CN105325424B - A kind of Pesticidal combination containing chlorine fluorine cyanogen insect amide and Tolfenpyrad - Google Patents
A kind of Pesticidal combination containing chlorine fluorine cyanogen insect amide and Tolfenpyrad Download PDFInfo
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- CN105325424B CN105325424B CN201410385033.2A CN201410385033A CN105325424B CN 105325424 B CN105325424 B CN 105325424B CN 201410385033 A CN201410385033 A CN 201410385033A CN 105325424 B CN105325424 B CN 105325424B
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- Prior art keywords
- pesticidal combination
- insect amide
- chlorine fluorine
- cyanogen insect
- fluorine cyanogen
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- PIBSCOULVOWSNY-UHFFFAOYSA-N OC1=CC=C(C=C1)[Na] Chemical compound OC1=CC=C(C=C1)[Na] PIBSCOULVOWSNY-UHFFFAOYSA-N 0.000 description 1
- RCEAADKTGXTDOA-UHFFFAOYSA-N OS(O)(=O)=O.CCCCCCCCCCCC[Na] Chemical compound OS(O)(=O)=O.CCCCCCCCCCCC[Na] RCEAADKTGXTDOA-UHFFFAOYSA-N 0.000 description 1
- 241000238814 Orthoptera Species 0.000 description 1
- 241000500441 Plutellidae Species 0.000 description 1
- 235000006040 Prunus persica var persica Nutrition 0.000 description 1
- 241000220324 Pyrus Species 0.000 description 1
- 241001253920 Ryania Species 0.000 description 1
- 241000258242 Siphonaptera Species 0.000 description 1
- 241000180219 Sitobion avenae Species 0.000 description 1
- HVUMOYIDDBPOLL-XWVZOOPGSA-N Sorbitan monostearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O HVUMOYIDDBPOLL-XWVZOOPGSA-N 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- 241001414989 Thysanoptera Species 0.000 description 1
- 241000018137 Trialeurodes vaporariorum Species 0.000 description 1
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- 229910021536 Zeolite Inorganic materials 0.000 description 1
- FHMBGAXGVUGLIR-LOVVWNRFSA-N [(3s,5s,8r,9s,10s,13r,14s)-10,13-dimethyl-2,3,4,5,6,7,8,9,11,12,14,15-dodecahydro-1h-cyclopenta[a]phenanthren-3-yl] hydrogen sulfate Chemical compound C1[C@@H](OS(O)(=O)=O)CC[C@]2(C)[C@H]3CC[C@](C)(C=CC4)[C@@H]4[C@@H]3CC[C@H]21 FHMBGAXGVUGLIR-LOVVWNRFSA-N 0.000 description 1
- HXELGNKCCDGMMN-UHFFFAOYSA-N [F].[Cl] Chemical compound [F].[Cl] HXELGNKCCDGMMN-UHFFFAOYSA-N 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 125000002252 acyl group Chemical group 0.000 description 1
- 150000003973 alkyl amines Chemical class 0.000 description 1
- 150000001346 alkyl aryl ethers Chemical class 0.000 description 1
- 150000005215 alkyl ethers Chemical class 0.000 description 1
- WMGSQTMJHBYJMQ-UHFFFAOYSA-N aluminum;magnesium;silicate Chemical compound [Mg+2].[Al+3].[O-][Si]([O-])([O-])[O-] WMGSQTMJHBYJMQ-UHFFFAOYSA-N 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 230000003042 antagnostic effect Effects 0.000 description 1
- 230000008485 antagonism Effects 0.000 description 1
- 239000000440 bentonite Substances 0.000 description 1
- 229910000278 bentonite Inorganic materials 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- 235000010233 benzoic acid Nutrition 0.000 description 1
- 238000009395 breeding Methods 0.000 description 1
- 230000001488 breeding effect Effects 0.000 description 1
- 235000021329 brown rice Nutrition 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 229910001424 calcium ion Inorganic materials 0.000 description 1
- 229920003064 carboxyethyl cellulose Polymers 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 210000004027 cell Anatomy 0.000 description 1
- 238000003889 chemical engineering Methods 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 230000000295 complement effect Effects 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 235000012343 cottonseed oil Nutrition 0.000 description 1
- 239000013530 defoamer Substances 0.000 description 1
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 1
- 235000019329 dioctyl sodium sulphosuccinate Nutrition 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 229960000878 docusate sodium Drugs 0.000 description 1
- VICYBMUVWHJEFT-UHFFFAOYSA-N dodecyltrimethylammonium ion Chemical class CCCCCCCCCCCC[N+](C)(C)C VICYBMUVWHJEFT-UHFFFAOYSA-N 0.000 description 1
- 239000002552 dosage form Substances 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 230000001586 eradicative effect Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 229960005082 etohexadiol Drugs 0.000 description 1
- 230000005713 exacerbation Effects 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 229920000159 gelatin Polymers 0.000 description 1
- 239000008273 gelatin Substances 0.000 description 1
- 235000019322 gelatine Nutrition 0.000 description 1
- 235000011852 gelatine desserts Nutrition 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 230000002363 herbicidal effect Effects 0.000 description 1
- 239000004009 herbicide Substances 0.000 description 1
- 125000004836 hexamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 244000000053 intestinal parasite Species 0.000 description 1
- 229940039717 lanolin Drugs 0.000 description 1
- 235000019388 lanolin Nutrition 0.000 description 1
- 231100001231 less toxic Toxicity 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 229910001629 magnesium chloride Inorganic materials 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 230000010534 mechanism of action Effects 0.000 description 1
- 229910052901 montmorillonite Inorganic materials 0.000 description 1
- 230000004118 muscle contraction Effects 0.000 description 1
- 125000001400 nonyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- FATBGEAMYMYZAF-UHFFFAOYSA-N oleicacidamide-heptaglycolether Natural products CCCCCCCCC=CCCCCCCCC(N)=O FATBGEAMYMYZAF-UHFFFAOYSA-N 0.000 description 1
- 230000005868 ontogenesis Effects 0.000 description 1
- 231100000194 ovacidal Toxicity 0.000 description 1
- 230000003151 ovacidal effect Effects 0.000 description 1
- 210000004681 ovum Anatomy 0.000 description 1
- 239000003002 pH adjusting agent Substances 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 235000021017 pears Nutrition 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 229920000259 polyoxyethylene lauryl ether Polymers 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 230000008092 positive effect Effects 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
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- 230000002265 prevention Effects 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 229910052903 pyrophyllite Inorganic materials 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
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- 210000004894 snout Anatomy 0.000 description 1
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 description 1
- 239000004299 sodium benzoate Substances 0.000 description 1
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- 239000011780 sodium chloride Substances 0.000 description 1
- 239000001509 sodium citrate Substances 0.000 description 1
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 1
- GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 description 1
- KSAVQLQVUXSOCR-UHFFFAOYSA-M sodium lauroyl sarcosinate Chemical compound [Na+].CCCCCCCCCCCC(=O)N(C)CC([O-])=O KSAVQLQVUXSOCR-UHFFFAOYSA-M 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
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- 235000011076 sorbitan monostearate Nutrition 0.000 description 1
- 229940035048 sorbitan monostearate Drugs 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 235000012424 soybean oil Nutrition 0.000 description 1
- 239000003549 soybean oil Substances 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 210000002784 stomach Anatomy 0.000 description 1
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- KDYFGRWQOYBRFD-UHFFFAOYSA-L succinate(2-) Chemical compound [O-]C(=O)CCC([O-])=O KDYFGRWQOYBRFD-UHFFFAOYSA-L 0.000 description 1
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Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The present invention relates to agriculture field, and in particular to a kind of Pesticidal combination, particularly a kind of Pesticidal combination containing chlorine fluorine cyanogen insect amide and Tolfenpyrad and its application.A kind of Pesticidal combination containing chlorine fluorine cyanogen insect amide and Tolfenpyrad, it is characterised in that the Pesticidal combination contains active component chlorine fluorine cyanogen insect amide and Tolfenpyrad.Wherein, the weight of chlorine fluorine cyanogen insect amide and Tolfenpyrad ratio is 100:1 to 1:100.The invention further relates to comprising above-mentioned active component chlorine fluorine cyanogen insect amide and Tolfenpyrad, the Pesticidal combination of agriculturally acceptable auxiliary agent and/or carrier, and the method and purposes of the composition for preventing and controlling agricultural pests.
Description
Technical field
The present invention relates to agriculture field, and in particular to a kind of Pesticidal combination, it is particularly a kind of to contain chlorine fluorine
The Pesticidal combination and its application of cyanogen insect amide and Tolfenpyrad.
Background technology
The resistance problem of agricultural pests is a global problem.With prolonging for agricultural pests chemical prevention medication history
The influence of long, the agricultural chemicals not factor such as scientifical use, in recent years, agricultural pests resistance getting worse, produce the pest species of resistance
Persistently increasing, particularly easily producing the Lepidoptera class pest of resistance, resistance level is higher, and resistance development speed is relatively
It hurry up.Agriculture chemical compounding or mixture have the features such as expanding insecticidal spectrum, delaying pest resistance and the resistance to the action of a drug, are to solve pest resistance to ask
Inscribe one of more effective method.Therefore, the Pesticidal combination of research and development efficiently, less toxic, environmentally friendly is to agricultural sustainable development
With positive effect.
Chlorine fluorine cyanogen insect amide (ZJ4042, Cas.NO：1262605-53-7) be Zhejiang Provincial Chemical Engineering Research Inst develop adjacent benzene
Diformamide insecticides, it is the unique novel pesticide of a kind of efficient, low toxicity and mechanism of action, it acts on insect ryania
Acceptor, promote the endogenous calcium ion release of insect cell, influence contraction of muscle, and then cause insect death；To Lepidoptera, elytrum
Mesh, Diptera and the larva of Homoptera have very high activity, but main effect model has certain interior suction based on stomach toxicity
Property, the primary pest available for rice, vegetables, fruit tree, cotton prevents and treats.
Tolfenpyrad (Tolfenpyrad, Cas.NO：129558-76-5) it is the new of Nihon Nihyaku Co., Ltd's production
Insecticide, toxicity is medium, has action of contace poison, and have concurrently ovicidal, suppression food, suppress spawning effect, insecticidal spectrum is wide, to Lepidoptera,
Semiptera, coleoptera, Hymenoptera, Diptera, Thysanoptera are effective, especially good to diamondback moth quick-acting, the lasting period is long, right
The diamondback moth of whole breeding time is effective, and the diamondback moth of resistance has been produced to conventional pesticide also good effect.
Diamondback moth is the main hair insect of China's leaf vegetables production, and normally only feeding brassicaceous vegetable, its generation are more, numerous
It is extremely strong to grow high rate, generation overlap and the resistance to the action of a drug, as long as there is host plant in field, even withered, it can also make it successfully complete
Into ontogeny, raise up seed.In some southern important leaf vegetables production bases, because agricultural chemicals largely uses and medicine variety list
One, the resistance to the action of a drug of diamondback moth drastically strengthens, and causes increasing agricultural chemicals to fail diamondback moth, and diamondback moth is in exacerbation hair year by year
Raw trend, very big to vegetables Influence of production, it is the ideal chose for solving resistance problem to develop rational Pesticidal composition.
The content of the invention
The present inventor have passed through long-term research, and is found surprisingly that on the basis of many experiments, by chlorine fluorine cyanogen worm acyl
After amine compounds with Tolfenpyrad, synergistic function is produced, can effectively prevent and treat agricultural pests, especially diamondback moth, and can
Effectively pest resistance is delayed to develop.
Therefore, the technical problems to be solved by the invention are to provide one kind and can effectively prevent and treat agricultural pests, delay insect
The Synergistic composition of development of drug resistance.
In order to solve the above problems, the present invention uses following technical scheme：
One object of the present invention is described to provide a kind of Pesticidal combination containing chlorine fluorine cyanogen insect amide and Tolfenpyrad
Pesticidal combination contains active component chlorine fluorine cyanogen insect amide and Tolfenpyrad.
In the Pesticidal combination, the weight ratio of active component chlorine fluorine cyanogen insect amide and Tolfenpyrad is 100:1 to 1:100.
Preferably, in the Pesticidal combination, the weight ratio of active component chlorine fluorine cyanogen insect amide and Tolfenpyrad is 50:
1 to 1:50th, preferably 20:1 to 1:20th, more preferably 10:1 to 1:10, particularly preferred 5:1 to 1:5.
Another object of the present invention for provide it is a kind of comprising above-mentioned active component chlorine fluorine cyanogen insect amide with Tolfenpyrad, with
And the agriculturally Pesticidal combination of acceptable auxiliary agent and/or carrier.
Wherein, in above-mentioned Pesticidal combination, the active component chlorine fluorine cyanogen insect amide accounts for the desinsection with Tolfenpyrad
The weight content of composition is 1wt.% to 90wt.%, preferably 10wt.% to 80wt.%, more preferably 12wt.% to 60wt.%, especially
It is preferred that 25 wt.% to 40 wt.%.
Above-mentioned Pesticidal combination can be prepared into agriculturally acceptable any formulation, preferably missible oil, granule, wettable
Pulvis, water dispersible granules, suspending agent, microcapsule suspending agent, aqueous emulsion, microemulsion.
Above-mentioned formulation is this area regular dosage form, what its preparation method was well known to those skilled in the art, is prepared into
State the agricultural agent used in various formulations and/or carrier and its dosage is similarly well-known to those skilled in the art, these are equal
It may refer to for example《Formulations of pesticide process technology》（Liu Bulin is edited, the second edition）.Auxiliary agent used and/or carrier for example include but
Solvent, cosolvent, emulsifying agent, dispersant, wetting agent, adhesive, disintegrant, thickener, antifreezing agent, stabilizer, pH is not limited to adjust
Save agent, filler and/or carrier etc..Those skilled in the art can select one or more auxiliary agents therein and/or carrier, such as：
The solvent can be selected：Toluene, dimethylbenzene, acetone, dimethylformamide, dimethyl sulfoxide (DMSO), benzene, three chloromethanes
Alkane, dichloromethane, hexamethylene, cyclohexanone, 1-METHYLPYRROLIDONE, methanol, ethanol, propyl alcohol, isopropanol, butanol, isobutanol, ring
Hexanol, Propylene Glycol ether, ethohexadiol ether, petroleum ether, acetonitrile, paraffin, tetrahydronaphthalene, isophorone, soybean oil, cottonseed
One or more in oil etc.；
The cosolvent can be selected：One or more in methanol, ethanol, isopropanol, n-butanol etc.；
The emulsifying agent can be selected：Lauryl sodium sulfate, neopelex, calcium dodecyl benzene sulfonate,
Thermally coupled distillation columns amine salt, castor oil polyoxyethylene ether phosphate amine salt, three phenethyl phenol polyoxy ether phosphoric acid
Ester amine salt, Polyoxyethylene fatty acid amides fatty acid ester, Fixanol, alkyl isoquinolinium salt, dialkylmorpholinum salts, oleamide sulfonic acid
Salt, diisopropyl naphthalene sulfonate, lignosulfonates, naphthalenesulfonate formaldehyde condensation compound, styryl phenyl APEO, benzene
Ethyl -phenol polyoxyethylene poly-oxygen propylene aether, NPE, AEO, polyoxyethylene alkyl ether,
Polyoxyethylene polyoxypropylene block polymer, alkyl phenol formaldehyde resin polyoxyethylene ether, Polyoxyethylene Sorbitol Fatty Acid Esters, mountain
In pears alcohol acid anhydride monostearate, sorbitan monostearate APEO, polyoxypropylene glycol mono fatty acid ester etc.
It is one or more；
The dispersant can be selected：Lignosulfonates, p-hydroxyphenyl sodium lignin sulfonate, AEO
Sulfate, alkylnaphthalene sulfonate, naphthalene sulfonic acid-formaldehyde condensation product sodium salt, dodecyl trimethyl ammonium salt, alkyl dimethyl benzyl ammonium
Salt, two polyoxyethylene lauryl ether phosphate, styrene-maleic acid salt copolymer, aliphatic alcohol polyoxyvinethene phosphate, nonyl
Base phenol polyethenoxy ether, glycerine fatty acid APEO, polyoxyethylene alkylaryl ether, polyoxyethylene lanolin alcohol, polyoxy
In ethene sorbitan aliphatic ester, polyoxyethylene glyceryl mono fatty acid ester, alkylolamides and polyoxyethylene alkyl amine etc.
One or more；
The wetting agent can be selected：Lauryl sodium sulfate, calcium dodecyl benzene sulfonate, isooctanol succinate sulfonic acid
Sodium, oleoyl methyl sodium taurocholate, polyoxyethylene lauryl ether carboxylic acid sodium, sodium N-lauroyl sarcosinate, N- lauroyl paddy ammonia
Sour sodium, dioctyl sulfosuccinate, polyoxyethylene alkylaryl ether phosphate ester salt, trisiloxanes APEO, triphen second
The poly- base ether formaldehyde contracting of base phenol APEO, castor oil polyoxyethylene ether, AEO, alkylphenol-polyethenoxy
Compound, alkylphenol-polyethenoxy base ether phosphate, polyoxyethylene fatty acid ester, higher fatty acid ester, sorbitan fatty
One or more in acid esters etc.；
Described adhesive can be selected：It is starch, polyvinylpyrrolidone, carboxymethyl cellulose, carboxyethyl cellulose, bright
One or more in glue, Arabic gum, xanthans etc.；
The disintegrant can be selected：Urea, sodium sulphate, calcium sulfate, sodium acid carbonate, ammonium sulfate, magnesium chloride, sodium chloride etc.
In one or more；
The thickener can be selected：Arabic gum, xanthans, gelatin, polyvinyl alcohol, aluminium-magnesium silicate, carboxymethyl cellulose
One or more in plain sodium etc.；
The defoamer can be selected：One or more in butylphosphoric acid ester, phosphoric acid isobutyl ester, n- octanol, silicone etc.；
The antifreezing agent can be selected：One or more in ethylene glycol, propane diols, glycerine etc.；
The stabilizer can be selected：Triphenyl phosphite, N- soybean oleyl trimethylene diamine, dialkyl group succinate
One or more in sulfonate, epoxychloropropane, butyl glycidyl ether etc.；
The preservative can be selected：One or more in benzoic acid, sodium benzoate etc.；
The pH adjusting agent can be selected：Hydrochloric acid, calgon, sodium citrate, sodium acid carbonate, sodium hydroxide, hydrogen-oxygen
One or more in agent, triethanolamine etc.；
The filler and/or carrier can be selected：Attapulgite, diatomite, kaolin, white carbon, bentonite, illiteracy are de-
One or more in stone, calcium carbonate, zeolite, acid clay, carclazyte, pyrophyllite, talcum, calcite etc..
The purposes that agricultural pests are prevented or controlled to another object of the present invention to provide above-mentioned Pesticidal combination to be used for.Example
It such as can effectively prevent and treat Lepidoptera, Diptera, coleoptera, Homoptera, Orthoptera, Hymenoptera, Isoptera, Siphonaptera, Blattaria, tassel
The agricultural pests such as tail mesh.
The composition is particularly effective to following insect：Diamondback moth, beet armyworm, lopper worm, tobacco budworm, peach
The vertical volume of aphid, cotten aphid, apple aphid, grain aphid, brown back rice plant hopper, small brown rice planthopper, Bemisia tabaci, Trialeurodes vaporariorum Westwood, leafhopper, rice green leafhopper, rice
Leaf snout moth's larva, bollworm, striped rice borer, yellow rice borer, scotinophora lurida, rice spiny coreid and Leptocorisa spp etc..
The composition is especially to diamondback moth, beet armyworm, lopper worm, bollworm, striped rice borer, yellow rice borer, cotten aphid etc.
Effectively, it is particularly effective to diamondback moth, beet armyworm.
Another object of the present invention for provide it is a kind of prevent or the method for control agricultural pests, specifically, by the present invention
The Pesticidal combination contacts with the agricultural pests, or active ingredient combination of the present invention or Pesticidal combination application
In the habitat of the agricultural pests or living environment.Specific application process can be foliar spray, seed treatment, at soil
Reason etc., preferably foliar spray；Its amount of application is that those skilled in the art can determine, such as 0.1-1000g ai./ha, excellent
Select 1-200g ai./ha, more preferably 10-50g ai./ha.
Various compounds and/or reagent used in the present invention are commercially available, easily can be bought from the market.
Beneficial effects of the present invention are shown：
A, synergistic effect is obvious, can reduce the dosage of two compositions；
B, proper control time is complementary, is more beneficial for the controlling mode of " seeing that worm is got rid of intestinal parasites by means of drugs "：Chlorine fluorine cyanogen insect amide is active high, anti-
The characteristics of property of medicine is low, the lasting period is long, there is good killing effect to low age worm and high instar larvae；Tolfenpyrad is to ovum and low age
Larva effect is preferable, and high dose need to be used to high instar larvae, has the characteristics of lasting effect is good, quick, and both are mixed it is contemplated that very
Good complementation；
C, the generation of resistance has been delayed：Both mechanisms of action and the mode of action are entirely different, to low age and height after combination
Instar larvae has good killing action, so as to delay the generation of resistance.
Embodiment
The present invention is further described with reference to specific embodiment, but does not limit the invention to these tools
Body embodiment.One skilled in the art would recognize that present invention encompasses may include in Claims scope
All alternatives, improvement project and equivalents.
（One）Example of formulations
The Tolfenpyrad microemulsion of 1 0.1% chlorine fluorine cyanogen insect amide of embodiment+10%
Chlorine fluorine cyanogen insect amide 0.1%
Tolfenpyrad 10%
Dimethylbenzene 8%
N-butanol 2%
Polyoxyethylene polyoxypropylene block polymer 10%
Lauryl sodium sulfate 7%
Polyvinyl alcohol 4%
N- octanol 1%
Propane diols 2%
Water supplies 100%
The above-mentioned each component of formula ratio is weighed respectively, then by pesticide activity component, solvent, cosolvent, surfactant
Oil phase is prepared by mixing into, other components are added to the water and are prepared into aqueous phase, then add oil phase into aqueous phase while stirring, is made
Microemulsion.
The Tolfenpyrad microemulsion of 2 8% chlorine fluorine cyanogen insect amide of embodiment+5%
Chlorine fluorine cyanogen insect amide 8%
Tolfenpyrad 5%
Toluene 7%
Ethanol 3%
Thermally coupled distillation columns amine salt 8%
Polyoxyethylene glyceryl mono fatty acid ester 9%
Sodium carboxymethylcellulose 3%
Phosphoric acid isobutyl ester 2%
Glycerine 3%
Butyl glycidyl ether 1%
Water supplies 100%
The above-mentioned each component of formula ratio is weighed respectively, then by pesticide activity component, solvent, cosolvent, surfactant
Oil phase is prepared by mixing into, other components are added to the water and are prepared into aqueous phase, then add oil phase into aqueous phase while stirring, is made
Microemulsion.
The Tolfenpyrad wettable powder of 3 18% chlorine fluorine cyanogen insect amide of embodiment+6%
Chlorine fluorine cyanogen insect amide 18%
Tolfenpyrad 6%
Calcium dodecyl benzene sulfonate 6%
NPE 3%
Diatomite supplies 100%
The above-mentioned each component of formula ratio is weighed respectively, and is mixed, grinds, crushes, and wettable powder is made.
The Tolfenpyrad wettable powder of 4 12% chlorine fluorine cyanogen insect amide of embodiment+20%
Chlorine fluorine cyanogen insect amide 12%
Tolfenpyrad 20%
Polyoxyethylene glyceryl mono fatty acid ester 7%
Trisiloxanes APEO 2%
Kaolin supplies 100%
The above-mentioned each component of formula ratio is weighed respectively, and is mixed, grinds, crushes, and wettable powder is made.
The Tolfenpyrad water dispersible granules of 5 4% chlorine fluorine cyanogen insect amide of embodiment+36%
Chlorine fluorine cyanogen insect amide 4%
Tolfenpyrad 36%
Naphthalene sulfonic acid-formaldehyde condensation product sodium 9%
Oleoyl methyl sodium taurocholate 6%
Carboxymethyl cellulose 3%
Ammonium sulfate 4%
Attapulgite supplies 100%
The above-mentioned each component of formula ratio is weighed respectively, and is mixed, is granulated, and water dispersible granules are made.
The Tolfenpyrad water dispersible granules of 6 40% chlorine fluorine cyanogen insect amide of embodiment+5%
Chlorine fluorine cyanogen insect amide 40%
Tolfenpyrad 5%
Naphthalene sulfonic acid-formaldehyde condensation product sodium salt 7%
Sorbitan aliphatic ester 8%
Arabic gum 4%
Urea 5%
Montmorillonite supplies 100%
The above-mentioned each component of formula ratio is weighed respectively, and is mixed, is granulated, and water dispersible granules are made.
The Tolfenpyrad suspending agent of 7 1% chlorine fluorine cyanogen insect amide of embodiment+19%
Chlorine fluorine cyanogen insect amide 1%
Tolfenpyrad 19%
Sodium lignin sulfonate 6%
Trisiloxanes APEO 4%
Arabic gum 3%
Silicone 1%
Ethylene glycol 2%
Water supplies 100%
The above-mentioned each component of formula ratio is weighed respectively, and by ultramicro grinding method, suspending agent is made.
The Tolfenpyrad suspending agent of 8 10% chlorine fluorine cyanogen insect amide of embodiment+0.1%
Chlorine fluorine cyanogen insect amide 10%
Tolfenpyrad 0.1%
Naphthalenesulfonate formaldehyde condensation compound 8%
Dioctyl sodium sulphosuccinate 6%
Castor oil polyoxyethylene ether 3%
Sodium carboxymethylcellulose 2%
Phosphoric acid isobutyl ester 2%
Propane diols 2%
Water supplies 100%
The above-mentioned each component of formula ratio is weighed respectively, and by ultramicro grinding method, suspending agent is made.
The Tolfenpyrad aqueous emulsion of 9 11% chlorine fluorine cyanogen insect amide of embodiment+4%
Chlorine fluorine cyanogen insect amide 11%
Tolfenpyrad 4%
Dimethylbenzene 8%
Neopelex 5%
Naphthalene sulfonic acid-formaldehyde condensation product sodium 2%
Arabic gum 2%
Butylphosphoric acid ester 1%
Propane diols 3%
Butyl glycidyl ether 1%
Water supplies 100%
The above-mentioned each component of formula ratio is weighed respectively, is then mixed with pesticide activity component, solvent, surfactant
Into oil phase, other components are added to the water and are prepared into aqueous phase, then add oil phase into aqueous phase while stirring, aqueous emulsion is made.
The Tolfenpyrad aqueous emulsion of 10 2% chlorine fluorine cyanogen insect amide of embodiment+17%
Chlorine fluorine cyanogen insect amide 2%
Tolfenpyrad 17%
Cyclohexanone 12%
Alkyl phenol formaldehyde resin polyoxyethylene ether 7%
Styrene-maleic acid salt copolymer 4%
Sodium carboxymethylcellulose 3%
N- octanol 2%
Ethylene glycol 4%
Water supplies 100%
The above-mentioned each component of formula ratio is weighed respectively, is then mixed with pesticide activity component, solvent, surfactant
Into oil phase, other components are added to the water and are prepared into aqueous phase, then add oil phase into aqueous phase while stirring, aqueous emulsion is made.
Proportioning is weight per distribution ratio in above example.
（Two）Biological test
Three kinds of situations occur after active compound：Antagonism, addition and synergistic effect, generally when activity
During the effect summation acted on when each reactive compound is administered alone of compound composition, you can think that active compound is deposited
In synergistic function.The predictive role of reactive compound is calculated by Colby formula（Calculating Synergistic
And Antagonistic Responses of Herbicide Combination ", Colby, S.R.；Weeds 15,20-
22,1967）：
X=is the killing rate when using active component A with m ppm amount of application, is expressed as the hundred of untreated control group
Divide ratio；
Y=is the killing rate when using active component B with n ppm amount of application, is expressed as the hundred of untreated control group
Divide ratio；
E=is the killing rate when using active component A and B with m and n ppm amount of application, is expressed as untreated control
The percentage of group.
If actual killing rate is higher than calculated value, the eradicative rate of conjugate has superadditivity, that is, synergy be present.
In this case, the killing rate actually observed, which must exceed, uses the counted expected killing rate (E) of above formula.Thus, if
It was observed that activity be more than active expected from Colby formula, then synergy be present.
The diamondback moth of biological test example 1 is tested
Material to be tested：Diamondback moth larvae
Medicament is prepared：Chlorine fluorine cyanogen insect amide, Tolfenpyrad active compound are dissolved with dimethylformamide respectively, are made into mother liquor,
It is standby.Used time, above-mentioned mother liquor is diluted to concentration with 5% lignin sulfonic acid sodium water solution.
Test method：With various medicaments of the deionized water containing 5% sodium lignin sulfonate respectively with 1 concentration of tabulation.Choosing
Healthy cabbage plant is taken, every plant is inoculated with 50 diamondback moths, then sprays the medicament of various concentration shown in table 1 respectively.Wherein, it is each
Individual concentration is a processing, and 10 plants of wild cabbages are selected in each processing, and it is consistent respectively to handle each repetition spray amount.After 7 days per treatment,
Death condition is investigated, finally calculates the death rate（Experiment is repeated 3 times, and is averaged）, the results are shown in Table 1.Wherein " observation killing rate "
For the actual killing rate observed, " theoretical killing rate " is the killing rate being calculated using Colby formula.
Effect test of the present composition of table 1 to diamondback moth
It is not difficult to find out by the data of table 1, in the present invention, chlorine fluorine cyanogen insect amide and Tolfenpyrad is compounded, diamondback moth is produced
Raw synergistic effect.
The beet armyworm of biological test example 2 is tested
Material to be tested：Beet armyworm
Medicament is prepared：Chlorine fluorine cyanogen insect amide, Tolfenpyrad active compound are dissolved with dimethylformamide respectively, are made into mother liquor,
It is standby.Used time, above-mentioned mother liquor is diluted to concentration with 5% lignin sulfonic acid sodium water solution.
Test method：With various medicaments of the deionized water containing 5% sodium lignin sulfonate respectively with 2 concentration of tabulation.Choosing
Healthy cabbage plant is taken, every plant is inoculated with 20 beet armyworms, then sprays the medicament of various concentration shown in table 2 respectively.Wherein, often
One concentration is a processing, and 10 plants of wild cabbages are selected in each processing, and it is consistent respectively to handle each repetition spray amount.At 7 days per treatment
Afterwards, death condition is investigated, finally calculates the death rate（Experiment is repeated 3 times, and is averaged）, the results are shown in Table 2.Wherein " observation is killed
Rate " is the actual killing rate observed, " theoretical killing rate " is the killing rate being calculated using Colby formula.
Effect test of the present composition of table 2 to beet armyworm
It is not difficult to find out by the data of table 2, in the present invention, chlorine fluorine cyanogen insect amide and Tolfenpyrad is compounded, to beet armyworm
Produce synergistic effect.
The Pesticidal combination of the present invention is described by specific embodiment.But examples detailed above is only to this
Being explained further for invention, is not limitation of the invention, as simply adjust obtained from such scheme
Scheme, without departing from the spirit of the present invention, it is regarded as being included within the scope of the present invention.
Claims (16)
1. a kind of Pesticidal combination containing chlorine fluorine cyanogen insect amide and Tolfenpyrad, it is characterised in that the Pesticidal combination contains
Active composition chlorine fluorine cyanogen insect amide and Tolfenpyrad, the weight ratio of the active component chlorine fluorine cyanogen insect amide and Tolfenpyrad are
100:1 to 1:100.
2. Pesticidal combination according to claim 1, it is characterised in that the active component chlorine fluorine cyanogen insect amide and azoles worm
The weight ratio of acid amides is 50:1 to 1:50.
3. Pesticidal combination according to claim 1, it is characterised in that the active component chlorine fluorine cyanogen insect amide and azoles worm
The weight ratio of acid amides is 20:1 to 1:20.
4. Pesticidal combination according to claim 1, it is characterised in that the active component chlorine fluorine cyanogen insect amide and azoles worm
The weight ratio of acid amides is 10:1 to 1:10.
5. Pesticidal combination according to claim 1, it is characterised in that the active component chlorine fluorine cyanogen insect amide and azoles worm
The weight ratio of acid amides is 5:1 to 1:5.
6. Pesticidal combination according to claim 1, it is characterised in that the Pesticidal combination includes claim 1 institute
The active component chlorine fluorine cyanogen insect amide and Tolfenpyrad stated, and agriculturally acceptable auxiliary agent and/or carrier.
7. Pesticidal combination according to claim 6, it is characterised in that the active component chlorine fluorine cyanogen insect amide and azoles worm
The weight content that acid amides is accounted in the Pesticidal combination is 1wt.% to 90wt.%.
8. Pesticidal combination according to claim 6, it is characterised in that the active component chlorine fluorine cyanogen insect amide and azoles worm
The weight content that acid amides is accounted in the Pesticidal combination is 10wt.% to 80wt.%.
9. Pesticidal combination according to claim 6, it is characterised in that the active component chlorine fluorine cyanogen insect amide and azoles worm
The weight content that acid amides is accounted in the Pesticidal combination is 12wt.% to 60wt.%.
10. Pesticidal combination according to claim 6, it is characterised in that the active component chlorine fluorine cyanogen insect amide and azoles
The weight content that insect amide is accounted in the Pesticidal combination is 25wt.% to 40wt.%.
11. Pesticidal combination according to claim 6, it is characterised in that be prepared into the Pesticidal combination agriculturally
Acceptable any formulation.
12. Pesticidal combination according to claim 6, it is characterised in that by the Pesticidal combination be prepared into missible oil,
Granula, wettable powder, water dispersible granules, suspending agent, microcapsule suspending agent, aqueous emulsion, microemulsion.
13. the Pesticidal combination described in claim 1 is used for the purposes for preventing or controlling agricultural pests.
14. purposes according to claim 13, it is characterised in that the agricultural pests are lepidoptera pest.
15. it is a kind of prevent or control agricultural pests method, it is characterised in that by the Pesticidal combination described in claim 1 with
Agricultural pests contact.
16. according to the method for claim 15, it is characterised in that by the Pesticidal combination described in claim 1 using extremely
The habitat of agricultural pests.
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| CN102302009A (en) * | 2011-07-12 | 2012-01-04 | 江苏龙灯化学有限公司 | Pesticide composition including Flubendiamide and tolfenpyrad and application thereof |
| CN102613183A (en) * | 2012-03-07 | 2012-08-01 | 中化蓝天集团有限公司 | Insecticide |
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| CN102302009A (en) * | 2011-07-12 | 2012-01-04 | 江苏龙灯化学有限公司 | Pesticide composition including Flubendiamide and tolfenpyrad and application thereof |
| CN102613183A (en) * | 2012-03-07 | 2012-08-01 | 中化蓝天集团有限公司 | Insecticide |
Non-Patent Citations (1)
| Title |
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| 新型杀虫剂氯氟氰虫酰胺对不同鳞翅目害虫的毒力和田间防效;邢家华等;《农药学学报》;20131231;第15卷(第2期);159-164 * |
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