CN102396475A - Pesticide composition containing cyantraniliprole and abamectin - Google Patents

Pesticide composition containing cyantraniliprole and abamectin Download PDF

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CN102396475A
CN102396475A CN2011104293188A CN201110429318A CN102396475A CN 102396475 A CN102396475 A CN 102396475A CN 2011104293188 A CN2011104293188 A CN 2011104293188A CN 201110429318 A CN201110429318 A CN 201110429318A CN 102396475 A CN102396475 A CN 102396475A
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avm
insect amide
cyanogen insect
bromine cyanogen
insecticides
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CN2011104293188A
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Chinese (zh)
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梁调
臧延琴
李现玲
张继甫
郑宏文
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广西田园生化股份有限公司
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Priority to CN2011104293188A priority Critical patent/CN102396475A/en
Publication of CN102396475A publication Critical patent/CN102396475A/en

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Abstract

The invention discloses a pesticide composition containing cyantraniliprole and abamectin. The weight ratio of cyantraniliprole to abamectin is 1:12 to 12:1; and the cyantraniliprole and abamectin account for 0.5 to 80 percent of the weight of the pesticide composition in total, and agriculturally acceptable surfactant and solid carrier or liquid diluent account for the balance. The pesticide composition can be used for preventing and controlling various ground and underground pests in field crops, fruit trees, vegetables, other special crops and lawns, including lepidopterous pests, homopterous pests, coleopterous pests, dipterous pests and hemipterous pests. The pesticide composition expands the application ranges of cyantraniliprole pesticide and abamectin pesticide; meanwhile under the conditions of obvious synergistic effect and optical prevention and control effects, the pesticide composition reduces the dosage, namely dosage per mu, of the pesticides, and therefore the cost is reduced, and the environment harms are reduced.

Description

The insecticides of a kind of brominated cyanogen insect amide and AVM

Technical field

The invention belongs to technical field of pesticide, specifically relate to the insecticides of a kind of brominated cyanogen insect amide and AVM.

Background technology

The bromine cyanogen insect amide, English common name: Cyantranilrole, molecular formula: C 19H 14BrClN 6O 2, structural formula:

The bromine cyanogen insect amide is the ryania acceptor insecticide of a new generation; The pest control through the ryania acceptor that activates target pest; The activation of ryania acceptor can discharge the calcium ion of storing in striated muscle and the smooth muscle cell, stops contraction of muscle, thereby makes insect stop to get food rapidly; Muscular paralysis, vigor disappearance, paralysis occur, final insect is dead.Its applicable crops is extensive, can effectively prevent and treat Lepidoptera, Semiptera and coleopteran pest.This medicine shows mammal and the extremely significant selective difference of insect ryania acceptor simultaneously, and this has improved the safety to mammal, other vertebrates and other natural enemies greatly.

AVM is a new bio source insecticides, english common name: Abamectin, molecular formula: C 48H 72O 14(Bla) C 47H 70O 14(B1b), structural formula:

AVM is a kind of macrolide disaccharide compounds, and tool is tagged, stomach poison function, and very strong penetration is arranged.AVM is the natural products that from edaphon, separates; Insect and mite class had tag with stomach poison function and faint fumigation action is arranged; No systemic action, but it has very strong osmosis to blade, can kill subepidermal insect; And the longevity of residure is long, and it all has good preventive effect to various pests such as Lepidoptera, coleoptera, diptera, Homopteras.

At present one Chinese patent application number is: CN200910110487, and patent name is: disclose suspending agent of a kind of cyanogen insect amide and preparation method thereof in the patent application document of suspending agent of a kind of cyanogen insect amide and preparation method thereof, the suspending agent of said cyanogen insect amide contains following component by mass percent: cyanogen insect amide 1%-50%; Dispersant 2%-15%, wetting agent 1%-5%, functional aid 0%-6%; Antifoaming agent 0.2%-1%; Antifreezing agent 0%-10%, thickener 0.1%-5%, mould inhibitor 0.05%-0.8%; PH regulator agent 0%-2%, surplus is a water.Characteristics such as it is little that this invention has a preparation particle diameter, and narrow diameter distribution, and the normal temperature long term storage is stable, do not have the knot end, and condensate rate is minimum can improve the availability of active component.On the market 1.8% abamectin emulsifiable concentrate has been arranged also simultaneously, 1% AVM associated pesticide such as avermectin micro-emulsion are sold, but do not see insecticides relevant report or the medicament sale that contains bromine cyanogen insect amide and AVM.

Bromine cyanogen insect amide, AVM are one type of highly active compositions; Its usage amount can reach rational control efficiency under lower situation; Therefore under composite situation of carrying out composition, the content of bromine cyanogen insect amide, AVM needs strict research consideration.Use checking through test with actual, bromine cyanogen insect amide and AVM make up between ratio and the content and the preventive effect of its combination and have very big relation.The research and development of the Pesticidal combination of bromine cyanogen insect amide and AVM both provided a kind of new insecticide, and the drug effect when effectively strengthening two kinds of insecticides again and using separately reduces the usage amount of agricultural chemicals, lowers the injury to environment,

Summary of the invention

The insecticides that the purpose of this invention is to provide a kind of brominated cyanogen insect amide and AVM; Can not only enlarge the range of application of these two kinds of insecticides; Under the situation of notable synergistic, the optimum control efficiency of assurance, reduce the usage amount of medicament simultaneously; Reduce a mu usage amount, thereby reduce cost and reduce environmental hazard.

Technical scheme of the present invention:

The insecticides of a kind of brominated cyanogen insect amide and AVM, the weight ratio of said bromine cyanogen insect amide and AVM is: 1: 12~12: 1.

The weight ratio of described bromine cyanogen insect amide and AVM is: 1: 10~10: 1.

The percentage by weight that the weight sum of said bromine cyanogen insect amide and AVM accounts for Pesticidal combination is 0.5%~80%, and surplus is that agricultural goes up acceptable surfactant and solid carrier or liquid diluent.

Described surfactant and solid carrier or liquid diluent comprise: emulsifier, solvent, wetting agent, dispersant, disintegrant, thickener, stabilizing agent, antifreezing agent, antifoaming agent, filler.

Described emulsifier is selected from: the mixture that any one or more in calcium dodecyl benzene sulfonate and aliphatic acid polyethenoxy ether, APES sulfosuccinate, styryl phenol APEO, NPE, castor oil polyoxyethylene ether, aliphatic acid polyethenoxy base ester, the polyoxyethylene aliphatic alcohol ether are formed with arbitrary proportion.

Said solvent is selected from: N, the mixed solvent that any one or more in dinethylformamide, cyclohexanone, 3-methyl cyclohexanol ketenes, N-octylpyrrolidone, N-pyrrolidones, propyl alcohol, butanols, ethylene glycol, diethylene glycol, EGME, butyl ether, ethyl acetate, vegetable oil, acetonitrile, xylol or biodiesel, toluene, diesel oil, methyl alcohol, ethanol, n-butanol, isopropyl alcohol, turpentine oil, solvent naphtha, dimethyl formamide, dimethyl sulfoxide (DMSO), the water equal solvent are formed with arbitrary proportion.

Described wetting agent is selected from: one or more in lauryl sodium sulfate, DBSA, Nekal BX, wetting and penetrating agent F, spaonin powder, silkworm excrement, the soapberry powder.

Described dispersant is selected from: one or more in polycarboxylate, lignosulfonates, APES formaldehyde condensation products sulphate, alkyl benzene sulfonate calcium salt, naphthalene sulfonic acid-formaldehyde condensation product sodium salt, APES, aliphatic amine polyoxyethylene ether, polyoxyethylene carboxylate, the fatty acid glyceride APEO.

Described disintegrant is selected from: one or more in bentonite, urea, ammonium sulfate, aluminium chloride, citric acid, succinic acid, the sodium bicarbonate.

Described thickener is selected from: one or more in xanthans, CMC, hydroxyethylcellulose, methylcellulose, Magnesiumaluminumsilicate, the polyvinyl alcohol.

Described stabilizing agent is selected from: a kind of in sodium citrate, the resorcinol.

Described antifreezing agent is selected from: one or more in ethylene glycol, propane diols, glycerine, the urea.

Described antifoaming agent is selected from: one or more in silicone oil, silicone compound, C10-20 saturated fat acid compounds, the C8-10 aliphatic alcohols compound.

Described filler is selected from: one or more in kaolin, diatomite, bentonite, attapulgite, white carbon, starch, the precipitated calcium carbonate.

Said Pesticidal combination can be prepared as the formulation of suitable agriculture production application such as granule, wetting powder, water dispersible granules, aqueous emulsion, microemulsion, suspending agent, oil-suspending agent, microcapsule suspending agent according to the method for well known to a person skilled in the art.Those of ordinary skill in the art can make the product of the various formulations of the present invention according to the common preparation method of existing agricultural chemicals.

Described Pesticidal combination, formulation are granule, and the gross weight in bromine cyanogen insect amide and AVM wherein contains:

Described Pesticidal combination, formulation are wetting powder, and the gross weight in bromine cyanogen insect amide and AVM wherein contains:

Described Pesticidal combination, formulation are water dispersible granules, and the gross weight in bromine cyanogen insect amide and AVM wherein contains:

Described Pesticidal combination, formulation are aqueous emulsion, and the gross weight in bromine cyanogen insect amide and AVM wherein contains:

Described Pesticidal combination, formulation are microemulsion, and the gross weight in bromine cyanogen insect amide and AVM wherein contains:

Described Pesticidal combination, formulation are suspending agent, and the gross weight in bromine cyanogen insect amide and AVM wherein contains:

Described Pesticidal combination, formulation are oil-suspending agent, and the gross weight in bromine cyanogen insect amide and AVM wherein contains:

Described Pesticidal combination, formulation are microcapsule suspending agent, and the gross weight in bromine cyanogen insect amide and AVM wherein contains:

The present invention is adapted at that various grounds and underground insect comprise the application in Lepidoptera, Homoptera, coleoptera, diptera, the Semiptera in control field crops, fruit tree, vegetables, other special crops and the lawn.Its insecticide-applying way can be for spraying, mix that soil spreads fertilizer over the fields, ditch spread, spread manuer in holes, irritate and insecticide-applying way commonly used in the technical field of pesticide such as execute.

Advantage of the present invention:

1, enlarged the insecticidal spectrum of bromine cyanogen insect amide and AVM, bromine cyanogen insect amide and AVM belong to the pesticide compositional of different insecticidal action mechanism, and be many to the insect action site.

2, the present invention can reduce the application dosage of each bioactivator, thereby has reduced use cost, and can reach the medicament complementation, plays notable synergistic, delays the effect that pest resistance produces.

3, the invention provides the best portfolio ratio of two kinds of insecticides of bromine cyanogen insect amide and AVM; Make it reach the optimum effect of the low preventive effect of usage amount; Reduce the agricultural chemicals use cost in every mu of field of peasant household, reach top gain, and reduced harm when reducing usage amount environment.

Embodiment

For a better understanding of the present invention, specify technology contents of the present invention with instance below, but do not limit the scope of the invention.

Embodiment 1

Bromine cyanogen insect amide: AVM=1: 1 suspending agent

837 gram deionized waters in the suction agitator tank; With 38 gram SOPA270,30 gram K12,5 gram formaldehyde, 55 gram pentanediols [1; 5], in the suction agitator tank; The limit is stirred 10 gram bromine cyanogen insect amides, 10 gram AVMs, 3 gram Sodium Benzoates, 12 gram white carbons, is dropped in order and shear jar then, shears to make mixing of materials even in 30 minutes.Open cycle water, with a certain amount of flow, below temperature control 40 degree, fineness is crossed 325 mesh sieves, promptly gets 2% bromine cyanogen insect amide abamectin insecticide composition suspending agent with the material ball milling.

Embodiment 2

Bromine cyanogen insect amide: AVM=10: 1 microemulsions

Bromine cyanogen insect amide 100 grams, AVM 10 grams, the DMF100 gram, ethanol 50 grams, ethylene glycol 100 grams, calcium dodecyl benzene sulfonate 50 grams, phenethyl phenol polyoxyethylene polyoxypropylene ether 50 grams, APES 80 grams, surplus is a deionized water.Above-mentioned former medicine, solvent, emulsifier are mixed in proportion, make it be dissolved as even oil phase; The mixed water that gets of water-soluble component and deionized water; Under agitation that oil phase is mixed with water, promptly get 11% bromine cyanogen insect amide abamectin insecticide composite microemulsion.

Embodiment 3

Bromine cyanogen insect amide: AVM=15: 3 suspending agents

634 gram deionized waters in the suction agitator tank; With 52 gram NNO, 34 gram lignosulfonates and 10 gram NPE, 3 Ke Kaisong, 75 grams hexylene glycol [2; 5], in the suction agitator tank; The limit is stirred 150 gram bromine cyanogen insect amides, 30 gram AVMs, 2 gram xanthans, 10 gram aluminium-magnesium silicates, is dropped in order and shear jar then, shears to make mixing of materials even in 30 minutes.Open cycle water, with a certain amount of flow, below temperature control 40 degree, fineness is crossed 325 mesh sieves, promptly gets 18% bromine cyanogen insect amide abamectin insecticide insecticides suspending agent with the material ball milling.

Embodiment 4

Bromine cyanogen insect amide: AVM=1: 10 microcapsule suspending agent

With bromine cyanogen insect amide 10 grams, AVM 100 grams are dissolved in the 35 gram xylol, suction tributyl phosphate 3 grams again; CMC 24 grams, sodium alginate 27 grams were sheared 30 minutes in high shear still high speed; Add 200 gram urea resin prepolymer, 2000 rev/mins of stirrings heat up down and solidified 60 minutes, add 608 gram deionized waters afterwards; 45 gram NNO dispersants, 18 gram bentonites, stir get final product 11% bromine cyanogen insect amide abamectin insecticide composition microcapsule suspending agent.

Embodiment 5

Bromine cyanogen insect amide: AVM=7.5: 1.5 aqueous emulsions

With bromine cyanogen insect amide 75 grams, AVM 15 grams, N-methyl adjoin pyrrolidone 50 grams, methyl naphthalene 150 grams, APES 30 grams, and triphen ethyl phenol APEO 45 grams, propane diols 50 grams, surplus is a deionized water.Above-mentioned prescription Central Plains medicine, solvent, emulsifiers dissolve are become even oil phase; The mixed water that gets of water-soluble component and deionized water in will filling a prescription; Under high-speed stirred, oil phase and water are spared the mixed 9% bromine cyanogen insect amide abamectin aqueous emulsion that gets of matter through high shear.

Embodiment 6

Bromine cyanogen insect amide: AVM=0.1: 0.4 granule

AVM 1 gram, bromine cyanogen insect amide 4 grams, polyvinyl alcohol 8 grams; Ethanol 8 grams; Gum Arabic 2 grams stir, and adopt the mode of high-pressure fog evenly to be sprayed onto on the load weighted 977 gram zeolites then; Fully after the stirring and adsorbing, get final product 0.5% bromine cyanogen insect amide abamectin insecticide composition granule.

Embodiment 7

Bromine cyanogen insect amide: AVM=1.6: 0.2 granules

With bromine cyanogen insect amide 16 grams, AVM 2 grams, MF6 gram; Potassium sorbate 15 grams, PVA2 gram, epoxidized vegetable oil 24 grams; Stir; Adopt the mode of high-pressure fog evenly to be sprayed onto on the load weighted 935 gram activation sepiolites then, fully after the stirring and adsorbing, get final product 1.8% bromine cyanogen insect amide abamectin insecticide composition granule.

Embodiment 8

Bromine cyanogen insect amide: AVM=40: 40 wetting powders

With bromine cyanogen insect amide 400 grams, AVM 400 grams, sodium lignin sulfonate 45 grams; Alkyl phenol (or fatty alcohol) polyoxyethylene poly-oxygen propylene aether sulphate 35 grams, 2 hexylene glycol [2,4] 25 grams; White carbon 50 grams, kaolin 45 grams stir; Employing comminution by gas stream processing, get final product 80% bromine cyanogen insect amide abamectin insecticide composite wettable powder.

Embodiment 9

Bromine cyanogen insect amide: AVM=1.5: 4.5 wetting powders

With bromine cyanogen insect amide 15 grams, AVM 45 grams, calcium lignosulfonate 25 grams; Naphthalenesulfonate formaldehyde condensation compound 20 grams, APES phosphoric acid fat and salt 14 grams thereof, white carbon 55 grams; Precipitated calcium carbonate 826 grams; Stir, adopt comminution by gas stream processing, get final product 6% bromine cyanogen insect amide abamectin insecticide composite wettable powder.

Embodiment 10

Bromine cyanogen insect amide: AVM=20: 10 water dispersible granules

With bromine cyanogen insect amide 200 grams, AVM 100 grams, triethanolamine 6 grams, white carbon 165 grams; MF 76 grams, starch 52 grams, kaolin 220 grams, ammonium sulfate 181 grams; Mix laggard comminution by gas stream, in mixer, spray into and mediate about 200 grams of agent deionized water, adjustment extrusion equipment; Carry out extruder grain, it is qualified under 50~80 ℃ of conditions, to dry to moisture, get final product 30% bromine cyanogen insect amide abamectin insecticide composition water dispersible granules.

Embodiment 11

Bromine cyanogen insect amide: AVM=5: 5 oil-suspending agents

With bromine cyanogen insect amide 50 grams, AVM 50 grams, wetting agent APES phosphate 40 grams; Dispersant calcium lignosulfonate 40 grams, emulsifier calcium dodecyl benzene sulfonate 30 grams, thickener sodium cellulose glycolate 20 grams; Stabilizing agent sodium sorbate 90 grams; Antifreezing agent glycerine 20 grams, antifoaming agent organic silicon modified by polyether 2 grams, non-water system dispersion medium vegetable oil is supplied 1000 grams; With above-mentioned prescription add to grind successively in proportion grind in the still after, drop into get final product behind the homogeneous blender mixing 10% bromine cyanogen insect amide abamectin insecticide composition oil-suspending agent.

Experiment embodiment 1

The test of bromine cyanogen insect amide abamectin composition toxicity test

In order further to understand the definite virulence of bromine cyanogen insect amide, AVM and mixture thereof and whether to have certain synergistic effect between the two, the present invention is provided with the different concentration proportioning and tests.

This test is to supply the examination insect with the prodenia litura, and periphery is gathered after indoor feeding to 2 instar larvaes of future generation from the Nanning City, chooses behind the larva of big or small basically identical subsequent use by a weighing and recording at random.

It is 1: 1,2: 1,4: 1,8: 1,12: 1 totally 7 chemicals treatment that bromine cyanogen insect amide, the agent of AVM list and the two weight ratio are set; Each is handled 5 concentration is set, and is contrast with the solvent, with microsyringe the soup point is dropped on the examination worm pronotary; 30 examinations of every processing worm; Repeat 3 times, the examination worm that will handle is then put in the climatic cabinate (28 ℃, 80%) and raises.The dead borer population of inspection record calculates lethality then behind the 24h, calculates each chemicals treatment LD50, correlation coefficient through DPS, calculates co-toxicity coefficient through formula again.

The theoretical toxicity index (TTI) of mixture=∑ (each single agent toxicity index TI * each single agent proportion P)

Can know by table 1; The bromine cyanogen insect amide is high than AVM to the virulence of prodenia litura, and when bromine cyanogen insect amide and AVM proportioning were 1: 1,2: 1,4: 1,8: 1,12: 1, co-toxicity coefficient was all greater than 120; Show significant synergistic effect; And so bromine cyanogen insect amide: AVM all had synergistic function between 1: 1 to 12: 1, and especially with the bromine cyanogen insect amide: AVM=co-toxicity coefficient was maximum in 4: 1 o'clock, and synergy is the most obvious.

Experiment embodiment 2

2% bromine cyanogen insect amide AVM suspending agent is to the control efficiency of balsam pear liriomyza bryoniae

The place: period is investigated in Guangzhou, Guangdong: 6 months: 2010

Table 2 2% bromine cyanogen insect amide AVM suspending agent is to the control efficiency of balsam pear liriomyza bryoniae

Chemicals treatment Usage amount Preventive effect (%) 12% bromine cyanogen insect amide SC 12ml/ mu 80.2 0.6% AVM SC 100ml/ mu 76.6 2% bromine cyanogen insect amide AVM SC 20ml/ mu 86.8 2% bromine cyanogen insect amide AVM SC 25ml/ mu 90.6

Know that by last table 2 result bromine cyanogen insect amide and abamectin compounded actual preventive effect to the balsam pear liriomyza bryoniae be apparently higher than these two kinds of compositions preventive effect of use separately, this shows that the present invention makes up and has obvious synergistic effect.

Experiment embodiment 3

11% bromine cyanogen insect amide AVM suspending agent is to the control efficiency of kidney bean lima bean pod borer

The place: period is investigated in the Haikou: 5 months: 2010

Table 3 11% bromine cyanogen insect amide avermectin micro-emulsion is to the control efficiency of kidney bean lima bean pod borer

Chemicals treatment Usage amount Preventive effect (%) 12% bromine cyanogen insect amide microemulsion 12ml/ mu 82.4 0.5% avermectin micro-emulsion 100ml/ mu 75.8 11% bromine cyanogen insect amide avermectin micro-emulsion 6ml/ mu 89.6 11% bromine cyanogen insect amide avermectin micro-emulsion 8ml/ mu 94.2

Know that by last table 3 result bromine cyanogen insect amide and abamectin compounded actual preventive effect to the kidney bean lima bean pod borer be apparently higher than the preventive effect of its single agent, this shows that the present invention makes up and has obvious synergistic effect.

Experiment embodiment 4

18% bromine cyanogen insect amide avermectin microcapsule suspending agent is to the control efficiency of green onion root maggot

The place: period is investigated in Zhaoqing, Guangdong: 11 months: 2010

Table 4 18% bromine cyanogen insect amide AVM suspending agent is to the control efficiency of green onion root maggot

Chemicals treatment Usage amount Preventive effect (%) 1.8% AVM EC 50ml/ mu 75.8 18% bromine cyanogen insect amide AVM suspending agent 2ml/ mu 82.4 18% bromine cyanogen insect amide AVM suspending agent 4ml/ mu 91.7

This test is adopted and to be watered the mode executed after medicament dilution and irritate mid-term in the green onion growth and execute; Can know by last table result; 18% bromine cyanogen insect amide avermectin microcapsule suspending agent is excellent to the preventive effect of green onion root maggot, and its preventive effect is significantly higher than AVM and uses separately, and visible this combination has obvious synergistic effect.

Experiment embodiment 5

11% bromine cyanogen insect amide avermectin microcapsule suspending agent is to the control efficiency of peanut root-knot nematode

The place: the Guangxi Yulin is investigated period: 9 months: 2009

Table 5 11% bromine cyanogen insect amide avermectin microcapsule suspending agent is to the control efficiency of peanut root-knot nematode

The mode that this test adopts medicament dilution back to execute along ridge irrigation is carried out dispenser; Can know by last table result; 11% bromine cyanogen insect amide avermectin microcapsule suspending agent has excellent control efficiency to peanut root-knot nematode; Its preventive effect is significantly higher than AVM and uses separately, and visible this combination has obvious synergistic effect.

Experiment embodiment 6

11% bromine cyanogen insect amide avermectin microcapsule suspending agent is to the control efficiency of peanut root-knot nematode

The place: period is investigated in Wuzhou, Guangxi: 9 months: 2009

Table 6 11% bromine cyanogen insect amide abamectin aqueous emulsion is to the control efficiency of peanut prodenia litura

Chemicals treatment Usage amount Preventive effect (%) 1.8% AVM EC 75ml/ mu 73.6 11% bromine cyanogen insect amide avermectin microcapsule suspending agent 8ml/ mu 81.5 11% bromine cyanogen insect amide avermectin microcapsule suspending agent 10ml/ mu 89.9

This test adopts the mode of medicament dilution back cauline leaf spraying to carry out dispenser; Can know by last table result; 11% bromine cyanogen insect amide avermectin microcapsule suspending agent has excellent control efficiency to the peanut prodenia litura; Its preventive effect is significantly higher than AVM and uses separately, and visible this combination has obvious synergistic effect.

Experiment embodiment 7

0.5% bromine cyanogen insect amide AVM granule is to the control efficiency of pawpaw root-knot nematode

The place: period is investigated in the Foshan: 4 months: 2010

Table 70.5% bromine cyanogen insect amide AVM granule is to the control efficiency of pawpaw root-knot nematode

Chemicals treatment Usage amount Preventive effect (%) 0.5% AVM GR 2kg/ mu 83.2 0.5% bromine cyanogen insect amide AVM GR 0.5kg/ mu 80.7 0.5% bromine cyanogen insect amide AVM GR 1kg/ mu 89.3 0.5% bromine cyanogen insect amide AVM GR 1.5kg/ mu 94.1

This test is employed in the mode of crop root ditch spread on every side and carries out dispenser; Can know by last table result; 0.5% bromine cyanogen insect amide AVM granule has excellent control efficiency to the pawpaw root-knot nematode, and its preventive effect is significantly higher than AVM and uses separately, and visible this combination has obvious synergistic effect.

Experiment embodiment 8

1.8% bromine cyanogen insect amide AVM granule is to the control efficiency of corn field tiger

The place: Baise of Guangxi is investigated period: 4 months: 2009

Table 8 1.8% bromine cyanogen insect amide AVM granule is to the control efficiency of corn field tiger

Chemicals treatment Usage amount Preventive effect (%) 0.5% AVM GR 3kg/ mu 84.3 1.8% bromine cyanogen insect amide AVM GR 0.75kg/ mu 81.6 1.8% bromine cyanogen insect amide AVM GR 1kg/ mu 91.5 1.8% bromine cyanogen insect amide AVM GR 1.25kg/ mu 95.4

This test is employed in the mode of spreading fertilizer over the fields around the crop root and carries out dispenser; Can know by last table result; 1.8% bromine cyanogen insect amide AVM granule has excellent control efficiency to the corn field tiger, and its preventive effect is significantly higher than AVM and uses separately, and visible this combination has obvious synergistic effect.

Experiment embodiment 9

80% bromine cyanogen insect amide AVM wetting powder is to the control efficiency of sugarcane moth borer

The place: period is investigated in Zhanjiang, Guangdong: 5 months: 2009

Table 9 80% bromine cyanogen insect amide AVM wetting powder is to the control efficiency of sugarcane moth borer

Chemicals treatment Usage amount Preventive effect (%) 16% bromine cyanogen insect amide WP 20g/ mu 82.7 1.8% AVM WP 60g/ mu 81.3 80% bromine cyanogen insect amide AVM WP 2g/ mu 87.3 80% bromine cyanogen insect amide AVM WP 3g/ mu 90.6

Can be known that by last table result 80% bromine cyanogen insect amide AVM wetting powder has excellent control efficiency to sugarcane moth borer, its preventive effect is apparently higher than the preventive effect that these two kinds of compositions use separately, this shows that the present invention makes up and has obvious synergistic effect.

Experiment embodiment 10

30% bromine cyanogen insect amide AVM water dispersible granules is to the control efficiency of paddy rice paddy stem borer

The place: period is investigated in Shaoguan, Guangdong: 10 months: 2010

Table 10 30% bromine cyanogen insect amide AVM water dispersible granules is to the control efficiency of paddy rice paddy stem borer

Chemicals treatment Usage amount Preventive effect (%) 10% AVM WDG 30g/ mu 79.5 16% bromine cyanogen insect amide WDG 20g/ mu 84.8 30% bromine cyanogen insect amide AVM WDG 8g/ mu 88.9 30% bromine cyanogen insect amide AVM WDG 12g/ mu 94.7

Can be known that by last table result 30% bromine cyanogen insect amide AVM water dispersible granules has excellent control efficiency to the paddy rice paddy stem borer, its preventive effect is apparently higher than the preventive effect that these two kinds of compositions use separately, this shows that the present invention makes up and has obvious synergistic effect.

Experiment embodiment 11

10% bromine cyanogen insect amide AVM oil-suspending agent is to the control efficiency of cabbage aphid

The place: period is investigated in Zhuhai, Guangdong: 10 months: 2009

Table 11 10% bromine cyanogen insect amide AVM oil-suspending agent is to the control efficiency of cabbage aphid

Chemicals treatment Usage amount Preventive effect (%) 10% AVM EC 15g/ mu 85.1 16% bromine cyanogen insect amide EC 12g/ mu 80.2 10% bromine cyanogen insect amide AVM oil-suspending agent 10g/ mu 90.9 10% bromine cyanogen insect amide AVM oil-suspending agent 15g/ mu 96.2

Can be known that by last table result 10% bromine cyanogen insect amide AVM oil-suspending agent has excellent control efficiency to cabbage aphid, its preventive effect is apparently higher than the preventive effect that these two kinds of compositions use separately, this shows that the present invention makes up and has obvious synergistic effect.

Claims (7)

1. the insecticides of brominated cyanogen insect amide and AVM, it is characterized in that: the weight ratio of said bromine cyanogen insect amide and AVM is: 1: 12~12: 1.
2. the insecticides of brominated cyanogen insect amide according to claim 1 and AVM is characterized in that: the weight ratio of said bromine cyanogen insect amide and AVM is: 1:10 ~ 10:1.
3. the insecticides of brominated cyanogen insect amide according to claim 1 and 2 and AVM; It is characterized in that: the percentage by weight that the weight sum of said bromine cyanogen insect amide and AVM accounts for Pesticidal combination is 0.5% ~ 80%, and surplus is that agricultural goes up acceptable surfactant and solid carrier or liquid diluent.
4. the insecticides of brominated cyanogen insect amide according to claim 3 and AVM is characterized in that: described surfactant and solid carrier or liquid diluent comprise: emulsifier, solvent, wetting agent, dispersant, disintegrant, thickener, stabilizing agent, antifreezing agent, antifoaming agent, filler.
5. the insecticides of brominated cyanogen insect amide according to claim 1 and 2 and AVM is characterized in that: said Pesticidal combination can be prepared as granule, wetting powder, water dispersible granules, aqueous emulsion, microemulsion, suspending agent, oil-suspending agent and microcapsule suspending agent.
6. the insecticides of brominated cyanogen insect amide according to claim 5 and AVM is characterized in that: its various grounds and underground insect in control field crops, fruit tree, vegetables, other special crops and lawn comprises the application in Lepidoptera, Homoptera, coleoptera, diptera, the Semiptera.
7. the insecticides of brominated cyanogen insect amide according to claim 5 and AVM is characterized in that: its insecticide-applying way for spraying, mix that soil spreads fertilizer over the fields, ditch spread, spread manuer in holes, irritate and execute.
CN2011104293188A 2011-12-20 2011-12-20 Pesticide composition containing cyantraniliprole and abamectin CN102396475A (en)

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CN104186504A (en) * 2014-09-25 2014-12-10 江苏省绿盾植保农药实验有限公司 Insecticidal composition containing emamectin benzoate and cyantraniliprole and application thereof
CN104542641A (en) * 2014-12-19 2015-04-29 唐睿 Hot fogging concentrate containing abamectin and cyantraniliprole and preparation method of hot fogging concentrate
CN104642348A (en) * 2015-03-13 2015-05-27 河北博嘉农业有限公司 Insecticide bactericidal composition containing thifluzamide
CN105994310A (en) * 2016-06-21 2016-10-12 南京华洲药业有限公司 Composite insecticide composition containing cyantraniliprole and avermectin and application thereof
WO2017189797A1 (en) * 2016-04-27 2017-11-02 Valent Biosciences Llc Synergistic bacillus thuringiensis, subsp. kurstaki and cyantraniliprole mixtures for diamondback moth, beet armyworm, sugarcane borer, and soybean looper control
CN107439557A (en) * 2017-09-20 2017-12-08 陕西嘉益蓝德生物工程有限公司 A kind of bromine cyanogen insect amide granule and application thereof
CN107549178A (en) * 2017-08-15 2018-01-09 浙江海正化工股份有限公司 Pesticidal combination and its preparation method and application
WO2018055022A1 (en) * 2016-09-22 2018-03-29 Syngenta Participations Ag Pesticidal mixtures

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Cited By (14)

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CN103283734B (en) * 2012-02-23 2016-08-03 陕西韦尔奇作物保护有限公司 A kind of brominated cyanogen insect amide and the Pesticidal combination of biogenic substances
CN103283734A (en) * 2012-02-23 2013-09-11 陕西韦尔奇作物保护有限公司 Cyantraniliprole/biological-source-containing pesticidal composition
CN102939970A (en) * 2012-10-18 2013-02-27 上海沪联生物药业(夏邑)股份有限公司 Microcapsule suspending agent containing spinosad and cyantraniliprole, and preparation method thereof
CN104186504A (en) * 2014-09-25 2014-12-10 江苏省绿盾植保农药实验有限公司 Insecticidal composition containing emamectin benzoate and cyantraniliprole and application thereof
CN104542641A (en) * 2014-12-19 2015-04-29 唐睿 Hot fogging concentrate containing abamectin and cyantraniliprole and preparation method of hot fogging concentrate
CN104542641B (en) * 2014-12-19 2016-03-16 唐睿 A kind of thermal fog containing Avermectin and bromine cyanogen insect amide and preparation method thereof
CN104642348A (en) * 2015-03-13 2015-05-27 河北博嘉农业有限公司 Insecticide bactericidal composition containing thifluzamide
CN104642348B (en) * 2015-03-13 2016-10-19 河北博嘉农业有限公司 A kind of insecticidal and bactericidal composition containing thifluzamide
US10278396B2 (en) 2016-04-27 2019-05-07 Valent Biosciences Llc Synergistic Bacillus thuringiensis subsp. kurstaki and cyantraniliprole mixtures for diamondback moth, beet armyworm, sugarcane borer, and soybean looper control
WO2017189797A1 (en) * 2016-04-27 2017-11-02 Valent Biosciences Llc Synergistic bacillus thuringiensis, subsp. kurstaki and cyantraniliprole mixtures for diamondback moth, beet armyworm, sugarcane borer, and soybean looper control
CN105994310A (en) * 2016-06-21 2016-10-12 南京华洲药业有限公司 Composite insecticide composition containing cyantraniliprole and avermectin and application thereof
WO2018055022A1 (en) * 2016-09-22 2018-03-29 Syngenta Participations Ag Pesticidal mixtures
CN107549178A (en) * 2017-08-15 2018-01-09 浙江海正化工股份有限公司 Pesticidal combination and its preparation method and application
CN107439557A (en) * 2017-09-20 2017-12-08 陕西嘉益蓝德生物工程有限公司 A kind of bromine cyanogen insect amide granule and application thereof

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