CN101406195B - Composition containing ethiprole and avermectin with synergistic disinsection function - Google Patents

Composition containing ethiprole and avermectin with synergistic disinsection function Download PDF

Info

Publication number
CN101406195B
CN101406195B CN2008101815127A CN200810181512A CN101406195B CN 101406195 B CN101406195 B CN 101406195B CN 2008101815127 A CN2008101815127 A CN 2008101815127A CN 200810181512 A CN200810181512 A CN 200810181512A CN 101406195 B CN101406195 B CN 101406195B
Authority
CN
China
Prior art keywords
avermectin
worm nitrile
rice
worm
medicine
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN2008101815127A
Other languages
Chinese (zh)
Other versions
CN101406195A (en
Inventor
罗才宏
朱卫锋
孔建
曹明章
李谱超
陈树茂
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shenzhen Noposion Agrochemicals Co Ltd
Original Assignee
Shenzhen Noposion Agrochemicals Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shenzhen Noposion Agrochemicals Co Ltd filed Critical Shenzhen Noposion Agrochemicals Co Ltd
Priority to CN2008101815127A priority Critical patent/CN101406195B/en
Publication of CN101406195A publication Critical patent/CN101406195A/en
Application granted granted Critical
Publication of CN101406195B publication Critical patent/CN101406195B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Abstract

The invention relates to a pesticide composition. The main components of the pesticide composition consist of ethiprole and avermectin, wherein the weight percentage of the ethiprole to the avermectin is between 40 to 1 and 1 to 1. The two active ingredients are prepared into emulsifiable solution, suspending agents, water emulsion, and water dispersible granules for controlling pests in agriculture. The pesticide composition is particularly suitable for controlling rice planthoppers, rice chilo suppressalis and cruciferous vegetable diamond back moths. The effect of the pesticide compositionis significantly higher than that of a singly-used agent.

Description

Contain the composition that second worm nitrile and Avermectin have synergistic insecticidal action
Technical field
The composition pesticide that this invention relates to is to be active ingredient with second worm nitrile and Avermectin, prevents and treats the insect on the agricultural.Especially be suitable for preventing and treating rice hoppers, rice leaf roller and diamond-back moth.
Technical background
Second worm nitrile, English general ethiprole by name.Be a kind of novel pyrazole insecticides, insecticidal spectrum is wide.By disturbing the chloride channel of γ-An Jidingsuan (GABA) mediation, insect is caused death thereby destroy central nervous system (CNS) normal activity.Is this medicine to the white clothing constraint of insect GABA chloride channel? the comparison vertebrate is tightr, thereby very high selection toxicity is provided.Its mechanism of action is different from main insecticide families such as pyrethroid, organic phosphor, carbamate, does not almost produce the chance of interactivity with the existing insecticide of majority.Therefore, it is the desirable reserve kind of resistance management, can be with the mixed pesticide of other chemical family, be used alternatingly.
Avermectin, English general abamectin by name.Avermectin is a kind of macrolide disaccharide compounds, is the natural products that separates from edaphon, insect and mite class is had tag and stomach poison function and faint fumigation action is arranged.It has very strong osmosis to blade, can kill subepidermal insect, and the longevity of residure is long.What its mechanism of action was different with general insecticide is that it disturbs the neurophysiology activity, stimulate and discharge gamma-aminobutyric acid, and gamma-aminobutyric acid has inhibitory action to arthropodan nerve conduction, the mite class becomes, if mite and insect larvae with paralysis symptom promptly appears after medicament contacts, inertia is not got food.Because of not causing that insect dewaters rapidly, so its lethal effect is slower.Though predatism and parasite there are direct killing effect, because of plant surface is residual few, therefore little to the damage of beneficial insect.
In the real process of agricultural production, chemical control is the main effective means of pest control.The problem that the chemical control insect is easy to generate most is the generation of pest resistance to insecticide.Be easy to generate normally big, the tangible insect of generation overlap of breeding amount of drug-fast insect.As plant hopper, aphid, two spotted spider mite, diamond-back moth etc.
Rice hoppers is one of paddy rice three major pests, the main harm paddy rice, and can propagate the paddy rice virus disease, often cause crushing disaster.Rice hoppers even can migrate at a distance is the important pests on the state paddy rice such as China and South Asia, Southeast Asia, Japan.In some serious zone, the phoxim in conventional pesticide composition such as the organic phosphor, the Mobucin of carbamates etc., control has not almost had any effect separately.
The paddy rice rice leaf roller belongs to Lepidoptera Pyralidae insect, also is one of paddy rice three major pests, all endangers seriously in rice belt, China north and south, bore moth paddy rice cane with larva, cause withered heart seedling or dead ears, paddy rice easily lodges, empty flat rate increases, and thousand kernel weight reduces, and can cause the serious underproduction.Mainly used high-toxic pesticide acephatemet and parathion control rice leaf roller in China in the past.China forbade 5 kinds of high-toxic pesticides in 2007 after the use on the paddy rice, and the control of paddy rice rice leaf roller becomes a difficult problem.Alternative medicaments such as Hostathion commonly used are lower to the vertical volume of rice activity, and pyrethrin pesticide is not recommended on the paddy rice and uses the high poison of fish.Because the generation of resistance, dimehypo commonly used, desinsection list typical concentrations use what effect it has not been had.
Diamond-back moth is the first insect that China south vegetables produce.It is mainly caused harm by the larval feeding blade.Blade is reticulated by food when serious, reduces edibility, influences economic benefit.Because its generation overlap is very serious, so this insect comes very soon to the resistance of medicament.Some of control diamond-back moth commonly used in the past are medicament such as Avermectin, beta-cypermethrin, phoxim etc. efficiently, and it is invalid to use separately now.Can only use expensive imported product to prevent and treat now, cost is very high.
Go up the insect that produces resistance for control agricultural, a kind of way is to release the new component that new and existing kind do not have cross resistance.But, the development cost height of new active ingredient, the construction cycle is long, and all produces the speed of resistance forever less than insect.Other method such as crop allocation adjustment, different agricultural chemicals are rotated etc., in the process of practical operation, are difficult to really play obvious effects.
It is control resistant insect or the very common way of evil mite that different classes of kind is carried out composite.Heterogeneity is carried out composite, according to the effect of biologicall test and practical application, judge certain composite be synergy, add and or antagonism.Compound synergic is well filled a prescription, owing to obviously improved actual control efficiency, reduced the usage amount of agricultural chemicals, simultaneously different classes of effective ingredient, its effect characteristics have nothing in common with each other, the mechanism of action, also different to the action site of insect, thus delayed the generation of pest resistance to insecticide greatly, be the important means of integrated control insect.
Have the second worm nitrile of synergistic effect and the composite and application of Avermectin at present and still do not have report.
Summary of the invention
The present invention is by a large amount of biologicall test screenings, be surprised to find that second worm nitrile and Avermectin are composite with certain proportion, insects such as antagonism property of medicine rice fulgorid, striped rice borer, diamond-back moth have remarkable synergistic effect, and second worm nitrile and abamectin compounded mass ratio are between 40:1-1:1; The prescription of these synergy is processed into the preparation of dosage forms by present known method, and suitable formulation comprises missible oil, suspending agent, aqueous emulsion, microemulsion, water dispersible granules etc., and the total content of active ingredient is 1-70% in the preparation.
Go up insects such as producing resistance rice planthopper, striped rice borer, diamond-back moth in order to prevent and treat agricultural, we have carried out mutual composite synergy research with compositions such as second worm nitrile, Avermectin.It is tested object that rice fulgorid, striped rice borer, diamond-back moth are adopted in test, and concrete grammar is:
1) the former medicine of rice fulgorid (brown planthopper Nilaparvata lugens) test medicine second worm nitrile adopts the former medicine that Bayer crop science company produces, the former medicine that the former medicine of Avermectin adopts Hebei Weiyuan Biochemical Co., Ltd. to produce.Former medicine is mixed with the test medicine that needs by my research department of company.Test method is with reference to " the agricultural industry criteria NY/T1154.7-2006 of the People's Republic of China (PRC) ".The examination worm is rice fulgorid (brown planthopper) pupa that picks up from the field, the water rice seedling is raised the three generations in the greenhouse, select the growth even one to four age nymph, insert to put the culture dish of 12 centimetres of the diameters of the tender seedling of paddy rice (with the cotton ball processing of preserving moisture), every ware connects and anaesthetizes 30 of nymphs, and every processing connects 5 wares, sprays under 50PSI pressure with the potter spray tower, ware of each spray, 3 milliliters of every ware spraying liquids.General each processing is provided with 6-7 concentration gradients.After treating that insect revives, the culture dish of handling is put into 25 ℃, cultivate in the 12H/12H illumination box, checked in 48 hours and to calculate lethality by dead borer population.Blank spray equivalent clear water.Carry out statistical analysis with the DPS data processing software, calculate the LC50 of each medicament, estimate the activity of reagent agent the examination worm with this.
The co-toxicity coefficient of mixture (CTC value) calculates by following formula:
AT 1 = S M x 100
In the formula:
AT1---mixture actual measurement toxicity index;
The LC50 of S---standard insecticide, unit are every liter (mg/l) of milligram;
The LC50 of M---mixture, unit are every liter (mg/l) of milligram;
TTI=TIAxPA+TIBxPB
In the formula:
The theoretical toxicity index of TTI---mixture;
TIA----A medicament toxicity index;
The percentage composition of PA-----A medicament in mixture, unit are percentage;
TIB----B medicament toxicity index;
The percentage composition of PA-----B medicament in mixture, unit are percentage.
CTC = AT 1 TTI x 100
In the formula:
The CTC----co-toxicity coefficient;
AT1---mixture actual measurement toxicity index;
The theoretical toxicity index of TTI---mixture.
Composite dose co-toxicity coefficient (CTC) 〉=120 shows as synergistic effect; CTC≤80 show as antagonism; 80<CTC<120 show as summation action.
2) the former medicine of striped rice borer (striped rice borer Chilo supperssalis (Walker)) test medicine second worm nitrile adopts the former medicine that Bayer crop science company produces, the former medicine that the former medicine of Avermectin adopts Hebei Weiyuan Biochemical Co., Ltd. to produce.Former medicine is mixed with the test medicine that needs by my research department of company.Test method is with reference to " the agricultural industry criteria NY/T1154.7-2006 of the People's Republic of China (PRC) ".The examination worm is the striped rice borer pieces of an egg that pick up from the field, and indoor rice seedling is raised, and adopts the larva of first generation hatching.Select the larva of growth uniformity, the culture dish that the diameter of the fresh rice bar of access storing is 12 centimetres.Every ware is put into 10 striped rice borer.5 wares of every processing.Spray under 50PSI pressure with the Potter spray tower.Culture dish of each spray, 3 milliliters of every ware spraying liquids.Sprayed the back and fast put into 25 ℃ behind the airing rice bar, cultivated in the 12H/12H illumination box, checked in 48 hours and to calculate lethality by dead borer population.Blank spray equivalent clear water.General each processing is provided with 6 concentration gradients.Statistical analysis technique is the same.
3) the former medicine of diamond-back moth (diamond-back moth Plutella xylostella) test medicine second worm nitrile adopts the former medicine that Bayer crop science company produces, the former medicine that the former medicine of Avermectin adopts Hebei Weiyuan Biochemical Co., Ltd. to produce.Former medicine is mixed with the test medicine that needs by my research department of company.Test method is with reference to " the agricultural industry criteria NY/T1154.7-2006 of the People's Republic of China (PRC) ".Resistance examination worm is picked up from the pupa of the diamond-back moth in field, and indoor Turnip Sprouts are raised the larva of first generation hatching.Select the third-instar larvae of growth uniformity, the culture dish that the diameter of the fresh a variety of Chinese cabbage of access storing is 12 centimetres.Every ware is put into 30 diamondback moth larvaes.5 wares of every processing.Spray under 50PSI pressure with the Potter spray tower.Culture dish of each spray, 3 milliliters of every ware spraying liquids.Sprayed the back and fast put into 25 ℃ behind the airing Chinese cabbage leaf, cultivated in the 12H/12H illumination box, checked in 48 hours and to calculate lethality by dead borer population.Sensitive strain adopt to give birth to is surveyed the chamber and is raised the sensitive population in 20 generations with Turnip Sprouts, and test method is the same with the resistant strain test method.Blank spray equivalent clear water.General each processing is provided with 6 concentration gradients.Statistical analysis technique is the same.
4) measurement result of rice fulgorid, rice leaf roller, diamond-back moth see Table 1 respectively, table 2 and table 3.
Table 1 different disposal is to the toxicity test result of rice fulgorid
Handle LC 50(mg/L) AT1 TTI Co-toxicity coefficient CTC
Second worm nitrile 22.22 100.00
Avermectin 1.02 2178.43
Second worm nitrile 1+ Avermectin 1 1.23 1806.50 1139.22 158.57
Second worm nitrile 5+ Avermectin 1 1.87 1188.24 446.41 266.18
Second worm nitrile 10+ Avermectin 1 2.51 885.26 288.95 306.37
Second worm nitrile 20+ Avermectin 1 3.21 692.21 198.97 347.89
Second worm nitrile 40+ Avermectin 1 5.02 442.63 150.69 293.73
Table 2 different disposal is to the toxicity test result of striped rice borer
Handle LC 50(mg/L) AT1 TTI Co-toxicity coefficient CTC
Second worm nitrile 4.35 100.00
Avermectin 0.84 517.86
Second worm nitrile 1+ Avermectin 1 0.65 669.23 308.93 216.63
Second worm nitrile 5+ Avermectin 1 0.71 612.68 169.64 361.16
Second worm nitrile 10+ Avermectin 1 0.82 530.49 137.99 384.45
Second worm nitrile 20+ Avermectin 1 1.54 282.47 119.90 235.59
Second worm nitrile 40+ Avermectin 1 1.88 231.38 110.19 209.98
Table 3 different disposal is to the toxicity test result of diamond-back moth
Handle (sensitive strain S) LC 50(mg/L) Resistance index AT1 TTI Co-toxicity coefficient CTC
Second worm nitrile (S) 10.21 100.00
Avermectin (S) 0.45 2268.89
Second worm 1+ Avermectin 1 (S) 0.55 1856.36 1184.44 156.73
Second worm nitrile 5+ Avermectin 1 (S) 1.21 843.80 461.48 182.85
Second worm nitrile 10+ Avermectin 1 (S) 2.01 507.96 297.17 170.93
Second worm nitrile 20+ Avermectin 1 (S) 2.88 354.51 203.28 174.40
Second worm nitrile 40+ Avermectin 1 (S) 4.21 242.52 152.90 158.61
Handle (resistant strain R) LC 50(mg/L) AT1 TTI Co-toxicity coefficient CTC
Second worm nitrile (R) 10.88 1.07 100.00
Avermectin (R) 22.24 49.42 48.92
Second worm nitrile 1+ Avermectin 1 (R) 6.25 174.08 74.46 233.79
Second worm nitrile 5+ Avermectin 1 (R) 3.88 280.41 91.49 306.51
Second worm nitrile 10+ Avermectin 1 (R) 2.84 383.10 95.36 401.75
Second worm nitrile 20+ Avermectin 1 (R) 2.56 425.00 97.57 435.60
Second worm nitrile 40+ Avermectin 1 (R) 3.65 298.08 98.75 301.84
As seen from Table 1, second worm nitrile and abamectin compounded has very high synergistic effect to rice fulgorid.Co-toxicity coefficient can reach more than 150 when second worm nitrile and Avermectin proportioning were 40-1:1.
As seen from Table 2, second worm nitrile and abamectin compounded, the synergistic effect very high to rice leaf roller.Co-toxicity coefficient can reach more than 200 when second worm nitrile and Avermectin proportioning were 40-1:1.
As seen from Table 1, second worm nitrile and abamectin compounded has higher synergistic effect to diamond-back moth.Especially the synergy of antagonism diamond-back moth is more obvious.Co-toxicity coefficient can reach more than 150 when sensitive strain second worm nitrile and Avermectin proportioning were 40-1:1.Co-toxicity coefficient can reach more than 230 when antagonism strain second worm nitrile and Avermectin proportioning were 40-1:1.
Embodiment
One: 11% second worm of embodiment nitrile abamectin emulsifiable concentrate
Second worm nitrile 10%
Avermectin 1%
Calcium dodecyl benzene sulfonate 3%
OPEO 4%
Isopropyl alcohol 4%
Dimethylbenzene to 100%
Active component, emulsifier and the auxiliary agent ratio in prescription is added in the blender successively, stir, make 11% second worm nitrile abamectin emulsifiable concentrate.
11% second worm nitrile abamectin emulsifiable concentrate is sprayed by 15 gram/mu thin ups, 72 hours control efficiency are 95.3% behind the medicine, 20% second worm nitrile suspending agent and 1.8% abamectin emulsifiable concentrate are according to using with quadrat method, and 72 hours preventive effects are respectively 69.3% and 73.2% behind the medicine.
Two: 22% second worms of embodiment nitrile Avermectin suspending agent
Second worm nitrile 20%
Avermectin 2%
Alkylaryl polyoxyethylene polyoxypropylene ether 2%
Poly-naphthaldehyde sulfonate sodium 3%
Ethylene glycol 4%
Xanthans 0.8%
Water to 100%
Active component, dispersant, wetting agent and the water ratio in prescription is mixed, after high speed shear, obtain 22% second worm nitrile Avermectin suspending agent.
22% second worm nitrile Avermectin suspending agent is sprayed by 10 gram/mu thin ups, 72 hours control efficiency are 96.8% behind the medicine, 20% second worm nitrile suspending agent and 1.8% abamectin emulsifiable concentrate are according to using with quadrat method, and 72 hours preventive effects are respectively 64.3% and 75.0% behind the medicine.
Three: 55% second worms of embodiment nitrile Avermectin water dispersible granules
Second worm nitrile 50%
Avermectin 5%
Sodium lignin sulfonate 3%
PO-EO block polyether 1%
Sodium alkyl benzene sulfonate 2%
Urea 5%
Precipitated calcium carbonate to 100%
Active component, dispersant, wetting agent, disintegrant and the filler ratio in prescription is mixed, become wetting powder, add a certain amount of water mixing extruding again and make material through comminution by gas stream.Obtain 55% second worm nitrile Avermectin water dispersible granules after the drying screening.
This prescription is sprayed by 3 gram/mu thin ups, and 72 hours control efficiency are 93.3%, 10% second worm nitrile suspending agent agent and 1.8% abamectin emulsifiable concentrate according to the quadrat method use behind the medicine, and 72 hours preventive effects are respectively 66.8% and 75.3% behind the medicine.
Four: 21% second worms of embodiment nitrile abamectin aqueous emulsion
Second worm nitrile 20%
Avermectin 1%
Calcium dodecyl benzene sulfonate 5%
Phenol formaldehyde resin APEO 2%
Xanthans 1%
Deionized water to 100%
Active component, emulsifier and the thickener ratio in prescription is added in the blender successively, stir, make 11% second worm nitrile abamectin aqueous emulsion.
21% second worm nitrile abamectin aqueous emulsion is by the spraying of 10 gram/mu thin ups, 72 hours control efficiency are 96.8% behind the medicine, 20% second worm nitrile suspending agent agent and 1.8% abamectin emulsifiable concentrate are according to using with quadrat method, and 72 hours preventive effects are respectively 71.1% and 76.2% behind the medicine.

Claims (3)

1. composition pesticide, effective ingredient is made up of second worm nitrile and Avermectin, and the mass ratio of second worm nitrile and Avermectin is 40: 1-1: between 1.
2. the composition of mentioning in the claim 1 is made missible oil, suspending agent, aqueous emulsion, water-dispersible granules during practical application.
3. composition according to claim 2 is characterized in that effective ingredient second worm nitrile and the mass percentage content of Avermectin in composition are between 1%-70%.
CN2008101815127A 2008-11-20 2008-11-20 Composition containing ethiprole and avermectin with synergistic disinsection function Active CN101406195B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN2008101815127A CN101406195B (en) 2008-11-20 2008-11-20 Composition containing ethiprole and avermectin with synergistic disinsection function

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN2008101815127A CN101406195B (en) 2008-11-20 2008-11-20 Composition containing ethiprole and avermectin with synergistic disinsection function

Publications (2)

Publication Number Publication Date
CN101406195A CN101406195A (en) 2009-04-15
CN101406195B true CN101406195B (en) 2011-12-07

Family

ID=40569583

Family Applications (1)

Application Number Title Priority Date Filing Date
CN2008101815127A Active CN101406195B (en) 2008-11-20 2008-11-20 Composition containing ethiprole and avermectin with synergistic disinsection function

Country Status (1)

Country Link
CN (1) CN101406195B (en)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101700017B (en) * 2009-08-01 2012-08-15 深圳诺普信农化股份有限公司 Ethiprole emulsion in water and preparation method thereof
CN102027926A (en) * 2011-01-06 2011-04-27 北京燕化永乐农药有限公司 Pesticidal composition of ethiprole and spinosad
CN103355320A (en) * 2012-04-09 2013-10-23 陕西韦尔奇作物保护有限公司 Efficient environment-friendly pesticide compound composition
CN104522006B (en) * 2014-12-19 2016-10-05 湖南化工研究院有限公司 A kind of preventing and treating Lepidoptera and homoptera pest compositions
CN105028441B (en) * 2015-02-12 2017-06-09 四川利尔作物科学有限公司 Insecticide acaricide composition and its application

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102004010716A1 (en) * 2003-03-18 2004-08-12 Syngenta Participations Ag New synergistic herbicidal composition, useful for total or selective weed control, contains 5-hydroxypyrazole derivative and, as synergist, an insecticidal or acaricidal agent
CN101160051A (en) * 2005-02-22 2008-04-09 拜尔农作物科学股份公司 Active ingredient combinations having insecticide and acaricide properties

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102004010716A1 (en) * 2003-03-18 2004-08-12 Syngenta Participations Ag New synergistic herbicidal composition, useful for total or selective weed control, contains 5-hydroxypyrazole derivative and, as synergist, an insecticidal or acaricidal agent
CN101160051A (en) * 2005-02-22 2008-04-09 拜尔农作物科学股份公司 Active ingredient combinations having insecticide and acaricide properties

Non-Patent Citations (4)

* Cited by examiner, † Cited by third party
Title
.阿维菌素的混配及混用.《新农业》.2007,(第3期),第47页.
刘延军
刘延军;郭英阅;.阿维菌素的混配及混用.《新农业》.2007,(第3期),第47页. *
郭英阅

Also Published As

Publication number Publication date
CN101406195A (en) 2009-04-15

Similar Documents

Publication Publication Date Title
CN102113516B (en) Insect killing compound containing chlorantraniliprole
CN101406195B (en) Composition containing ethiprole and avermectin with synergistic disinsection function
CN105941451A (en) Insecticide composition containing chromafenozide and neonicotinoid
CN103004867B (en) Insecticidal composition with synergism
CN102379308A (en) Mixed insecticidal composition containing clothianidin and application of mixed insecticidal composition
CN101322493A (en) Insecticidal composition containing spinosad and emamectin-benzoate
CN101647434A (en) Pesticide composition having synergistic function and application thereof
CN104996458B (en) Composition pesticide and its application
CN102228056B (en) Pesticide composition containing sulfur-fluorine oxime ether and part of organophosphorus pesticides
CN101589720A (en) A kind of insecticides that contains indenes worm prestige
CN101617676B (en) Pesticide compound
CN101485329B (en) Agricultural chemical composition for disinsection and use thereof
CN101356919B (en) Composition containing ethiprole and nitenpyram with synergistic insecticidal activity
CN104186554A (en) Compounded biological insecticide of pyrethrin and acillus thuringiensis and application of compounded biological insecticide
CN102217623B (en) Pesticide composition containing chlorbenzuron and flubendiamide
CN102027967B (en) Pesticide composition containing pyriproxyfen and metaflumizone and application thereof
CN102484994B (en) Synergy composition of matrine and chlorantraniliprole
CN101690493B (en) Pesticide composition of thiamethoxam and application thereof
CN106879609A (en) A kind of Pesticidal combination containing doractin and Nylar
CN103518773B (en) Insecticidal composition with synergism
CN101480185B (en) Pesticide composition with synergistic insecticidal action and use thereof
CN105104396B (en) A kind of composition pesticide containing rosickyite azoles and amino-oligosaccharide
CN101708002A (en) Synergistic pesticide composition and application thereof
CN101444215A (en) Desinsection composite and application thereof
CN103503896A (en) Insecticide composition having synergistic effect

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant