CN106070285A - A kind of compound pesticide compositions of brominated cyanogen insect amide and indoxacarb and application thereof - Google Patents
A kind of compound pesticide compositions of brominated cyanogen insect amide and indoxacarb and application thereof Download PDFInfo
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- CN106070285A CN106070285A CN201610451240.2A CN201610451240A CN106070285A CN 106070285 A CN106070285 A CN 106070285A CN 201610451240 A CN201610451240 A CN 201610451240A CN 106070285 A CN106070285 A CN 106070285A
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- Prior art keywords
- indoxacarb
- insect amide
- cyanogen insect
- pesticide compositions
- compound pesticide
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
- A01N47/38—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the group >N—CO—N< where at least one nitrogen atom is part of a heterocyclic ring; Thio analogues thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
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- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
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- General Health & Medical Sciences (AREA)
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- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses compound pesticide compositions of a kind of brominated cyanogen insect amide and indoxacarb and application thereof, this Pesticidal combination is with bromine cyanogen insect amide and indoxacarb as active insecticidal components, and wherein, the weight ratio of bromine cyanogen insect amide and indoxacarb is 0.1~80:0.5~80.This Pesticidal combination can produce higher synergistic function, overcomes and delayed pest resistance to insecticide, and parasite killing speed is fast, and the lasting period is long, reduces drug cost, and prevention effect uses apparently higher than its single dose.The present invention can prevent and treat the lepidoptera pest occurred on crops, is used especially for preventing and treating bollworm, snout moths larva, and its effect uses apparently higher than its single dose.
Description
Technical field
The invention belongs to the field of agricultural pesticide containing heterocyclic compound, concrete body relates to a kind of composite insecticidal combination
Thing.
Background technology
Bromine cyanogen insect amide (cyantraniliprole), is E.I.Du Pont Company's second filial generation that success is developed after chlorantraniliprole
Ryanodine receptor inhibitor insecticides, cyanogen insect amide is to be formed by the various polar groups on change phenyl ring, has higher
Effect, applicable crops is more extensive, can effectively prevent and treat Lepidoptera, Semiptera and coleopteran pest.
Indoxacarb (indoxacarb), has another name called safety hit, chemical name: 7-chloro-2,3,4a, 5-tetrahydrochysene-2-[methoxycarbonyl
(4-Trifluoromethoxyphen-l) carbamoyl] indeno [1,2-e] [1,3,4-] oxadiazines-4a-carboxylate methyl ester, structural formula is:
Indoxacarb mainly blocks the sodium channel in insect neurocyte, causes target pest to coordinate poor, paralysis, the most extremely
Die.Medicament is by tagging and the entrance polypide that ingests, and the behavior of insect changes rapidly, causes insect to terminate rapidly ingesting, thus pole
Good protects Target crops.Test shows and other insecticide no interactions resistance.
But the insect such as bollworm, snout moths larva is under conditions of current long-term prescription, and resistance is gradually increased, pesticide single dose is to evil
The effect of worm preventing and treating is gradually reduced.
Summary of the invention
It is an object of the invention to provide a kind of brominated cyanogen insect amide and the compound pesticide compositions of indoxacarb, this Insecticidal combinations
Thing is the multifunctional insecticide compositions of preventing and treating lepidoptera pest.
It is a further object of the present invention to provide this Pesticidal combination and prevent and treat the insecticidal materials of resistance lepidoptera pest in preparation
On application, particularly preparation preventing and treating bollworm or snout moths larva insecticidal materials on application.
It is an object of the invention to be achieved through the following technical solutions:
A kind of brominated cyanogen insect amide and the compound pesticide compositions of indoxacarb, this compound pesticide compositions is with bromine cyanogen insect amide
Being principle active component with indoxacarb, wherein, the weight ratio of bromine cyanogen insect amide and indoxacarb is 0.1~80:0.5~80.
In this compound pesticide compositions, the weight ratio of bromine cyanogen insect amide (A) and indoxacarb (B) is preferably 1~60:1~60,
More preferably 1~40:1~40, most preferably 1~30:1~30.In some preferred technical schemes: bromine cyanogen insect amide
With indoxacarb can 1:30,1:29,1:28,1:27,1:26,1:25,1:24,1:24,1:22,1:21,1:20,1:19,1:
18、1:17、1:16、1:15、1:14、1:13、1:12、1:11、1:10、1:9、1:8、1:7、1:6、1:5、1:4、1:3、1:2、1:
1、2:1、3:1、4:1、5:1、6:1、7:1、8:1、9:1、10:1、11:1、12:1、13:1、14:1、15:1、16:1、17:1、18:
1、19:1、20:1、21:1、22:1、23:1、24:1、25:1、26:1、27:1、28:1、29:1、30:1、2:3、3:2、2:5、5:
2, these ratios of 3:4,4:3,5:2,2:5,5:3,3:5,5:4,4:5 select.
This compound pesticide compositions can comprise only active component bromine cyanogen insect amide and indoxacarb, it is possible to when using or prepare
Adding other components in active component, the active ingredient in this Pesticidal combination can be present in compositions with enhancing effective amount
In.
In compound pesticide compositions of the present invention, bromine cyanogen insect amide and both indoxacarbs are in this compound pesticide compositions
Weight percentage is 3%~80%.It is preferably 5%~55%, most preferably 10%~40%.
Compound pesticide compositions of the present invention is with bromine cyanogen insect amide and indoxacarb as active component or principle active component, and agriculture
Medicine auxiliary agent and excipient become any one dosage form allowed on pesticide, the preferred cream of described dosage form, suspending agent, wettability
Powder, aqueous emulsion, microemulsion or water dispersion granule.
The insecticides adjuvant of the aforementioned present invention of can be applicable to is not particularly limited, and includes, but are not limited to detergent alkylate
Sulfoacid calcium, 600#, polyoxyethylene polyoxy propylene block compound are (such as agriculture breast 33#), NPE etc., aforementioned should
Excipient for the present invention is also not particularly limited, include, but are not limited to solvent naphtha, water, antifreezing agent (such as propylene glycol),
Deionized water etc..Above auxiliary agent, excipient and other adjuvant can be alone or and use.
Compound pesticide compositions of the present invention easily produces multiple Semiptera and the Lepidoptera of resistance to planthopper and snout moths larva etc.
Insect has good preventive effect;And suppress insect that the Drug resistance of unitary agent (bromine cyanogen insect amide or indoxacarb are arbitrary) is produced
Raw.
Above-mentioned compound pesticide compositions prevents and treats the application on resistance lepidoptera pest insecticidal materials in preparation, especially in system
Application effect on standby preventing and treating bollworm or snout moths larva insecticidal materials is notable.
Compared with prior art beneficial effects of the present invention: (1) compared with single dose, said composition antagonism lepidoptera pest
As bollworm, snout moths larva etc. have obvious synergistic function, overcoming and delayed pest resistance to insecticide, expanding prevention is composed, parasite killing speed
Hurry up, hence it is evident that improve prevention effect;(2) preventing and treating recruitment, drug cost are reduced;(3) alternative high-toxic pesticide;(4) have concurrently quick-acting
With long-acting;(5) with bromine cyanogen insect amide compared with indoxacarb single dose, produce and use cost reduces;(6) suppression lepidoptera pest pair
The resistance of pesticide strengthens, and its effect uses apparently higher than its single dose.
Detailed description of the invention
Below in conjunction with embodiment, the invention will be further described, but limits the present invention never in any form.
Embodiment 1:
Weigh 80g bromine cyanogen insect amide, 2g indoxacarb, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 3g, two
Toluene puts into mixing in mixing kettle to 100g, the method that above raw material is prepared cream routinely, forms principle active component weight
Amount percentage composition is the bromine cyanogen insect amide indoxacarb cream of 82%.
Embodiment 2:
Weigh 2g bromine cyanogen insect amide, 80g indoxacarb, lignin 10g, Negel 2g, add to 100g with Kaolin,
Above raw material is mixed in super micron mill, forms the bromine cyanogen insect amide that principle active component weight percentage is 82%
Indoxacarb wettable powder.
Embodiment 3:
Weigh 60g bromine cyanogen insect amide, 2g indoxacarb, calcium dodecyl benzene sulfonate 8g, phenethyl phenol polyethenoxy ether 6g, two
Toluene adds to 100g, and the method that above raw material is prepared cream routinely puts into mixing in mixing kettle, forms principle active component
Weight percentage is the bromine cyanogen insect amide indoxacarb cream of 62%.
Embodiment 4:
Weigh 2g bromine cyanogen insect amide, 60g indoxacarb, nonyl phenol phosphate 5g, alkylphenol polyoxyethylene 4g, n-butyl alcohol
The dimethylbenzene of 3g, 10g and the ketopyrrolidine of 10g, the xanthan gum of 0.1g, remaining supplies 100g, n-butyl alcohol and water dissolution shape with water
Becoming aqueous phase, remaining component mix and blend forms oil phase, slowly aqueous phase is added in oil phase, and continue to cut under cutter effect
Cut 10~30 minutes, form the bromine cyanogen insect amide indoxacarb aqueous emulsion that principle active component weight percentage is 62%.
Embodiment 5:
Weigh 40g bromine cyanogen insect amide, 2g indoxacarb, calcium dodecyl benzene sulfonate 5g, alkylphenol polyoxyethylene 4g, 30g
Solvent xylene and the ketopyrrolidine of 15g, remaining complements to 100g with water, and the mixing of former medicine, solvent, emulsifying agent, cosolvent is stirred
Mix formation homogeneous phase transparent solution, be then slowly added into water and stir formation clear solution, being principle active component weight percent
Content is the bromine cyanogen insect amide indoxacarb microemulsion of 42%.
Embodiment 6:
Weigh 2g bromine cyanogen insect amide, 40g indoxacarb, calcium dodecyl benzene sulfonate 5g, phenethyl phenol polyethenoxy ether 3g, two
Toluene is to 100g.The method that above raw material is prepared cream routinely puts into mixing in mixing kettle, forms principle active component weight
Amount percentage composition is the bromine cyanogen insect amide indoxacarb cream of 42%.
Embodiment 7:
Weigh 20g bromine cyanogen insect amide, 2g indoxacarb, sodium lignin sulfonate 3g, polyoxyethylene poly-oxygen propylene aether and sulphuric acid thereof
Salt 4g, xanthan gum 0.2g, ethylene glycol 10g, silica ethane 0.1g, aluminium-magnesium silicate 0.5g, supply 100g with water, at the work of sand mill
With the bromine cyanogen insect amide indoxacarb suspending agent that lower formation principle active component weight percentage is 22%.
Embodiment 8:
Weigh 2g bromine cyanogen insect amide, 20g indoxacarb, alkylphenol polyoxyethylene 14g, phenethyl phenol polyethenoxy ether 15g,
Dimethylbenzene puts into mixing in mixing kettle to 100g, the method that above raw material is prepared cream routinely, forms principle active component
Weight percentage is the bromine cyanogen insect amide indoxacarb cream of 22%.
Embodiment 9:
Weigh 10g bromine cyanogen insect amide, 2g indoxacarb, sodium lignin sulfonate 8g, sodium lauryl sulphate 2g, ammonium sulfate 5g,
Polyvinyl alcohol 5g, Borax 2g, Kaolin 28g, the method that above raw material is pressed water dispersion granule forms principle active component weight
Amount percentage composition is the bromine cyanogen insect amide indoxacarb water dispersible granule of 12%.
Embodiment 10:
Weigh 10g bromine cyanogen insect amide, 5g indoxacarb, alkylphenol polyoxyethylene 14g, phenethyl phenol polyethenoxy ether 15g,
Dimethylbenzene puts into mixing in mixing kettle to 100g, the method that above raw material is prepared cream routinely, forms principle active component
Weight percentage is the bromine cyanogen insect amide indoxacarb cream of 15%.
Embodiment 11:
Weigh 10g bromine cyanogen insect amide, 10g indoxacarb, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 3g,
Dimethylbenzene puts into mixing in mixing kettle to 100g, the method that above raw material is prepared cream routinely, forms principle active component
Weight percentage is the bromine cyanogen insect amide indoxacarb cream of 20%.
Drug effect checking test
1, indoor virulence determination of activity
Weigh bromine cyanogen insect amide and indoxacarb 30g, calcium dodecyl benzene sulfonate 4g altogether, phenethyl phenol polyethenoxy ether 4g,
Vegetable oil is to 100g.The method that above raw material is prepared cream routinely puts into mixing in mixing kettle, is configured to main effectively one-tenth
The bromine cyanogen insect amide indoxacarb cream dividing weight percentage to be 30%.Wherein bromine cyanogen insect amide and the concrete ratio of indoxacarb
It is shown in Table 1 and 2.
Using feedstuff to add poison method and carry out indoor potentiation bioassay, selection resistant bollworm is target pest, often processes weight
Multiple 3 times, every concentration processes 60, with probability value method calculate each medicament antagonism bollworm toxicity regression equation and lethal in dense
Degree LC50, use LC50Value press Sun Yun abundant method calculating co-toxicity coefficient, the results are shown in Table 1:
Table 1 bromine cyanogen insect amide, indoxacarb and the toxicity test of compounding sample antagonism bollworm thereof and co-toxicity coefficient
In table, data show, antagonism bollworm are had potentiation, in table after bromine cyanogen insect amide and indoxacarb mixture
Listed proportioning co-toxicity coefficient is both greater than 120, and therefore bromine cyanogen insect amide and indoxacarb mixture have significant synergies.
Weigh bromine cyanogen insect amide, indoxacarb uses conventional formulation method to be configured to principle active component weight by different proportion
Percentage composition is the bromine cyanogen insect amide indoxacarb cream of 30%.Concrete ratio is shown in Table 2.
Using feedstuff to add poison method and carry out indoor potentiation bioassay, selection rice-stem borer is target pest, often processes weight
Multiple 3 times, calculate toxicity regression equation and lethal concentration of 50 LC of each medicament antagonism striped rice borer by probability value method50, use LC50Value
Calculate co-toxicity coefficient by the abundant method of Sun Yun, the results are shown in Table 2:
Table 2 bromine cyanogen insect amide, indoxacarb and compounding sample thereof to striped rice borer toxicity test and co-toxicity coefficient
In table, data show, have potentiation, institute in table after bromine cyanogen insect amide and indoxacarb mixture to rice-stem borer
The proportioning co-toxicity coefficient of row is all much larger than 120, and therefore bromine cyanogen insect amide and indoxacarb mixture have significant synergies.
2, field control effectiveness test
Using embodiment institute sample product to carry out the field test of control in field bollworm, comparison medicament is 30% indoxacarb
WDG (water dispersible granules) and 20% bromine cyanogen insect amide WP (wettable powder), be diluted according to the extension rate in form 3,
3 days are looked into after medicine, 7 days, the result of 14 days, result is shown in Table 3:
Table 3 bromine cyanogen insect amide-indoxacarb compounds the field test results of antagonism bollworm
Example has fabulous quick-acting to antagonism bollworm as can be seen from Table 3, and the lasting period is long, in field
Performance is good, is the outstanding medicament preventing and treating antagonism bollworm.
Measure through indoor synergism test and show: by bromine cyanogen insect amide with indoxacarb built agent to bollworm and rice-stem borer
There is significant synergistic insecticidal action;Field control effectiveness test also indicates that all of built agent of the present invention is to bollworm insecticidal effect equally
It is all remarkably higher than the effect of corresponding single dose pesticide.
Claims (10)
1. brominated cyanogen insect amide and a compound pesticide compositions for indoxacarb, is characterized in that this compound pesticide compositions is with bromine cyanogen
Insect amide and indoxacarb are active insecticidal components, wherein, the weight ratio of bromine cyanogen insect amide and indoxacarb be 0.1~80:0.5~
80。
Brominated cyanogen insect amide the most according to claim 1 and the compound pesticide compositions of indoxacarb, is characterized in that described
The weight ratio of bromine cyanogen insect amide and indoxacarb is 1~60:1~60.
Brominated cyanogen insect amide the most according to claim 2 and the compound pesticide compositions of indoxacarb, is characterized in that described
The weight ratio of bromine cyanogen insect amide and indoxacarb is 1~40:1~40.
Brominated cyanogen insect amide the most according to claim 3 and the compound pesticide compositions of indoxacarb, is characterized in that described
The weight ratio of bromine cyanogen insect amide and indoxacarb is 1~30:1~30.
Brominated cyanogen insect amide the most according to claim 1 and the compound pesticide compositions of indoxacarb, is characterized in that bromine cyanogen worm
Amide and both indoxacarbs weight percentage in this compound pesticide compositions are 3%~80%.
Brominated cyanogen insect amide the most according to claim 5 and the compound pesticide compositions of indoxacarb, is characterized in that bromine cyanogen worm
Amide and both indoxacarbs weight percentage in this compound pesticide compositions are 5%~55%.
Brominated cyanogen insect amide the most according to claim 1 and the compound pesticide compositions of indoxacarb, is characterized in that this is combined
Pesticidal combination is with bromine cyanogen insect amide and indoxacarb as active insecticidal components and insecticides adjuvant and excipient are configured on pesticide to permit
The dosage form permitted.
Brominated cyanogen insect amide the most according to claim 7 and the compound pesticide compositions of indoxacarb, is characterized in that described dose
Type is cream, suspending agent, aqueous emulsion, wettable powder, microemulsion or water dispersion granule.
9. the compound pesticide compositions of brominated cyanogen insect amide described in claim 1 and indoxacarb prevents and treats resistance Lepidoptera in preparation
Application on the insecticidal materials of insect.
The compound pesticide compositions of brominated cyanogen insect amide the most according to claim 9 and indoxacarb is at preparation preventing and treating cotton boll
Application on the insecticidal materials of worm or snout moths larva.
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110338194A (en) * | 2019-07-17 | 2019-10-18 | 中国热带农业科学院环境与植物保护研究所 | A kind of granular pesticide for preventing and treating Spodopterafrugiperda |
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CN102283205A (en) * | 2004-07-26 | 2011-12-21 | 杜邦公司 | Mixtures of anthranilamide invertebrate pest control agents |
CN102326577A (en) * | 2011-10-19 | 2012-01-25 | 北京燕化永乐农药有限公司 | Pesticide composition |
EP2962568A1 (en) * | 2014-07-01 | 2016-01-06 | Basf Se | Mixtures comprising a bacillus amyliquefaciens ssp. plantarum strain and a pesticide |
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2016
- 2016-06-21 CN CN201610451240.2A patent/CN106070285A/en active Pending
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102283205A (en) * | 2004-07-26 | 2011-12-21 | 杜邦公司 | Mixtures of anthranilamide invertebrate pest control agents |
CN102326577A (en) * | 2011-10-19 | 2012-01-25 | 北京燕化永乐农药有限公司 | Pesticide composition |
EP2962568A1 (en) * | 2014-07-01 | 2016-01-06 | Basf Se | Mixtures comprising a bacillus amyliquefaciens ssp. plantarum strain and a pesticide |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110338194A (en) * | 2019-07-17 | 2019-10-18 | 中国热带农业科学院环境与植物保护研究所 | A kind of granular pesticide for preventing and treating Spodopterafrugiperda |
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