CN106035352A - Lepimectin and cyantraniliprole contained compound insecticidal composition and use thereof - Google Patents
Lepimectin and cyantraniliprole contained compound insecticidal composition and use thereof Download PDFInfo
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- CN106035352A CN106035352A CN201610451338.8A CN201610451338A CN106035352A CN 106035352 A CN106035352 A CN 106035352A CN 201610451338 A CN201610451338 A CN 201610451338A CN 106035352 A CN106035352 A CN 106035352A
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- China
- Prior art keywords
- lepimectin
- cyanogen insect
- bromine cyanogen
- insect amide
- pesticide compositions
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
Abstract
The invention discloses a Lepimectin and cyantraniliprole containing compound insecticidal composition and use thereof. The insecticidal composition employs Lepimectin and cyantraniliprole as insecticidal active ingredients, wherein the weight ratio of the Lepimectin to the cyantraniliprole is (0.1 to 80) to (0.5 to 80). The insecticidal composition can generate a relatively high synergistic effect, the pesticide resistance of insect pests is overcome and retarded, the insecticidal speed is high, and the effect duration is long, so that the pesticide use cost is reduced, and the control efficiency is apparently higher than that of a single agent. The insecticidal composition can be used for preventing and treating Lepidoptera pests on crops and particularly can be used to prevent and treat Helicoverpa armigera and snout moth's larva, and the control efficiency is apparently higher than that of the single agent.
Description
Technical field
The invention belongs to the field of agricultural pesticide containing heterocyclic compound, concrete body relates to a kind of composite insecticidal combination
Thing.
Background technology
Lepimectin, is by the derivant of Japan three mibemycin (milbemycin) A3/A4 that company finds altogether,
Used in Japan's registration in 2006.As novel pesticide for vegetable and water such as Caulis et Folium Brassicae capitatae, Fructus Lycopersici esculenti, Citrus, Fructus Fragariae Ananssae and Fructus Vitis viniferaes
Really, the main preventing and treating insect such as Lepidoptera and Semiptera.This medical instrument has insecticidal activity high, and dosage is few, to person poultry safety, does not pollutes
Environment, specificity is strong, does not injure natural enemy, is not easy to produce the features such as resistance, can use with avermectins rotation, with
Anti-avilamycin produces resistance.Therefore it is referred to as the most promising wide spectrum, the insecticide of no interactions resistance efficient, novel at present
One of.Its mechanism of action is the permeability that can increase polypide nerve synapse caudacoria to C1-, thus the transmission of block nerves signal,
Insecticide neural paralysis is finally made to cause insect death.
Bromine cyanogen insect amide (cyantraniliprole), is E.I.Du Pont Company's second filial generation that success is developed after chlorantraniliprole
Ryanodine receptor inhibitor insecticides, cyanogen insect amide is to be formed by the various polar groups on change phenyl ring, has higher
Effect, applicable crops is more extensive, can effectively prevent and treat Lepidoptera, Semiptera and coleopteran pest.
Insecticide variety containing single component often existing defects in pesticide Pest control: use continuously easily produce anti-
The property of medicine, insecticidal spectrum is narrow, it is impossible to providing comprehensively protection for crop, peasant's drug cost is high.
Summary of the invention
It is an object of the invention to provide a kind of containing Lepimectin with the compound pesticide compositions of bromine cyanogen insect amide, this parasite killing
Compositions is the multifunctional insecticide compositions of preventing and treating lepidoptera pest.
It is a further object of the present invention to provide this Pesticidal combination and prevent and treat the insecticidal materials of resistance lepidoptera pest in preparation
On application, particularly preparation preventing and treating bollworm or snout moths larva insecticidal materials on application.
It is an object of the invention to be achieved through the following technical solutions:
A kind of containing Lepimectin with the compound pesticide compositions of bromine cyanogen insect amide, this compound pesticide compositions with
Lepimectin and bromine cyanogen insect amide are principle active component, and wherein, the weight ratio of Lepimectin and bromine cyanogen insect amide is 0.1
～80:0.5～80.
In this compound pesticide compositions, the weight ratio of Lepimectin (A) and Profenofos (B) is preferably 1～60:1～60,
More preferably 1～40:1～40, most preferably 1～30:1～30.
In some preferred technical schemes: Lepimectin and Profenofos can 1:30,1:29,1:28,1:27,1:
26、1:25、1:24、1:24、1:22、1:21、1:20、1:19、1:18、1:17、1:16、1:15、1:14、1:13、1:12、1:
11、1:10、1:9、1:8、1:7、1:6、1:5、1:4、1:3、1:2、1:1、2:1、3:1、4:1、5:1、6:1、7:1、8:1、9:1、
10:1、11:1、12:1、13:1、14:1、15:1、16:1、17:1、18:1、19:1、20:1、21:1、22:1、23:1、24:1、
25:1、26:1、27:1、28:1、29:1、30:1、2:3、3:2、2:5、5:2、3:4、4:3、5:2、2:5、5:3、3:5、5:4、4:5
These ratios select.
This compound pesticide compositions can comprise only active component Lepimectin and bromine cyanogen insect amide, it is possible to is using or is joining
Adding other components time processed in active component, the active ingredient in this Pesticidal combination can be present in group with enhancing effective amount
In compound.
In this compound pesticide compositions, the weight ratio of Lepimectin (A) and bromine cyanogen insect amide (B) is preferably 1～60:1
～60, more preferably 1～40:1～40, most preferably 1～30:1～30.
In some preferred technical schemes: Lepimectin and bromine cyanogen insect amide can 1:30,1:29,1:28,1:
27、1:26、1:25、1:24、1:24、1:22、1:21、1:20、1:19、1:18、1:17、1:16、1:15、1:14、1:13、1:
12、1:11、1:10、1:9、1:8、1:7、1:6、1:5、1:4、1:3、1:2、1:1、2:1、3:1、4:1、5:1、6:1、7:1、8:1、
9:1、10:1、11:1、12:1、13:1、14:1、15:1、16:1、17:1、18:1、19:1、20:1、21:1、22:1、23:1、24:
1、25:1、26:1、27:1、28:1、29:1、30:1、2:3、3:2、2:5、5:2、3:4、4:3、5:2、2:5、5:3、3:5、5:4、
These ratios of 4:5 select.
Compound pesticide compositions of the present invention with Lepimectin and bromine cyanogen insect amide as active component or principle active component,
Become with insecticides adjuvant and excipient on pesticide allow any one dosage form, the preferred cream of described dosage form, suspending agent, can
WP, aqueous emulsion, microemulsion or water dispersion granule.
The insecticides adjuvant of the aforementioned present invention of can be applicable to is not particularly limited, and includes, but are not limited to detergent alkylate
Sulfoacid calcium, 600#, polyoxyethylene polyoxy propylene block compound are (such as agriculture breast 33#), NPE etc., aforementioned should
Excipient for the present invention is also not particularly limited, include, but are not limited to solvent naphtha, water, antifreezing agent (such as propylene glycol),
Deionized water etc..Above auxiliary agent, excipient and other adjuvant can be alone or and use.
Compound pesticide compositions of the present invention easily produces multiple Semiptera and the Lepidoptera of resistance to planthopper and snout moths larva etc.
Insect has good preventive effect；And suppress the insect drug resistance to unitary agent (Lepimectin or bromine cyanogen insect amide are arbitrary)
Property produce.
Above-mentioned compound pesticide compositions prevents and treats the application on resistance lepidoptera pest insecticidal materials in preparation, especially in system
Application effect on standby preventing and treating bollworm or snout moths larva insecticidal materials is notable.
Compared with prior art beneficial effects of the present invention: (1) compared with single dose, said composition antagonism lepidoptera pest
As bollworm, snout moths larva etc. have obvious synergistic function, overcoming and delayed pest resistance to insecticide, expanding prevention is composed, parasite killing speed
Hurry up, hence it is evident that improve prevention effect；(2) preventing and treating recruitment, drug cost are reduced；(3) alternative high-toxic pesticide；(4) have concurrently quick-acting
With long-acting；(5) with Lepimectin compared with bromine cyanogen insect amide single dose, produce and use cost reduces；(6) suppression Lepidoptera evil
The resistance of pesticide is strengthened by worm, and its effect uses apparently higher than its single dose.
Detailed description of the invention
Below in conjunction with embodiment, the invention will be further described, but limits the present invention never in any form.
Embodiment 1:
Weigh 80gLepimectin, 2g bromine cyanogen insect amide, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether
3g, dimethylbenzene put into mixing in mixing kettle to 100g, the method that above raw material is prepared cream routinely, are formed and the most effectively become
The Lepimectin bromine cyanogen insect amide cream dividing weight percentage to be 82%.
Embodiment 2:
Weigh 2gLepimectin, 80g bromine cyanogen insect amide, lignin 10g, Negel 2g, add to Kaolin
100g, mixes above raw material in super micron mill, and forming principle active component weight percentage is 82%
Lepimectin bromine cyanogen insect amide wettable powder.
Embodiment 3:
Weigh 60gLepimectin, 2g bromine cyanogen insect amide, calcium dodecyl benzene sulfonate 8g, phenethyl phenol polyethenoxy ether
6g, dimethylbenzene add to 100g, and the method that above raw material is prepared cream routinely puts into mixing in mixing kettle, are formed main effective
Ingredients Weight percentage composition is the Lepimectin bromine cyanogen insect amide cream of 62%.
Embodiment 4:
Weigh 2gLepimectin, 60g bromine cyanogen insect amide, nonyl phenol phosphate 5g, alkylphenol polyoxyethylene 4g, positive fourth
The dimethylbenzene of alcohol 3g, 10g and the ketopyrrolidine of 10g, the xanthan gum of 0.1g, remaining supplies 100g, n-butyl alcohol and water dissolution with water
Forming aqueous phase, remaining component mix and blend forms oil phase, slowly aqueous phase is added in oil phase, and continue under cutter effect
Shear 10～30 minutes, form the Lepimectin bromine cyanogen insect amide water and milk that principle active component weight percentage is 62%
Agent.
Embodiment 5:
Weigh 40gLepimectin, 2g bromine cyanogen insect amide, calcium dodecyl benzene sulfonate 5g, alkylphenol polyoxyethylene 4g,
The solvent xylene of 30g and the ketopyrrolidine of 15g, remaining complements to 100g, the mixing of former medicine, solvent, emulsifying agent, cosolvent with water
Stirring forms homogeneous phase transparent solution, is then slowly added into water and stirs formation clear solution, being principle active component weight hundred
The Lepimectin bromine cyanogen insect amide microemulsion dividing content to be 42%.
Embodiment 6:
Weigh 2gLepimectin, 40g bromine cyanogen insect amide, calcium dodecyl benzene sulfonate 5g, phenethyl phenol polyethenoxy ether
3g, dimethylbenzene are to 100g.The method that above raw material is prepared cream routinely puts into mixing in mixing kettle, is formed and the most effectively becomes
The Lepimectin bromine cyanogen insect amide cream dividing weight percentage to be 42%.
Embodiment 7:
Weigh 20gLepimectin, 2g bromine cyanogen insect amide, sodium lignin sulfonate 3g, polyoxyethylene poly-oxygen propylene aether and
Sulfate 4g, xanthan gum 0.2g, ethylene glycol 10g, silica ethane 0.1g, aluminium-magnesium silicate 0.5g, supply 100g with water, at sand mill
Effect lower form the Lepimectin bromine cyanogen insect amide suspending agent that principle active component weight percentage is 22%.
Embodiment 8:
Weigh 2gLepimectin, 20g bromine cyanogen insect amide, alkylphenol polyoxyethylene 14g, phenethyl phenol polyethenoxy ether
15g, dimethylbenzene put into mixing in mixing kettle to 100g, the method that above raw material is prepared cream routinely, are formed main effective
Ingredients Weight percentage composition is the Lepimectin bromine cyanogen insect amide cream of 22%.
Embodiment 9:
Weigh 10gLepimectin, 2g bromine cyanogen insect amide, sodium lignin sulfonate 8g, sodium lauryl sulphate 2g, ammonium sulfate
5g, polyvinyl alcohol 5g, Borax 2g, Kaolin 28g, the method that above raw material is pressed water dispersion granule forms principle active component
Weight percentage is the Lepimectin bromine cyanogen insect amide water dispersible granules of 12%.
Embodiment 10:
Weigh 10gLepimectin, 5g bromine cyanogen insect amide, alkylphenol polyoxyethylene 14g, phenethyl phenol polyethenoxy ether
15g, dimethylbenzene put into mixing in mixing kettle to 100g, the method that above raw material is prepared cream routinely, are formed main effective
Ingredients Weight percentage composition is the Lepimectin bromine cyanogen insect amide cream of 15%.
Embodiment 11:
Weigh 10gLepimectin, 10g bromine cyanogen insect amide, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether
3g, dimethylbenzene put into mixing in mixing kettle to 100g, the method that above raw material is prepared cream routinely, are formed and the most effectively become
The Lepimectin bromine cyanogen insect amide cream dividing weight percentage to be 20%.
Drug effect checking test
1, indoor virulence determination of activity
Weigh Lepimectin and bromine cyanogen insect amide 30g, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether altogether
4g, vegetable oil are to 100g.The method that above raw material is prepared cream routinely puts into mixing in mixing kettle, is configured to main effective
Ingredients Weight percentage composition is the Lepimectin bromine cyanogen insect amide cream of 30%.Wherein Lepimectin and bromine cyanogen insect amide
Concrete ratio be shown in Table 1 and 2.
Using feedstuff to add poison method and carry out indoor potentiation bioassay, selection resistant bollworm is target pest, often processes weight
Multiple 3 times, every concentration processes 60, with probability value method calculate each medicament antagonism bollworm toxicity regression equation and lethal in dense
Degree LC50, use LC50Value press Sun Yun abundant method calculating co-toxicity coefficient, the results are shown in Table 1:
Table 1 Lepimectin, bromine cyanogen insect amide and the toxicity test of compounding sample antagonism bollworm thereof and co-toxicity coefficient
In table, data show, after Lepimectin and bromine cyanogen insect amide mixture, antagonism bollworm are had potentiation,
Proportioning co-toxicity coefficient listed in table is both greater than 120, and therefore Lepimectin and bromine cyanogen insect amide mixture have significant potentiation
Effect.
Weigh Lepimectin, bromine cyanogen insect amide uses conventional formulation method to be configured to principle active component by different proportion
Weight percentage is the Lepimectin bromine cyanogen insect amide cream of 30%.Concrete ratio is shown in Table 2.
Using feedstuff to add poison method and carry out indoor potentiation bioassay, selection rice-stem borer is target pest, often processes weight
Multiple 3 times, calculate toxicity regression equation and lethal concentration of 50 LC of each medicament antagonism striped rice borer by probability value method50, use LC50Value
Calculate co-toxicity coefficient by the abundant method of Sun Yun, the results are shown in Table 2:
Table 2 Lepimectin, bromine cyanogen insect amide and compounding sample thereof to striped rice borer toxicity test and co-toxicity coefficient
In table, data show, have potentiation, table after Lepimectin and bromine cyanogen insect amide mixture to rice-stem borer
Proportioning co-toxicity coefficient listed by is all much larger than 120, and therefore Lepimectin and bromine cyanogen insect amide mixture have significant potentiation
Effect.
2, field control effectiveness test
Using embodiment institute sample product to carry out the field test of control in field bollworm, comparison medicament is 20% bromine cyanogen worm acyl
Amine EC and 10%LepimectinEC (cream), is diluted according to the extension rate in form 3, looks into 3 days after medicine, 7 days, 14 days
Result, result is shown in Table 3:
Table 3 Lepimectin-bromine cyanogen insect amide compounds the field test results of antagonism bollworm
Example has fabulous quick-acting to antagonism bollworm as can be seen from Table 3, and the lasting period is long, in field
Performance is good, is the outstanding medicament preventing and treating antagonism bollworm.
Measure through indoor synergism test and show: by Lepimectin with bromine cyanogen insect amide built agent to bollworm and Oryza sativa L. two
Change snout moth's larva and have significant synergistic insecticidal action；Field control effectiveness test also indicates that all of built agent of the present invention is to bollworm parasite killing equally
Effect is all remarkably higher than the effect of corresponding single dose pesticide.
Claims (10)
1. containing Lepimectin and a compound pesticide compositions for bromine cyanogen insect amide, it is characterized in that this compound pesticide compositions with
Lepimectin and bromine cyanogen insect amide are active insecticidal components, and wherein, the weight ratio of Lepimectin and bromine cyanogen insect amide is 0.1
～80:0.5～80.
The most according to claim 1 containing Lepimectin with the compound pesticide compositions of bromine cyanogen insect amide, it is characterized in that institute
The Lepimectin stated and the weight ratio of bromine cyanogen insect amide are 1～60:1～60.
The most according to claim 2 containing Lepimectin with the compound pesticide compositions of bromine cyanogen insect amide, it is characterized in that institute
The Lepimectin stated and the weight ratio of bromine cyanogen insect amide are 1～40:1～40.
The most according to claim 3 containing Lepimectin with the compound pesticide compositions of bromine cyanogen insect amide, it is characterized in that institute
The Lepimectin stated and the weight ratio of bromine cyanogen insect amide are 1～30:1～30.
The most according to claim 1 containing Lepimectin with the compound pesticide compositions of bromine cyanogen insect amide, it is characterized in that
Lepimectin and both bromine cyanogen insect amides weight percentage in this compound pesticide compositions are 3%～80%.
The most according to claim 5 containing Lepimectin with the compound pesticide compositions of bromine cyanogen insect amide, it is characterized in that
Lepimectin and both bromine cyanogen insect amides weight percentage in this compound pesticide compositions are 5%～55%.
The most according to claim 1 containing Lepimectin with the compound pesticide compositions of bromine cyanogen insect amide, it is characterized in that this
With Lepimectin, as active insecticidal components and insecticides adjuvant is configured on pesticide to permit compound pesticide compositions with bromine cyanogen insect amide
The dosage form permitted.
The most according to claim 7 containing Lepimectin with the compound pesticide compositions of bromine cyanogen insect amide, it is characterized in that institute
Stating dosage form is cream, suspending agent, aqueous emulsion, wettable powder, microemulsion or water dispersion granule.
9. the compound pesticide compositions containing Lepimectin and bromine cyanogen insect amide described in claim 1 prevents and treats resistance squama in preparation
Application on the insecticidal materials of wing mesh insect.
Compound pesticide compositions containing Lepimectin and bromine cyanogen insect amide the most according to claim 9 is in preparation preventing and treating
Application on the insecticidal materials of bollworm or snout moths larva.
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| CN201610451338.8A CN106035352A (en) | 2016-06-21 | 2016-06-21 | Lepimectin and cyantraniliprole contained compound insecticidal composition and use thereof |
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| CN201610451338.8A CN106035352A (en) | 2016-06-21 | 2016-06-21 | Lepimectin and cyantraniliprole contained compound insecticidal composition and use thereof |
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Citations (3)
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| US20100130366A1 (en) * | 2007-04-17 | 2010-05-27 | Bayer Cropscience Ag | Method for better utilising the production of potential transgenic plants |
| CN103283734A (en) * | 2012-02-23 | 2013-09-11 | 陕西韦尔奇作物保护有限公司 | Cyantraniliprole/biological-source-containing pesticidal composition |
| CN104304276A (en) * | 2014-09-25 | 2015-01-28 | 江苏省绿盾植保农药实验有限公司 | Insecticidal composition containing avermectin and cyantraniliprole and application thereof |
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2016
- 2016-06-21 CN CN201610451338.8A patent/CN106035352A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20100130366A1 (en) * | 2007-04-17 | 2010-05-27 | Bayer Cropscience Ag | Method for better utilising the production of potential transgenic plants |
| CN103283734A (en) * | 2012-02-23 | 2013-09-11 | 陕西韦尔奇作物保护有限公司 | Cyantraniliprole/biological-source-containing pesticidal composition |
| CN104304276A (en) * | 2014-09-25 | 2015-01-28 | 江苏省绿盾植保农药实验有限公司 | Insecticidal composition containing avermectin and cyantraniliprole and application thereof |
Non-Patent Citations (1)
| Title |
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| 胡萍 等: "生物杀虫剂—Lepimectin", 《世界农药》 * |
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Application publication date: 20161026 |