CN106035341A - Acaricidal compound containing ethyl cyanide and spirodiclofen - Google Patents
Acaricidal compound containing ethyl cyanide and spirodiclofen Download PDFInfo
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- CN106035341A CN106035341A CN201610479446.6A CN201610479446A CN106035341A CN 106035341 A CN106035341 A CN 106035341A CN 201610479446 A CN201610479446 A CN 201610479446A CN 106035341 A CN106035341 A CN 106035341A
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- Prior art keywords
- envidor
- demodicid mite
- agent
- azoles demodicid
- nitrile
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Classifications
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
- A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
- A01N43/06—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings
- A01N43/12—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings condensed with a carbocyclic ring
Abstract
The invention belongs to the field of a pesticide acaricide and especially relates to an acaricidal compound containing ethyl cyanide and spirodiclofen. The weight ratio of ethyl cyanide to spirodiclofen is (50:1)-(1:50) and preferably is (10:1)-(1:10). The compound also contains a surface active agent and a functional accessory ingredient; the compound can be prepared into a suspending agent and water dispersible granules; and the weight of the active ingredient formed by ethyl cyanide and spirodiclofen is 10%-80% of the total weight. The effective compounding of ethyl cyanide and spirodiclofen can expand the acaricidal scope, reinforce the adaptability, prolong the lasting period, promote the pesticide effect and delay the generation of drug resistance; the acaricidal compound can be used as the acaricide in the growing period of plants, can be used for killing various mites on other crops, such as rice, apples, vegetables and fruit trees, and especially has an obvious effect on killing red spiders in the fruit trees; and the compound product has the advantages that the pesticide dosage is reduced, the residual quantity of pesticides on the crops is reduced and the environmental pollution is relieved.
Description
Technical field
The present invention relates to agricultural acaricides field, relate in particular to the combination of a kind of mite killing containing second azoles demodicid mite nitrile and Envidor
Thing.
Background technology
Second azoles demodicid mite nitrile is novel acaricide.Shenyang Sciencreat Chemicals Co., Ltd. develops 30% second azoles demodicid mite nitrile suspending agent and produces
Product, are 22.5～45g a.i./hm in effective ingredient consumption2In the case of the preventive effect of European red mite is reached more than 98%,
This pesticide visible prevention effect on preventing and treating mite pest is notable, has good application prospect.Its mechanism of action is with anti-at present
Controlling spectrum etc. and be still in conceptual phase, after the indices such as physicochemical property and safety index improves, said preparation has the biggest development
Leeway.
Envidor is broad spectrum acaricides, has the brand-new mechanism of action, has action of contace poison, does not has interior absorption.Main suppression
The lipogenesis of demodicid mite, block demodicid mite energy metabolism, if to evil demodicid mite ovum, children demodicid mite demodicid mite there is good fragmentation effect, to become demodicid mite without
Effect, but there is the effect suppressing female demodicid mite spawning and hatching rate.
Defect in various degree is often there is in the acaricide kind containing single-activity component on agricultural acaricides is prevented and treated,
Such as mite killing narrow range, if the most individually to demodicid mite, becoming demodicid mite to have effect, invalid to ovum or invalid to becoming demodicid mite, prevention effect is poor, dispenser agent
Amount is easily generated greatly Drug resistance, and application times increases the weight of environmental pollution etc. more.Preventing and treating agriculturally being produced to the demodicid mite class of resistance, one is done
Method is to release the new new component with existing kind no interactions resistance.But, the development cost of new effective ingredient is high, exploitation week
Phase is long, and does not forever all catch up with harmful demodicid mite and produce the speed of resistance.Other way such as crop structure adjustment, different pesticide wheel
Change, during practical operation, be difficult to really play obvious effect.
Different cultivars composition compounds, and is the preventing and treating modal method of resistant mite class.Heterogeneity compounds, permissible
Improve prevention effect, expanding prevention scope, reduce the consumption of effective ingredient, save drug cost, reduce environmental pollution, be comprehensive
The important means of preventing and treating mite pest.Do not find the document that second azoles demodicid mite nitrile is compounding with Envidor and applies at present.
Summary of the invention
The present invention is directed to deficiency of the prior art, it is provided that a kind of acaricidal activity is efficient, lasting period length, quick-acting are high and low
Poison, the miticide composition of environmental protection.Being specifically related to second azoles demodicid mite nitrile with Envidor is the miticide composition of effective ingredient.
Another object of the present invention is to utilize above-mentioned miticide composition, is equipped with known to a person skilled in the art helping
Agent, can make the dosage form of the present invention with method known to a person skilled in the art.Its machinable dosage form is suspending agent, water
Dispersible granule.
The technical scheme is that a kind of compound acaricide, its effective ingredient is second azoles demodicid mite nitrile and Envidor.Described have
Effect composition second azoles demodicid mite nitrile is 50:1～1:50, preferably 1:10～10:1 with the weight ratio of Envidor.Described effective ingredient second azoles demodicid mite
Nitrile and Envidor weight percentage in described compound acaricide are 10%～80%.
Above-mentioned effective ingredient second azoles demodicid mite nitrile and Envidor are all acaricides well known in the art, can be by various business canals
Road is buied.
In addition to above-mentioned effective ingredient second azoles demodicid mite nitrile with Envidor, described acaricide composition also includes carrier and auxiliary agent,
To be configured to water dispersible granules and suspending agent.
Described filler is in Kaolin, kieselguhr, bentonite, attapulgite, white carbon, starch or precipitated calcium carbonate
The mixture of one or more compositions.
Described auxiliary agent at least includes a kind of surfactant.Surfactant can be emulsifying agent, dispersant, wetting agent or
One or more in penetrating agent, can be nonionic or anionic, it is also possible to be two types compound use.
Described emulsifying agent selected from OP series phosphate ester (thermally coupled distillation columns), 600#Phosphate ester (phenyl phenol
Polyoxyethylene ether phosphate), styrene polyoxyethylene ether ammonium sulfate salt, alkyl biphenyl ether disulfonic acid magnesium salt, triethanolamine salt, agriculture
Breast 400#(benzyl dimethyl phenol polyoxyethyl ether), Nongru-700#(alkylphenol-formaldehyde resin polyoxyethyl ether), peaceful breast 36#(benzene second
Base fluosite polyoxyethyl ether), agriculture breast 1600#(phenethyl phenol polyoxyethanyl polypropylene-base ether), oxirane-epoxy
Propane block copolymer, OP series (NPE), BY series (castor oil polyoxyethylene ether), agriculture breast 33#(alkyl
Aryl polyoxyethylene poly-oxygen propylene aether), Span series (sorbitol anhydride monostearate), TWEEN Series (anhydrous sorbitol fat acid ester
Polyoxyethylene ether) or AEO series (fatty alcohol-polyoxyethylene ether) in one or more composition mixture.
Described dispersant selected from polycarboxylate, lignosulfonates, alkylphenol polyoxyethylene formaldehyde condensation products sulfate,
Alkyl benzene calcium sulfonate, naphthalene sulfonic acid-formaldehyde condensation product sodium salt, alkylphenol polyoxyethylene, aliphatic amine polyoxyethylene ether, fatty acid polyglycol
The mixture of one or more compositions in oxygen vinyl Ether or fatty acid glyceride polyoxyethylene ether.
Described wetting agent is selected from sodium lauryl sulphate, dodecylbenzene sodium sulfonate, Nekal BX, wetting and penetrating agent F, soap
The mixture of one or more compositions in angle powder, Bombyx mori L. or Fructus Sapindi Mukouossi powder.
Described penetrating agent is selected from penetrating agent JFC (fatty alcohol-polyoxyethylene ether), penetrant t (diisooctyl maleate
Sulfonate), azone, mixture of one or more compositions in organosilicon.
According to different use occasions and demand, described compound acaricide also can add antifreezing agent, thickening agent, stabilizer,
Other functional aids such as disintegrating agent, defoamer.
Described thickening agent is selected from gelatin, sodium carboxymethyl cellulose, hydroxyethyl cellulose, sodium polyacrylate, modified starch, Huang
The mixture of one or more compositions in virgin rubber, bentonite, silicon dioxide and Magnesiumaluminumsilicate.
The mixture of the described antifreezing agent one or more compositions in ethylene glycol, propylene glycol, glycerol or carbamide.
Described defoamer is selected from silicone oil, silicone compound, C10～C20Saturated fat acid compounds or C8～C10Fat
The mixture of one or more compositions in alcohol compound.
Described disintegrating agent is selected from bentonite, carbamide, ammonium sulfate, aluminum chloride, low-substituted hydroxypropyl cellulose, lactose, Fructus Citri Limoniae
The mixture of one or more compositions in acid, succinic acid or sodium bicarbonate.
Described stabilizer is selected from epoxy soybean oil, epoxychloropropane, BHT, ethyl acetate, the one or many of triphenyl phosphate
Plant the mixture of composition.
Material described above is all to well known to a person skilled in the art material, can be commercially available.
The beneficial effects of the present invention is: 1. mite killing scope is wide；2. the lasting period is long；3. low toxicity, noresidue, nuisanceless, right
Environmental security；4. use compound formulation, two kinds of acaricidal consumptions all than single use time reduce, thus improve mite killing effect
Really, add safety, decrease environmental pollution.
Detailed description of the invention
Technical scheme in the embodiment of the present invention will be clearly and completely described below, it is clear that described enforcement
Example is only a part of embodiment of the present invention rather than whole embodiments.Based on the embodiment in the present invention, this area is common
The every other embodiment that technical staff is obtained under not making creative work premise, broadly falls into the model of present invention protection
Enclose.
Embodiments providing a kind of miticide composition, its effective ingredient is second azoles demodicid mite nitrile and Envidor, second azoles demodicid mite
Nitrile is 50:1～1:50, preferably 1:10～10:1 with the weight ratio of Envidor.
In the present embodiment, in order to ensure good insecticidal effect and the synergistic effect of complex insecticidal composition, preferably
The weight ratio of second azoles demodicid mite nitrile and Envidor be: 50:1,10:1,5:1,1:1,1:3,1:4,1:5,1:10,1:50.But can manage
Solve, along with during using, the selection of effective ingredient concentration is different, above-mentioned second azoles demodicid mite nitrile and the ratio of Envidor, this area
Technical staff can do the arbitrary number ratios of selection as required in above-mentioned weight ratio.
The another aspect of the embodiment of the present invention is by the miticide composition of second azoles demodicid mite nitrile Yu Envidor, is equipped with suitable auxiliary agent
Make the acaricide of multiple dosage form, described effective ingredient second azoles demodicid mite nitrile and Envidor weight percent in described compound acaricide
Content is 10%～80%.
In order to become apparent from introducing the mite killing combination containing second azoles demodicid mite nitrile with Envidor that the embodiment of the present invention is provided in detail
Thing, illustrates below with reference to specific embodiment.In embodiment, percentage ratio is all weight percentage, the inorganic agent of field efficacy
Amount is effective ingredient consumption.
Embodiment 1:30% water dispersible granules
Preparation method: in proportion, adds effective ingredient second azoles demodicid mite nitrile in carrier with Envidor, and adds surface wherein
Activating agent and other functional aids, mix, and after comminution by gas stream, pelletize prepares water dispersible granules again.Capital equipment has mixed
Conjunction machine, jet mill, Squeezinggranulator.
Compositions proportioning: second azoles demodicid mite nitrile 6%；Envidor 24%；Wetting agent sodium lauryl sulphate 4%；Dispersant is wooden
Element sulfoacid calcium 8%；Filler white carbon 24%, filler Kaolin surplus.
Embodiment 2:24% suspending agent
Preparation method: in proportion, by effective ingredient second azoles demodicid mite nitrile and Envidor and other wetting dispersing agents, thickening agent, prevents
Freezing the mixing such as agent, preservative, water, the clipped rear horizontal sand mill that adds carries out 2～3 hours sand millings, adds defoamer afterwards and continue
Continuous shearing, prepares suspending agent product.Capital equipment has mixer, cutter, horizontal sand mill.
Compositions proportioning: second azoles demodicid mite nitrile 6%；Envidor 18%；Wetting dispersing agent carboxylate+sulfonate 8%；Thickening agent
1%；Antifreezing agent 4%；Preservative 0.2%；Defoamer 0.2%；Water surplus.
Embodiment 3:51% water dispersible granules
Preparation method is with embodiment 1
Compositions proportioning: second azoles demodicid mite nitrile 50%；Envidor 1%；Wetting agent sodium lauryl sulphate 4%；Dispersant is wooden
Element sulfoacid calcium 8%；Filler white carbon 24%, filler Kaolin surplus.
Embodiment 4:51% water dispersible granules
Preparation method is with embodiment 1, compositions proportioning: second azoles demodicid mite nitrile 1%；Envidor 50%；Wetting agent dodecyl sulfur
Acid sodium 4%；Dispersant calcium lignosulfonate 8%；Filler white carbon 24%, filler Kaolin surplus.
Embodiment 5:11% suspending agent
Preparation method is with embodiment 2, compositions proportioning: second azoles demodicid mite nitrile 1%；Envidor 10%；Wetting dispersing agent carboxylate+
Sulfonate 8%；Thickening agent 1%；Antifreezing agent 4%；Preservative 0.2%；Defoamer 0.2%；Water surplus.
Embodiment 6:11% suspending agent
Preparation method is with embodiment 2, compositions proportioning: second azoles demodicid mite nitrile 10%；Envidor 1%；Wetting dispersing agent carboxylate+
Sulfonate 8%；Thickening agent 1%；Antifreezing agent 4%；Preservative 0.2%；Defoamer 0.2%；Water surplus.
Toxicity Determination
The present invention first passes through Toxicity Determination, and test medicine uses the 95% second azoles former medicine of demodicid mite nitrile and 96% Envidor former
Medicine；Examination worm is the European red mite gathered from field, if through the first generation demodicid mite of indoor feeding breeding hatching.
Test method uses leaf butterfly nebulization (with reference to " NY/T 1154.13-2008 farm-chemical indoor determination test rule
Insecticide. the 13rd part: leaf butterfly nebulization ").Concrete operation method is as follows.
Each single dose is arranged with Mixed Pharmacy 5 different Concentraton gradient (on the basis of pilot study result, cotton leaf
If demodicid mite demodicid mite mortality rate is set by geometric progression in the range of 5%～90%).
Choose the Apple Leaves that growth is consistent, make leaf butterfly with card punch, in culture dish, place a wet sponge block, on it
Putting filter paper, foliation butterfly on filter paper, every ware puts 2 pieces of leaf butterflies, European red mite that select indoor feeding, that healthy, age is consistent
If being completely inoculated on leaf butterfly, every leaf butterfly inoculates 20.
Being placed under potter spray tower by the culture dish being connected to leaf butterfly, spray under 50PSI pressure, spray amount is 1ml, heavy
Taking out culture dish after fall 1min, then the culture dish processed is put into 12H/12H illumination box and cultivates, 48h checks dead
Borer population, calculates mortality rate.Often process and set 4 repetitions, and set the process of clear water blank.
Carry out statistical analysis with DPS statistical analysis software, calculate the LC of each medicament50, evaluate the insecticidal activity of each medicament.
And the co-toxicity coefficient (CTC value) of mixture is calculated according to the abundant method of Sun Yun.
Actual measurement toxicity index (ATI)=(standard agent LC50/ reagent agent LC50)×100。
Percentage composition+B medicament the toxicity index of A in theoretical toxicity index (TTI)=A medicament toxicity index × mixture × mixed
The percentage composition of B in agent.
Co-toxicity coefficient (CTC)=[mixture actual measurement toxicity index (ATI)/mixture theory toxicity index (TTI)] × 100.
According to the NY/T11547.7-2006 insecticide combination effect criteria for classifying: co-toxicity coefficient (CTC) >=120 shows as
Potentiation；Co-toxicity coefficient (CTC)≤80 shows as antagonism；80 ＜ co-toxicity coefficient (CTC) ＜ 120 show as being added and make
With.
Result of the test is shown in Table 1.
| Nomenclature of drug and proportioning (weight ratio) | LC50(mg/l) | ATI | TTI | CTC |
| Second azoles demodicid mite nitrile | 11.82 | 41.45 | — | — |
| Envidor | 8.71 | 126.12 | — | — |
| Second azoles demodicid mite nitrile: Envidor (50: 1) | 10.12 | 44.67 | 35.82 | 123.48 |
| Second azoles demodicid mite nitrile: Envidor (10: 1) | 7.03 | 65.54 | 39.58 | 158.34 |
| Second azoles demodicid mite nitrile: Envidor (5: 1) | 6.52 | 81.42 | 41.39 | 176.22 |
| Second azoles demodicid mite nitrile: Envidor (1: 1) | 4.34 | 137.17 | 59.44 | 230.66 |
| Second azoles demodicid mite nitrile: Envidor (1: 5) | 5.18 | 142.41 | 79.82 | 185.38 |
| Second azoles demodicid mite nitrile: Envidor (1: 10) | 6.24 | 132.79 | 67.19 | 164.58 |
| Second azoles demodicid mite nitrile: Envidor (1: 50) | 7.48 | 122.35 | 62.12 | 131.16 |
Table 1 second azoles demodicid mite nitrile and the Envidor indoor joint toxicity measuring to European red mite
As it can be seen from table 1 the compositions of embodiments of the invention has the highest activity, especially second azoles demodicid mite to red spider
Nitrile and Envidor are in the range of mass fraction is than for 10:1～1:10, and potentiation becomes apparent from, and co-toxicity coefficient (CTC) all exists
More than 120, it is seen that second azoles demodicid mite nitrile is compounding with Envidor has reasonability and feasibility.
In order to better illustrate the effective prevention effect of the present invention, underneath with above-described embodiment medicament and 30% second azoles demodicid mite nitrile
Suspending agent, 24% Envidor suspending agent carry out field efficacy preventing and treating to European red mite, and result of the test is as shown in table 2 below.
This field control effectiveness test sets totally 5 process such as enforcement medicament, contrast agents, clear water, and each experimental plot area is
50m2, often process 4 repetitions, community random alignment.0.5m protection row it is designed with between each community and around experimental plot.Make
By the method for artificial spraying, Fructus Mali pumilae being carried out dispenser, dispenser is investigated 1 time for first 1 day, 3 days, 7 days and 14 days respectively investigation 1 time after dispenser,
Totally 4 times.Investigation method takes five point samplings and listing mark method.Every community fixed point 10 apple trees of investigation, every choosing difference
10 blades of position listing mark, investigate insect population cardinal sum remaining borer population, calculate Revision insect recluced rate and prevention effect.Computing formula
As follows:
Revision insect recluced rate (%)=[borer population before (borer population after borer population-dispenser before dispenser)/dispenser] × 100
Prevention effect (%)=[(treatment region Revision insect recluced rate-blank district Revision insect recluced rate)/(1-blank
District's Revision insect recluced rate)] × 100
Table 2 different disposal prevention effect to European red mite
Show from table 2 result of the test, implement medicament after dispenser and the prevention effect of European red mite is significantly higher than contrast medicine
Agent；After dispenser 14 days, implement medicament to the prevention effect of European red mite still more than 92%, up to 98% had.This table
Bright second azoles demodicid mite nitrile and Envidor Compositional acaricide have obvious potentiation, and efficiency time is considerably longer than single medicament.
Experiment shows, this complex composition substantially reduces medicament usage amount, decreases production cost, pesticide residues and environmental pollution.Separately
Outward, field observation during test, embodiment medicament respectively processes medicinal liquid to plant growth without impact, to beneficial organism safety around,
Being compatible with the environment property is good.As can be seen here, second azoles demodicid mite nitrile and Envidor are preferable compound acaricide products.
Claims (10)
1. containing second azoles demodicid mite nitrile and the miticide composition of Envidor, it is characterised in that effective ingredient is second azoles demodicid mite nitrile and Envidor.
The most according to claim 1 containing second azoles demodicid mite nitrile and the miticide composition of Envidor, it is characterised in that described effective one-tenth
The weight ratio of point second azoles demodicid mite nitrile and Envidor is 50:1～1:50.
The most according to claim 2 containing second azoles demodicid mite nitrile and the miticide composition of Envidor, it is characterised in that described effective one-tenth
The weight ratio of point second azoles demodicid mite nitrile and Envidor is 10:1～1:10.
The most according to claim 3 containing second azoles demodicid mite nitrile and the miticide composition of Envidor, it is characterised in that described effective one-tenth
Point second azoles demodicid mite nitrile and Envidor weight percentage in described miticide composition are 10%～80%.
The most according to claim 1 containing second azoles demodicid mite nitrile and the miticide composition of Envidor, it is characterised in that described mite killing group
Compound also includes carrier and auxiliary agent.
The most according to claim 5 containing second azoles demodicid mite nitrile and the miticide composition of Envidor, it is characterised in that described carrier selects
One or both in water, filler.
The most according to claim 5 containing second azoles demodicid mite nitrile and the miticide composition of Envidor, it is characterised in that described auxiliary agent bag
Include surfactant, one or more in emulsifying agent, dispersant, wetting agent or penetrating agent of surfactant；Described help
Agent also includes other functional aids, and other functional aids are selected from antifreezing agent, thickening agent, stabilizer, disintegrating agent or defoamer
In one or more.
8. arbitrary described containing second azoles demodicid mite nitrile and the miticide composition of Envidor according to claim 1 to 7, it is characterised in that institute
The dosage form stating miticide composition is water dispersible granules or suspending agent.
9. the arbitrary described miticide composition containing second azoles demodicid mite nitrile and Envidor of claim 1 to 7 is at preventing and treating pest mite apoplexy due to endogenous wind
Application.
Miticide composition containing second azoles demodicid mite nitrile and Envidor the most according to claim 9 should preventing and treating pest mite apoplexy due to endogenous wind
With, it is characterised in that described pest mite class is harmful resistant mite class.
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| CN106818766A (en) * | 2017-02-18 | 2017-06-13 | 佛山市瑞生通科技有限公司 | A kind of composition pesticide of the mite nitrile of azoles containing second and spirodiclofen |
| CN106942235A (en) * | 2017-03-21 | 2017-07-14 | 佛山市瑞生通科技有限公司 | A kind of Pesticidal combination containing propylene glycol alginate and second azoles mite nitrile |
| CN108902158A (en) * | 2018-08-17 | 2018-11-30 | 沈阳中化农药化工研发有限公司 | A kind of suspending agent containing second azoles mite cyanide composition and its application |
| CN110583668A (en) * | 2019-09-27 | 2019-12-20 | 浙江工业大学 | Mite-killing pesticide composition and application thereof |
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| CN106818766A (en) * | 2017-02-18 | 2017-06-13 | 佛山市瑞生通科技有限公司 | A kind of composition pesticide of the mite nitrile of azoles containing second and spirodiclofen |
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| CN108902158A (en) * | 2018-08-17 | 2018-11-30 | 沈阳中化农药化工研发有限公司 | A kind of suspending agent containing second azoles mite cyanide composition and its application |
| CN110583668A (en) * | 2019-09-27 | 2019-12-20 | 浙江工业大学 | Mite-killing pesticide composition and application thereof |
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