CN101669488A - Binary complex pesticide composition containing chlorantraniliprole - Google Patents
Binary complex pesticide composition containing chlorantraniliprole Download PDFInfo
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- CN101669488A CN101669488A CN200910019508A CN200910019508A CN101669488A CN 101669488 A CN101669488 A CN 101669488A CN 200910019508 A CN200910019508 A CN 200910019508A CN 200910019508 A CN200910019508 A CN 200910019508A CN 101669488 A CN101669488 A CN 101669488A
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Abstract
The invention relates to a binary complex pesticide composition containing chlorantraniliprole, which comprises active ingredients with the content of 3-80 percent by weight and chlorantraniliprole with the content accounting for 10-90 percent by weight of the active ingredients. Complex components mainly comprise emamectin benzoate or a bishydrazide type pesticide, and can be any possible preparation formulations. The binary complex pesticide composition containing chlorantraniliprole has high efficiency, low toxicity, low residuals, broad pesticidal spectrum, remarkable synergy, can markedlylower the use cost, can be processed into the preparation formulations containing suspending agents, wettable powder, granular formulations, water-dispersible granular formulations, missible oil, microemulsion and aqueous emulsion, is suitable for controlling multiple pests on vegetables and crops including cabbages, rice, brassicaceous vegetables, cotton, potatoes and the like, has remarkable action effect on multiple plant pests including asparagus caterpillars, cabbage butterflies, prodenia litura, striped rice borers, paddy borers, cotton bollworms, fall webworms and the like, and is particularly suitable for the production of green foods.
Description
One, technical field
The present invention relates to technical field of pesticide, relate to the agriculture chemical compounding technology, particularly the compounded technology of Rynaxypyr.
Two, background technology
Rynaxypyr is a kind of efficient pesticides.Chemical name: benzene 3-bromo-N-[4-chloro-2-methyl-6-[(methyl-carbamoyl)]-1-(3-chloropyridine-2-yl)-1-hydrogen-pyridine-5-formamide, molecular formula: C
18H
14N
5O
2BrCl
2, relative molecular weight: 481, structural formula is:
Rynaxypyr is a kind of brand-new insecticide, because the chemical constitution of Rynaxypyr has the brand-new desinsection principle that other any insecticides do not possess, can efficiently activate insect ryania (muscle) acceptor.Excessively discharge the calcium ion in the intracellular calcium store, cause the insect paralysis dead, active high to the larva of lepidoptera pest, insecticidal spectrum is wide, lasting effect good.As safe as a house to crop under different temperature conditions, to person poultry safety, low toxicity.
Three, summary of the invention
The object of the present invention is to provide a kind of is a kind of insecticides of main body component with the Rynaxypyr, reaches the purpose of synergy, wide spectrum, reduction use cost.
The object of the present invention is achieved like this, based on Rynaxypyr, carries out compositely obtaining having synergy with other pesticide, wide spectrum, binary built preparation that use cost is low.
The binary complex pesticide composition that contains Rynaxypyr that the present invention relates to, active ingredient weight percent content are 3%～80%, and Rynaxypyr occupies imitates 10%～90% of composition.
The binary complex pesticide composition that contains Rynaxypyr that the present invention relates to, second component composite with Rynaxypyr is emamection benaoate.
The binary complex pesticide composition that contains Rynaxypyr that the present invention relates to, second component composite with Rynaxypyr is the bishydrazide insecticide.
The binary complex pesticide composition that contains Rynaxypyr that the present invention relates to is selected from a kind of combination in methoxyfenozide, worm hydrazides, chlorine worm hydrazides, the furans worm hydrazides with the composite bishydrazide insecticide of Rynaxypyr.
The formulation of the binary complex pesticide composition that contains Rynaxypyr that the present invention relates to is a kind of in missible oil, wetting powder, suspending agent, granule, microemulsion, aqueous emulsion, the water-dispersible granules.
The binary complex pesticide composition that contains Rynaxypyr that the present invention relates to, auxiliary element comprises acceptable organic solvent, emulsifier, surfactant, inert filler etc.
The binary complex pesticide composition that contains Rynaxypyr that the present invention relates to, the solvent that uses comprises fat hydrocarbon organic solvent, arene organic solvent, plant oil solvent, alcohol organic solvent, lipid organic solvent or organic solvent of ketone etc.
The binary complex pesticide composition that contains Rynaxypyr that the present invention relates to, the surfactant that uses, comprise alkylbenzenesulfonate, the lignin sulfonic acid salt, alkyl sulfate, the alkyl polyoxyethylene ether carboxylate, phosphate ester salt, sulfosuccinate ester salt, naphthalene sulfonate, anion surfactants such as sulfonate and formaldehyde condensation product, amine salt, quaternary amine, cationic surfactants such as amine oxide, betain, imidazoline type, Amino acid, amphoteric surfactantes such as phosphine ester, fatty alcohol ether, alkyl phenol ether, alkyl ether amine, non-ionic surface active agents such as alkoxide such as polyethers also have aliphatic alcohol ester, fatty acid alkane ester, alkylamide, mixed surfactants such as alcohol ether type.
The binary complex pesticide composition that contains Rynaxypyr that the present invention relates to, employed other auxiliary element also comprises thickeners such as xanthans, sodium carboxymethyl starch, antifreezing agents such as ethylene glycol, glycerine, urea; Fillers such as kaolin, bentonite, attapulgite, charcoal acid calcium, and the acceptable stabilizing agent of other pesticidal preparations, safener, colouring agent etc.
The binary complex pesticide composition that contains Rynaxypyr that the present invention relates to has efficient, low toxicity, low-residual, insecticidal spectrum is wide, synergistic effect is remarkable, can significantly reduce use cost.
The binary complex pesticide composition that contains Rynaxypyr that the present invention relates to, be used for preventing and treating the various pests on vegetables such as wild cabbage, paddy rice, brassicaceous vegetable, cotton, potato and the crop, to remarkable, be specially adapted to the production of pollution-free food as various plants insect action effects such as beet armyworm, cabbage caterpillar, prodenia litura, striped rice borer, paddy stem borer, cotton bollworm, fall webworm.
Four, embodiment
Below in conjunction with embodiment the technical scheme that invention relates to is further specified, so that help understanding of the present invention, but not as the restriction to technical scheme.
Except that mentioning especially, the component ratio that uses is weight portion among the embodiment.
Embodiment one
20% Rynaxypyr methoxyfenozide suspending agent
Raw material consists of 4 parts of former medicines of Rynaxypyr, 16 parts of former medicines of methoxyfenozide, 1.2 part is drawn back powder, 1 part of di-2-ethylhexylphosphine oxide bitter edible plant sodium sulfonate, 1.3 parts of calcium dodecyl benzene sulfonates, 3 parts of triphen ethyl-phenol APEOs, 1.5 part white carbon, 0.15 part xanthans, water is supplied 100 parts, suspending agent mode of production preparation routinely.
Toxicity test, rat (female/hero) acute oral LD50＞5000mg/kg to the skin nonirritant of rabbit, has no stimulation to the eyes of rabbit.Show that Recompounded pesticide belongs to low-toxin farm chemicals.
Using dosage: control wild cabbage beet armyworm, convert 1000～2000 times of water dilutions, spray medicine 3～7 days, effect is obvious, and preventive effect is more than 95%.
Rynaxypyr and methoxyfenozide are pressed 1/10 respectively, 1/8,1/4,1/1,4/1,8/1,10/1 ratio is composite, does contrast with 20% Tebufenozide suspending agent and the floating agent of 5% Rynaxypyr, carries out the Toxicity Determination of wild cabbage beet armyworm, the result shows that each medicament is 141.58～198.82 to the co-toxicity coefficient (same under the abundant co-toxicity coefficient computational methods of Sun Yun) of beet armyworm, and is wherein the most obvious with 1/4 synergistic effect.
Embodiment two
3% Rynaxypyr emamectin benzoate microemulsion
Raw material consists of 2 parts of former medicines of Rynaxypyr, 1 part of former medicine of emamectin-benzoate, 5 parts of N, N dimethyl formamide, 10 parts of cyclohexanone, 5 parts of acetone, 3 parts of phenethyl phenolformaldehyde resin APEOs, 2 parts of calcium dodecyl benzene sulfonates, 3 parts of alkylphenol polyoxyethylene, 3 parts of ethylene glycol, water is supplied 100 parts, in the usual way preparation.
Toxicity test, rat acute per os LD50＞1000mg/kg, chmice acute per os LD50LD50＞1000mg/kg, rabbit acute through skin LD50 greater than 1000mg/kg, rat acute through skin LD50 greater than 1000mg/kg, skin is had no stimulation, eye is had no stimulation, show that compound drug belongs to low-toxin farm chemicals.
Using dosage: the control diamond-back moth, convert 1000～1500 times of water dilutions, spray medicine 2～5 days, effect is obvious, and preventive effect is more than 90%.
Rynaxypyr and emamectin-benzoate are pressed 10/1 respectively, 5/1,2/1,1/1,1/2,1/5,1/10 ratio is composite, do contrast with 5% Rynaxypyr suspending agent and 2.2% emamectin benzoate microemulsion, carry out the Toxicity Determination of diamond-back moth, the result shows: each medicament is 185.43～223.74 to the co-toxicity coefficient of diamond-back moth.Show to have significant synergistic effect, wherein the most outstanding with 2/1 effect.
Embodiment three
80% Rynaxypyr worm hydrazides wetting powder
Raw material consists of 9 parts of former medicines of Rynaxypyr, 72 parts of former medicines of worm hydrazides, and 14 parts of di-2-ethylhexylphosphine oxide bitter edible plant sodium sulfonates, 2 parts of lauryl sodium sulfate, 5 parts of calcium lignosulfonates are supplied 100 parts with ammonium sulfate.Preparation in the usual way.
Toxicity test, rat acute per os LD50＞5000mg/kg, chmice acute per os LD50＞5000mg/kg, rabbit acute through skin LD50 greater than 3000mg/kg, rat acute through skin LD50 greater than＞3000mg/kg, skin is had no stimulation, eye is had no stimulation, show that compound drug belongs to low-toxin farm chemicals.
Using dosage: the control beet armyworm, convert 3000～5000 times of water dilutions, spray medicine 4～7 days, effect is obvious, and preventive effect is more than 90%.
Former medicine of Rynaxypyr and the former medicine of worm hydrazides are pressed 10/1,8/1,5/1 respectively, 2/1,1/1,1/2,1/5,1/8,1/10 ratio is composite, does contrast with 5% Rynaxypyr suspending agent and 30% worm hydrazides wetting powder, carrying out the beet armyworm indoor virulence surveys, the result shows to have significant synergistic effect, and wherein 8/1 proportioning medicament synergy is the most obvious, co-toxicity coefficient 245.36.
Embodiment four
9% Rynaxypyr worm hydrazides missible oil
Raw material is formed: 1 part of former medicine of Rynaxypyr, 8 parts of former medicines of worm hydrazides, 8 parts of N, N dimethyl formamide, 10 parts of methyl alcohol, 4 parts of calcium dodecyl benzene sulfonates, 4 parts of triphen ethyl-phenol APEOs, 3 parts of phenethyl phenolformaldehyde resin APEOs are supplied 100 parts with toluene.Preparation in the usual way.
Toxicity test, rat acute per os LD50＞5000mg/kg, chmice acute per os LD50＞5000mg/kg, rabbit acute through skin LD50 greater than 3000mg/kg, rat acute through skin LD50 greater than＞3000mg/kg, skin is had no stimulation, eye is had no stimulation, show that compound drug belongs to low-toxin farm chemicals.
Using dosage: the control beet armyworm, convert 1000～1500 times of water dilutions, spray medicine 4～7 days, effect is obvious, and preventive effect is more than 90%.
Former medicine of Rynaxypyr and the former medicine of worm hydrazides are pressed 10/1,8/1,5/1 respectively, 2/1,1/1,1/2,1/5,1/8,1/10 ratio is composite, does contrast with 5% Rynaxypyr suspending agent and 30% worm hydrazides wetting powder, carry out the beet armyworm Toxicity Determination, the result shows to have significant synergistic effect, and wherein 8/1 proportioning medicament synergy is the most obvious, co-toxicity coefficient 238.56.
Embodiment five
60% Rynaxypyr chlorine worm hydrazides water-dispersible granules
Raw material is formed: 10 parts of former medicines of Rynaxypyr, 50 parts of former medicines of chlorine worm hydrazides; 1 part of calcium dodecyl benzene sulfonate, 15 parts of di-2-ethylhexylphosphine oxide bitter edible plant sodium sulfonates, 3 parts of naphthalenesulfonate formaldehyde condensation compounds, 5 parts of calcium lignosulfonates, 5 parts of sodium carboxymethyl starches are supplied 100 parts with ammonium sulfate, and the extruder grain mode is prepared routinely.
Toxicity test, rat acute per os LD50＞5000mg/kg, rabbit acute through skin LD50 greater than 5000mg/kg, skin is had no stimulation, eye is had no stimulation, show that compound drug belongs to low-toxin farm chemicals.
Using dosage: the control prodenia litura, convert 3000～5000 times of water dilutions, spray medicine 4-6 days, effect is obvious, and preventive effect is more than 90%.
Rynaxypyr and chlorine worm hydrazides are pressed 10/1 respectively, 5/1,2/1,1/1,1/2,1/5,1/10,1/20 ratio is composite, do contrast with 5% Rynaxypyr suspending agent and 20% chlorine Tebufenozide suspending agent, co-toxicity coefficient is 126.19～182.73, and wherein 1/10 proportioning medicament co-toxicity coefficient is the highest, and the result shows and has significant synergies.
Embodiment six
The agent of 30% Rynaxypyr first dimension salt particle
Raw material is formed: 20 parts of former medicines of Rynaxypyr, 10 parts of emamection benaoates; 5 parts of sodium lignin sulfonates of 10 parts of di-2-ethylhexylphosphine oxide bitter edible plant sodium sulfonates, 4 parts of calcium lignosulfonates, 2 parts of dodecyl sodium sulfates, 10 parts of ammonium sulfate, 8 parts of carboxyrnethyl starch sodiums are supplied 100 parts with corn starch, and the extruder grain mode is prepared routinely.
Toxicity test, rat acute per os LD50＞10000mg/kg, rabbit acute through skin LD50 greater than 10000mg/kg, skin is had no stimulation, eye is had no stimulation, show that compound drug belongs to low-toxin farm chemicals.
Using dosage: the control cotton bollworm, convert 3000～5000 times of water dilutions, spray medicine 3-5 days, effect is obvious, and preventive effect is more than 90%.
Rynaxypyr and emamectin-benzoate are pressed 10/1 respectively, 5/1,2/1,1/1,1/2,1/5,1/10 ratio is composite, do contrast with 5% Rynaxypyr suspending agent and 5% emamectin-benzoate, co-toxicity coefficient is 164.32～212.45, and the result shows and has significant synergies, and is wherein the most obvious with 2/1 synergistic effect.
Embodiment seven
3% Rynaxypyr emamectin-benzoate aqueous emulsion
Raw material consists of 2 parts of former medicines of Rynaxypyr, 1 part of former medicine of emamectin-benzoate, 7 parts of dimethylbenzene, 10 parts of cyclohexanone, 5 parts of acetone, 1 part of phenethyl phenolformaldehyde resin APEO, 0.3 part calcium dodecyl benzene sulfonate, 1 part of alkylphenol polyoxyethylene, 3 parts of ethylene glycol, water is supplied 100 parts, in the usual way preparation.
Toxicity test, rat acute per os LD50＞1000mg/kg, chmice acute per os LD50LD50＞1000mg/kg, rabbit acute through skin LD50 greater than 1000mg/kg, rat acute through skin LD50 greater than 1000mg/kg, skin is had no stimulation, eye is had no stimulation, show that compound drug belongs to low-toxin farm chemicals.
Using dosage: the control diamond-back moth, convert 1000～1500 times of water dilutions, spray medicine 2～5 days, effect is obvious, and preventive effect is more than 90%.
Rynaxypyr and emamectin-benzoate are pressed 10/1 respectively, 5/1,2/1,1/1,1/2,1/5,1/10 ratio is composite, do contrast with 5% Rynaxypyr suspending agent and 2.2% emamectin benzoate microemulsion, carry out the Toxicity Determination of diamond-back moth, the result shows: each medicament is 185.43～223.74 to the co-toxicity coefficient of diamond-back moth.Show to have significant synergistic effect, wherein the most outstanding with 2/1 effect.
Embodiment eight
72% Rynaxypyr furans worm hydrazides wetting powder
Raw material consists of 8 parts of former medicines of Rynaxypyr, 64 parts of former medicines of worm hydrazides, and 15 parts of di-2-ethylhexylphosphine oxide bitter edible plant sodium sulfonates, 3 parts of lauryl sodium sulfate, 7 parts of calcium lignosulfonates are supplied 100 parts with ammonium sulfate.Preparation in the usual way.
Toxicity test, rat acute per os LD50＞5000mg/kg, chmice acute per os LD50＞5000mg/kg, rabbit acute through skin LD50 greater than 3000mg/kg, rat acute through skin LD50 greater than＞3000mg/kg, skin is had no stimulation, eye is had no stimulation, show that compound drug belongs to low-toxin farm chemicals.
Using dosage: the control beet armyworm, convert 3000～5000 times of water dilutions, spray medicine 4～7 days, effect is obvious, and preventive effect is more than 92%.
Former medicine of Rynaxypyr and the former medicine of furans worm hydrazides are pressed 10/1,8/1,5/1 respectively, 2/1,1/1,1/2,1/5,1/8,1/10 ratio is composite, does contrast with 5% Rynaxypyr suspending agent and 60% furans worm hydrazides wetting powder, carrying out the beet armyworm indoor virulence surveys, the result shows to have significant synergistic effect, and wherein 8/1 proportioning medicament synergy is the most obvious, co-toxicity coefficient 2837.57.
Claims (5)
1, a kind of binary complex pesticide composition that contains Rynaxypyr is characterized in that: the active ingredient weight percent content is 3%～80%, and Rynaxypyr occupies imitates 10%～90% of composition.
2, the binary complex pesticide composition that contains Rynaxypyr that claim 1 relates to is characterized in that: second component composite with Rynaxypyr is emamection benaoate.
3, the binary complex pesticide composition that contains Rynaxypyr that claim 1 relates to is characterized in that: second component composite with Rynaxypyr is the bishydrazide insecticide.
4, the binary complex pesticide composition that contains Rynaxypyr that claim 3 relates to is characterized in that: be selected from a kind of combination in methoxyfenozide, worm hydrazides, chlorine worm hydrazides, the furans worm hydrazides with the composite bishydrazide insecticide of Rynaxypyr.
5, the binary complex pesticide composition that contains Rynaxypyr that claim 1 relates to is characterized in that: its formulation is a kind of in missible oil, wetting powder, suspending agent, granule, microemulsion, aqueous emulsion, the water-dispersible granules.
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| CN101971866A (en) * | 2010-10-20 | 2011-02-16 | 华南理工大学 | Chlorantraniliprole and natural pyrethrin compound insecticidal microemulsion and preparation method thereof |
| CN102246762A (en) * | 2011-05-23 | 2011-11-23 | 陕西韦尔奇作物保护有限公司 | Insecticidal composition containing furan tebufenozide and amide compounds |
| CN102578161A (en) * | 2012-01-18 | 2012-07-18 | 华南理工大学 | Chlorantraniliprole and natural pyrethrin compound suspension and preparation method thereof |
| CN103518730A (en) * | 2012-07-04 | 2014-01-22 | 陕西美邦农药有限公司 | Pesticide composition containing bromine benzamide and bishydrazide |
| CN103651428A (en) * | 2011-05-17 | 2014-03-26 | 陕西韦尔奇作物保护有限公司 | Insecticidal composition containing furan tebufenozide and antibiotic compound |
| CN104604876A (en) * | 2012-07-04 | 2015-05-13 | 陕西美邦农药有限公司 | Insecticidal composition containing bromine benzamide and bishydrazide |
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| CN105685051A (en) * | 2016-04-20 | 2016-06-22 | 陕西上格之路生物科学有限公司 | Dispersible oil suspension agent with methoxyfenozide |
| CN105724389A (en) * | 2016-04-19 | 2016-07-06 | 陕西上格之路生物科学有限公司 | Dispersible oil suspension containing chlorantraniliprole |
| CN108174853A (en) * | 2018-02-05 | 2018-06-19 | 广东真格生物科技有限公司 | A kind of Pesticidal combination and its preparation containing fourth chlorantraniliprole and molting hormone class |
| CN109845740A (en) * | 2019-01-22 | 2019-06-07 | 海利尔药业集团股份有限公司 | A kind of Pesticidal combination of fluorine-containing chlorine worm bisamide and bishydrazide insecticide |
| CN110754475A (en) * | 2019-11-12 | 2020-02-07 | 安徽省农业科学院植物保护与农产品质量安全研究所 | Medicament composition for preventing and treating spodoptera frugiperda and use method thereof |
| CN110896955A (en) * | 2019-10-25 | 2020-03-24 | 河北威远生物化工有限公司 | Insecticidal composition for preventing and treating lepidoptera pests |
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| CN101971866B (en) * | 2010-10-20 | 2013-11-13 | 华南理工大学 | Chlorantraniliprole and natural pyrethrin compound insecticidal microemulsion and preparation method thereof |
| CN101971866A (en) * | 2010-10-20 | 2011-02-16 | 华南理工大学 | Chlorantraniliprole and natural pyrethrin compound insecticidal microemulsion and preparation method thereof |
| CN103651428A (en) * | 2011-05-17 | 2014-03-26 | 陕西韦尔奇作物保护有限公司 | Insecticidal composition containing furan tebufenozide and antibiotic compound |
| CN102246762A (en) * | 2011-05-23 | 2011-11-23 | 陕西韦尔奇作物保护有限公司 | Insecticidal composition containing furan tebufenozide and amide compounds |
| CN102578161B (en) * | 2012-01-18 | 2014-04-02 | 华南理工大学 | Chlorantraniliprole and natural pyrethrin compound suspension and preparation method thereof |
| CN102578161A (en) * | 2012-01-18 | 2012-07-18 | 华南理工大学 | Chlorantraniliprole and natural pyrethrin compound suspension and preparation method thereof |
| CN103518730B (en) * | 2012-07-04 | 2015-08-19 | 陕西美邦农药有限公司 | The Pesticidal combination of a kind of brominated worm benzamide and bishydrazide |
| CN104604876A (en) * | 2012-07-04 | 2015-05-13 | 陕西美邦农药有限公司 | Insecticidal composition containing bromine benzamide and bishydrazide |
| CN103518730A (en) * | 2012-07-04 | 2014-01-22 | 陕西美邦农药有限公司 | Pesticide composition containing bromine benzamide and bishydrazide |
| CN104604876B (en) * | 2012-07-04 | 2016-12-07 | 陕西美邦农药有限公司 | A kind of brominated worm Benzoylamide and the Pesticidal combination of bishydrazide |
| CN105613509A (en) * | 2014-10-30 | 2016-06-01 | 陕西美邦农药有限公司 | Pesticidal composition containing ZJ3757 |
| CN105724389A (en) * | 2016-04-19 | 2016-07-06 | 陕西上格之路生物科学有限公司 | Dispersible oil suspension containing chlorantraniliprole |
| CN105685051A (en) * | 2016-04-20 | 2016-06-22 | 陕西上格之路生物科学有限公司 | Dispersible oil suspension agent with methoxyfenozide |
| EP3634131A4 (en) * | 2017-06-09 | 2021-03-10 | UPL Ltd | Novel pesticidal combinations |
| CN108174853A (en) * | 2018-02-05 | 2018-06-19 | 广东真格生物科技有限公司 | A kind of Pesticidal combination and its preparation containing fourth chlorantraniliprole and molting hormone class |
| CN109845740A (en) * | 2019-01-22 | 2019-06-07 | 海利尔药业集团股份有限公司 | A kind of Pesticidal combination of fluorine-containing chlorine worm bisamide and bishydrazide insecticide |
| CN110896955A (en) * | 2019-10-25 | 2020-03-24 | 河北威远生物化工有限公司 | Insecticidal composition for preventing and treating lepidoptera pests |
| CN110896955B (en) * | 2019-10-25 | 2021-08-03 | 河北威远生物化工有限公司 | Insecticidal composition for preventing and treating lepidoptera pests |
| CN110754475A (en) * | 2019-11-12 | 2020-02-07 | 安徽省农业科学院植物保护与农产品质量安全研究所 | Medicament composition for preventing and treating spodoptera frugiperda and use method thereof |
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| CN101669488B (en) | 2015-04-29 |
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