CN105325439A - Insecticidal composition containing cyhalodiamide and metaflumizone - Google Patents
Insecticidal composition containing cyhalodiamide and metaflumizone Download PDFInfo
- Publication number
- CN105325439A CN105325439A CN201410386305.0A CN201410386305A CN105325439A CN 105325439 A CN105325439 A CN 105325439A CN 201410386305 A CN201410386305 A CN 201410386305A CN 105325439 A CN105325439 A CN 105325439A
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- CN
- China
- Prior art keywords
- metaflumizone
- pesticidal combination
- insect amide
- chlorine fluorine
- cyanogen insect
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000005914 Metaflumizone Substances 0.000 title claims abstract description 58
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- NNRSYETYEADPBW-UHFFFAOYSA-N cyhalodiamide Chemical compound CC1=CC(C(F)(C(F)(F)F)C(F)(F)F)=CC=C1NC(=O)C1=CC=CC(Cl)=C1C(=O)NC(C)(C)C#N NNRSYETYEADPBW-UHFFFAOYSA-N 0.000 title abstract description 8
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- 150000001408 amides Chemical class 0.000 claims description 50
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- MGWBOJLDWNUQAK-UHFFFAOYSA-N OC1=C(C=CC=C1)[Na] Chemical compound OC1=C(C=CC=C1)[Na] MGWBOJLDWNUQAK-UHFFFAOYSA-N 0.000 description 1
- 241000238814 Orthoptera Species 0.000 description 1
- 229920001214 Polysorbate 60 Polymers 0.000 description 1
- NAMPHRGXOPFKSX-UHFFFAOYSA-L S(=O)(=O)(O)C(C(=O)[O-])CC(=O)[O-].[Na+].[Na+].C(CCCCC(C)C)O Chemical compound S(=O)(=O)(O)C(C(=O)[O-])CC(=O)[O-].[Na+].[Na+].C(CCCCC(C)C)O NAMPHRGXOPFKSX-UHFFFAOYSA-L 0.000 description 1
- 241000258242 Siphonaptera Species 0.000 description 1
- 241000180219 Sitobion avenae Species 0.000 description 1
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 description 1
- 241000176086 Sogatella furcifera Species 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 241001414989 Thysanoptera Species 0.000 description 1
- 241000018137 Trialeurodes vaporariorum Species 0.000 description 1
- 229910021536 Zeolite Inorganic materials 0.000 description 1
- YBOFEONRFJMHND-UHFFFAOYSA-N [Br].N#CC#N Chemical compound [Br].N#CC#N YBOFEONRFJMHND-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 150000003973 alkyl amines Chemical class 0.000 description 1
- 150000005215 alkyl ethers Chemical class 0.000 description 1
- WMGSQTMJHBYJMQ-UHFFFAOYSA-N aluminum;magnesium;silicate Chemical compound [Mg+2].[Al+3].[O-][Si]([O-])([O-])[O-] WMGSQTMJHBYJMQ-UHFFFAOYSA-N 0.000 description 1
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 1
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 1
- 235000011130 ammonium sulphate Nutrition 0.000 description 1
- 230000008485 antagonism Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000000440 bentonite Substances 0.000 description 1
- 229910000278 bentonite Inorganic materials 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- 235000010233 benzoic acid Nutrition 0.000 description 1
- 235000021329 brown rice Nutrition 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 229910001424 calcium ion Inorganic materials 0.000 description 1
- 239000001175 calcium sulphate Substances 0.000 description 1
- 235000011132 calcium sulphate Nutrition 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 235000013877 carbamide Nutrition 0.000 description 1
- 229920003064 carboxyethyl cellulose Polymers 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 210000004027 cell Anatomy 0.000 description 1
- 238000003889 chemical engineering Methods 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 235000012343 cottonseed oil Nutrition 0.000 description 1
- HPXRVTGHNJAIIH-UHFFFAOYSA-N cyclohexanol Chemical compound OC1CCCCC1 HPXRVTGHNJAIIH-UHFFFAOYSA-N 0.000 description 1
- 239000013530 defoamer Substances 0.000 description 1
- 230000001934 delay Effects 0.000 description 1
- 230000003111 delayed effect Effects 0.000 description 1
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 229960000878 docusate sodium Drugs 0.000 description 1
- VICYBMUVWHJEFT-UHFFFAOYSA-N dodecyltrimethylammonium ion Chemical class CCCCCCCCCCCC[N+](C)(C)C VICYBMUVWHJEFT-UHFFFAOYSA-N 0.000 description 1
- 239000002552 dosage form Substances 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 230000001586 eradicative effect Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 229960005082 etohexadiol Drugs 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- 230000036039 immunity Effects 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 229910001629 magnesium chloride Inorganic materials 0.000 description 1
- 235000011147 magnesium chloride Nutrition 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 229910052901 montmorillonite Inorganic materials 0.000 description 1
- 230000004118 muscle contraction Effects 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- FATBGEAMYMYZAF-KTKRTIGZSA-N oleamide Chemical compound CCCCCCCC\C=C/CCCCCCCC(N)=O FATBGEAMYMYZAF-KTKRTIGZSA-N 0.000 description 1
- FATBGEAMYMYZAF-UHFFFAOYSA-N oleicacidamide-heptaglycolether Natural products CCCCCCCCC=CCCCCCCCC(N)=O FATBGEAMYMYZAF-UHFFFAOYSA-N 0.000 description 1
- 239000003002 pH adjusting agent Substances 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- NAYYNDKKHOIIOD-UHFFFAOYSA-N phthalamide Chemical class NC(=O)C1=CC=CC=C1C(N)=O NAYYNDKKHOIIOD-UHFFFAOYSA-N 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920000259 polyoxyethylene lauryl ether Polymers 0.000 description 1
- 229920002503 polyoxyethylene-polyoxypropylene Polymers 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 230000008092 positive effect Effects 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- 230000003449 preventive effect Effects 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 229910052903 pyrophyllite Inorganic materials 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 102000042094 ryanodine receptor (TC 1.A.3.1) family Human genes 0.000 description 1
- 108091052345 ryanodine receptor (TC 1.A.3.1) family Proteins 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 108700004121 sarkosyl Proteins 0.000 description 1
- 150000007659 semicarbazones Chemical class 0.000 description 1
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 description 1
- 239000004299 sodium benzoate Substances 0.000 description 1
- 235000010234 sodium benzoate Nutrition 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- APSBXTVYXVQYAB-UHFFFAOYSA-M sodium docusate Chemical compound [Na+].CCCCC(CC)COC(=O)CC(S([O-])(=O)=O)C(=O)OCC(CC)CCCC APSBXTVYXVQYAB-UHFFFAOYSA-M 0.000 description 1
- KSAVQLQVUXSOCR-UHFFFAOYSA-M sodium lauroyl sarcosinate Chemical compound [Na+].CCCCCCCCCCCC(=O)N(C)CC([O-])=O KSAVQLQVUXSOCR-UHFFFAOYSA-M 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- GOLXNESZZPUPJE-UHFFFAOYSA-N spiromesifen Chemical compound CC1=CC(C)=CC(C)=C1C(C(O1)=O)=C(OC(=O)CC(C)(C)C)C11CCCC1 GOLXNESZZPUPJE-UHFFFAOYSA-N 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 210000002784 stomach Anatomy 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-L succinate(2-) Chemical compound [O-]C(=O)CCC([O-])=O KDYFGRWQOYBRFD-UHFFFAOYSA-L 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 235000012222 talc Nutrition 0.000 description 1
- CXWXQJXEFPUFDZ-UHFFFAOYSA-N tetralin Chemical compound C1=CC=C2CCCCC2=C1 CXWXQJXEFPUFDZ-UHFFFAOYSA-N 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 230000005945 translocation Effects 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention specifically relates to an insecticidal composition, especially to an insecticidal composition containing cyhalodiamide and metaflumizone and application thereof, belonging to the field of agriculture. The insecticidal composition containing cyhalodiamide and metaflumizone is characterized in that the insecticidal composition contains active components consisting of cyhalodiamide and metaflumizone, wherein a weight ratio of the active component cyhalodiamide to the active component metaflumizone is 100: 1 to 1: 100. The invention also relates to an insecticidal composition containing the active components consisting of cyhalodiamide and metaflumizone and an agriculturally acceptable auxiliary agent and/or carrier of the composition, a method for prevention and treatment of agricultural insects with the composition, and application of the composition in prevention and treatment of agricultural insects.
Description
Technical field
What the present invention relates to is agriculture field, is specifically related to a kind of Pesticidal combination, particularly a kind of Pesticidal combination and application thereof containing chlorine fluorine cyanogen insect amide and metaflumizone.
Background technology
The resistance problem of pest is global problems.Along with the impact of the prolongation of pest chemical control medication history, the agricultural chemicals not factor such as scientifical use, in recent years, pest resistance is day by day serious, the pest species producing resistance is continuing to increase, particularly very easily produce resistance Lepidoptera class pest, resistance level is higher, and resistance development speed is relatively very fast.Agriculture chemical compounding or mixture have expansion insecticidal spectrum, delay the feature such as pest resistance and pesticide resistance, are to solve pest resistance problem comparatively one of effective method.Therefore, the Pesticidal combination of efficient, the low toxicity of research and development, environmental protection has positive effect to agricultural sustainable development.
Chlorine fluorine cyanogen insect amide (ZJ4042, Cas.NO:1262605-53-7) be the phthalic diamides insecticide that Zhejiang Provincial Chemical Engineering Research Inst is developed, it is the novel pesticide of a kind of efficient, low toxicity and mechanism of action uniqueness, it acts on insect ryanodine receptor, impel the endogenous calcium ion release of insect cell, affect contraction of muscle, and then cause insect death; To the larva of Lepidoptera, coleoptera, diptera and Homoptera, there is very high activity, but main effect model is based on stomach toxicity, has certain interior absorption, can be used for the primary pest control of paddy rice, vegetables, fruit tree, cotton.
Metaflumizone (Metaflumizone, Cas.NO:139968-49-3) is a kind of brand-new compound that BASF Aktiengesellschaft and Japanese agricultural chemicals company develop jointly, and belongs to semicarbazones insecticides.The mechanism of action of metaflumizone is unique, and itself has insecticidal activity, does not need bioactivation, with existing each insecticides without cross resistance.Metaflumizone can prevent and treat larva, the adult of lepidoptera pest and some coleoptera effectively.Metaflumizone can not be transmitted to other parts of plant from the blade processed, also do not have vaned settlement point place to show significantly to ambient radiation diffusion motion.Therefore metaflumizone only has medium osmotically active at blade surface, at the chlorenchyma of plant and root without Uptake and translocation, thus cause it to have good effect to the striped rice borer that the rice leaf roller of paddy rice and end have enough time to bore moth, but also limit its administration time, bore the first ovum phase of moth property snout moth's larva just effectively, so administration time can not too early can not be excessively slow.
Rice-stem borer is from the primary pest being the Yangtze river basin major part single cropping rice and double rice cropping system at the beginning of the 21 century eighties 20th century; Along with the appearance of many batches of efficient medicaments such as Hostathion, Cupric sulfate, ethiprole, striped rice borer declines gradually, with the third-largest insect after becoming rice leaf roller and rice fulgorid.But the adjustment along with profitable agriculture, crop mix and the Hostathion to routine, Cupric sulfate develop immunity to drugs; The forbidding of efficient medicament ethiprole, striped rice borer has the trend continuing rise.With ethiprole forbid dock release the wideling popularize of the efficient amides pesticide such as Rynaxypyr, fluorobenzene insect amide, chlorine fluorine cyanogen insect amide, become rapidly the principal item of paddy rice pesticide control, efficiently be undivided to striped rice borer with it, it is still main pesticide control that 5-7 is carried out at end.
Current amide-type is listing and the use that main compound has numerous amide-type products such as Rynaxypyr, fluorobenzene insect amide, bromine cyanogen insect amide, four chlorantraniliproles, chlorine fluorine cyanogen insect amide by coming into the market, and its pesticide resistance and cross resistance will certainly produce rapidly.So exploitation can produce synergy with the said goods, delay the agriculture chemical compounding kind that pest resistance develops become current urgent problem.
Summary of the invention
The present invention seeks to for above-mentioned weak point as providing a kind of Pesticidal combination containing chlorine fluorine cyanogen insect amide and metaflumizone.
The present inventor have passed through long-term research, and find unexpectedly on the basis of great many of experiments, by chlorine fluorine cyanogen insect amide and metaflumizone composite after, produce synergistic function, can effectively prevent and treat pest as the snout moth's larva of rice, this on the one hand overcomes the development of insect to amide-type Drug Resistance, can improve relatively partially short shortcoming in metaflumizone dispenser period on the other hand.
Therefore, technical problem to be solved by this invention is to provide one effectively can prevent and treat pest, delays insect to amide-type Drug Resistance, and can the Synergistic composition in proper extension metaflumizone dispenser period.
In order to solve the problem, the present invention adopts following technical scheme:
One object of the present invention is for providing a kind of Pesticidal combination containing chlorine fluorine cyanogen insect amide and metaflumizone, and described Pesticidal combination contains active component chlorine fluorine cyanogen insect amide and metaflumizone.
In described Pesticidal combination, the weight ratio of active component chlorine fluorine cyanogen insect amide and metaflumizone is 100:1 to 1:100.
Preferably, in described Pesticidal combination, the weight ratio of active component chlorine fluorine cyanogen insect amide and metaflumizone is 50:1 to 1:50, preferably 20:1 to 1:20, more preferably 10:1 to 1:10, especially preferably 5:1 to 1:5.
Another object of the present invention is for providing a kind of Pesticidal combination comprising above-mentioned active component chlorine fluorine cyanogen insect amide and metaflumizone and agriculturally acceptable auxiliary agent and/or carrier.
Wherein, in above-mentioned Pesticidal combination, the weight content that described active component chlorine fluorine cyanogen insect amide and metaflumizone account for desinsection is 1wt.% to 90wt.%, preferably 10wt.% to 80wt.%, more preferably 20wt.% to 60wt.%, especially preferably 25wt.% to 40wt.%.
Above-mentioned Pesticidal combination can be prepared into agriculturally acceptable any formulation, preferred particulates agent, wetting powder, water dispersible granules, suspending agent, microcapsule suspending agent, aqueous emulsion, microemulsion.
Above-mentioned formulation is this area regular dosage form, its preparation method is well known to those skilled in the art, be prepared into agricultural agent used by above-mentioned various formulation and/or carrier and consumption thereof and be similarly well-known to those skilled in the art, these all can see such as " formulations of pesticide process technology " (Liu Bulin edits, the second edition).Auxiliary agent used and/or carrier such as include but not limited to solvent, cosolvent, emulsifier, dispersant, wetting agent, adhesive, disintegrant, thickener, antifreezing agent, stabilizing agent, pH adjusting agent, filler and/or carrier etc.Those skilled in the art can select one or more auxiliary agents wherein and/or carrier, such as:
Described solvent can be selected: one or more in toluene, dimethylbenzene, acetone, dimethyl formamide, dimethyl sulfoxide (DMSO), benzene, chloroform, carrene, cyclohexane, cyclohexanone, 1-METHYLPYRROLIDONE, methyl alcohol, ethanol, propyl alcohol, isopropyl alcohol, butanols, isobutanol, cyclohexanol, Propylene Glycol ether, ethohexadiol ether, benzinum, acetonitrile, paraffin, tetrahydronaphthalene, isophorone, soybean oil, cottonseed wet goods;
Described cosolvent can be selected: one or more in methyl alcohol, ethanol, isopropyl alcohol, n-butanol etc.;
Described emulsifier can be selected: lauryl sodium sulfate, neopelex, calcium dodecyl benzene sulfonate, thermally coupled distillation columns amine salt, castor oil polyoxyethylene ether phosphate amine salt, triphen ethyl phenol polyoxy ether phosphate amine salt, Polyoxyethylene fatty acid amides, Fixanol, alkyl isoquinolinium salt, dialkylmorpholinum salts, oleamide sulfonate, diisopropyl naphthalene sulfonate, lignosulfonates or naphthalenesulfonate formaldehyde condensation compound, styryl phenyl APEO, phenethyl phenol polyoxyethylene poly-oxygen propylene aether, polyoxyethylene nonylphenol ether, fatty alcohol-polyoxyethylene ether, polyoxyethylene alkyl ether, polyoxyethylene polyoxypropylene block polymer, alkyl phenol formaldehyde resin polyoxyethylene ether, Polyoxyethylene Sorbitol Fatty Acid Esters, sorbitan monostearate, sorbitan monostearate APEO, one or more in polyoxypropylene glycol mono fatty acid ester etc.,
Described dispersant can be selected: lignosulfonates, to hydroxyphenyl sodium lignin sulfonate, fatty alcohol polyoxyethylene ether sulfate, alkylnaphthalene sulfonate, naphthalene sulfonic acid-formaldehyde condensation product sodium salt, dodecyl trimethyl ammonium salt, alkyl dimethyl benzyl ammonium salt, two polyoxyethylene lauryl ether phosphate, styrene-maleic acid salt copolymer, aliphatic alcohol polyoxyvinethene phosphate, polyoxyethylene nonylphenol ether, glycerine fatty acid APEO, polyoxyethylene alkylaryl ether, polyoxyethylene lanolin alcohol, Polyoxyethylene Sorbitan acid esters, polyoxyethylene glyceryl mono fatty acid ester, one or more in alkylolamides and polyoxyethylene alkyl amine etc.,
Described wetting agent can be selected: lauryl sodium sulfate, calcium dodecyl benzene sulfonate, isooctanol Disodium sulfosuccinate, oleoyl methyl sodium taurocholate, polyoxyethylene lauryl ether carboxylic acid sodium, sodium N-lauroyl sarcosinate, N-sodium lauroyl glutamate, dioctyl sulfosuccinate, polyoxyethylene alkylaryl ether phosphate ester salt, trisiloxanes APEO, triphenoethyl benzene phenol polyethenoxy ether, castor oil polyoxyethylene ether, fatty alcohol-polyoxyethylene ether, alkylphenol-polyethenoxy gathers base ether formaldehyde condensation products, alkylphenol-polyethenoxy base ether phosphate, polyoxyethylene fatty acid ester, higher fatty acid ester, one or more in sorbitan aliphatic ester etc.,
Described adhesive can be selected: one or more in starch, polyvinylpyrrolidone, carboxymethyl cellulose, carboxyethyl cellulose, gelatin, gum Arabic, xanthans etc.;
Described disintegrant can be selected: one or more in urea, sodium sulphate, calcium sulphate, sodium bicarbonate, ammonium sulfate, magnesium chloride, sodium chloride etc.;
Described thickener can be selected: one or more in gum Arabic, xanthans, gelatin, polyvinyl alcohol, aluminium-magnesium silicate, sodium carboxymethylcellulose etc.;
Described defoamer can be selected: one or more in butylphosphoric acid ester, phosphoric acid isobutyl ester, n-octanol, silicone etc.;
Described antifreezing agent can be selected: be selected from ethylene glycol, propane diols, glycerine etc. one or more;
Described stabilizing agent can be selected: one or more in the soybean oil based trimethylene diamine of triphenyl phosphite, N-, dialkyl group succinate sulfonate, epoxychloropropane, butyl glycidyl ether etc.;
Described preservative can be selected: one or more in benzoic acid, Sodium Benzoate etc.;
Described filler and/or carrier can be selected: one or more in attapulgite, diatomite, kaolin, white carbon, bentonite, montmorillonite, calcium carbonate, zeolite, acid clay, carclazyte, pyrophyllite, talcum, calcite etc.
Another object of the present invention is for providing above-mentioned Pesticidal combination for preventing or control the purposes of pest.Such as can effectively prevent and treat the pest such as Lepidoptera, diptera, coleoptera, Homoptera, orthoptera, Hymenoptera, Isoptera, Siphonaptera, Blattaria, Thysanoptera.
Described composition is particularly effective to following insect: beet armyworm, black peach aphid, cotten aphid, apple aphid, English grain aphid, brown back rice plant hopper, small brown rice planthopper, Bemisia tabaci, Trialeurodes vaporariorum Westwood, leafhopper, rice leafhopper, tobacco budworm, rice leaf roller, diamond-back moth, tomato moth, cotton bollworm, striped rice borer, paddy stem borer, scotinophora lurida, rice spiny coreid, Leptocorisa spp and blattaria.
Described composition is especially effective to beet armyworm, diamond-back moth, tomato moth, cotton bollworm, striped rice borer, paddy stem borer, cotten aphid etc., particularly effective to striped rice borer, paddy stem borer, beet armyworm.
Another object of the present invention is for providing a kind of method of prevention or control pest, be specially, Pesticidal combination of the present invention is contacted with described pest, or Pesticidal combination of the present invention is applied to habitat or the living environment of described pest.Concrete application process can be foliar spray, seed treatment, soil treatment etc., preferred foliar spray; Its amount of application is that those skilled in the art can determine, such as 0.1-1000gai./ha, preferred 1-200gai./ha, more preferably 10-50gai./ha.
The various compound that the present invention is used and/or reagent are commercially available, can easily buy from the market.
Beneficial effect of the present invention shows:
A, synergistic effect obviously, can reduce the dosage of two single doses;
B, delay the generation of resistance: both mechanisms of action and the mode of action are completely different, good killing action is had to low age and high instar larvae after combination, thus delayed the period that the generation of resistance, particularly amide-type use in a large number, thus ensure control efficiency;
C, solve the metaflumizone preventive effect factors of instability: chlorine fluorine cyanogen insect amide insecticide spraying time can incubate instar larvae phase phase to 3 from ovum and use, metaflumizone is highly active solves the narrow problem of insecticide spraying time simultaneously playing.
Embodiment
Below in conjunction with specific embodiment, the present invention is further described, but does not limit the invention to these embodiments.One skilled in the art would recognize that all alternatives, improvement project and the equivalents that present invention encompasses and may comprise in Claims scope.
(1) example of formulations
embodiment 12% chlorine fluorine cyanogen insect amide+18% metaflumizone wetting powder
Chlorine fluorine cyanogen insect amide 2%
Metaflumizone 18%
Calcium dodecyl benzene sulfonate 5%
Polyoxyethylene nonylphenol ether 4%
Attapulgite supplies 100%
Take above-mentioned each component of formula ratio respectively, and mixed, grind, pulverize, obtained wetting powder.
embodiment 224% chlorine fluorine cyanogen insect amide+1% metaflumizone wetting powder
Chlorine fluorine cyanogen insect amide 24%
Metaflumizone 1%
Alkylphenol-polyethenoxy base ether phosphate 7%
Naphthalene sulfonic acid-formaldehyde condensation product sodium salt 2%
Diatomite supplies 100%
Take above-mentioned each component of formula ratio respectively, and mixed, grind, pulverize, obtained wetting powder.
embodiment 325% chlorine fluorine cyanogen insect amide+15% metaflumizone suspending agent
Chlorine fluorine cyanogen insect amide 25%
Metaflumizone 15%
Polyoxyethylene Sorbitol Fatty Acid Esters 5%
Naphthalene sulfonic acid-formaldehyde condensation product sodium salt 6%
Polyvinyl alcohol 2%
Silicone 0.5%
Ethylene glycol 2%
Water supplies 100%
Take above-mentioned each component of formula ratio respectively, by ultramicro grinding method, obtained suspending agent.
embodiment 45% chlorine fluorine cyanogen insect amide+40% metaflumizone suspending agent
Chlorine fluorine cyanogen insect amide 5%
Metaflumizone 40%
Naphthalenesulfonate formaldehyde condensation compound 4%
Oleoyl methyl sodium taurocholate 4%
Polyoxyethylene lanolin alcohol 4%
Gum Arabic 2.5%
N-octanol 1%
Ethylene glycol 2%
Water supplies 100%
Take above-mentioned each component of formula ratio respectively, by ultramicro grinding method, obtained suspending agent.
embodiment 542% chlorine fluorine cyanogen insect amide+6% metaflumizone water dispersible granules
Chlorine fluorine cyanogen insect amide 42%
Metaflumizone 6%
Naphthalene sulfonic acid-formaldehyde condensation product sodium 7%
Triphenoethyl benzene phenol polyethenoxy ether 3%
Polyvinylpyrrolidone 4%
Sodium sulphate 5%
Attapulgite supplies 100%
Take above-mentioned each component of formula ratio respectively, and mixed, granulation, obtained water dispersible granules.
embodiment 612% chlorine fluorine cyanogen insect amide+28% metaflumizone water dispersible granules
Chlorine fluorine cyanogen insect amide 12%
Metaflumizone 28%
Polyoxyethylene glyceryl mono fatty acid ester 5%
N-sodium lauroyl glutamate 4%
Carboxymethyl cellulose 4%
Sodium bicarbonate 3%
Kaolin supplies 100%
Take above-mentioned each component of formula ratio respectively, and mixed, granulation, obtained water dispersible granules.
embodiment 70.1% chlorine fluorine cyanogen insect amide+10% metaflumizone aqueous emulsion
Chlorine fluorine cyanogen insect amide 0.1%
Metaflumizone 10%
Dimethyl formamide 11%
Neopelex 8%
Polyoxyethylene alkylaryl ether 4%
Gum Arabic 2%
Butylphosphoric acid ester 2%
Ethylene glycol 3%
Butyl glycidyl ether 1%
Water supplies 100%
Take above-mentioned each component of formula ratio respectively, then pesticide activity component, solvent, surfactant are mixed with into oil phase, other components are added to the water and are prepared into aqueous phase, then in aqueous phase, add oil phase while stirring, obtained aqueous emulsion.
embodiment 812% chlorine fluorine cyanogen insect amide+2% metaflumizone aqueous emulsion
Chlorine fluorine cyanogen insect amide 12%
Metaflumizone 2%
Cyclohexanone 10%
Sodium lignin sulfonate 6%
Polyoxyethylene nonylphenol ether 4%
Sodium carboxymethylcellulose 3%
Silicone 2%
Glycerine 2%
Water supplies 100%
Take above-mentioned each component of formula ratio respectively, then pesticide activity component, solvent, surfactant are mixed with into oil phase, other components are added to the water and are prepared into aqueous phase, then in aqueous phase, add oil phase while stirring, obtained aqueous emulsion.
embodiment 910% chlorine fluorine cyanogen insect amide+0.1% metaflumizone microemulsion
Chlorine fluorine cyanogen insect amide 10%
Metaflumizone 0.1%
Dimethylbenzene 15%
Isopropyl alcohol 3%
Phenethyl phenol polyoxyethylene poly-oxygen propylene aether 12%
Negel 8%
Gelatin 2%
Silicone 2%
Propane diols 4%
Water supplies 100%
Take above-mentioned each component of formula ratio respectively, then pesticide activity component, solvent, cosolvent, surfactant are mixed with into oil phase, other components are added to the water and are prepared into aqueous phase, then in aqueous phase, add oil phase while stirring, obtained microemulsion.
embodiment 108% chlorine fluorine cyanogen insect amide+8% metaflumizone microemulsion
Chlorine fluorine cyanogen insect amide 8%
Metaflumizone 8%
Acetone 10%
Ethanol 2%
Castor oil polyoxyethylene ether phosphate amine salt 10%
Glycerine fatty acid APEO 7%
Xanthans 3%
Phosphoric acid isobutyl ester 3%
Ethylene glycol 4%
Triphenyl phosphite 1%
Water supplies 100%
Take above-mentioned each component of formula ratio respectively, then pesticide activity component, solvent, cosolvent, surfactant are mixed with into oil phase, other components are added to the water and are prepared into aqueous phase, then in aqueous phase, add oil phase while stirring, obtained microemulsion.
In above embodiment, proportioning is weight per distribution ratio.
(2) biological test
There will be three kinds of situations: antagonism, addition and synergistic effect after active compound, during effect summation usually when each reactive compound of effect of active compound combinations is used separately, can think that active compound exists synergistic function.The predictive role of reactive compound by Colby formulae discovery (CalculatingSynergisticandAntagonisticResponsesofHerbicid eCombination ", Colby, S.R.; Weeds15,20-22,1967):
X=is the killing rate when using active component A with the amount of application of mppm, is expressed as the percentage of untreated control group;
Y=is the killing rate when using active component B with the amount of application of nppm, is expressed as the percentage of untreated control group;
E=is the killing rate when using active component A and B with the amount of application of m and nppm, is expressed as the percentage of untreated control group.
If the killing rate of reality is higher than calculated value, then the eradicative rate of bond has superadditivity, namely there is synergy.In this case, the killing rate actually observed must exceed the expection killing rate (E) adopting above formula to calculate.Thus, if the activity observed is greater than the activity from the expection of Colby formula, then there is synergy.
biological test example 1 striped rice borer is tested
For examination material: striped rice borer
Medicament is prepared: chlorine fluorine cyanogen insect amide, the former medicine of metaflumizone are used acetone solution respectively, is made into mother liquor, for subsequent use.Used time, with 5% lignin sulfonic acid sodium water solution, above-mentioned mother liquor is diluted to working concentration.
Test method: the various medicaments preparing concentration described in table 1 by the deionized water containing 5% sodium lignin sulfonate respectively.Being transplanted by the rice seedlings in all for 2-3 ages is respectively in the pallet of 100cm × 100cm × 20cm into length, width and height, cellar culture.When rice seedlings grows to 6-8 leaf period, inoculate 50 rice-stem borer larvas to each pallet, then spray the medicament of various concentration shown in table 1 respectively.Wherein, each concentration is a process, often processes 3 times and repeats.Each process each repetition spray amount is consistent.In each process after 7 days, investigation death condition, finally calculates lethality (test repetition 3 times, averages), the results are shown in Table 1.Wherein " observation killing rate " actual killing rate for observing, " theoretical killing rate " is the killing rate using Colby formulae discovery to obtain.
table 1 present composition is to the effect test of striped rice borer
Be not difficult to find out by the data of table 1, in the present invention, by chlorine fluorine cyanogen insect amide and metaflumizone composite, to striped rice borer produce synergistic effect.
biological test example 2 beet armyworm is tested
For examination material: beet armyworm
Medicament is prepared: chlorine fluorine cyanogen insect amide, the former medicine of metaflumizone are used acetone solution respectively, is made into mother liquor, for subsequent use.Used time, with 5% lignin sulfonic acid sodium water solution, above-mentioned mother liquor is diluted to working concentration.
Test method: the various medicaments preparing concentration described in table 2 by the deionized water containing 5% sodium lignin sulfonate respectively.Choose healthy cabbage plant, 20 beet armyworms are inoculated in every strain, then spray the medicament of various concentration shown in table 2 respectively.Wherein, each concentration is a process, and 10 strain wild cabbages are selected in each process, each repetition spray amount of each process consistent (spray amount amounts to about per hectare 300 liters).In each process after 7 days, investigation death condition, finally calculates lethality (test repetition 3 times, averages), the results are shown in Table 2.Wherein " observation killing rate " actual killing rate for observing, " theoretical killing rate " is the killing rate using Colby formulae discovery to obtain.
table 2 present composition is to the effect test of beet armyworm
Be not difficult to find out by the data of table 2, in the present invention, by chlorine fluorine cyanogen insect amide and metaflumizone composite, to beet armyworm produce synergistic effect.
Pesticidal combination of the present invention is described by specific embodiment.But above-mentioned example is only to further explanation of the present invention, is not limitation of the invention, by the scheme simply adjusted by such scheme and then obtain, does not depart from spirit of the present invention, be all deemed to be included within scope of the present invention.
Claims (12)
1. contain a Pesticidal combination for chlorine fluorine cyanogen insect amide and metaflumizone, it is characterized in that, described Pesticidal combination contains active component chlorine fluorine cyanogen insect amide and metaflumizone.
2. Pesticidal combination according to claim 1, is characterized in that, the weight ratio of described chlorine fluorine cyanogen insect amide and metaflumizone is 100:1 to 1:100.
3. Pesticidal combination according to claim 1, is characterized in that, the weight ratio of described chlorine fluorine cyanogen insect amide and metaflumizone is 50:1 to 1:50.
4. Pesticidal combination according to claim 1, is characterized in that, the weight ratio of described chlorine fluorine cyanogen insect amide and metaflumizone is 20:1 to 1:20.
5. Pesticidal combination according to claim 1, is characterized in that, the weight ratio of described chlorine fluorine cyanogen insect amide and metaflumizone is 10:1 to 1:10.
6. Pesticidal combination according to claim 1, is characterized in that, described Pesticidal combination comprises active component chlorine fluorine cyanogen insect amide and metaflumizone, and agriculturally acceptable auxiliary agent and/or carrier.
7. Pesticidal combination according to claim 6, it is characterized in that, described active component chlorine fluorine cyanogen insect amide and the metaflumizone weight content accounted in described Pesticidal combination are 1wt.% to 90wt.%, preferably 10wt.% to 80wt.%, more preferably 20wt.% to 60wt.%.
8. Pesticidal combination according to claim 6, it is characterized in that, described Pesticidal combination is prepared into agriculturally acceptable any formulation, preferred particulates agent, wetting powder, water dispersible granules, suspending agent, microcapsule suspending agent, aqueous emulsion, microemulsion.
9. Pesticidal combination according to claim 1 is for preventing or control the purposes of pest.
10. purposes according to claim 9, is characterized in that, the preferred lepidoptera pest of described pest.
The method of 11. 1 kinds of preventions or control pest, is characterized in that, contacted by Pesticidal combination according to claim 1 with pest.
The method of 12. 1 kinds of preventions or control pest, is characterized in that, Pesticidal combination according to claim 1 is applied to habitat or the living environment of pest.
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| CN101935291A (en) * | 2010-09-13 | 2011-01-05 | 中化蓝天集团有限公司 | A cyano-containing phthalamide compound, preparation method and use as an agrochemical insecticide |
| CN103283743A (en) * | 2012-02-27 | 2013-09-11 | 陕西韦尔奇作物保护有限公司 | Metaflumizone-containing pesticidal composition |
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| CN101935291A (en) * | 2010-09-13 | 2011-01-05 | 中化蓝天集团有限公司 | A cyano-containing phthalamide compound, preparation method and use as an agrochemical insecticide |
| CN103283743A (en) * | 2012-02-27 | 2013-09-11 | 陕西韦尔奇作物保护有限公司 | Metaflumizone-containing pesticidal composition |
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| CN105994328A (en) * | 2016-06-21 | 2016-10-12 | 南京华洲药业有限公司 | Composite insecticide composition containing cyantraniliprole and metaflumizone and application thereof |
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