CN102715182A - Sterilization composition containing active components Bellkute and imazalil - Google Patents
Sterilization composition containing active components Bellkute and imazalil Download PDFInfo
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- CN102715182A CN102715182A CN2012101820437A CN201210182043A CN102715182A CN 102715182 A CN102715182 A CN 102715182A CN 2012101820437 A CN2012101820437 A CN 2012101820437A CN 201210182043 A CN201210182043 A CN 201210182043A CN 102715182 A CN102715182 A CN 102715182A
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- mould azoles
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- active component
- bactericidal composition
- fruit
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- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
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- 235000015097 nutrients Nutrition 0.000 description 1
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- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
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Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention provides a sterilization composition containing active components Bellkute and imazalil and relates to the sterilization composition with a synergistic effect. The sterilization composition is applied to the chemical protection field of agricultural plants and the composition has extremely strong antibacterial and sterilizing activities to harmful funguses in agriculture or gardening. The sterilization composition with the synergistic effect contains the active components Bellkute and imazalil. The weight ratio of the active components Bellkute to the imazalil is between (1:20)-(20:1). The weight percentage of the active components Bellkute and imazalil in the sterilization composition is 10-50%. The active components Bellkute and imazalil, a known adjuvant and an excipient are complexed to form any one preparation acceptable by pesticides; and the selected preparation can be wettable powder, aqueous dispersion granule or a suspension agent. The sterilization composition containing the active components Bellkute and imazalil can be applied to preventing and treating germs harms of grains, fruits, vegetables and cash crops.
Description
Technical field
A kind of active component hundred that contains of the present invention can relate to a kind of bactericidal composition with synergistic function with the bactericidal composition that presses down mould azoles; This bactericidal composition is applied to agricultural plant chemoproection field, and said composition shows extremely strong antibiotic and bactericidal activity to harmful fungoid in agricultural or gardening.
Technical background
In recent years, China's fruits and vegetables cultivated area enlarges rapidly, and annual production constantly increases; In the storage transportation that fruits and vegetables are sold from gathering to; Because compound the infecting of multiple fungi can cause that multiple storage disease takes place, and causes to rot in the back of adopting of fruit, vegetables, brings about great losses.So,, fruit, vegetables in time carry out chemicals treatment after gathering, and be to prevent and reduce agricultural product to rot, prolong the effective measures of storage shelf life.
Domestic and international application mainly contains benzimidazole in the fresh-keeping chemical preservative of postharvest fruit and vegetable, sodium ortho-phenylphenate class, biguanides salt, imidazoles etc. at present.Benzimidazole germicide (Te Keduo suspending agent) acts on the tubulin of thalline, plays the effect of sterilization through the mitosis that suppresses fungi.Antimicrobial spectrum is wide, has control, treatment and eradicant action., green mold bacterium blue or green to oranges and tangerines, anthrax bacteria, the resin germ is all effective.But because the action site of medicament is single, germ develops immunity to drugs to this type medicament easily.And it is invalid to black rot, brown rot, sour germ.In oranges and tangerines preservation and freshness practice, use benzimidazole germicide to handle fruit for a long time, the pesticide resistance accumulation of germ is strengthened; Drug effect descends significantly; Some are adopted the important pathogen in back, like head mold, chain lattice spore, epidemic disease is mould, the inhibitory action of rotting also not have that causes such as mould, Mucor.Sodium ortho-phenylphenate since service life for a long time, citrus is blue or green, green mould pesticide resistance also occurred to it.On behalf of kind, imidazoles Prochloraz is arranged and is pressed down mould azoles, effective to penicilliosis, green mould, anthracnose, blossom-end rot and black rot, but invalid to sour rot.Hundred can get; Belonging to the biguanides salt, is a kind of contact killing type protective fungicide, and mainly biosynthesis and the cell membrane function to the lipids of fungi works; Suppress the formation of spore germination, germ tube elongation, appresorium and mycelia, be one type and tag and preventative bactericide.Can effectively prevent and treat citrus powdery mildew, anthracnose, ring spot, scab, leaf spot, spot defoliation.Superior to oranges and tangerines sour rot, blossom-end rot preventive effect, but invalid to black rot.
Since 1993; Press down mould azoles (Wan Lide, it is mould to wear azoles), Prochloraz (Shi Baoke) fruit fresh-keeping particularly the citrus corrosion protection fresh-keeping aspect obtained effect preferably; And this type of antisepsis antistaling agent low price, imidazoles bactericide have become most popular main antisepsis antistaling agent.But in recent years, oranges and tangerines storage period sour rot takes place to increase the weight of year by year, and oranges and tangerines storage period disease to press down mould azoles, Prochloraz has produced certain resistance.Therefore, be badly in need of delaying the oranges and tangerines germ imidazoles bactericide is developed immunity to drugs, solve the problem that the oranges and tangerines sour rot increases the weight of year by year simultaneously, with the problem of guaranteeing that citrusfruit storage safety and numerous citrus farmers' synergy increase income.
Using chemical agent is the most effectively one of means of control phytopathogen.Coming controlling plant diseases with the novel pesticide that does not have cross resistance is a good solution.But, develop a novel pesticide at present and need screen 10,000-1.2 ten thousand compounds, expensive 1.2 hundred million-1.5 hundred million dollars, the construction cycle is 5-10, is difficult to catch up with the speed that pathogen develops immunity to drugs.Other method such as crop allocation are adjusted, different agricultural chemicals is rotated etc., in the process of practical operation, are difficult to really play obvious effects.
Reasonably chemical bactericide is composite or be mixed and have the expansion fungicidal spectrum; Improve control efficiency, prolong the optimum period for applying fertilizer, reduce dosage, reduce poisoning, reduce residual, delay fungi drug resistance and advantages such as drug-fast generation and development, so select suitable bactericide compounded or to be mixed be one of the effective method the most that addresses the above problem.
Exploitation new product bactericide price is constantly soaring, and by contrast, exploitation is efficient with research, low toxicity, low-residual composite be mixed that to have the investment lead time short and receive attention both domestic and external, strengthen the development dynamics one after another.The effective necessary condition of drug combination is not have cross tolerance between the activating agent.
Iminoctadine class and imidazoles bactericide are variant in control spectrum and control efficiency, and the effect characteristics are also different with mechanism.Can also not appear in the newspapers with the combination that presses down mould azoles about hundred.
Summary of the invention
One object of the present invention be to provide a kind of contain active component hundred can with the bactericidal composition that presses down mould azoles, be a kind of contain hundred can with the bactericidal composition that presses down mould azoles with synergistic function.Another object of the present invention provides a kind of method of preventing and treating plant pathogenic fungi, the especially treatment of oranges and tangerines storage period disease, the method for preventing and rooting out.Utilize method of the present invention can realize these and other purpose of the present invention wholly or in part.
A kind of active component hundred that contains can be to take following technical scheme to realize with the bactericidal composition that presses down mould azoles:
A kind of contain active component hundred can with the bactericidal composition that presses down mould azoles, it is characterized in that containing active component hundred can with press down mould azoles.
A kind of contain active component hundred can with the bactericidal composition that presses down mould azoles, it is characterized in that said active component hundred can be 1:20-20:1 with the weight ratio that presses down mould azoles.
A kind of contain active component hundred can with the bactericidal composition that presses down mould azoles, it is characterized in that said active component hundred can be 1:5-5:1. with the weight ratio that presses down mould azoles
A kind of contain active component hundred can with the bactericidal composition that presses down mould azoles, it is characterized in that said active component hundred can be 10-50% with pressing down the weight percentage that mould azoles accounts for composition.
A kind of contain active component hundred can with the bactericidal composition that presses down mould azoles, it is characterized in that said active component hundred can be 20-45% with pressing down the weight percentage that mould azoles accounts for composition.
A kind of contain active component hundred can with the bactericidal composition that presses down mould azoles; Said active component hundred can be re-dubbed any one formulation that allows on the agricultural chemicals with pressing down mould azoles and known auxiliary agent and excipient, and selecting formulation for use is wetting powder, water dispersible granules or suspending agent.
A kind ofly contain the germ disease that active component hundred can be applied to prevent and treat cereal, fruit, vegetables, economic crops with the bactericidal composition that presses down mould azoles.
A kind ofly contain germ (the causing corruption) disease that active component hundred can be applied to prevent and treat the fruit storage phase with the bactericidal composition that presses down mould azoles.
A kind of active component hundred that contains can be applied to prevent and treat oranges and tangerines, apple, banana, mango, the germ of lychee storage phase (causing corruption) disease with the bactericidal composition that presses down mould azoles.
Detailed Description Of The Invention
The present invention provide a kind of contain hundred can with the bactericidal composition that presses down mould azoles with synergistic function.
Pressing down mould azoles is a kind of systemic fungicide with protective effect and therapeutic action, and it is used to control large-scale fungi on fruit, vegetables and ornamental plants, and said fungi comprises mold powder and the plant black spot on the rose on the cucumber.Pressing down mould azoles also is used as seed dressing and is used for the processing afterwards of oranges and tangerines, banana and other fruit harvests rotten with the control storage.The 1-general by name [2-(2,4 dichloro benzene base)-2-(2-acrylic oxygen base) ethyl] that presses down mould azoles]-the 1H-imidazoles, this compound can be expressed from the next
Hundred can get (biguanides three octyl benzene sulfonates), and mainly biosynthesis and the cell membrane function to the lipids of fungi works, and suppresses the formation of spore germination, germ tube elongation, appresorium and mycelia, is one type and tags and preventative bactericide.Can effectively prevent and treat citrus powdery mildew, anthracnose, ring spot, scab, leaf spot, spot defoliation.Superior to oranges and tangerines sour rot, blossom-end rot preventive effect.But it is invalid to black rot.English common name Iminoctadine tris (albesilate), chemical name 1 ' 1-imino group (octyl group methylene) biguanides 3 (alkyl benzene sulfonate)
Hundred can be variant with the control spectrum and the control efficiency that press down mould azoles; The effect special efficacy is also different with mechanism, hundred can with but mould azoles is composite to have an obvious synergistic effect, enlarged fungicidal spectrum simultaneously; Reduced dosage; Reduced spraying times, even the effect of preventing and treating some disease surpasses existing other bactericide, and hundred can and press down between the mould azoles and not have cross resistance.
The present invention provide a kind of have synergistic function contain hundred can with the bactericidal composition that presses down mould azoles.
Concrete scheme of the present invention is: a kind of bactericide pesticide composite of preventing and treating corps diseases, form by following component: press down mould azoles, hundred and can get wetting powder, water dispersible granules or the aqueous suspension agent that bactericide and insecticides adjuvant are formed.
Pressing down mould azoles bactericide and hundred in the composition of the present invention, can to get bactericide be the Synergistic effective dose, and hundred can be 1:20-20:1 with the weight ratio that presses down mould azoles in the present composition, preferred 1:5-5:1.
Active component presses down mould azoles and hundred and can get the 10-50% that bactericide accounts for composition in the composition of the present invention, preferred 20%-45%.
Above-mentioned composition of the present invention can only comprise active ingredient, also can be mixed together use with additive, and therefore composition of the present invention can be prepared into various formulations, for example liquor; Wetting powder, emulsion, water dispersion granule, suspending agent; Pulvis, microcapsules, foaming agent, paste; Granule, tablet, aerosol etc.According to the character of these compositions and use composition the purpose and the ambient conditions that will reach, can select composition is used with spraying, immersion, atomizing, the method for bumping powder, broadcast sowing or pouring etc. and so on.
Can produce these preparations through known method; For example, under the situation of selectively using surfactant,, reactive compound prepares preparation through being mixed with filler; Said filler is the diluent or carrier of liquid or liquid gas or solid; Said surfactant is an emulsifier, dispersant, and/or foam agent.Under the situation of water, also can with an organic solvent for example, organic solvent be used as cosolvent as filler.
Liquid diluent or the carrier that can address are generally: aromatic compound is xylol, toluene or Fluhyzon for example; Chlorination aromatic compound or chlorinated aliphatic be chlorobenzene, vinyl chloride or carrene for example, and aliphatic hydrocarbon is cyclohexane or paraffin petroleum distillate for example for example, mineral and vegetable oil; Alcohol is butanols or ethylene glycol and ether and ester for example; Ketone is acetone, MEK, methyl iso-butyl ketone (MIBK) or cyclohexanone for example, and intensive polar solvent is dimethyl formamide and dimethyl sulfoxide (DMSO) for example, or water.
But as be used for pulvis and dispersible granule; The solid carrier that is fit to is: the natural minerals of ammonium salt and pulverizing for example; For example kaolin, clay, talcum powder, chalk, quartz, attapulgite, montmorillonite or silicate, and the synthetic mineral of pulverizing for example high dispersive silica, aluminium oxide and silicate.
Spendable solid carrier is the particle of natural minerals, like kaolin, and clay, talcum, chalk, quartz, Attagel, imvite or diatomite and synthetic mineral particle, like the silicic acid of high dispersive, aluminium oxide and silicate.
The solid carrier that can be used for granule is to pulverize and the natural rock of classification for example calcite, marble, float stone, sepiolite and dolomite; And inorganic synthetic particle and organic dust; With the particle of organic product, for example sawmilling, coconut husk, corncob and tobacco stem.
The emulsifier that is fit to is: for example nonionic and anion emulsifier, for example polyoxyethylene fatty acid ester, polyoxyethylene aliphatic alcohol ether, alkylaryl polyglycol ether for example, alkylsulfonate, alkyl sulfate, arylsulphonate, or protein hydrolysate.The dispersant that is fit to is: for example lignin sulfite waste liquor and methylcellulose.
Can use for example carboxymethyl cellulose of tackifier in the preparation, and the natural and synthetic polymer of powder, particle or latex form, for example gum Arabic, polyvinyl alcohol and polyvinyl acetate or natural phospholipid, for example cephalin and lecithin, and synthetic phospholipid.Other additive is for being mineral oil and vegetable oil.
Can employable colouring agent such as inorganic pigment, for example, iron oxide, titanium oxide and Prussia are blue, and organic dyestuff, like alizarin dyes, azo dyes or metal phthalein mountain valley with clumps of trees and bamboo dyestuff and trace nutrient, like iron, manganese, boron, ketone, cobalt, molybdenum and zinc salt.
Active compounds of the present invention, they can its dosage forms or use with its type of service, and its type of service prepares through further dilution, like stock solution, emulsion suspension, powder is stuck with paste particle and tablet.Can use these formulations in a usual manner, for example, through pouring, dipping sprays cloth, and spraying is stifling, and immersion liquid suspends, and dressing dusts, and broadcasts sowing, dried dressing, moist dressing, wet type dressing, slurries dressing or involucrum mode.
When on each position that is administered to plant, the concentration of the reactive compound of type of service can change within a large range.Usually, this concentration is by weight 0.0001 to 1%, is preferably by weight 0.001 to 0.5%.
When carrying out seed treatment, the per kilogram seed is used 0.001 usually to 50g, the reactive compound of preferred 0.01 to 10g/1kg seed.
When carrying out soil treatment, the reactive compound that is administered to target usually is the reactive compound of 0.00001 to 0.1% concentration by weight, preferably by weight 0.0001 to 0.02%.
When being used for oranges and tangerines, mango, lichee, banana, apple and adopting the back anti-corrosive fresh-keeping, dilute with water 200-2000 times liquid soaks about one minute drop of fruit and goes out to get final product usually.
A kind of bactericidal composition advantage with synergistic function of the present invention: hundred can be variant with the control spectrum and the control efficiency that press down mould azoles; The effect special efficacy is also different with mechanism, the present invention provide a kind of contain hundred can with but the bactericidal composition with synergistic function of mould azoles.Hundred can with press down that mould azoles is composite to have an obvious role in synergism; Enlarge fungicidal spectrum simultaneously, reduced dosage, reduced spraying times; Even the effect of preventing and treating some disease surpasses existing other bactericide, and hundred can and press down between the mould azoles and not have cross resistance.
Embodiment
Embodiment subsequently will explain the present invention more specifically, but they do not constitute any type of restriction to scope of the present invention.
Formulation prepares embodiment
Embodiment 1 water dispersible granules (gross weight of preparation is 100 parts)
Hundred can get 2.0 weight portions
Press down mould azoles 10.0 weight portions
Polyvinyl alcohol 5.0 weight portions
Sodium Laurylsulfate 7.0 weight portions
Lignosulfonates 11.0 weight portions
The kaolin surplus
Above-mentioned substance is evenly mixed, grinds, mixes suitable quantity of water and granulation, promptly get said preparation after the drying.
Embodiment 2 wetting powders (gross weight of preparation is 100 parts)
Hundred can get 20.0 weight portions
Press down mould azoles 1.0 weight portions
Alkyl polyoxyethylene ether sulfonate 5.0 weight portions
Sodium lignin sulfonate 4.0 weight portions
NONIN HS 240
(8-9 moles of ethylene oxide) 3.0 weight portions
The kaolin surplus
Active ingredient is thoroughly mixed with auxiliary agent, and it is thoroughly ground in suitable mill, promptly obtains wetting powder.
Embodiment 3 suspending agents (gross weight of preparation is 100 parts)
Hundred can get 1.0 weight portions
Press down mould azoles 20.0 weight portions
Propane diols 3.0 weight portions
Lignosulfonates 10.0 weight portions
Sodium Polyacrylate 5.0 weight portions
Octyl phenol polyglycol ether (11-14 moles of ethylene oxide) 5.0 weight portions
Water surplus
The very thin active ingredient of mill is thoroughly mixed with auxiliary agent, promptly obtain suspending agent.
Embodiment 4 water dispersible granules (gross weight of preparation is 100 parts)
Hundred can get 1.0 weight portions
Press down mould azoles 9.0 weight portions
Polyvinyl alcohol 5.0 weight portions
Sodium Laurylsulfate 7.0 weight portions
Lignosulfonates 11.0 weight portions
The kaolin surplus
Above-mentioned substance is evenly mixed, grinds, mixes suitable quantity of water and granulation, promptly get said preparation after the drying.
Embodiment 5 wetting powders (gross weight of preparation is 100 parts)
Hundred can get 20.0 weight portions
Press down mould azoles 2.0 weight portions
Alkyl polyoxyethylene ether sulfonate 5.0 weight portions
Sodium lignin sulfonate 4.0 weight portions
NONIN HS 240
(8-9 moles of ethylene oxide) 3.0 weight portions
The kaolin surplus
Active ingredient is thoroughly mixed with auxiliary agent, and it is thoroughly ground in suitable mill, promptly obtains wetting powder.
Embodiment 6 suspending agents (gross weight of preparation is 100 parts)
Hundred can get 20.0 weight portions
Press down mould azoles 4.0 weight portions
Propane diols 3.0 weight portions
Lignosulfonates 10.0 weight portions
Sodium Polyacrylate 5.0 weight portions
Octyl phenol polyglycol ether (11-14 moles of ethylene oxide) 5.0 weight portions
Water surplus
The very thin active ingredient of mill is thoroughly mixed the suspending agent that promptly obtains with auxiliary agent.
Embodiment 7 water dispersible granules (gross weight of preparation is 100 parts)
Hundred can get 15.0 weight portions
Press down mould azoles 5.0 weight portions
Polyvinyl alcohol 5.0 weight portions
Sodium Laurylsulfate 7.0 weight portions
Lignosulfonates 11.0 weight portions
The kaolin surplus
Above-mentioned substance is evenly mixed, grinds, mixes suitable quantity of water and granulation, promptly get said preparation after the drying.
Embodiment 8 wetting powders (gross weight of preparation is 100 parts)
Hundred can get 15.0 weight portions
Press down mould azoles 30.0 weight portions
Alkyl polyoxyethylene ether sulfonate 5.0 weight portions
Sodium lignin sulfonate 4.0 weight portions
NONIN HS 240
(8-9 moles of ethylene oxide) 3.0 weight portions
The kaolin surplus
Active ingredient is thoroughly mixed with auxiliary agent, and it is thoroughly ground in suitable mill, promptly obtains wetting powder.
Embodiment 9 suspending agents (gross weight of preparation is 100 parts)
Hundred can get 25.0 weight portions
Press down mould azoles 25.0 weight portions
Propane diols 3.0 weight portions
Lignosulfonates 10.0 weight portions
Sodium Polyacrylate 5.0 weight portions
Octyl phenol polyglycol ether (11-14 moles of ethylene oxide) 5.0 weight portions
Water surplus
The very thin active ingredient of mill is thoroughly mixed with auxiliary agent, promptly obtain suspending agent.The application implementation example
Embodiment 1,000 can with press down the synergistic effect of exsomatizing of mould azoles and measure the result
Adopt spray-on process, measure different proportion hundred can with press down the composite indoor virulence of mould azoles to the oranges and tangerines penicilliosis.
Calculate the toxicity index of each medicament and the co-toxicity coefficient of mixture (CTC value) according to the abundant method of Sun Yun, when CTC≤80, then compositions table reveals antagonism; When 80<CTC<120; Then compositions table reveals summation action, and when CTC>=120, then compositions table reveals synergistic effect.
Actual measurement toxicity index (ATI)=(standard medicament EC
50/ confession reagent agent EC
50) X100
The percentage composition of B in percentage composition+B medicament toxicity index X mixture of A in theoretical toxicity index (TTI)=A medicament toxicity index X mixture
Co-toxicity coefficient (CTC)=[mixture actual measurement toxicity index (the ATI)/theoretical toxicity index (TTI) of mixture] X100
Table 1 hundred can with press down mould azoles and different proportioning thereof virulence to oranges and tangerines penicilliosis germ
Experiment shows that pressing down mould azoles and hundred can be mixed, and oranges and tangerines penicilliosis germ is had good indoor virulence.Obvious synergistic effect can be with the ratio that presses down mould azoles be arranged when hundred during at 1:20-20:1.Through being mixed, can reach the effect that reduces cost, improves the medicament activity and delay the generation of pathogen pesticide resistance.
Embodiment 1,100 can with press down the synergistic effect of exsomatizing of mould azoles and measure the result
Adopt spray-on process, measure different proportion hundred can with press down the composite indoor virulence of mould azoles to the citrus anthracnose germ.
Table 2 hundred can with press down mould azoles and different proportioning thereof virulence to the citrus anthracnose germ
Experiment shows that hundred can be mixed with pressing down mould azoles, and the citrus anthracnose germ is had good indoor virulence.Hundred can have obvious synergistic effect to the citrus anthracnose germ with the ratio that presses down mould azoles in the 1:20-20:1 scope.Through being mixed, can reach the effect that reduces cost, improves the medicament activity and delay the generation of pathogen pesticide resistance.
Embodiment 1,200 can with press down the synergistic effect of exsomatizing of mould azoles and measure the result
Adopt spray-on process, measure different proportion hundred can with press down the composite indoor virulence of mould azoles to oranges and tangerines sour rot germ.
Table 3 hundred can with press down mould azoles and different proportioning thereof virulence to oranges and tangerines sour rot germ
Experiment shows that hundred can be mixed with pressing down mould azoles, and oranges and tangerines sour rot germ is had good indoor virulence.Hundred can have obvious synergistic effect to oranges and tangerines sour rot germ with the ratio that presses down mould azoles in the 1:20-20:1 scope.Through being mixed, can reach the effect that reduces cost, improves the medicament activity and delay the generation of pathogen pesticide resistance.
Embodiment 13 oranges and tangerines storage period disease controls test
7 processing are established in experiment, are respectively
40,%00 can get 1000 times of liquid of wetting powder (A), and Tso Tat Co., Ltd., Japan produces, and dragon lantern chemical company in Jiangsu provides;
50% presses down 1000 times of liquid of mould azoles missible oil (B)
Embodiment 1800 times of liquid of 1 medicament (C)
Embodiment 1800 times of liquid of 3 medicaments (D)
Embodiment 1800 times of liquid of 5 medicaments (E)
Embodiment 1800 times of liquid of 7 medicaments (F)
Embodiment 1800 times of liquid of 9 medicaments (G)
Clear water contrast (CK)
More than handle and all add 2,4-D 226mg/kg, fruit picking on November 28 in adorn fruit on December 2,2011 at random and is handled, and each is handled fruit 50kg and calculates each respectively and handle really number, does not establish repetition.Each is handled fruit and fully soaks the corresponding soup of handling respectively, ventilates after 3 days, and each is handled two plastic crates of fruit packing (not making the fruit packing) and deposits in simple and easy warehouse.Preserved 60 days, 100 days, the decayed fruit number was respectively handled in investigation in 120 days, calculated the decayed fruit rate and proofreaied and correct preventive effect.The decayed fruit rate is following with correction preventive effect computational methods:
Decayed fruit rate (%)=decayed fruit number/total fruit number * 100,
Proofread and correct preventive effect (%)=(contrast decayed fruit rate-processing decayed fruit rate)/contrast decayed fruit rate * 100.
Each handles the rotting rate and the preventive effect of different storage fruit
60 days, 100 days, oranges and tangerines storage experiment result showed in 120 days, did short-term (100 days) storage like citrusfruit, and above each treatment formulations preventive effect according to the present invention is all more than 96%; Indefinite or make long term storage like storage period, according to 1800 times of liquid treatment formulations of medicament of the present invention, decayed fruit is few, and preventive effect is high, remains on more than 91%, can guarantee the corrosion-resistanting fresh-keeping effect of oranges and tangerines.
Embodiment 14 apple storage period disease controls test
7 processing are established in experiment, are respectively
40,%00 can get 1000 times of liquid of wetting powder (A), and Tso Tat Co., Ltd., Japan produces, and dragon lantern chemical company in Jiangsu provides;
50% presses down 1000 times of liquid of mould azoles missible oil (B)
Embodiment 1800 times of liquid of 2 medicaments (C)
Embodiment 1800 times of liquid of 4 medicaments (D)
Embodiment 1800 times of liquid of 6 medicaments (E)
Embodiment 1800 times of liquid of 8 medicaments (F)
Embodiment 1800 times of liquid of 9 medicaments (G)
Clear water contrast (CK)
More than handle and all add 2,4-D226mg/kg, fruit picking on November 28 in adorn fruit on December 2,2011 at random and is handled, and each is handled fruit 50kg and calculates each respectively and handle really number, does not establish repetition.Each is handled fruit and fully soaks the corresponding soup of handling respectively, ventilates after 3 days, and each is handled two plastic crates of fruit packing (not making the fruit packing) and deposits in simple and easy warehouse.Preserved 60 days, 100 days, the decayed fruit number was respectively handled in investigation in 120 days, calculated the decayed fruit rate and proofreaied and correct preventive effect.The decayed fruit rate is following with correction preventive effect computational methods:
Decayed fruit rate (%)=decayed fruit number/total fruit number * 100,
Proofread and correct preventive effect (%)=(contrast decayed fruit rate-processing decayed fruit rate)/contrast decayed fruit rate * 100.
Each handles the rotting rate and the preventive effect of different storage fruit
60 days, 100 days, apple storage experiment result showed in 120 days, did short-term (100 days) storage like apple, and above each treatment formulations preventive effect according to the present invention is all more than 97%; Indefinite or make long term storage like storage period, according to 1800 times of liquid treatment formulations of medicament of the present invention, decayed fruit is few, and preventive effect is high, remains on more than 92%, can guarantee the corrosion-resistanting fresh-keeping effect of apple.
Embodiment 15 banana storage phase disease control test
7 processing are established in experiment, are respectively
40,%00 can get 1000 times of liquid of wetting powder (A), and Tso Tat Co., Ltd., Japan produces, and dragon lantern chemical company in Jiangsu provides;
50% presses down 1000 times of liquid of mould azoles missible oil (B)
Embodiment 1800 times of liquid of 2 medicaments (C)
Embodiment 1800 times of liquid of 3 medicaments (D)
Embodiment 1800 times of liquid of 5 medicaments (E)
Embodiment 1800 times of liquid of 8 medicaments (F)
Embodiment 1800 times of liquid of 9 medicaments (G)
Clear water contrast (CK)
More than handle and all add 2,4-D226mg/kg, fruit picking on September 28 in adorn fruit on October 2,2011 at random and is handled, and each is handled fruit 50kg and calculates each respectively and handle really number, does not establish repetition.Each is handled fruit and fully soaks the corresponding soup of handling respectively, ventilates after 3 days, and each is handled two plastic crates of fruit packing (not making the fruit packing) and deposits in simple and easy warehouse.Preserved 60 days, 100 days, the decayed fruit number was respectively handled in investigation in 120 days, calculated the decayed fruit rate and proofreaied and correct preventive effect.The decayed fruit rate is following with correction preventive effect computational methods:
Decayed fruit rate (%)=decayed fruit number/total fruit number * 100,
Proofread and correct preventive effect (%)=(contrast decayed fruit rate-processing decayed fruit rate)/contrast decayed fruit rate * 100.
Each handles the rotting rate and the preventive effect of different storage fruit
60 days, 100 days, apple storage experiment result showed in 120 days, did short-term (100 days) storage like banana, and above each treatment formulations preventive effect according to the present invention is all more than 93%; Indefinite or make long term storage like storage period, according to 1800 times of liquid treatment formulations of medicament of the present invention, decayed fruit is few, and preventive effect is high, remains on more than 90%, can guarantee the corrosion-resistanting fresh-keeping effect of banana.
Embodiment 16 mango storage period disease controls test
7 processing are established in experiment, are respectively
40,%00 can get 1000 times of liquid of wetting powder (A), and Tso Tat Co., Ltd., Japan produces, and dragon lantern chemical company in Jiangsu provides;
50% presses down 1000 times of liquid of mould azoles missible oil (B)
Embodiment 1800 times of liquid of 1 medicament (C)
Embodiment 1800 times of liquid of 2 medicaments (D)
Embodiment 1800 times of liquid of 4 medicaments (E)
Embodiment 1800 times of liquid of 6 medicaments (F)
Embodiment 1800 times of liquid of 8 medicaments (G)
Clear water contrast (CK)
More than handle and all add 2,4-D226mg/kg, fruit picking on July 28 in adorn fruit on September 2,2011 at random and is handled, and each is handled fruit 50kg and calculates each respectively and handle really number, does not establish repetition.Each is handled fruit and fully soaks the corresponding soup of handling respectively, ventilates after 3 days, and each is handled two plastic crates of fruit packing (not making the fruit packing) and deposits in simple and easy warehouse.Preserved 60 days, 100 days, the decayed fruit number was respectively handled in investigation in 120 days, calculated the decayed fruit rate and proofreaied and correct preventive effect.The decayed fruit rate is following with correction preventive effect computational methods:
Decayed fruit rate (%)=decayed fruit number/total fruit number * 100,
Proofread and correct preventive effect (%)=(contrast decayed fruit rate-processing decayed fruit rate)/contrast decayed fruit rate * 100.
Each handles the rotting rate and the preventive effect of different storage fruit
60 days, 100 days, mango storage experiment result showed in 120 days, did short-term (100 days) storage like Mango Fruit, and above each treatment formulations preventive effect according to the present invention is all more than 96%; Indefinite or make long term storage like storage period, according to 1800 times of liquid treatment formulations of medicament of the present invention, decayed fruit is few, and preventive effect is high, remains on more than 91%, can guarantee the corrosion-resistanting fresh-keeping effect of mango.
Embodiment 17 lychee storage phase disease control test
7 processing are established in experiment, are respectively
40,%00 can get 1000 times of liquid of wetting powder (A), and Tso Tat Co., Ltd., Japan produces, and dragon lantern chemical company in Jiangsu provides;
50% presses down 1000 times of liquid of mould azoles missible oil (B)
Embodiment 1800 times of liquid of 1 medicament (C)
Embodiment 1800 times of liquid of 2 medicaments (D)
Embodiment 1800 times of liquid of 4 medicaments (E)
Embodiment 1800 times of liquid of 6 medicaments (F)
Embodiment 1800 times of liquid of 8 medicaments (G)
Clear water contrast (CK)
More than handle and all add 2,4-D226mg/kg, fruit picking on June 28 in adorn fruit on July 2,2011 at random and is handled, and each is handled fruit 20kg and calculates each respectively and handle really number, does not establish repetition.Each is handled fruit and fully soaks the corresponding soup of handling respectively, ventilates after 3 days, and each is handled two plastic crates of fruit packing (not making the fruit packing) and deposits in simple and easy warehouse.Preserved 60 days, 100 days, the decayed fruit number was respectively handled in investigation in 120 days, calculated the decayed fruit rate and proofreaied and correct preventive effect.The decayed fruit rate is following with correction preventive effect computational methods:
Decayed fruit rate (%)=decayed fruit number/total fruit number * 100,
Proofread and correct preventive effect (%)=(contrast decayed fruit rate-processing decayed fruit rate)/contrast decayed fruit rate * 100.
Each handles the rotting rate and the preventive effect of different storage fruit
60 days, 100 days, the lychee storage experimental result showed in 120 days, did short-term (100 days) storage like litchi fruits, and above each treatment formulations preventive effect according to the present invention is all more than 90%; Indefinite or make long term storage like storage period, according to 1800 times of liquid treatment formulations of medicament of the present invention, decayed fruit is few, and preventive effect is high, remains on more than 87%, can guarantee the corrosion-resistanting fresh-keeping effect of lichee.
Embodiment 18 cucumber anthracnoses control test
The employing foliar spray is handled, and begins dispenser in the disease initial stage of origination, 7-10 days checkout facility results behind the medicine.The disease classification of field control effectiveness test, preventive effect computational methods are all carried out State Standard of the People's Republic of China's " pesticide field efficacy medicine test criterion ".Experimental result: apparently higher than two single agent of contrast, have synergistic effect clearly according to the field efficacy of medicament of the present invention.
7 processing are established in experiment, are respectively
40,%00 can get 500 times of liquid of wetting powder (A), and Tso Tat Co., Ltd., Japan produces, and dragon lantern chemical company in Jiangsu provides;
50% presses down 500 times of liquid of mould azoles missible oil (B)
Embodiment 500 times of liquid of 1 medicament (C)
Embodiment 800 times of liquid of 3 medicaments (D)
Embodiment 800 times of liquid of 5 medicaments (E)
Embodiment 800 times of liquid of 7 medicaments (F)
Embodiment 800 times of liquid of 9 medicaments (G)
Clear water contrast (CK)
Be respectively 93.55%, 93.9%, 93.55%, 93.00 and 94.1 according to 7 days preventive effect behind agricultural chemicals embodiment 1,3,5,7 of the present invention and the 9 medicament 400g/ha control cucumber anthracnose medicine; 10 days preventive effect is respectively 87.46%, 90.83% behind the medicine, and 89.91%, 90.52% and 90.83%, equal preventive effects when bactericidal composition of the present invention two active ingredients of higher dosage are done single agent respectively.Result of the test shows: use composition of the present invention, its control efficiency has been used tangible synergistic effect separately with respect to two components.
Claims (9)
- One kind contain active component hundred can with the bactericidal composition that presses down mould azoles, it is characterized in that: contain active component hundred can with press down mould azoles.
- 2. bactericidal composition according to claim 1 is characterized in that: said active component hundred can be 1:20-20:1 with the weight ratio that presses down mould azoles.
- 3. bactericidal composition according to claim 1 is characterized in that: said active component hundred can be 1:5-5:1 with the weight ratio that presses down mould azoles.
- 4. bactericidal composition according to claim 1 is characterized in that: said active component hundred can be 10-50% with pressing down the weight percentage that mould azoles accounts for bactericidal composition.
- 5. according to claim 1 or 4 described bactericidal compositions, it is characterized in that: said active component hundred can be 20-45% with pressing down the weight percentage that mould azoles accounts for bactericidal composition.
- 6. bactericidal composition according to claim 1; It is characterized in that: said active component hundred can be re-dubbed any one formulation that allows on the agricultural chemicals with pressing down mould azoles and known auxiliary agent and excipient, and selecting formulation for use is wetting powder, water dispersible granules or suspending agent.
- 7. the described a kind of active component hundred that contains of claim 1 can be applied to prevent and treat fruit, the harm of vegetables germ with the bactericidal composition that presses down mould azoles.
- 8. a kind of active component hundred that contains according to claim 7 can be applied to prevent and treat the germ harm of fruit storage phase with the bactericidal composition that presses down mould azoles.
- 9. according to Claim 8 a kind of contained active component hundred and can be applied to prevent and treat oranges and tangerines, apple, banana, mango, the harm of the germ of lychee storage phase with the bactericidal composition that presses down mould azoles.
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| CN103563997A (en) * | 2013-06-06 | 2014-02-12 | 浙江大学 | Chemical bactericide containing bio-control yeast and used for controlling citrus postharvest diseases |
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| CN103229777A (en) * | 2013-05-08 | 2013-08-07 | 陕西农心作物科技有限公司 | Pyraclostrobin-containing sterilization composition |
| CN103229777B (en) * | 2013-05-08 | 2014-11-12 | 陕西农心作物科技有限公司 | Pyraclostrobin-containing sterilization composition |
| CN103563997A (en) * | 2013-06-06 | 2014-02-12 | 浙江大学 | Chemical bactericide containing bio-control yeast and used for controlling citrus postharvest diseases |
| CN103563997B (en) * | 2013-06-06 | 2015-08-05 | 浙江大学 | The chemical bactericide for controlling oranges and tangerines postharvest disease containing bio-control yeast |
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