarb 50g, lufenuron 300g, sodium lignin sulfonate 50g, sodium lauryl sulphate 10g,
Starch 20g, ethylene glycol 60g, silicone 50g, water complement to 1kg.
Preparation method: with water as medium, by indoxacarb, lufenuron, sodium lignin sulfonate, dodecyl
Sodium sulfate, starch, ethylene glycol, silicone add in sand milling still finely ground, make aqueous suspension agent A12.
Preparation example 13
This preparation example is in order to illustrate the preparation method of the aqueous suspension agent containing 35% active component.
Indoxacarb 300g, lufenuron 50g, sorbitan fatty acid ester polyoxyethylene ether 30g, ten
Sodium dialkyl sulfate 10g, butyl oleate 50g, ethylene glycol 50g, go back virgin rubber 3g, tributyl phosphate 40g,
Water complements to 1kg.
Preparation method: with water as medium, by indoxacarb, lufenuron, sorbitan fatty acid ester polyoxy
Vinyl ethers, sodium lauryl sulphate, butyl oleate, ethylene glycol, go back virgin rubber, tributyl phosphate add
In sand milling still finely ground, make aqueous suspension agent A13.
Preparation example 14
This preparation example is in order to illustrate the preparation method of the oil-suspending agent containing 35% active component.
Indoxacarb 300g, lufenuron 50g, organobentonite 100g, butyl oleate 50g, tricresyl phosphate fourth
Ester 50g, plant soybean oil are mended to 1kg.
Preparation method: with plant soybean oil as medium, by indoxacarb, lufenuron, organobentonite, oil
Acid butyl ester, tributyl phosphate add in sand milling still finely ground, make oil-suspending agent A14.
Preparation example 15
This preparation example is in order to illustrate the preparation method of the oil-suspending agent containing 0.42% active component.
Indoxacarb 1.2g, lufenuron 3g, fatty alcohol-polyoxyethylene ether 100g, NPE
50g, organobentonite 30g, tributyl phosphate 40g, epoxy soybean oil are mended to 1kg.
Preparation method: with epoxy soybean oil as medium, by indoxacarb, lufenuron, aliphatic alcohol polyethenoxy
Ether, NPE, organobentonite, tributyl phosphate add in sand milling still finely ground, make
Oil-suspending agent A15.
Preparation example 16
This preparation example is in order to illustrate the preparation method of the oil-suspending agent containing 0.42% active component.
Indoxacarb 3g, lufenuron 1.2g, 1,2-dicarboxylic acids ethyl-N-alkyl sulfosuccinates amide four sodium 90g,
Butyl oleate 50g, organobentonite 10g, silicone 20g, paraffin oil are mended to 1kg.
Preparation method: with paraffin oil as medium, by indoxacarb, lufenuron, 1,2-dicarboxylic acids ethyl-N-
Alkyl sulfosuccinates amide four sodium, butyl oleate, silicone, organobentonite add in sand milling still finely ground,
Make oil-suspending agent A16.
Preparation example 17
This preparation example is in order to illustrate the preparation method of the oil-suspending agent containing 49.55% active component.
Indoxacarb 0.5g, lufenuron 495g, fatty alcohol-polyoxyethylene ether 100g, Nonyl pheno
Ether (7) 50g, attapulgite 30g, silicone 20g, epoxy soybean oil are mended to 1kg.
Preparation method: with epoxy soybean oil as medium, by indoxacarb, lufenuron, aliphatic alcohol polyethenoxy
Ether, NPE (7), attapulgite, silicone add in sand milling still finely ground, make oil outstanding
Floating agent A17.
Preparation example 18
This preparation example is in order to illustrate the preparation method of the oil-suspending agent containing 49.55% active component.
Indoxacarb 495g, lufenuron 0.5g, polyoxyethylene sorbitan list isostearate 100g,
Castor oil polyoxyethylene ether (20) 50g, alkylphenol polyoxyethylene 50g, white carbon 50g, tricresyl phosphate
Butyl ester 20g, solvent naphtha 180 are mended to 1kg.
Preparation method: with solvent naphtha 180 as medium, by indoxacarb, lufenuron, polyoxyethylene sorbitan
Sorbitol list isostearate, castor oil polyoxyethylene ether (20), alkylphenol polyoxyethylene, Linesless charcoal
Black, tributyl phosphate adds in sand milling still finely ground, makes oil-suspending agent A18.
Preparation example 19
This preparation example is in order to illustrate the preparation method of the wettable powder containing 50.5% active component.
Indoxacarb 1g, lufenuron 504g, sodium lauryl sulphate 20g, Kaolin are complemented to 1kg,
It is sufficiently mixed, after ultra-fine pulverizer disintegrating, i.e. obtains the wettable powder containing 50.5% active component
A19。
Preparation example 20
This preparation example is in order to illustrate the preparation method of the wettable powder containing 90% active component.
Indoxacarb 250g, lufenuron 650g, sodium lignin sulfonate 10g, soluble starch are complemented to
1kg, is sufficiently mixed, and after ultra-fine pulverizer disintegrating, i.e. obtains the wettable powder containing 90% active component
Agent A20.
Preparation example 21
This preparation example is in order to illustrate the preparation method of the wettable powder containing 90% active component.
By indoxacarb 650g, lufenuron 250g, styryl phenyl polyoxyethylene ether 50g, bentonite
50g, attapulgite complement to 1kg, are sufficiently mixed, and after ultra-fine pulverizer disintegrating, i.e. obtain containing 90%
The wettable powder A21 of active component.
Preparation example 22
This preparation example is in order to illustrate the preparation method of the wettable powder containing 21.6% active component.
By indoxacarb 100g, lufenuron 116g, N-methyl-N-long-chain fatty acid taurate 20g, shallow lake
Powder 20g, precipitated calcium carbonate complement to 1kg, are sufficiently mixed, and after ultra-fine pulverizer disintegrating, i.e. obtain
Wettable powder A22 containing 21.6% active component.
Preparation example 23
This preparation example is in order to illustrate the preparation method of the wettable powder containing 21.6% active component.
By indoxacarb 116g, lufenuron 100g, alkyl phosphate triethanolamine salt 50g, lignin sulfonic acid
Sodium 50g, Pulvis Talci complement to 1kg, are sufficiently mixed, and after ultra-fine pulverizer disintegrating, i.e. obtain containing 21.6%
The wettable powder A23 of active component.
Preparation example 24
This preparation example is in order to illustrate the preparation method of the water-dispersible granules containing 96% active component.
Indoxacarb 60g, lufenuron 900g, alkylphenol polyoxyethylene succinate monoester sulfonate 20g,
Sodium lauryl sulphate 10g, carbamide complement to 1kg, i.e. obtain water-dispersible through airpillow-dry after co-grinding
Granule A24.
Preparation example 25
This preparation example is in order to illustrate the preparation method of the water-dispersible granules containing 96% active component.
Indoxacarb 900g, lufenuron 60g, aliphatic alcohol polyoxyethylene sulfonate 10g, alkyl naphthalene sulfonic acid
Salt 10g, polyvinylpyrrolidone complement to 1kg, co-grinding, spray-dried i.e. obtain water-dispersible grain
Agent A25.
Preparation example 26
This preparation example is in order to illustrate the preparation method of the water-dispersible granules containing 30% active component.
Indoxacarb 1g, lufenuron 299g, dialkyl group succinic acid sulfonate 30g, sodium lignin sulfonate 20g,
Gypsum Fibrosum complements to 1kg, co-grinding, after adding water kneading, adds in comminutor and carries out pelletize, then
Again drying, sieve and i.e. obtain water dispersible granules A26.
Preparation example 27
This preparation example is in order to illustrate the preparation method of the water-dispersible granules containing 30% active component.
Indoxacarb 299g, lufenuron 1g, LOMAR PWA EINECS 246-676-2-phenol sulfonic acid-formaldehyde condensation substance 20g, ammonium sulfate 30g,
Carbamide complements to 1kg, co-grinding, after adding water kneading, adds in comminutor and carries out pelletize, then
Again drying, sieve and i.e. obtain water dispersible granules A27.
Test case 1
This test case is in order to illustrate that this insecticides is to beet armyworm, lopper worm, bollworm, dish
Kattapillar field efficacy
According to the Ministry of Agriculture's " pesticide field efficacy medicine test criterion " requirement, carry out different geographic region in field
The repeatedly test of pesticide effectiveness in territory, checking the present composition to beet armyworm, lopper worm, bollworm,
The field control effect of Pieris rapae.
Test medication: the insecticide of the present invention of preparation in indoxacarb, lufenuron and above-mentioned preparation example 1-27
Composite preparation A1-A27.
Test method: use the squama wing of GB/T 17980.13-2000 insecticide control brassicaceous vegetable
The method of mesh larva field control effectiveness test principle states, formulation rate is as shown in table 3, investigates insect population before dispenser
Radix, 3 days, 7 days investigation remaining borer populations alive after dispenser.DMRT method is used to carry out data statistics and divide
Analysis, and calculate Rectifying efficacies according to following formula.The results are shown in Table 3 (table 3 is indoxacarb, lufenuron and
Insecticides preparation of the present invention is to beet armyworm, lopper worm, bollworm, the field 7 of Pieris rapae
It prevention effect).
Rectifying efficacies (%)=(insect population number after insect population number × chemicals treatment district medicine before 1-blank district medicine/
Insect population number before insect population number/chemicals treatment district medicine after blank district medicine) × 100
Table 3
As can be seen from Table 3, compare two single-activity component preparations, indoxacarb system compounding with lufenuron
The prevention effect of beet armyworm, lopper worm etc. is significantly improved by agent, to bollworm, Pieris rapae also
There is obvious potentiation.
The preferred embodiment of the present invention described in detail above, but, the present invention is not limited to above-mentioned reality
Execute the detail in mode, in the technology concept of the present invention, can be to the technical side of the present invention
Case carries out multiple simple variant, and these simple variant belong to protection scope of the present invention.
It is further to note that each the concrete technology described in above-mentioned detailed description of the invention is special
Levy, in the case of reconcilable, can be combined by any suitable means, in order to avoid need not
The repetition wanted, various possible compound modes are illustrated by the present invention the most separately.
Additionally, combination in any can also be carried out between the various different embodiment of the present invention, as long as its
Without prejudice to the thought of the present invention, it should be considered as content disclosed in this invention equally.
Claims (10)
1. an insecticides, it is characterised in that the active component of described insecticides contains
Having indoxacarb and lufenuron, the weight ratio of described indoxacarb and described lufenuron is 1:0.001-1000.
Insecticides the most according to claim 1, wherein, described indoxacarb and described louse
The weight ratio of demodicid mite urea is 1:0.01-600.
Insecticides the most according to claim 1, wherein, described indoxacarb and described louse
The weight ratio of demodicid mite urea is 1:0.3-50.
Insecticides the most according to claim 1, wherein, described indoxacarb and described louse
The weight ratio of demodicid mite urea is 1:0.4-15.
Insecticides the most according to claim 1, wherein, described indoxacarb and described louse
The weight ratio of demodicid mite urea is 1:2-8.
6. according to the insecticides described in any one in claim 1-5, wherein, described work
Property composition content in described insecticides is 0.1-96 weight %;
Preferably, described active component content in described insecticides is 0.2-80 weight %;
It is highly preferred that the content that described active component is in described insecticides is 0.5-60 weight %.
Insecticides the most according to claim 6, wherein, described insecticides is also
Comprising surfactant, described surfactant is the one in emulsifying agent, dispersant and wetting agent
Or it is multiple.
Insecticides the most according to claim 7, wherein, described insecticides is also
Containing preparation used additives and/or carrier;
Described auxiliary agent is one or more in solvent, thickening agent, antifreezing agent and defoamer.
9. by the preparation prepared by the insecticides described in any one in claim 1-8, its
In, the dosage form of described preparation is cream, aqueous emulsion, microemulsion, soluble liquid, aqueous suspension agent, hangs
Emulsion, ultra-low volume spray agent, oil-suspending agent, microcapsule suspending agent, water surface film-spreading oil solution, wettable powder
Agent, water dispersible granules, dry suspending agent, soluble powder, soluble granula, emulsifiable powder, can breast
Change granule, granule, solid microcapsule formulation, effervescent tablet, effervescent granule, the floating dispersion of water
Granule or seed coat agent;
Preferably, the dosage form of described preparation is cream, aqueous emulsion, aqueous suspension agent, oil-suspending agent, wettable
Property powder, water dispersible granules, soluble powder or soluble granula.
10. in claim 1-8 described in insecticides described in any one or claim 9
Preparation is at preventing and treating beet armyworm, diamondback moth, Pieris rapae, Prodenia litura, lopper worm, bollworm, cigarette
One or more in Kattapillar, leaf rollers, carpocapsa pononella, leafhopper, diamond and colorado potato bug
Application.
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111972426A (en) * | 2020-08-17 | 2020-11-24 | 广东省农业科学院植物保护研究所 | Compound pesticide for preventing and treating drug-resistant spodoptera frugiperda and preparation method thereof |
CN115211435A (en) * | 2021-09-13 | 2022-10-21 | 山东统防生物科技有限公司 | Efficient plant insect-resistant composition and preparation method thereof |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1992011249A1 (en) * | 1990-12-21 | 1992-07-09 | E.I. Du Pont De Nemours And Company | Arthropodicidal carboxanilides |
CN1868278A (en) * | 1994-06-08 | 2006-11-29 | 辛根塔参与股份公司 | Synergistic compositions |
CN101485329A (en) * | 2009-02-12 | 2009-07-22 | 深圳诺普信农化股份有限公司 | Agricultural chemical composition for disinsection and use thereof |
CN102379282A (en) * | 2011-09-13 | 2012-03-21 | 广西田园生化股份有限公司 | Ultralow volume liquid containing benzoylurea insecticide |
EP2476313A1 (en) * | 2011-01-14 | 2012-07-18 | Basf Se | Synergistic pesticidal compositions comprising a dithiocarbamate and an insecticide |
-
2016
- 2016-03-31 CN CN201610196464.3A patent/CN105707107A/en active Pending
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1992011249A1 (en) * | 1990-12-21 | 1992-07-09 | E.I. Du Pont De Nemours And Company | Arthropodicidal carboxanilides |
CN1868278A (en) * | 1994-06-08 | 2006-11-29 | 辛根塔参与股份公司 | Synergistic compositions |
CN101209047A (en) * | 1994-06-08 | 2008-07-02 | 辛根塔参与股份公司 | Synergistic compositions |
CN101485329A (en) * | 2009-02-12 | 2009-07-22 | 深圳诺普信农化股份有限公司 | Agricultural chemical composition for disinsection and use thereof |
EP2476313A1 (en) * | 2011-01-14 | 2012-07-18 | Basf Se | Synergistic pesticidal compositions comprising a dithiocarbamate and an insecticide |
CN102379282A (en) * | 2011-09-13 | 2012-03-21 | 广西田园生化股份有限公司 | Ultralow volume liquid containing benzoylurea insecticide |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111972426A (en) * | 2020-08-17 | 2020-11-24 | 广东省农业科学院植物保护研究所 | Compound pesticide for preventing and treating drug-resistant spodoptera frugiperda and preparation method thereof |
CN115211435A (en) * | 2021-09-13 | 2022-10-21 | 山东统防生物科技有限公司 | Efficient plant insect-resistant composition and preparation method thereof |
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