CN106614629A - Sterilization composition including flutianil - Google Patents
Sterilization composition including flutianil Download PDFInfo
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- CN106614629A CN106614629A CN201611173054.3A CN201611173054A CN106614629A CN 106614629 A CN106614629 A CN 106614629A CN 201611173054 A CN201611173054 A CN 201611173054A CN 106614629 A CN106614629 A CN 106614629A
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- China
- Prior art keywords
- flutianil
- cyflufenamid
- powdery mildew
- bactericidal composition
- active ingredient
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/74—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,3
- A01N43/78—1,3-Thiazoles; Hydrogenated 1,3-thiazoles
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/52—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing groups, e.g. carboxylic acid amidines
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- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a sterilization composition including flutianil. The effective component of the sterilization composition is composed of the flutianil and cyflufenamid in a mass ratio of 1:50-50:1. The composition is significant in synergism, good in prevention effect, and suitable for preventing and treating various diseases on cereals, fruits and vegetables, particularly suitable for preventing and treating powdery mildew.
Description
Technical field
The present invention relates to a kind of bactericidal composition, more particularly to a kind of bactericidal composition containing flutianil and its anti-
The application of corps diseases is controlled, belongs to technical field of pesticide.
Background technology
Powdery mildew is the plant disease caused by the Erysiphaceae (Erysiphacesae) in fungi.For example：By standing grain white powder
The Cereal powdery mildew that bacterium (Erysiphe graminis) causes；By Siberian cocklebur monofilament shell (Sphaerotheca fuliginea)
The powdery mildew of the various plants such as the melon, beans, the crudefiber crop that cause；The grass caused by strawberry snag shell (Uncinula necator)
Certain kind of berries powdery mildew；Mulberry, pears, persimmon, walnut, chestnut, lichee, papaya caused by hazel ball pin shell (Phyllactinia corylea) etc.
The powdery mildew of more than 80 kinds of trees；The powdery mildew of the Flowers of Rosa caused by rose monofilament shell (Sphaerotheca pannosa)
Deng.
In the preventing and treating of powdery mildew, benzimidazole, triazole bactericidal agent are relied primarily at present.These medicaments are because long-term
Using the different degrees of resistance to the action of a drug is generated, prevention effect is reduced.
Flutianil be thiazolidines bactericide, molecular formula：C19H14F4N20S2, molecular weight 426.5.The medicament is by suppression
The mycelial growth of pathogen processed and take effect.Flutianil is in extremely low concentration (10mg/L) to powdery mildew of gourd, fruit and vegetable etc. etc.
The tall and erect effect of disease tool.
, used as a kind of new type bactericide, current production and use cost is higher, and individually makes for a long time for flutianil
With also there is very big resistance risk.
The content of the invention
It is an object of the invention to provide a kind of synergistic effect is substantially, low cost good to powdery mildew prevention effect, resistance risk
Low bactericidal composition.
It is a further object of the present invention to provide the application of the bactericidal composition.
Inventor by substantial amounts of indoor biometricses and field control effectiveness test, have been surprisingly found that flutianil and cyflufenamid with
After certain ratio mixture, there is significant synergistic effect to diseases such as Powdery Mildews.
The cyflufenamid (cyflufenamid), molecular formula C20H17F5N2O2, molecular weight 412.4.Cyflufenamid is to crowd
Many powdery mildews have excellent protection and therapeutic activity, and have good holding effect activity and resistance of rainwater washing against activity.Ring fluorine bacterium
Amine mainly suppresses the formation of haustorium mitogenetic on mycelia in the Powdery Mildew history of life and growth, the growth of secondary hyphae and hapteron
Formation.
Cyflufenamid is acid amide fungicides well known in the art, with other series bactericidal agent no interactions resistances, can be passed through
Various commercial channel obtain.
To overcome the deficiencies in the prior art, such solution is the technical scheme is that：It is a kind of containing flutianil's
Bactericidal composition, containing active ingredient flutianil and cyflufenamid, both mass ratioes are the ︰ 1 of 1 ︰ 50～50, preferred mass
Than for 1:30～30:1.
Said composition can be processed into any formulation for agriculturally allowing, and preferable formulation has missible oil, microemulsion, water and milk
Agent, suspending agent, suspension emulsion, wettable powder or water dispersible granules.
In the bactericidal composition of the present invention, active ingredient flutianil is with the mass accumulation percentage composition of cyflufenamid
5%～85%, remaining is auxiliary agent and filler or diluent.
The formulation of above-mentioned bactericidal composition in addition to including effective ingredient f lutianil and cyflufenamid, also including auxiliary agent
Contribute to the material of drug effect performance with other.Missible oil includes organic solvent, cosolvent and emulsifying agent；Microemulsion includes organic molten
Agent, emulsifying agent and water；Aqueous emulsion includes organic solvent, dispersant, emulsifying agent and water；Suspending agent includes water, dispersant, thickening
Agent, antifreezing agent and wetting agent；Wettable powder includes wetting agent, dispersant and filler；Water dispersible granules include dispersant, disintegration
Agent, filler and wetting agent.Below all it is to commonly use in pesticidal preparations or allow the various composition for using, is not particularly limited, specifically
Composition and consumption are determined according to recipe requirements by simple experiment.For example：
Organic solvent may be selected isopropanol, dimethylbenzene, N,N-dimethylformamide, ring ethyl ketone, toluene, dimethyl sulfoxide (DMSO),
Methyl alcohol, ethanol, trimethyl cyclic ethylene ketone, NOP, 1-METHYLPYRROLIDONE, propyl alcohol, butanol, ethylene glycol, diethyl
One or more in glycol, EGME, butyl ether, ethyl acetate, vegetable oil.
Cosolvent may be selected the one kind or many in 1-METHYLPYRROLIDONE, dimethylformamide, ethanol, the third ethanol, acetone
Kind.
Dispersant may be selected sodium lignin sulfonate, calcium lignosulfonate, pull open powder, calcium dodecyl benzene sulfonate, polycarboxylic acids
Salt, alkyl benzene sulfonate calcium salt, APES, aliphatic amine polyoxyethylene ether, polyoxyethylene carboxylate, glycerin fatty
One or more in acid ester polyoxyethylene ether.
Emulsifying agent may be selected agricultural emulsifier NO.600 (phenyl phenol polyoxyethyl ether), agriculture breast 1601, and (phenethyl phenol polyoxyethanyl gathers
Propenyl ether), agriculture breast 500 (alkyl benzene calcium sulfonate), OP series phosphate (thermally coupled distillation columns), No. 600
Phosphate (phenyl phenol polyoxyethanyl ether phosphate), styrene polyoxyethylene rice ammonium sulfate, alkyl biphenyl ether disulfonic acid magnesium salts,
Triethanolamine salt, agriculture breast 400 (benzyl xylenol polyoxyethyl ether), Nongru-700 number (alkyl phenolic resin polyoxyethyl ether),
Agriculture breast 36 (phenethyl phenol formaldehyde resin polyoxyethyl ether), agriculture breast 1600 (phenethyl phenol polyoxyethanyl polypropylene-base ether),
Ethylene oxide-propylene oxide block copolymer, OP series (NPE), No. 33 (alkylaryl polyoxies third of agriculture breast
Alkene APEO), agriculture breast 34 (alkylaryl polyoxyethylene poly-oxygen propylene aether), Span series (sorbitol anhydride monostearate
Ester), TWEEN Series (sorbitan fatty acid ester APEO), AEO series (fat alcohol alcohol APEO) in one kind
Or it is various.
Antifreezing agent may be selected one or more in glycerine, urea, ethylene glycol, propane diols.
Wetting agent may be selected methyl naphthalene sulfonate formaldehyde condensate, lauryl sodium sulfate, Negel, alkylbenzene
One or more in sulfoacid calcium, tea seed cake, spaonin powder, silkworm excrement, spaonin powder, bay alcohol radical sodium sulphate, washing powder, pull open powder.
Disintegrant may be selected the one kind in ammonium sulfate, urea, bentonite, aluminium chloride, citric acid, succinic acid, sodium acid carbonate
Or it is various.
Thickener may be selected the one kind in xanthans, hydroxymethyl cellulose, methylcellulose, Magnesiumaluminumsilicate, polyvinyl alcohol
Or it is various.
Filler may be selected White Carbon black, ridge soil, precipitated calcium carbonate, talcum, montmorillonite or convex-concave rod stone, float stone, brickbat, Hai Pao
One or more in stone or bentonite and non-adsorbent calcium soil or sand.
Product described in the invention can be provided in finished product preparation form, i.e., each material is blended in composition, combination
The composition of thing can also be provided with unit dose form, directly be mixed in proportion in bucket or tank using front, needed for being then diluted to
Concentration.
The bactericidal composition of the present invention is particularly suited for preventing and treating powdery mildew.The composition of the present invention can be by common method
Apply, such as cast, injection, spraying, dusting, distribution or smoke, its amount of application changes with weather condition or crop condition.
Compared with prior art, its advantage is the present invention：1st, substantially, preventive effect is notable compared with single dose for composition synergistic effect
Improve；2nd, after drug effect is improved, the effective ingredient consumption in field declines, and reduces production and use cost, reduces residues of pesticides
And environmental pollution；3rd, composition is made up of the active ingredient of different mechanism of action, and action site increases, and is conducive to overcoming and delays
The drug-fast generation of germ.
Specific embodiment
The present composition has obvious synergistic function, and not exclusively two kinds pharmacy effects to Powdery Mildew etc.
Simple addition, this can from following Toxicity Determination test result in be clear that.Biologicall test example 1：Combination
Thing is tested the Toxicity Determination of wheat powdery mildew, cucumber powdery mildew's pathogen
Subjects are wheat powdery mildew (Erysiphe graminis), cucumber powdery mildew's pathogen (Sphaerotheca
fuliginea)。
Test method：Reference《People's Republic of China (PRC) agricultural industry criteria NY/T 1156.11-2008》.Choose growth potential
Consistent potted plant one heart stage of two leaves wheat seedling (two panels leaf period cucumber seedling), is sprayed with Potter spray towers under 50PSI pressure,
Per basin 5mL.Each medicament arranges 5 concentration gradients.Inoculum density is carried out after 24h for 3 × 105The wheat of individual spore/mL is (yellow
Melon) Powdery Mildew conidial suspension.To spray wheat (cucumber) seedling of equivalent clear water as blank.By wheat after inoculation
(cucumber) seedling is put in greenhouse and cultivates.After 10d, disease index is investigated according to the morbidity grade scale of wheat (cucumber) powdery mildew,
And calculate prevention effect.
Wheat (cucumber) powdery mildew severity Scaling standard：
0 grade：Blade disease-free spot；
1 grade：Lesion area accounts for the area of whole blade below 5%；
3 grades：Lesion area accounts for the 6%～10% of the area of whole blade；
5 grades：Lesion area accounts for the 11%～25% of whole blade area；
7 grades：Lesion area accounts for the 26%～50% of whole blade area；
9 grades：Lesion area accounts for more than the 50% of whole blade area.
The expected effect (i.e. theoretical prevention effect, %) of mixture of active principles determined using Colby formula and with observation
To effect compare：
Colby formula：E=X+Y-X*Y/100
E：When active components A concentration is a in composition, compositions contemplated effect when active component B concentrations are b
Power.
X：Effect when active components A dosage is a.
Y：Effect when active component B dosages are b.
When the actual prevention effect observed exceedes expected preventive effect, explanation mixture has synergistic effect.
Toxicity test result is referring to table 1 to table 2.
The flutianil of table 1 compounds the pot experiment measurement result to wheat powdery mildew with cyflufenamid
The flutianil of table 2 compounds the pot experiment measurement result to cucumber powdery mildew's pathogen with cyflufenamid
Result of the test shows that flutianil compounds within the specific limits preventing and treating wheat powdery mildew and Huang with cyflufenamid
Melon Powdery Mildew, with synergistic effect.
In order that the objects, technical solutions and advantages of the present invention become more apparent, present invention preparation reality in detail below
Example is illustrated, but the present invention is limited to absolutely not these examples.Described below is only the present invention preferably embodiment, only to solve
The present invention is released, therefore the restriction to the scope of the claims of the present invention can not be interpreted as.It should be pointed out that all essences in the present invention
Any modification, equivalent and improvement made within god and principle etc., should be included within the scope of the present invention.Cause
This, the protection domain of patent of the present invention should be defined by claims.
Missible oil embodiment
Pesticide active ingredient, emulsifying agent, solvent are mixed in proportion, is mixed in modulation kettle, until completely dissolved,
Remaining solvent is slowly added into again, uniform oil phase is obtained after being sufficiently stirred for, make missible oil product.
Embodiment 1,51%flutianil 〃 cyflufenamid missible oil
Flutianil 50%, cyflufenamid 1%, agriculture breast No. 500 2% (emulsifying agent), dimethylbenzene (solvent) are supplemented to
100%.
Embodiment 2,31%flutianil 〃 cyflufenamid missible oil
Flutianil 30%, cyflufenamid 1%, POLYSORBATE 80 3% (emulsifying agent), dimethylbenzene (solvent) are supplemented to
100%.
Microemulsion, aqueous emulsion embodiment
By each group distribution ratio, active component is dissolved in solvent and cosolvent, adds surfactant, be well mixed system
Obtain oil phase.Water-soluble component and water are mixed to prepare into water phase, then oil phase are added in water phase or water is added in oil phase, side edged
Stirring, is obtained microemulsion or aqueous emulsion.
Embodiment 3,5%flutianil 〃 cyflufenamid microemulsions
Flutianil 2.5%, cyflufenamid 2.5%, cyclohexanol (solvent) 10%, agriculture breast No. 500 8% (emulsifying agent),
Agricultural emulsifier NO.600 5% (emulsifying agent), agriculture breast No. 1,600 5% (emulsifying agent), sldium lauryl sulfate 2% (wetting agent), ethylene glycol 5%
(antifreezing agent), water are supplemented to 100%
Embodiment 4,11%flutianil 〃 cyflufenamid aqueous emulsions
Flutianil 0%, cyflufenamid 1%, DMF (solvent) 5%, toluene 8% (solvent), glycerine (antifreezing agent) 5%,
Phenethyl phenol polyethenoxy ether (emulsifying agent) 10%, calcium dodecyl benzene sulfonate (wetting agent) 5%, water is supplemented to 100%
Suspension emulsion embodiment
The each components such as active ingredient, dispersant, wetting agent, defoamer, thickener and water is equal in the ratio mixing of formula
It is even, semi-finished product are obtained Jing after sand milling or high speed shear, the filtration that is mixed with water is mended after analysis and obtains final product suspending agent.
First solid active ingredient is obtained into stable dense suspension.Using high-shear mixer, by liquid active ingredient breast
Liquid phase is added in suspension, and suspension emulsion is obtained.
Embodiment 5,31%flutianil 〃 cyflufenamid suspending agents
Flutianil 1%, cyflufenamid 30%, sodium lignin sulfonate (dispersant) 5%, APES
8% (wetting agent), propane diols 2% (antifreezing agent), xanthans 1% (thickener), organosilicon 2% (defoamer), water are supplemented to
100%
Embodiment 6,51%flutianil 〃 cyflufenamid suspending agents
Flutianil 1%, cyflufenamid 50%, calcium lignosulfonate (dispersant) 5%, APES
8% (wetting agent), propane diols 2% (antifreezing agent), xanthans 1% (thickener), organosilicon 2% (defoamer), water are supplemented to
100%
Water dispersible granules embodiment
Pesticide activity component, auxiliary agent and filler are mixed in proportion, Jing air-flow crushings, then add the water of 15-20%, Jing to pinch
Close, granulate, being dried, screening is obtained water dispersible granules product.Capital equipment：Mixer, airslide disintegrating mill, kneader, extruding are made
Grain machine, drying equipment (drying room or fluid bed).
Embodiment 7,85%flutianil 〃 cyflufenamid water dispersible granules
Flutianil 50%, cyflufenamid 35%, neopelex 2% (wetting agent), sodium lignin sulfonate
4% (dispersant), ammonium sulfate 2% (disintegrant), kaolin (filler) to 100%
Wettable powder embodiment
Pesticide activity component, auxiliary agent, filler are mixed in proportion Jing after air-flow crushing and remixes prepared wettable powder.It is main
Want equipment：Mixer, airslide disintegrating mill.
Embodiment 8,50%flutianil 〃 cyflufenamid wettable powders
Flutianil 15%, cyflufenamid 35%, bay alcohol radical sodium sulphate 4% (wetting agent), mersolates 7%
(dispersant), white carbon 8% (filler), kaolin (filler) to 100%
Embodiment 9,11%flutianil 〃 cyflufenamid wettable powders
Flutianil 1%, cyflufenamid 10%, bay alcohol radical sodium sulphate 4% (wetting agent), mersolates 7%
(dispersant), white carbon 8% (filler), talcum powder (filler) to 100%
Field information embodiment 1：Flutianil compounds the field control effectiveness test to wheat powdery mildew with cyflufenamid
Test site Nanyang, henan.Test medicine and consumption are shown in Table 3, often process 4 cells and repeat, each plot area 20
Square metre.First time dispenser is carried out in disease early period of origination, even spraying is sprayed onto till blade drips, and with clear water sky is processed as
White control.Second medicine is applied after 7 days.The incidence of 7 days investigation wheat powdery mildews before first time medicine and after second medicine.Often
Cell investigates all blades per the root and stem of certain plants, with the percentage that lesion area accounts for whole leaf area using 5 points of samplings, per two root and stem of certain plants of investigation
To be classified record.Calculate each process disease index and prevention effect.
Grade scale：
0 grade：Disease-free spot；
1 grade：Lesion area accounts for less than the 5% of whole leaf area；
3 grades：Lesion area accounts for the 6%-15% of whole leaf area；
5 grades：Lesion area accounts for the 16%-25% of whole leaf area；
7 grades：Lesion area accounts for the 26%-50% of whole leaf area；
9 grades：Lesion area accounts for more than the 50% of whole leaf area.
Drug effect computational methods：
As can be seen from Table 3：Flutianil, cyflufenamid single dose are respectively 79.9% and to the preventive effect of wheat powdery mildew
73.9%, and embodiment of the present invention bactericidal composition is significantly increased in preventive effect, minimum preventive effect is 89.5%, up to
95.3%.The result of field test fully shows have significantly to wheat powdery mildew after flutianil and cyflufenamid compounding
Synergistic function, effective ingredient consumption compared with single dose reduction in the case of, prevention effect is greatly improved.Therefore, the present invention
The beneficial effect that composition has reduces cost, delaying drug resistance, reduces spraying times and residues of pesticides.
The flutianil of table 3 compounds the field test results to wheat powdery mildew with cyflufenamid
Field information example 2：Flutianil compounds the field control effectiveness test to powdery mildew of cucumber with cyflufenamid
Test site Shandong Shouguang.Test method and method of statistical survey are with Field information example 1
As can be seen from Table 4：Flutianil, cyflufenamid single dose are respectively 74.8% and to the preventive effect of powdery mildew of cucumber
70.3%, and embodiment of the present invention bactericidal composition is significantly increased in preventive effect, minimum preventive effect is 85.2%, up to
90.7%.The result of field test fully shows have significantly to powdery mildew of cucumber after flutianil and cyflufenamid compounding
Synergistic function, effective ingredient consumption compared with single dose reduction in the case of, prevention effect is greatly improved.Therefore, the present invention
The beneficial effect that composition has reduces cost, delaying drug resistance, reduces spraying times and residues of pesticides.
The flutianil of table 4 compounds the field test results to powdery mildew of cucumber with cyflufenamid
Claims (6)
1. a kind of bactericidal composition containing flutianil, it is characterised in that：Containing active ingredient flutianil and ring fluorine bacterium
Amine, both mass ratioes are the ︰ 1 of 1 ︰ 50～50.
2. bactericidal composition according to claim 1, it is characterised in that：Active ingredient flutianil and cyflufenamid
Mass ratio is the ︰ 1 of 1 ︰ 30～30.
3. bactericidal composition according to claim 2, it is characterised in that：Active ingredient flutianil and cyflufenamid
Mass ratio is the ︰ 1 of 1 ︰ 10～10.
4. the bactericidal composition according to any one of claims 1 to 3, it is characterised in that：Active ingredient is tired in composition
Product weight/mass percentage composition is 5%～85%.
5. bactericidal composition according to claim 4, it is characterised in that：Formulation is missible oil, microemulsion, aqueous emulsion, suspension
Agent, suspension emulsion, wettable powder or water dispersible granules.
6. application of the bactericidal composition described in claim 1 on preventing and treating crop powdery mildew.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611173054.3A CN106614629A (en) | 2016-12-20 | 2016-12-20 | Sterilization composition including flutianil |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611173054.3A CN106614629A (en) | 2016-12-20 | 2016-12-20 | Sterilization composition including flutianil |
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Family
ID=58823772
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109077056A (en) * | 2018-10-10 | 2018-12-25 | 山东省联合农药工业有限公司 | A kind of efficient bactericidal composite |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2004043149A1 (en) * | 2002-11-12 | 2004-05-27 | Otsuka Chemical Co., Ltd. | Bactericide composition for agricultural or horticultural use and method of enhancing bactericidal activity of agricultural or horticultural bactericide |
| WO2010029030A2 (en) * | 2008-09-12 | 2010-03-18 | Basf Se | Fungicidal mixtures |
-
2016
- 2016-12-20 CN CN201611173054.3A patent/CN106614629A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2004043149A1 (en) * | 2002-11-12 | 2004-05-27 | Otsuka Chemical Co., Ltd. | Bactericide composition for agricultural or horticultural use and method of enhancing bactericidal activity of agricultural or horticultural bactericide |
| WO2010029030A2 (en) * | 2008-09-12 | 2010-03-18 | Basf Se | Fungicidal mixtures |
Non-Patent Citations (1)
| Title |
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| 马韵升等: "新型白粉病杀菌剂环氟菌胺", 《农药》 * |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109077056A (en) * | 2018-10-10 | 2018-12-25 | 山东省联合农药工业有限公司 | A kind of efficient bactericidal composite |
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Application publication date: 20170510 |