CN103283734B - A kind of brominated cyanogen insect amide and the Pesticidal combination of biogenic substances - Google Patents
A kind of brominated cyanogen insect amide and the Pesticidal combination of biogenic substances Download PDFInfo
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- CN103283734B CN103283734B CN201210042444.2A CN201210042444A CN103283734B CN 103283734 B CN103283734 B CN 103283734B CN 201210042444 A CN201210042444 A CN 201210042444A CN 103283734 B CN103283734 B CN 103283734B
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- insect amide
- cyanogen insect
- bromine cyanogen
- ethyl pleocidin
- amide
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Abstract
The invention discloses a kind of brominated cyanogen insect amide and the Pesticidal combination of biogenic substances, being characterized mainly in that of said composition: containing active components A, active component B, adjuncts Balance.Wherein active components A is bromine cyanogen insect amide, active component B is arbitrary a kind of in avilamycin, ethyl pleocidin, and the weight ratio 1: 80～80: 1 of active components A and active component B, compositions makes wettable powder, water dispersible granules, suspending agent, suspension emulsion, aqueous emulsion, microemulsion, micro-capsule suspension, microcapsule suspension suspending agent.The present composition can prevent and treat various pests, and has obvious potentiation, expands insecticidal spectrum, and the insect on Oryza sativa L., Semen Tritici aestivi, Cotton Gossypii, fruit tree, brassicaceous vegetable is had greater activity；And having slow releasing function, decrease pesticide usage amount, to person poultry safety, without poisoning, Environmental compatibility is good；The advantages such as preparation adhesion strength strengthens, resistance of rainwater washing against, lasting period length.
Description
Technical field
The invention belongs to technical field of pesticide, relate to a kind of brominated cyanogen insect amide and the Pesticidal combination of biogenic substances.
Background technology
Bromine cyanogen insect amide (cyantraniliprole), the bromo-1-of chemical name: 3-(3-chloro-2-pyridyl)-N-[4-cyanogen
Base-2-methyl-6-[(methylamino) hydroxyl] phenyl]-1H-pyrazoles-5-Methanamide, chemical molecular formula: C19H14BrClN6O2.Bromine
Cyanogen insect amide is E.I.Du Pont Company's second filial generation ryanodine receptor inhibitor insecticides that success is developed after chlorantraniliprole, cyanogen worm
Amide is to be formed by the various polar groups on change phenyl ring, has more efficient, and applicable crops is more extensive, can effectively prevent and treat squama
Wing mesh, Semiptera and coleopteran pest.
Avilamycin (Avermectins), chemical molecular formula: C48H72O14(B1a)·C47H70O14(B1b).Avilamycin
Belonging to biogenic pesticide, it is a kind of macrolide disaccharidase compounds.It it is the natural product separated from soil microorganism
Thing, has insecticide and demodicid mite class and tags and stomach poison function have faint fumigation action, without systemic action.But blade is had very by it
Strong osmosis, can kill subepidermal insect, and the longevity of residure is long.Its not ovicidal.Its mechanism of action is with general insecticide not
Same is that its interference nervous physiology is movable, stimulates release r-aminobutyric acid, and arthropodan nerve is passed by r-aminobutyric acid
Having led inhibitory action, if demodicid mite class becomes demodicid mite paralysis symptom i.e. occur after contacting with medicament with larva with insecticide, inertia does not takes food,
Death after 2-4 days.Because not causing insecticide rapid dehydration, so its lethal effect is slower.But to predatism and parasite
Though there being direct killing effect, but because plant surface residual is few, therefore the damage to beneficial insect is little.
Ethyl pleocidin (spinetoram), chemical molecular formula: C42H69NO10.Ethyl pleocidin is by the many sterilizations of ethyl
Element-J and two kinds of component compositions of ethyl pleocidin-L, act on the nervous system of insecticide, to diamondback moth, beet armyworm, leaf mining
The prevention effect that fly, thrips, Prodenia litura, bean-pod borer have had.
In the real process of agricultural production, pest control is easiest to generate the problem that the generation of pest resistance to insecticide.No
Compound with kind composition, be to prevent and treat the method that resistant insect is the most common.Heterogeneity compounds, according to reality application effect
Really, judge certain compounding be potentiation, add and or antagonism.In most cases, the compounding effect of pesticide all adds
And effect, really have potentiation compounding seldom, especially potentiation clearly, co-toxicity coefficient the highest compounding the most more
Few.Finding through inventor's lot of experiments, after bromine cyanogen insect amide and avilamycin, ethyl pleocidin compound, potentiation shows
Writing, Environmental compatibility is fabulous, considerably reduces pesticide usage amount.
Summary of the invention
The Pesticidal combination that the present invention proposes contains in bromine cyanogen insect amide and avilamycin, ethyl pleocidin any one
Two kinds of active components, and appropriate surfactant and carrier.
A kind of brominated cyanogen insect amide and the Pesticidal combination of biogenic substances, including active components A, active component B, more than auxiliary agent
Amount, it is characterised in that: active components A is bromine cyanogen insect amide, and active component B is arbitrary in avilamycin, ethyl pleocidin
One, and the weight ratio of active components A and active component B is 1:80～80:1.
Described Pesticidal combination, it is characterised in that: the weight ratio of active components A and active component B is 1:60～40:1.
Described Pesticidal combination, it is characterised in that: the weight ratio of bromine cyanogen insect amide and avilamycin is 1:10～30:1.
Described Pesticidal combination, it is characterised in that: the weight ratio of bromine cyanogen insect amide and ethyl pleocidin be 1:30～
30:1。
Described Pesticidal combination, it is characterised in that: compositions is made wettable powder, water dispersible granules, suspending agent, is hanged
Emulsion, aqueous emulsion, microemulsion, microcapsule suspending agent, microcapsule suspension-suspendinagent agent.
Described Pesticidal combination is for preventing and treating the application of insect on Oryza sativa L., Semen Tritici aestivi, Cotton Gossypii, fruit tree, brassicaceous vegetable.
Described application, pest control includes: brown paddy plant hopper, white backed planthopper, small brown rice planthopper, trialeurodes vaporariorum, Bemisia tabaci, aphid, Jie
Shell worm, thrips, rice leaf roller, striped rice borer, yellow rice borer, twill diamond-back moth, Pieris rapae, apple leaf miner, beet armyworm, tetranychid, wart
Demodicid mite, yellow tea mite, bollworm.
At least containing a kind of surfactant in the Pesticidal combination of the present invention, when being beneficial to use, active component is in water
Dispersion.Surface-active contents is the 5%～30% of total formulation weight amount, and surplus is solid or liquid diluent.The present invention's
Surfactant selected by Pesticidal combination is known in those skilled in the art: can be selected from dispersant, wetting agent, breast
One or more in agent or defoamer.
Described brominated cyanogen insect amide and the Pesticidal combination of biogenic substances, it is characterised in that: bag when making wettable powder
Containing following constituent content: active components A 0.1%～80%, active component B 0.1%～80%, dispersant 5%～10%, wet
Profit agent 2%～10%, filler surplus.
By active components A, active component B, dispersant, wetting agent, filler mixing, mix homogeneously in mixed cylinder, through gas
Stream pulverizer remixes uniformly after pulverizing, and i.e. can be made into wettable powder product of the present invention.
Described brominated cyanogen insect amide and the Pesticidal combination of biogenic substances, it is characterised in that: compositions makes water-dispersible grain
Include following constituent content during agent: active components A 0.1%～80%, active component B 0.1%～80%, dispersant 3%～
12%, wetting agent 1%～8%, disintegrating agent 1%～10%, filler surplus.
Active components A, active component B, dispersant, wetting agent, disintegrating agent, filler etc. are needed through comminution by gas stream together
The particle diameter wanted, obtains granulation materials.Through in item is quantitatively sent into fluidized bed granulating dryer and granulation and dried, prepare this
Water dispersible granules product described in invention.
Described brominated cyanogen insect amide and the Pesticidal combination of biogenic substances, it is characterised in that: when compositions makes suspending agent
Including following constituent content: active components A 0.1%～60%, active component B 0.1%～60%, dispersant 2～10%, wet
Profit agent 2～10%, defoamer 0.1～1%, thickening agent 0.1～2%, antifreeze 0.1～8%, deionized water add to 100%.
Dispersant, wetting agent, defoamer, thickening agent, antifreeze, emulsifying agent in above-mentioned formulation material are mixed through high speed shear
Close uniformly, add bromine cyanogen insect amide, avilamycin ball milling 2～3 hours in ball mill, make diameter of particle all below 5 μm,
Prepare suspending agent product of the present invention.
Described brominated cyanogen insect amide and the Pesticidal combination of biogenic substances, it is characterised in that: when compositions makes suspension emulsion
Including following constituent content: active components A 0.1%～60%, active component B 0.1%～60%, emulsifying agent 2%～12%,
Dispersant 2%～10%, defoamer 0.1%～2%, thickening agent 0.1%～2%, antifreeze 0.1%～8%, stabilizer
0.05%～3%, deionized water adds to 100%.
By dispersant, defoamer, thickening agent, antifreeze, stabilizer in above-mentioned formulation material through high speed shear mix homogeneously,
Add the former medicine of bromine cyanogen insect amide, ball milling 2～3 hours in ball mill, make diameter of particle all below 5 μm, prepare bromine cyanogen worm
Amide suspending agents, then by former for active component B medicine, emulsifying agent and the various direct emulsifying of auxiliary agent high speed agitator to suspending agent
In, prepare suspension emulsion product of the present invention.
Compositions comprises following constituent content when making aqueous emulsion: activity composition A0.1%～60%, active component B
0.1%～60%, solvent 0%～30%, emulsifying agent 1%～15%, co-emulsifier 0%～8%, antifreeze 0%～10%, increasing
Thick dose 0.1%～2%, defoamer 0.01%～2%, deionized water supply surplus.
Above-mentioned formula is mixed, effective ingredient, solvent, emulsifying agent, co-emulsifier are added together, make to be dissolved into uniform oil
Phase；Water, antifreeze, thickening agent, defoamer are mixed, becomes homogeneous aqueous phase.Under high velocity agitation, aqueous phase is added oil
Phase, prepares aqueous emulsion product of the present invention.
Compositions comprises following constituent content when making microemulsion: active components A 0.1%～60%, active component B
0.1%～60%, solvent 0%～30%, emulsifying agent 3%～20%, co-emulsifier 0%～12%, antifreeze 0%～10%,
Thickening agent 0.1%～2%, defoamer 0.01%～2%, stabilizer 0%～4%, deionized water supply surplus.
Bromine cyanogen insect amide and the former medicine of active component B are dissolved in the homogenizer equipped with solvent and cosolvent；By emulsifying agent,
Stabilizer and antifreeze, water strongly mix after joining in the homogenizer equipped with above-mentioned solution and homogenize, and finally obtain
The microemulsion product of the present invention that clear appearance is transparent.
Compositions is made micro-capsule suspension and is included following constituent content: active components A 0.1%～60%, active component
B 0.1%～40%, macromolecule cyst material 1%～12%, surfactant 2%～10%, organic solvent 1%～15%,
Emulsifying agent 1%～8%, pH adjusting agent 0.1%～5%, deionized water add to 100%.
Macromolecule cyst material addition PH regulator is heated to uniform temperature, obtains thick liquid, then dilute,
Form stable prepolymer solution, effective ingredient B, bromine cyanogen insect amide are dissolved in organic solvent, are then added to prepolymer solution
In, add emulsifying agent, surfactant, and fully shear agitation is dispersed into superfine microgranular, adds PH regulator, and rises
Temperature, catalyzed polycondensation forms the firm microcapsule being difficult to infiltration, prepares micro-capsule suspension of the present invention.
When the dosage form of compositions is microcapsule suspension-suspending agent, the auxiliary agent of interpolation be surfactant, emulsifying agent, solvent,
PH regulator, macromolecule cyst material, defoamer, thickening agent, water add to 100%.
Compositions includes following constituent content when making microcapsule suspension-suspendinagent agent: active components A 0.1%～60%, activity
Composition B 0.1%～40%, macromolecule cyst material 2%～12%, surfactant 3%～15%, organic solvent 1%～
5%, emulsifying agent 1%～6%, defoamer 0.2%～5%, thickening agent 0.2%～5%, pH adjusting agent 0.1%～5%, water add
To 100%.
Use interfacial polymerization, by above-mentioned formula having effective ingredient B, macromolecule cyst material, organic solvent mix, make
Be dissolved into homogeneous oil phase, oil phase is joined in a shear condition containing emulsifying agent, pH adjusting agent aqueous phase solution in, two kinds of materials
Material reacts at oil-water interfaces, around the droplet formation macromolecule cyst wall containing chemical substance, makes effective ingredient B microcapsule
Suspending agent.By surfactant, defoamer, thickening agent, antifreeze through high speed shear mix homogeneously, add bromine cyanogen insect amide former
Medicine, ball milling 2～3 hours in ball mill, make diameter of particle all below 5 μm, prepare bromine cyanogen insect amide suspending agent, then will
It is dissolved in water in the aqueous phase solution that stable bromine cyanogen insect amide suspending agent joins effective ingredient B micro-capsule suspension, makes
The present composition finely disseminated microcapsule suspension-suspendinagent agent product.
Described dispersant is selected from alkylnaphthalene sulfonate, double (alkyl) naphthalenesulfonate formaldehyde condensation compound, naphthalenesulfonateformaldehyde formaldehyde contracting
Compound, aryl phenol polyoxyethylene succinate sulfonate, octylphenol polyethylene oxyethylene group ether sulfate, polycarboxylate, sulfomethylated lignin
Hydrochlorate, alkylphenol-polyethenoxy phonetic formaldehyde condensation products sulfate, alkyl benzene sulfonate calcium salt, naphthalene sulfonic acid-formaldehyde condensation product sodium salt, alkane
Base phenol polyethenoxy is phonetic, aliphatic amine polyoxyethylene is phonetic, polyoxyethylene carboxylate, ester polyoxyethylene phonetic in one or more.
Described wetting agent is selected from: sodium lauryl sulphate, dodecylbenzene sodium sulfonate, Nekal BX, detergent, agriculture breast
One in 2000# series, sodium laurylsulfate, wetting and penetrating agent F, wetting agent T, spaonin powder, tea seed cake, Bombyx mori L., Fructus Sapindi Mukouossi powder
Or it is multiple.
Described disintegrating agent is selected from: one or more in bentonite, carbamide, ammonium sulfate, aluminum chloride, glucose.
Described emulsifying agent is selected from: agriculture breast 500#(alkyl benzene calcium sulfonate), OP series phosphate ester (NPE
Phosphate ester), 600#Phosphate ester (phenyl phenol polyoxyethanyl ether phosphate), styrene polyoxyethylene ether ammonium sulfate salt, alkyl biphenyl
Ether disulfonic acid magnesium salt, triethanolamine salt, agriculture breast 400#(benzyl dimethyl phenol polyoxyethyl ether), agriculture breast 600#(phenyl phenol polyoxy second
Base ether), Nongru-700#(alkylphenol-formaldehyde resin polyoxyethyl ether), agriculture breast 36#(phenethyl fluosite polyoxyethyl ether),
Agriculture breast 1600#(phenethyl phenol polyoxyethanyl polypropylene-base ether), ethylene oxide-propylene oxide block copolymer, OP series (nonyl
Phenol polyethenoxy ether), By series (castor oil polyoxyethylene ether), agriculture breast 33#(alkylaryl polyoxyethylene polyoxypropylene ether), agriculture
Breast 34#(alkylaryl polyoxyethylene poly-oxygen propylene aether), Span series (sorbitan monostearate), TWEEN Series (dehydration
Span polyoxyethylene ether), EO series (fat alcohol polyoxyethylenated alcohol) in one or more.
Described antifreeze is selected from: one or more in ethylene glycol, propylene glycol, glycerol, Polyethylene Glycol.
Described defoamer is selected from: silicone, C8～10Aliphatic alcohols, C10～20Saturated fat acids (such as capric acid) and amide,
One or more in silicone oil, silicone compound.
Described thickening agent is selected from: xanthan gum, hydroxymethyl cellulose, hydroxyethyl cellulose, methylcellulose, aluminium silicate
One or more in magnesium, polyvinyl alcohol.
Macromolecule cyst material is selected from carbamide, formaldehyde, polyisocyanate, polyfunctional group acyl halide polyamines, polyfunctional group acyl
Base halogen dihydroxylic alcohols, sodium alginate, polyvinyl alcohol, gelatin, arabic gum, sucrose, modified starch, maltose, deformation lactoprotein, sweet
One or more in oil, calcium chloride, carboxymethyl cellulose, beta-schardinger dextrin-.
Described filler is selected from: Kaolin, kieselguhr, bentonite, attapulgite, white carbon, starch, precipitated calcium carbonate,
One or more in vegetable oil.
The wettable powder the key technical indexes of the present invention:
The water dispersible granules the key technical indexes of the present invention:
The suspending agent the key technical indexes of the present invention:
The suspension emulsion the key technical indexes of the present invention:
The aqueous emulsion the key technical indexes of the present invention:
The microemulsion the key technical indexes of the present invention:
The microcapsule suspending agent the key technical indexes of the present invention:
The microcapsule suspension-suspendinagent agent the key technical indexes of the present invention:
It is an advantage of the current invention that:
(1), after bromine cyanogen insect amide and avilamycin, ethyl pleocidin compound, there is notable synergistic and lasting effect；
(2) expand insecticidal spectrum, to Oryza sativa L., Semen Tritici aestivi, Cotton Gossypii, fruit tree, the brown paddy plant hopper of brassicaceous vegetable, white backed planthopper,
Small brown rice planthopper, trialeurodes vaporariorum, Bemisia tabaci, aphid, scale insect, thrips, rice leaf roller, striped rice borer, yellow rice borer, twill diamond-back moth, dark greyish green
Worm, apple leaf miner, beet armyworm, tetranychid, wart demodicid mite, yellow tea mite, bollworm etc. all have greater activity；
(3) decrease the dosage of pesticide, reduce pesticide residual quantity on crop, alleviate environmental pollution；
(4) to person poultry safety, Environmental compatibility is good, and insect is not likely to produce Drug resistance.
Detailed description of the invention
Below in conjunction with embodiment, further instruction of the present invention, the percentage ratio in embodiment are all weight percentage, but
The invention is not limited in this.
Application Example one
Embodiment 1 40.5% bromine cyanogen insect amide avilamycin wettable powder
Bromine cyanogen insect amide 40%, avilamycin 0.5%, polycarboxylate 6%, sodium laurylsulfate 5%, attapulgite add to
100%, mixture carries out comminution by gas stream, prepares 40.5% bromine cyanogen insect amide avilamycin wettable powder.
Embodiment 2 40% bromine cyanogen insect amide avilamycin wettable powder
Bromine cyanogen insect amide 30%, avilamycin 10%, alkylphenol-polyethenoxy are phonetic 6%, tea seed cake 4%, Kaolin add to
100%, mixture carries out comminution by gas stream, prepares 40% bromine cyanogen insect amide avilamycin wettable powder.
Embodiment 3 15% bromine cyanogen insect amide avilamycin wettable powder
Bromine cyanogen insect amide 10%, avilamycin 5%, alkylphenol-polyethenoxy are phonetic 6%, Fructus Sapindi Mukouossi powder 4%, Kaolin add to
100%, mixture carries out comminution by gas stream, prepares 15% bromine cyanogen insect amide avilamycin wettable powder.
Embodiment 4 8.1% bromine cyanogen insect amide avilamycin water dispersible granules
Bromine cyanogen insect amide 0.1%, avilamycin 8%, alkylphenol-polyethenoxy phonetic formaldehyde condensation products sulfate 6%, Laurel
Alcohol sodium sulfate 5%, carbamide 2%, Kaolin add to 100%, are mixed to prepare 8.1% bromine cyanogen insect amide avilamycin water-dispersible grain
Agent.
Embodiment 5 25% bromine cyanogen insect amide avilamycin water dispersible granules
Bromine cyanogen insect amide 15%, avilamycin 10%, dodecylbenzene sodium sulfonate 4%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt
6.8%, ammonium sulfate 2.2%, bentonite add to 100%, are mixed to prepare 25% bromine cyanogen insect amide avilamycin water dispersible granules.
Embodiment 6 18% bromine cyanogen insect amide avilamycin water dispersible granules
Bromine cyanogen insect amide 12%, avilamycin 6%, Nekal BX 6%, ester polyoxyethylene are phonetic 7%, glucose 2%, swollen
Profit soil adds to 100%, is mixed to prepare 18% bromine cyanogen insect amide avilamycin water dispersible granules.
Embodiment 7 35% bromine cyanogen insect amide avilamycin suspending agent
Bromine cyanogen insect amide 33%, avilamycin 2%, polycarboxylate 5%, dodecylbenzene sodium sulfonate 4%, C10～20Saturated
Fatty acid 2%, polyvinylpyrrolidone 1.2%, diethylene glycol 0.8%, deionized water add to 100%, are mixed to prepare 35% bromine
Cyanogen insect amide avilamycin suspending agent.
Embodiment 8 30% bromine cyanogen insect amide avilamycin suspending agent
Bromine cyanogen insect amide 25%, avilamycin 5%, alkylaryl polyoxyethylene ether 6%, sodium lauryl sulphate 6%, silicon
Ketone 1%, sodium alginate 2%, deionized water add to 100%, are mixed to prepare 30% bromine cyanogen insect amide avilamycin suspending agent.
Embodiment 9 30% bromine cyanogen insect amide avilamycin suspending agent
Bromine cyanogen insect amide 20%, avilamycin 10%, polyoxyethylene carboxylate 6%, Bombyx mori L. 5%, C8～10Aliphatic alcohols
1.2%, polyvinyl alcohol 2%, deionized water add to 100%, are mixed to prepare 30% bromine cyanogen insect amide avilamycin suspending agent.
Embodiment 10 40% bromine cyanogen insect amide avilamycin suspension emulsion
Bromine cyanogen insect amide 35%, avilamycin 5%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 7%, dodecylbenzene sodium sulfonate
6%, benzyl dimethyl phenol polyoxyethyl ether 6%, ethyl acetate 5%, C8～10 aliphatic alcohols 1%, polyvinyl alcohol 2%, poly-second
Glycol 1.8%, deionized water add to 100%, are mixed to prepare 40% bromine cyanogen insect amide avilamycin suspension emulsion.
Embodiment 11 30% bromine cyanogen insect amide avilamycin suspension emulsion
Bromine cyanogen insect amide 24%, avilamycin 6%, polyoxyethylene carboxylate 7%, spaonin powder 4%, Oleum Ricini polyoxy second
Alkene ether 2%, silicone oil 0.8%, hydroxymethyl cellulose 1.5%, Polyethylene Glycol 2%, deionized water add to 100%, are mixed to prepare
30% bromine cyanogen insect amide avilamycin suspension emulsion.
Embodiment 12 20% bromine cyanogen insect amide avilamycin suspension emulsion
Bromine cyanogen insect amide 13%, avilamycin 7%, ester polyoxyethylene are phonetic 6%, tea seed cake 4%, styrene polyoxyethylene ether sulfur
Acid ammonium salt 5%, silicone 0.5%, phenolic resin 1.5%, ethylene glycol 1.2%, deionized water add to 100%, are mixed to prepare
20% bromine cyanogen insect amide avilamycin suspension emulsion.
Embodiment 13 55% bromine cyanogen insect amide avermectin micro-emulsion
Bromine cyanogen insect amide 50%, avilamycin 5%, sorbitan fatty acid ester polyoxyethylene ether 7%, Ketohexamethylene 4%,
Diethylene glycol 1%, sodium acrylate 1%, silicone oil 0.9%, organic acid 2%, deionized water supplies 100%, is mixed to prepare 55% bromine cyanogen
Insect amide avermectin micro-emulsion.
Embodiment 14 25% bromine cyanogen insect amide avermectin micro-emulsion
Bromine cyanogen insect amide 21%, avilamycin 4%, N-ketopyrrolidine 7%, xanthan gum 5%, phenolic resin 1.6%, fat
Polyoxyethylenated alcohol 7%, C8～10Aliphatic alcohols 1.4%, ethanolamine 1.5%, deionized water supplies 100%, prepares 25% bromine cyanogen
Insect amide avermectin micro-emulsion.
Embodiment 15 9% bromine cyanogen insect amide avermectin micro-emulsion
Bromine cyanogen insect amide 6%, avilamycin 3%, butyl ether 7%, phenethyl fluosite polyoxyethyl ether 6%, propylene
Acid sodium 1.5%, propylene glycol 2%, silicone 1.4%, triethanolamine 1%, deionized water supplies 100%, is mixed to prepare 9% bromine cyanogen
Insect amide avermectin micro-emulsion.
Embodiment 16 40% bromine cyanogen insect amide abamectin aqueous emulsion
Bromine cyanogen insect amide 20%, avilamycin 20%, toluene 5%, vegetable oil 5%, phenethyl fluosite polyoxy second
Base ether 6%, propylene glycol 2%, C8～10Aliphatic alcohols 0.8%, deionized water adds to 100%, is mixed to prepare 40% bromine cyanogen worm acyl
Amine abamectin aqueous emulsion.
Embodiment 17 30% bromine cyanogen insect amide abamectin aqueous emulsion
Bromine cyanogen insect amide 22%, avilamycin 8%, acetonitrile 4%, propanol 3%, castor oil polyoxyethylene ether 8%, propylene glycol
1.6%, C8～10Aliphatic alcohols 1.5%, deionized water adds to 100%, blended prepared 30% bromine cyanogen insect amide avilamycin
Aqueous emulsion.
Embodiment 18 20% bromine cyanogen insect amide abamectin aqueous emulsion
Bromine cyanogen insect amide 12%, avilamycin 8%, acetone 4%, vegetable oil 5%, sorbitan monostearate 8%, poly-
Vinyl alcohol 1.8%, silicone 0.8%, deionized water adds to 100%, blended prepared 20% bromine cyanogen insect amide avilamycin
Aqueous emulsion.
Embodiment 19 25% bromine cyanogen insect amide avermectin microcapsule suspending agent
Bromine cyanogen insect amide 15%, avilamycin 10%, sodium alginate 3%, maltose 2%, dodecylbenzene sodium sulfonate 5%,
Ester polyoxyethylene is phonetic 2.4%, Ketohexamethylene 6%, alkylphenol-formaldehyde resin polyoxyethyl ether 5%, citric acid 0.9%, sodium hydroxide
0.6%, deionized water adds to 100% weight portion, prepares 25% bromine cyanogen insect amide avermectin microcapsule suspending agent.
Embodiment 20 15% bromine cyanogen insect amide avermectin microcapsule suspension-suspending agent
Bromine cyanogen insect amide 10%, avilamycin 5%, modified starch 3%, calcium chloride 4%, fatty acyl amido are to methoxybenzene
Sodium sulfonate 6%, wetting agent T 2.5%, methanol 4%, Ketohexamethylene 3%, agriculture breast 500#5%, agriculture breast 33#4%, C8～10Aliphatic alcohols
0.6%, white dextrin 1.2%, pH adjusting agent sodium hydroxide and citric acid altogether 3.8%, water add to 100% weight portion, prepare
15% bromine cyanogen insect amide avermectin microcapsule suspension-suspending agent.
Embodiment 21 80% bromine cyanogen insect amide ethyl pleocidin wettable powder
Bromine cyanogen insect amide 79%, ethyl pleocidin 1%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 6%, Fructus Sapindi Mukouossi powder 5%, light
Matter calcium carbonate adds to 100%, and mixture carries out comminution by gas stream, prepares 80% bromine cyanogen insect amide ethyl pleocidin wettable powder
Agent.
Embodiment 22 60% bromine cyanogen insect amide ethyl pleocidin wettable powder
Bromine cyanogen insect amide 30%, ethyl pleocidin 30%, alkylphenol-polyethenoxy are phonetic 6%, Bombyx mori L. 4%, Kaolin add
To 100%, mixture carries out comminution by gas stream, prepares 60% bromine cyanogen insect amide ethyl pleocidin wettable powder.
Embodiment 23 40% bromine cyanogen insect amide ethyl pleocidin wettable powder
Bromine cyanogen insect amide 30%, ethyl pleocidin 10%, aliphatic amine polyoxyethylene are phonetic 6%, wetting and penetrating agent F 4%,
Kieselguhr adds to 100%, and mixture carries out comminution by gas stream, prepares 40% bromine cyanogen insect amide ethyl pleocidin wettable powder
Agent.
Embodiment 24 40.5% bromine cyanogen insect amide ethyl pleocidin water dispersible granules
Bromine cyanogen insect amide 0.5%, ethyl pleocidin 40%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 6%, detergent alkylate sulphur
Acid sodium 5%, carbamide 2%, Kaolin add to 100%, are mixed to prepare 40.5% bromine cyanogen insect amide ethyl pleocidin water-dispersible
Granule.
Embodiment 25 50% bromine cyanogen insect amide ethyl pleocidin water dispersible granules
Bromine cyanogen insect amide 25%, ethyl pleocidin 25%, sodium lauryl sulphate 4%, alkylphenol-polyethenoxy are phonetic
6%, sodium carbonate 2.2%, bentonite add to 100%, are mixed to prepare 50% bromine cyanogen insect amide ethyl pleocidin water-dispersible grain
Agent.
Embodiment 26 30% bromine cyanogen insect amide ethyl pleocidin water dispersible granules
Bromine cyanogen insect amide 10%, ethyl pleocidin 20%, bentonite 6%, the phonetic formaldehyde condensation products of alkylphenol-polyethenoxy
Sulfate 7%, aluminum chloride 2%, bentonite add to 100%, are mixed to prepare 30% bromine cyanogen insect amide ethyl pleocidin moisture
Shot agent.
Embodiment 27 30% bromine cyanogen insect amide ethyl pleocidin suspending agent
Bromine cyanogen insect amide 20%, ethyl pleocidin 10%, aryl phenol polyoxyethylene succinate sulfonate 5%, Fructus Gleditsia
Powder 4%, silicone oil 2%, polyvinylpyrrolidone 1.2%, diethylene glycol 0.8%, deionized water add to 100%, are mixed to prepare 30%
Bromine cyanogen insect amide ethyl pleocidin suspending agent.
Embodiment 28 20% bromine cyanogen insect amide ethyl pleocidin suspending agent
Bromine cyanogen insect amide 10%, ethyl pleocidin 10%, alkylphenol-polyethenoxy are phonetic 6%, dodecylbenzene sodium sulfonate
6%, C8～10Aliphatic alcohols 1%, phenolic resin 2%, deionized water add to 100%, are mixed to prepare 20% bromine cyanogen insect amide second
Base pleocidin suspension.
Embodiment 29 15% bromine cyanogen insect amide ethyl pleocidin suspending agent
Bromine cyanogen insect amide 10%, ethyl pleocidin 5%, ester polyoxyethylene are phonetic 6%, Fructus Sapindi Mukouossi powder 5%, silicone
1.2%, methylcellulose 2%, deionized water add to 100%, are mixed to prepare 15% bromine cyanogen insect amide ethyl pleocidin and hang
Floating agent.
Embodiment 30 45% bromine cyanogen insect amide ethyl pleocidin suspension emulsion
Bromine cyanogen insect amide 30%, ethyl pleocidin 15%, alkylphenol-polyethenoxy are phonetic 7%, spaonin powder 6%, alkyl phenol
Formaldehyde resin polyoxyethyl ether 6%, vegetable oil 5%, C10～20Saturated fat acids 1%, polyvinyl alcohol 2%, Polyethylene Glycol
1.8%, deionized water adds to 100%, is mixed to prepare 45% bromine cyanogen insect amide ethyl pleocidin suspension emulsion.
Embodiment 31 30% bromine cyanogen insect amide ethyl pleocidin suspension emulsion
Bromine cyanogen insect amide 24%, ethyl pleocidin 6%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 7%, wetting and penetrating agent F
4%, fatty alcohol-polyoxyethylene ether 2%, C8～10Aliphatic alcohols 0.8%, sodium tripolyphosphate 1.5%, ethylene glycol 2%, deionized water
Add to 100%, be mixed to prepare 30% bromine cyanogen insect amide ethyl pleocidin suspension emulsion.
Embodiment 32 10% bromine cyanogen insect amide ethyl pleocidin suspension emulsion
Bromine cyanogen insect amide 5%, ethyl pleocidin 5%, polyoxyethylene carboxylate 6%, Bombyx mori L. 4%, alkyl biphenyl ether
Disulfonic acid magnesium salt 5%, silicone oil 0.5%, sodium alginate 1.5%, ethylene glycol 1.2%, deionized water add to 100%, are mixed to prepare
10% bromine cyanogen insect amide ethyl pleocidin suspension emulsion.
Embodiment 33 35% bromine cyanogen insect amide ethyl pleocidin microemulsion
Bromine cyanogen insect amide 20%, ethyl pleocidin 15%, fatty alcohol-polyoxyethylene ether 7%, ethyl acetate 4%, poly-second
Glycol 1%, polyvinylpyrrolidone 1%, silicone 0.9%, antioxidant 2%, deionized water supplies 100%, is mixed to prepare
35% bromine cyanogen insect amide ethyl pleocidin microemulsion.
Embodiment 34 30% bromine cyanogen insect amide ethyl pleocidin microemulsion
Bromine cyanogen insect amide 15%, ethyl pleocidin 15%, toluene 7%, sodium acrylate 5%, sodium alginate 1.6%, alkane
Base aryl polyoxyethylene poly-oxygen propylene aether 7%, C10～20Saturated fat acids 1.4%, triethanolamine 1.5%, deionized water is supplied
100%, prepare 30% bromine cyanogen insect amide ethyl pleocidin microemulsion.
Embodiment 35 15% bromine cyanogen insect amide ethyl pleocidin microemulsion
Bromine cyanogen insect amide 10%, ethyl pleocidin 5%, vegetable oil 7%, phenethyl phenol polyoxyethanyl polypropylene-base ether
6%, polyvinylpyrrolidone 1.5%, glycerol 2%, silicone 1.5%, organic acid 1%, deionized water supplies 100%, mixed
Close and prepare 15% bromine cyanogen insect amide ethyl pleocidin microemulsion.
Embodiment 36 40% bromine cyanogen insect amide ethyl pleocidin aqueous emulsion
Bromine cyanogen insect amide 10%, ethyl pleocidin 30%, ethyl acetate 7%, epoxy ethane-epoxy propane block copolymerization
Thing 6%, glycerol 2%, C8～10Aliphatic alcohols 0.8%, deionized water adds to 100%, is mixed to prepare 40% bromine cyanogen insect amide
Ethyl pleocidin aqueous emulsion.
Embodiment 37 30% bromine cyanogen insect amide ethyl pleocidin aqueous emulsion
Bromine cyanogen insect amide 10%, ethyl pleocidin 20%, vegetable oil 4%, ethyl acetate 5%, sorbitol anhydride list are stearic
Acid esters 8%, Polyethylene Glycol 1.6%, C10～20Saturated fat acids 1.5%, deionized water adds to 100%, blended prepared 30%
Bromine cyanogen insect amide ethyl pleocidin aqueous emulsion.
Embodiment 38 25% bromine cyanogen insect amide ethyl pleocidin aqueous emulsion
Bromine cyanogen insect amide 5%, ethyl pleocidin 20%, ethyl acetate 4%, butyl ether 5%, sorbitan fatty acid ester
Polyoxyethylene ether 8%, Polyethylene Glycol 1.8%, C8～10Aliphatic alcohols 0.8%, deionized water adds to 100%, blended prepares
25% bromine cyanogen insect amide ethyl pleocidin aqueous emulsion.
Embodiment 39 35% bromine cyanogen insect amide ethyl pleocidin micro-capsule suspension
Bromine cyanogen insect amide 25%, ethyl pleocidin 10%, polyfunctional group acyl halide dihydroxylic alcohols 3%, polyisocyanate
2%, dodecylbenzene sodium sulfonate 5%, polyoxyethylene carboxylate 2.4%, ethyl acetate 6%, phenethyl fluosite polyoxy
Ethylether 5%, citric acid 0.8%, sodium hydroxide 0.4%, deionized water add to 100% weight portion, prepare 35% bromine cyanogen worm acyl
Amine ethyl pleocidin micro-capsule suspension.
Embodiment 40 35% bromine cyanogen insect amide ethyl pleocidin microcapsule suspension-suspendinagent agent
Bromine cyanogen insect amide 20%, ethyl pleocidin 15%, maltose 3%, glycerol 4%, fatty acyl amido are to methoxyl group
Benzene sulfonic acid sodium salt 6%, wetting agent T 2.5%, vegetable oil 4%, butyl ether 3%, phenyl phenol polyoxyethanyl ether phosphate 5%, alkyl virtue
Base polyoxyethylene polyoxypropylene ether 4%, silicone 0.6%, sodium acrylate 1.2%, pH adjusting agent sodium hydroxide are with citric acid altogether
Meter 3.8%, water add to 100% weight portion, prepare 35% bromine cyanogen insect amide ethyl pleocidin microcapsule suspension-suspendinagent agent.
The embodiment of the present invention is the method using Toxicity Determination and field test to combine.First pass through indoor virulence to survey
Fixed, after clear and definite two kinds of medicaments are compounding by a certain percentage co-toxicity coefficient (CTC), CTC ＜ 80 is antagonism, 80≤CTC≤120
For summation action, CTC ＞ 120 is potentiation, on this basis, then carries out field test.
Test method: respectively the mother solution of each mixed agent is diluted to during test five series concentration, is respectively placed in beaker
Standby.Use the method that first leaching leaf is followed by worm, by the blade of the same size not in contact with any medicament in the medicinal liquid configured
Take out after soaking 5s, naturally dry, put in insect box, then connect for examination larva, raise under the conditions of 25 DEG C, often process 3
Secondary repetition, often repeating examination borer population used is 50, sets blank simultaneously, checks dead borer population in 72h, calculates mortality rate and correction
Mortality rate, tries to achieve virulence regression equation and calculates LC50Value.If comparison mortality rate is more than 10%, then it is considered as invalid test.Calculate public affairs
Formula is as follows:
Insect corrected mortality is converted into probit value (y), and concentration for the treatment of (μ g/ml) is converted into logarithm value (x), with minimum
Square law draws virulence regression equation, and thus calculates the value of every kind of medicament.Common poison system is calculated according to the abundant equation of Sun Yun
Number CTC.Computing formula is following (with bromine cyanogen insect amide as standard agent, its toxicity index is 100):
TI × the P of theoretical toxicity index (the TTI)=bromine cyanogen insect amide of MBromine cyanogen insect amideTI × the P of+active component BActive componentB
In formula: M is the mixture of different ratio；
PActive componentB is the ratio that active component B is shared in the composition；
PBromine cyanogen insect amideFor the ratio that bromine cyanogen insect amide is shared in the composition.
Note: active component B is arbitrary a kind of in avilamycin, ethyl pleocidin.
Application Example two:
For examination insect: white backed planthopper.
EXPERIMENTAL DESIGN: determine the former medicine of bromine cyanogen insect amide, avilamycin and the two different ratio mixture through pilot study
Effectively lethasl concentration scope.
Toxicity test result one
Table 1 bromine cyanogen insect amide and the avilamycin different ratio toxicity test to diamondback moth
As shown in Table 1, bromine cyanogen insect amide fits over abamectin compounded preventing and treating diamondback moth: during 80:1 to 1:80, altogether poison
Coefficient is all higher than 120, illustrates that both all show potentiation, especially when bromine cyanogen worm acyl at mixture in the range of 80:1 to 1:80
Amine and avilamycin obtain proportioning when 20:1 to 1:20, and potentiation becomes apparent from highlighting, wherein as bromine cyanogen insect amide and A Wei
When rhzomorph weight ratio is 2:1, co-toxicity coefficient is maximum, and potentiation is the most obvious, finds, bromine cyanogen insect amide and avilamycin simultaneously
Proportioning 19:1,18:1,17:1,16:1,15:1,14:1,13:1,12:1,11:1,10:1,9:1,8:1,7:1,6:1,5:1,
4:1、3:1、2:1、1:1、1:2、1:3、1:4、1:5、1:6、1:7、1:8、1:9、1:10、1:11、1:12、1:13、1:14、1:
15,16:1,17:1,18:1,19:1 recurrence of disease at the same time next year pairing preventing and treating brown paddy plant hopper, white backed planthopper, small brown rice planthopper, trialeurodes vaporariorum, Bemisia tabaci, aphid,
Scale insect, thrips, rice leaf roller, striped rice borer, yellow rice borer, twill diamond-back moth, Pieris rapae, apple leaf miner, beet armyworm, tetranychid,
The insects such as wart demodicid mite, yellow tea mite, bollworm also have preferable potentiation, and co-toxicity coefficient is all higher than 140.
Application Example three:
For examination insect: beet armyworm.
EXPERIMENTAL DESIGN: determine that the former medicine of bromine cyanogen insect amide, ethyl pleocidin and the two different ratio mix through pilot study
Effective lethasl concentration scope of agent.
Toxicity test result two
Table 2 bromine cyanogen insect amide and the ethyl pleocidin different ratio toxicity test to beet armyworm
As shown in Table 2, bromine cyanogen insect amide and ethyl pleocidin compound the proportioning of preventing and treating beet armyworm at 80:1 to 1:80
Time, co-toxicity coefficient is all higher than 120, illustrates that both all show potentiation at mixtures in the range of 80:1 to 1:80, especially when
Bromine cyanogen insect amide and ethyl pleocidin obtain proportioning when 20:1 to 1:20, and potentiation becomes apparent from highlighting, wherein when bromine cyanogen
When insect amide and ethyl pleocidin weight ratio are 1:1, co-toxicity coefficient is maximum, and potentiation is the most obvious, finds, bromine cyanogen simultaneously
Insect amide and ethyl pleocidin proportioning 19:1,18:1,17:1,16:1,15:1,14:1,13:1,12:1,11:1,10:1,
9:1、8:1、7:1、6:1、5:1、4:1、3:1、2:1、1:1、1:2、1:3、1:4、1:5、1:6、1:7、1:8、1:9、1:10、1:
11,1:12,1:13,1:14,1:15,16:1,17:1,18:1,19:1 recurrence of disease at the same time next year pairing preventing and treating brown paddy plant hopper, white backed planthopper, small brown rice planthopper,
Trialeurodes vaporariorum, Bemisia tabaci, aphid, scale insect, thrips, rice leaf roller, striped rice borer, yellow rice borer, twill diamond-back moth, Pieris rapae, Jin Wen
The insects such as thin moth, beet armyworm, tetranychid, wart demodicid mite, yellow tea mite, bollworm also have preferable potentiation, and co-toxicity coefficient is the biggest
In 160.
Application Example tetrabromo cyanogen insect amide and avilamycin and the compounding preventing and treating rice leaf roller test of pesticide effectiveness thereof
This experimental establishment is carried by Shaanxi Welch Crop Protection Co., Ltd. at Haiyan County, Jiaxing City, Zhejiang Province, test medicine
Confession, comparison medicament 10% bromine cyanogen insect amide suspending agent (autogamy), 2% abamectin emulsifiable concentrate (commercial).
Test uses conventional nebulization, investigates rice leaf roller insect pest index, in insect pest early period of origination dispenser, dispenser before medicine
Within latter 3 days, 7 days, 14 days, investigate insect pest indexes and calculate preventive effect.Experimental result is as follows:
Table 3 bromine cyanogen insect amide, avilamycin and the compounding preventing and treating rice leaf roller test of pesticide effectiveness thereof
As can be seen from Table 3, bromine cyanogen insect amide can effectively prevent and treat rice leaf roller, prevention effect after abamectin compounded
It is superior to the preventive effect of single dose, and the preventive effect time is long.In test scope of medication, target crop is had no adverse effects.
Application Example pentabromo-cyanogen insect amide and avilamycin and the compounding preventing and treating cotton boll worm test of pesticide effectiveness thereof
This experimental establishment is in Weinan City Dali County, Shaanxi Province, and test medicine is carried by Shaanxi Welch Crop Protection Co., Ltd.
Confession, comparison medicament 10% bromine cyanogen insect amide suspending agent (autogamy), 2% abamectin emulsifiable concentrate (commercial).
Test uses conventional nebulization, investigates cotton boll pests index, in insect pest early period of origination dispenser, dispenser before medicine
Within latter 3 days, 7 days, 14 days, investigate insect pest indexes and calculate preventive effect.Experimental result is as follows:
Table 4 bromine cyanogen insect amide, avilamycin and the compounding preventing and treating cotton boll worm test of pesticide effectiveness thereof
As can be seen from Table 4, bromine cyanogen insect amide can effectively prevent and treat cotton boll worm, prevention effect after abamectin compounded
It is superior to the preventive effect of single dose, and the preventive effect time is long.In test scope of medication, target crop is had no adverse effects.
Application Example hexabromo cyanogen insect amide and ethyl pleocidin and the compounding preventing and treating rice-stem borer test of pesticide effectiveness thereof
This experimental establishment is carried by Shaanxi Welch Crop Protection Co., Ltd. at Haiyan County, Jiaxing City, Zhejiang Province, test medicine
Confession, comparison medicament 10% bromine cyanogen insect amide suspending agent (autogamy), 10% ethyl pleocidin suspending agent (autogamy).
Test uses conventional nebulization, investigates rice-stem borer insect pest index, in insect pest early period of origination dispenser, dispenser before medicine
Within latter 3 days, 7 days, 14 days, investigate insect pest indexes and calculate preventive effect.Experimental result is as follows:
Table 5 bromine cyanogen insect amide, ethyl pleocidin and the compounding preventing and treating rice-stem borer test of pesticide effectiveness thereof
As can be seen from Table 5, rice-stem borer can effectively be prevented and treated after bromine cyanogen insect amide is compounding with ethyl pleocidin, preventing and treating
Effect is superior to the preventive effect of single dose, and the preventive effect time is long.In test scope of medication, target crop is had no adverse effects.
Application Example seven bromine cyanogen insect amide and ethyl pleocidin and the compounding preventing and treating Caulis et Folium Brassicae capitatae diamondback moth test of pesticide effectiveness thereof
This experimental establishment is in Chencang District, Baoji, Shaanxi province city, and test medicine is carried by Shaanxi Welch Crop Protection Co., Ltd.
Confession, comparison medicament 10% bromine cyanogen insect amide suspending agent (autogamy), 10% ethyl pleocidin suspending agent (autogamy).
Test uses conventional nebulization, investigates Caulis et Folium Brassicae capitatae diamondback moth insect pest index, in insect pest early period of origination dispenser, dispenser before medicine
Within latter 3 days, 7 days, 14 days, investigate insect pest indexes and calculate preventive effect.Experimental result is as follows:
Table 6 bromine cyanogen insect amide, ethyl pleocidin and compounding preventing and treating Caulis et Folium Brassicae capitatae diamondback moth effect test thereof
As can be seen from Table 6, Caulis et Folium Brassicae capitatae diamondback moth can effectively be prevented and treated after bromine cyanogen insect amide is compounding with ethyl pleocidin, preventing and treating
Effect is superior to the preventive effect of single dose, and the preventive effect time is long.In test scope of medication, target crop is had no adverse effects.
Claims (6)
1. brominated cyanogen insect amide and a Pesticidal combination for biogenic substances, effective ingredient is active components A, active component B, helps
Agent surplus, it is characterised in that: active components A is bromine cyanogen insect amide, and active component B is to appoint in avilamycin, ethyl pleocidin
Meaning one, wherein the weight ratio of bromine cyanogen insect amide and avilamycin be 80:1 ~ 20:1,6:1,1:6 ~ 1:8,3:1,7:1, bromine cyanogen
The weight ratio of insect amide and ethyl pleocidin is 1:80 ~ 80:1.
Brominated cyanogen insect amide the most according to claim 1 and the Pesticidal combination of biogenic substances, it is characterised in that: bromine cyanogen worm
The weight ratio of amide and ethyl pleocidin is 1:60 ~ 40:1.
Brominated cyanogen insect amide the most according to claim 2 and the Pesticidal combination of biogenic substances, it is characterised in that: bromine cyanogen worm
The weight ratio of amide and ethyl pleocidin is 1:30 ~ 30:1.
4., according to the brominated cyanogen insect amide described in any one in claim 1 ~ 3 and the Pesticidal combination of biogenic substances, it is special
Levy and be: compositions makes wettable powder, water dispersible granules, suspending agent, suspension emulsion, aqueous emulsion, microemulsion, microcapsule suspension
Agent, microcapsule suspension-suspendinagent agent.
The Pesticidal combination of brominated cyanogen insect amide the most according to claim 4 and biogenic substances be used for preventing and treating Oryza sativa L., Semen Tritici aestivi,
The application of insect on Cotton Gossypii, fruit tree, brassicaceous vegetable.
Application the most according to claim 5, it is characterised in that institute's pest control includes: brown paddy plant hopper, white backed planthopper, ash fly
Louse, trialeurodes vaporariorum, Bemisia tabaci, aphid, scale insect, thrips, rice leaf roller, striped rice borer, yellow rice borer, twill diamond-back moth, Pieris rapae, gold
The thin moth of stricture of vagina, beet armyworm, tetranychid, wart demodicid mite, yellow tea mite, bollworm.
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| CN103518733B (en) * | 2013-10-24 | 2015-09-16 | 江苏龙灯化学有限公司 | A kind of Pesticidal combination containing ethyl pleocidin and bromine cyanogen insect amide |
| CN104304276A (en) * | 2014-09-25 | 2015-01-28 | 江苏省绿盾植保农药实验有限公司 | Insecticidal composition containing avermectin and cyantraniliprole and application thereof |
| CN106035352A (en) * | 2016-06-21 | 2016-10-26 | 南京华洲药业有限公司 | Lepimectin and cyantraniliprole contained compound insecticidal composition and use thereof |
| CN105994310A (en) * | 2016-06-21 | 2016-10-12 | 南京华洲药业有限公司 | Composite insecticide composition containing cyantraniliprole and avermectin and application thereof |
| CN105994289A (en) * | 2016-06-21 | 2016-10-12 | 南京华洲药业有限公司 | Composite insecticide composition containing cyantraniliprole and spinetoram and application thereof |
| CN107549178A (en) * | 2017-08-15 | 2018-01-09 | 浙江海正化工股份有限公司 | Pesticidal combination and its preparation method and application |
| CN109845746B (en) * | 2019-01-25 | 2024-01-23 | 海利尔药业集团股份有限公司 | Insecticidal composition containing flucloxapyroxad and biological insecticide |
| CN114946891B (en) * | 2022-06-27 | 2024-04-02 | 河南农王实业有限公司 | Agricultural composition containing cyantraniliprole and spinosad |
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