CN103283734A - Cyantraniliprole/biological-source-containing pesticidal composition - Google Patents
Cyantraniliprole/biological-source-containing pesticidal composition Download PDFInfo
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- CN103283734A CN103283734A CN2012100424442A CN201210042444A CN103283734A CN 103283734 A CN103283734 A CN 103283734A CN 2012100424442 A CN2012100424442 A CN 2012100424442A CN 201210042444 A CN201210042444 A CN 201210042444A CN 103283734 A CN103283734 A CN 103283734A
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- insect amide
- cyanogen insect
- bromine cyanogen
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- avermectin
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Abstract
The invention discloses a cyantraniliprole/biological-source-containing pesticidal composition. The composition is mainly characterized by containing an active component A, an active component B and the balance of assistant, wherein the active component A is cyantraniliprole, and the active component B is abamectin or spinetoram; the weight ratio of the active component A to the active component B is 1:80-80:1; and the composition can be prepared into wettable powder, water-dispersible granules, a suspending agent, a suspended emulsion, an aqueous emulsion, a microemulsion, a microcapsule suspending agent and a microcapsule suspending-suspending agent. The composition disclosed by the invention can prevent and treat many soil pests, has an obvious synergistic action, widens the pesticidal spectrum, and has higher activity for pests on paddy rice, wheat, cotton, fruit trees and cruciferous vegetables. The composition has a slow-release action, reduces the pesticide consumption, is safe for human and livestock, does not have chemical injury, and has favorable environmental compatibility; and the preparation has the advantages of higher adhesive force, rainfall erosion resistance, long lasting period and the like.
Description
Technical field
The invention belongs to technical field of pesticide, relate to the Pesticidal combination of a kind of brominated cyanogen insect amide and biogenic class.
Background technology
Bromine cyanogen insect amide (cyantraniliprole), chemical name: hydroxyl 3-bromo-1-(3-chloro-2-pyridine radicals)-N-[4-cyano group-2-methyl-6-[(methylamino)] phenyl]-1H-pyrazoles-5-formamide, chemical molecular formula: C
19H
14BrClN
6O
2The bromine cyanogen insect amide is E.I.Du Pont Company's second generation ryania acceptor inhibitor insecticides that success is developed after the chlorine insect amide, cyanogen insect amide is to form by the various polar groups that change on the phenyl ring, have more efficient, applicable crops is more extensive, can effectively prevent and treat Lepidoptera, Semiptera and coleopteran pest.
Avermectin (Avermectins), chemical molecular formula: C
48H
72O
14(B1a) C
47H
70O
14(B1b).Avermectin belongs to the biogenic insecticides, and it is a kind of macrolide disaccharide compounds.Be the natural products that from edaphon, separates, insect and mite class had tag and stomach poison function and faint fumigation action is arranged, no systemic action.But it has very strong osmosis to blade, can kill subepidermal insect, and the longevity of residure is long.It does not kill ovum.What its mechanism of action was different with general insecticide is that it disturbs the neurophysiology activity, stimulate and discharge the r-aminobutyric acid, and the r-aminobutyric acid has inhibitory action to arthropodan nerve conduction, the mite class becomes, if mite and insect and larva with paralysis symptom namely appears after medicament contacts, inertia is not got food, and is dead after 2-4 days.Because not causing that insect dewaters rapidly, so its lethal effect is slower.But though predatism and parasite are had direct killing effect, because plant surface is residual few, therefore little to the damage of beneficial insect.
Ethyl pleocidin (spinetoram), chemical molecular formula: C
42H
69NO
10Ethyl pleocidin is made up of ethyl pleocidin-J and two kinds of components of ethyl pleocidin-L, acts on the nervous system of insect, and diamond-back moth, beet armyworm, Liriomyza, thrips, prodenia litura, lima bean pod borer are had good control efficiency.
In the real process of agricultural production, the problem that pest control is easy to generate most is the generation of pest resistance to insecticide.The different cultivars composition carries out composite, is the very common method of control resistant insect.Heterogeneity is carried out composite, according to practical application effect, judge certain composite be synergy, add and or antagonism.In most cases, the composite effect of agricultural chemicals all is additive effect, and the seldom composite of synergistic effect really arranged, especially synergistic effect very obviously, co-toxicity coefficient very high composite just still less.Test discovery in a large number through the inventor, after bromine cyanogen insect amide and Avermectin, ethyl pleocidin were composite, synergistic effect was remarkable, and Environmental compatibility is fabulous, has greatly reduced the agricultural chemicals dosage.
Summary of the invention
The Pesticidal combination that the present invention proposes contains in bromine cyanogen insect amide and Avermectin, the ethyl pleocidin any one two kinds of active components, and an amount of surfactant and carrier.
The Pesticidal combination of a kind of brominated cyanogen insect amide and biogenic class, comprise active components A, active component B, the auxiliary agent surplus, it is characterized in that: active components A is the bromine cyanogen insect amide, active component B is a kind of arbitrarily in Avermectin, the ethyl pleocidin, and the weight ratio of active components A and active component B is 1: 80～80: 1.
Described Pesticidal combination is characterized in that: the weight ratio of active components A and active component B is 1: 60～40: 1.
Described Pesticidal combination is characterized in that: the weight ratio of bromine cyanogen insect amide and Avermectin is 1: 10～30: 1.
Described Pesticidal combination is characterized in that: the weight ratio of bromine cyanogen insect amide and ethyl pleocidin is 1: 30～30: 1.
Described Pesticidal combination is characterized in that: composition is made wetting powder, water dispersible granules, suspending agent, suspension emulsion, aqueous emulsion, microemulsion, microcapsule suspending agent, microcapsule suspension-suspending agent.
Described Pesticidal combination is used for the application of insect on control paddy rice, wheat, cotton, fruit tree, the brassicaceous vegetable.
Described application, pest control comprises: brown planthopper, white-backed planthopper, small brown rice planthopper, trialeurodes vaporariorum, Bemisia tabaci, aphid, scale insect, thrips, rice leaf roller, striped rice borer, paddy stem borer, twill diamond-back moth, cabbage caterpillar, apple leaf miner, beet armyworm, tetranychid, goitre mite, yellow tea mite, cotton bollworm.
At least contain a kind of surfactant in the Pesticidal combination of the present invention, the dispersion of active component in water when being beneficial to use.Surface-active contents is 5%～30% of total formulation weight amount, and surplus is solid or liquid diluent.The selected surfactant of Pesticidal combination of the present invention is known in those skilled in the art: can be selected from dispersant, wetting agent, emulsifier or the defoamer one or more.
The Pesticidal combination of described brominated cyanogen insect amide and biogenic class is characterized in that: comprise following constituent content when making wetting powder: active components A 0.1%～80%, active component B 0.1%～80%, dispersant 5%～10%, wetting agent 2%～10%, filler surplus.
Active components A, active component B, dispersant, wetting agent, filler are mixed, in mixed cylinder, mix, after airslide disintegrating mill is pulverized, mix again, namely can be made into wetting powder product of the present invention.
The Pesticidal combination of described brominated cyanogen insect amide and biogenic class is characterized in that: comprise following constituent content when composition is made water dispersible granules: active components A 0.1%～80%, active component B 0.1%～80%, dispersant 3%～12%, wetting agent 1%～8%, disintegrant 1%～10%, filler surplus.
Active components A, active component B, dispersant, wetting agent, disintegrant, filler etc. are pulverized the particle diameter that obtains needs through air-flow together, obtain the materials of granulating.It is interior through after granulation and the drying to expect that product are quantitatively sent the fluidized bed granulation dryer to, makes water dispersible granules product of the present invention.
The Pesticidal combination of described brominated cyanogen insect amide and biogenic class is characterized in that: comprise following constituent content when composition is made suspending agent: active components A 0.1%～60%, active component B 0.1%～60%, dispersant 2～10%, wetting agent 2～10%, defoamer 0.1～1%, thickener 0.1～2%, antifreeze 0.1～8%, deionized water add to 100%.
Dispersant, wetting agent, defoamer, thickener, antifreeze, emulsifier in the above-mentioned formulation material are mixed through high speed shear, add bromine cyanogen insect amide, Avermectin ball milling 2～3 hours in ball mill, make diameter of particle all below 5 μ m, make suspending agent product of the present invention.
The Pesticidal combination of described brominated cyanogen insect amide and biogenic class, it is characterized in that: comprise following constituent content when composition is made suspension emulsion: active components A 0.1%～60%, active component B 0.1%～60%, emulsifier 2%～12%, dispersant 2%～10%, defoamer 0.1%～2%, thickener 0.1%～2%, antifreeze 0.1%～8%, stabilizing agent 0.05%～3%, deionized water add to 100%.
Dispersant, defoamer, thickener, antifreeze, stabilizing agent in the above-mentioned formulation material are mixed through high speed shear, add the former medicine of bromine cyanogen insect amide, ball milling is 2～3 hours in ball mill, make diameter of particle all below 5 μ m, make bromine cyanogen insect amide suspending agent, then with the former medicine of active component B, emulsifier and various auxiliary agent with the direct emulsification of high speed agitator in suspending agent, make suspension emulsion product of the present invention.
Comprise following constituent content when composition is made aqueous emulsion: property composition A0.1%～60%, active component B 0.1%～60%, solvent 0%～30%, emulsifier 1%～15%, co-emulsifier 0%～8%, antifreeze 0%～10%, thickener 0.1%～2%, defoamer 0.01%～2%, deionized water are supplied surplus while still alive.
Above-mentioned prescription is mixed, active ingredient, solvent, emulsifier, co-emulsifier are added together, make and be dissolved into even oil phase; Water, antifreeze, thickener, defoamer are mixed, become the homogeneous water.Under high-speed stirred, water is added oil phase, make aqueous emulsion product of the present invention.
Comprise following constituent content active components A 0.1%～60%, active component B 0.1%～60%, solvent 0%～30%, emulsifier 3%～20%, co-emulsifier 0%～12%, antifreeze 0%～10%, thickener 0.1%～2%, defoamer 0.01%～2%, stabilizing agent 0%～4% when composition is made microemulsion, deionized water is supplied surplus.
Bromine cyanogen insect amide and the former medicine of active component B are dissolved in the homogenizer that solvent and cosolvent are housed; Mix strongly after joining emulsifier, stabilizing agent and antifreeze, water in the homogenizer that above-mentioned solution is housed and homogenize, obtain the as clear as crystal microemulsion product of the present invention of outward appearance at last.
Composition is made micro-capsule suspension and is comprised following constituent content: active components A 0.1%～60%, active component B 0.1%～40%, macromolecule cyst material 1%～12%, surfactant 2%～10%, organic solvent 1%～15%, emulsifier 1%～8%, pH conditioning agent 0.1%～5%, deionized water adds to 100%.
The macromolecule cyst material is added the PH conditioning agent be heated to uniform temperature, obtain thick liquid, thin up forms stable prepolymer solution then, active ingredient B, bromine cyanogen insect amide are dissolved in the organic solvent, be added to again in the prepolymer solution, add emulsifier, surfactant, and fully shear agitation is dispersed into superfine microgranular, add the PH conditioning agent again, and heat up, the catalysis polycondensation forms the microcapsules of firm difficult infiltration, makes micro-capsule suspension of the present invention.
When the formulation of composition was microcapsules suspension-suspending agent, the auxiliary agent of interpolation was that surfactant, emulsifier, solvent, PH conditioning agent, macromolecule cyst material, defoamer, thickener, water add to 100%.
Composition comprises following constituent content when making microcapsule suspension-suspending agent: active components A 0.1%～60%, active component B 0.1%～40%, macromolecule cyst material 2%～12%, surfactant 3%～15%, organic solvent 1%～5%, emulsifier 1%～6%, defoamer 0.2%～5%, thickener 0.2%～5%, pH conditioning agent 0.1%～5%, water add to 100%.
Adopt interfacial polymerization, to there be active ingredient B, macromolecule cyst material, organic solvent to mix in the above-mentioned prescription, make and be dissolved into even oil phase, oil phase is joined under shearing condition in the aqueous phase solution that contains emulsifier, pH conditioning agent, two kinds of materials react at oil-water interfaces, form the macromolecule cyst wall around the drop that contains chemical substance, make active ingredient B micro-capsule suspension.Surfactant, defoamer, thickener, antifreeze are mixed through high speed shear, add the former medicine of bromine cyanogen insect amide, ball milling is 2～3 hours in ball mill, make diameter of particle all below 5 μ m, make bromine cyanogen insect amide suspending agent, to be dissolved in bromine cyanogen insect amide suspending agent stable in the water then and join in the aqueous phase solution of active ingredient B micro-capsule suspension, make the finely disseminated microcapsule suspension of the present composition-suspending agent product.
Described dispersant is selected from alkylnaphthalene sulfonate, two (alkyl) naphthalenesulfonate formaldehyde condensation compound, naphthalene sulfonic acid-formaldehyde condensation product, aryl phenol polyoxyethylene succinate sulfonate, octylphenol polyethylene oxyethylene group ether sulfate, polycarboxylate, lignosulfonates, the phonetic formaldehyde condensation products sulphate of alkylphenol-polyethenoxy, alkyl benzene sulfonate calcium salt, the naphthalene sulfonic acid-formaldehyde condensation product sodium salt, alkylphenol-polyethenoxy is phonetic, aliphatic amine polyoxyethylene is phonetic, polyoxyethylene carboxylate, during the ester polyoxyethylene is phonetic one or more.
Described wetting agent is selected from: lauryl sodium sulfate, neopelex, Nekal BX, washing powder, farming breast 2000
#Series, sldium lauryl sulfate, wetting and penetrating agent F, wetting agent T, spaonin powder, tea are withered, in the silkworm excrement, soapberry powder one or more.
Described disintegrant is selected from: one or more in bentonite, urea, ammonium sulfate, aluminium chloride, the glucose.
Described emulsifier is selected from: farming breast 500
#(alkyl benzene calcium sulfonate), OP series phosphate (polyoxyethylene nonylphenol ether phosphate), 600
#Phosphate (phenyl phenol polyoxy ethyl ether phosphate), styrene polyoxyethylene ether ammonium sulfate salt, alkyl biphenyl ether disulfonic acid magnesium salts, triethanolamine salt, farming breast 400
#(benzyl dimethyl phenol polyoxy ethyl ether), farming breast 600
#(phenyl phenol polyoxy ethyl ether), Nongru-700
#(alkylphenol-formaldehyde resin polyoxy ethyl ether), farming breast 36
#(phenethyl fluosite polyoxy ethyl ether), farming breast 1600
#(phenethyl phenol polyoxy ethyl polypropylene-base ether), ethylene oxide-propylene oxide block copolymer, OP series (polyoxyethylene nonylphenol ether), By series (castor oil polyoxyethylene ether), farming breast 33
#(alkylaryl polyoxyethylene polyoxypropylene ether), farming breast 34
#In (alkylaryl polyoxyethylene poly-oxygen propylene aether), sapn series (sorbitan monostearate), tween series (sorbitan fatty acid ester APEO), the EO series (the pure APEO of fat) one or more.
Described antifreeze is selected from: one or more in ethylene glycol, propane diols, glycerine, the polyethylene glycol.
Described defoamer is selected from: silicone, C
8～10Aliphatic alcohols, C
10～20In saturated fat acids (as capric acid) and acid amides, silicone oil, the silicone compound one or more.
Described thickener is selected from: one or more in xanthans, CMC, hydroxyethylcellulose, methylcellulose, Magnesiumaluminumsilicate, the polyvinyl alcohol.
The macromolecule cyst material is selected from one or more in urea, formaldehyde, PIC, polyfunctional group acyl halide polyamines, polyfunctional group acyl halide dihydroxylic alcohols, sodium alginate, polyvinyl alcohol, gelatin, gum Arabic, sucrose, modified starch, maltose, distortion milk protein, glycerine, calcium chloride, carboxymethyl cellulose, the beta-schardinger dextrin-.
Described filler is selected from: one or more in kaolin, diatomite, bentonite, attapulgite, white carbon, starch, precipitated calcium carbonate, the vegetable oil.
Wetting powder the key technical indexes of the present invention:
Water dispersible granules the key technical indexes of the present invention:
Suspending agent the key technical indexes of the present invention:
Suspension emulsion the key technical indexes of the present invention:
Aqueous emulsion the key technical indexes of the present invention:
Microemulsion the key technical indexes of the present invention:
Microcapsule suspending agent the key technical indexes of the present invention:
Microcapsule suspension of the present invention-suspending agent the key technical indexes:
The invention has the advantages that:
(1) bromine cyanogen insect amide and Avermectin, ethyl pleocidin composite after, have notable synergistic and lasting effect;
(2) enlarged insecticidal spectrum, the brown planthopper of paddy rice, wheat, cotton, fruit tree, brassicaceous vegetable, white-backed planthopper, small brown rice planthopper, trialeurodes vaporariorum, Bemisia tabaci, aphid, scale insect, thrips, rice leaf roller, striped rice borer, paddy stem borer, twill diamond-back moth, cabbage caterpillar, apple leaf miner, beet armyworm, tetranychid, goitre mite, yellow tea mite, cotton bollworm etc. have all been had greater activity;
(3) reduce the dosage of agricultural chemicals, reduced the residual quantity of agricultural chemicals on crop, alleviated environmental pollution;
(4) to the person poultry safety, Environmental compatibility is good, and insect is difficult for developing immunity to drugs.
Embodiment
Below in conjunction with the further instruction of the present invention of embodiment, the percentage among the embodiment all is weight percentage, but the present invention is not limited thereto.
Application Example one
Embodiment 1 40.5% bromine cyanogen insect amide Avermectin wetting powder
Bromine cyanogen insect amide 40%, Avermectin 0.5%, polycarboxylate 6%, sldium lauryl sulfate 5%, attapulgite add to 100%, and mixture carries out air-flow to be pulverized, and makes 40.5% bromine cyanogen insect amide Avermectin wetting powder.
Embodiment 2 40% bromine cyanogen insect amide Avermectin wetting powders
Bromine cyanogen insect amide 30%, Avermectin 10%, alkylphenol-polyethenoxy are phonetic 6%, tea is withered 4%, kaolin adds to 100%, and mixture carries out air-flow to be pulverized, and makes 40% bromine cyanogen insect amide Avermectin wetting powder.
Embodiment 3 15% bromine cyanogen insect amide Avermectin wetting powders
Bromine cyanogen insect amide 10%, Avermectin 5%, alkylphenol-polyethenoxy are phonetic 6%, soapberry powder 4%, kaolin add to 100%, and mixture carries out air-flow to be pulverized, and makes 15% bromine cyanogen insect amide Avermectin wetting powder.
Embodiment 4 8.1% bromine cyanogen insect amide Avermectin water dispersible granules
Bromine cyanogen insect amide 0.1%, Avermectin 8%, the phonetic formaldehyde condensation products sulphate 6% of alkylphenol-polyethenoxy, sldium lauryl sulfate 5%, urea 2%, kaolin add to 100%, the mixed 8.1% bromine cyanogen insect amide Avermectin water dispersible granules that gets.
Embodiment 5 25% bromine cyanogen insect amide Avermectin water dispersible granules
Bromine cyanogen insect amide 15%, Avermectin 10%, neopelex 4%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 6.8%, ammonium sulfate 2.2%, bentonite add to 100%, the mixed 25% bromine cyanogen insect amide Avermectin water dispersible granules that gets.
Embodiment 6 18% bromine cyanogen insect amide Avermectin water dispersible granules
Bromine cyanogen insect amide 12%, Avermectin 6%, Nekal BX 6%, ester polyoxyethylene are phonetic 7%, glucose 2%, bentonite add to 100%, mixed 18% bromine cyanogen insect amide Avermectin water dispersible granules.
Embodiment 7 35% bromine cyanogen insect amide Avermectin suspending agents
Bromine cyanogen insect amide 33%, Avermectin 2%, polycarboxylate 5%, neopelex 4%, C
10～20Saturated fat acids 2%, polyvinylpyrrolidone 1.2%, diethylene glycol (DEG) 0.8%, deionized water add to 100%, the mixed 35% bromine cyanogen insect amide Avermectin suspending agent that gets.
Embodiment 8 30% bromine cyanogen insect amide Avermectin suspending agents
Bromine cyanogen insect amide 25%, Avermectin 5%, alkylaryl APEO 6%, lauryl sodium sulfate 6%, silicone 1%, sodium alginate 2%, deionized water add to 100%, the mixed 30% bromine cyanogen insect amide Avermectin suspending agent that gets.
Embodiment 9 30% bromine cyanogen insect amide Avermectin suspending agents
Bromine cyanogen insect amide 20%, Avermectin 10%, polyoxyethylene carboxylate 6%, silkworm excrement 5%, C
8～10Aliphatic alcohols 1.2%, polyvinyl alcohol 2%, deionized water add to 100%, the mixed 30% bromine cyanogen insect amide Avermectin suspending agent that gets.
Embodiment 10 40% bromine cyanogen insect amide Avermectin suspension emulsions
Bromine cyanogen insect amide 35%, Avermectin 5%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 7%, neopelex 6%, benzyl dimethyl phenol polyoxy ethyl ether 6%, ethyl acetate 5%, C8～10 aliphatic alcohols 1%, polyvinyl alcohol 2%, polyethylene glycol 1.8%, deionized water add to 100%, the mixed 40% bromine cyanogen insect amide Avermectin suspension emulsion that gets.
Embodiment 11 30% bromine cyanogen insect amide Avermectin suspension emulsions
Bromine cyanogen insect amide 24%, Avermectin 6%, polyoxyethylene carboxylate 7%, spaonin powder 4%, castor oil polyoxyethylene ether 2%, silicone oil 0.8%, CMC 1.5%, polyethylene glycol 2%, deionized water add to 100%, the mixed 30% bromine cyanogen insect amide Avermectin suspension emulsion that gets.
Embodiment 12 20% bromine cyanogen insect amide Avermectin suspension emulsions
Bromine cyanogen insect amide 13%, Avermectin 7%, ester polyoxyethylene are phonetic 6%, tea is withered 4%, styrene polyoxyethylene ether ammonium sulfate salt 5%, silicone 0.5%, phenolic resins 1.5%, ethylene glycol 1.2%, deionized water add to 100%, mixed 20% bromine cyanogen insect amide Avermectin suspension emulsion.
Embodiment 13 55% bromine cyanogen insect amide avermectin micro-emulsions
Bromine cyanogen insect amide 50%, Avermectin 5%, sorbitan fatty acid ester APEO 7%, cyclohexanone 4%, diethylene glycol (DEG) 1%, PAA 1%, silicone oil 0.9%, organic acid 2%, deionized water supplies 100%, the mixed 55% bromine cyanogen insect amide avermectin micro-emulsion that gets.
Embodiment 14 25% bromine cyanogen insect amide avermectin micro-emulsions
Bromine cyanogen insect amide 21%, Avermectin 4%, N-pyrrolidones 7%, xanthans 5%, phenolic resins 1.6%, fatty alcohol-polyoxyethylene ether 7%, C
8～10Aliphatic alcohols 1.4%, monoethanolamine 1.5%, deionized water supplies 100%, makes 25% bromine cyanogen insect amide avermectin micro-emulsion.
Embodiment 15 9% bromine cyanogen insect amide avermectin micro-emulsions
Bromine cyanogen insect amide 6%, Avermectin 3%, butyl ether 7%, phenethyl fluosite polyoxy ethyl ether 6%, PAA 1.5%, propane diols 2%, silicone 1.4%, triethanolamine 1%, deionized water supplies 100%, the mixed 9% bromine cyanogen insect amide avermectin micro-emulsion that gets.
Embodiment 16 40% bromine cyanogen insect amide abamectin aqueous emulsions
Bromine cyanogen insect amide 20%, Avermectin 20%, toluene 5%, vegetable oil 5%, phenethyl fluosite polyoxy ethyl ether 6%, propane diols 2%, C
8～10Aliphatic alcohols 0.8%, deionized water adds to 100%, the mixed 40% bromine cyanogen insect amide abamectin aqueous emulsion that gets.
Embodiment 17 30% bromine cyanogen insect amide abamectin aqueous emulsions
Bromine cyanogen insect amide 22%, Avermectin 8%, acetonitrile 4%, propyl alcohol 3%, castor oil polyoxyethylene ether 8%, propane diols 1.6%, C
8～10Aliphatic alcohols 1.5%, deionized water adds to 100%, through the mixed 30% bromine cyanogen insect amide abamectin aqueous emulsion that gets.
Embodiment 18 20% bromine cyanogen insect amide abamectin aqueous emulsions
Bromine cyanogen insect amide 12%, Avermectin 8%, acetone 4%, vegetable oil 5%, sorbitan monostearate 8%, polyvinyl alcohol 1.8%, silicone 0.8%, deionized water adds to 100%, through the mixed 20% bromine cyanogen insect amide abamectin aqueous emulsion that gets.
Embodiment 19 25% bromine cyanogen insect amide avermectin microcapsule suspending agents
Bromine cyanogen insect amide 15%, Avermectin 10%, sodium alginate 3%, maltose 2%, dodecylbenzene sodium sulfonate 5%, ester polyoxyethylene are phonetic 2.4%, cyclohexanone 6%, alkylphenol-formaldehyde resin polyoxy ethyl ether 5%, citric acid 0.9%, sodium hydroxide 0.6%, deionized water add to 100% weight portion, make 25% bromine cyanogen insect amide avermectin microcapsule suspending agent.
Embodiment 20 15% bromine cyanogen insect amide avermectin microcapsule suspension-suspending agents
Bromine cyanogen insect amide 10%, Avermectin 5%, modified starch 3%, calcium chloride 4%, fatty acyl amido be to methoxy benzenesulfonic acid sodium 6%, wetting agent T 2.5%, methyl alcohol 4%, cyclohexanone 3%, farming breast 500
#5%, the farming breast 33
#4%, C
8～10Aliphatic alcohols 0.6%, white dextrin 1.2%, pH conditioning agent sodium hydroxide and citric acid amount to 3.8%, water adds to 100% weight portion, make 15% bromine cyanogen insect amide avermectin microcapsule suspension-suspending agent.
Embodiment 21 80% bromine cyanogen insect amide ethyl pleocidin wetting powders
Bromine cyanogen insect amide 79%, ethyl pleocidin 1%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 6%, soapberry powder 5%, precipitated calcium carbonate add to 100%, and mixture carries out air-flow to be pulverized, and makes 80% bromine cyanogen insect amide ethyl pleocidin wetting powder.
Embodiment 22 60% bromine cyanogen insect amide ethyl pleocidin wetting powders
Bromine cyanogen insect amide 30%, ethyl pleocidin 30%, alkylphenol-polyethenoxy are phonetic 6%, silkworm excrement 4%, kaolin add to 100%, and mixture carries out air-flow to be pulverized, and makes 60% bromine cyanogen insect amide ethyl pleocidin wetting powder.
Embodiment 23 40% bromine cyanogen insect amide ethyl pleocidin wetting powders
Bromine cyanogen insect amide 30%, ethyl pleocidin 10%, aliphatic amine polyoxyethylene are phonetic 6%, wetting and penetrating agent F 4%, diatomite add to 100%, and mixture carries out air-flow to be pulverized, and makes 40% bromine cyanogen insect amide ethyl pleocidin wetting powder.
Embodiment 24 40.5% bromine cyanogen insect amide ethyl pleocidin water dispersible granules
Bromine cyanogen insect amide 0.5%, ethyl pleocidin 40%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 6%, neopelex 5%, urea 2%, kaolin add to 100%, the mixed 40.5% bromine cyanogen insect amide ethyl pleocidin water dispersible granules that gets.
Embodiment 25 50% bromine cyanogen insect amide ethyl pleocidin water dispersible granules
Bromine cyanogen insect amide 25%, ethyl pleocidin 25%, lauryl sodium sulfate 4%, alkylphenol-polyethenoxy are phonetic 6%, sodium carbonate 2.2%, bentonite add to 100%, mixed 50% bromine cyanogen insect amide ethyl pleocidin water dispersible granules.
Embodiment 26 30% bromine cyanogen insect amide ethyl pleocidin water dispersible granules
Bromine cyanogen insect amide 10%, ethyl pleocidin 20%, bentonite 6%, the phonetic formaldehyde condensation products sulphate 7% of alkylphenol-polyethenoxy, aluminium chloride 2%, bentonite add to 100%, the mixed 30% bromine cyanogen insect amide ethyl pleocidin water dispersible granules that gets.
Embodiment 27 30% bromine cyanogen insect amide ethyl pleocidin suspending agents
Bromine cyanogen insect amide 20%, ethyl pleocidin 10%, aryl phenol polyoxyethylene succinate sulfonate 5%, spaonin powder 4%, silicone oil 2%, polyvinylpyrrolidone 1.2%, diethylene glycol (DEG) 0.8%, deionized water add to 100%, the mixed 30% bromine cyanogen insect amide ethyl pleocidin suspending agent that gets.
Embodiment 28 20% bromine cyanogen insect amide ethyl pleocidin suspending agents
Bromine cyanogen insect amide 10%, ethyl pleocidin 10%, alkylphenol-polyethenoxy are phonetic 6%, neopelex 6%, C
8～10Aliphatic alcohols 1%, phenolic resins 2%, deionized water add to 100%, the mixed 20% bromine cyanogen insect amide ethyl pleocidin suspending agent that gets.
Embodiment 29 15% bromine cyanogen insect amide ethyl pleocidin suspending agents
Bromine cyanogen insect amide 10%, ethyl pleocidin 5%, ester polyoxyethylene are phonetic 6%, soapberry powder 5%, silicone 1.2%, methylcellulose 2%, deionized water add to 100%, mixed 15% bromine cyanogen insect amide ethyl pleocidin suspending agent.
Embodiment 30 45% bromine cyanogen insect amide ethyl pleocidin suspension emulsions
Bromine cyanogen insect amide 30%, ethyl pleocidin 15%, alkylphenol-polyethenoxy are phonetic 7%, spaonin powder 6%, alkylphenol-formaldehyde resin polyoxy ethyl ether 6%, vegetable oil 5%, C
10～20Saturated fat acids 1%, polyvinyl alcohol 2%, polyethylene glycol 1.8%, deionized water add to 100%, the mixed 45% bromine cyanogen insect amide ethyl pleocidin suspension emulsion that gets.
Embodiment 31 30% bromine cyanogen insect amide ethyl pleocidin suspension emulsions
Bromine cyanogen insect amide 24%, ethyl pleocidin 6%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 7%, wetting and penetrating agent F 4%, fatty alcohol-polyoxyethylene ether 2%, C
8～10Aliphatic alcohols 0.8%, sodium phosphate trimer 1.5%, ethylene glycol 2%, deionized water add to 100%, the mixed 30% bromine cyanogen insect amide ethyl pleocidin suspension emulsion that gets.
Embodiment 32 10% bromine cyanogen insect amide ethyl pleocidin suspension emulsions
Bromine cyanogen insect amide 5%, ethyl pleocidin 5%, polyoxyethylene carboxylate 6%, silkworm excrement 4%, alkyl biphenyl ether disulfonic acid magnesium salts 5%, silicone oil 0.5%, sodium alginate 1.5%, ethylene glycol 1.2%, deionized water add to 100%, the mixed 10% bromine cyanogen insect amide ethyl pleocidin suspension emulsion that gets.
Embodiment 33 35% bromine cyanogen insect amide ethyl pleocidin microemulsions
Bromine cyanogen insect amide 20%, ethyl pleocidin 15%, fatty alcohol-polyoxyethylene ether 7%, ethyl acetate 4%, polyethylene glycol 1%, polyvinylpyrrolidone 1%, silicone 0.9%, antioxidant 2%, deionized water supplies 100%, the mixed 35% bromine cyanogen insect amide ethyl pleocidin microemulsion that gets.
Embodiment 34 30% bromine cyanogen insect amide ethyl pleocidin microemulsions
Bromine cyanogen insect amide 15%, ethyl pleocidin 15%, toluene 7%, PAA 5%, sodium alginate 1.6%, alkylaryl polyoxyethylene poly-oxygen propylene aether 7%, C
10～20Saturated fat acids 1.4%, triethanolamine 1.5%, deionized water supplies 100%, makes 30% bromine cyanogen insect amide ethyl pleocidin microemulsion.
Embodiment 35 15% bromine cyanogen insect amide ethyl pleocidin microemulsions
Bromine cyanogen insect amide 10%, ethyl pleocidin 5%, vegetable oil 7%, phenethyl phenol polyoxy ethyl polypropylene-base ether 6%, polyvinylpyrrolidone 1.5%, glycerine 2%, silicone 1.5%, organic acid 1%, deionized water supplies 100%, the mixed 15% bromine cyanogen insect amide ethyl pleocidin microemulsion that gets.
Embodiment 36 40% bromine cyanogen insect amide ethyl pleocidin aqueous emulsions
Bromine cyanogen insect amide 10%, ethyl pleocidin 30%, ethyl acetate 7%, ethylene oxide-propylene oxide block copolymer 6%, glycerine 2%, C
8～10Aliphatic alcohols 0.8%, deionized water adds to 100%, the mixed 40% bromine cyanogen insect amide ethyl pleocidin aqueous emulsion that gets.
Embodiment 37 30% bromine cyanogen insect amide ethyl pleocidin aqueous emulsions
Bromine cyanogen insect amide 10%, ethyl pleocidin 20%, vegetable oil 4%, ethyl acetate 5%, sorbitan monostearate 8%, polyethylene glycol 1.6%, C
10～20Saturated fat acids 1.5%, deionized water adds to 100%, through the mixed 30% bromine cyanogen insect amide ethyl pleocidin aqueous emulsion that gets.
Embodiment 38 25% bromine cyanogen insect amide ethyl pleocidin aqueous emulsions
Bromine cyanogen insect amide 5%, ethyl pleocidin 20%, ethyl acetate 4%, butyl ether 5%, sorbitan fatty acid ester APEO 8%, polyethylene glycol 1.8%, C
8～10Aliphatic alcohols 0.8%, deionized water adds to 100%, through the mixed 25% bromine cyanogen insect amide ethyl pleocidin aqueous emulsion that gets.
Embodiment 39 35% bromine cyanogen insect amide ethyl pleocidin micro-capsule suspensions
Bromine cyanogen insect amide 25%, ethyl pleocidin 10%, polyfunctional group acyl halide dihydroxylic alcohols 3%, PIC 2%, dodecylbenzene sodium sulfonate 5%, polyoxyethylene carboxylate 2.4%, ethyl acetate 6%, phenethyl fluosite polyoxy ethyl ether 5%; citric acid 0.8%, sodium hydroxide 0.4%, deionized water add to 100% weight portion, make 35% bromine cyanogen insect amide ethyl pleocidin micro-capsule suspension.
Embodiment 40 35% bromine cyanogen insect amide ethyl pleocidin microcapsule suspension-suspending agents
Bromine cyanogen insect amide 20%, ethyl pleocidin 15%, maltose 3%, glycerine 4%, fatty acyl amido are to methoxy benzenesulfonic acid sodium 6%, wetting agent T 2.5%, vegetable oil 4%, butyl ether 3%, phenyl phenol polyoxy ethyl ether phosphate 5%, alkylaryl polyoxyethylene polyoxypropylene ether 4%, silicone 0.6%, PAA 1.2%, pH conditioning agent sodium hydroxide and citric acid amount to 3.8%, water adds to 100% weight portion, make 35% bromine cyanogen insect amide ethyl pleocidin microcapsule suspension-suspending agent.
The embodiment of the invention is the method that adopts Toxicity Determination and field trial to combine.Earlier by Toxicity Determination, the co-toxicity coefficient (CTC) after clear and definite two kinds of medicaments are composite by a certain percentage, CTC＜80 are antagonism, and 80≤CTC≤120 are summation action, and CTC＞120 are synergistic effect, on this basis, carry out field trial again.
Test method: respectively the mother liquor of each mixed agent is diluted to five series concentration during test, places beaker standby respectively.Adopt and to soak the method that connects worm behind the leaf earlier, the blade of the same size that does not contact any medicament soaked in the soup that configures behind the 5s take out, dry naturally, put into insect box, connect then for the examination larva, under 25 ℃ of conditions, raise, every processing repeats for 3 times, every to repeat used examination borer population be 50, establishes blank simultaneously, checks dead borer population in 72h, calculate lethality and corrected mortality, try to achieve virulence regression equation and calculate the LC50 value.If the contrast lethality then is considered as invalid test greater than 10%.Computing formula is as follows:
The insect corrected mortality is converted into probit value (y), and concentration for the treatment of (μ g/ml) converts logarithm value (x) to, draws virulence regression equation with method of least squares, and calculates the value of every kind of medicament thus.Calculate co-toxicity coefficient CTC according to the abundant equation of Sun Yun.Computing formula following (be standard medicament with the bromine cyanogen insect amide, its toxicity index is 100):
TI * the P of theoretical toxicity index (TTI)=bromine cyanogen insect amide of M
The bromine cyanogen insect amideTI * P of+active component B
Active component B
In the formula: M is the mixture of different proportionings;
P
Active component BBe active component B shared ratio in composition;
P
The bromine cyanogen insect amideBe bromine cyanogen insect amide shared ratio in composition.
Annotate: active component B is a kind of arbitrarily in Avermectin, the ethyl pleocidin.
Application Example two:
For trying insect: white-backed planthopper.
Experimental scheme: effective lethal concentration scope of determining bromine cyanogen insect amide, the former medicine of Avermectin and the two different proportioning mixture through preliminary experiment.
Toxicity test result one
The different proportionings with Avermectin of table 1 bromine cyanogen insect amide are to the toxicity test of diamond-back moth
As shown in Table 1, fitting over of bromine cyanogen insect amide and abamectin compounded control diamond-back moth: 80: 1 to 1: 80 o'clock, co-toxicity coefficient is all greater than 120, illustrating that both were mixed in the scope at 80: 1 to 1: 80 all shows synergistic effect, especially when bromine cyanogen insect amide and Avermectin get proportioning at 20: 1 to 1: 20, synergistic effect is more obviously outstanding, co-toxicity coefficient maximum when bromine cyanogen insect amide and Avermectin weight ratio are 2: 1 wherein, synergistic effect is the most obvious, find simultaneously, bromine cyanogen insect amide and Avermectin proportioning were at 19: 1,18: 1,17: 1,16: 1,15: 1,14: 1,13: 1,12: 1,11: 1,10: 1,9: 1,8: 1,7: 1,6: 1,5: 1,4: 1,3: 1,2: 1,1: 1,1: 2,1: 3,1: 4,1: 5,1: 6,1: 7,1: 8,1: 9,1: 10,1: 11,1: 12,1: 13,1: 14,1: 15,16: 1,17: 1,18: 1,19: 1 o'clock composite to the control brown planthopper, white-backed planthopper, small brown rice planthopper, trialeurodes vaporariorum, Bemisia tabaci, aphid, scale insect, thrips, rice leaf roller, striped rice borer, paddy stem borer, the twill diamond-back moth, cabbage caterpillar, apple leaf miner, beet armyworm, tetranychid, the goitre mite, yellow tea mite, insects such as cotton bollworm also have synergistic effect preferably, and co-toxicity coefficient is all greater than 140.
Application Example three:
For trying insect: beet armyworm.
Experimental scheme: effective lethal concentration scope of determining bromine cyanogen insect amide, the former medicine of ethyl pleocidin and the two different proportioning mixture through preliminary experiment.
Toxicity test result two
The different proportionings with ethyl pleocidin of table 2 bromine cyanogen insect amide are to the toxicity test of beet armyworm
As shown in Table 2, the proportioning of the composite control of bromine cyanogen insect amide and ethyl pleocidin beet armyworm was at 80: 1 to 1: 80 o'clock, co-toxicity coefficient is all greater than 120, illustrating that both were mixed in the scope at 80: 1 to 1: 80 all shows synergistic effect, especially when bromine cyanogen insect amide and ethyl pleocidin get proportioning at 20: 1 to 1: 20, synergistic effect is more obviously outstanding, co-toxicity coefficient maximum when bromine cyanogen insect amide and ethyl pleocidin weight ratio are 1: 1 wherein, synergistic effect is the most obvious, find simultaneously, bromine cyanogen insect amide and ethyl pleocidin proportioning were at 19: 1,18: 1,17: 1,16: 1,15: 1,14: 1,13: 1,12: 1,11: 1,10: 1,9: 1,8: 1,7: 1,6: 1,5: 1,4: 1,3: 1,2: 1,1: 1,1: 2,1: 3,1: 4,1: 5,1: 6,1: 7,1: 8,1: 9,1: 10,1: 11,1: 12,1: 13,1: 14,1: 15,16: 1,17: 1,18: 1,19: 1 o'clock composite to the control brown planthopper, white-backed planthopper, small brown rice planthopper, trialeurodes vaporariorum, Bemisia tabaci, aphid, scale insect, thrips, rice leaf roller, striped rice borer, paddy stem borer, the twill diamond-back moth, cabbage caterpillar, apple leaf miner, beet armyworm, tetranychid, the goitre mite, yellow tea mite, insects such as cotton bollworm also have synergistic effect preferably, and co-toxicity coefficient is all greater than 160.
Application Example tetrabromo cyanogen insect amide and Avermectin and the composite control rice leaf roller test of pesticide effectiveness thereof
This experimental establishment is in the Haiyan County, Jiaxing City, Zhejiang Province, and test medicine is provided by Shaanxi Welch Crop Protection Co., Ltd., contrast medicament 10% bromine cyanogen insect amide suspending agent (autogamy), 2% abamectin emulsifiable concentrate (commercial).
Conventional spray-on process is adopted in test, and investigation rice leaf roller insect pest index before the medicine in the dispenser of insect pest initial stage of origination, was investigated the insect pest indexes in 3 days, 7 days, 14 days after the dispenser and calculated preventive effect.Experimental result is as follows:
Table 3 bromine cyanogen insect amide, Avermectin and the composite control rice leaf roller test of pesticide effectiveness thereof
As can be seen from Table 3, the bromine cyanogen insect amide and abamectin compounded after can effectively prevent and treat rice leaf roller, control efficiency all is better than the preventive effect of single agent, and the preventive effect time is long.In the test scope of medication, the target crop is had no adverse effects.
Application Example pentabromo-cyanogen insect amide and Avermectin and the composite control cotton cotton bollworm test of pesticide effectiveness thereof
This experimental establishment is in Weinan City Dali County, Shaanxi Province, and test medicine is provided by Shaanxi Welch Crop Protection Co., Ltd., contrast medicament 10% bromine cyanogen insect amide suspending agent (autogamy), 2% abamectin emulsifiable concentrate (commercial).
Conventional spray-on process is adopted in test, and investigation cotton cotton bollworm insect pest index in the dispenser of insect pest initial stage of origination, was investigated the insect pest indexes in 3 days, 7 days, 14 days after the dispenser and calculated preventive effect before the medicine.Experimental result is as follows:
Table 4 bromine cyanogen insect amide, Avermectin and the composite control cotton cotton bollworm test of pesticide effectiveness thereof
As can be seen from Table 4, the bromine cyanogen insect amide and abamectin compounded after can effectively prevent and treat the cotton cotton bollworm, control efficiency all is better than the preventive effect of single agent, and the preventive effect time is long.In the test scope of medication, the target crop is had no adverse effects.
Application Example hexabromo cyanogen insect amide and ethyl pleocidin and the composite control rice-stem borer test of pesticide effectiveness thereof
This experimental establishment is in the Haiyan County, Jiaxing City, Zhejiang Province, and test medicine is provided by Shaanxi Welch Crop Protection Co., Ltd., contrast medicament 10% bromine cyanogen insect amide suspending agent (autogamy), 10% ethyl pleocidin suspending agent (autogamy).
Conventional spray-on process is adopted in test, and investigation rice-stem borer insect pest index before the medicine in the dispenser of insect pest initial stage of origination, was investigated the insect pest indexes in 3 days, 7 days, 14 days after the dispenser and calculated preventive effect.Experimental result is as follows:
Table 5 bromine cyanogen insect amide, ethyl pleocidin and the composite control rice-stem borer test of pesticide effectiveness thereof
As can be seen from Table 5, can effectively prevent and treat rice-stem borer after bromine cyanogen insect amide and ethyl pleocidin are composite, control efficiency all is better than the preventive effect of single agent, and the preventive effect time is long.In the test scope of medication, the target crop is had no adverse effects.
Application Example seven bromine cyanogen insect amides and ethyl pleocidin and the composite control wild cabbage diamond-back moth test of pesticide effectiveness thereof
This experimental establishment is at Baoji, Shaanxi province city Chencang District, and test medicine is provided by Shaanxi Welch Crop Protection Co., Ltd., contrast medicament 10% bromine cyanogen insect amide suspending agent (autogamy), 10% ethyl pleocidin suspending agent (autogamy).
Conventional spray-on process is adopted in test, and investigation wild cabbage diamond-back moth insect pest index in the dispenser of insect pest initial stage of origination, was investigated the insect pest indexes in 3 days, 7 days, 14 days after the dispenser and calculated preventive effect before the medicine.Experimental result is as follows:
Table 6 bromine cyanogen insect amide, ethyl pleocidin and composite control wild cabbage diamond-back moth thereof are imitated test
As can be seen from Table 6, can effectively prevent and treat the wild cabbage diamond-back moth after bromine cyanogen insect amide and ethyl pleocidin are composite, control efficiency all is better than the preventive effect of single agent, and the preventive effect time is long.In the test scope of medication, the target crop is had no adverse effects.
Claims (7)
1. the Pesticidal combination of a brominated cyanogen insect amide and biogenic class, comprise active components A, active component B, the auxiliary agent surplus, it is characterized in that: active components A is the bromine cyanogen insect amide, active component B is a kind of arbitrarily in Avermectin, the ethyl pleocidin, and the weight ratio of active components A and active component B is 1: 80～80: 1.
2. Pesticidal combination according to claim 1, it is characterized in that: the weight ratio of active components A and active component B is 1: 60～40: 1.
3. Pesticidal combination according to claim 2, it is characterized in that: the weight ratio of bromine cyanogen insect amide and Avermectin is 1: 10～30: 1.
4. Pesticidal combination according to claim 2, it is characterized in that: the weight ratio of bromine cyanogen insect amide and ethyl pleocidin is 1: 30～30: 1.
5. according to any described Pesticidal combination in the claim 1～4, it is characterized in that: composition is made wetting powder, water dispersible granules, suspending agent, suspension emulsion, aqueous emulsion, microemulsion, microcapsule suspending agent, microcapsule suspension-suspending agent.
6. Pesticidal combination according to claim 5 is used for the application of insect on control paddy rice, wheat, cotton, fruit tree, the brassicaceous vegetable.
7. application according to claim 6 is characterized in that institute's pest control comprises: brown planthopper, white-backed planthopper, small brown rice planthopper, trialeurodes vaporariorum, Bemisia tabaci, aphid, scale insect, thrips, rice leaf roller, striped rice borer, paddy stem borer, twill diamond-back moth, cabbage caterpillar, apple leaf miner, beet armyworm, tetranychid, goitre mite, yellow tea mite, cotton bollworm.
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