CN106417321A - Compound miticide as well as dose form and use thereof - Google Patents
Compound miticide as well as dose form and use thereof Download PDFInfo
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- CN106417321A CN106417321A CN201610778899.9A CN201610778899A CN106417321A CN 106417321 A CN106417321 A CN 106417321A CN 201610778899 A CN201610778899 A CN 201610778899A CN 106417321 A CN106417321 A CN 106417321A
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- Prior art keywords
- compound
- agent
- demodicid mite
- etoxazole
- miticide
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/74—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,3
- A01N43/76—1,3-Oxazoles; Hydrogenated 1,3-oxazoles
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
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- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention relates to a compound miticide. The compound miticide comprises the effective components of Yizuomanjing (SYP-9625) and etoxazole in a weight ratio of (30 to 1)-(1 to 20). The compound miticide has the advantages and beneficial effects that (1) the compound miticide is wide in miticidal range, long in lasting period and low in toxicity and safe to environment and has no residue and pollution; (2) two miticides are combined in use, so that the synergistic effect is obvious; (3) the two miticides are combined in use, and the field dosages of the effective components are decreased, so that the production cost and the use cost are lowered, and the pesticide residue and the environmental pollution are reduced; (4) the compound miticide consists of the effective components with different action mechanisms, so that the generation of drug resistance of pests can be overcome and delayed; and (5) the compound miticide does not contain organic solvent, is safe to crops and is an important measure for controlling crop pests.
Description
Technical field
The present invention relates to agricultural acaricides field, relate in particular to one kind with second azoles demodicid mite nitrile and etoxazole as effective ingredient
Acaricide and its dosage form and purposes.
Background technology
Second azoles demodicid mite nitrile is new acaricide.Shenyang Sciencreat Chemicals Co., Ltd. develops 30% second azoles demodicid mite nitrile suspending agent and produces
Product, in the case that effective ingredient consumption is 22.5～45gai/hm2, the preventive effect of cotton red spider is reached more than 98% it is seen that
Prevention effect on preventing and treating mite pest for this pesticide is notable, has good application prospect.Its mechanism of action and preventing and treating spectrum at present
It is in conceptual phase Deng still, after the indices such as physicochemical property and safety index improve, said preparation has very big room for development.
Etoxazole, English common name (etoxazole), belong to 2,4- diphenyloxazole derivatives quasi-compound, be a kind of
Selectivity acaricide.Mainly suppress the embry ogenesis of demodicid mite ovum, and from young demodicid mite to the molting process becoming demodicid mite, ovum and young demodicid mite are had
Effect, to becoming, demodicid mite is invalid, but becomes demodicid mite to have sterile effect well female.Therefore its optimal preventing and treating time is evil mite harm
Initial stage.Rain fastness is strong, and the lasting period is up to 50 days.The molting process of suppression mite class, thus to demodicid mite from ovum, larva to pupa different phase
Have excellent contact.The mite class having produced resistance to Hexythiazox has good prevention effect.Main preventing and treating Fructus Mali pumilae, Citrus
Red spider, also has to mite class such as the tetranychid of the crops such as Cotton Gossypii, flowers, vegetable, beginning tetranychid, Panonychus citri, Tetranychus urticae, Tetranychus cinnabarinus
Remarkable preventive effect.
Often there is different degrees of defect on agricultural acaricides are prevented and treated in the acaricide kind containing single-activity component,
As mite killing narrow range, only individually there is effect to deutonymph, one-tenth demodicid mite, invalid to ovum or invalid to one-tenth demodicid mite, prevention effect is poor, dispenser agent
Amount is also easy to produce greatly Drug resistance, increases environmental pollution etc. application times more.Preventing and treating is agriculturally produced to the mite class of resistance, one kind is done
Method is to release the new new component with existing kind no interactions resistance.But, the development cost of new effective ingredient is high, exploitation week
Phase is long, and does not forever all catch up with the speed that evil mite produces resistance.Other methods such as crop structure adjustment, different pesticide wheel
Change, during practical operation, be difficult to really play obvious effect.
Content of the invention
It is an object of the invention to provide a kind of acaricidal activity efficiently, the high and low poison of lasting period length, quick-acting, the mite killing of environmental protection
Compositionss.
Technical scheme is as follows：
A kind of compound acaricide, with second azoles demodicid mite nitrile and etoxazole as effective ingredient.
The weight of described second azoles demodicid mite nitrile and etoxazole is than for 30: 1～1: 20.
The described second azoles demodicid mite nitrile and etoxazole weight percentage in compound acaricide is 10%～80%.
In addition to above-mentioned effective ingredient, the compound acaricide of the present invention also includes carrier and auxiliary agent.
Described carrier is water or filler；Described filler be selected from Kaolin, kieselguhr, bentonite, attapulgite, white carbon,
The mixture of one or more of starch and precipitated calcium carbonate composition.
Described auxiliary agent includes surfactant, and described surfactant is solvent, emulsifying agent, dispersant, wetting agent and oozes
One or more of agent thoroughly；
Described emulsifying agent be selected from OP series phosphate ester (thermally coupled distillation columns), 600#Phosphate ester (phenyl phenol
Polyoxyethylene ether phosphate), styrene polyoxyethylene ether ammonium sulfate salt, alkyl biphenyl ether disulfonic acid magnesium salt, triethanolamine salt, agriculture
Breast 400#(benzyl dimethyl phenol polyoxyethyl ether), Nongru-700#(alkylphenol-formaldehyde resin polyoxyethyl ether), rather breast 36#(benzene second
Base fluosite polyoxyethyl ether), agriculture breast 1600#(phenethyl phenol polyoxyethanyl polypropylene-base ether), oxirane-epoxy third
Alkane block copolymer, OP series (NPE), BY series (castor oil polyoxyethylene ether), agriculture breast 33#(alkyl virtue
Base polyoxyethylene poly-oxygen propylene aether), Span series (sorbitol anhydride monostearate), TWEEN Series (anhydrous sorbitol fat acid ester gather
Oxygen vinyl Ether) or AEO series one of (fatty alcohol-polyoxyethylene ether) or multiple composition mixture.
Described dispersant be selected from polycarboxylate, lignosulfonates, APES formaldehyde condensation products sulfat,
Alkyl benzene calcium sulfonate, naphthalene sulfonic acid-formaldehyde condensation product sodium salt, alkylphenol polyoxyethylene, aliphatic amine polyoxyethylene ether, fatty acid polyglycol
The mixture of one or more of oxygen vinyl Ether or glycerine fatty acid ester APEO composition.
Described wetting agent is selected from sodium lauryl sulphate, dodecylbenzene sodium sulfonate, Nekal BX, wetting and penetrating agent F, soap
The mixture of one or more of angle powder, Bombyx mori L. or spaonin powder composition.
Described penetrating agent is selected from penetrating agent JFC (fatty alcohol-polyoxyethylene ether), penetrant t (diisooctyl maleate
Sulfonate), azone, the mixture of one or more of organosilicon composition.
Described solvent selects dimethylbenzene, toluene, methanol, Ketohexamethylene and N-Methyl pyrrolidone etc..
Described second azoles demodicid mite nitrile active compound is bought from Shenyang Sciencreat Chemicals Co., Ltd.；Etoxazole active compound is from Wuxi Kai Mumaigao
Chemical industry is bought.
According to different use occasions and demand, described composite insecticide also can add antifreezing agent, thickening agent, stabilizer,
The other functions auxiliary agent such as disintegrating agent, defoamer.
Described thickening agent is selected from gelatin, sodium carboxymethyl cellulose, hydroxyethyl cellulose, sodium polyacrylate, modified starch, Huang
The mixture of one or more of virgin rubber, bentonite, silicon dioxide and Magnesiumaluminumsilicate composition.
Described antifreezing agent is selected from the mixture of one or more of ethylene glycol, propylene glycol, glycerol or carbamide composition.
Described defoamer is selected from silicone oil, silicone compound, C10～C20 saturated fat acids compound or C8～C10 fat
The mixture of one or more of fat alcohol compound composition.
Described disintegrating agent is selected from bentonite, carbamide, ammonium sulfate, aluminum chloride, low-substituted hydroxypropyl cellulose, Lactose, Fructus Citri Limoniae
The mixture of one or more of acid, succinic acid or sodium bicarbonate composition.
Described stabilizer is selected from epoxy soybean oil, epoxychloropropane, BHT, ethyl acetate, one kind of triphenyl phosphate or many
Plant the mixture of composition.
In order to reach more preferable insecticidal effect, the compound acaricidal dosage form of the present invention is：Suspending agent, microemulsion or moisture
Shot agent.
The insecticides that the present invention provides are mainly used in preventing and treating red spider on the crops such as Cotton Gossypii, fruit tree, simultaneously for
The mite class producing resistance to conventional pesticides also has good prevention effect.
The present invention has the advantage that and beneficial effect：1st, mite killing scope is wide, lasting period length, low toxicity, noresidue, nuisanceless,
Environmentally safe；2nd, two kinds of acaricides of the present invention are applied in combination, and potentiation is obvious；3rd, two kinds of acaricide combinations of the present invention
Use, the field rate of effective ingredient declines, and reduces production and use cost, reduces pesticide residues and environmental pollution；4th, originally
The acaricide of invention, is made up of the effective ingredient of different mechanism of action, is conducive to overcoming and delay the generation of pest resistance to insecticide；5、
Do not contain organic solvent in the acaricide of the present invention, to crop safety, be the important means of integrated control crop pest.
Specific embodiment
Following examples are used for the present invention is described, but are not limited to the scope of the present invention.Without departing substantially from present invention spirit
In the case of essence, the modification that the inventive method, step or condition are made or replacement, belong to the protection model of the present invention
Enclose.
If not specializing, the conventional meanses that in embodiment, technological means used are well known to those skilled in the art.
In embodiment, percentage ratio is all weight percentage, and the treatment dosage of field efficacy is effective ingredient consumption.
Embodiment 1
A kind of 35% second azoles demodicid mite nitrile etoxazole suspending agent
Raw material：Second azoles demodicid mite nitrile, 20%；Etoxazole, 15%；Dispersant lignin sulfonate, 3%；Dispersant phosphate ester,
2%；Wetting agent dodecylbenzene sodium sulfonate, 1%；Thickening agent selects xanthan gum and aluminium-magnesium silicate, and consumption is respectively 0.12% He
2%；；Antifreeze glycol, 4%；Defoamer silicone, 0.2%；Water, surplus.
Preparation method：In Example formulations ratio, all raw materials (in addition to defoamer) are mixed, clipped rear addition is horizontal
Sand mill carries out 2-3 hour sand milling, adds defoamer to continue shearing, prepared suspending agent product afterwards.Capital equipment have mixer,
Cutter, horizontal sand mill.
Embodiment 2
A kind of 15% second azoles demodicid mite nitrile etoxazole microemulsion
Raw material：Second azoles demodicid mite nitrile, 5%；Etoxazole, 10%；Emulsifying agent selects 600# phosphate ester and Nongru-700 #, and consumption is respectively
For 7% and 8%；Solvent select Ketohexamethylene and N-Methyl pyrrolidone, 8% and 15%；Water, surplus.
Preparation method：By above-mentioned formula proportion, effective ingredient second azoles demodicid mite nitrile is dissolved in a solvent with etoxazole, and at it
Middle addition surfactant, stirring in stirring mixing kettle makes it be in homogeneous oil phase, more slowly stirs lower addition water stirring in thoroughly
Bright state.Stirring mixing kettle can be selected for enamel reaction still, rustless steel stirred tank etc..
Embodiment 3
A kind of 50% second azoles demodicid mite nitrile etoxazole water dispersible granules
Raw material：Second azoles demodicid mite nitrile, 30%；Etoxazole, 20%；Naphthalene sulfonic acid-formaldehyde condensation product sodium salt, 4%；Polycarboxylate, 2%；
Pull open powder, 2；Kieselguhr, 3%；Carbamide, 3%；Attapulgite supplies 100%.
Preparation method：In Example formulations ratio, various raw materials are mixed, Jia 10 after comminution by gas stream～25% water,
Then water dispersible granules product is obtained through kneading, pelletize, drying, screening；Or the powder body pulverized is sprayed in boiling granulator
Water, pelletize, drying, sieve afterwards and product are obtained.Capital equipment has mixer, jet mill, kneader, Squeezinggranulator,
Drying room or fluid bed drying, or boiling granulator, screening machine.
For making technical scheme, purpose and advantage become more apparent, present invention specific examples below
Illustrate, but the present invention is not limited to these examples.The effect experimental of the present invention adopts indoor biometricses and field test phase
In conjunction with mode.
Toxicity Determination
The present invention first passes through Toxicity Determination, and test medicine adopts 95% second azoles demodicid mite nitrile active compound and 96% etoxazole former
Medicine；Test worm is the apple tetranychus from field collection, the first generation deutonymph through indoor feeding breeding hatching.
Test method adopts leaf butterfly nebulization (reference《NY/T 1154.13-2008 farm-chemical indoor determination test rule
Insecticide. the 13rd part：Leaf butterfly nebulization》).Concrete operation method is as follows.
By each single dose and Mixed Pharmacy arrange 5 different Concentraton gradient (on the basis of pilot study result, cotton leaf
Demodicid mite deutonymph mortality rate is pressed geometric progressions in the range of 5%～90% and is set).
Choose the consistent Apple Leaves of growth, make leaf butterfly with card punch, place a wet sponge block in culture dish, thereon
Put filter paper, foliation butterfly on filter paper, every ware puts 2 pieces of leaf butterflies, if select indoor feeding, health, apple tetranychus that age is consistent
Completely it is inoculated on leaf butterfly, every leaf butterfly inoculates 20.
The culture dish being connected to leaf butterfly is placed under potter spray tower, sprays under 50PSI pressure, spray amount is 1ml, sinks
Take out culture dish after fall 1min, then the culture dish processing is put into culture in 12H/12H illumination box, 48h checks dead
Borer population, calculates mortality rate.Often process and set 4 repetitions, and set clear water blank and process.
Carry out statistical analysiss with DPS statistical analysis software, calculate the LC50 of each medicament, the parasite killing to evaluate each medicament is lived
Property.And the co-toxicity coefficient (CTC value) of mixture is calculated according to the abundant method of Sun Yun.
Actual measurement toxicity index (ATI)=(standard agent LC50/ reagent agent LC50) × 100.
Percentage composition+B the medicament toxicity index of A in theoretical toxicity index (TTI)=A medicament toxicity index × mixture × mixed
The percentage composition of B in agent.
Co-toxicity coefficient (CTC)=[mixture actual measurement toxicity index (ATI)/mixture theoretical toxicity index (TTI)] × 100.
Act on the criteria for classifying according to NY/T11547.7-2006 insecticide combination：Co-toxicity coefficient (CTC) >=120 shows as increasing
Effect acts on；Co-toxicity coefficient (CTC)≤80 shows as antagonism；80 ＜ co-toxicity coefficient (CTC) ＜ 120 show as summation action.
Result of the test is shown in Table 1.
Table 1, the second azoles demodicid mite nitrile and etoxazole indoor joint toxicity measuring to apple tetranychus
As it can be seen from table 1 the compositionss of embodiments of the invention have very high activity, especially second azoles demodicid mite nitrile to tetranychid
With etoxazole quality parts ratio be 5: 1～1: 5 in the range of, potentiation becomes apparent from, co-toxicity coefficient (CTC) all 160 with
Above it is seen that second azoles demodicid mite nitrile is compounded with etoxazole has reasonability and feasibility.
Field test prevents and treats the experimental result of European red mite
Test method：This field control effectiveness test sets totally 6 process such as enforcement medicament, contrast agents, clear water, each experimental plot
Area is 50m2, often process 4 repetitions, cell random alignment.It is designed with 0.5m between each cell and around experimental plot to protect
Shield row.Method using artificial spraying carries out dispenser to Cotton Gossypii, and dispenser is investigated 1 time for first 1 day, 3 days after dispenser, 7 days and 14 days each
Investigation 1 time, totally 4 times.Investigation method takes five point sampling and listing mark method.Every cell fixed point 10 plants of Cotton Gossypiis of investigation, every plant
Select 10 blades of different parts listing mark, investigation insect population and remaining borer population, calculate Revision insect recluced rate and prevention effect.Meter
Calculate formula as follows：
Revision insect recluced rate (%)=[borer population before (borer population after borer population-dispenser before dispenser)/dispenser] × 100
Prevention effect (%)=[(treatment region Revision insect recluced rate-blank district Revision insect recluced rate)/(1- blank district
Revision insect recluced rate)] × 100.
The prevention effect to cotton red spider for table 2 different disposal
Show from table 2 result of the test, implement medicament after dispenser and contrast medicine is significantly higher than to the prevention effect of cotton red spider
Agent, after dispenser 14 days, this shows second azoles demodicid mite nitrile and second demodicid mite still more than 93% to implement the prevention effect of medicament cotton red spider
Azoles compounded pesticides have obvious potentiation, and efficiency time is considerably longer than single medicament.Experiment shows, this compounding group
Compound substantially reduces medicament usage amount, decreases production cost, pesticide residues and environmental pollution.In addition, field is seen during test
Examine, embodiment medicament respectively processes medicinal liquid no to be affected on plant growth, to beneficial organism safety around, being compatible with the environment property is good.By
This is visible, and second azoles demodicid mite nitrile and etoxazole are preferable compound acaricide products.
The embodiment above is the optimal embodiment of the present invention, but embodiment of the present invention is not subject to above-mentioned embodiment party
The restriction of case, other any without prejudice under conditions of the principle of the invention, can be real produced by the form of parameter by changing
Apply example, be all contained within protection scope of the present invention.
Claims (10)
1. a kind of compound acaricide is it is characterised in that effective ingredient is second azoles demodicid mite nitrile and etoxazole.
2. compound acaricide according to claim 1 is it is characterised in that described second azoles demodicid mite nitrile with the weight ratio of etoxazole is
30: 1～1: 20.
3. compound acaricide according to claim 2 is it is characterised in that described second azoles demodicid mite nitrile with the weight ratio of etoxazole is
5: 1～1: 5.
4. the compound acaricide according to any one of claim 1-3 is it is characterised in that described second azoles demodicid mite nitrile and etoxazole exist
Weight percentage in compound acaricide is 10%～80%.
5. compound acaricide according to claim 4 is it is characterised in that also include carrier and auxiliary agent.
6. compound acaricide according to claim 5 is it is characterised in that described carrier is water or filler；Described auxiliary agent bag
Include surfactant, described surfactant is one or more of emulsifying agent, dispersant, wetting agent and penetrating agent.
7. compound acaricide according to claim 6 is it is characterised in that described auxiliary agent also includes functional aid, described
Functional aid is one or more of antifreezing agent, thickening agent, stabilizer, disintegrating agent and defoamer.
8. the compound acaricidal dosage form described in a kind of any one according to claim 1-7 is it is characterised in that described dosage form is：Outstanding
Floating agent, microemulsion or water dispersible granules.
9. the compound acaricidal purposes described in a kind of any one according to claim 1-7 is it is characterised in that described compound mite killing
Agent is used for preventing and treating the mite class on Cotton Gossypii, Fructus Mali pumilae, mandarin orange, flowers and vegetable.
10. compound acaricidal purposes according to claim 9 is it is characterised in that described mite class includes tetranychid, beginning leaf
The ovum of demodicid mite, Panonychus citri, Tetranychus urticae, Tetranychus cinnabarinus etc., young demodicid mite, deutonymph with become demodicid mite.
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| CN201610778899.9A CN106417321A (en) | 2016-08-23 | 2016-08-23 | Compound miticide as well as dose form and use thereof |
Applications Claiming Priority (1)
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| CN201610778899.9A CN106417321A (en) | 2016-08-23 | 2016-08-23 | Compound miticide as well as dose form and use thereof |
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