CN105994328A - Composite insecticide composition containing cyantraniliprole and metaflumizone and application thereof - Google Patents

Composite insecticide composition containing cyantraniliprole and metaflumizone and application thereof Download PDF

Info

Publication number
CN105994328A
CN105994328A CN201610450163.9A CN201610450163A CN105994328A CN 105994328 A CN105994328 A CN 105994328A CN 201610450163 A CN201610450163 A CN 201610450163A CN 105994328 A CN105994328 A CN 105994328A
Authority
CN
China
Prior art keywords
metaflumizone
insect amide
cyanogen insect
pesticide compositions
compound pesticide
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610450163.9A
Other languages
Chinese (zh)
Inventor
石振龙
陈叶青
杨琴
万维肖
高瑞花
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nanjing Huazhou Pharmaceutical Co Ltd
Original Assignee
Nanjing Huazhou Pharmaceutical Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nanjing Huazhou Pharmaceutical Co Ltd filed Critical Nanjing Huazhou Pharmaceutical Co Ltd
Priority to CN201610450163.9A priority Critical patent/CN105994328A/en
Publication of CN105994328A publication Critical patent/CN105994328A/en
Pending legal-status Critical Current

Links

Classifications

    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
    • A01N47/34—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the groups, e.g. biuret; Thio analogues thereof; Urea-aldehyde condensation products
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The invention discloses a composite insecticide composition containing cyantraniliprole and metaflumizone and the application thereof. The insecticidal active constituents of the insecticide composition are cyantraniliprole and metaflumizone, and the weight ratio of cyantraniliprole to metaflumizone is (0.1-80):(0.5-80). The insecticide composition can generate a good synergistic interaction effect, overcomes and delays pest resistance to insecticides, has a high insecticide speed and long lasting period, reduces pesticide cost and has a control effect obviously better than that of single application of cyantraniliprole or metaflumizone. The insecticide composition can control lepidoptera pests on crops, especially cotton bollworms and stem borers, and the effect is obviously better than that of single application of cyantraniliprole or metaflumizone.

Description

A kind of compound pesticide compositions of brominated cyanogen insect amide and metaflumizone and application thereof
Technical field
The invention belongs to the field of agricultural pesticide containing heterocyclic compound, concrete body relates to a kind of compound pesticide compositions.
Background technology
Bromine cyanogen insect amide (cyantraniliprole), it it is E.I.Du Pont Company's second filial generation ryanodine receptor inhibitor insecticides that success is developed after chlorantraniliprole, cyanogen insect amide is to be formed by the various polar groups on change phenyl ring, have more efficient, applicable crops is more extensive, can effectively prevent and treat Lepidoptera, Semiptera and coleopteran pest.
Metaflumizone (metaflumizone), have another name called Chinese mugwort and kill spy, chemical name: (E+Z)-[2-(4-cyano group benzene)-1-[3-(trifluoromethyl) benzene] ethylidene]-N-[4-(trifluoromethyl) benzene]-hydrazine carbonyl oxamides, structural formula is:
Metaflumizone (metaflumizone, BAS320I) it is BASF Aktiengesellschaft and a kind of brand-new compound of pesticide company of Japan joint development, belong to semicarbazones insecticides, the mechanism of action of metaflumizone is unique, itself has insecticidal activity, need not bioactivation, with existing each insecticides no interactions resistance.Metaflumizone can prevent and treat various places lepidoptera pest and the larva of some coleoptera, adult effectively.
Insecticide variety containing single component often existing defects in pesticide Pest control: use is easily developed immunity to drugs continuously, and insecticidal spectrum is narrow, it is impossible to providing comprehensively protection for crop, peasant's drug cost is high.Combination by two kinds or two or more active component to a certain extent can customer service disadvantages mentioned above.There is two kinds of potentiation or the combination mixture of two or more active component, can improve preventive effect, reduce effective ingredient ground dosage, cost-effective, slow down pest resistance occur and can expanding prevention spectrum, play that many worms are double to be controlled, reduce the use cost of peasant.
Summary of the invention
It is an object of the invention to provide a kind of brominated cyanogen insect amide and the compound pesticide compositions of metaflumizone, this Pesticidal combination is the multifunctional insecticide compositions of preventing and treating lepidoptera pest.
It is a further object of the present invention to provide this Pesticidal combination and prevent and treat the application on the insecticidal materials of resistance lepidoptera pest, the particularly application on the insecticidal materials of preparation preventing and treating bollworm or snout moths larva in preparation.
It is an object of the invention to be achieved through the following technical solutions:
A kind of brominated cyanogen insect amide and the compound pesticide compositions of metaflumizone, this compound pesticide compositions is with bromine cyanogen insect amide and metaflumizone as principle active component, and wherein, the weight ratio of bromine cyanogen insect amide and metaflumizone is 0.1～80:0.5～80.
In this compound pesticide compositions, the weight ratio of bromine cyanogen insect amide (A) and metaflumizone (B) is preferably 1～60:1～60, and more preferably 1～40:1～40, most preferably 1～30:1～30.nullIn some preferred technical schemes: bromine cyanogen insect amide and metaflumizone can be at 1:30、1:29、1:28、1:27、1:26、1:25、1:24、1:24、1:22、1:21、1:20、1:19、1:18、1:17、1:16、1:15、1:14、1:13、1:12、1:11、1:10、1:9、1:8、1:7、1:6、1:5、1:4、1:3、1:2、1:1、2:1、3:1、4:1、5:1、6:1、7:1、8:1、9:1、10:1、11:1、12:1、13:1、14:1、15:1、16:1、17:1、18:1、19:1、20:1、21:1、22:1、23:1、24:1、25:1、26:1、27:1、28:1、29:1、30:1、2:3、3:2、2:5、5:2、3:4、4:3、5:2、2:5、5:3、3:5、5:4、These ratios of 4:5 select.
But this compound pesticide compositions of this compound pesticide compositions can comprise only active component bromine cyanogen insect amide and metaflumizone, also can add other components in active component when using or prepare, the active ingredient in this Pesticidal combination can be present in compositions with enhancing effective amount.
In compound pesticide compositions of the present invention, bromine cyanogen insect amide and both metaflumizones weight percentage in this compound pesticide compositions are 3%～80%.It is preferably 5%～55%, most preferably 10%～40%.
Compound pesticide compositions of the present invention is with bromine cyanogen insect amide and metaflumizone as active component or principle active component, any one dosage form allowed on pesticide, the preferred cream of described dosage form, suspending agent, wettable powder, aqueous emulsion, microemulsion or water dispersion granule is become with insecticides adjuvant and excipient.
The insecticides adjuvant of the aforementioned present invention of can be applicable to is not particularly limited, and includes, but are not limited to calcium dodecyl benzene sulfonate, 600#, polyoxyethylene polyoxy propylene block compound (such as agriculture breast 33#), NPE etc., the excipient of the aforementioned present invention of can be applicable to also is not particularly limited, and includes, but are not limited to solvent naphtha, water, antifreezing agent (such as propylene glycol), deionized water etc..Above auxiliary agent, excipient and other adjuvant can be alone or and use.
Compound pesticide compositions of the present invention has good preventive effect to multiple Semiptera and the lepidoptera pest of the easily generation resistance such as planthopper and snout moths larva；And suppress insect that the Drug resistance of unitary agent (bromine cyanogen insect amide or metaflumizone are arbitrary) is produced.
It is notable that above-mentioned compound pesticide compositions prevents and treats the application on resistance lepidoptera pest insecticidal materials, especially the application effect on preparation preventing and treating bollworm or snout moths larva insecticidal materials in preparation.
Compared with prior art beneficial effects of the present invention: (1) is compared with single dose, said composition antagonism lepidoptera pest such as bollworm, snout moths larva etc. have obvious synergistic function, overcome and delayed pest resistance to insecticide, and expanding prevention is composed, parasite killing speed is fast, hence it is evident that improve prevention effect；(2) preventing and treating recruitment, drug cost are reduced；(3) alternative high-toxic pesticide；(4) have concurrently quick-acting and long-acting；(5) with bromine cyanogen insect amide compared with metaflumizone single dose, produce and use cost reduces；(6) resistance of pesticide is strengthened by suppression lepidoptera pest, and its effect uses apparently higher than its single dose.
Detailed description of the invention
Below in conjunction with embodiment, the invention will be further described, but limits the present invention never in any form.
Embodiment 1:
Weigh 80g bromine cyanogen insect amide, 2g metaflumizone, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 3g, dimethylbenzene to 100g, the method that above raw material is prepared cream routinely puts into mixing in mixing kettle, forms the bromine cyanogen insect amide metaflumizone cream that principle active component weight percentage is 82%.
Embodiment 2:
Weigh 2g bromine cyanogen insect amide, 80g metaflumizone, lignin 10g, Negel 2g, add to 100g with Kaolin, above raw material is mixed in super micron mill, forms the bromine cyanogen insect amide metaflumizone wettable powder that principle active component weight percentage is 82%.
Embodiment 3:
Weigh 60g bromine cyanogen insect amide, 2g metaflumizone, calcium dodecyl benzene sulfonate 8g, phenethyl phenol polyethenoxy ether 6g, dimethylbenzene add to 100g, the method that above raw material is prepared cream routinely puts into mixing in mixing kettle, forms the bromine cyanogen insect amide metaflumizone cream that principle active component weight percentage is 62%.
Embodiment 4:
Weigh 2g bromine cyanogen insect amide, 60g metaflumizone, nonyl phenol phosphate 5g, alkylphenol polyoxyethylene 4g, the dimethylbenzene of n-butyl alcohol 3g, 10g and the ketopyrrolidine of 10g, the xanthan gum of 0.1g, remaining supplies 100g with water, n-butyl alcohol and water dissolution form aqueous phase, and remaining component mix and blend forms oil phase, slowly aqueous phase are added in oil phase under cutter effect, and continue to shear 10～30 minutes, form the bromine cyanogen insect amide metaflumizone aqueous emulsion that principle active component weight percentage is 62%.
Embodiment 5:
Weigh 40g bromine cyanogen insect amide, 2g metaflumizone, calcium dodecyl benzene sulfonate 5g, alkylphenol polyoxyethylene 4g, the solvent xylene of 30g and the ketopyrrolidine of 15g, remaining complements to 100g with water, former medicine, solvent, emulsifying agent, cosolvent mix and blend form homogeneous phase transparent solution, then it is slowly added into water and stirs formation clear solution, being the bromine cyanogen insect amide metaflumizone microemulsion that principle active component weight percentage is 42%.
Embodiment 6:
Weigh 2g bromine cyanogen insect amide, 40g metaflumizone, calcium dodecyl benzene sulfonate 5g, phenethyl phenol polyethenoxy ether 3g, dimethylbenzene to 100g.The method that above raw material is prepared cream routinely puts into mixing in mixing kettle, forms the bromine cyanogen insect amide metaflumizone cream that principle active component weight percentage is 42%.
Embodiment 7:
Weigh 20g bromine cyanogen insect amide, 2g metaflumizone, sodium lignin sulfonate 3g, polyoxyethylene poly-oxygen propylene aether and sulfate 4g thereof, xanthan gum 0.2g, ethylene glycol 10g, silica ethane 0.1g, aluminium-magnesium silicate 0.5g, supplies 100g with water, forms the bromine cyanogen insect amide metaflumizone suspending agent that principle active component weight percentage is 22% under the effect of sand mill.
Embodiment 8:
Weigh 2g bromine cyanogen insect amide, 20g metaflumizone, alkylphenol polyoxyethylene 14g, phenethyl phenol polyethenoxy ether 15g, dimethylbenzene to 100g, the method that above raw material is prepared cream routinely puts into mixing in mixing kettle, forms the bromine cyanogen insect amide metaflumizone cream that principle active component weight percentage is 22%.
Embodiment 9:
Weigh 10g bromine cyanogen insect amide, 2g metaflumizone, sodium lignin sulfonate 8g, sodium lauryl sulphate 2g, ammonium sulfate 5g, polyvinyl alcohol 5g, Borax 2g, Kaolin 28g, forms, by the method for water dispersion granule, the bromine cyanogen insect amide metaflumizone water dispersible granules that principle active component weight percentage is 12% by above raw material.
Embodiment 10:
Weigh 10g bromine cyanogen insect amide, 5g metaflumizone, alkylphenol polyoxyethylene 14g, phenethyl phenol polyethenoxy ether 15g, dimethylbenzene to 100g, the method that above raw material is prepared cream routinely puts into mixing in mixing kettle, forms the bromine cyanogen insect amide metaflumizone cream that principle active component weight percentage is 15%.
Embodiment 11:
Weigh 10g bromine cyanogen insect amide, 10g metaflumizone, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 3g, dimethylbenzene to 100g, the method that above raw material is prepared cream routinely puts into mixing in mixing kettle, forms the bromine cyanogen insect amide metaflumizone cream that principle active component weight percentage is 20%.
Drug effect checking test
1, indoor virulence determination of activity
Weigh bromine cyanogen insect amide and metaflumizone 30g, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 4g, vegetable oil to 100g altogether.The method that above raw material is prepared cream routinely puts into mixing in mixing kettle, is configured to the bromine cyanogen insect amide metaflumizone cream that principle active component weight percentage is 30%.Wherein the concrete ratio of bromine cyanogen insect amide and metaflumizone is shown in Table 1 and 2.
Using feedstuff to add poison method and carry out indoor potentiation bioassay, selection resistant bollworm is target pest, often processes and is repeated 3 times, and every concentration processes 60, calculates toxicity regression equation and lethal concentration of 50 LC of each medicament antagonism bollworm by probability value method50, use LC50Value press Sun Yun abundant method calculating co-toxicity coefficient, the results are shown in Table 1:
Table 1 bromine cyanogen insect amide, metaflumizone and the toxicity test of compounding sample antagonism bollworm thereof and co-toxicity coefficient
In table, data show, after bromine cyanogen insect amide and metaflumizone mixture, antagonism bollworm are had potentiation, and proportioning co-toxicity coefficient listed in table is both greater than 120, and therefore bromine cyanogen insect amide and metaflumizone mixture have significant synergies.
Weigh bromine cyanogen insect amide, metaflumizone uses conventional formulation method to be configured to, by different proportion, the bromine cyanogen insect amide metaflumizone cream that principle active component weight percentage is 30%.Concrete ratio is shown in Table 2.
Using feedstuff to add poison method and carry out indoor potentiation bioassay, selection rice-stem borer is target pest, often processes and is repeated 3 times, and calculates toxicity regression equation and lethal concentration of 50 LC of each medicament antagonism striped rice borer by probability value method50, use LC50Value press Sun Yun abundant method calculating co-toxicity coefficient, the results are shown in Table 2:
Table 2 bromine cyanogen insect amide, metaflumizone and compounding sample thereof to striped rice borer toxicity test and co-toxicity coefficient
In table, data show, have potentiation after bromine cyanogen insect amide and metaflumizone mixture to rice-stem borer, and proportioning co-toxicity coefficient listed in table is all much larger than 120, and therefore bromine cyanogen insect amide and metaflumizone mixture have significant synergies.
2, field control effectiveness test
Embodiment institute sample product are used to carry out the field test of control in field bollworm, comparison medicament is 22% metaflumizone SC (suspending agent) and 20% bromine cyanogen insect amide WP (wettable powder), it is diluted according to the extension rate in form 3,3 days are looked into after medicine, 7 days, the result of 14 days, result is shown in Table 3:
Table 3 bromine cyanogen insect amide-metaflumizone compounds the field test results of antagonism bollworm
Example has fabulous quick-acting to antagonism bollworm as can be seen from Table 3, and the lasting period is long, good at variable rate technology, is the outstanding medicament preventing and treating antagonism bollworm.
Measure through indoor synergism test and show: by bromine cyanogen insect amide and metaflumizone built agent, bollworm and rice-stem borer are had significant synergistic insecticidal action；Field control effectiveness test also indicates that all of built agent of the present invention is all remarkably higher than the effect of corresponding single dose pesticide to bollworm insecticidal effect equally.

Claims (10)

1. brominated cyanogen insect amide and a compound pesticide compositions for metaflumizone, it is characterized in that this compound pesticide compositions with Bromine cyanogen insect amide and metaflumizone are active insecticidal components, and wherein, the weight ratio of bromine cyanogen insect amide and metaflumizone is 0.1～80: 0.5～80.
Brominated cyanogen insect amide the most according to claim 1 and the compound pesticide compositions of metaflumizone, is characterized in that institute The bromine cyanogen insect amide stated and the weight ratio of metaflumizone are 1～60:1～60.
Brominated cyanogen insect amide the most according to claim 2 and the compound pesticide compositions of metaflumizone, is characterized in that institute The bromine cyanogen insect amide stated and the weight ratio of metaflumizone are 1～40:1～40.
Brominated cyanogen insect amide the most according to claim 3 and the compound pesticide compositions of metaflumizone, is characterized in that institute The bromine cyanogen insect amide stated and the weight ratio of metaflumizone are 1～30:1～30.
Brominated cyanogen insect amide the most according to claim 1 and the compound pesticide compositions of metaflumizone, is characterized in that bromine Cyanogen insect amide and both metaflumizones weight percentage in this compound pesticide compositions are 3%～80%.
Brominated cyanogen insect amide the most according to claim 5 and the compound pesticide compositions of metaflumizone, is characterized in that bromine Cyanogen insect amide and both metaflumizones weight percentage in this compound pesticide compositions are 5%～55%.
Brominated cyanogen insect amide the most according to claim 1 and the compound pesticide compositions of metaflumizone, is characterized in that this Compound pesticide compositions is with bromine cyanogen insect amide and metaflumizone as active insecticidal components and insecticides adjuvant and excipient are configured to agriculture The dosage form allowed on medicine.
Brominated cyanogen insect amide the most according to claim 7 and the compound pesticide compositions of metaflumizone, is characterized in that institute Stating dosage form is cream, suspending agent, aqueous emulsion, wettable powder, microemulsion or water dispersion granule.
9. the compound pesticide compositions of brominated cyanogen insect amide described in claim 1 and metaflumizone prevents and treats resistance squama in preparation Application on the insecticidal materials of wing mesh insect.
The compound pesticide compositions of brominated cyanogen insect amide the most according to claim 9 and metaflumizone is in preparation preventing and treating cotton Application on the insecticidal materials of earworm or snout moths larva.
CN201610450163.9A 2016-06-21 2016-06-21 Composite insecticide composition containing cyantraniliprole and metaflumizone and application thereof Pending CN105994328A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610450163.9A CN105994328A (en) 2016-06-21 2016-06-21 Composite insecticide composition containing cyantraniliprole and metaflumizone and application thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610450163.9A CN105994328A (en) 2016-06-21 2016-06-21 Composite insecticide composition containing cyantraniliprole and metaflumizone and application thereof

Publications (1)

Publication Number Publication Date
CN105994328A true CN105994328A (en) 2016-10-12

Family

ID=57085483

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201610450163.9A Pending CN105994328A (en) 2016-06-21 2016-06-21 Composite insecticide composition containing cyantraniliprole and metaflumizone and application thereof

Country Status (1)

Country Link
CN (1) CN105994328A (en)

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103238614A (en) * 2012-02-10 2013-08-14 陕西美邦农药有限公司 Insecticidal composition containing metaflumizone and cyantraniliprole
CN103651473A (en) * 2012-10-25 2014-03-26 海利尔药业集团股份有限公司 Insecticidal combination containing metaflumizone and cyantraniliprole
CN105325439A (en) * 2014-08-07 2016-02-17 江苏龙灯化学有限公司 Insecticidal composition containing cyhalodiamide and metaflumizone

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103238614A (en) * 2012-02-10 2013-08-14 陕西美邦农药有限公司 Insecticidal composition containing metaflumizone and cyantraniliprole
CN103651473A (en) * 2012-10-25 2014-03-26 海利尔药业集团股份有限公司 Insecticidal combination containing metaflumizone and cyantraniliprole
CN105325439A (en) * 2014-08-07 2016-02-17 江苏龙灯化学有限公司 Insecticidal composition containing cyhalodiamide and metaflumizone

Similar Documents

Publication Publication Date Title
CN105994310A (en) Composite insecticide composition containing cyantraniliprole and avermectin and application thereof
CN105994328A (en) Composite insecticide composition containing cyantraniliprole and metaflumizone and application thereof
CN104642363B (en) A kind of containing metaflumizone and the Pesticidal combination of ethyl pleocidin and application
CN106070285A (en) A kind of compound pesticide compositions of brominated cyanogen insect amide and indoxacarb and application thereof
CN105941467A (en) Compound insecticide composition containing cyantraniliprole and chlorpyrifos and application thereof
CN105475339B (en) A kind of Synergistic insecticidal compositions and its application containing propargite and cycloprothrin
CN106070278A (en) A kind of compound pesticide compositions of brominated cyanogen insect amide and Cascade and application thereof
CN106070228A (en) A kind of brominated cyanogen insect amide and the Synergistic insecticidal compositions of Nitenpyram and application thereof
CN105941460A (en) Synergistic insecticidal composition containing cyantraniliprole and thiamethoxam and application thereof
CN106070227A (en) A kind of compound pesticide compositions of brominated cyanogen insect amide and pleocidin and application thereof
CN105994289A (en) Composite insecticide composition containing cyantraniliprole and spinetoram and application thereof
CN105941462A (en) Compound insecticidal composition containing cyantraniliprole and fenpropathrin and application thereof
CN106417344A (en) Synergistic insecticidal composition containing cyantraniliprole and acetamiprid and application of synergistic insecticidal composition
CN106035352A (en) Lepimectin and cyantraniliprole contained compound insecticidal composition and use thereof
CN105994287A (en) Composite insecticide composition containing cyantraniliprole and methoxyfenozide and application thereof
CN106035369A (en) Lepimectin and Profenofos contained compound insecticidal composition and use thereof
CN104642358B (en) A kind of containing ethyl pleocidin and the Synergistic insecticidal compositions of MTMC and application
CN105638667B (en) A kind of Synergistic insecticidal compositions and its application containing propargite and ethyl spinosad
CN105994352A (en) Composite insecticide composition containing cyantraniliprole and profenofos and application thereof
CN105994288A (en) Composite insecticide composition containing cyantraniliprole and tebufenozide and application thereof
CN105941449A (en) Compound insecticidal composition containing Lepimectin and indoxacarb and application thereof
CN105475344B (en) A kind of Synergistic insecticidal compositions and its application containing propargite and silicon ethofenprox
CN105557746B (en) A kind of Synergistic insecticidal compositions and its application containing etoxazole and silicon ethofenprox
CN105994297A (en) Synergistic insecticide composition containing cyantraniliprole and pymetrozine and application thereof
CN105994330A (en) Composite insecticide composition containing cyantraniliprole and chlorfluazuron and application thereof

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication

Application publication date: 20161012

RJ01 Rejection of invention patent application after publication