CN105994330A - Composite insecticide composition containing cyantraniliprole and chlorfluazuron and application thereof - Google Patents

Composite insecticide composition containing cyantraniliprole and chlorfluazuron and application thereof Download PDF

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Publication number
CN105994330A
CN105994330A CN201610454686.0A CN201610454686A CN105994330A CN 105994330 A CN105994330 A CN 105994330A CN 201610454686 A CN201610454686 A CN 201610454686A CN 105994330 A CN105994330 A CN 105994330A
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Prior art keywords
chlorfluazuron
insect amide
cyanogen insect
pesticide compositions
compound pesticide
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CN201610454686.0A
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Inventor
陈叶青
杨琴
高瑞花
孙会杰
万维肖
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Nanjing Huazhou Pharmaceutical Co Ltd
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Nanjing Huazhou Pharmaceutical Co Ltd
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Priority to CN201610454686.0A priority Critical patent/CN105994330A/en
Publication of CN105994330A publication Critical patent/CN105994330A/en
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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
    • A01N47/34—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the groups, e.g. biuret; Thio analogues thereof; Urea-aldehyde condensation products
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles

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  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The invention discloses a composite insecticide composition containing cyantraniliprole and chlorfluazuron and the application thereof. The insecticidal active constituents of the insecticide composition are cyantraniliprole and chlorfluazuron, and the weight ratio of cyantraniliprole to chlorfluazuron is (0.1-80):(0.5-80). The insecticide composition can generate a good synergistic interaction effect, overcomes and delays pest resistance to insecticides, has a high insecticide speed and long lasting period, reduces pesticide cost and has a control effect obviously better than that of single application of cyantraniliprole or chlorfluazuron. The insecticide composition can control lepidoptera pests on crops, especially cotton bollworms and stem borers, and the effect is obviously better than that of single application of cyantraniliprole or chlorfluazuron.

Description

A kind of compound pesticide compositions of brominated cyanogen insect amide and chlorfluazuron and application thereof
Technical field
The invention belongs to the field of agricultural pesticide containing heterocyclic compound, concrete body relates to a kind of composite insecticidal combination Thing.
Background technology
Bromine cyanogen insect amide (cyantraniliprole), is E.I.Du Pont Company's second filial generation that success is developed after chlorantraniliprole Ryanodine receptor inhibitor insecticides, cyanogen insect amide is to be formed by the various polar groups on change phenyl ring, has higher Effect, applicable crops is more extensive, can effectively prevent and treat Lepidoptera, Semiptera and coleopteran pest.
Chlorfluazuron (Chlorfluazuron), chemical name: 1-(3,5-bis-chloro-4-(3-chloro-5-trifluoromethyl-2-pyridine Epoxide) phenyl)-3-(2,6-difluoro benzoyl) urea, structural formula is:
Chlorfluazuron is a kind of widely used growth regulator, has stomach toxicity, action of contace poison.The mechanism of action is that suppression is several Fourth matter synthesizes, and hinders insecticide normally to cast off a skin, makes the developmental disorder of the hatching of ovum, larval molting and pupa, and adult eclosion is obstructed.Drug effect Height, speed of action is relatively slow, to many Species of Lepidopterous Insect Pests, and Orthoptera, coleoptera, Hymenoptera, Diptera isoreactivity height, but right Aphid, leafhopper, plant hopper are invalid.The chlorfluazuron acute percutaneous LD to mammal50> 8500mg/kg, acute oral LD50> 1000mg/kg。
Insecticide variety containing single component often existing defects in pesticide Pest control: use continuously easily produce anti- The property of medicine, insecticidal spectrum is narrow, it is impossible to providing comprehensively protection for crop, peasant's drug cost is high.
Summary of the invention
It is an object of the invention to provide a kind of brominated cyanogen insect amide and the compound pesticide compositions of chlorfluazuron, this Insecticidal combinations Thing is the multifunctional insecticide compositions of preventing and treating lepidoptera pest.
It is a further object of the present invention to provide this Pesticidal combination and prevent and treat the insecticidal materials of resistance lepidoptera pest in preparation On application, particularly preparation preventing and treating bollworm or snout moths larva insecticidal materials on application.
It is an object of the invention to be achieved through the following technical solutions:
A kind of brominated cyanogen insect amide and the compound pesticide compositions of chlorfluazuron, this compound pesticide compositions is with bromine cyanogen insect amide Being principle active component with chlorfluazuron, wherein, the weight ratio of bromine cyanogen insect amide and chlorfluazuron is 0.1～80:0.5～80.
In this compound pesticide compositions, the weight ratio of bromine cyanogen insect amide (A) and chlorfluazuron (B) is preferably 1～60:1～60, More preferably 1～40:1～40, most preferably 1～30:1～30.In some preferred technical schemes: bromine cyanogen insect amide With chlorfluazuron can 1:30,1:29,1:28,1:27,1:26,1:25,1:24,1:24,1:22,1:21,1:20,1:19,1: 18、1:17、1:16、1:15、1:14、1:13、1:12、1:11、1:10、1:9、1:8、1:7、1:6、1:5、1:4、1:3、1:2、1: 1、2:1、3:1、4:1、5:1、6:1、7:1、8:1、9:1、10:1、11:1、12:1、13:1、14:1、15:1、16:1、17:1、18: 1、19:1、20:1、21:1、22:1、23:1、24:1、25:1、26:1、27:1、28:1、29:1、30:1、2:3、3:2、2:5、5: 2, these ratios of 3:4,4:3,5:2,2:5,5:3,3:5,5:4,4:5 select.
This compound pesticide compositions can comprise only active component bromine cyanogen insect amide and chlorfluazuron, it is possible to when using or prepare Adding other components in active component, the active ingredient in this Pesticidal combination can be present in compositions with enhancing effective amount In.
In compound pesticide compositions of the present invention, bromine cyanogen insect amide and both chlorfluazurons are in this compound pesticide compositions Weight percentage is 3%～80%.It is preferably 5%～55%, most preferably 10%～40%.
Compound pesticide compositions of the present invention is with bromine cyanogen insect amide and chlorfluazuron as active component or principle active component, and agriculture Medicine auxiliary agent and excipient become any one dosage form allowed on pesticide, the preferred cream of described dosage form, suspending agent, wettability Powder, aqueous emulsion, microemulsion or water dispersion granule.
The insecticides adjuvant of the aforementioned present invention of can be applicable to is not particularly limited, and includes, but are not limited to detergent alkylate Sulfoacid calcium, 600#, polyoxyethylene polyoxy propylene block compound are (such as agriculture breast 33#), NPE etc., aforementioned should Excipient for the present invention is also not particularly limited, include, but are not limited to solvent naphtha, water, antifreezing agent (such as propylene glycol), Deionized water etc..Above auxiliary agent, excipient and other adjuvant can be alone or and use.
Compound pesticide compositions of the present invention easily produces multiple Semiptera and the Lepidoptera of resistance to planthopper and snout moths larva etc. Insect has good preventive effect；And suppress insect that the Drug resistance of unitary agent (bromine cyanogen insect amide or chlorfluazuron are arbitrary) is produced Raw.
Above-mentioned compound pesticide compositions prevents and treats the application on resistance lepidoptera pest insecticidal materials in preparation, especially in system Application effect on standby preventing and treating bollworm or snout moths larva insecticidal materials is notable.
Compared with prior art beneficial effects of the present invention: (1) compared with single dose, said composition antagonism lepidoptera pest As bollworm, snout moths larva etc. have obvious synergistic function, overcoming and delayed pest resistance to insecticide, expanding prevention is composed, parasite killing speed Hurry up, hence it is evident that improve prevention effect；(2) preventing and treating recruitment, drug cost are reduced；(3) alternative high-toxic pesticide；(4) have concurrently quick-acting With long-acting；(5) with bromine cyanogen insect amide compared with chlorfluazuron single dose, produce and use cost reduces；(6) suppression lepidoptera pest pair The resistance of pesticide strengthens, and its effect uses apparently higher than its single dose.
Detailed description of the invention
Below in conjunction with embodiment, the invention will be further described, but limits the present invention never in any form.
Embodiment 1:
Weigh 80g bromine cyanogen insect amide, 2g chlorfluazuron, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 3g, two Toluene puts into mixing in mixing kettle to 100g, the method that above raw material is prepared cream routinely, forms principle active component weight Amount percentage composition is the bromine cyanogen insect amide 5 percent of hexaflumuron emulsifiable concentrate of 82%.
Embodiment 2:
Weigh 2g bromine cyanogen insect amide, 80g chlorfluazuron, lignin 10g, Negel 2g, add to 100g with Kaolin, Above raw material is mixed in super micron mill, forms the bromine cyanogen insect amide that principle active component weight percentage is 82% Chlorfluazuron wettable powder.
Embodiment 3:
Weigh 60g bromine cyanogen insect amide, 2g chlorfluazuron, calcium dodecyl benzene sulfonate 8g, phenethyl phenol polyethenoxy ether 6g, two Toluene adds to 100g, and the method that above raw material is prepared cream routinely puts into mixing in mixing kettle, forms principle active component Weight percentage is the bromine cyanogen insect amide 5 percent of hexaflumuron emulsifiable concentrate of 62%.
Embodiment 4:
Weigh 2g bromine cyanogen insect amide, 60g chlorfluazuron, nonyl phenol phosphate 5g, alkylphenol polyoxyethylene 4g, n-butyl alcohol The dimethylbenzene of 3g, 10g and the ketopyrrolidine of 10g, the xanthan gum of 0.1g, remaining supplies 100g, n-butyl alcohol and water dissolution shape with water Becoming aqueous phase, remaining component mix and blend forms oil phase, slowly aqueous phase is added in oil phase, and continue to cut under cutter effect Cut 10～30 minutes, form the bromine cyanogen insect amide chlorfluazuron aqueous emulsion that principle active component weight percentage is 62%.
Embodiment 5:
Weigh 40g bromine cyanogen insect amide, 2g chlorfluazuron, calcium dodecyl benzene sulfonate 5g, alkylphenol polyoxyethylene 4g, 30g Solvent xylene and the ketopyrrolidine of 15g, remaining complements to 100g with water, and the mixing of former medicine, solvent, emulsifying agent, cosolvent is stirred Mix formation homogeneous phase transparent solution, be then slowly added into water and stir formation clear solution, being principle active component weight percent Content is the bromine cyanogen insect amide chlorfluazuron microemulsion of 42%.
Embodiment 6:
Weigh 2g bromine cyanogen insect amide, 40g chlorfluazuron, calcium dodecyl benzene sulfonate 5g, phenethyl phenol polyethenoxy ether 3g, two Toluene is to 100g.The method that above raw material is prepared cream routinely puts into mixing in mixing kettle, forms principle active component weight Amount percentage composition is the bromine cyanogen insect amide 5 percent of hexaflumuron emulsifiable concentrate of 42%.
Embodiment 7:
Weigh 20g bromine cyanogen insect amide, 2g chlorfluazuron, sodium lignin sulfonate 3g, polyoxyethylene poly-oxygen propylene aether and sulphuric acid thereof Salt 4g, xanthan gum 0.2g, ethylene glycol 10g, silica ethane 0.1g, aluminium-magnesium silicate 0.5g, supply 100g with water, at the work of sand mill With the bromine cyanogen insect amide chlorfluazuron suspending agent that lower formation principle active component weight percentage is 22%.
Embodiment 8:
Weigh 2g bromine cyanogen insect amide, 20g chlorfluazuron, alkylphenol polyoxyethylene 14g, phenethyl phenol polyethenoxy ether 15g, Dimethylbenzene puts into mixing in mixing kettle to 100g, the method that above raw material is prepared cream routinely, forms principle active component Weight percentage is the bromine cyanogen insect amide 5 percent of hexaflumuron emulsifiable concentrate of 22%.
Embodiment 9:
Weigh 10g bromine cyanogen insect amide, 2g chlorfluazuron, sodium lignin sulfonate 8g, sodium lauryl sulphate 2g, ammonium sulfate 5g, Polyvinyl alcohol 5g, Borax 2g, Kaolin 28g, the method that above raw material is pressed water dispersion granule forms principle active component weight Amount percentage composition is the bromine cyanogen insect amide chlorfluazuron water dispersible granules of 12%.
Embodiment 10:
Weigh 15g bromine cyanogen insect amide, 5g chlorfluazuron, alkylphenol polyoxyethylene 14g, phenethyl phenol polyethenoxy ether 15g, Dimethylbenzene puts into mixing in mixing kettle to 100g, the method that above raw material is prepared cream routinely, forms principle active component Weight percentage is the bromine cyanogen insect amide 5 percent of hexaflumuron emulsifiable concentrate of 20%.
Embodiment 11:
Weigh 10g bromine cyanogen insect amide, 10g chlorfluazuron, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 3g, Dimethylbenzene puts into mixing in mixing kettle to 100g, the method that above raw material is prepared cream routinely, forms principle active component Weight percentage is the bromine cyanogen insect amide 5 percent of hexaflumuron emulsifiable concentrate of 20%.
Drug effect checking test
1, indoor virulence determination of activity
Weigh bromine cyanogen insect amide and chlorfluazuron 30g, calcium dodecyl benzene sulfonate 4g altogether, phenethyl phenol polyethenoxy ether 4g, Vegetable oil is to 100g.The method that above raw material is prepared cream routinely puts into mixing in mixing kettle, is configured to main effectively one-tenth The bromine cyanogen insect amide 5 percent of hexaflumuron emulsifiable concentrate dividing weight percentage to be 30%.Wherein bromine cyanogen insect amide and the concrete ratio of chlorfluazuron It is shown in Table 1 and 2.
Using feedstuff to add poison method and carry out indoor potentiation bioassay, selection resistant bollworm is target pest, often processes weight Multiple 3 times, every concentration processes 60, with probability value method calculate each medicament antagonism bollworm toxicity regression equation and lethal in dense Degree LC50, use LC50Value press Sun Yun abundant method calculating co-toxicity coefficient, the results are shown in Table 1:
Table 1 bromine cyanogen insect amide, chlorfluazuron and the toxicity test of compounding sample antagonism bollworm thereof and co-toxicity coefficient
In table, data show, antagonism bollworm are had potentiation, in table after bromine cyanogen insect amide and chlorfluazuron mixture Listed proportioning co-toxicity coefficient is both greater than 120, and therefore bromine cyanogen insect amide and chlorfluazuron mixture have significant synergies.
Weigh bromine cyanogen insect amide, chlorfluazuron uses conventional formulation method to be configured to principle active component weight by different proportion Percentage composition is the bromine cyanogen insect amide 5 percent of hexaflumuron emulsifiable concentrate of 30%.Concrete ratio is shown in Table 2.
Using feedstuff to add poison method and carry out indoor potentiation bioassay, selection rice-stem borer is target pest, often processes weight Multiple 3 times, calculate toxicity regression equation and lethal concentration of 50 LC of each medicament antagonism striped rice borer by probability value method50, use LC50Value Calculate co-toxicity coefficient by the abundant method of Sun Yun, the results are shown in Table 2:
Table 2 bromine cyanogen insect amide, chlorfluazuron and compounding sample thereof to striped rice borer toxicity test and co-toxicity coefficient
In table, data show, have potentiation, institute in table after bromine cyanogen insect amide and chlorfluazuron mixture to rice-stem borer The proportioning co-toxicity coefficient of row is all much larger than 120, and therefore bromine cyanogen insect amide and chlorfluazuron mixture have significant synergies.
2, field control effectiveness test
Using embodiment institute sample product to carry out the field test of control in field bollworm, comparison medicament is 5% chlorfluazuron EC (cream) and 20% bromine cyanogen insect amide WP (wettable powder), be diluted according to the extension rate in form 3, look into 3 days after medicine, 7 days, the result of 14 days, result is shown in Table 3:
Table 3 bromine cyanogen insect amide-chlorfluazuron compounds the field test results of antagonism bollworm
Example has fabulous quick-acting to antagonism bollworm as can be seen from Table 3, and the lasting period is long, in field Performance is good, is the outstanding medicament preventing and treating antagonism bollworm.
Measure through indoor synergism test and show: by bromine cyanogen insect amide with chlorfluazuron built agent to bollworm and rice-stem borer There is significant synergistic insecticidal action；Field control effectiveness test also indicates that all of built agent of the present invention is to bollworm insecticidal effect equally It is all remarkably higher than the effect of corresponding single dose pesticide.

Claims (10)

1. brominated cyanogen insect amide and a compound pesticide compositions for chlorfluazuron, is characterized in that this compound pesticide compositions is with bromine cyanogen Insect amide and chlorfluazuron are active insecticidal components, wherein, the weight ratio of bromine cyanogen insect amide and chlorfluazuron be 0.1～80:0.5～ 80。
Brominated cyanogen insect amide the most according to claim 1 and the compound pesticide compositions of chlorfluazuron, is characterized in that described The weight ratio of bromine cyanogen insect amide and chlorfluazuron is 1～60:1～60.
Brominated cyanogen insect amide the most according to claim 2 and the compound pesticide compositions of chlorfluazuron, is characterized in that described The weight ratio of bromine cyanogen insect amide and chlorfluazuron is 1～40:1～40.
Brominated cyanogen insect amide the most according to claim 3 and the compound pesticide compositions of chlorfluazuron, is characterized in that described The weight ratio of bromine cyanogen insect amide and chlorfluazuron is 1～30:1～30.
Brominated cyanogen insect amide the most according to claim 1 and the compound pesticide compositions of chlorfluazuron, is characterized in that bromine cyanogen worm Amide and both chlorfluazurons weight percentage in this compound pesticide compositions are 3%～80%.
Brominated cyanogen insect amide the most according to claim 5 and the compound pesticide compositions of chlorfluazuron, is characterized in that bromine cyanogen worm Amide and both chlorfluazurons weight percentage in this compound pesticide compositions are 5%～55%.
Brominated cyanogen insect amide the most according to claim 1 and the compound pesticide compositions of chlorfluazuron, is characterized in that this is combined Pesticidal combination is with bromine cyanogen insect amide and chlorfluazuron as active insecticidal components and insecticides adjuvant and excipient are configured on pesticide to permit The dosage form permitted.
Brominated cyanogen insect amide the most according to claim 7 and the compound pesticide compositions of chlorfluazuron, is characterized in that described dose Type is cream, suspending agent, aqueous emulsion, wettable powder, microemulsion or water dispersion granule.
9. the compound pesticide compositions of brominated cyanogen insect amide described in claim 1 and chlorfluazuron prevents and treats resistance Lepidoptera in preparation Application on the insecticidal materials of insect.
The compound pesticide compositions of brominated cyanogen insect amide the most according to claim 9 and chlorfluazuron is at preparation preventing and treating cotton boll Application on the insecticidal materials of worm or snout moths larva.
CN201610454686.0A 2016-06-21 2016-06-21 Composite insecticide composition containing cyantraniliprole and chlorfluazuron and application thereof Pending CN105994330A (en)

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1829707A (en) * 2003-01-28 2006-09-06 杜邦公司 Cyano anthranilamide insecticides
CN102283205A (en) * 2004-07-26 2011-12-21 杜邦公司 Mixtures of anthranilamide invertebrate pest control agents
CN102626070B (en) * 2012-03-29 2013-07-31 广西田园生化股份有限公司 Ultra-low volume liquid containing cyantraniliprole and organophosphorus insecticides

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1829707A (en) * 2003-01-28 2006-09-06 杜邦公司 Cyano anthranilamide insecticides
CN102283205A (en) * 2004-07-26 2011-12-21 杜邦公司 Mixtures of anthranilamide invertebrate pest control agents
CN102626070B (en) * 2012-03-29 2013-07-31 广西田园生化股份有限公司 Ultra-low volume liquid containing cyantraniliprole and organophosphorus insecticides

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