CN105746521A - Chromafenozid-containing biogenic pesticide composition - Google Patents
Chromafenozid-containing biogenic pesticide composition Download PDFInfo
- Publication number
- CN105746521A CN105746521A CN201610087542.6A CN201610087542A CN105746521A CN 105746521 A CN105746521 A CN 105746521A CN 201610087542 A CN201610087542 A CN 201610087542A CN 105746521 A CN105746521 A CN 105746521A
- Authority
- CN
- China
- Prior art keywords
- pleocidin
- lice sulfanilamide
- fluorine lice
- benzoate
- emamectin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 88
- 239000000575 pesticide Substances 0.000 title claims abstract description 43
- 230000000035 biogenic effect Effects 0.000 title claims abstract description 8
- 239000000839 emulsion Substances 0.000 claims abstract description 42
- 239000000375 suspending agent Substances 0.000 claims abstract description 41
- 239000000725 suspension Substances 0.000 claims abstract description 38
- 241000607479 Yersinia pestis Species 0.000 claims abstract description 28
- 239000003094 microcapsule Substances 0.000 claims abstract description 28
- 239000004562 water dispersible granule Substances 0.000 claims abstract description 25
- 239000004530 micro-emulsion Substances 0.000 claims abstract description 18
- FDDDEECHVMSUSB-UHFFFAOYSA-N sulfanilamide Chemical compound NC1=CC=C(S(N)(=O)=O)C=C1 FDDDEECHVMSUSB-UHFFFAOYSA-N 0.000 claims description 468
- 229940124530 sulfonamide Drugs 0.000 claims description 468
- 241001674048 Phthiraptera Species 0.000 claims description 239
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims description 236
- 229910052731 fluorine Inorganic materials 0.000 claims description 236
- 239000011737 fluorine Substances 0.000 claims description 236
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 138
- 239000003795 chemical substances by application Substances 0.000 claims description 36
- 230000000694 effects Effects 0.000 claims description 18
- 241000500437 Plutella xylostella Species 0.000 claims description 16
- 241000256259 Noctuidae Species 0.000 claims description 13
- 241000008892 Cnaphalocrocis patnalis Species 0.000 claims description 11
- 241001414989 Thysanoptera Species 0.000 claims description 11
- 241001124076 Aphididae Species 0.000 claims description 8
- 241000256135 Chironomus thummi Species 0.000 claims description 8
- 241001498622 Cixius wagneri Species 0.000 claims description 8
- 241000254171 Curculionidae Species 0.000 claims description 8
- 241000258937 Hemiptera Species 0.000 claims description 8
- 241000254043 Melolonthinae Species 0.000 claims description 8
- 241000255969 Pieris brassicae Species 0.000 claims description 8
- 239000000126 substance Substances 0.000 claims description 8
- 210000004894 snout Anatomy 0.000 claims description 7
- 241000426497 Chilo suppressalis Species 0.000 claims description 6
- 241000255588 Tephritidae Species 0.000 claims description 6
- 235000020971 citrus fruits Nutrition 0.000 claims description 6
- CXEGAUYXQAKHKJ-NSBHKLITSA-N emamectin B1a Chemical compound C1=C[C@H](C)[C@@H]([C@@H](C)CC)O[C@]11O[C@H](C\C=C(C)\[C@@H](O[C@@H]2O[C@@H](C)[C@H](O[C@@H]3O[C@@H](C)[C@H](NC)[C@@H](OC)C3)[C@@H](OC)C2)[C@@H](C)\C=C\C=C/2[C@]3([C@H](C(=O)O4)C=C(C)[C@@H](O)[C@H]3OC\2)O)C[C@H]4C1 CXEGAUYXQAKHKJ-NSBHKLITSA-N 0.000 abstract description 123
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 46
- 239000005660 Abamectin Substances 0.000 abstract description 26
- 230000002195 synergetic effect Effects 0.000 abstract description 20
- 239000004563 wettable powder Substances 0.000 abstract description 19
- IBSREHMXUMOFBB-JFUDTMANSA-N 5u8924t11h Chemical compound O1[C@@H](C)[C@H](O)[C@@H](OC)C[C@@H]1O[C@@H]1[C@@H](OC)C[C@H](O[C@@H]2C(=C/C[C@@H]3C[C@@H](C[C@@]4(O3)C=C[C@H](C)[C@@H](C(C)C)O4)OC(=O)[C@@H]3C=C(C)[C@@H](O)[C@H]4OC\C([C@@]34O)=C/C=C/[C@@H]2C)/C)O[C@H]1C.C1=C[C@H](C)[C@@H]([C@@H](C)CC)O[C@]11O[C@H](C\C=C(C)\[C@@H](O[C@@H]2O[C@@H](C)[C@H](O[C@@H]3O[C@@H](C)[C@H](O)[C@@H](OC)C3)[C@@H](OC)C2)[C@@H](C)\C=C\C=C/2[C@]3([C@H](C(=O)O4)C=C(C)[C@@H](O)[C@H]3OC\2)O)C[C@H]4C1 IBSREHMXUMOFBB-JFUDTMANSA-N 0.000 abstract description 18
- 229950008167 abamectin Drugs 0.000 abstract description 18
- JFLRKDZMHNBDQS-UCQUSYKYSA-N CC[C@H]1CCC[C@@H]([C@H](C(=O)C2=C[C@H]3[C@@H]4C[C@@H](C[C@H]4C(=C[C@H]3[C@@H]2CC(=O)O1)C)O[C@H]5[C@@H]([C@@H]([C@H]([C@@H](O5)C)OC)OC)OC)C)O[C@H]6CC[C@@H]([C@H](O6)C)N(C)C.CC[C@H]1CCC[C@@H]([C@H](C(=O)C2=C[C@H]3[C@@H]4C[C@@H](C[C@H]4C=C[C@H]3C2CC(=O)O1)O[C@H]5[C@@H]([C@@H]([C@H]([C@@H](O5)C)OC)OC)OC)C)O[C@H]6CC[C@@H]([C@H](O6)C)N(C)C Chemical compound CC[C@H]1CCC[C@@H]([C@H](C(=O)C2=C[C@H]3[C@@H]4C[C@@H](C[C@H]4C(=C[C@H]3[C@@H]2CC(=O)O1)C)O[C@H]5[C@@H]([C@@H]([C@H]([C@@H](O5)C)OC)OC)OC)C)O[C@H]6CC[C@@H]([C@H](O6)C)N(C)C.CC[C@H]1CCC[C@@H]([C@H](C(=O)C2=C[C@H]3[C@@H]4C[C@@H](C[C@H]4C=C[C@H]3C2CC(=O)O1)O[C@H]5[C@@H]([C@@H]([C@H]([C@@H](O5)C)OC)OC)OC)C)O[C@H]6CC[C@@H]([C@H](O6)C)N(C)C JFLRKDZMHNBDQS-UCQUSYKYSA-N 0.000 abstract description 4
- 239000005930 Spinosad Substances 0.000 abstract description 4
- 229940014213 spinosad Drugs 0.000 abstract description 4
- 230000007613 environmental effect Effects 0.000 abstract description 3
- 241001465754 Metazoa Species 0.000 abstract description 2
- 239000005929 Spinetoram Substances 0.000 abstract description 2
- GOENIMGKWNZVDA-OAMCMWGQSA-N Spinetoram Chemical compound CO[C@@H]1[C@H](OCC)[C@@H](OC)[C@H](C)O[C@H]1OC1C[C@H]2[C@@H]3C=C4C(=O)[C@H](C)[C@@H](O[C@@H]5O[C@H](C)[C@H](CC5)N(C)C)CCC[C@H](CC)OC(=O)CC4[C@@H]3CC[C@@H]2C1 GOENIMGKWNZVDA-OAMCMWGQSA-N 0.000 abstract description 2
- 239000004480 active ingredient Substances 0.000 abstract 6
- 231100000674 Phytotoxicity Toxicity 0.000 abstract 1
- 239000000853 adhesive Substances 0.000 abstract 1
- 230000001070 adhesive effect Effects 0.000 abstract 1
- 238000002360 preparation method Methods 0.000 abstract 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 44
- 241000238631 Hexapoda Species 0.000 description 41
- 238000012360 testing method Methods 0.000 description 40
- 239000008367 deionised water Substances 0.000 description 39
- 229910021641 deionized water Inorganic materials 0.000 description 39
- 239000003814 drug Substances 0.000 description 35
- 238000013329 compounding Methods 0.000 description 29
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 24
- WSFSSNUMVMOOMR-UHFFFAOYSA-N formaldehyde Substances O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 24
- 241000209094 Oryza Species 0.000 description 18
- 235000007164 Oryza sativa Nutrition 0.000 description 18
- 235000009566 rice Nutrition 0.000 description 18
- -1 Ester disaccharide compounds Chemical class 0.000 description 16
- 230000003449 preventive effect Effects 0.000 description 16
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 15
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 15
- CGQCWMIAEPEHNQ-UHFFFAOYSA-N Vanillylmandelic acid Chemical compound COC1=CC(C(O)C(O)=O)=CC=C1O CGQCWMIAEPEHNQ-UHFFFAOYSA-N 0.000 description 14
- 238000000034 method Methods 0.000 description 14
- 229920001296 polysiloxane Polymers 0.000 description 13
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 11
- 150000001298 alcohols Chemical class 0.000 description 11
- 150000001875 compounds Chemical class 0.000 description 11
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 10
- 239000002253 acid Substances 0.000 description 10
- 239000007859 condensation product Substances 0.000 description 10
- 229920001568 phenolic resin Polymers 0.000 description 10
- 230000008569 process Effects 0.000 description 10
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 9
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 9
- 239000000843 powder Substances 0.000 description 9
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 8
- RRZXIRBKKLTSOM-XPNPUAGNSA-N avermectin B1a Chemical compound C1=C[C@H](C)[C@@H]([C@@H](C)CC)O[C@]11O[C@H](C\C=C(C)\[C@@H](O[C@@H]2O[C@@H](C)[C@H](O[C@@H]3O[C@@H](C)[C@H](O)[C@@H](OC)C3)[C@@H](OC)C2)[C@@H](C)\C=C\C=C/2[C@]3([C@H](C(=O)O4)C=C(C)[C@@H](O)[C@H]3OC\2)O)C[C@H]4C1 RRZXIRBKKLTSOM-XPNPUAGNSA-N 0.000 description 8
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 8
- 239000000470 constituent Substances 0.000 description 8
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 8
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 8
- 230000002265 prevention Effects 0.000 description 8
- 231100000820 toxicity test Toxicity 0.000 description 8
- 239000005995 Aluminium silicate Substances 0.000 description 7
- 235000006008 Brassica napus var napus Nutrition 0.000 description 7
- 235000001169 Brassica oleracea var oleracea Nutrition 0.000 description 7
- 241001674939 Caulanthus Species 0.000 description 7
- 206010067482 No adverse event Diseases 0.000 description 7
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 7
- 235000012211 aluminium silicate Nutrition 0.000 description 7
- 230000010165 autogamy Effects 0.000 description 7
- 230000003750 conditioning effect Effects 0.000 description 7
- 239000004495 emulsifiable concentrate Substances 0.000 description 7
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 description 6
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 6
- RCEAADKTGXTDOA-UHFFFAOYSA-N OS(O)(=O)=O.CCCCCCCCCCCC[Na] Chemical compound OS(O)(=O)=O.CCCCCCCCCCCC[Na] RCEAADKTGXTDOA-UHFFFAOYSA-N 0.000 description 6
- 244000269722 Thea sinensis Species 0.000 description 6
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 6
- 240000008042 Zea mays Species 0.000 description 6
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 6
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 6
- 150000007513 acids Chemical class 0.000 description 6
- 235000005822 corn Nutrition 0.000 description 6
- GHVNFZFCNZKVNT-UHFFFAOYSA-N decanoic acid Chemical compound CCCCCCCCCC(O)=O GHVNFZFCNZKVNT-UHFFFAOYSA-N 0.000 description 6
- 239000013530 defoamer Substances 0.000 description 6
- NVVZQXQBYZPMLJ-UHFFFAOYSA-N formaldehyde;naphthalene-1-sulfonic acid Chemical compound O=C.C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 NVVZQXQBYZPMLJ-UHFFFAOYSA-N 0.000 description 6
- 239000005011 phenolic resin Substances 0.000 description 6
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 6
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 6
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 6
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 6
- 231100000419 toxicity Toxicity 0.000 description 6
- 230000001988 toxicity Effects 0.000 description 6
- 230000009471 action Effects 0.000 description 5
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 5
- 239000002270 dispersing agent Substances 0.000 description 5
- MOTZDAYCYVMXPC-UHFFFAOYSA-N dodecyl hydrogen sulfate Chemical compound CCCCCCCCCCCCOS(O)(=O)=O MOTZDAYCYVMXPC-UHFFFAOYSA-N 0.000 description 5
- 229940043264 dodecyl sulfate Drugs 0.000 description 5
- 239000003995 emulsifying agent Substances 0.000 description 5
- 239000002574 poison Substances 0.000 description 5
- 231100000614 poison Toxicity 0.000 description 5
- 229920002545 silicone oil Polymers 0.000 description 5
- 159000000000 sodium salts Chemical class 0.000 description 5
- 239000002904 solvent Substances 0.000 description 5
- 230000001954 sterilising effect Effects 0.000 description 5
- 238000004659 sterilization and disinfection Methods 0.000 description 5
- 239000004094 surface-active agent Substances 0.000 description 5
- 239000002562 thickening agent Substances 0.000 description 5
- VIESAWGOYVNHLV-UHFFFAOYSA-N 1,3-dihydropyrrol-2-one Chemical class O=C1CC=CN1 VIESAWGOYVNHLV-UHFFFAOYSA-N 0.000 description 4
- 241000255789 Bombyx mori Species 0.000 description 4
- 229920000742 Cotton Polymers 0.000 description 4
- 240000008067 Cucumis sativus Species 0.000 description 4
- 235000010799 Cucumis sativus var sativus Nutrition 0.000 description 4
- 229920001732 Lignosulfonate Polymers 0.000 description 4
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Natural products OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 4
- 244000061458 Solanum melongena Species 0.000 description 4
- 235000002597 Solanum melongena Nutrition 0.000 description 4
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 4
- 235000010489 acacia gum Nutrition 0.000 description 4
- 239000001785 acacia senegal l. willd gum Substances 0.000 description 4
- 239000003905 agrochemical Substances 0.000 description 4
- 125000002877 alkyl aryl group Chemical group 0.000 description 4
- 150000004996 alkyl benzenes Chemical class 0.000 description 4
- 125000000217 alkyl group Chemical group 0.000 description 4
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 4
- 229910021529 ammonia Inorganic materials 0.000 description 4
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 4
- 229940077388 benzenesulfonate Drugs 0.000 description 4
- 239000011575 calcium Substances 0.000 description 4
- 229910052791 calcium Inorganic materials 0.000 description 4
- 238000013401 experimental design Methods 0.000 description 4
- 230000000749 insecticidal effect Effects 0.000 description 4
- 238000011835 investigation Methods 0.000 description 4
- 230000010534 mechanism of action Effects 0.000 description 4
- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical class CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 description 4
- 239000002689 soil Substances 0.000 description 4
- 235000015112 vegetable and seed oil Nutrition 0.000 description 4
- 239000008158 vegetable oil Substances 0.000 description 4
- 239000000080 wetting agent Substances 0.000 description 4
- 229920001285 xanthan gum Polymers 0.000 description 4
- DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical compound CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 description 3
- 241000273311 Aphis spiraecola Species 0.000 description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 3
- 239000005632 Capric acid (CAS 334-48-5) Substances 0.000 description 3
- 241000255967 Helicoverpa zea Species 0.000 description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 3
- 239000002202 Polyethylene glycol Substances 0.000 description 3
- 240000003377 Shepherdia canadensis Species 0.000 description 3
- 235000018324 Shepherdia canadensis Nutrition 0.000 description 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 3
- 239000005864 Sulphur Substances 0.000 description 3
- 230000002528 anti-freeze Effects 0.000 description 3
- 230000009286 beneficial effect Effects 0.000 description 3
- ZCILODAAHLISPY-UHFFFAOYSA-N biphenyl ether Natural products C1=C(CC=C)C(O)=CC(OC=2C(=CC(CC=C)=CC=2)O)=C1 ZCILODAAHLISPY-UHFFFAOYSA-N 0.000 description 3
- LLEMOWNGBBNAJR-UHFFFAOYSA-N biphenyl-2-ol Chemical compound OC1=CC=CC=C1C1=CC=CC=C1 LLEMOWNGBBNAJR-UHFFFAOYSA-N 0.000 description 3
- 210000000481 breast Anatomy 0.000 description 3
- 239000004202 carbamide Substances 0.000 description 3
- 230000006378 damage Effects 0.000 description 3
- 229940079593 drug Drugs 0.000 description 3
- GQBJGCRYICJRII-UHFFFAOYSA-N formaldehyde 2-(2-phenylethyl)phenol Chemical compound C=O.C1(=CC=CC=C1)CCC1=C(C=CC=C1)O GQBJGCRYICJRII-UHFFFAOYSA-N 0.000 description 3
- 235000011187 glycerol Nutrition 0.000 description 3
- 159000000003 magnesium salts Chemical class 0.000 description 3
- 229920005646 polycarboxylate Polymers 0.000 description 3
- 229920001223 polyethylene glycol Polymers 0.000 description 3
- 229940051841 polyoxyethylene ether Drugs 0.000 description 3
- 229920000056 polyoxyethylene ether Polymers 0.000 description 3
- 229920002503 polyoxyethylene-polyoxypropylene Polymers 0.000 description 3
- 229920005989 resin Polymers 0.000 description 3
- 239000011347 resin Substances 0.000 description 3
- 210000003491 skin Anatomy 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- 229910052708 sodium Inorganic materials 0.000 description 3
- 229960000468 sulfalene Drugs 0.000 description 3
- KXRZBTAEDBELFD-UHFFFAOYSA-N sulfamethopyrazine Chemical compound COC1=NC=CN=C1NS(=O)(=O)C1=CC=C(N)C=C1 KXRZBTAEDBELFD-UHFFFAOYSA-N 0.000 description 3
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 3
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 2
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 description 2
- DMAXMXPDVWTIRV-UHFFFAOYSA-N 2-(2-phenylethyl)phenol Chemical compound OC1=CC=CC=C1CCC1=CC=CC=C1 DMAXMXPDVWTIRV-UHFFFAOYSA-N 0.000 description 2
- XNWFRZJHXBZDAG-UHFFFAOYSA-N 2-METHOXYETHANOL Chemical compound COCCO XNWFRZJHXBZDAG-UHFFFAOYSA-N 0.000 description 2
- 235000009024 Ceanothus sanguineus Nutrition 0.000 description 2
- 241000675108 Citrus tangerina Species 0.000 description 2
- 206010011732 Cyst Diseases 0.000 description 2
- QWCKQJZIFLGMSD-GSVOUGTGSA-N D-alpha-aminobutyric acid Chemical compound CC[C@@H](N)C(O)=O QWCKQJZIFLGMSD-GSVOUGTGSA-N 0.000 description 2
- 239000004375 Dextrin Substances 0.000 description 2
- 229920001353 Dextrin Polymers 0.000 description 2
- 229920005682 EO-PO block copolymer Polymers 0.000 description 2
- 241000219146 Gossypium Species 0.000 description 2
- 240000003553 Leptospermum scoparium Species 0.000 description 2
- 235000015459 Lycium barbarum Nutrition 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 2
- 206010033799 Paralysis Diseases 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 2
- 239000004372 Polyvinyl alcohol Substances 0.000 description 2
- 241001249129 Scirpophaga incertulas Species 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- HVUMOYIDDBPOLL-XWVZOOPGSA-N Sorbitan monostearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O HVUMOYIDDBPOLL-XWVZOOPGSA-N 0.000 description 2
- 241000209140 Triticum Species 0.000 description 2
- 235000021307 Triticum Nutrition 0.000 description 2
- OIPILFWXSMYKGL-UHFFFAOYSA-N acetylcholine Chemical compound CC(=O)OCC[N+](C)(C)C OIPILFWXSMYKGL-UHFFFAOYSA-N 0.000 description 2
- 229960004373 acetylcholine Drugs 0.000 description 2
- 150000001266 acyl halides Chemical class 0.000 description 2
- 150000001336 alkenes Chemical class 0.000 description 2
- 150000001408 amides Chemical class 0.000 description 2
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 2
- 235000011130 ammonium sulphate Nutrition 0.000 description 2
- 230000008485 antagonism Effects 0.000 description 2
- 229960000892 attapulgite Drugs 0.000 description 2
- 208000031513 cyst Diseases 0.000 description 2
- 235000019425 dextrin Nutrition 0.000 description 2
- 235000013399 edible fruits Nutrition 0.000 description 2
- 238000003912 environmental pollution Methods 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 235000013305 food Nutrition 0.000 description 2
- 239000005556 hormone Substances 0.000 description 2
- 229940088597 hormone Drugs 0.000 description 2
- 239000002917 insecticide Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 229920002521 macromolecule Polymers 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 229920000609 methyl cellulose Polymers 0.000 description 2
- 239000001923 methylcellulose Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 210000000653 nervous system Anatomy 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 125000006353 oxyethylene group Chemical group 0.000 description 2
- 239000003002 pH adjusting agent Substances 0.000 description 2
- 229910052625 palygorskite Inorganic materials 0.000 description 2
- 230000000149 penetrating effect Effects 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 2
- 239000010452 phosphate Substances 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 229920002451 polyvinyl alcohol Polymers 0.000 description 2
- 235000010413 sodium alginate Nutrition 0.000 description 2
- 239000000661 sodium alginate Substances 0.000 description 2
- 229940005550 sodium alginate Drugs 0.000 description 2
- 235000019832 sodium triphosphate Nutrition 0.000 description 2
- PYODKQIVQIVELM-UHFFFAOYSA-M sodium;2,3-bis(2-methylpropyl)naphthalene-1-sulfonate Chemical compound [Na+].C1=CC=C2C(S([O-])(=O)=O)=C(CC(C)C)C(CC(C)C)=CC2=C1 PYODKQIVQIVELM-UHFFFAOYSA-M 0.000 description 2
- 239000001587 sorbitan monostearate Substances 0.000 description 2
- 235000011076 sorbitan monostearate Nutrition 0.000 description 2
- 229940035048 sorbitan monostearate Drugs 0.000 description 2
- 238000001228 spectrum Methods 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- 210000002784 stomach Anatomy 0.000 description 2
- 208000024891 symptom Diseases 0.000 description 2
- HTSABYAWKQAHBT-UHFFFAOYSA-N trans 3-methylcyclohexanol Natural products CC1CCCC(O)C1 HTSABYAWKQAHBT-UHFFFAOYSA-N 0.000 description 2
- 235000013311 vegetables Nutrition 0.000 description 2
- 230000001018 virulence Effects 0.000 description 2
- 238000009736 wetting Methods 0.000 description 2
- OWEGMIWEEQEYGQ-UHFFFAOYSA-N 100676-05-9 Natural products OC1C(O)C(O)C(CO)OC1OCC1C(O)C(O)C(O)C(OC2C(OC(O)C(O)C2O)CO)O1 OWEGMIWEEQEYGQ-UHFFFAOYSA-N 0.000 description 1
- 125000000094 2-phenylethyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])C([H])([H])* 0.000 description 1
- QGHDLJAZIIFENW-UHFFFAOYSA-N 4-[1,1,1,3,3,3-hexafluoro-2-(4-hydroxy-3-prop-2-enylphenyl)propan-2-yl]-2-prop-2-enylphenol Chemical group C1=C(CC=C)C(O)=CC=C1C(C(F)(F)F)(C(F)(F)F)C1=CC=C(O)C(CC=C)=C1 QGHDLJAZIIFENW-UHFFFAOYSA-N 0.000 description 1
- JCUDAMKYTWVICI-UHFFFAOYSA-N 4-benzyl-2,3-dimethylphenol Chemical compound C1=C(O)C(C)=C(C)C(CC=2C=CC=CC=2)=C1 JCUDAMKYTWVICI-UHFFFAOYSA-N 0.000 description 1
- 239000005711 Benzoic acid Substances 0.000 description 1
- 108010062745 Chloride Channels Proteins 0.000 description 1
- 102000011045 Chloride Channels Human genes 0.000 description 1
- 241000254173 Coleoptera Species 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- 241000283073 Equus caballus Species 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- 102000005915 GABA Receptors Human genes 0.000 description 1
- 108010005551 GABA Receptors Proteins 0.000 description 1
- 108010010803 Gelatin Proteins 0.000 description 1
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
- 229920002907 Guar gum Polymers 0.000 description 1
- 241000594036 Liriomyza Species 0.000 description 1
- GUBGYTABKSRVRQ-PICCSMPSSA-N Maltose Natural products O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@@H]1O[C@@H]1[C@@H](CO)OC(O)[C@H](O)[C@H]1O GUBGYTABKSRVRQ-PICCSMPSSA-N 0.000 description 1
- 241001232130 Maruca testulalis Species 0.000 description 1
- WPPOGHDFAVQKLN-UHFFFAOYSA-N N-Octyl-2-pyrrolidone Chemical compound CCCCCCCCN1CCCC1=O WPPOGHDFAVQKLN-UHFFFAOYSA-N 0.000 description 1
- IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 description 1
- 241000721451 Pectinophora gossypiella Species 0.000 description 1
- 208000005374 Poisoning Diseases 0.000 description 1
- 229920000388 Polyphosphate Polymers 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 1
- 241000256247 Spodoptera exigua Species 0.000 description 1
- 241000985245 Spodoptera litura Species 0.000 description 1
- 206010044565 Tremor Diseases 0.000 description 1
- XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical compound ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical class OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000000895 acaricidal effect Effects 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 238000012271 agricultural production Methods 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 239000010242 baoji Substances 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 239000000440 bentonite Substances 0.000 description 1
- 229910000278 bentonite Inorganic materials 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- 235000010233 benzoic acid Nutrition 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- 229920001400 block copolymer Polymers 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 150000007942 carboxylates Chemical class 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 230000037011 constitutive activity Effects 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 239000007884 disintegrant Substances 0.000 description 1
- 210000002615 epidermis Anatomy 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- CASPZMCSNJZQMV-UHFFFAOYSA-N ethane;2-methyloxirane Chemical compound CC.CC1CO1 CASPZMCSNJZQMV-UHFFFAOYSA-N 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 238000003958 fumigation Methods 0.000 description 1
- 229960003692 gamma aminobutyric acid Drugs 0.000 description 1
- BTCSSZJGUNDROE-UHFFFAOYSA-N gamma-aminobutyric acid Chemical compound NCCCC(O)=O BTCSSZJGUNDROE-UHFFFAOYSA-N 0.000 description 1
- 229920000159 gelatin Polymers 0.000 description 1
- 239000008273 gelatin Substances 0.000 description 1
- 235000019322 gelatine Nutrition 0.000 description 1
- 235000011852 gelatine desserts Nutrition 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- 239000000665 guar gum Substances 0.000 description 1
- 235000010417 guar gum Nutrition 0.000 description 1
- 229960002154 guar gum Drugs 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 229920003063 hydroxymethyl cellulose Polymers 0.000 description 1
- 229940031574 hydroxymethyl cellulose Drugs 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 229910052622 kaolinite Inorganic materials 0.000 description 1
- 230000002147 killing effect Effects 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 238000002386 leaching Methods 0.000 description 1
- 230000001665 lethal effect Effects 0.000 description 1
- 239000003120 macrolide antibiotic agent Substances 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- PQIOSYKVBBWRRI-UHFFFAOYSA-N methylphosphonyl difluoride Chemical group CP(F)(F)=O PQIOSYKVBBWRRI-UHFFFAOYSA-N 0.000 description 1
- 239000012452 mother liquor Substances 0.000 description 1
- PSZYNBSKGUBXEH-UHFFFAOYSA-N naphthalene-1-sulfonic acid Chemical class C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 PSZYNBSKGUBXEH-UHFFFAOYSA-N 0.000 description 1
- 229930014626 natural product Natural products 0.000 description 1
- 210000005036 nerve Anatomy 0.000 description 1
- 230000007830 nerve conduction Effects 0.000 description 1
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 1
- 231100000194 ovacidal Toxicity 0.000 description 1
- 230000003151 ovacidal effect Effects 0.000 description 1
- AICOOMRHRUFYCM-ZRRPKQBOSA-N oxazine, 1 Chemical compound C([C@@H]1[C@H](C(C[C@]2(C)[C@@H]([C@H](C)N(C)C)[C@H](O)C[C@]21C)=O)CC1=CC2)C[C@H]1[C@@]1(C)[C@H]2N=C(C(C)C)OC1 AICOOMRHRUFYCM-ZRRPKQBOSA-N 0.000 description 1
- 244000045947 parasite Species 0.000 description 1
- 230000035479 physiological effects, processes and functions Effects 0.000 description 1
- 231100000572 poisoning Toxicity 0.000 description 1
- 230000000607 poisoning effect Effects 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000001205 polyphosphate Substances 0.000 description 1
- 235000011176 polyphosphates Nutrition 0.000 description 1
- 235000013809 polyvinylpolypyrrolidone Nutrition 0.000 description 1
- 229920000523 polyvinylpolypyrrolidone Polymers 0.000 description 1
- 244000144977 poultry Species 0.000 description 1
- 229940088417 precipitated calcium carbonate Drugs 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- HNJBEVLQSNELDL-UHFFFAOYSA-N pyrrolidin-2-one Chemical compound O=C1CCCN1 HNJBEVLQSNELDL-UHFFFAOYSA-N 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 230000004936 stimulating effect Effects 0.000 description 1
- 230000001629 suppression Effects 0.000 description 1
- 230000002459 sustained effect Effects 0.000 description 1
- 230000009885 systemic effect Effects 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 210000001519 tissue Anatomy 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
- A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
- A01N43/22—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom rings with more than six members
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
- A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
- A01N43/14—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings
- A01N43/16—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings with oxygen as the ring hetero atom
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a chromafenozid-containing biogenic pesticide composition; the pesticide composition is mainly characterized by being prepared from an active ingredient A and an active ingredient B, wherein the active ingredient A is SIOC-I-002, the active ingredient B is any one of abamectin, emamectin benzoate, spinosad and spinetoram, and the weight ratio of the active ingredient A to the active ingredient B is equal to (1: 80)-(80: 1); the pesticide composition can be prepared into wettable powder, water dispersible granules, a suspending agent, a suspension emulsion, an emulsion in water, a microemulsion, a microcapsule suspension and a microcapsule suspension-suspending agent. The chromafenozid-containing biogenic pesticide composition can be used for controlling multiple pests on multiple crops, has an obvious synergistic effect, reduces dosage of pesticide, and is safe to human and animals, free from phytotoxicity and good in environmental compatibility; the adhesive force of the preparation of the pesticide composition is enhanced, so that the pesticide composition has resistance to rain wash.
Description
The application is divisional application, and original application is patent application " a kind of fluorine-containing lice of Shaanxi Welch Crop Protection Co., Ltd.
The composition pesticide of sulfanilamide (SN) and biogenic substances ", the Application No. 201210106597.9 of original application, original application day is
2012.04.12。
Technical field
The invention belongs to technical field of pesticide, relate to a kind of fluorine-containing lice sulfanilamide (SN) composition pesticide with biogenic substances for preventing
Control the application of crop pest.
Background technology
Fluorine lice sulfanilamide (SN) (chromafenozid) molecular formula: C24H30N2O3, fluorine lice sulfanilamide (SN) is bishydrazide insecticide, insect
After taking food, suppression feed in several hours, causes insect to cast off a skin in advance simultaneously and causes death.It is by regulation young hormone and sloughs off
The molting process of skin hormone moving obstacle insect, causes the death of casting off a skin too early of insect.Because it can quickly suppress insect
Feed, for the similar medicament that other are conventional, can reduce the harm to crop.To noctuid and other caterpillar, no matter
In which, fluorine lice sulfanilamide (SN) has the strongest insecticidal activity in period.
AVM (abamectin) molecular formula: C48H72O14(B1a)·C47H70O14(B1b).In AVM is a kind of macrocyclic
Ester disaccharide compounds.AVM be from edaphon separate natural products, insect and mite class are had tag and
Stomach poison function also has faint fumigation action, without systemic action.But it has the strongest osmosis to blade, can kill under epidermis
Insect, and the longevity of residure is long, its not ovicidal.Its mechanism of action its interference nervous physiology unlike general insecticide is movable,
Stimulate release r-aminobutyric acid, and r-aminobutyric acid has inhibitory action to arthropodan nerve conduction, if mite class becomes mite and elder brother
I.e. there is paralysis symptom after contacting with medicament with larva in worm, and inertia does not takes food, dead after 2-4 days.Because not causing insect rapid
Dehydration, so its lethal effect is slower.But though predatism and parasite are had direct killing effect, but because of plant surface
Residual is few, and therefore the damage to beneficial insect is little.
Emamectin-benzoate (emamectin benzoate) chemical molecular formula: C49H75NO13·C7H6O2.First ammonia
Base abamectin benzoate is a kind of efficient, wide spectrum, insecticidal/acaricidal agent of longevity of residure length, and its mechanism of action is for hindering insect fortune
Dynamic nerve information transmits and makes health paralysis death.The mode of action, based on stomach toxicity, also has action of contace poison, to crop without interior absorption
Can, but effectively penetrate into and use crop epidermal tissue, thus there is the longer longevity of residure.To mite class, coleoptera and homoptera pest
Have high activity, soil and in degradable noresidue, free from environmental pollution, to beneficial insect and sky in normal dosage ranges
Enemy, people, animal safety, can be with major part combined use of pesticides.
Pleocidin (spinosad), the mechanism of action of pleocidin is the most novel and unique, is different from general macrolide
Compounds, the chemical constitution of its uniqueness determines the insecticidal mechanism of its uniqueness.Pleocidin to insect exist quickly tag and
Ingesting toxicity, it has the distinctive poisoning symptom of never poison, and its mechanism of action is the nervous system by stimulating insect, increases
Add its constitutive activity, cause the flesh of non-functional to shrink, exhaustion, and with trembling and benumbing, demonstrate nicotinic acetylcholine
Acceptor is caused acetylcholine to extend release reaction by sustained activation.Pleocidin also acts on GABA receptor simultaneously, changes
Become the function of GABA gate chloride channel, promote the raising of its insecticidal activity further.
Ethyl pleocidin (spinetoram) chemical molecular formula: C42H69NO10, ethyl pleocidin is by ethyl pleocidin-J
With two kinds of component compositions of ethyl pleocidin-L, act on the nervous system of insect, to diamondback moth, beet armyworm, Liriomyza, Ji
The prevention effect that horse, prodenia litura, bean-pod borer have had.
In the real process of agricultural production, pest control, evil mite are easiest to generate the problem that drug-fast generation.Different product
Kind composition compounds, and is preventing and treating resistant insect, does harm to the method that mite is the most common.Heterogeneity compounds, and applies according to reality
Effect, judge certain compounding be synergy, add and or antagonism.In most cases, the compounding effect of agricultural chemicals is all
Additive effect, really have synergistic effect compounding seldom, especially synergistic effect clearly, the highest compounding of co-toxicity coefficient
The most less.Find through inventor's lot of experiments, fluorine lice sulfanilamide (SN) and AVM, emamectin-benzoate, kill more
After rhzomorph, ethyl pleocidin are compounding, synergistic effect is notable, and Environmental compatibility is fabulous, considerably reduces pesticide usage amount.
Summary of the invention
The composition pesticide that the present invention proposes is except comprising fluorine lice sulfanilamide (SN) and AVM, Affirm (Merck Co.) benzoic acid
In salt, pleocidin, ethyl pleocidin outside any one two kinds of active components, also comprise appropriate surfactant and load
Body.
A kind of fluorine lice sulfanilamide (SN) and the composition pesticide of biogenic substances, comprise active components A and active component B, it is characterised in that: live
Property composition A be fluorine lice sulfanilamide (SN), active component B be selected from AVM, emamectin-benzoate, pleocidin, ethyl
In pleocidin arbitrary a kind of, and the weight ratio of active components A and active component B is 1:80～80:1.
Described composition pesticide, it is characterised in that: active components A is 1:40～60:1 with the weight ratio of active component B.
Described composition pesticide, it is characterised in that: fluorine lice sulfanilamide (SN) is 1:10～20:1 with the weight ratio of AVM.
Described composition pesticide, it is characterised in that: fluorine lice sulfanilamide (SN) is 1 with the weight ratio of emamectin-benzoate:
10～30:1.
Described composition pesticide, it is characterised in that: fluorine lice sulfanilamide (SN) is 1:10～20:1 with the weight ratio of pleocidin.
Described composition pesticide, it is characterised in that: fluorine lice sulfanilamide (SN) is 1:10～10:1 with the weight ratio of ethyl pleocidin.
Described composition pesticide, it is characterised in that: composition makes wettable powder, water dispersible granules, suspending agent, outstanding breast
Agent, aqueous emulsion, microemulsion, micro-capsule suspension, microcapsule suspension-suspendinagent agent.
Described composition pesticide for preventing and treating the application of crop pests, described crops include paddy rice, wheat, cotton,
Fruit tree, vegetables, tea tree, flowers, corn；Described insect includes: rice leaf roller, striped rice borer, yellow rice borer, planthopper, diamondback moth,
Cabbage caterpillar, aphid, thrips, mite class, scale insect, chafer, weevil, midge worm, 2 committees noctuid, citrus fruit flies.
Including at least a kind of surfactant in the composition pesticide of the present invention, active component dividing in water when being beneficial to use
Dissipate.Surface-active contents is the 5%～30% of total formulation weight amount, and surplus is solid or liquid diluent.The agricultural chemicals of the present invention
Surfactant selected by composition is known in those skilled in the art: can be selected from dispersant, wetting agent, emulsifying agent
Or one or more in defoamer.
Comprise following constituent content when making wettable powder: active components A 0.1%～80%, active component B 0.1%～
80%, dispersant 3%～15%, wetting agent 2%～10%, filler surplus.
Composition includes following constituent content when making water dispersible granules: active components A 0.1%～80%, active component B
0.1%～80%, dispersant 3%～12%, wetting agent 1%～10%, disintegrant 1%～10%, binding agent 0～8%, filler
Surplus.
Composition includes following constituent content when making suspending agent: active components A 0.1%～60%, active component B0.1%～
60%, dispersant 2～10%, wetting agent 2～10%, defoamer 0.1～2%, thickener 0.05～2%, antifreeze 0～8%,
Deionized water adds to 100%.
Composition includes following constituent content when making suspension emulsion: active components A 0.1%～60%, active component B0.1%～
60%, emulsifying agent 2%～12%, dispersant 2%～10%, defoamer 0.1%～2%, thickener 0.05%～2%, freeze proof
Agent 0～8%, stabilizer 0～5%, solvent 0～15%, deionized water add to 100%.
Composition comprises following constituent content when making aqueous emulsion: activity composition A 0.1%～60%, active component B0.1%
～60%, solvent 0～30%, emulsifying agent 1%～15%, antifreeze 0～10%, thickener 0.05%～2%, defoamer
0.01%～2%, deionized water supplies surplus.
Composition comprise when making microemulsion following constituent content active components A 0.1%～60%, active component B 0.1%～
60%, solvent 0～30%, emulsifying agent 3%～20%, antifreeze 0～10%, thickener 0～2%, defoamer 0.01%～
2%, stabilizer 0～4%, deionized water surplus.
Composition is made micro-capsule suspension and is included following constituent content: active components A 0.1%～60%, active component
B0.1%～60%, macromolecule cyst material 1%～12%, surfactant 2%～10%, organic solvent 1%～15%, breast
Agent 1%～8%, pH adjusting agent 0.1%～5%, deionized water adds to 100%.
Composition includes following constituent content when making microcapsule suspension-suspendinagent agent: active components A 0.1%～60%, activity become
Point B 0.1%～60%, macromolecule cyst material 2%～12%, surfactant 3%～15%, organic solvent 1%～5%,
Emulsifying agent 1%～6%, defoamer 0.1%～5%, thickener 0.05%～2%, pH adjusting agent 0.1%～5%, water add to
100%.The wettable powder the key technical indexes of the present invention:
The water dispersible granules the key technical indexes of the present invention:
The suspending agent the key technical indexes of the present invention:
The suspension emulsion the key technical indexes of the present invention:
The aqueous emulsion the key technical indexes of the present invention:
The microemulsion the key technical indexes of the present invention:
The microcapsule suspending agent the key technical indexes of the present invention:
The microcapsule suspension-suspendinagent agent the key technical indexes of the present invention:
It is an advantage of the current invention that:
(1) after fluorine lice sulfanilamide (SN) and AVM, emamectin-benzoate, pleocidin, ethyl pleocidin compound,
There is notable synergistic and lasting effect；
(2) preventing and treating spectrum is expanded, to the rice leaf roller on paddy rice, wheat, cotton, fruit tree, vegetables, tea tree, corn, two changes
Snout moth's larva, yellow rice borer, planthopper, diamondback moth, cabbage caterpillar, aphid, thrips, mite class, scale insect, chafer, weevil, midge worm, 2 points
Committee noctuid, citrus fruit fly etc. all have greater activity；
(3) decrease the dosage of agricultural chemicals, reduce agricultural chemicals residual quantity on crop, alleviate environmental pollution；
(4) to person poultry safety, Environmental compatibility is good, is not likely to produce the resistance to the action of a drug.
Detailed description of the invention
Below in conjunction with embodiment, further instruction of the present invention, the percentage in embodiment are all weight percentage, but this
Bright it is not limited thereto.
Application Example one
Embodiment 116.2% fluorine lice sulfanilamide (SN) AVM wettable powder
Fluorine lice sulfanilamide (SN) 16%, AVM 0.2%, alkylnaphthalene sulfonate 5%, lauryl sodium sulfate 5%, kaolin add to
100%, mixture carries out air-flow crushing, prepares 16.2% fluorine lice sulfanilamide (SN) AVM wettable powder.
AVM is changed to emamectin-benzoate, pleocidin, ethyl pleocidin can form new embodiment.
Embodiment 255% fluorine lice sulfanilamide (SN) AVM wettable powder
Fluorine lice sulfanilamide (SN) 50%, AVM 5%, double (alkyl) naphthalenesulfonate formaldehyde condensation compound 6%, neopelex
4%, attapulgite adds to 100%, and mixture carries out air-flow crushing, prepares 55% fluorine lice sulfanilamide (SN) AVM wettable powder
Agent.
AVM is changed to emamectin-benzoate, pleocidin, ethyl pleocidin can form new embodiment.
Embodiment 320% fluorine lice sulfanilamide (SN) AVM water dispersible granules
Fluorine lice sulfanilamide (SN) 18%, AVM 2%, naphthalene sulfonic acid-formaldehyde condensation product 5%, Nekal BX 4.5%, sodium acid carbonate
1.9%, kaolin adds to 100%, is mixed to prepare 20% fluorine lice sulfanilamide (SN) AVM water dispersible granules.
AVM is changed to emamectin-benzoate, pleocidin, ethyl pleocidin can form new embodiment.
Embodiment 481% fluorine lice sulfanilamide (SN) AVM water dispersible granules
Fluorine lice sulfanilamide (SN) 1%, AVM 80%, wetting and penetrating agent F 2.5%, aryl phenol polyoxyethylene succinate sulfonate
4%, urea 2%, precipitated calcium carbonate add to 100%, are mixed to prepare 81% fluorine lice sulfanilamide (SN) AVM water dispersible granules.
AVM is changed to emamectin-benzoate, pleocidin, ethyl pleocidin can form new embodiment.
Embodiment 542% fluorine lice sulfanilamide (SN) AVM suspending agent
Fluorine lice sulfanilamide (SN) 40%, AVM 2%, octylphenol polyethylene oxyethylene group ether sulfate 6%, tea seed cake 3.8%, silicone
0.1%, hydroxymethyl cellulose 0.16%, ethylene glycol 3.8%, deionized water add to 100%, are mixed to prepare 42% fluorine lice sulfanilamide (SN)
AVM suspending agent.
AVM is changed to emamectin-benzoate, pleocidin, ethyl pleocidin can form new embodiment.
Embodiment 615% fluorine lice sulfanilamide (SN) AVM suspending agent
Fluorine lice sulfanilamide (SN) 10%, AVM 5%, polycarboxylate 6.5%, soapberry powder 5%, silicone oil 0.12%, Arabic gum
0.15%, propane diols 4%, deionized water add to 100%, are mixed to prepare 15% fluorine lice sulfanilamide (SN) AVM suspending agent.
AVM is changed to emamectin-benzoate, pleocidin, ethyl pleocidin can form new embodiment.
Embodiment 720% fluorine lice sulfanilamide (SN) AVM suspension emulsion
Fluorine lice sulfanilamide (SN) 15%, AVM 5%, lignosulfonates 4.8%, soapberry powder 5.2%, phenyl phenol polyoxyethyl ether
Phosphate 6%, butyl ether 8%, C10～20Saturated fat acids 0.09%, polyvinylpyrrolidone 0.11%, polyethylene glycol 3.0%,
Deionized water adds to 100%, is mixed to prepare 20% fluorine lice sulfanilamide (SN) AVM suspension emulsion.
AVM is changed to emamectin-benzoate, pleocidin, ethyl pleocidin can form new embodiment.
Embodiment 840% fluorine lice sulfanilamide (SN) AVM suspension emulsion
Fluorine lice sulfanilamide (SN) 32%, AVM 8%, alkyl benzene sulfonate calcium salt 5%, spaonin powder 4%, triethanolamine salt 6%, cyclohexanone
5%, silicone oil 0.08%, phenolic resin 0.15%, propane diols 3.1%, deionized water add to 100%, are mixed to prepare 40% fluorine lice
Sulfanilamide (SN) AVM suspension emulsion.
AVM is changed to emamectin-benzoate, pleocidin, ethyl pleocidin can form new embodiment.
Embodiment 97.5% fluorine lice sulfanilamide (SN) avermectin micro-emulsion
Fluorine lice sulfanilamide (SN) 5%, AVM 2.5%, alkylphenol-formaldehyde resin polyoxyethyl ether 7%, N-pyrrolidones 9%, poly-second
Glycol 1%, polyvinylpyrrolidone 0.18%, C8～10Aliphatic alcohols 0.12%, deionized water supplies 100%, is mixed to prepare
7.5% fluorine lice sulfanilamide (SN) avermectin micro-emulsion.
AVM is changed to emamectin-benzoate, pleocidin, ethyl pleocidin can form new embodiment.
Embodiment 1010% fluorine lice sulfanilamide (SN) avermectin micro-emulsion
Fluorine lice sulfanilamide (SN) 8%, AVM 2%, acetonitrile 6%, polyvinylpyrrolidone 0.2%, phenyl phenol polyoxyethyl ether 7%,
Silicone compound 1.4%, deionized water supplies 100%, prepares 10% fluorine lice sulfanilamide (SN) avermectin micro-emulsion.
AVM is changed to emamectin-benzoate, pleocidin, ethyl pleocidin can form new embodiment.
Embodiment 1130% fluorine lice sulfanilamide (SN) abamectin aqueous emulsion
Fluorine lice sulfanilamide (SN) 20%, AVM 10%, methyl alcohol 4%, EGME 5.5%, epoxy ethane-epoxy propane block are altogether
Polymers 6%, Arabic gum 0.18%, silicone 0.11%, deionized water adds to 100%, is mixed to prepare 30% fluorine lice sulfanilamide (SN)
Abamectin aqueous emulsion.
AVM is changed to emamectin-benzoate, pleocidin, ethyl pleocidin can form new embodiment.
Embodiment 1215% fluorine lice sulfanilamide (SN) abamectin aqueous emulsion
Fluorine lice sulfanilamide (SN) 5%, AVM 10%, acetonitrile 3.5%, vegetable oil 5.5%, alkylaryl polyoxyethylene polyoxypropylene ether
7%, polyvinylpyrrolidone 0.12%, C10～20Saturated fat acids 0.11%, deionized water adds to 100%, blended prepares
15% fluorine lice sulfanilamide (SN) abamectin aqueous emulsion.
AVM is changed to emamectin-benzoate, pleocidin, ethyl pleocidin can form new embodiment.
Embodiment 1320% fluorine lice sulfanilamide (SN) avermectin microcapsule suspending agent
Fluorine lice sulfanilamide (SN) 10%, AVM 10%, deformation lactoprotein 3%, PIC 2%, spaonin powder 5%, naphthalene sulfonic acids first
Aldehyde condensate sodium salt 2.8%, propyl alcohol 4%, sorbitan fatty acid ester APEO 5%, PH conditioning agent NaOH and
Hydrochloric acid altogether 3.6%, deionized water add to 100% weight portion, prepare 20% fluorine lice sulfanilamide (SN) avermectin microcapsule suspending agent.
AVM is changed to emamectin-benzoate, pleocidin, ethyl pleocidin can form new embodiment.
Embodiment 146% fluorine lice sulfanilamide (SN) avermectin microcapsule suspension-suspending agent
Fluorine lice sulfanilamide (SN) 0.5%, AVM 5.5%, polyfunctional group acyl halide dihydroxylic alcohols 5%, maltose 2%, silkworm excrement 2.5%,
Ethyl acetate 7%, alkylphenol-formaldehyde resin polyoxyethyl ether 5%, alkylaryl polyoxyethylene polyoxypropylene ether 3%, C8～10Fat
Fat alcohols 0.15%, phenolic resin 1.2%, PH conditioning agent NaOH and hydrochloric acid altogether 3.9%, water add to 100% weight portion,
Prepare 6% fluorine lice sulfanilamide (SN) avermectin microcapsule suspension-suspending agent.
AVM is changed to emamectin-benzoate, pleocidin, ethyl pleocidin can form new embodiment.
Embodiment 1510% fluorine lice sulfanilamide (SN) emamectin-benzoate wettable powder
Fluorine lice sulfanilamide (SN) 9%, emamectin-benzoate 1%, ester polyoxyethylene are phonetic 5%, soapberry powder 4%, concave convex rod
Soil adds to 100%, and mixture carries out air-flow crushing, prepares 10% fluorine lice sulfanilamide (SN) emamectin-benzoate wettable
Pulvis.
Emamectin-benzoate is changed to AVM, pleocidin, ethyl pleocidin can form new embodiment.
Embodiment 1660% fluorine lice sulfanilamide (SN) emamectin-benzoate wettable powder
Fluorine lice sulfanilamide (SN) 50%, emamectin-benzoate 10%, polyoxyethylene carboxylate 5%, silkworm excrement 5%, kaolinite
Soil adds to 100%, and mixture carries out air-flow crushing, prepares 60% fluorine lice sulfanilamide (SN) emamectin-benzoate wettable
Pulvis.
Emamectin-benzoate is changed to AVM, pleocidin, ethyl pleocidin can form new embodiment.
Embodiment 1712% fluorine lice sulfanilamide (SN) emamectin-benzoate water dispersible granules
Fluorine lice sulfanilamide (SN) 9%, emamectin-benzoate 3%, aliphatic amine polyoxyethylene are phonetic 6%, tea seed cake 5%, aluminium chloride
2.5%, bentonite adds to 100%, is mixed to prepare 12% fluorine lice sulfanilamide (SN) emamectin-benzoate water dispersible granules.
Emamectin-benzoate is changed to AVM, pleocidin, ethyl pleocidin can form new embodiment.
Embodiment 1862% fluorine lice sulfanilamide (SN) emamectin-benzoate water dispersible granules
Fluorine lice sulfanilamide (SN) 60%, emamectin-benzoate 2%, sldium lauryl sulfate 5%, alkyl benzene sulfonate calcium salt 5%,
Ammonium sulfate 1.8%, kaolin add to 100%, are mixed to prepare 62% fluorine lice sulfanilamide (SN) emamectin-benzoate moisture
Shot agent.
Emamectin-benzoate is changed to AVM, pleocidin, ethyl pleocidin can form new embodiment.
Embodiment 1920% fluorine lice sulfanilamide (SN) emamectin benzoate suspending agent
Fluorine lice sulfanilamide (SN) 15%, emamectin-benzoate 5%, alkylphenol-polyethenoxy phonetic formaldehyde condensation products sulfate
5%, spaonin powder 3%, C8～10Aliphatic alcohols 0.1%, Magnesiumaluminumsilicate 0.15%, propane diols 3.6%, deionized water add to 100%,
It is mixed to prepare 20% fluorine lice sulfanilamide (SN) emamectin benzoate suspending agent.
Emamectin-benzoate is changed to AVM, pleocidin, ethyl pleocidin can form new embodiment.
Embodiment 2015% fluorine lice sulfanilamide (SN) emamectin benzoate suspending agent
Fluorine lice sulfanilamide (SN) 12%, emamectin-benzoate 3%, lignosulfonates 6%, silkworm excrement 4%, C8～10Fatty alcohol
Class 0.07%, white dextrin 0.15%, triethylene glycol 2%, deionized water add to 100%, are mixed to prepare 15% fluorine lice sulfalene ammonia
Base abamectin benzoate suspending agent.
Emamectin-benzoate is changed to AVM, pleocidin, ethyl pleocidin can form new embodiment.
Embodiment 2130.5% fluorine lice sulfanilamide (SN) emamectin-benzoate suspension emulsion
Fluorine lice sulfanilamide (SN) 30%, emamectin-benzoate 0.5%, alkylaryl APEO 5%, pull open powder
BX5%, benzyl dimethyl phenol polyoxyethyl ether 6%, butanol 8%, C10～20Saturated fat acids 0.1%, polyvinylpyrrolidone
0.12%, polyethylene glycol 3.8%, deionized water add to 100%, are mixed to prepare 30.5% fluorine lice sulfanilamide (SN) Affirm (Merck Co.)
Benzoate suspension emulsion.
Emamectin-benzoate is changed to AVM, pleocidin, ethyl pleocidin can form new embodiment.
Embodiment 228.2% fluorine lice sulfanilamide (SN) emamectin-benzoate suspension emulsion
Fluorine lice sulfanilamide (SN) 0.2%, emamectin-benzoate 8%, aliphatic alcohol polyethenoxy base ether 5%, detergent alkylate
Sodium sulfonate 4%, alkyl biphenyl ether disulfonic acid magnesium salts 6%, N-pyrrolidones 5%, silicone 0.08%, phenolic resin 0.15%,
Propane diols 4%, deionized water add to 100%, are mixed to prepare the outstanding breast of 8.2% fluorine lice sulfanilamide (SN) emamectin-benzoate
Agent.
Emamectin-benzoate is changed to AVM, pleocidin, ethyl pleocidin can form new embodiment.
Embodiment 2311% fluorine lice sulfanilamide (SN) emamectin benzoate microemulsion
Fluorine lice sulfanilamide (SN) 1%, emamectin-benzoate 10%, phenyl phenol polyoxyethyl ether 7%, cyclohexanone 4%, crosslinking
Polyvinylpyrrolidone 0.15%, capric acid 0.15%, deionized water supplies 100%, is mixed to prepare 11% fluorine lice sulfalene ammonia
Base abamectin benzoate microemulsion.
Emamectin-benzoate is changed to AVM, pleocidin, ethyl pleocidin can form new embodiment.
Embodiment 2420% fluorine lice sulfanilamide (SN) emamectin-benzoate aqueous emulsion
Fluorine lice sulfanilamide (SN) 10%, emamectin-benzoate 10%, toluene 4%, 3-methyl cyclohexanol ketenes 5%, phenethyl
Phenol polyoxyethanyl polypropylene-base ether 6%, Magnesiumaluminumsilicate 0.18%, silicone 0.05%, deionized water adds to 100%, mixing system
Obtain 20% fluorine lice sulfanilamide (SN) emamectin-benzoate aqueous emulsion.
Emamectin-benzoate is changed to AVM, pleocidin, ethyl pleocidin can form new embodiment.
Embodiment 2512% fluorine lice sulfanilamide (SN) emamectin-benzoate aqueous emulsion
Fluorine lice sulfanilamide (SN) 10%, emamectin-benzoate 2%, acetonitrile 3.5%, solvent naphtha 5.5%, oxirane-ring
Ethylene Oxide block copolymer 5%, phenolic resin 0.12%, silicone oil 0.09%, deionized water adds to 100%, blended prepares
12% fluorine lice sulfanilamide (SN) emamectin-benzoate aqueous emulsion.
Emamectin-benzoate is changed to AVM, pleocidin, ethyl pleocidin can form new embodiment.
Embodiment 2615% fluorine lice sulfanilamide (SN) emamectin-benzoate micro-capsule suspension
Fluorine lice sulfanilamide (SN) 5%, emamectin-benzoate 10%, polyfunctional group acyl halide dihydroxylic alcohols 3%, sodium alginate
2%, sldium lauryl sulfate 5%, lignosulfonates 5%, N-pyrrolidones 4%, ethylene oxide-propylene oxide block copolymer
5%, PH conditioning agent NaOH and citric acid altogether 2.8%, deionized water add to 100% weight portion, prepare 15% fluorine lice sulphur
Amine emamectin-benzoate micro-capsule suspension.
Emamectin-benzoate is changed to AVM, pleocidin, ethyl pleocidin can form new embodiment.
Embodiment 2712% fluorine lice sulfanilamide (SN) emamectin-benzoate microcapsule suspension-suspendinagent agent
Fluorine lice sulfanilamide (SN) 2%, emamectin-benzoate 10%, urea 5%, formaldehyde 3%, tea seed cake 2.5%, butyl ether 7%,
Phenethyl phenol polyoxyethanyl polypropylene-base ether 5%, AEO 3%, silicone 1.6%, sodium tripolyphosphate
1.2%, PH conditioning agent NaOH and hydrochloric acid altogether 3%, water add to 100% weight portion, prepare 12% fluorine lice sulfalene ammonia
Base abamectin benzoate microcapsule suspension-suspendinagent agent.
Emamectin-benzoate is changed to AVM, pleocidin, ethyl pleocidin can form new embodiment.
Embodiment 2880% fluorine lice sulfanilamide (SN) pleocidin wettable powder
Fluorine lice sulfanilamide (SN) 60%, pleocidin 20%, lignosulfonates 6%, lauryl sodium sulfate 5%, attapulgite add to
100%, mixture carries out air-flow crushing, prepares 80% fluorine lice sulfanilamide (SN) pleocidin wettable powder.
Effective active composition pleocidin is changed to emamectin-benzoate, AVM, ethyl pleocidin shape
The embodiment of Cheng Xin.
Embodiment 2930% fluorine lice sulfanilamide (SN) pleocidin wettable powder
Fluorine lice sulfanilamide (SN) 20%, pleocidin 10%, aliphatic alcohol polyethenoxy base ether 6%, Nekal BX 5%, kaolin add to
100%, mixture carries out air-flow crushing, prepares 30% fluorine lice sulfanilamide (SN) pleocidin wettable powder.
Effective active composition pleocidin is changed to AVM, emamectin-benzoate, ethyl pleocidin shape
The embodiment of Cheng Xin.
Embodiment 3060% fluorine lice sulfanilamide (SN) pleocidin water dispersible granules
Fluorine lice sulfanilamide (SN) 20%, pleocidin 40%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 5%, silkworm excrement 6%, glucose 2.6%, swollen
Profit soil adds to 100%, is mixed to prepare 60% fluorine lice sulfanilamide (SN) pleocidin water dispersible granules.
Effective active composition pleocidin is changed to AVM, emamectin-benzoate, ethyl pleocidin shape
The embodiment of Cheng Xin.
Embodiment 3130% fluorine lice sulfanilamide (SN) pleocidin water dispersible granules
Fluorine lice sulfanilamide (SN) 15%, pleocidin 15%, neopelex 5%, octylphenol polyethylene oxyethylene group ether sulfate
6%, ammonium sulfate 2%, kaolin add to 100%, are mixed to prepare
30% fluorine lice sulfanilamide (SN) pleocidin water dispersible granules.
Effective active composition pleocidin is changed to AVM, emamectin-benzoate, ethyl pleocidin shape
The embodiment of Cheng Xin.
Embodiment 3215% fluorine lice sulfanilamide (SN) pleocidin suspension
Fluorine lice sulfanilamide (SN) 10%, pleocidin 5%, alkyl benzene sulfonate calcium salt 5%, lauryl sodium sulfate 4%, silicone oil 0.1%, three
Polyphosphate sodium 0.2%, glycerine 4%, deionized water add to 100%, are mixed to prepare 15% fluorine lice sulfanilamide (SN) pleocidin and suspend
Agent.
Effective active composition pleocidin is changed to AVM, emamectin-benzoate, ethyl pleocidin shape
The embodiment of Cheng Xin.
Embodiment 3330% fluorine lice sulfanilamide (SN) pleocidin suspension
Fluorine lice sulfanilamide (SN) 25%, pleocidin 5%, polycarboxylate 6%, tea seed cake 4%, silicone 0.07%, xanthans 0.14%, third
Triol 3%, deionized water add to 100%, are mixed to prepare 30% fluorine lice sulfanilamide (SN) pleocidin suspension.
Effective active composition pleocidin is changed to AVM, emamectin-benzoate, ethyl pleocidin shape
The embodiment of Cheng Xin.
Embodiment 3410% fluorine lice sulfanilamide (SN) pleocidin suspension emulsion
Fluorine lice sulfanilamide (SN) 5%, pleocidin 5%, alkyl benzene sulfonate calcium salt 6%, wetting and penetrating agent F 4%, alkylphenol-formaldehyde resin
Polyoxyethyl ether 6%, EGME 5%, C10～20Saturated fat acids 0.1%, polyvinyl alcohol 0.12%, polyethylene glycol
2.5%, deionized water adds to 100%, is mixed to prepare 10% fluorine lice sulfanilamide (SN) pleocidin suspension emulsion.
Effective active composition pleocidin is changed to AVM, emamectin-benzoate, ethyl pleocidin shape
The embodiment of Cheng Xin.
Embodiment 3525% fluorine lice sulfanilamide (SN) pleocidin suspension emulsion
Fluorine lice sulfanilamide (SN) 5%, pleocidin 20%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 7%, sldium lauryl sulfate 6%, phenethyl phenol
Formaldehyde resin polyoxyethyl ether 6%, ethyl acetate 4%, C8～10Aliphatic alcohols 0.1%, methylcellulose 0.15%, glycerine 4%,
Deionized water adds to 100%, is mixed to prepare 25% fluorine lice sulfanilamide (SN) pleocidin suspension emulsion.
Effective active composition pleocidin is changed to AVM, emamectin-benzoate, ethyl pleocidin shape
The embodiment of Cheng Xin.
Embodiment 3621% fluorine lice sulfanilamide (SN) pleocidin microemulsion
Fluorine lice sulfanilamide (SN) 20%, pleocidin 1%, propyl alcohol 6%, phenolic resin 0.18%, alkylaryl polyoxyethylene polyoxypropylene
Ether 6%, silicone 0.14%, deionized water supplies 100%, prepares 21% fluorine lice sulfanilamide (SN) pleocidin microemulsion.
Effective active composition pleocidin is changed to AVM, emamectin-benzoate, ethyl pleocidin shape
The embodiment of Cheng Xin.
Embodiment 3720% fluorine lice sulfanilamide (SN) pleocidin microemulsion
Fluorine lice sulfanilamide (SN) 15%, pleocidin 5%, cyclohexanone 6%, PAA 0.19%, sorbitan monostearate 7%,
C8～10Aliphatic alcohols 0.09%, triethylene glycol 3.5%, deionized water supplies 100%, prepares 20% fluorine lice sulfanilamide (SN) pleocidin micro-
Emulsion.
Effective active composition pleocidin is changed to AVM, emamectin-benzoate, ethyl pleocidin shape
The embodiment of Cheng Xin.
Embodiment 3825% fluorine lice sulfanilamide (SN) pleocidin aqueous emulsion
Fluorine lice sulfanilamide (SN) 15%, pleocidin 10%, acetonitrile 5%, toluene 5%, alkyl biphenyl ether disulfonic acid magnesium salts 6%, xanthans
0.18%, silicone compound 0.08%, ethylene glycol 4%, deionized water adds to 100%, is mixed to prepare 25% fluorine lice sulfanilamide (SN)
Pleocidin aqueous emulsion.
Effective active composition pleocidin is changed to AVM, emamectin-benzoate, ethyl pleocidin shape
The embodiment of Cheng Xin.
Embodiment 3930.5% fluorine lice sulfanilamide (SN) pleocidin aqueous emulsion
Fluorine lice sulfanilamide (SN) 30%, pleocidin 0.5%, DMF 5%, N octylpyrrolidone 5%, alkyl phenol
Formaldehyde resin polyoxyethyl ether 6%, xanthans 0.18%, C8～10Aliphatic alcohols 0.06%, deionized water adds to 100%, mixing
Prepare 30.5% fluorine lice sulfanilamide (SN) pleocidin aqueous emulsion.
Effective active composition pleocidin is changed to AVM, emamectin-benzoate, ethyl pleocidin shape
The embodiment of Cheng Xin.
Embodiment 4011% fluorine lice sulfanilamide (SN) spinosad microcapsule suspending agent
Fluorine lice sulfanilamide (SN) 1%, pleocidin 10%, urea 3%, sodium alginate 3%, sldium lauryl sulfate 5%, alkyl phenol polyoxy second
Alkene is phonetic 2.8%, vegetable oil 6%, styrene polyoxyethylene ether ammonium sulfate salt 5%, ph conditioning agent NaOH and hydrochloric acid amount to
4%, deionized water adds to 100% weight portion, prepares 11% fluorine lice sulfanilamide (SN) spinosad microcapsule suspending agent.
Effective active composition pleocidin is changed to AVM, emamectin-benzoate, ethyl pleocidin shape
The embodiment of Cheng Xin.
Embodiment 4121% fluorine lice sulfanilamide (SN) pleocidin microcapsule suspension-suspendinagent agent
Fluorine lice sulfanilamide (SN) 20%, pleocidin 1%, gelatin 5%, Arabic gum 2%, lauryl sodium sulfate 2.5%, vegetable oil
6%, phenethyl fluosite polyoxyethyl ether 5%, castor oil polyoxyethylene ether 3%, silicone compound 0.06%, poly-second
Alkene pyrrolidone 1.2%, ph conditioning agent NaOH and hydrochloric acid amount to 3.8%, and deionized water adds to 100% weight portion, prepare
21% fluorine lice sulfanilamide (SN) pleocidin microcapsule suspension-suspendinagent agent.
Effective active composition pleocidin is changed to AVM, emamectin-benzoate, ethyl pleocidin shape
The embodiment of Cheng Xin.
Embodiment 4260% fluorine lice sulfanilamide (SN) ethyl pleocidin wettable powder
Fluorine lice sulfanilamide (SN) 50%, ethyl pleocidin 10%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 4%, neopelex
5%, diatomite adds to 100%, and mixture carries out air-flow crushing, prepares 60% fluorine lice sulfanilamide (SN) ethyl pleocidin wettable powder
Agent.
Effective active composition ethyl pleocidin is changed to emamectin-benzoate, AVM, pleocidin shape
The embodiment of Cheng Xin.
Embodiment 4330% fluorine lice sulfanilamide (SN) ethyl pleocidin wettable powder
Fluorine lice sulfanilamide (SN) 15%, ethyl pleocidin 15%, alkylphenol-polyethenoxy phonetic formaldehyde condensation products sulfate 5%, spaonin powder
4%, kaolin adds to 100%, and mixture carries out air-flow crushing, prepares 30% fluorine lice sulfanilamide (SN) ethyl pleocidin wettable powder
Agent.
Effective active composition ethyl pleocidin is changed to AVM, emamectin-benzoate, pleocidin shape
The embodiment of Cheng Xin.
Embodiment 4425% fluorine lice sulfanilamide (SN) ethyl pleocidin water dispersible granules
Fluorine lice sulfanilamide (SN) 15%, ethyl pleocidin 10%, alkylphenol-polyethenoxy are phonetic 6%, tea seed cake 4%, aluminium chloride 3%, lightweight
Calcium carbonate adds to 100%, is mixed to prepare 25% fluorine lice sulfanilamide (SN) ethyl pleocidin water dispersible granules.
Effective active composition ethyl pleocidin is changed to AVM, emamectin-benzoate, pleocidin shape
The embodiment of Cheng Xin.
Embodiment 4550% fluorine lice sulfanilamide (SN) ethyl pleocidin water dispersible granules
Fluorine lice sulfanilamide (SN) 40%, ethyl pleocidin 10%, sldium lauryl sulfate 5%, the phonetic formaldehyde condensation products of alkylphenol-polyethenoxy
Sulfate 6%, sodium carbonate 2%, kaolin add to 100%, are mixed to prepare 50% fluorine lice sulfanilamide (SN) ethyl pleocidin water-dispersible
Granula.
Effective active composition ethyl pleocidin is changed to AVM, emamectin-benzoate, pleocidin shape
The embodiment of Cheng Xin.
Embodiment 4630% fluorine lice sulfanilamide (SN) ethyl pleocidin suspending agent
Fluorine lice sulfanilamide (SN) 20%, ethyl pleocidin 10%, polycarboxylate 5%, neopelex 4%, silicone
0.1%, phenolic resin 0.2%, glycerine 4%, deionized water add to 100%, are mixed to prepare 30% fluorine lice sulfanilamide (SN) ethyl and kill more
Rhzomorph suspending agent.
Effective active composition ethyl pleocidin is changed to AVM, emamectin-benzoate, pleocidin shape
The embodiment of Cheng Xin.
Embodiment 4720% fluorine lice sulfanilamide (SN) ethyl pleocidin suspending agent
Fluorine lice sulfanilamide (SN) 5%, ethyl pleocidin 15%, alkylphenol-polyethenoxy phonetic formaldehyde condensation products sulfate 5%, laruyl alcohol sulphur
Acid sodium 4%, C8～10Aliphatic alcohols 0.07%, guar gum 0.14%, diethylene glycol (DEG) 3%, deionized water add to 100%, are mixed to prepare
20% fluorine lice sulfanilamide (SN) ethyl pleocidin suspending agent.
Effective active composition ethyl pleocidin is changed to AVM, emamectin-benzoate, pleocidin shape
The embodiment of Cheng Xin.
Embodiment 4825% fluorine lice sulfanilamide (SN) ethyl pleocidin suspension emulsion
Fluorine lice sulfanilamide (SN) 20%, ethyl pleocidin 5%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 6%, tea seed cake 4%, phenethyl phenol formaldehyde
Resin polyoxyethyl ether 6%, butyl ether 5%, silicone oil 0.1%, white dextrin 0.12%, diethylene glycol (DEG) 3.5%, deionized water add to
100%, it is mixed to prepare 25% fluorine lice sulfanilamide (SN) ethyl pleocidin suspension emulsion.
Effective active composition ethyl pleocidin is changed to AVM, emamectin-benzoate, pleocidin shape
The embodiment of Cheng Xin.
Embodiment 4935% fluorine lice sulfanilamide (SN) ethyl pleocidin suspension emulsion
Fluorine lice sulfanilamide (SN) 25%, ethyl pleocidin 10%, alkylphenol-polyethenoxy are phonetic 7%, lauryl sodium sulfate 6%, nonyl
Phenol polyethenoxy ether phosphate 6%, N-pyrrolidones 4%, C10～20Saturated fat acids (such as capric acid) and acid amides 0.07%, hydroxyl
Methylcellulose 0.15%, ethylene glycol 4%, deionized water add to 100%, are mixed to prepare the 35% fluorine lice many sterilizations of sulfanilamide (SN) ethyl
Element suspension emulsion.
Effective active composition ethyl pleocidin is changed to AVM, emamectin-benzoate, pleocidin shape
The embodiment of Cheng Xin.
Embodiment 5011% fluorine lice sulfanilamide (SN) ethyl pleocidin microemulsion
Fluorine lice sulfanilamide (SN) 10%, ethyl pleocidin 1%, cyclohexanone 5%, xanthans 0.12%, sorbitan monostearate
6%, C8～10Aliphatic alcohols 0.14%, deionized water supplies 100%, prepares 11% fluorine lice sulfanilamide (SN) ethyl pleocidin micro emulsion
Agent.
Effective active composition ethyl pleocidin is changed to AVM, emamectin-benzoate, pleocidin shape
The embodiment of Cheng Xin.
Embodiment 5130% fluorine lice sulfanilamide (SN) ethyl pleocidin aqueous emulsion
Fluorine lice sulfanilamide (SN) 20%, ethyl pleocidin 10%, solvent naphtha 5%, vegetable oil 5%, styrene polyoxyethylene ether ammonium sulfate
Salt salt 6%, Arabic gum 0.11%, silicone 0.08%, triethylene glycol 4%, deionized water adds to 100%, is mixed to prepare 30%
Fluorine lice sulfanilamide (SN) ethyl pleocidin aqueous emulsion.
Effective active composition ethyl pleocidin is changed to AVM, emamectin-benzoate, pleocidin shape
The embodiment of Cheng Xin.
Embodiment 5225% fluorine lice sulfanilamide (SN) ethyl pleocidin aqueous emulsion
Fluorine lice sulfanilamide (SN) 12.5%, ethyl pleocidin 12.5%, 3-methyl cyclohexanol ketenes 5%, propyl alcohol 5%, phenethyl phenol formaldehyde
Resin polyoxyethyl ether 6%, sodium tripolyphosphate 0.18%, C10～20Saturated fat acids (such as capric acid) and acid amides 0.11%, go from
Sub-water adds to 100%, is mixed to prepare 25% fluorine lice sulfanilamide (SN) ethyl pleocidin aqueous emulsion.
Effective active composition ethyl pleocidin is changed to AVM, emamectin-benzoate, pleocidin shape
The embodiment of Cheng Xin.
Embodiment 5330% fluorine lice sulfanilamide (SN) ethyl pleocidin micro-capsule suspension
Fluorine lice sulfanilamide (SN) 10%, ethyl pleocidin 20%, PIC 4%, formaldehyde 3%, lauryl sodium sulfate 5%, alkane
Base phenol polyethenoxy phonetic formaldehyde condensation products sulfate 2.8%, acetonitrile 6%, alkyl biphenyl ether disulfonic acid magnesium salts 5%, ph conditioning agent
NaOH and citric acid altogether 2.6%, deionized water add to 100% weight portion, prepare 30% fluorine lice sulfanilamide (SN) ethyl and kill more
Rhzomorph micro-capsule suspension.
Effective active composition ethyl pleocidin is changed to AVM, emamectin-benzoate, pleocidin shape
The embodiment of Cheng Xin.
Embodiment 5420% fluorine lice sulfanilamide (SN) ethyl pleocidin microcapsule suspension-suspendinagent agent
Fluorine lice sulfanilamide (SN) 10%, ethyl pleocidin 10%, deformation lactoprotein 5%, polyvinyl alcohol 2%, neopelex
2.5%, ethyl acetate 6%, ethylene oxide-propylene oxide block copolymer 5%, NPE 3%, silicone
Compound 0.6%, PVPP 1.2%, NaOH 0.4%, citric acid 0.5%, water add to 100% weight
Part, prepare 20% fluorine lice sulfanilamide (SN) ethyl pleocidin microcapsule suspension-suspendinagent agent.
Effective active composition ethyl pleocidin is changed to AVM, emamectin-benzoate, pleocidin shape
The embodiment of Cheng Xin.
The embodiment of the present invention is the method using Toxicity Determination and field test to combine.First pass through Toxicity Determination,
Co-toxicity coefficient (CTC) after clear and definite two kinds of medicaments are compounding by a certain percentage, CTC ＜ 80 is antagonism, and 80≤CTC≤120 are
Summation action, CTC ＞ 120 is synergistic effect, on this basis, then carries out field test.
Test method: respectively the mother liquor of each mixed agent is diluted to during test five series concentration, is respectively placed in beaker standby.
Use the method that first leaching leaf is followed by worm, the blade of the same size not in contact with any medicament is soaked in the liquid configured 5s
Rear taking-up, naturally dry, put in insect box, then connect for examination larva, raise under the conditions of 25 DEG C, often process 3 times and repeat,
Often repeating examination borer population used is 50, sets blank simultaneously, checks dead borer population in 72h, calculates the death rate and corrected mortality,
Try to achieve virulence regression equation and calculate LC50Value.If the comparison death rate is more than 10%, then it is considered as invalid test.Computing formula is as follows:
Insect corrected mortality is converted into probit value (y), and concentration for the treatment of (μ g/ml) is converted into logarithm value (x), with least square
Method draws virulence regression equation, and thus calculates the value of every kind of medicament.Co-toxicity coefficient is calculated according to the abundant equation of Sun Yun
CTC.Computing formula is following (with fluorine lice sulfanilamide (SN) as standard agent, its toxicity index is 100):
TI × P active component B of the TI × P fluorine lice sulfanilamide (SN)+active component B of the theoretical toxicity index (TTI) of M=fluorine lice sulfanilamide (SN)
In formula: M is the mixture of different ratio；
P active component B is the ratio that active component B is shared in the composition；
P fluorine lice sulfanilamide (SN) is the ratio that fluorine lice sulfanilamide (SN) is shared in the composition.
Note: active component B is any in AVM, emamectin-benzoate, pleocidin, ethyl pleocidin
One.
Application Example two:
For examination insect: rice hoppers.
Experimental design: determine effective cause of fluorine lice sulfanilamide (SN), the former medicine of AVM and the two different ratio mixture through pilot study
Dead concentration range.
Toxicity test result one
Table 1 fluorine lice sulfanilamide (SN) and the AVM different ratio toxicity test to rice hoppers
As shown in Table 1, fluorine lice sulfanilamide (SN) prevents and treats when fitting over 80:1 to 1:80 of rice hoppers, co-toxicity coefficient with abamectin compounded
It is all higher than 120, illustrates that both all show synergistic effect, especially as fluorine lice sulfanilamide (SN) and Ah at mixture in the range of 80:1 to 1:80
Dimension rhzomorph obtains proportioning when 20:1 to 1:10, and synergistic effect becomes apparent from highlighting, wherein when fluorine lice sulfanilamide (SN) and AVM weight
More maximum than for co-toxicity coefficient during 2:1, synergistic effect is the most obvious.Find simultaneously, fluorine lice sulfanilamide (SN) and AVM proportioning 20:1,
19:1、18:1、17:1、16:1、15:1、14:1、13:1、12:1、11:1、10:1、9:1、8:1、7:1、6:1、5:1、4:1、3:
1, compounding to rice leaf roller, the snout moth's larva of rice, rice when 2:1,1:1,1:2,1:3,1:4,1:5,1:6,1:7,1:8,1:9,1:10
Plant hopper, diamondback moth, cabbage caterpillar, aphid, thrips, mite class, scale insect, chafer, weevil, midge worm, two select committee noctuid, the little reality of tangerine
The insects such as fly also have preferable synergistic effect, and co-toxicity coefficient is all higher than 120.
Application Example three:
For examination insect: paddy rice rice leaf roller.
Experimental design: determine that fluorine lice sulfanilamide (SN), Methylaminoemamectin benzoate and the two difference are joined through pilot study
Ratio
Effective lethasl concentration scope of mixture.
Toxicity test result two
Table 2 fluorine lice sulfanilamide (SN) and the emamectin-benzoate different ratio toxicity test to paddy rice rice leaf roller
As shown in Table 2, fluorine lice sulfanilamide (SN) and emamectin-benzoate compound the proportioning of preventing and treating paddy rice rice leaf roller and exist
During 80:1 to 1:80, co-toxicity coefficient is all higher than 120, illustrates that both mixtures in the range of 80:1 to 1:80 all show synergy and make
With, especially when the proportioning of fluorine lice sulfanilamide (SN) and emamectin-benzoate is at 30:1 to 1:10, synergistic effect is more
The most prominent, wherein when fluorine lice sulfanilamide (SN) and emamectin-benzoate weight ratio are 3:1, co-toxicity coefficient is maximum, synergy
Effect is the most obvious, finds simultaneously, fluorine lice sulfanilamide (SN) and emamectin-benzoate proportioning 30:1,29:1,28:1,
27:1、26:1、25:1、24:1、23:1、22:1、21:1、20:1、19:1、18:1、17:1、16:1、15:1、14:1、13:1、
12:1、11:1、10:1、9:1、8:1、7:1、6:1、5:1、4:1、3:1、2:1、1:1、1:2、1:3、1:4、1:5、1:6、1:7、1:
8, compounding to rice leaf roller, the snout moth's larva of rice, planthopper, diamondback moth, cabbage caterpillar, aphid, thrips, mite class, Jie when 1:9,1:10
Shell worm, chafer, weevil, midge worm, 2 committee insects such as noctuid, citrus fruit fly also have preferable synergistic effect, poison system altogether
Number is all higher than 140.
Application Example four:
For examination insect: wild cabbage diamondback moth.
Experimental design: determine having of fluorine lice sulfanilamide (SN), the former medicine of ethyl pleocidin and the two different ratio mixture through pilot study
Effect lethasl concentration scope.
Toxicity test result three
Table 3 fluorine lice sulfanilamide (SN) and the ethyl pleocidin different ratio toxicity test to wild cabbage diamondback moth
As shown in Table 3, fluorine lice sulfanilamide (SN) and ethyl pleocidin compound the proportioning of preventing and treating wild cabbage diamondback moth when 80:1 to 1:80, altogether
Poison coefficient is all higher than 120, illustrates that both all show synergistic effect, especially when fluorine lice sulphur at mixture in the range of 80:1 to 1:80
The proportioning of amine and ethyl pleocidin is when 20:1 to 1:10, and synergistic effect becomes apparent from highlighting, wherein when fluorine lice sulfanilamide (SN) and second
When Quito bacteriocidin weight ratio is 1:1, co-toxicity coefficient is maximum, and synergistic effect is the most obvious, finds, fluorine lice sulfanilamide (SN) and ethyl simultaneously
Pleocidin proportioning 20:1,10:1,9:1,8:1,7:1,6:1,5:1,4:1,3:1,2:1,1:1,1:2,1:3,1:4,1:5,
1:6,1:7,1:8,1:9,1:10, time compounding to rice leaf roller, the snout moth's larva of rice, planthopper, diamondback moth, cabbage caterpillar, aphid, Ji
Horse, mite class, scale insect, chafer, weevil, midge worm, 2 committee insects such as noctuid, citrus fruit fly also have preferable synergy and make
With, co-toxicity coefficient is all higher than 150.
Application Example five:
For examination insect: apple aphid.
Experimental design: determine effective cause of fluorine lice sulfanilamide (SN), the former medicine of pleocidin and the two different ratio mixture through pilot study
Dead concentration range.
Toxicity test result four
Table 4 fluorine lice sulfanilamide (SN) and the pleocidin different ratio toxicity test to apple aphid
As shown in Table 4, the proportioning of fluorine lice sulfanilamide (SN) and pleocidin compound preventing and treating apple aphid when 80:1 to 1:80, co-toxicity coefficient
It is all higher than 120, illustrates that both mixtures in the range of 80:1 to 1:80 all show synergistic effect, especially when fluorine lice sulfanilamide (SN) is with many
The proportioning of bacteriocidin is when 20:1 to 1:10, and synergistic effect becomes apparent from highlighting, wherein when fluorine lice sulfanilamide (SN) and pleocidin weight
Than being that during 2:1, co-toxicity coefficient is maximum, synergistic effect is the most obvious, finds simultaneously, fluorine lice sulfanilamide (SN) and pleocidin proportioning 20:1,
19:1、18:1、17:1、16:1、15:1、14:1、13:1、12:1、11:1、10:1、9:1、8:1、7:1、6:1、5:1、4:1、3:
1,2:1,1:1,1:2,1:3,1:4,1:5,1:6,1:7,1:8,1:9,1:10, time compounding to rice leaf roller, the snout moth's larva of rice, rice
Plant hopper, diamondback moth, cabbage caterpillar, aphid, thrips, mite class, scale insect, chafer, weevil, midge worm, two select committee noctuid, the little reality of tangerine
The insects such as fly also have preferable synergistic effect, and co-toxicity coefficient is all higher than 140.
Application Example hexafluoro lice sulfanilamide (SN) and AVM, emamectin-benzoate, pleocidin, the many sterilizations of ethyl
Element and the effect test of compounding preventing and treating wild cabbage diamondback moth thereof
This EE is provided by Shaanxi Welch Crop Protection Co., Ltd. at Qishan County of Baoji, Shaanxi province city, test medicine,
Comparison medicament 10% fluorine lice sulfanilamide (SN) suspending agent (autogamy), 2% abamectin emulsifiable concentrate (commercial), 3% Affirm (Merck Co.) benzene first
Hydrochlorate water dispersible granules, 5% pleocidin suspension (commercial), the ethyl pleocidin suspending agent (commercial) of 60 grams per liters.
Test uses conventional spray-on process, investigates wild cabbage diamondback moth insect pest index before medicine, in insect pest early period of origination dispenser, after dispenser 1
My god, 3 days, 7 days investigation insect pest indexes calculate preventive effect.Experimental result is as follows:
Table 5 fluorine lice sulfanilamide (SN) and AVM, emamectin-benzoate, pleocidin, ethyl pleocidin and
The compounding preventing and treating wild cabbage diamondback moth test of pesticide effectiveness
As can be seen from Table 5, fluorine lice sulfanilamide (SN) kills with AVM, emamectin-benzoate, pleocidin, ethyl more
Can effectively prevent and treat wild cabbage diamondback moth after rhzomorph is compounding, prevention effect is superior to the preventive effect of single dose, and efficiency time is long.Use in test
In the range of medicine, target crop is had no adverse effects.
Application Example seven fluorine lice sulfanilamide (SN) and AVM and the test of pesticide effectiveness of compounding preventing and treating rice-stem borer thereof
This EE is in Pingchang County, Bazhong City, Sichuan Province, and test medicine is provided by Shaanxi Welch Crop Protection Co., Ltd.,
10% fluorine lice sulfanilamide (SN) suspending agent (autogamy), 2% abamectin emulsifiable concentrate (commercial), 3% emamectin-benzoate moisture
Shot agent, 5% pleocidin suspension (commercial), the ethyl pleocidin suspending agent (commercial) of 60 grams per liters.
Test uses conventional spray-on process, investigates rice-stem borer insect pest index before medicine, in insect pest early period of origination dispenser, after dispenser 1
My god, 5 days, 7 days investigation insect pest indexes calculate preventive effect.Experimental result is as follows:
Table 6 fluorine lice sulfanilamide (SN) and AVM, emamectin-benzoate, pleocidin, ethyl pleocidin and multiple
Join the preventing and treating rice-stem borer test of pesticide effectiveness
As can be seen from Table 6, fluorine lice sulfanilamide (SN) kills with AVM, emamectin-benzoate, pleocidin, ethyl more
Can effectively prevent and treat rice-stem borer after rhzomorph is compounding, prevention effect is superior to the preventive effect of single dose, and efficiency time is long.Use in test
In the range of medicine, target crop is had no adverse effects.
Application Example octafluoro lice sulfanilamide (SN) and AVM, emamectin-benzoate, pleocidin, the many sterilizations of ethyl
Element and the test of pesticide effectiveness of compounding and compounding preventing and treating cotton boll worm thereof
This EE is provided by Shaanxi Welch Crop Protection Co., Ltd. at Changan District, Xi'an City, Shanxi Province, test medicine,
10% fluorine lice sulfanilamide (SN) suspending agent (autogamy), 2% abamectin emulsifiable concentrate (commercial), 3% emamectin-benzoate moisture
Shot agent, 5% pleocidin suspension (commercial), the ethyl pleocidin suspending agent (commercial) of 60 grams per liters.
Test uses conventional spray-on process, investigates cotton boll pests index before medicine, in insect pest early period of origination dispenser, after dispenser 1
My god, 5 days, 7 days investigation insect pest indexes calculate preventive effect.Experimental result is as follows:
Table 7 fluorine lice sulfanilamide (SN), AVM, emamectin-benzoate, pleocidin, ethyl pleocidin and compounding
The preventing and treating cotton boll worm test of pesticide effectiveness
As can be seen from Table 7, fluorine lice sulfanilamide (SN) kills with AVM, emamectin-benzoate, pleocidin, ethyl more
Can effectively prevent and treat cotton boll worm after rhzomorph is compounding, prevention effect is superior to the preventive effect of single dose, and efficiency time is long.Use in test
In the range of medicine, target crop is had no adverse effects.
Application Example nine fluorine lice sulfanilamide (SN) and AVM, emamectin-benzoate, pleocidin, the many sterilizations of ethyl
Element and compounding prevent and treat the rice hoppers test of pesticide effectiveness
This EE is in Weinan City Pucheng County, Shaanxi Province, and test medicine is provided by Shaanxi Welch Crop Protection Co., Ltd.,
Comparison medicament 10% fluorine lice sulfanilamide (SN) suspending agent (autogamy), 2% abamectin emulsifiable concentrate (commercial), 3% Affirm (Merck Co.) benzene first
Hydrochlorate water dispersible granules, 5% pleocidin suspension (commercial), the ethyl pleocidin suspending agent (commercial) of 60 grams per liters.
Test uses conventional spray-on process, investigates cotton pink bollworm insect pest index before medicine, in insect pest early period of origination dispenser, after dispenser 1
My god, 5 days, 7 days investigation insect pest indexes calculate preventive effect.Experimental result is as follows:
Table 8 fluorine lice sulfanilamide (SN), AVM, emamectin-benzoate, pleocidin, ethyl pleocidin and compounding
Prevent and treat the rice hoppers test of pesticide effectiveness
As can be seen from Table 8, fluorine lice sulfanilamide (SN) kills with AVM, emamectin-benzoate, pleocidin, ethyl more
Can effectively prevent and treat rice hoppers after rhzomorph is compounding, prevention effect is superior to the preventive effect of single dose, and efficiency time is long.Use in test
In the range of medicine, target crop is had no adverse effects.
Application Example ten fluorine lice sulfanilamide (SN) and AVM, emamectin-benzoate, pleocidin, the many sterilizations of ethyl
Element and the test of pesticide effectiveness of compounding preventing and treating eggplant thrips thereof
This EE is provided by Shaanxi Welch Crop Protection Co., Ltd. at Yangling District, Shaanxi Province, test medicine, compares medicine
Agent 10% fluorine lice sulfanilamide (SN) suspending agent (autogamy), 2% abamectin emulsifiable concentrate (commercial), 3% emamectin-benzoate water
Dispersible granule, 5% pleocidin suspension (commercial), the ethyl pleocidin suspending agent (commercial) of 60 grams per liters.
Test uses conventional spray-on process, investigates eggplant thrips insect pest index before medicine, in insect pest early period of origination dispenser, after dispenser 1 day,
Within 5 days, 7 days, investigate insect pest indexes and calculate preventive effect.Experimental result is as follows:
Table 9 fluorine lice sulfanilamide (SN), AVM, emamectin-benzoate, pleocidin, ethyl pleocidin and compounding
The preventing and treating eggplant thrips test of pesticide effectiveness
As can be seen from Table 9, fluorine lice sulfanilamide (SN) kills with AVM, emamectin-benzoate, pleocidin, ethyl more
Can effectively prevent and treat eggplant thrips after rhzomorph is compounding, prevention effect is superior to the preventive effect of single dose, and efficiency time is long.In test medication
In the range of target crop is had no adverse effects.
Application Example 11 fluorine lice sulfanilamide (SN) kills with AVM, emamectin-benzoate, pleocidin, ethyl more
Rhzomorph and compounding preventing and treating corn 2 the committee noctuid test of pesticide effectiveness thereof
This EE is provided by Shaanxi Welch Crop Protection Co., Ltd. at Changan District, Xi'an City, Shanxi Province, test medicine,
Comparison medicament 10% fluorine lice sulfanilamide (SN) suspending agent (autogamy), 2% abamectin emulsifiable concentrate (commercial), 3% Affirm (Merck Co.) benzene first
Hydrochlorate water dispersible granules, 5% pleocidin suspension (commercial), the ethyl pleocidin suspending agent (commercial) of 60 grams per liters.
Test uses conventional spray-on process, investigates corn 2 committee noctuid insect pest index, in insect pest early period of origination dispenser, dispenser before medicine
Within latter 1 day, 5 days, 7 days, investigate insect pest indexes and calculate preventive effect.Experimental result is as follows:
Table 10 fluorine lice sulfanilamide (SN), AVM, emamectin-benzoate, pleocidin, ethyl pleocidin and multiple
Join and prevent and treat corn 2 the committee noctuid test of pesticide effectiveness
As can be seen from Table 10, fluorine lice sulfanilamide (SN) and AVM, emamectin-benzoate, pleocidin, ethyl are many
Can effectively prevent and treat corn 2 committee noctuid after bacteriocidin is compounding, prevention effect is superior to the preventive effect of single dose, and efficiency time is long.?
In test scope of medication, target crop is had no adverse effects.
Application Example ten difluoro lice sulfanilamide (SN) kills with AVM, emamectin-benzoate, pleocidin, ethyl more
Rhzomorph and the test of pesticide effectiveness of compounding preventing and treating cucumber aleyrodid thereof
This EE is provided by Shaanxi Welch Crop Protection Co., Ltd. at XiaoShan, HangZhou City, Zhejiang Province district, test medicine,
Comparison medicament 10% fluorine lice sulfanilamide (SN) suspending agent (autogamy), 2% abamectin emulsifiable concentrate (commercial), 3% Affirm (Merck Co.) benzene first
Hydrochlorate water dispersible granules, 5% pleocidin suspension (commercial), the ethyl pleocidin suspending agent (commercial) of 60 grams per liters.
Test uses conventional spray-on process, investigates cucumber powder mite evil index before medicine, in insect pest early period of origination dispenser, after dispenser 1 day,
Within 5 days, 7 days, investigate insect pest indexes and calculate preventive effect.Experimental result is as follows:
Table 11 fluorine lice sulfanilamide (SN), AVM, emamectin-benzoate, pleocidin, ethyl pleocidin and multiple
Join the preventing and treating cucumber aleyrodid test of pesticide effectiveness
As can be seen from Table 11, fluorine lice sulfanilamide (SN) and AVM, emamectin-benzoate, pleocidin, ethyl are many
Can effectively prevent and treat cucumber aleyrodid after bacteriocidin is compounding, prevention effect is superior to the preventive effect of single dose, and efficiency time is long.Use in test
In the range of medicine, target crop is had no adverse effects.
After draw through tests different local throughout the country, fluorine lice sulfanilamide (SN) and AVM, Affirm (Merck Co.) benzene first
Hydrochlorate, ethyl pleocidin, pleocidin compound make wettable powder, water dispersible granules, suspending agent, suspension emulsion, aqueous emulsion,
After microemulsion, microcapsule suspending agent, microcapsule suspension-suspendinagent agent to the rice leaf roller on all kinds of crops, the snout moth's larva of rice, planthopper,
Diamondback moth, cabbage caterpillar, aphid, thrips, mite class, scale insect, chafer, weevil, midge worm, 2 committees noctuid, citrus fruit flies etc.
The preventive effect of common insect pests, all more than 95%, is better than single dose preventive effect, and synergistic effect is obvious.
Claims (7)
1. fluorine-containing lice sulfanilamide (SN) and a composition pesticide for biogenic substances, comprise active components A and active component B, and its feature exists
In: active components A is fluorine lice sulfanilamide (SN), and active component B is arbitrary a kind of in pleocidin, ethyl pleocidin, and activity
Composition A and weight ratio 1:80 of active component B～80:1.
Composition pesticide the most according to claim 1, it is characterised in that: active components A with the weight ratio of active component B is
1:40～60:1.
Composition pesticide the most according to claim 2, it is characterised in that: fluorine lice sulfanilamide (SN) is 1 with the weight ratio of pleocidin:
10～20:1.
Composition pesticide the most according to claim 2, it is characterised in that: fluorine lice sulfanilamide (SN) and the weight ratio of ethyl pleocidin
For 1:10～10:1.
5. according to the composition pesticide described in any one in Claims 1 to 4, it is characterised in that: composition makes wettable
Pulvis, water dispersible granules, suspending agent, suspension emulsion, aqueous emulsion, microemulsion, micro-capsule suspension, microcapsule suspension-suspendinagent agent.
Composition pesticide the most according to claim 6 is for preventing and treating the application of crop pests.
Application the most according to claim 6, it is characterised in that institute's pest control includes: rice leaf roller, striped rice borer, three changes
Snout moth's larva, planthopper, diamondback moth, cabbage caterpillar, aphid, thrips, mite class, scale insect, chafer, weevil, midge worm, 2 committee noctuid,
Citrus fruit fly.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610087542.6A CN105746521B (en) | 2012-04-12 | 2012-04-12 | A kind of composition pesticide of fluorine-containing lice sulfanilamide (SN) and biogenic substances |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610087542.6A CN105746521B (en) | 2012-04-12 | 2012-04-12 | A kind of composition pesticide of fluorine-containing lice sulfanilamide (SN) and biogenic substances |
| CN201210106597.9A CN103371154B (en) | 2012-04-12 | 2012-04-12 | The composition pesticide of a kind of fluorine-containing lice sulfanilamide (SN) and biogenic substances |
Related Parent Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201210106597.9A Division CN103371154B (en) | 2012-04-12 | 2012-04-12 | The composition pesticide of a kind of fluorine-containing lice sulfanilamide (SN) and biogenic substances |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105746521A true CN105746521A (en) | 2016-07-13 |
| CN105746521B CN105746521B (en) | 2018-08-03 |
Family
ID=56330805
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610087542.6A Expired - Fee Related CN105746521B (en) | 2012-04-12 | 2012-04-12 | A kind of composition pesticide of fluorine-containing lice sulfanilamide (SN) and biogenic substances |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105746521B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106305709A (en) * | 2016-08-20 | 2017-01-11 | 广东中迅农科股份有限公司 | Pesticide micro-emulsion |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1858038A (en) * | 2006-06-09 | 2006-11-08 | 中国科学院上海有机化学研究所 | Oxo fluoroalkyl sulfamide compound and its preparing method and use |
| US20100144888A1 (en) * | 2008-08-18 | 2010-06-10 | Ecosmart Technologies, Inc. | Pesticidal methods and compositions for modulating gaba receptors |
| US20100215706A1 (en) * | 2006-05-25 | 2010-08-26 | Dow Agrosciences Llc | Spinosyn fumigants |
-
2012
- 2012-04-12 CN CN201610087542.6A patent/CN105746521B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20100215706A1 (en) * | 2006-05-25 | 2010-08-26 | Dow Agrosciences Llc | Spinosyn fumigants |
| CN1858038A (en) * | 2006-06-09 | 2006-11-08 | 中国科学院上海有机化学研究所 | Oxo fluoroalkyl sulfamide compound and its preparing method and use |
| US20100144888A1 (en) * | 2008-08-18 | 2010-06-10 | Ecosmart Technologies, Inc. | Pesticidal methods and compositions for modulating gaba receptors |
Non-Patent Citations (2)
| Title |
|---|
| 付群梅 等: ""氟虱磺胺(SIOC-I-002)对水稻褐飞虱的生物活性及田间防效"", 《植物保护学报》 * |
| 沈娟等: ""10%SIOC-I-002水乳剂配方研究"", 《上海化工》 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106305709A (en) * | 2016-08-20 | 2017-01-11 | 广东中迅农科股份有限公司 | Pesticide micro-emulsion |
Also Published As
| Publication number | Publication date |
|---|---|
| CN105746521B (en) | 2018-08-03 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103283734B (en) | A kind of brominated cyanogen insect amide and the Pesticidal combination of biogenic substances | |
| CN102349539B (en) | Insecticidal composition containing lythidathion and antibiotic compound | |
| CN103355319A (en) | Insecticidal composition containing pyridalyl and biological source | |
| CN101564038B (en) | Insecticidal composition containing metaflumizone | |
| CN104186514A (en) | Pesticide composition containing cyhalodiamide | |
| CN104970038B (en) | A kind of composition pesticide | |
| CN101406197B (en) | Compositional mite-killing composition containing spirodiclofen and ivermectin | |
| CN103238630A (en) | Bifenazate-bearing insecticidal composition | |
| CN103250716B (en) | A kind of Pesticidal combination containing spiral shell worm ethyl ester and neires toxin | |
| CN104705329A (en) | Pesticide composition of chlorantraniliprole and benzoyl urea insecticides | |
| CN105994275B (en) | A kind of composition pesticide of ring tebufenozide and biogenic substances | |
| CN103314987A (en) | Insecticidal composition containing chromafenozide and pyrethroids | |
| CN103300036A (en) | Insecticidal composition containing flonicamid | |
| CN105746521A (en) | Chromafenozid-containing biogenic pesticide composition | |
| CN103355299A (en) | Insecticide composition containing pyridalyl and nereistoxin | |
| CN103371154B (en) | The composition pesticide of a kind of fluorine-containing lice sulfanilamide (SN) and biogenic substances | |
| CN103355320A (en) | Efficient environment-friendly pesticide compound composition | |
| CN103283738B (en) | A kind of Pesticidal combination containing spiral shell worm ethyl ester | |
| CN102217645B (en) | Insecticidal composition containing novaluron and organophosphorus compounds | |
| CN102326570A (en) | Pesticide composition containing novaluron and antibiotics compound | |
| CN103283741A (en) | Tolfenpyrad-containing pesticidal composition | |
| CN103300005A (en) | Insecticidal composition comprising tolfenpyrad and nereistoxin | |
| CN105454259A (en) | Insecticidal combination containing o-phenylenediamine insecticide and abamectin | |
| CN101543224B (en) | Insecticidal composition containing triaguron and chlorpyrifos | |
| CN103300002A (en) | Insecticidal composition containing chromafenozide and nereistoxins |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| CP01 | Change in the name or title of a patent holder |
Address after: 715500 Pucheng Shaanxi chemical base industrial park, Shaanxi, Weinan Patentee after: Shaanxi yitianfeng crop Technology Co.,Ltd. Address before: 715500 Pucheng Shaanxi chemical base industrial park, Shaanxi, Weinan Patentee before: Shaanxi Welch Crop Protection Co.,Ltd. |
|
| CP01 | Change in the name or title of a patent holder | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20180803 |
|
| CF01 | Termination of patent right due to non-payment of annual fee |