CN106605657A - Pesticide combination containing SYP-9625 - Google Patents
Pesticide combination containing SYP-9625 Download PDFInfo
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- CN106605657A CN106605657A CN201510697783.8A CN201510697783A CN106605657A CN 106605657 A CN106605657 A CN 106605657A CN 201510697783 A CN201510697783 A CN 201510697783A CN 106605657 A CN106605657 A CN 106605657A
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- Prior art keywords
- azoles
- demodicid mite
- nitrile
- weight ratio
- jing
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/36—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/42—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing within the same carbon skeleton a carboxylic group or a thio analogue, or a derivative thereof, and a carbon atom having only two bonds to hetero atoms with at the most one bond to halogen, e.g. keto-carboxylic acids
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
- A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
- A01N43/06—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings
- A01N43/12—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings condensed with a carbocyclic ring
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/54—1,3-Diazines; Hydrogenated 1,3-diazines
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/713—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with four or more nitrogen atoms as the only ring hetero atoms
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/74—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,3
- A01N43/76—1,3-Oxazoles; Hydrogenated 1,3-oxazoles
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
- A01N47/38—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the group >N—CO—N< where at least one nitrogen atom is part of a heterocyclic ring; Thio analogues thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N55/00—Biocides, pest repellants or attractants, or plant growth regulators, containing organic compounds containing elements other than carbon, hydrogen, halogen, oxygen, nitrogen and sulfur
- A01N55/02—Biocides, pest repellants or attractants, or plant growth regulators, containing organic compounds containing elements other than carbon, hydrogen, halogen, oxygen, nitrogen and sulfur containing metal atoms
- A01N55/04—Tin
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Abstract
The invention discloses a pesticide combination containing SYP-9625. The effective active ingredients include the active ingredient A and the active ingredient B, wherein the active ingredient A is the SYP-9625, the active ingredient B is one of the following compounds including hexythiazox, spirodiclofen, clofentezine, fenbutatin oxide, etoxazole, bromopropylate, flutenzine, cyflumetofen, fluacrypyrim and pyriminostrobin, and the weight ratio of the active ingredient A to the active ingredient B is 1:80-80:1. The combination has the synergistic effect to various pests endangering agricultural production, the quantity of pesticides is reduced, pesticide residues on plants are reduced, pollution to the environment is relieved, the combination is safe to human beings and livestock and has good environmental compatibility, and pests are not liable to have drug resistance.
Description
Technical field
The invention belongs to technical field of pesticide, is related to a kind of composition pesticide of the demodicid mite of azoles containing second nitrile and exists
Application on crop pests.
Background technology
Second azoles demodicid mite nitrile is Shenyang Sciencreat Chemicals Co., Ltd.'s product, and apple tree red spider is had
Good preventive effect, after medicine, 7d preventive effects are 82.17%～100%, and quick-acting is preferable, holding effect
Phase 14d or so, recommends to start dispenser in red spider generation Sheng phase beginning.
Hexythiazox, Envidor, clofentezine, fenbutatin oxide, etoxazole, fenisobromolate, flufenzine,
Cyflumetofen, fluacrypyrim, pyriminostrobin belong to conventional insecticide, are widely used in preventing and treating
Insect pest on crops, prevention effect are preferable.
But in the real process of agricultural production, pest control is easiest to generate the problem that
The generation of pest resistance to insecticide.Different cultivars composition is compounded, and is that preventing and treating resistant insect is very normal
The method seen.Heterogeneity is compounded, and according to practical application effect, judges that certain is multiple
Be potentiation, plus and or antagonism.In most cases, the compounding effect of pesticide
All it is additive effect, really has the compounding of potentiation seldom, especially potentiation is very
Substantially, the very high compounding of co-toxicity coefficient is just less.Study through inventor, find second
Azoles demodicid mite nitrile and Hexythiazox, Envidor, clofentezine, fenbutatin oxide, etoxazole, fenisobromolate, fluorine demodicid mite
Good potentiation can be produced after piperazine, cyflumetofen, fluacrypyrim, pyriminostrobin compounding, and
With regard to second azoles demodicid mite nitrile and Hexythiazox, Envidor, clofentezine, fenbutatin oxide, etoxazole, fenisobromolate,
Flufenzine, cyflumetofen, fluacrypyrim, the relevant report of pyriminostrobin compounding are not yet disclosed.
The content of the invention
Have that synergistic function, use cost be low, preventive effect the purpose of the present invention is to propose to a kind of
The composition pesticide of the good demodicid mite nitrile of azoles containing second.
The composition pesticide of the demodicid mite of azoles containing second nitrile proposed by the present invention by active components A with activity into
Divide B compositions, active components A is 1 ︰, 80～80 ︰ 1 with active component B weight ratio, described
Active components A be second azoles demodicid mite nitrile, active component B be selected from Hexythiazox, Envidor, four demodicid mites
Piperazine, fenbutatin oxide, etoxazole, fenisobromolate, flufenzine, cyflumetofen, fluacrypyrim, pyriminostrobin
One of plant, active components A and the preferred weight ratios of active component B are 1 ︰, 40～40 ︰ 1；
More preferably the weight ratio of second azoles demodicid mite nitrile and Hexythiazox is 20:1～1:20, second azoles demodicid mite nitrile and spiral shell demodicid mite
The weight ratio of ester is 20:1～1:20, the weight ratio of second azoles demodicid mite nitrile and clofentezine is 20:1～1:20,
The weight ratio of second azoles demodicid mite nitrile and fenbutatin oxide is 15:1～1:25, the weight of second azoles demodicid mite nitrile and etoxazole
Than for 20:1～1:20, the weight ratio of second azoles demodicid mite nitrile and fenisobromolate is 15:1～1:25, second azoles demodicid mite nitrile
Weight ratio with flufenzine is 20:1～1:20, the weight ratio of second azoles demodicid mite nitrile and cyflumetofen is
20:1～1:20, the weight ratio of second azoles demodicid mite nitrile and fluacrypyrim is 20:1～1:20, second azoles demodicid mite nitrile and phonetic
The weight ratio of demodicid mite amine is 20:1～1:20.
The composition pesticide of the demodicid mite of azoles containing second nitrile proposed by the present invention is used to prevent and treat insect on crops
Purposes, described crops include cereal crops, legume crop, fibre crops, sugar material make
Thing, melon crop, fruits crop, dry fruit crop, hobby crop, root crop,
Oil crop, flower crop, medicinal crop, crop, green manure pasture crop；Described
Insect is red spider, Panonychus citri, tetranychid, blister mite, pear sucker, oystershell scale or leaf
Cicadae.
Active components A, the weight ratio of active component B are 1 ︰, 80～80 ︰ 1.Usual compositionss
The weight percentage of middle active component for gross weight 0.5%～90%, preferably 5%～
80%.According to different preparation types, active component content scope is different.Generally, liquid
Body preparation contains by weight 1%～70% active substance, and preferably 5%～50%；Gu
Body preparation contains by weight 5%～80% active substance, and preferably 10%～80%.
At least contain a kind of surfactant in the Pesticidal combination of the present invention, when being beneficial to administration
Dispersion of the active component in water.Surface-active contents for total formulation weight 5%～30%,
Balance of solid or liquid diluent.
The Pesticidal combination of the present invention can be being diluted using front Jing or directly used by user.
Which is prepared and can be prepared by common processing method known in those skilled in the art, will activity
After material is mixed with liquid flux or solid carrier, surfactant such as dispersant, steady is added
Determine one or more in agent, wetting agent, binding agent, defoamer, disintegrating agent, antifreeze etc..
The Pesticidal combination of the present invention, can be processed into acceptable dose on any pesticide on demand
Type, wherein more preferably dosage form be wettable powder, water dispersible granules, suspending agent, suspension emulsion,
Aqueous emulsion, microemulsion, microcapsule suspending agent, microcapsule suspension-suspendinagent agent, can also make effervescent
Tablet, seed coat agent, ultra-low-volume formulation, water preparation, soluble liquid, soluble powder, hot mist
Agent.
Compositionss include following constituent content when making wettable powder：Active components A 0.1%～
80%th, active component B0.1%～80 dispersant 2%～10%, wetting agent 2%～10%, filler
Surplus.
Compositionss include following constituent content when making water dispersible granules：Active components A 0.1%～
80%th, active component B0.1%～80 dispersant 3%～12%, wetting agent 1%～8%, disintegrating agent
1%～10%, binding agent 0～8%, filler surplus.
Compositionss include following constituent content when making suspending agent：Active components A 0.1%～50%,
Active component B0.1%～50%, dispersant 2%～10%, wetting agent 2%～10%, defoamer
0.01%～2%, thickening agent 0～2%, antifreeze 0～8%, deionized water add to 100%.
Compositionss include following constituent content when making suspension emulsion：Active components A 0.1%～50%,
Active component B0.1%～50%, dispersant 2%～10%, defoamer 0.01%～2%, solvent
1%～15%, thickening agent 0～2%, emulsifying agent 2%～12%, antifreeze 0～8%, deionized water
Add to 100%.
Compositionss include following constituent content when making aqueous emulsion：Active components A 0.1%～50%,
Active component B0.1%～50%, solvent 1%～30%, emulsifying agent 1%～15%, antifreeze 0～8%,
Thickening agent 0～2%, defoamer 0.01%～2%, deionized water supply surplus.
Compositionss include following constituent content when making microcapsule suspending agent：Active components A
0.1%～50%, active component B0.1%～50%, macromolecule cyst material 2%～10%, dispersion
Agent 1%～10%, organic solvent 1%～10%, defoamer 0.01%～2%, emulsifying agent 1%～7%,
PH adjusting agent 0.01%～5%, deionized water adds to 100%.
Compositionss include following constituent content when making microcapsule suspension-suspendinagent agent：Active components A
0.1%～50%, active component B0.1%～50%, macromolecule cyst material 2%～10%, dispersion
Agent 1%～12%, wetting agent 1%～8%, organic solvent 1%～15%, emulsifying agent 1%～6%,
Defoamer 0.01%～2%, thickening agent 0～2%, pH adjusting agent 0.01%～5%, deionized water
Add to 100%.
The wettable powder the key technical indexes of the present invention：
The water dispersible granules the key technical indexes of the present invention：
The suspending agent the key technical indexes of the present invention：
The suspension emulsion the key technical indexes of the present invention：
The aqueous emulsion the key technical indexes of the present invention：
The microcapsule suspending agent the key technical indexes of the present invention：
The microcapsule suspension-suspendinagent agent the key technical indexes of the present invention：
It is an advantage of the current invention that：
(1) second azoles demodicid mite nitrile and red spider, Panonychus citri, tetranychid, blister mite, pear sucker, elm oyster
After armored scale or leafhopper compounding, with obvious potentiation and lasting effect；(2) to cereal crops,
Legume crop, fibre crops, sugar crop, melon crop, fruits crop, dry fruit are made
Thing, hobby crop, root crop, oil crop, flower crop, medicinal crop, raw material
Crop, green manure pasture crop insect have greater activity；(3) pesticide usage amount is reduced, is dropped
Low residual quantity of the pesticide on crop, alleviates environmental pollution；(4) to person poultry safety, ring
The border compatibility is good；And preparation adhesion strength strengthens, resistance of rainwater washing against.
Specific embodiment
With reference to embodiment to further instruction of the present invention, the percentage ratio in embodiment is
Percentage by weight, but the invention is not limited in this.
Application Example one
1～13 wettable powder of embodiment
Second azoles demodicid mite nitrile, active component B, dispersant, wetting agent, filler are mixed in mixed cylinder
Close uniform, remix Jing after jet mill is crushed uniform, you can be obtained it is of the present invention can
WP product, is specifically shown in Table 1.
1 embodiment of table, 1～13 each component and weight portion
14～26 water dispersible granules of embodiment
By second azoles demodicid mite nitrile, active component B, dispersant, wetting agent, disintegrating agent, filler etc.
Play the particle diameter that Jing comminution by gas stream obtains needing, add binding agent (can plus can be not added with) etc. other
Auxiliary agent, obtains materials of pelletizing.Item is quantitatively sent in fluidized bed granulating dryer through granulation
And after being dried, you can water dispersible granules product of the present invention is obtained, 2 are specifically shown in Table.
2 embodiment of table, 14～26 each component and weight portion
27～39 suspending agent of embodiment
By dispersant, wetting agent, defoamer, thickening agent (can plus can be not added with), antifreeze (can
Plus can be not added with), through high speed shear mix homogeneously, second azoles demodicid mite nitrile, active component B are added,
Ball milling 2～3 hours in ball mill, make diameter of particle all below 5 μm, and surplus spends
Ionized water is supplied, you can suspending agent product of the present invention is obtained, 3 are specifically shown in Table.
3 embodiment of table, 27～39 each component and weight portion
40～42 suspension emulsion of embodiment
By dispersant, defoamer, thickening agent (can plus can be not added with), antifreeze (can plus can
It is not added with) through high speed shear mix homogeneously, add active component B, the ball milling in ball mill
2～3 hours, make diameter of particle all below 5 μm, active component B suspending agents are obtained, so
Afterwards by second azoles demodicid mite nitrile, solvent (can plus can be not added with), emulsifying agent and various auxiliary agent high-speed stirrings
The direct emulsifying of device is mixed in suspending agent, surplus deionized water is supplied, be obtained of the present invention
Suspension emulsion product, be specifically shown in Table 4.
4 embodiment of table, 40～42 each component and weight portion
43～45 aqueous emulsion of embodiment
Second azoles demodicid mite nitrile, active component B, solvent, emulsifying agent are added together, make to be dissolved into
Even oil phase；By deionized water, antifreeze (can plus can be not added with), thickening agent (can plus can be not added with),
Defoamer is mixed, into homogeneous water phase.Under high velocity agitation, water is added to into oil phase,
Surplus deionized water is supplied；Aqueous emulsion product of the present invention is can be prepared by, is specifically shown in Table
5。
5 embodiment of table, 43～45 each component and weight portion
Hexythiazox, Envidor, clofentezine in table 3～5 are exchanged or fenbutatin oxide, second is replaced with
Demodicid mite azoles, fenisobromolate, flufenzine, cyflumetofen, fluacrypyrim, pyriminostrobin, can be obtained novel formulation.
46～48 microemulsion of embodiment
Second azoles demodicid mite nitrile, active component B are dissolved in the homogenizer equipped with solvent, by emulsifying
Agent, antifreeze (can plus can be not added with), defoamer are added in the homogenizer equipped with above-mentioned solution,
Surplus deionized water mixes strongly and homogenizes after supplying, and finally obtains clear appearance transparent
Microemulsion product of the present invention, be specifically shown in Table 6.
6 embodiment of table, 46～48 each component and content
Embodiment 49,50 microcapsule suspending agents
By second azoles demodicid mite nitrile, active component B, macromolecule cyst material, solvent, defoamer mixing,
Make to be dissolved into homogeneous oil phase, in a shear condition, oil phase is added to containing emulsifying agent, pH
In regulator, the aqueous phase solution of dispersant, surplus deionized water is supplied, and bi-material is in oil
Water termination reacts, and forms high score ascus wall, makes well dispersed micro- of the present composition
Capsule suspending agent product, is specifically shown in Table 7.
7 embodiment 49 of table, 50 each components and weight portion
Embodiment 51,52 microcapsule suspension-suspendinagent agents
By second azoles demodicid mite nitrile, macromolecule cyst material, solvent mixing, make to be dissolved into homogeneous oil phase,
During be added in a shear condition,
Make well dispersed microcapsule suspending agent.By dispersant, wetting agent, defoamer, thickening agent (can
Plus can be not added with) through high speed shear mix homogeneously, add active component B, the ball in ball mill
Mill 2～3 hours, makes diameter of particle all below 5 μm, and suspending agent is obtained, then will be outstanding
Floating agent is added in the aqueous phase solution of micro-capsule suspension, and deionized water supplies surplus, makes this
The well dispersed microcapsule suspension-suspendinagent agent product of inventive composition, is specifically shown in Table 8.
8 embodiment 51 of table, 52 each components and weight portion
The embodiment of the present invention is the method combined using Toxicity Determination and field test.First
By Toxicity Determination, clear and definite two kinds of medicaments compound by a certain percentage after co-toxicity coefficient
(CTC), CTC ＜ 80 be antagonism, 80≤CTC≤120 be summation action, CTC
＞ 120 is potentiation, on this basis, then carries out field test.
Test method：The mother solution of each mixed agent is diluted to into five series concentrations respectively during test,
It is respectively placed in standby in beaker.Using the method that leaf is followed by worm is first soaked, will be not in contact with any medicament
Blade of the same size soak 5s in the medicinal liquid for having configured after take out, dry naturally, put
Enter in insect box, then connect for examination larva, raise under the conditions of 25 DEG C, often process 3 times
Repeat, often repeat test worm number used for 50, while setting blank, check dead in 72h
Borer population, calculates mortality rate and corrected mortality, tries to achieve virulence regression equation and calculate LC50Value.
If control mortality rate is more than 10%, it is considered as invalid test.Computing formula is as follows：
Insect corrected mortality is converted into into probit value (y), concentration for the treatment of (μ g/ml) is converted into
Logarithm value (x), draws virulence regression equation with method of least square, and thus calculates every kind of medicine
The value of agent, calculates co-toxicity coefficient CTC according to the abundant equations of Sun Yun.Computing formula it is following (with
Second azoles demodicid mite nitrile is standard agent, and its toxicity index is for 100)：
TI × the P of the theoretical toxicity index (TTI) of M=second azoles demodicid mite nitrileSecond azoles demodicid mite nitrile+Effective active into
Divide the TI × P of BEffective active composition B
In formula：Mixture of the M for different ratio
PEffective active composition BFor effective active composition B ratio shared in the composition
PSecond azoles demodicid mite nitrileFor second azoles demodicid mite nitrile ratio shared in the composition
B is selected from Hexythiazox, Envidor, clofentezine, fenbutatin oxide, etoxazole, fenisobromolate, fluorine
One of demodicid mite piperazine, cyflumetofen, fluacrypyrim, pyriminostrobin are planted.
Application Example two：
For trying insect：Cotton red spider
Test medicine is provided by Shaanxi Welch Crop Protection Co., Ltd..
EXPERIMENTAL DESIGN：Second azoles demodicid mite nitrile and Hexythiazox active compound are determined through pilot study and the two is different
Effective lethasl concentration scope of proportioning mixture.
Toxicity test result
9 second azoles demodicid mite nitrile of table compounds the toxicity test analysis of results table to cotton red spider with Hexythiazox
| Reagent agent | Proportioning | LC50(ug/mL) | Co-toxicity coefficient (CTC) |
| Second azoles demodicid mite nitrile | — | 1.75 | — |
| Hexythiazox | — | 0.71 | — |
| Second azoles Man Jing ︰ Hexythiazoxs | 80:1 | 0.91 | 188.89 |
| Second azoles Man Jing ︰ Hexythiazoxs | 60:1 | 0.89 | 192.02 |
| Second azoles Man Jing ︰ Hexythiazoxs | 40:1 | 0.84 | 201.15 |
| Second azoles Man Jing ︰ Hexythiazoxs | 20:1 | 0.73 | 224.09 |
| Second azoles Man Jing ︰ Hexythiazoxs | 10:1 | 0.65 | 237.59 |
| Second azoles Man Jing ︰ Hexythiazoxs | 4:1 | 0.55 | 246.09 |
| Second azoles Man Jing ︰ Hexythiazoxs | 2:1 | 0.45 | 261.30 |
| Second azoles Man Jing ︰ Hexythiazoxs | 1:1 | 0.39 | 259.02 |
| Second azoles Man Jing ︰ Hexythiazoxs | 1:4 | 0.33 | 244.17 |
| Second azoles Man Jing ︰ Hexythiazoxs | 1:9 | 0.32 | 235.89 |
| Second azoles Man Jing ︰ Hexythiazoxs | 1:20 | 0.32 | 228.34 |
| Second azoles Man Jing ︰ Hexythiazoxs | 1:40 | 0.35 | 205.84 |
| Second azoles Man Jing ︰ Hexythiazoxs | 1:60 | 0.36 | 199.16 |
| Second azoles Man Jing ︰ Hexythiazoxs | 1:80 | 0.37 | 193.31 |
As shown in Table 9, second azoles demodicid mite nitrile and Hexythiazox to cotton red spider proportioning in 1 ︰ 80～80
During ︰ 1, co-toxicity coefficient is all higher than 120, illustrates both mixtures in the range of 1 ︰, 80～80 ︰ 1
Potentiation is shown, when the proportioning of second azoles demodicid mite nitrile and Hexythiazox is 1：20～20：When 1,
Potentiation becomes apparent from projecting, and co-toxicity coefficient is all higher than 220.Jing applicant's test finds second
The optimum ratio of azoles demodicid mite nitrile and Hexythiazox be 20 ︰ 1,19 ︰ 1,18 ︰ 1,17 ︰ 1,16 ︰ 1,
15 ︰ 1,14 ︰ 1,13 ︰ 1,12 ︰ 1,11 ︰ 1,10 ︰ 1,9 ︰ 1,8 ︰ 1,7 ︰ 1,
6 ︰ 1,5 ︰ 1,4 ︰ 1,3 ︰ 1,2 ︰ 1,1 ︰ 1,1 ︰ 2,1 ︰ 3,1 ︰ 4,1 ︰ 5,
1 ︰ 6,1 ︰ 7,1 ︰ 8,1 ︰ 9,1 ︰ 10,1 ︰ 11,1 ︰ 12,1 ︰ 13,1 ︰ 14,1
︰ 15,1 ︰ 16,1 ︰ 17,1 ︰ 18,1 ︰ 19,1 ︰ 20, wherein when second azoles demodicid mite nitrile and thiophene
Demodicid mite ketone weight ratio is 2：When 1, co-toxicity coefficient is maximum, and potentiation is the most obvious.
Application Example three：
For trying insect：Citrus red mite
Test medicine is provided by Shaanxi Welch Crop Protection Co., Ltd..
EXPERIMENTAL DESIGN：Second azoles demodicid mite nitrile and Envidor active compound are determined through pilot study and the two is different
Effective lethasl concentration scope of proportioning mixture.
Toxicity test result
10 second azoles demodicid mite nitrile of table compounds the toxicity test analysis of results table to citrus red mite with Envidor
| Reagent agent | Proportioning | LC50(ug/mL) | Co-toxicity coefficient (CTC) |
| Second azoles demodicid mite nitrile | — | 1.84 | — |
| Envidor | — | 1.28 | — |
| Second azoles Man Jing ︰ Envidors | 80:1 | 0.98 | 186.75 |
| Second azoles Man Jing ︰ Envidors | 60:1 | 0.92 | 198.58 |
| Second azoles Man Jing ︰ Envidors | 40:1 | 0.88 | 206.88 |
| Second azoles Man Jing ︰ Envidors | 20:1 | 0.79 | 228.16 |
| Second azoles Man Jing ︰ Envidors | 9:1 | 0.75 | 235.05 |
| Second azoles Man Jing ︰ Envidors | 4:1 | 0.70 | 241.71 |
| Second azoles Man Jing ︰ Envidors | 1:1 | 0.59 | 255.89 |
| Second azoles Man Jing ︰ Envidors | 1:4 | 0.55 | 247.81 |
| Second azoles Man Jing ︰ Envidors | 1:9 | 0.56 | 235.75 |
| Second azoles Man Jing ︰ Envidors | 1:20 | 0.57 | 227.86 |
| Second azoles Man Jing ︰ Envidors | 1:40 | 0.64 | 201.50 |
| Second azoles Man Jing ︰ Envidors | 1:60 | 0.65 | 197.91 |
| Second azoles Man Jing ︰ Envidors | 1:80 | 0.69 | 186.21 |
As shown in Table 10, second azoles demodicid mite nitrile and Envidor to citrus red mite proportioning in 1 ︰ 80～80
During ︰ 1, co-toxicity coefficient is all higher than 120, illustrates both mixtures in the range of 1 ︰, 80～80 ︰ 1
Potentiation is shown, when the proportioning of second azoles demodicid mite nitrile and Envidor is 1：20～20：When 1,
Potentiation becomes apparent from projecting, and co-toxicity coefficient is all higher than 225.Jing applicant's test finds second
The optimum ratio of azoles demodicid mite nitrile and Envidor be 20 ︰ 1,19 ︰ 1,18 ︰ 1,17 ︰ 1,16 ︰ 1,
15 ︰ 1,14 ︰ 1,13 ︰ 1,12 ︰ 1,11 ︰ 1,10 ︰ 1,9 ︰ 1,8 ︰ 1,7 ︰ 1,
6 ︰ 1,5 ︰ 1,4 ︰ 1,3 ︰ 1,2 ︰ 1,1 ︰ 1,1 ︰ 2,1 ︰ 3,1 ︰ 4,1 ︰ 5,
1 ︰ 6,1 ︰ 7,1 ︰ 8,1 ︰ 9,1 ︰ 10,1 ︰ 11,1 ︰ 12,1 ︰ 13,1 ︰ 14,1
︰ 15,1 ︰ 16,1 ︰ 17,1 ︰ 18,1 ︰ 19,1 ︰ 20, wherein when second azoles demodicid mite nitrile and spiral shell
Demodicid mite ester weight ratio is 1：When 1, co-toxicity coefficient is maximum, and potentiation is the most obvious.
Application Example four：
For trying insect：European red mite
Test medicine is provided by Shaanxi Welch Crop Protection Co., Ltd..
EXPERIMENTAL DESIGN：Second azoles demodicid mite nitrile and clofentezine active compound are determined through pilot study and the two is different
Effective lethasl concentration scope of proportioning mixture.
Toxicity test result
11 second azoles demodicid mite nitrile of table compounds the toxicity test analysis of results table to European red mite with clofentezine
| Reagent agent | Proportioning | LC50(ug/mL) | Co-toxicity coefficient (CTC) |
| Second azoles demodicid mite nitrile | — | 1.78 | — |
| Clofentezine | — | 2.81 | — |
| Second azoles Man Jing ︰ clofentezines | 80:1 | 0.98 | 182.46 |
| Second azoles Man Jing ︰ clofentezines | 60:1 | 0.92 | 194.65 |
| Second azoles Man Jing ︰ clofentezines | 40:1 | 0.88 | 204.10 |
| Second azoles Man Jing ︰ clofentezines | 20:1 | 0.79 | 229.32 |
| Second azoles Man Jing ︰ clofentezines | 9:1 | 0.77 | 239.96 |
| Second azoles Man Jing ︰ clofentezines | 4:1 | 0.78 | 246.26 |
| Second azoles Man Jing ︰ clofentezines | 1:1 | 0.86 | 253.42 |
| Second azoles Man Jing ︰ clofentezines | 1:2 | 0.88 | 267.67 |
| Second azoles Man Jing ︰ clofentezines | 1:4 | 1.01 | 249.35 |
| Second azoles Man Jing ︰ clofentezines | 1:9 | 1.11 | 239.29 |
| Second azoles Man Jing ︰ clofentezines | 1:20 | 1.21 | 225.99 |
| Second azoles Man Jing ︰ clofentezines | 1:40 | 1.34 | 206.77 |
| Second azoles Man Jing ︰ clofentezines | 1:60 | 1.45 | 191.96 |
| Second azoles Man Jing ︰ clofentezines | 1:80 | 1.51 | 184.76 |
As shown in Table 11, second azoles demodicid mite nitrile and clofentezine to European red mite proportioning in 1 ︰ 80～80
During ︰ 1, co-toxicity coefficient is all higher than 120, illustrates both mixtures in the range of 1 ︰, 80～80 ︰ 1
Potentiation is shown, when the proportioning of second azoles demodicid mite nitrile and clofentezine is 1：20～20：When 1,
Potentiation becomes apparent from projecting, and co-toxicity coefficient is all higher than 225.Jing applicant's test finds second
The optimum ratio of azoles demodicid mite nitrile and clofentezine be 20 ︰ 1,19 ︰ 1,18 ︰ 1,17 ︰ 1,16 ︰ 1,
15 ︰ 1,14 ︰ 1,13 ︰ 1,12 ︰ 1,11 ︰ 1,10 ︰ 1,9 ︰ 1,8 ︰ 1,7 ︰ 1,
6 ︰ 1,5 ︰ 1,4 ︰ 1,3 ︰ 1,2 ︰ 1,1 ︰ 1,1 ︰ 2,1 ︰ 3,1 ︰ 4,1 ︰ 5,
1 ︰ 6,1 ︰ 7,1 ︰ 8,1 ︰ 9,1 ︰ 10,1 ︰ 11,1 ︰ 12,1 ︰ 13,1 ︰ 14,1
︰ 15,1 ︰ 16,1 ︰ 17,1 ︰ 18,1 ︰ 19,1 ︰ 20, wherein when second azoles demodicid mite nitrile and four
Demodicid mite piperazine weight ratio is 1：When 2, co-toxicity coefficient is maximum, and potentiation is the most obvious.
Application Example five：
For trying insect：European red mite
Test medicine is provided by Shaanxi Welch Crop Protection Co., Ltd..
EXPERIMENTAL DESIGN：Second azoles demodicid mite nitrile and fenbutatin oxide active compound are determined through pilot study and the two is different
Effective lethasl concentration scope of proportioning mixture.
Toxicity test result
12 second azoles demodicid mite nitrile of table compounds the toxicity test analysis of results table to European red mite with fenbutatin oxide
| Reagent agent | Proportioning | LC50(ug/mL) | Co-toxicity coefficient (CTC) |
| Second azoles demodicid mite nitrile | — | 1.89 | — |
| Fenbutatin oxide | — | 5.04 | — |
| Second azoles Man Jing ︰ fenbutatin oxides | 80:1 | 0.98 | 194.36 |
| Second azoles Man Jing ︰ fenbutatin oxides | 60:1 | 0.92 | 207.56 |
| Second azoles Man Jing ︰ fenbutatin oxides | 40:1 | 0.92 | 208.61 |
| Second azoles Man Jing ︰ fenbutatin oxides | 25:1 | 0.91 | 212.81 |
| Second azoles Man Jing ︰ fenbutatin oxides | 15:1 | 0.83 | 236.97 |
| Second azoles Man Jing ︰ fenbutatin oxides | 4:1 | 0.88 | 245.45 |
| Second azoles Man Jing ︰ fenbutatin oxides | 1:1 | 1.06 | 259.35 |
| Second azoles Man Jing ︰ fenbutatin oxides | 1:4 | 1.45 | 260.69 |
| Second azoles Man Jing ︰ fenbutatin oxides | 1:9 | 1.71 | 252.63 |
| Second azoles Man Jing ︰ fenbutatin oxides | 1:14 | 1.88 | 241.28 |
| Second azoles Man Jing ︰ fenbutatin oxides | 1:25 | 1.98 | 239.21 |
| Second azoles Man Jing ︰ fenbutatin oxides | 1:40 | 2.23 | 217.18 |
| Second azoles Man Jing ︰ fenbutatin oxides | 1:60 | 2.41 | 203.57 |
| Second azoles Man Jing ︰ fenbutatin oxides | 1:80 | 2.54 | 194.42 |
As shown in Table 12, second azoles demodicid mite nitrile and fenbutatin oxide to European red mite proportioning in 1 ︰ 80～80
During ︰ 1, co-toxicity coefficient is all higher than 120, illustrates both mixtures in the range of 1 ︰, 80～80 ︰ 1
Potentiation is shown, when the proportioning of second azoles demodicid mite nitrile and fenbutatin oxide is 15：1～1：When 25,
Potentiation becomes apparent from projecting, and co-toxicity coefficient is all higher than 235.Jing applicant's test finds second
The optimum ratio of azoles demodicid mite nitrile and fenbutatin oxide be 15 ︰ 1,14 ︰ 1,13 ︰ 1,12 ︰ 1,11 ︰ 1,
10 ︰ 1,9 ︰ 1,8 ︰ 1,7 ︰ 1,6 ︰ 1,5 ︰ 1,4 ︰ 1,3 ︰ 1,2 ︰ 1,1 ︰ 1,
1 ︰ 2,1 ︰ 3,1 ︰ 4,1 ︰ 5,1 ︰ 6,1 ︰ 7,1 ︰ 8,1 ︰ 9,1 ︰ 10,1 ︰ 11,
1 ︰ 12,1 ︰ 13,1 ︰ 14,1 ︰ 15,1 ︰ 16,1 ︰ 17,1 ︰ 18,1 ︰ 19,1 ︰
20th, 1 ︰ 21,1 ︰ 22,1 ︰ 23,1 ︰ 24,1 ︰ 25, wherein when second azoles demodicid mite nitrile and benzene fourth
Stannum weight ratio is 1：When 4, co-toxicity coefficient is maximum, and potentiation is the most obvious.
Application Example six：
For trying insect：Citrus red mite
Test medicine is provided by Shaanxi Welch Crop Protection Co., Ltd..
EXPERIMENTAL DESIGN：Second azoles demodicid mite nitrile and etoxazole active compound are determined through pilot study and the two is different
Effective lethasl concentration scope of proportioning mixture.
Toxicity test result
13 second azoles demodicid mite nitrile of table compounds the toxicity test analysis of results table to citrus red mite with etoxazole
| Reagent agent | Proportioning | LC50(ug/mL) | Co-toxicity coefficient (CTC) |
| Second azoles demodicid mite nitrile | — | 1.74 | — |
| Etoxazole | — | 0.6 | — |
| Second azoles Man Jing ︰ etoxazoles | 80:1 | 0.91 | 186.83 |
| Second azoles Man Jing ︰ etoxazoles | 60:1 | 0.85 | 198.52 |
| Second azoles Man Jing ︰ etoxazoles | 40:1 | 0.81 | 205.30 |
| Second azoles Man Jing ︰ etoxazoles | 20:1 | 0.70 | 227.95 |
| Second azoles Man Jing ︰ etoxazoles | 9:1 | 0.61 | 239.70 |
| Second azoles Man Jing ︰ etoxazoles | 4:1 | 0.51 | 247.23 |
| Second azoles Man Jing ︰ etoxazoles | 2:1 | 0.41 | 259.83 |
| Second azoles Man Jing ︰ etoxazoles | 1:1 | 0.35 | 254.95 |
| Second azoles Man Jing ︰ etoxazoles | 1:4 | 0.28 | 246.60 |
| Second azoles Man Jing ︰ etoxazoles | 1:9 | 0.27 | 237.80 |
| Second azoles Man Jing ︰ etoxazoles | 1:20 | 0.27 | 229.38 |
| Second azoles Man Jing ︰ etoxazoles | 1:40 | 0.30 | 203.25 |
| Second azoles Man Jing ︰ etoxazoles | 1:60 | 0.31 | 195.65 |
| Second azoles Man Jing ︰ etoxazoles | 1:80 | 0.32 | 189.03 |
As shown in Table 13, second azoles demodicid mite nitrile and etoxazole to citrus red mite proportioning in 1 ︰ 80～80
During ︰ 1, co-toxicity coefficient is all higher than 120, illustrates both mixtures in the range of 1 ︰, 80～80 ︰ 1
Potentiation is shown, when the proportioning of second azoles demodicid mite nitrile and etoxazole is 20：1～1：When 20,
Potentiation becomes apparent from projecting, and co-toxicity coefficient is all higher than 225.Jing applicant's test finds second
The optimum ratio of azoles demodicid mite nitrile and etoxazole be 20 ︰ 1,19 ︰ 1,18 ︰ 1,17 ︰ 1,16 ︰ 1,
15 ︰ 1,14 ︰ 1,13 ︰ 1,12 ︰ 1,11 ︰ 1,10 ︰ 1,9 ︰ 1,8 ︰ 1,7 ︰ 1,
6 ︰ 1,5 ︰ 1,4 ︰ 1,3 ︰ 1,2 ︰ 1,1 ︰ 1,1 ︰ 2,1 ︰ 3,1 ︰ 4,1 ︰ 5,
1 ︰ 6,1 ︰ 7,1 ︰ 8,1 ︰ 9,1 ︰ 10,1 ︰ 11,1 ︰ 12,1 ︰ 13,1 ︰ 14,1
︰ 15,1 ︰ 16,1 ︰ 17,1 ︰ 18,1 ︰ 19,1 ︰ 20, wherein when second azoles demodicid mite nitrile and second
Demodicid mite azoles weight ratio is 2：When 1, co-toxicity coefficient is maximum, and potentiation is the most obvious.
Application Example seven：
For trying insect：Citrus red mite
Test medicine is provided by Shaanxi Welch Crop Protection Co., Ltd..
EXPERIMENTAL DESIGN：Second azoles demodicid mite nitrile and fenisobromolate active compound are determined through pilot study and the two is different
Effective lethasl concentration scope of proportioning mixture.
Toxicity test result
14 second azoles demodicid mite nitrile of table compounds the toxicity test analysis of results table to citrus red mite with fenisobromolate
| Reagent agent | Proportioning | LC50(ug/mL) | Co-toxicity coefficient (CTC) |
| Second azoles demodicid mite nitrile | — | 1.86 | — |
| Fenisobromolate | — | 7.5 | — |
| Second azoles Man Jing ︰ fenisobromolates | 80:1 | 1.03 | 182.27 |
| Second azoles Man Jing ︰ fenisobromolates | 60:1 | 0.98 | 192.16 |
| Second azoles Man Jing ︰ fenisobromolates | 40:1 | 0.94 | 201.57 |
| Second azoles Man Jing ︰ fenisobromolates | 25:1 | 0.91 | 210.48 |
| Second azoles Man Jing ︰ fenisobromolates | 15:1 | 0.85 | 229.62 |
| Second azoles Man Jing ︰ fenisobromolates | 4:1 | 0.92 | 237.96 |
| Second azoles Man Jing ︰ fenisobromolates | 1:1 | 1.23 | 242.34 |
| Second azoles Man Jing ︰ fenisobromolates | 1:4 | 1.81 | 257.94 |
| Second azoles Man Jing ︰ fenisobromolates | 1:6 | 1.95 | 268.37 |
| Second azoles Man Jing ︰ fenisobromolates | 1:9 | 2.31 | 249.13 |
| Second azoles Man Jing ︰ fenisobromolates | 1:14 | 2.64 | 236.32 |
| Second azoles Man Jing ︰ fenisobromolates | 1:25 | 2.97 | 226.15 |
| Second azoles Man Jing ︰ fenisobromolates | 1:40 | 3.42 | 204.20 |
| Second azoles Man Jing ︰ fenisobromolates | 1:60 | 3.61 | 197.92 |
| Second azoles Man Jing ︰ fenisobromolates | 1:80 | 3.87 | 186.81 |
As shown in Table 14, second azoles demodicid mite nitrile and fenisobromolate to citrus red mite proportioning in 1 ︰ 80～80
During ︰ 1, co-toxicity coefficient is all higher than 120, illustrates both mixtures in the range of 1 ︰, 80～80 ︰ 1
Potentiation is shown, when the proportioning of second azoles demodicid mite nitrile and fenisobromolate is 15：1～1：When 25,
Potentiation becomes apparent from projecting, and co-toxicity coefficient is all higher than 225.Jing applicant's test finds second
The optimum ratio of azoles demodicid mite nitrile and fenisobromolate be 15 ︰ 1,14 ︰ 1,13 ︰ 1,12 ︰ 1,11 ︰ 1,
10 ︰ 1,9 ︰ 1,8 ︰ 1,7 ︰ 1,6 ︰ 1,5 ︰ 1,4 ︰ 1,3 ︰ 1,2 ︰ 1,1 ︰ 1,
1 ︰ 2,1 ︰ 3,1 ︰ 4,1 ︰ 5,1 ︰ 6,1 ︰ 7,1 ︰ 8,1 ︰ 9,1 ︰ 10,1 ︰ 11,
1 ︰ 12,1 ︰ 13,1 ︰ 14,1 ︰ 15,1 ︰ 16,1 ︰ 17,1 ︰ 18,1 ︰ 19,1 ︰
20th, 1 ︰ 21,1 ︰ 22,1 ︰ 23,1 ︰ 24,1 ︰ 25, wherein when second azoles demodicid mite nitrile and bromine demodicid mite
Ester weight ratio is 1：When 6, co-toxicity coefficient is maximum, and potentiation is the most obvious.
Application Example eight：
For trying insect：Citrus red mite
Test medicine is provided by Shaanxi Welch Crop Protection Co., Ltd..
EXPERIMENTAL DESIGN：Second azoles demodicid mite nitrile and the former medicine of flufenzine are determined through pilot study and the two is different
Effective lethasl concentration scope of proportioning mixture.
Toxicity test result
15 second azoles demodicid mite nitrile of table compounds the toxicity test analysis of results table to citrus red mite with flufenzine
| Reagent agent | Proportioning | LC50(ug/mL) | Co-toxicity coefficient (CTC) |
| Second azoles demodicid mite nitrile | — | 1.75 | — |
| Flufenzine | — | 1.81 | — |
| Second azoles Man Jing ︰ flufenzines | 80:1 | 0.95 | 184.29 |
| Second azoles Man Jing ︰ flufenzines | 60:1 | 0.91 | 192.41 |
| Second azoles Man Jing ︰ flufenzines | 40:1 | 0.86 | 203.65 |
| Second azoles Man Jing ︰ flufenzines | 20:1 | 0.77 | 227.63 |
| Second azoles Man Jing ︰ flufenzines | 9:1 | 0.76 | 231.03 |
| Second azoles Man Jing ︰ flufenzines | 4:1 | 0.71 | 248.12 |
| Second azoles Man Jing ︰ flufenzines | 1:1 | 0.69 | 257.89 |
| Second azoles Man Jing ︰ flufenzines | 2:3 | 0.67 | 266.49 |
| Second azoles Man Jing ︰ flufenzines | 1:4 | 0.73 | 246.25 |
| Second azoles Man Jing ︰ flufenzines | 1:9 | 0.78 | 231.25 |
| Second azoles Man Jing ︰ flufenzines | 1:20 | 0.79 | 228.73 |
| Second azoles Man Jing ︰ flufenzines | 1:40 | 0.89 | 203.19 |
| Second azoles Man Jing ︰ flufenzines | 1:60 | 0.91 | 198.78 |
| Second azoles Man Jing ︰ flufenzines | 1:80 | 0.95 | 190.44 |
As shown in Table 15, second azoles demodicid mite nitrile and flufenzine to citrus red mite proportioning in 1 ︰ 80～80
During ︰ 1, co-toxicity coefficient is all higher than 120, illustrates both mixtures in the range of 1 ︰, 80～80 ︰ 1
Potentiation is shown, when the proportioning of second azoles demodicid mite nitrile and flufenzine is 20：1～1：When 20,
Potentiation becomes apparent from projecting, and co-toxicity coefficient is all higher than 225.Jing applicant's test finds second
The optimum ratio of azoles demodicid mite nitrile and flufenzine be 20 ︰ 1,19 ︰ 1,18 ︰ 1,17 ︰ 1,16 ︰ 1,
15 ︰ 1,14 ︰ 1,13 ︰ 1,12 ︰ 1,11 ︰ 1,10 ︰ 1,9 ︰ 1,8 ︰ 1,7 ︰ 1,
6 ︰ 1,5 ︰ 1,4 ︰ 1,3 ︰ 1,2 ︰ 1,1 ︰ 1,1 ︰ 2,1 ︰ 3,1 ︰ 4,1 ︰ 5,
1 ︰ 6,1 ︰ 7,1 ︰ 8,1 ︰ 9,1 ︰ 10,1 ︰ 11,1 ︰ 12,1 ︰ 13,1 ︰ 14,1
︰ 15,1 ︰ 16,1 ︰ 17,1 ︰ 18,1 ︰ 19,1 ︰ 20, wherein when second azoles demodicid mite nitrile and fluorine
Demodicid mite piperazine weight ratio is 2：When 3, co-toxicity coefficient is maximum, and potentiation is the most obvious.
Application Example nine：
For trying insect：Cotton red spider
Test medicine is provided by Shaanxi Welch Crop Protection Co., Ltd..
EXPERIMENTAL DESIGN：Through pilot study determine second azoles demodicid mite nitrile and cyflumetofen active compound and the two not
With effective lethasl concentration scope of proportioning mixture.
Toxicity test result
16 second azoles demodicid mite nitrile of table compounds the toxicity test analysis of results table to cotton red spider with cyflumetofen
| Reagent agent | Proportioning | LC50(ug/mL) | Co-toxicity coefficient (CTC) |
| Second azoles demodicid mite nitrile | — | 1.87 | — |
| Cyflumetofen | — | 2.63 | — |
| Second azoles Man Jing ︰ cyflumetofens | 80:1 | 0.95 | 197.55 |
| Second azoles Man Jing ︰ cyflumetofens | 60:1 | 0.91 | 206.47 |
| Second azoles Man Jing ︰ cyflumetofens | 40:1 | 0.86 | 218.99 |
| Second azoles Man Jing ︰ cyflumetofens | 20:1 | 0.81 | 234.09 |
| Second azoles Man Jing ︰ cyflumetofens | 9:1 | 0.78 | 246.88 |
| Second azoles Man Jing ︰ cyflumetofens | 4:1 | 0.78 | 254.45 |
| Second azoles Man Jing ︰ cyflumetofens | 1:1 | 0.81 | 269.86 |
| Second azoles Man Jing ︰ cyflumetofens | 1:2 | 0.83 | 279.07 |
| Second azoles Man Jing ︰ cyflumetofens | 1:4 | 0.95 | 256.04 |
| Second azoles Man Jing ︰ cyflumetofens | 1:9 | 1.03 | 245.38 |
| Second azoles Man Jing ︰ cyflumetofens | 1:20 | 1.11 | 232.45 |
| Second azoles Man Jing ︰ cyflumetofens | 1:40 | 1.21 | 215.23 |
| Second azoles Man Jing ︰ cyflumetofens | 1:60 | 1.28 | 204.12 |
| Second azoles Man Jing ︰ cyflumetofens | 1:80 | 1.31 | 199.77 |
As shown in Table 16, second azoles demodicid mite nitrile and cyflumetofen to cotton red spider proportioning in 1 ︰
During 80～80 ︰ 1, co-toxicity coefficient is all higher than 120, illustrates both in the range of 1 ︰, 80～80 ︰ 1
Mixture shows potentiation, when the proportioning of second azoles demodicid mite nitrile and cyflumetofen is 20：1～1：
When 20, potentiation becomes apparent from projecting, and co-toxicity coefficient is all higher than 230.Jing applicant tests
It was found that second azoles demodicid mite nitrile is 20 ︰ 1,19 ︰ 1,18 ︰ 1,17 ︰ with the optimum ratio of cyflumetofen
1st, 16 ︰ 1,15 ︰ 1,14 ︰ 1,13 ︰ 1,12 ︰ 1,11 ︰ 1,10 ︰ 1,9 ︰ 1,8
︰ 1,7 ︰ 1,6 ︰ 1,5 ︰ 1,4 ︰ 1,3 ︰ 1,2 ︰ 1,1 ︰ 1,1 ︰ 2,1 ︰ 3,1
︰ 4,1 ︰ 5,1 ︰ 6,1 ︰ 7,1 ︰ 8,1 ︰ 9,1 ︰ 10,1 ︰ 11,1 ︰ 12,1 ︰
13rd, 1 ︰ 14,1 ︰ 15,1 ︰ 16,1 ︰ 17,1 ︰ 18,1 ︰ 19,1 ︰ 20, wherein when
Second azoles demodicid mite nitrile is 1 with cyflumetofen weight ratio：When 2, co-toxicity coefficient is maximum, and potentiation is the most
Substantially.
Application Example ten：
For trying insect：European red mite
Test medicine is provided by Shaanxi Welch Crop Protection Co., Ltd..
EXPERIMENTAL DESIGN：Second azoles demodicid mite nitrile and fluacrypyrim active compound are determined through pilot study and the two is different
Effective lethasl concentration scope of proportioning mixture.
Toxicity test result
17 second azoles demodicid mite nitrile of table compounds the toxicity test analysis of results table to European red mite with fluacrypyrim
| Reagent agent | Proportioning | LC50(ug/mL) | Co-toxicity coefficient (CTC) |
| Second azoles demodicid mite nitrile | — | 1.78 | — |
| Fluacrypyrim | — | 1.31 | — |
| Second azoles Man Jing ︰ fluacrypyrims | 80:1 | 0.95 | 186.54 |
| Second azoles Man Jing ︰ fluacrypyrims | 60:1 | 0.91 | 194.46 |
| Second azoles Man Jing ︰ fluacrypyrims | 40:1 | 0.86 | 205.18 |
| Second azoles Man Jing ︰ fluacrypyrims | 20:1 | 0.78 | 224.37 |
| Second azoles Man Jing ︰ fluacrypyrims | 9:1 | 0.74 | 232.21 |
| Second azoles Man Jing ︰ fluacrypyrims | 4:1 | 0.68 | 244.24 |
| Second azoles Man Jing ︰ fluacrypyrims | 1:1 | 0.59 | 255.80 |
| Second azoles Man Jing ︰ fluacrypyrims | 1:4 | 0.56 | 246.97 |
| Second azoles Man Jing ︰ fluacrypyrims | 1:9 | 0.58 | 231.98 |
| Second azoles Man Jing ︰ fluacrypyrims | 1:20 | 0.59 | 224.86 |
| Second azoles Man Jing ︰ fluacrypyrims | 1:40 | 0.65 | 202.84 |
| Second azoles Man Jing ︰ fluacrypyrims | 1:60 | 0.68 | 193.48 |
| Second azoles Man Jing ︰ fluacrypyrims | 1:80 | 0.71 | 185.11 |
As shown in Table 17, second azoles demodicid mite nitrile and fluacrypyrim to European red mite proportioning in 1 ︰ 80～80
During ︰ 1, co-toxicity coefficient is all higher than 120, illustrates both mixtures in the range of 1 ︰, 80～80 ︰ 1
Potentiation is shown, when the proportioning of second azoles demodicid mite nitrile and fluacrypyrim is 20：1～1：When 20,
Potentiation becomes apparent from projecting, and co-toxicity coefficient is all higher than 220.Jing applicant's test finds second
The optimum ratio of azoles demodicid mite nitrile and fluacrypyrim be 20 ︰ 1,19 ︰ 1,18 ︰ 1,17 ︰ 1,16 ︰ 1,
15 ︰ 1,14 ︰ 1,13 ︰ 1,12 ︰ 1,11 ︰ 1,10 ︰ 1,9 ︰ 1,8 ︰ 1,7 ︰ 1,
6 ︰ 1,5 ︰ 1,4 ︰ 1,3 ︰ 1,2 ︰ 1,1 ︰ 1,1 ︰ 2,1 ︰ 3,1 ︰ 4,1 ︰ 5,
1 ︰ 6,1 ︰ 7,1 ︰ 8,1 ︰ 9,1 ︰ 10,1 ︰ 11,1 ︰ 12,1 ︰ 13,1 ︰ 14,1
︰ 15,1 ︰ 16,1 ︰ 17,1 ︰ 18,1 ︰ 19,1 ︰ 20, wherein when second azoles demodicid mite nitrile with it is phonetic
Demodicid mite ester weight ratio is 1：When 1, co-toxicity coefficient is maximum, and potentiation is the most obvious.
Application Example 11：
For trying insect：European red mite
Test medicine is provided by Shaanxi Welch Crop Protection Co., Ltd..
EXPERIMENTAL DESIGN：Second azoles demodicid mite nitrile and pyriminostrobin active compound are determined through pilot study and the two is different
Effective lethasl concentration scope of proportioning mixture.
Toxicity test result
18 second azoles demodicid mite nitrile of table compounds the toxicity test analysis of results table to European red mite with pyriminostrobin
| Reagent agent | Proportioning | LC50(ug/mL) | Co-toxicity coefficient (CTC) |
| Second azoles demodicid mite nitrile | — | 1.93 | — |
| Pyriminostrobin | — | 1.41 | — |
| Second azoles Man Jing ︰ pyriminostrobins | 80:1 | 1.05 | 182.98 |
| Second azoles Man Jing ︰ pyriminostrobins | 60:1 | 0.99 | 193.78 |
| Second azoles Man Jing ︰ pyriminostrobins | 40:1 | 0.95 | 201.35 |
| Second azoles Man Jing ︰ pyriminostrobins | 20:1 | 0.83 | 228.52 |
| Second azoles Man Jing ︰ pyriminostrobins | 9:1 | 0.78 | 238.64 |
| Second azoles Man Jing ︰ pyriminostrobins | 4:1 | 0.73 | 246.22 |
| Second azoles Man Jing ︰ pyriminostrobins | 1:1 | 0.65 | 250.69 |
| Second azoles Man Jing ︰ pyriminostrobins | 1:4 | 0.62 | 240.37 |
| Second azoles Man Jing ︰ pyriminostrobins | 1:9 | 0.63 | 230.01 |
| Second azoles Man Jing ︰ pyriminostrobins | 1:20 | 0.63 | 226.72 |
| Second azoles Man Jing ︰ pyriminostrobins | 1:40 | 0.69 | 205.70 |
| Second azoles Man Jing ︰ pyriminostrobins | 1:60 | 0.71 | 199.47 |
| Second azoles Man Jing ︰ pyriminostrobins | 1:80 | 0.72 | 196.49 |
As shown in Table 18, second azoles demodicid mite nitrile and pyriminostrobin to European red mite proportioning in 1 ︰ 80～80
During ︰ 1, co-toxicity coefficient is all higher than 120, illustrates both mixtures in the range of 1 ︰, 80～80 ︰ 1
Potentiation is shown, when the proportioning of second azoles demodicid mite nitrile and pyriminostrobin is 20：1～1：When 20,
Potentiation becomes apparent from projecting, and co-toxicity coefficient is all higher than 225.Jing applicant's test finds second
The optimum ratio of azoles demodicid mite nitrile and pyriminostrobin be 20 ︰ 1,19 ︰ 1,18 ︰ 1,17 ︰ 1,16 ︰ 1,
15 ︰ 1,14 ︰ 1,13 ︰ 1,12 ︰ 1,11 ︰ 1,10 ︰ 1,9 ︰ 1,8 ︰ 1,7 ︰ 1,
6 ︰ 1,5 ︰ 1,4 ︰ 1,3 ︰ 1,2 ︰ 1,1 ︰ 1,1 ︰ 2,1 ︰ 3,1 ︰ 4,1 ︰ 5,
1 ︰ 6,1 ︰ 7,1 ︰ 8,1 ︰ 9,1 ︰ 10,1 ︰ 11,1 ︰ 12,1 ︰ 13,1 ︰ 14,1
︰ 15,1 ︰ 16,1 ︰ 17,1 ︰ 18,1 ︰ 19,1 ︰ 20, wherein when second azoles demodicid mite nitrile with it is phonetic
Demodicid mite amine weight ratio is 1：When 1, co-toxicity coefficient is maximum, and potentiation is the most obvious.
Jing tests find：To red in various crop after second azoles demodicid mite nitrile and active component B compounding
The preventing and treating of Aranea, Panonychus citri, tetranychid, blister mite, pear sucker, oystershell scale or leafhopper
There is obvious potentiation, co-toxicity coefficient is more than 120.
Effect experiment part：Test medicine is researched and developed, is carried by Shaanxi Welch Crop Protection Co., Ltd.
For, 30% second azoles demodicid mite nitrile suspending agent (autogamy) of comparison medicament, 5% Hexythiazox cream (commercial),
240g/l Envidor suspending agents (autogamy), 20% clofentezine suspension agent (commercial), 50% benzene fourth
Stannum suspending agent (commercial), 110g/L etoxazole suspending agents (autogamy), 500g/L fenisobromolates hang
Floating agent (commercial), 10% flufenzine suspending agent (autogamy), 20% cyflumetofen suspending agent are (certainly
With), 30% fluacrypyrim suspending agent (autogamy), 15% pyriminostrobin soluble concentrate (autogamy).
Ten diethyl azoles demodicid mite nitrile of Application Example and active component B and its compounding preventing and treating cotton red spider
The test of pesticide effectiveness
This test arrangement investigates cotton red spider insect pest in Shaanxi Province Weinan City Dali County, before medicine
Index, in insect pest early period of origination dispenser, 3 days after dispenser, investigates insect pest and refers to for 10 days, 20 days
Count and calculate preventive effect.Result of the test is as follows：
19 second azoles demodicid mite nitrile of table and active component B and its compounding preventing and treating cotton red spider test of pesticide effectiveness
As can be seen from Table 19, cotton can effectively be prevented and treated after second azoles demodicid mite nitrile and active component B compoundings
Premium Aranea, can also Jing after inventor's test proves second azoles demodicid mite nitrile and active component B compoundings
Cotton boll worm is prevented and treated effectively, prevention effect is above 96%, it is better than the preventive effect of single dose and anti-
The effect phase is long.Target crop is had no adverse effects in test scope of medication.
13 second azoles demodicid mite nitrile of Application Example and active component B and its compounding preventing and treating citrus red mite
The test of pesticide effectiveness
This test arrangement is investigated citrus red mite insect pest in Shaanxi Province Hanzhong suburban area, before medicine and is referred to
Number, in insect pest early period of origination dispenser, 3 days after dispenser, investigates insect pest index in 10 days, 20 days
And calculate preventive effect.Result of the test is as follows：
20 second azoles demodicid mite nitrile of table and active component B and its compounding preventing and treating citrus red mite test of pesticide effectiveness
As can be seen from Table 20, Citrus chachiensis Hort. can effectively be prevented and treated after second azoles demodicid mite nitrile and active component B compoundings
Exocarpium Citri Rubrum Aranea, can also Jing after inventor's test proves second azoles demodicid mite nitrile and active component B compoundings
Panonychus citri, blister mite, tetranychid are prevented and treated effectively, prevention effect is above 96%, better than list
The preventive effect of agent, and preventive effect phase is long.Target crop is had no adverse effects in test scope of medication.
Ten tetrem azoles demodicid mite nitrile of Application Example and active component B and its compounding preventing and treating pear tree pear sucker
The test of pesticide effectiveness
This test arrangement investigates pear tree pear sucker insect pest in Shaanxi Province Weinan City Dali County, before medicine
Index, in insect pest early period of origination dispenser, 3 days after dispenser, investigates insect pest and refers to for 10 days, 20 days
Count and calculate preventive effect.Result of the test is as follows：
21 second azoles demodicid mite nitrile of table and active component B and its compounding preventing and treating pear tree pear sucker test of pesticide effectiveness
As can be seen from Table 21, pears can effectively be prevented and treated after second azoles demodicid mite nitrile and active component B compoundings
Tree pear sucker, can also Jing after inventor's test proves second azoles demodicid mite nitrile and active component B compoundings
Pear tree red spider, oystershell scale, leafhopper are prevented and treated effectively, prevention effect is above 96%, is better than
The preventive effect of single dose, and preventive effect phase is long.Target crop is had no adverse effects in test scope of medication.
15 second azoles demodicid mite nitrile of Application Example and active component B and its compounding preventing and treating European red mite
The test of pesticide effectiveness
This test arrangement investigates European red mite insect pest in Shaanxi Province Weinan City Dali County, before medicine
Index, in insect pest early period of origination dispenser, 3 days after dispenser, investigates insect pest and refers to for 10 days, 20 days
Count and calculate preventive effect.Result of the test is as follows：
22 second azoles demodicid mite nitrile of table and active component B and its compounding preventing and treating Pesticide Effect for Apple Red Spiders
As can be seen from Table 22, Herba Marsileae Quadrifoliae can effectively be prevented and treated after second azoles demodicid mite nitrile and active component B compoundings
Arnotto Aranea, can also Jing after inventor's test proves second azoles demodicid mite nitrile and active component B compoundings
Fructus Mali pumilae oystershell scale is prevented and treated effectively, prevention effect is above 96%, better than the preventive effect of single dose, and
Preventive effect phase is long.Target crop is had no adverse effects in test scope of medication.
16 second azoles demodicid mite nitrile of Application Example and active component B and its compounding preventing and treating Citrus blister mite
The test of pesticide effectiveness
This test arrangement is investigated Citrus blister mite insect pest in Shaanxi Province Hanzhong suburban area, before medicine and is referred to
Number, in insect pest early period of origination dispenser, 3 days after dispenser, investigates insect pest index in 10 days, 20 days
And calculate preventive effect.Result of the test is as follows：
23 second azoles demodicid mite nitrile of table and active component B and its compounding preventing and treating Citrus blister mite test of pesticide effectiveness
As can be seen from Table 23, Citrus chachiensis Hort. can effectively be prevented and treated after second azoles demodicid mite nitrile and active component B compoundings
Phyllocoptruta oleivora Ahmcad, can also Jing after inventor's test proves second azoles demodicid mite nitrile and active component B compoundings
Citrus red mite, Panonychus citri, tetranychid are prevented and treated effectively, prevention effect is above 96%, better than list
The preventive effect of agent, and preventive effect phase is long.Target crop is had no adverse effects in test scope of medication.
Test through different places throughout the country afterwards draws, second azoles demodicid mite nitrile and Hexythiazox, spiral shell
Demodicid mite ester, clofentezine, fenbutatin oxide, etoxazole, fenisobromolate, flufenzine, cyflumetofen, phonetic demodicid mite
Ester, pyriminostrobin compounding after to the red spider in various crop, Panonychus citri, tetranychid, blister mite,
The preventive effect of the common insect pests such as pear sucker, oystershell scale or leafhopper more than 96%, better than list
Agent preventive effect, potentiation are obvious.
Claims (6)
1. a kind of composition pesticide of the demodicid mite of azoles containing second nitrile, effective active composition is active components A
With active component B, it is characterised in that：Active components A is 1 with the weight ratio of active component B
80～80 ︰ 1 of ︰, described active components A are second azoles demodicid mite nitrile, and active component B is selected from thiophene demodicid mite
Ketone, Envidor, clofentezine, fenbutatin oxide, etoxazole, fenisobromolate, flufenzine, cyflumetofen,
One of fluacrypyrim, pyriminostrobin are planted.
2. the composition pesticide of the demodicid mite of azoles containing second nitrile according to claim 1, its feature exist
In：Active components A is 1 ︰, 40～40 ︰ 1 with the weight ratio of active component B.
3. the composition pesticide of the demodicid mite of azoles containing second nitrile according to claim 2, its feature exist
In：
The weight ratio of second azoles demodicid mite nitrile and Hexythiazox is 20:1～1:20；
The weight ratio of second azoles demodicid mite nitrile and Envidor is 20:1～1:20；
The weight ratio of second azoles demodicid mite nitrile and clofentezine is 20:1～1:20；
The weight ratio of second azoles demodicid mite nitrile and fenbutatin oxide is 15:1～1:25；
The weight ratio of second azoles demodicid mite nitrile and etoxazole is 20:1～1:20；
The weight ratio of second azoles demodicid mite nitrile and fenisobromolate is 15:1～1:25；
The weight ratio of second azoles demodicid mite nitrile and flufenzine is 20:1～1:20；
The weight ratio of second azoles demodicid mite nitrile and cyflumetofen is 20:1～1:20；
The weight ratio of second azoles demodicid mite nitrile and fluacrypyrim is 20:1～1:20；
The weight ratio of second azoles demodicid mite nitrile and pyriminostrobin is 20:1～1:20.
4. the pesticide combination of the demodicid mite of azoles containing second nitrile according to any one of claim 1 to 3
Thing, it is characterised in that：Compositionss make wettable powder, water dispersible granules, suspending agent, outstanding
Emulsion, aqueous emulsion, microemulsion, microcapsule suspending agent or microcapsule suspension-suspendinagent agent.
5. the composition pesticide of the demodicid mite of azoles containing second nitrile according to claim 4 is used to prevent and treat agriculture
The purposes of pest on crop.
6. purposes according to claim 5, it is characterised in that：Described insect is red
Aranea, Panonychus citri, tetranychid, blister mite, pear sucker, oystershell scale or leafhopper.
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106035341A (en) * | 2016-06-27 | 2016-10-26 | 青岛润生农化有限公司 | Acaricidal compound containing ethyl cyanide and spirodiclofen |
| CN106417321A (en) * | 2016-08-23 | 2017-02-22 | 青岛东生药业有限公司 | Compound miticide as well as dose form and use thereof |
| CN106719687A (en) * | 2017-02-16 | 2017-05-31 | 佛山市瑞生通科技有限公司 | A kind of composition pesticide of the mite nitrile of azoles containing second and cyflumetofen |
| CN106937634A (en) * | 2017-03-15 | 2017-07-11 | 安徽省农业科学院植物保护与农产品质量安全研究所 | A kind of acaricide composition and its application method |
| CN108902158A (en) * | 2018-08-17 | 2018-11-30 | 沈阳中化农药化工研发有限公司 | A kind of suspending agent containing second azoles mite cyanide composition and its application |
| CN109832283A (en) * | 2017-11-29 | 2019-06-04 | 江苏龙灯化学有限公司 | A kind of miticide composition |
| CN114586796A (en) * | 2020-12-04 | 2022-06-07 | 浙江省化工研究院有限公司 | Acaricidal composition containing oxazofen |
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| CN104663670A (en) * | 2013-11-26 | 2015-06-03 | 中国中化股份有限公司 | Synergistic miticidal composition |
| CN104663704A (en) * | 2013-11-26 | 2015-06-03 | 中国中化股份有限公司 | Insecticidal and acaricidal composition containing ATP synthetase inhibitor acaricide |
| CN104663672A (en) * | 2013-11-26 | 2015-06-03 | 中国中化股份有限公司 | Pest-killing and mite-killing composition containing mite growth inhibitor mite-killing agent |
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Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN104663670A (en) * | 2013-11-26 | 2015-06-03 | 中国中化股份有限公司 | Synergistic miticidal composition |
| CN104663704A (en) * | 2013-11-26 | 2015-06-03 | 中国中化股份有限公司 | Insecticidal and acaricidal composition containing ATP synthetase inhibitor acaricide |
| CN104663672A (en) * | 2013-11-26 | 2015-06-03 | 中国中化股份有限公司 | Pest-killing and mite-killing composition containing mite growth inhibitor mite-killing agent |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106035341A (en) * | 2016-06-27 | 2016-10-26 | 青岛润生农化有限公司 | Acaricidal compound containing ethyl cyanide and spirodiclofen |
| CN106417321A (en) * | 2016-08-23 | 2017-02-22 | 青岛东生药业有限公司 | Compound miticide as well as dose form and use thereof |
| CN106719687A (en) * | 2017-02-16 | 2017-05-31 | 佛山市瑞生通科技有限公司 | A kind of composition pesticide of the mite nitrile of azoles containing second and cyflumetofen |
| CN106937634A (en) * | 2017-03-15 | 2017-07-11 | 安徽省农业科学院植物保护与农产品质量安全研究所 | A kind of acaricide composition and its application method |
| CN109832283A (en) * | 2017-11-29 | 2019-06-04 | 江苏龙灯化学有限公司 | A kind of miticide composition |
| CN108902158A (en) * | 2018-08-17 | 2018-11-30 | 沈阳中化农药化工研发有限公司 | A kind of suspending agent containing second azoles mite cyanide composition and its application |
| CN114586796A (en) * | 2020-12-04 | 2022-06-07 | 浙江省化工研究院有限公司 | Acaricidal composition containing oxazofen |
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Application publication date: 20170503 |