CN105340922A - Insecticide composition containing benclothiaz and abamectin - Google Patents
Insecticide composition containing benclothiaz and abamectin Download PDFInfo
- Publication number
- CN105340922A CN105340922A CN201510922200.7A CN201510922200A CN105340922A CN 105340922 A CN105340922 A CN 105340922A CN 201510922200 A CN201510922200 A CN 201510922200A CN 105340922 A CN105340922 A CN 105340922A
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- Prior art keywords
- benclothiaz
- avermectin
- pesticidal combination
- pesticide
- abamectin
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
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- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention relates to an insecticide composition containing benclothiaz and abamectin. The insecticide composition contains active components of the benclothiaz and abamectin and the balance of auxiliary components for preparing a pesticide formulation, wherein the weight part ratio of the active components of benclothiaz to abamectin is (3 to 30):(5 to 0.1), the total weight parts of the active components account for 1 percent to 30 percent of the total weight parts of the formulation, and the insecticide composition can be prepared into the pesticide formulations of wettable powder, suspending agents, dissoluble liquid, emulsion in water and water dispersible granules. The composition can be prepared into preparations applicable to agricultural application, and has obvious synergistic effect; the insecticidal spectrum is enlarged, the amount of pesticides is reduced, the control efficiency is improved, the residues are few, the lasting period is long, the generation of drug resistance of injurious insects is delayed, and the environment protection is benefited.
Description
Technical field
The present invention relates to technical field of pesticide combination, be specifically related to a kind of Pesticidal combination containing benclothiaz and Avermectin.
Background technology
Benclothiaz is considered to nematocide usually, thinks the highest to nematode activity, and since compound structure is announced, seldom see the activity research to other field or other insects, the more rare application in agriculture chemical compounding field, its chemical structural formula is as follows:
。
Avermectin, English common name abamectin is a kind of macrolide disaccharide compounds, is isolated biopesticide from edaphon.It has tags and stomach poison function have faint fumigation action, without systemic action, has very strong osmosis to plant leaf blade, can kill insect under epidermis, and the lasting period is long.Its mechanism of action is different from chemical insecticide, and its interference neurophysiology is movable, stimulates release γ-aminobutyric acid.Thus Avermectin is widely used in and pest control with insecticide pesticide compositional, to expand insecticidal spectrum, improve drug effect and reduce costs.It can be used for preventing and treating various pests, the insects such as various insects, pear sucker, cabbage caterpillar, diamond-back moth, beet armyworm, apple leaf miner, leaf miner, Liriomyza, Americal rice leaf miner and vegetables trialeurodes vaporariorum.Especially special efficacy is had to root-knot nematode.But Avermectin is through extensive application in recent years, and insecticidal effect obviously declines.
The insecticide that Long-Time Service is single, insect is easy to develop immunity to drugs, and pesticide dosage is increased, and cause the adverse consequencess such as high poison, consumption are large, residual many, drug effect is poor, and effect field is more single.And research and develop the agricultural chemical compound that seems, then the R&D cycle is long, and screening compounds arrangement works is very numerous and diverse, and non-general research and development institution can bear.But the different mechanism of action and without the insecticide rational mixture by a certain percentage of cross resistance, crop disease prevention effect can be improved, reduce dosage, residual few, reduce environmental pollution, effectively reducing the pesticide resistance of crop, is the study hotspot of current medium and small research and development institution.
Summary of the invention
According to the deficiencies in the prior art; the present invention proposes a kind of Pesticidal combination containing benclothiaz and Avermectin; said composition contains benclothiaz and Avermectin two kinds of effective active components, and can be prepared into the preparation being suitable for agricultural application, and this Pesticidal combination has notable synergistic effect; expand insecticidal spectrum; decrease pesticide volume, improve preventive effect, residual few; lasting period is long, and the pesticide resistance being conducive to delaying insect produces and environmental protection.
The application is a kind of Pesticidal combination containing benclothiaz and Avermectin, its feature is that in this Pesticidal combination, active component is benclothiaz and Avermectin, all the other are the auxiliary element of the preparation formulations of pesticide, and wherein the ratio of weight and number of active component benclothiaz and Avermectin is 3 ~ 30: 5 ~ 0.1.
In above-described Pesticidal combination, the ratio of weight and number of active component benclothiaz and Avermectin is 5 ~ 20: 3 ~ 0.1.
The formulations of pesticide that above-described Pesticidal combination can be prepared into are wetting powder, suspending agent, soluble liquid, aqueous emulsion and water dispersible granules.
In the above the application's formulations of pesticide, active component total weight parts accounts for 1% ~ 30% of formulation total weight parts.
In the above the application's formulations of pesticide, active component total weight parts accounts for 5% ~ 20% of formulation total weight parts.
This Pesticidal combination of the application may be used for preventing and treating paddy rice, cotton, wheat, fruit tree, the aphid section on vegetables, Aleyrodidae, Cicadellidae, Delphacidae insect, and nematode, acarid, the various pests such as the especially various snout moth's larva of rice, pear sucker, cabbage caterpillar, diamond-back moth, beet armyworm, apple leaf miner, leaf miner, Liriomyza, Americal rice leaf miner, vegetables trialeurodes vaporariorum root-knot nematode, acarid have efficient effect.
When the application's Pesticidal combination is prepared as wetting powder, the parts by weight of each component are:
Benclothiaz3 ~ 30 part
Avermectin 0.1 ~ 5 part
Dispersant 1 ~ 6 part
Wetting agent 1 ~ 8 part
Filler 40 ~ 70 parts.
The concrete procedure of processing of this Pesticidal combination wetting powder is: by above-mentioned formula by benclothiaz and Avermectin and the mixing of dispersant, wetting agent and filler, uniform stirring in stirred tank, mixing after airslide disintegrating mill, namely can be made into the wetting powder of the present composition.
When the application's Pesticidal combination is prepared as suspending agent, the parts by weight of each component are:
Benclothiaz3 ~ 30 part
Avermectin 0.1 ~ 5 part
Dispersant 2 ~ 7 parts
Antifreezing agent 1 ~ 4 part
Thickener 0.1 ~ 4 part
Defoamer 0.1 ~ 1 part
Water surplus.
The concrete production stage of this suspending agent is for first to mix other auxiliary agents, mix through high speed shear, add benclothiaz and Avermectin, abrading-ball 2 ~ 3 hours in ball crusher, make a diameter all at below 5mm, the aqueous suspension formulations of obtained Pesticidal combination described in the application.
When the application's Pesticidal combination is prepared as aqueous emulsion, the parts by weight of each component are:
Benclothiaz3 ~ 30 part
Avermectin 0.1 ~ 5 part
Emulsifier 3 ~ 5 parts
Solvent 3 ~ 8 parts
Stabilizing agent 2 ~ 4 parts
Antifreezing agent 1 ~ 6 part
Defoamer 0.1 ~ 8 part
Thickener 0.2 ~ 2 part
Water surplus.
The concrete production stage of this aqueous emulsion is: first former medicine benclothiaz and Avermectin, solvent and emulsifier, cosolvent are added together, and makes to be dissolved into uniform oil phase; By part water, antifreeze, other the insecticides adjuvant such as antimicrobial mixes uniformly aqueous phase; While high-speed stirred, oil phase is added aqueous phase in a kettle., slowly add water until reach phase inversion point, open clipper and carry out high speed shear, and add remaining water, shear about half an hour, form the aqueous emulsion of oil-in-water type.
When the application's Pesticidal combination is prepared as water dispersible granules, the parts by weight of each component are:
Benclothiaz3 ~ 30 part
Avermectin 0.1 ~ 5 part
Dispersant 3 ~ 8 parts
Wetting agent 3 ~ 9 parts
Disintegrant 2 ~ 8 parts
Filler 40 ~ 70 parts.
The concrete procedure of processing of this Pesticidal combination water dispersible granules is: benclothiaz, Avermectin and dispersant, wetting agent, disintegrant and filler are mixed by above-mentioned formula, pulverize with micro jet, through mediating, then add in fluidized-bed granulation dryer and carry out through sample analysis after granulation, drying, screening, be i.e. the water dispersible granules of obtained Pesticidal combination.
Described emulsifier is selected from the mixture that calcium dodecyl benzene sulfonate and aliphatic acid polyethenoxy ether form.
Described solvent is methyl alcohol.
Described dispersant is selected from lignosulfonates.
Described wetting agent is selected from the one in lauryl sodium sulfate, spaonin powder.
Described disintegrant is selected from the one in bentonite, aluminium chloride.
Described thickener is selected from the one in xanthans, CMC, hydroxyethylcellulose, methylcellulose.
Described stabilizing agent is selected from the one in sodium citrate, resorcinol.
Described antifreezing agent is selected from the one in ethylene glycol, propane diols, glycerine.
Described defoamer is selected from silicone oil, silicone compound, C
10-20saturated fat acid compounds, C
8-10one in aliphatic alcohols compound.
Described filler is selected from the one in kaolin, diatomite, bentonite, attapulgite, white carbon, starch, precipitated calcium carbonate.
In addition, the Pesticidal combination of the application compares similar medicament also has other obvious advantages a lot, the first, compares single dose sphere of action wider, can expand insecticidal spectrum; The second, greatly delay the generation of pest resistance to insecticide, decreased agricultural chemicals Reusability number of times, reduce Pesticide use amount, reduce agricultural cost; 3rd, the residual quantity of this Pesticidal combination is lower, more friendly to environment, is significant to the increasing both production and income of agricultural region.
Embodiment:
Clearly understand to make object of the present invention, technical scheme and advantage; the following specific embodiment of the present invention is described; following examples are the preferred embodiment of the application, do not represent only test example, and the application's protection domain is as the criterion with claims.
Indoor biometrics screening and field experiment:
The method that the present invention adopts indoor bioassay and field trial to combine.If no special instructions, the ratio (comprising percentage) below mentioned is all ratio of weight and number.
Determination of activity example 1:
(1) reagent agent
The former medicine of benclothiaz, Syngenta Co., Ltd, the former medicine of Avermectin, Qingdao KYX Chemical Co., Ltd. provides.
(2) for examination worm source
Indoor diamondback moth larvae of for many generations raising, indoor conditions: temperature (26 ± 2)
oc, relative moisture 68% ± 5%, periodicity of illumination 16/8h (L/D).
(3) single dose assay method
Adopt dip method respectively two groups of former medicines all to be used a small amount of acetone solution, then be diluted to into the dense solution of 5 of equal difference with the Tween solution of 0.1%, be diluted in for subsequent use in beaker, and with clear water in contrast.
Diamondback moth larvae of the same size is flooded 5S in the liquid of leaching worm cage, and being placed on diameter after sucking unnecessary liquid is in the culture dish of 9cm, is placed with fresh vegetable leaf and adds a cover in ware.Every concentration process 10, repeats 4 times, if blank.Check lethality keep 24h in (27 ± 1) DEG C illumination box after, it is dead for touching polypide nonresponder by pulling needle.Lethality Abbott formula correction, then according to log concentration---lethality probit value analyzes (Bliss) method, obtains virulence regression equation and puts dead middle amount LC
50value.
(4) the joint toxicity measuring method of different ratio
According to the toxicity test result of single dose, by active ingredient ratio of weight and number benclothiaz: Avermectin is respectively 17:0.1,15:0.5,13:1,11:2,9:3.
Adopt above-mentioned 1.3 methods to carry out toxicity test, calculate LC
50, and press abundant method calculating co-toxicity coefficient (CTC) of Sun Yun.
(5) toxicity test result and analysis
The indoor measurement result of table 1benclothiaz, Abamectin on Plutella
As can be seen from the table, in the mixture of different proportion, its co-toxicity coefficient is all greater than 120, shows certain synergistic effect, wherein benclothiaz: Avermectin be 15: 0.5 synergistic effect the most obvious, co-toxicity coefficient is 190.32.Result of the test shows, Avermectin, benclothiaz two kinds of medicaments all have higher activity to diamond-back moth in room conditions, the result of the test of different proportion proportioning shows, by active ingredient benclothiaz: when Avermectin is 17:0.1,15:0.5,13:1,11:2,9:3, all show stronger synergistic effect, wherein with benclothiaz: when Avermectin is 15: 0.5, synergistic effect is best.Suggestion carries out further field control effectiveness test to the mixture preparation of suitable proportion about 15:0.5 scope, to evaluate its field practical application effect.
Field experiment: field experiment control wild cabbage damage by disease and insect
(1) test method
Test sprays medicine 1 time altogether, and the dispenser date is June 5.Now wild cabbage not yet balling, diamondback moth larvae major part was in for 2 ~ 3 length of times, and during spray medicine, weather is cloudy calm, and with sharp agriculture board level pressure knapsack hand sprayer to each process even spraying, leave dual sides all requires to be sprayed with effect liquid, every community liquid 2L.
Investigate each community and fix 15 strain wild cabbages as investigation strain, record the larva quantity on whole blade, before spraying medicine, investigate insect population radix, respectively 3,7 days and investigation in 10 days borer population alive after spray medicine.This test investigates 3 times altogether.
After dispenser, continuous 10d estimates medicament does not have poisoning to produce to crop, wild cabbage well-grown.
(2) field control effectiveness test result of the test
Table 2 treatment agent control diamond-back moth field control effectiveness test result
As can be seen from Table 2, the successful of the mixture combination control diamond-back moth of 15%benclothiaz+0.5% Avermectin is better than 1.8% Avermectin EC and contrasts single dose, 15.5%benclothiaz Avermectin insecticidal effect of 10 days after medicine is respectively 92.14%, 93.38% and 93.75%, insecticidal effect increases progressively along with the increase of consumption, estimate according to field, substantially disease is not had with the wild cabbage of 15.5%benclothiaz Avermectin, and growth fraction is more vigorous, and the wild cabbage of 1.8% Avermectin EC single dose occurs that disease is more, the disease plant much about about 10% of ratio complex preparation.
In addition within the scope of test dose, plant growth is normal, and the poisoning phenomenon to wild cabbage does not all appear in each treatment agent, illustrates that it is safe to wild cabbage.
Claims (7)
1. one kind contains the Pesticidal combination of benclothiaz and Avermectin, it is characterized in that: in this Pesticidal combination, active component is benclothiaz and Avermectin, all the other are the auxiliary element of the preparation formulations of pesticide, and wherein the ratio of weight and number of active component benclothiaz and Avermectin is 3 ~ 30: 5 ~ 0.1.
2. a kind of Pesticidal combination containing benclothiaz and Avermectin according to claim 1, is characterized in that: in described Pesticidal combination, the ratio of weight and number of active component benclothiaz and Avermectin is 5 ~ 20: 3 ~ 0.1.
3. a kind of Pesticidal combination containing benclothiaz and Avermectin according to claim 1 and 2, is characterized in that: the formulations of pesticide that described Pesticidal combination can be prepared into are wetting powder, suspending agent, soluble liquid, aqueous emulsion and water dispersible granules.
4. a kind of Pesticidal combination containing benclothiaz and Avermectin according to claim 3, is characterized in that: in the formulations of pesticide, active component benclothiaz and Avermectin total weight parts account for 1% ~ 30% of formulation total weight parts.
5. a kind of Pesticidal combination containing benclothiaz and Avermectin according to claim 1 or 2 or 4, is characterized in that: in the formulations of pesticide, active component benclothiaz and Avermectin total weight parts account for 5% ~ 20% of formulation total weight parts.
6. a kind of Pesticidal combination containing benclothiaz and Avermectin according to claim 1 or 2 or 4, is characterized in that: this Pesticidal combination may be used for preventing and treating the insect on paddy rice, cotton, wheat, fruit tree, vegetables.
7. a kind of Pesticidal combination containing benclothiaz and Avermectin according to claim 6, is characterized in that: the insect that this Pesticidal combination may be used for preventing and treating is aphid section, Aleyrodidae, Cicadellidae, Delphacidae insect, and nematode, acarid.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510922200.7A CN105340922A (en) | 2015-12-14 | 2015-12-14 | Insecticide composition containing benclothiaz and abamectin |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510922200.7A CN105340922A (en) | 2015-12-14 | 2015-12-14 | Insecticide composition containing benclothiaz and abamectin |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5447945A (en) * | 1990-04-23 | 1995-09-05 | Ciba-Geigy Corporation | Nematicidal compositions |
| CN101156580A (en) * | 2007-11-20 | 2008-04-09 | 张少武 | Abmectin-acetamiprid pesticide composition |
| CN102365969A (en) * | 2011-09-30 | 2012-03-07 | 山东京蓬生物药业股份有限公司 | Synergetic insecticidal composition containing clothianidin and abamectin |
| CN102415400A (en) * | 2010-09-28 | 2012-04-18 | 南京华洲药业有限公司 | Composite pesticidal composition containing dinotefuran and abamectin and application thereof |
-
2015
- 2015-12-14 CN CN201510922200.7A patent/CN105340922A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5447945A (en) * | 1990-04-23 | 1995-09-05 | Ciba-Geigy Corporation | Nematicidal compositions |
| CN101156580A (en) * | 2007-11-20 | 2008-04-09 | 张少武 | Abmectin-acetamiprid pesticide composition |
| CN102415400A (en) * | 2010-09-28 | 2012-04-18 | 南京华洲药业有限公司 | Composite pesticidal composition containing dinotefuran and abamectin and application thereof |
| CN102365969A (en) * | 2011-09-30 | 2012-03-07 | 山东京蓬生物药业股份有限公司 | Synergetic insecticidal composition containing clothianidin and abamectin |
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Application publication date: 20160224 |