CN104186471B - A kind of composition pesticide containing chlorine fluorine cyanogen insect amide and methoxyfenozide - Google Patents
A kind of composition pesticide containing chlorine fluorine cyanogen insect amide and methoxyfenozide Download PDFInfo
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- CN104186471B CN104186471B CN201410379684.0A CN201410379684A CN104186471B CN 104186471 B CN104186471 B CN 104186471B CN 201410379684 A CN201410379684 A CN 201410379684A CN 104186471 B CN104186471 B CN 104186471B
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- methoxyfenozide
- chlorine fluorine
- insect amide
- fluorine cyanogen
- cyanogen insect
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Abstract
The invention discloses a kind of composition pesticide containing chlorine fluorine cyanogen insect amide and methoxyfenozide, active ingredient is chlorine fluorine cyanogen insect amide and methoxyfenozide, and remaining is conventional pesticidal preparations auxiliary element, and the weight ratio of chlorine fluorine cyanogen insect amide and methoxyfenozide is 10:1~1:10.Composition pesticide of the present invention has obvious synergistic function, prevention effect is substantially better than single dose exclusive use, while reduces Pesticide use amount, reduces residual quantity of the agricultural chemicals on crops, the pollution to environment is alleviated, has delayed the drug-fast generation of pest and disease damage.
Description
Technical field
The present invention relates to composition pesticide and its application field, and specifically one kind is with chlorine fluorine cyanogen insect amide and methoxy worm
Hydrazides is active ingredient composition pesticide, the Lepidoptera class pest being mainly used on preventing and treating crops.
Background technology
Chlorine fluorine cyanogen insect amide is phthalic diamides novel pesticide, is mainly used in preventing and treating Lepidoptera children on crops
Worm, there is good prevention effect to diamondback moth, striped rice borer, rice leaf roller.
Methoxyfenozide is a kind of novel specific benzoyl hydrazine low toxic pesticide, there is height to select lepidoptera pest
Insecticidal activity, based on action of contace poison, and there is certain systemic action.The medicine category biomimetic type moulting hormone class.Pests
After medicament, that is, produce husking reaction and start to cast off a skin, larva dehydration, hungry and dead is caused due to that can not cast off a skin completely.The medicine
The mechanism of action for the medicament casted off a skin with suppressing insect in the whole larval phase medication of insect on the contrary, can be prevented and treated.Methoxyfenozide
It is mainly used in preventing and treating the larva of lepidoptera pest, as beet armyworm, lopper worm, prodenia litura, dish agree worm, bollworm, Jin Wen
Thin moth, fall webworms, pine moth, looper and snout moth's larva of rice etc., applicable crops for example brassicaceous vegetable, solanaceous vegetables, it is melon,
Cotton, apple, peach, rice, forest etc..
The present inventor has made intensive studies to the screening of the compounded formula of chlorine fluorine cyanogen insect amide and methoxyfenozide, unexpectedly
It was found that chlorine fluorine cyanogen insect amide and methoxyfenozide are compounded, there is obvious Synergistic in the range of certain compound proportion
Effect, in actual use, has outstanding preventive effect to the lepidoptera pest on crops, after further study, completes
The present invention.
The content of the invention
The purpose of the present invention is that the different chlorine fluorine cyanogen insect amide of the mechanism of action and methoxyfenozide are carried out into mixture, makes to mix
The preventive effect of agent gets a promotion, and drug effect is more lasting, avoids the use of single agricultural chemicals, causes the generation of resistance, so as to reduce agricultural chemicals
Usage amount, lower Pesticide use during to caused by environment negative effect.
Technical scheme：A kind of composition pesticide containing chlorine fluorine cyanogen insect amide and methoxyfenozide, with chlorine fluorine
Cyanogen insect amide and methoxyfenozide are active ingredient, and the weight ratio of chlorine fluorine cyanogen insect amide and methoxyfenozide is 10:1~1:10,
The percentage by weight of chlorine fluorine cyanogen insect amide and the weight summation of methoxyfenozide in the composition is 0.1%~85%, and remaining is
Allow to use and acceptable auxiliary element in agricultural chemicals.
Described auxiliary element is solvent, emulsifying agent, wetting agent, dispersant, stabilizer, antifreezing agent, thickener, disintegration
One or more kinds of combinations in agent, binding agent, defoamer, bleeding agent, synergist, fire retardant and filler, above material
It is the known substance commonly used in pesticidal preparations, is varied from according to the different formulations of pesticide are prepared into, but have no special limit
It is fixed.
Composition pesticide of the present invention can be prepared into a variety of application forms for being adapted to agriculturally use, and relatively good formulation has
Suspending agent, water dispersible granules, wettable powder.
The production technology of the various application forms of described composition pesticide belongs to existing known technology, will not be repeated here.
Product described in the invention can be provided in the form of finished product preparation, i.e., each material is blended in composition, group
The composition of compound can also single dose form provide, directly mixed using preceding in tank or bucket, be then diluted to required for it is dense
Degree.The frequency of administration and amount of application of the present composition change and changed with weather condition and crop condition.
The beneficial effects of the present invention are：
1st, chlorine fluorine cyanogen insect amide and methoxyfenozide mixed synergies are obvious, and drug effect is greatly improved, and dosage is bright
It is aobvious to reduce, so as to reduce use cost, reduce the residual of agricultural chemicals and the pollution to environment.
2nd, field test observation during it was also found that this formula processing above-mentioned formulation, lasting medicine, effectively
Delay the rising repeatedly of insect population number, reduced spraying times, reduce the Productive statistics of peasant household to a certain extent.
Embodiment
Essence for a better understanding of the present invention, present disclosure is described further with reference to embodiment,
But limitation of the present invention can not be considered as, it is as described below to be only used for explaining the present invention, for without departing from spirit of the invention and principle
Modification, replacement or the improvement made, belong to the scope of protection of present invention.
Embodiment one：Indoor biological determination of activity.
Active compound is made into missible oil to test indoor feeding striped rice borer, Experimental Method in Laboratory is with reference to Wu Wenjun《Vegetalization
Learn Protection technology introduction》(1993) carry out, by calculating the co-toxicity coefficient (CTC) of different complex preparations to different ratios
Drug effect comparison is carried out, so that it is determined that going out the best mixed proportion of effect.Result of the test is with reference to following table.
Table 1, chlorine fluorine cyanogen insect amide, methoxyfenozide mixture are to the toxicity test result of rice-stem borer
The toxicity index of each medicament and the co-toxicity coefficient (CTC values) of mixture are calculated according to the abundant methods of Sun Yun, when CTC≤80 are
Antagonism, 80 ﹤ CTC ﹤ 120 are summation action, and CTC >=120 are synergistic effect.
It can be seen from table 1, chlorine fluorine cyanogen insect amide, methoxyfenozide are with 1:10-10:After 1 ratio compounding, rice two is changed
Snout moth's larva shows synergistic effect.
Embodiment two：25% chlorine fluorine cyanogen insect amide methoxyfenozide wettable powder.
Above-mentioned material is mixed, is well mixed again through air-flow crushing after mechanical crushing, you can 25% chlorine fluorine cyanogen worm acyl is made
Amine methoxyfenozide wettable powder.
The embodiment is used to prevent and treat rice terrace striped rice borer, and test site is Huizhou, and test period is 2013 5
Month, striped rice borer endangers peak period dispenser, using spray pesticide mode.With 5% Rynaxypyr suspending agent, 1000 times of liquid and 24%
1000 times of liquid of methoxyfenozide suspending agent are comparison medicament, 25% chlorine fluorine cyanogen insect amide methoxyfenozide wettable powder 2000
Times liquid even spraying, 3d preventive effects are respectively 81.2%, 83.9%, 89.7% after medicine.Experiment proves 25% chlorine fluorine cyanogen worm acyl
Amine methoxyfenozide wettable powder is better than corresponding single dose to the preventive effect of striped rice borer.
Embodiment three：40% chlorine fluorine cyanogen insect amide methoxyfenozide water dispersible granules.
Above-mentioned material is well mixed, crushed with micro jet, through mediating, fluidized bed prilling is then added and dries
It is granulated, dried, sieved in machine, you can 40% chlorine fluorine cyanogen insect amide methoxyfenozide water dispersible granules is made.
The embodiment is used to prevent and treat rice terrace striped rice borer, and test site is Sichuan Guangyuan city, and test period is 2013 9
Month, striped rice borer endangers peak period dispenser, using spray pesticide mode.With 5% Rynaxypyr suspending agent, 1000 times of liquid and 24%
1000 times of liquid of methoxyfenozide suspending agent are comparison medicament, and with above-mentioned 2000 times of liquid even sprayings of medicament, 3d preventive effects are distinguished after medicine
For 85.4%, 84.1%, 86.8%.Experiment proves 40% chlorine fluorine cyanogen insect amide methoxyfenozide water dispersible granules to rice two
The preventive effect for changing snout moth's larva is better than corresponding single dose.
Example IV：30% chlorine fluorine cyanogen insect amide methoxyfenozide suspending agent.
It is the high dispersive that is formed in water-medium, stable by above-mentioned material through high speed shear is scattered, is sanded in sand mill
Suspension system, you can 30% chlorine fluorine cyanogen insect amide methoxyfenozide suspending agent is made.
The embodiment is used to prevent and treat wild cabbage diamondback moth, and test site is Huizhou City of city of Guangdong Province, and test period is 2013 8
Month, wild cabbage diamondback moth egg hatching peak period dispenser, using spray pesticide mode.With 5% Rynaxypyr suspending agent, 1000 times of liquid
It is comparison medicament with 24% methoxyfenozide suspending agent, 1000 times of liquid, with 30% Rynaxypyr methoxyfenozide suspending agent
2000 times of liquid even sprayings, 3d preventive effects are respectively 81.7%, 86.3%, 91.6% after medicine.Experiment proves 30% chlorine fluorine cyanogen worm acyl
Amine methoxyfenozide suspending agent is better than corresponding single dose to the preventive effect of wild cabbage diamondback moth.
Shown by indoor biometricses experiment and outdoor field test, chlorine fluorine cyanogen insect amide and methoxyfenozide compounding are to rice
Striped rice borer, wild cabbage diamondback moth have higher preventive effect, in actual use, in the case where the amount of mixture is reduced than the amount of single dose,
Preventive effect is still very high, therefore is a kind of pesticidal preparations being worthy to be popularized.
Claims (4)
- A kind of 1. composition pesticide containing chlorine fluorine cyanogen insect amide and methoxyfenozide, it is characterised in that：Active ingredient is chlorine fluorine The weight ratio of cyanogen insect amide and methoxyfenozide, wherein chlorine fluorine cyanogen insect amide and methoxyfenozide is 10:1~1:10, chlorine fluorine cyanogen The gross weight percentage composition of insect amide and methoxyfenozide in the composition is 0.1%~85%.
- 2. a kind of composition pesticide containing chlorine fluorine cyanogen insect amide and methoxyfenozide according to claim 1, its feature It is：Described composition pesticide also contain agricultural chemicals in allow use and receptible auxiliary element, so as to be made be adapted to agricultural The application forms used, its formulation have suspending agent, water dispersible granules or wettable powder.
- 3. a kind of composition pesticide containing chlorine fluorine cyanogen insect amide and methoxyfenozide according to claim 1 is in preventing and treating agriculture The application of insect in industry.
- 4. a kind of composition pesticide containing chlorine fluorine cyanogen insect amide and methoxyfenozide according to claim 3, its feature It is：Described insect is Lepidoptera class pest.
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| CN201410379684.0A CN104186471B (en) | 2014-08-04 | 2014-08-04 | A kind of composition pesticide containing chlorine fluorine cyanogen insect amide and methoxyfenozide |
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| CN104186471B true CN104186471B (en) | 2017-11-28 |
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Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN104322491A (en) * | 2014-09-16 | 2015-02-04 | 北京燕化永乐生物科技股份有限公司 | Insecticidal composition |
| CN104430498B (en) * | 2014-12-18 | 2017-02-22 | 陕西上格之路生物科学有限公司 | Insecticidal composition containing chlorine-fluorine cyantraniliprole |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2006113274A1 (en) * | 2005-04-15 | 2006-10-26 | Parallel Solutions, Inc. | Biodegradable polyphosphazenes containing pyrrolidone side groups |
| US20080318785A1 (en) * | 2004-04-18 | 2008-12-25 | Sebastian Koltzenburg | Preparation Comprising at Least One Conazole Fungicide |
| WO2009000407A1 (en) * | 2007-06-22 | 2008-12-31 | Bayer Cropscience Ag | Method for reducing the phytotoxicity of azoles on dicotyledonous plants by adding additives |
| CN103039512A (en) * | 2013-01-05 | 2013-04-17 | 中化蓝天集团有限公司 | Agricultural insecticidal composition containing chlorpyrifos and ZJ4042 |
| CN103039450A (en) * | 2013-01-06 | 2013-04-17 | 中化蓝天集团有限公司 | Agricultural insecticidal composition containing spinosad and ZJ4042 |
| CN103947646A (en) * | 2014-05-21 | 2014-07-30 | 北京燕化永乐生物科技股份有限公司 | Insecticidal composition |
-
2014
- 2014-08-04 CN CN201410379684.0A patent/CN104186471B/en active Active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20080318785A1 (en) * | 2004-04-18 | 2008-12-25 | Sebastian Koltzenburg | Preparation Comprising at Least One Conazole Fungicide |
| WO2006113274A1 (en) * | 2005-04-15 | 2006-10-26 | Parallel Solutions, Inc. | Biodegradable polyphosphazenes containing pyrrolidone side groups |
| WO2009000407A1 (en) * | 2007-06-22 | 2008-12-31 | Bayer Cropscience Ag | Method for reducing the phytotoxicity of azoles on dicotyledonous plants by adding additives |
| CN103039512A (en) * | 2013-01-05 | 2013-04-17 | 中化蓝天集团有限公司 | Agricultural insecticidal composition containing chlorpyrifos and ZJ4042 |
| CN103039450A (en) * | 2013-01-06 | 2013-04-17 | 中化蓝天集团有限公司 | Agricultural insecticidal composition containing spinosad and ZJ4042 |
| CN103947646A (en) * | 2014-05-21 | 2014-07-30 | 北京燕化永乐生物科技股份有限公司 | Insecticidal composition |
Non-Patent Citations (2)
| Title |
|---|
| "新型杀虫剂氯氟氰虫酰胺对不同鳞翅目害虫的毒力和田间防效";刑家华等;《农药学学报》;20130415;第159-164页 * |
| "甲氧虫酰肼的合成";邵敬华等;《现代农药》;20030410;第13-14页 * |
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