CN101669488A - Binary complex pesticide composition containing chlorantraniliprole - Google Patents
Binary complex pesticide composition containing chlorantraniliprole Download PDFInfo
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- CN101669488A CN101669488A CN200910019508A CN200910019508A CN101669488A CN 101669488 A CN101669488 A CN 101669488A CN 200910019508 A CN200910019508 A CN 200910019508A CN 200910019508 A CN200910019508 A CN 200910019508A CN 101669488 A CN101669488 A CN 101669488A
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- Prior art keywords
- rynaxypyr
- parts
- pesticide composition
- binary complex
- complex pesticide
- Prior art date
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- PSOVNZZNOMJUBI-UHFFFAOYSA-N chlorantraniliprole Chemical compound CNC(=O)C1=CC(Cl)=CC(C)=C1NC(=O)C1=CC(Br)=NN1C1=NC=CC=C1Cl PSOVNZZNOMJUBI-UHFFFAOYSA-N 0.000 title claims abstract description 66
- 239000000203 mixture Substances 0.000 title claims abstract description 28
- 239000000575 pesticide Substances 0.000 title claims abstract description 25
- 239000005886 Chlorantraniliprole Substances 0.000 title abstract 4
- 239000000375 suspending agent Substances 0.000 claims abstract description 14
- 238000009472 formulation Methods 0.000 claims abstract description 6
- 239000004530 micro-emulsion Substances 0.000 claims abstract description 6
- 239000004480 active ingredient Substances 0.000 claims abstract description 4
- 239000000839 emulsion Substances 0.000 claims abstract description 4
- 229940042795 hydrazides for tuberculosis treatment Drugs 0.000 claims description 21
- -1 worm hydrazides Chemical compound 0.000 claims description 21
- 239000002131 composite material Substances 0.000 claims description 14
- 239000000843 powder Substances 0.000 claims description 8
- 239000002917 insecticide Substances 0.000 claims description 7
- 238000009736 wetting Methods 0.000 claims description 7
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 6
- 239000000460 chlorine Substances 0.000 claims description 6
- 229910052801 chlorine Inorganic materials 0.000 claims description 6
- 239000005917 Methoxyfenozide Substances 0.000 claims description 5
- QCAWEPFNJXQPAN-UHFFFAOYSA-N methoxyfenozide Chemical compound COC1=CC=CC(C(=O)NN(C(=O)C=2C=C(C)C=C(C)C=2)C(C)(C)C)=C1C QCAWEPFNJXQPAN-UHFFFAOYSA-N 0.000 claims description 5
- 150000002240 furans Chemical class 0.000 claims description 4
- 239000004562 water dispersible granule Substances 0.000 claims description 3
- 239000008187 granular material Substances 0.000 claims description 2
- 230000000694 effects Effects 0.000 abstract description 12
- CXEGAUYXQAKHKJ-NSBHKLITSA-N emamectin B1a Chemical compound C1=C[C@H](C)[C@@H]([C@@H](C)CC)O[C@]11O[C@H](C\C=C(C)\[C@@H](O[C@@H]2O[C@@H](C)[C@H](O[C@@H]3O[C@@H](C)[C@H](NC)[C@@H](OC)C3)[C@@H](OC)C2)[C@@H](C)\C=C\C=C/2[C@]3([C@H](C(=O)O4)C=C(C)[C@@H](O)[C@H]3OC\2)O)C[C@H]4C1 CXEGAUYXQAKHKJ-NSBHKLITSA-N 0.000 abstract description 11
- 238000002360 preparation method Methods 0.000 abstract description 10
- 238000001228 spectrum Methods 0.000 abstract description 5
- 235000001169 Brassica oleracea var oleracea Nutrition 0.000 abstract description 4
- 241000607479 Yersinia pestis Species 0.000 abstract description 4
- 235000013311 vegetables Nutrition 0.000 abstract description 4
- 241000255967 Helicoverpa zea Species 0.000 abstract description 3
- 241000985245 Spodoptera litura Species 0.000 abstract description 3
- 231100000053 low toxicity Toxicity 0.000 abstract description 3
- 238000004519 manufacturing process Methods 0.000 abstract description 3
- 241000426497 Chilo suppressalis Species 0.000 abstract description 2
- 229920000742 Cotton Polymers 0.000 abstract description 2
- 241000196324 Embryophyta Species 0.000 abstract description 2
- 241001531327 Hyphantria cunea Species 0.000 abstract description 2
- 240000007594 Oryza sativa Species 0.000 abstract description 2
- 235000007164 Oryza sativa Nutrition 0.000 abstract description 2
- 241000255969 Pieris brassicae Species 0.000 abstract description 2
- 244000061456 Solanum tuberosum Species 0.000 abstract description 2
- 235000002595 Solanum tuberosum Nutrition 0.000 abstract description 2
- 235000013305 food Nutrition 0.000 abstract description 2
- 230000000361 pesticidal effect Effects 0.000 abstract description 2
- 235000009566 rice Nutrition 0.000 abstract description 2
- 244000003416 Asparagus officinalis Species 0.000 abstract 1
- 235000005340 Asparagus officinalis Nutrition 0.000 abstract 1
- 240000007124 Brassica oleracea Species 0.000 abstract 1
- 235000003899 Brassica oleracea var acephala Nutrition 0.000 abstract 1
- 235000011301 Brassica oleracea var capitata Nutrition 0.000 abstract 1
- 241001325166 Phacelia congesta Species 0.000 abstract 1
- 235000012015 potatoes Nutrition 0.000 abstract 1
- 239000004563 wettable powder Substances 0.000 abstract 1
- 239000003814 drug Substances 0.000 description 43
- 230000001154 acute effect Effects 0.000 description 25
- 229940079593 drug Drugs 0.000 description 19
- 230000000638 stimulation Effects 0.000 description 15
- 239000000126 substance Substances 0.000 description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 11
- 241000256247 Spodoptera exigua Species 0.000 description 10
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 9
- 241000283973 Oryctolagus cuniculus Species 0.000 description 9
- 235000015424 sodium Nutrition 0.000 description 9
- 150000001875 compounds Chemical class 0.000 description 8
- 239000012895 dilution Substances 0.000 description 8
- 238000010790 dilution Methods 0.000 description 8
- 230000003449 preventive effect Effects 0.000 description 8
- 239000002994 raw material Substances 0.000 description 8
- 239000011734 sodium Substances 0.000 description 8
- 229910052708 sodium Inorganic materials 0.000 description 8
- 239000007921 spray Substances 0.000 description 8
- 230000002195 synergetic effect Effects 0.000 description 8
- 231100000820 toxicity test Toxicity 0.000 description 8
- 239000003053 toxin Substances 0.000 description 8
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 6
- 241000500437 Plutella xylostella Species 0.000 description 6
- 239000003960 organic solvent Substances 0.000 description 6
- 235000018927 edible plant Nutrition 0.000 description 5
- 239000004094 surface-active agent Substances 0.000 description 5
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 4
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 4
- 235000011130 ammonium sulphate Nutrition 0.000 description 4
- 229920005551 calcium lignosulfonate Polymers 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 4
- IXQGCWUGDFDQMF-UHFFFAOYSA-N o-Hydroxyethylbenzene Natural products CCC1=CC=CC=C1O IXQGCWUGDFDQMF-UHFFFAOYSA-N 0.000 description 4
- 231100000419 toxicity Toxicity 0.000 description 4
- 230000001988 toxicity Effects 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 235000006008 Brassica napus var napus Nutrition 0.000 description 3
- 241001674939 Caulanthus Species 0.000 description 3
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- 241000238631 Hexapoda Species 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- RCEAADKTGXTDOA-UHFFFAOYSA-N OS(O)(=O)=O.CCCCCCCCCCCC[Na] Chemical compound OS(O)(=O)=O.CCCCCCCCCCCC[Na] RCEAADKTGXTDOA-UHFFFAOYSA-N 0.000 description 3
- 229920002472 Starch Polymers 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- HCWYXKWQOMTBKY-UHFFFAOYSA-N calcium;dodecyl benzenesulfonate Chemical class [Ca].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 HCWYXKWQOMTBKY-UHFFFAOYSA-N 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 229920001568 phenolic resin Polymers 0.000 description 3
- 235000019698 starch Nutrition 0.000 description 3
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 2
- 239000005937 Tebufenozide Substances 0.000 description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 2
- 150000001412 amines Chemical group 0.000 description 2
- 239000011575 calcium Substances 0.000 description 2
- 229910052791 calcium Inorganic materials 0.000 description 2
- OOCMUZJPDXYRFD-UHFFFAOYSA-L calcium;2-dodecylbenzenesulfonate Chemical compound [Ca+2].CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O.CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O OOCMUZJPDXYRFD-UHFFFAOYSA-L 0.000 description 2
- 235000013339 cereals Nutrition 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 230000000749 insecticidal effect Effects 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000008107 starch Substances 0.000 description 2
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 2
- QYPNKSZPJQQLRK-UHFFFAOYSA-N tebufenozide Chemical compound C1=CC(CC)=CC=C1C(=O)NN(C(C)(C)C)C(=O)C1=CC(C)=CC(C)=C1 QYPNKSZPJQQLRK-UHFFFAOYSA-N 0.000 description 2
- 230000001018 virulence Effects 0.000 description 2
- 229920001285 xanthan gum Polymers 0.000 description 2
- 239000005995 Aluminium silicate Substances 0.000 description 1
- 229910014265 BrCl Inorganic materials 0.000 description 1
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 241000665051 Chilo sacchariphagus indicus Species 0.000 description 1
- 229920002261 Corn starch Polymers 0.000 description 1
- 241000255777 Lepidoptera Species 0.000 description 1
- 229920001732 Lignosulfonate Polymers 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 206010033799 Paralysis Diseases 0.000 description 1
- XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Natural products P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 description 1
- 241001253920 Ryania Species 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000004703 alkoxides Chemical class 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 150000008051 alkyl sulfates Chemical class 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 229960000892 attapulgite Drugs 0.000 description 1
- 239000000440 bentonite Substances 0.000 description 1
- 229910000278 bentonite Inorganic materials 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- 229910001424 calcium ion Inorganic materials 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 150000007942 carboxylates Chemical class 0.000 description 1
- 239000003093 cationic surfactant Chemical group 0.000 description 1
- 239000003610 charcoal Substances 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 238000000205 computational method Methods 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 239000007859 condensation product Substances 0.000 description 1
- 239000008120 corn starch Substances 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- NVVZQXQBYZPMLJ-UHFFFAOYSA-N formaldehyde;naphthalene-1-sulfonic acid Chemical compound O=C.C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 NVVZQXQBYZPMLJ-UHFFFAOYSA-N 0.000 description 1
- ZHNUHDYFZUAESO-UHFFFAOYSA-N formamide Substances NC=O ZHNUHDYFZUAESO-UHFFFAOYSA-N 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- MTNDZQHUAFNZQY-UHFFFAOYSA-N imidazoline Chemical compound C1CN=CN1 MTNDZQHUAFNZQY-UHFFFAOYSA-N 0.000 description 1
- 230000003834 intracellular effect Effects 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 229920005610 lignin Polymers 0.000 description 1
- 150000002632 lipids Chemical class 0.000 description 1
- 210000003205 muscle Anatomy 0.000 description 1
- PSZYNBSKGUBXEH-UHFFFAOYSA-M naphthalene-1-sulfonate Chemical compound C1=CC=C2C(S(=O)(=O)[O-])=CC=CC2=C1 PSZYNBSKGUBXEH-UHFFFAOYSA-M 0.000 description 1
- 229910052625 palygorskite Inorganic materials 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 229910000073 phosphorus hydride Inorganic materials 0.000 description 1
- 239000010773 plant oil Substances 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 229920000056 polyoxyethylene ether Polymers 0.000 description 1
- 229940051841 polyoxyethylene ether Drugs 0.000 description 1
- 244000144977 poultry Species 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 150000003460 sulfonic acids Chemical class 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention relates to a binary complex pesticide composition containing chlorantraniliprole, which comprises active ingredients with the content of 3-80 percent by weight and chlorantraniliprole with the content accounting for 10-90 percent by weight of the active ingredients. Complex components mainly comprise emamectin benzoate or a bishydrazide type pesticide, and can be any possible preparation formulations. The binary complex pesticide composition containing chlorantraniliprole has high efficiency, low toxicity, low residuals, broad pesticidal spectrum, remarkable synergy, can markedlylower the use cost, can be processed into the preparation formulations containing suspending agents, wettable powder, granular formulations, water-dispersible granular formulations, missible oil, microemulsion and aqueous emulsion, is suitable for controlling multiple pests on vegetables and crops including cabbages, rice, brassicaceous vegetables, cotton, potatoes and the like, has remarkable action effect on multiple plant pests including asparagus caterpillars, cabbage butterflies, prodenia litura, striped rice borers, paddy borers, cotton bollworms, fall webworms and the like, and is particularly suitable for the production of green foods.
Description
One, technical field
The present invention relates to technical field of pesticide, relate to the agriculture chemical compounding technology, particularly the compounded technology of Rynaxypyr.
Two, background technology
Rynaxypyr is a kind of efficient pesticides.Chemical name: benzene 3-bromo-N-[4-chloro-2-methyl-6-[(methyl-carbamoyl)]-1-(3-chloropyridine-2-yl)-1-hydrogen-pyridine-5-formamide, molecular formula: C
18H
14N
5O
2BrCl
2, relative molecular weight: 481, structural formula is:
Rynaxypyr is a kind of brand-new insecticide, because the chemical constitution of Rynaxypyr has the brand-new desinsection principle that other any insecticides do not possess, can efficiently activate insect ryania (muscle) acceptor.Excessively discharge the calcium ion in the intracellular calcium store, cause the insect paralysis dead, active high to the larva of lepidoptera pest, insecticidal spectrum is wide, lasting effect good.As safe as a house to crop under different temperature conditions, to person poultry safety, low toxicity.
Three, summary of the invention
The object of the present invention is to provide a kind of is a kind of insecticides of main body component with the Rynaxypyr, reaches the purpose of synergy, wide spectrum, reduction use cost.
The object of the present invention is achieved like this, based on Rynaxypyr, carries out compositely obtaining having synergy with other pesticide, wide spectrum, binary built preparation that use cost is low.
The binary complex pesticide composition that contains Rynaxypyr that the present invention relates to, active ingredient weight percent content are 3%～80%, and Rynaxypyr occupies imitates 10%～90% of composition.
The binary complex pesticide composition that contains Rynaxypyr that the present invention relates to, second component composite with Rynaxypyr is emamection benaoate.
The binary complex pesticide composition that contains Rynaxypyr that the present invention relates to, second component composite with Rynaxypyr is the bishydrazide insecticide.
The binary complex pesticide composition that contains Rynaxypyr that the present invention relates to is selected from a kind of combination in methoxyfenozide, worm hydrazides, chlorine worm hydrazides, the furans worm hydrazides with the composite bishydrazide insecticide of Rynaxypyr.
The formulation of the binary complex pesticide composition that contains Rynaxypyr that the present invention relates to is a kind of in missible oil, wetting powder, suspending agent, granule, microemulsion, aqueous emulsion, the water-dispersible granules.
The binary complex pesticide composition that contains Rynaxypyr that the present invention relates to, auxiliary element comprises acceptable organic solvent, emulsifier, surfactant, inert filler etc.
The binary complex pesticide composition that contains Rynaxypyr that the present invention relates to, the solvent that uses comprises fat hydrocarbon organic solvent, arene organic solvent, plant oil solvent, alcohol organic solvent, lipid organic solvent or organic solvent of ketone etc.
The binary complex pesticide composition that contains Rynaxypyr that the present invention relates to, the surfactant that uses, comprise alkylbenzenesulfonate, the lignin sulfonic acid salt, alkyl sulfate, the alkyl polyoxyethylene ether carboxylate, phosphate ester salt, sulfosuccinate ester salt, naphthalene sulfonate, anion surfactants such as sulfonate and formaldehyde condensation product, amine salt, quaternary amine, cationic surfactants such as amine oxide, betain, imidazoline type, Amino acid, amphoteric surfactantes such as phosphine ester, fatty alcohol ether, alkyl phenol ether, alkyl ether amine, non-ionic surface active agents such as alkoxide such as polyethers also have aliphatic alcohol ester, fatty acid alkane ester, alkylamide, mixed surfactants such as alcohol ether type.
The binary complex pesticide composition that contains Rynaxypyr that the present invention relates to, employed other auxiliary element also comprises thickeners such as xanthans, sodium carboxymethyl starch, antifreezing agents such as ethylene glycol, glycerine, urea; Fillers such as kaolin, bentonite, attapulgite, charcoal acid calcium, and the acceptable stabilizing agent of other pesticidal preparations, safener, colouring agent etc.
The binary complex pesticide composition that contains Rynaxypyr that the present invention relates to has efficient, low toxicity, low-residual, insecticidal spectrum is wide, synergistic effect is remarkable, can significantly reduce use cost.
The binary complex pesticide composition that contains Rynaxypyr that the present invention relates to, be used for preventing and treating the various pests on vegetables such as wild cabbage, paddy rice, brassicaceous vegetable, cotton, potato and the crop, to remarkable, be specially adapted to the production of pollution-free food as various plants insect action effects such as beet armyworm, cabbage caterpillar, prodenia litura, striped rice borer, paddy stem borer, cotton bollworm, fall webworm.
Four, embodiment
Below in conjunction with embodiment the technical scheme that invention relates to is further specified, so that help understanding of the present invention, but not as the restriction to technical scheme.
Except that mentioning especially, the component ratio that uses is weight portion among the embodiment.
Embodiment one
20% Rynaxypyr methoxyfenozide suspending agent
Raw material consists of 4 parts of former medicines of Rynaxypyr, 16 parts of former medicines of methoxyfenozide, 1.2 part is drawn back powder, 1 part of di-2-ethylhexylphosphine oxide bitter edible plant sodium sulfonate, 1.3 parts of calcium dodecyl benzene sulfonates, 3 parts of triphen ethyl-phenol APEOs, 1.5 part white carbon, 0.15 part xanthans, water is supplied 100 parts, suspending agent mode of production preparation routinely.
Toxicity test, rat (female/hero) acute oral LD50＞5000mg/kg to the skin nonirritant of rabbit, has no stimulation to the eyes of rabbit.Show that Recompounded pesticide belongs to low-toxin farm chemicals.
Using dosage: control wild cabbage beet armyworm, convert 1000～2000 times of water dilutions, spray medicine 3～7 days, effect is obvious, and preventive effect is more than 95%.
Rynaxypyr and methoxyfenozide are pressed 1/10 respectively, 1/8,1/4,1/1,4/1,8/1,10/1 ratio is composite, does contrast with 20% Tebufenozide suspending agent and the floating agent of 5% Rynaxypyr, carries out the Toxicity Determination of wild cabbage beet armyworm, the result shows that each medicament is 141.58～198.82 to the co-toxicity coefficient (same under the abundant co-toxicity coefficient computational methods of Sun Yun) of beet armyworm, and is wherein the most obvious with 1/4 synergistic effect.
Embodiment two
3% Rynaxypyr emamectin benzoate microemulsion
Raw material consists of 2 parts of former medicines of Rynaxypyr, 1 part of former medicine of emamectin-benzoate, 5 parts of N, N dimethyl formamide, 10 parts of cyclohexanone, 5 parts of acetone, 3 parts of phenethyl phenolformaldehyde resin APEOs, 2 parts of calcium dodecyl benzene sulfonates, 3 parts of alkylphenol polyoxyethylene, 3 parts of ethylene glycol, water is supplied 100 parts, in the usual way preparation.
Toxicity test, rat acute per os LD50＞1000mg/kg, chmice acute per os LD50LD50＞1000mg/kg, rabbit acute through skin LD50 greater than 1000mg/kg, rat acute through skin LD50 greater than 1000mg/kg, skin is had no stimulation, eye is had no stimulation, show that compound drug belongs to low-toxin farm chemicals.
Using dosage: the control diamond-back moth, convert 1000～1500 times of water dilutions, spray medicine 2～5 days, effect is obvious, and preventive effect is more than 90%.
Rynaxypyr and emamectin-benzoate are pressed 10/1 respectively, 5/1,2/1,1/1,1/2,1/5,1/10 ratio is composite, do contrast with 5% Rynaxypyr suspending agent and 2.2% emamectin benzoate microemulsion, carry out the Toxicity Determination of diamond-back moth, the result shows: each medicament is 185.43～223.74 to the co-toxicity coefficient of diamond-back moth.Show to have significant synergistic effect, wherein the most outstanding with 2/1 effect.
Embodiment three
80% Rynaxypyr worm hydrazides wetting powder
Raw material consists of 9 parts of former medicines of Rynaxypyr, 72 parts of former medicines of worm hydrazides, and 14 parts of di-2-ethylhexylphosphine oxide bitter edible plant sodium sulfonates, 2 parts of lauryl sodium sulfate, 5 parts of calcium lignosulfonates are supplied 100 parts with ammonium sulfate.Preparation in the usual way.
Toxicity test, rat acute per os LD50＞5000mg/kg, chmice acute per os LD50＞5000mg/kg, rabbit acute through skin LD50 greater than 3000mg/kg, rat acute through skin LD50 greater than＞3000mg/kg, skin is had no stimulation, eye is had no stimulation, show that compound drug belongs to low-toxin farm chemicals.
Using dosage: the control beet armyworm, convert 3000～5000 times of water dilutions, spray medicine 4～7 days, effect is obvious, and preventive effect is more than 90%.
Former medicine of Rynaxypyr and the former medicine of worm hydrazides are pressed 10/1,8/1,5/1 respectively, 2/1,1/1,1/2,1/5,1/8,1/10 ratio is composite, does contrast with 5% Rynaxypyr suspending agent and 30% worm hydrazides wetting powder, carrying out the beet armyworm indoor virulence surveys, the result shows to have significant synergistic effect, and wherein 8/1 proportioning medicament synergy is the most obvious, co-toxicity coefficient 245.36.
Embodiment four
9% Rynaxypyr worm hydrazides missible oil
Raw material is formed: 1 part of former medicine of Rynaxypyr, 8 parts of former medicines of worm hydrazides, 8 parts of N, N dimethyl formamide, 10 parts of methyl alcohol, 4 parts of calcium dodecyl benzene sulfonates, 4 parts of triphen ethyl-phenol APEOs, 3 parts of phenethyl phenolformaldehyde resin APEOs are supplied 100 parts with toluene.Preparation in the usual way.
Toxicity test, rat acute per os LD50＞5000mg/kg, chmice acute per os LD50＞5000mg/kg, rabbit acute through skin LD50 greater than 3000mg/kg, rat acute through skin LD50 greater than＞3000mg/kg, skin is had no stimulation, eye is had no stimulation, show that compound drug belongs to low-toxin farm chemicals.
Using dosage: the control beet armyworm, convert 1000～1500 times of water dilutions, spray medicine 4～7 days, effect is obvious, and preventive effect is more than 90%.
Former medicine of Rynaxypyr and the former medicine of worm hydrazides are pressed 10/1,8/1,5/1 respectively, 2/1,1/1,1/2,1/5,1/8,1/10 ratio is composite, does contrast with 5% Rynaxypyr suspending agent and 30% worm hydrazides wetting powder, carry out the beet armyworm Toxicity Determination, the result shows to have significant synergistic effect, and wherein 8/1 proportioning medicament synergy is the most obvious, co-toxicity coefficient 238.56.
Embodiment five
60% Rynaxypyr chlorine worm hydrazides water-dispersible granules
Raw material is formed: 10 parts of former medicines of Rynaxypyr, 50 parts of former medicines of chlorine worm hydrazides; 1 part of calcium dodecyl benzene sulfonate, 15 parts of di-2-ethylhexylphosphine oxide bitter edible plant sodium sulfonates, 3 parts of naphthalenesulfonate formaldehyde condensation compounds, 5 parts of calcium lignosulfonates, 5 parts of sodium carboxymethyl starches are supplied 100 parts with ammonium sulfate, and the extruder grain mode is prepared routinely.
Toxicity test, rat acute per os LD50＞5000mg/kg, rabbit acute through skin LD50 greater than 5000mg/kg, skin is had no stimulation, eye is had no stimulation, show that compound drug belongs to low-toxin farm chemicals.
Using dosage: the control prodenia litura, convert 3000～5000 times of water dilutions, spray medicine 4-6 days, effect is obvious, and preventive effect is more than 90%.
Rynaxypyr and chlorine worm hydrazides are pressed 10/1 respectively, 5/1,2/1,1/1,1/2,1/5,1/10,1/20 ratio is composite, do contrast with 5% Rynaxypyr suspending agent and 20% chlorine Tebufenozide suspending agent, co-toxicity coefficient is 126.19～182.73, and wherein 1/10 proportioning medicament co-toxicity coefficient is the highest, and the result shows and has significant synergies.
Embodiment six
The agent of 30% Rynaxypyr first dimension salt particle
Raw material is formed: 20 parts of former medicines of Rynaxypyr, 10 parts of emamection benaoates; 5 parts of sodium lignin sulfonates of 10 parts of di-2-ethylhexylphosphine oxide bitter edible plant sodium sulfonates, 4 parts of calcium lignosulfonates, 2 parts of dodecyl sodium sulfates, 10 parts of ammonium sulfate, 8 parts of carboxyrnethyl starch sodiums are supplied 100 parts with corn starch, and the extruder grain mode is prepared routinely.
Toxicity test, rat acute per os LD50＞10000mg/kg, rabbit acute through skin LD50 greater than 10000mg/kg, skin is had no stimulation, eye is had no stimulation, show that compound drug belongs to low-toxin farm chemicals.
Using dosage: the control cotton bollworm, convert 3000～5000 times of water dilutions, spray medicine 3-5 days, effect is obvious, and preventive effect is more than 90%.
Rynaxypyr and emamectin-benzoate are pressed 10/1 respectively, 5/1,2/1,1/1,1/2,1/5,1/10 ratio is composite, do contrast with 5% Rynaxypyr suspending agent and 5% emamectin-benzoate, co-toxicity coefficient is 164.32～212.45, and the result shows and has significant synergies, and is wherein the most obvious with 2/1 synergistic effect.
Embodiment seven
3% Rynaxypyr emamectin-benzoate aqueous emulsion
Raw material consists of 2 parts of former medicines of Rynaxypyr, 1 part of former medicine of emamectin-benzoate, 7 parts of dimethylbenzene, 10 parts of cyclohexanone, 5 parts of acetone, 1 part of phenethyl phenolformaldehyde resin APEO, 0.3 part calcium dodecyl benzene sulfonate, 1 part of alkylphenol polyoxyethylene, 3 parts of ethylene glycol, water is supplied 100 parts, in the usual way preparation.
Toxicity test, rat acute per os LD50＞1000mg/kg, chmice acute per os LD50LD50＞1000mg/kg, rabbit acute through skin LD50 greater than 1000mg/kg, rat acute through skin LD50 greater than 1000mg/kg, skin is had no stimulation, eye is had no stimulation, show that compound drug belongs to low-toxin farm chemicals.
Using dosage: the control diamond-back moth, convert 1000～1500 times of water dilutions, spray medicine 2～5 days, effect is obvious, and preventive effect is more than 90%.
Rynaxypyr and emamectin-benzoate are pressed 10/1 respectively, 5/1,2/1,1/1,1/2,1/5,1/10 ratio is composite, do contrast with 5% Rynaxypyr suspending agent and 2.2% emamectin benzoate microemulsion, carry out the Toxicity Determination of diamond-back moth, the result shows: each medicament is 185.43～223.74 to the co-toxicity coefficient of diamond-back moth.Show to have significant synergistic effect, wherein the most outstanding with 2/1 effect.
Embodiment eight
72% Rynaxypyr furans worm hydrazides wetting powder
Raw material consists of 8 parts of former medicines of Rynaxypyr, 64 parts of former medicines of worm hydrazides, and 15 parts of di-2-ethylhexylphosphine oxide bitter edible plant sodium sulfonates, 3 parts of lauryl sodium sulfate, 7 parts of calcium lignosulfonates are supplied 100 parts with ammonium sulfate.Preparation in the usual way.
Toxicity test, rat acute per os LD50＞5000mg/kg, chmice acute per os LD50＞5000mg/kg, rabbit acute through skin LD50 greater than 3000mg/kg, rat acute through skin LD50 greater than＞3000mg/kg, skin is had no stimulation, eye is had no stimulation, show that compound drug belongs to low-toxin farm chemicals.
Using dosage: the control beet armyworm, convert 3000～5000 times of water dilutions, spray medicine 4～7 days, effect is obvious, and preventive effect is more than 92%.
Former medicine of Rynaxypyr and the former medicine of furans worm hydrazides are pressed 10/1,8/1,5/1 respectively, 2/1,1/1,1/2,1/5,1/8,1/10 ratio is composite, does contrast with 5% Rynaxypyr suspending agent and 60% furans worm hydrazides wetting powder, carrying out the beet armyworm indoor virulence surveys, the result shows to have significant synergistic effect, and wherein 8/1 proportioning medicament synergy is the most obvious, co-toxicity coefficient 2837.57.
Claims (5)
1, a kind of binary complex pesticide composition that contains Rynaxypyr is characterized in that: the active ingredient weight percent content is 3%～80%, and Rynaxypyr occupies imitates 10%～90% of composition.
2, the binary complex pesticide composition that contains Rynaxypyr that claim 1 relates to is characterized in that: second component composite with Rynaxypyr is emamection benaoate.
3, the binary complex pesticide composition that contains Rynaxypyr that claim 1 relates to is characterized in that: second component composite with Rynaxypyr is the bishydrazide insecticide.
4, the binary complex pesticide composition that contains Rynaxypyr that claim 3 relates to is characterized in that: be selected from a kind of combination in methoxyfenozide, worm hydrazides, chlorine worm hydrazides, the furans worm hydrazides with the composite bishydrazide insecticide of Rynaxypyr.
5, the binary complex pesticide composition that contains Rynaxypyr that claim 1 relates to is characterized in that: its formulation is a kind of in missible oil, wetting powder, suspending agent, granule, microemulsion, aqueous emulsion, the water-dispersible granules.
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