CN101642131A - Pesticide composition - Google Patents

Pesticide composition Download PDF

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Publication number
CN101642131A
CN101642131A CN200910173092A CN200910173092A CN101642131A CN 101642131 A CN101642131 A CN 101642131A CN 200910173092 A CN200910173092 A CN 200910173092A CN 200910173092 A CN200910173092 A CN 200910173092A CN 101642131 A CN101642131 A CN 101642131A
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Prior art keywords
fosthiazate
days
nimbin
root
nematode
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Inventor
张洪
曹明章
殷如龙
刘胜召
王新军
孔建
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Shenzhen Noposion Agrochemicals Co Ltd
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Shenzhen Noposion Agrochemicals Co Ltd
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Abstract

The invention relates to a pesticide composition comprising the active components including (A) which is fosthiazate, and (B) which is at least one of abamectin and azadirachtin. The mass ratio of A to B is 100:1-1:50. By combining A and B, the composition has obvious synergistic effect and is used for controlling the pests on such crops as fruit trees, cotton, wheat, rice, rape, vegetables, flowers and the like, especially for controlling nematodes.

Description

A kind of composition pesticide
Technical field
The present invention relates to a kind of Pesticidal combination, especially a kind of composition pesticide that contains fosthiazate.
Background technology
Plant nematode mainly comprises: Meloidogyne (Meloidogyne), kidney shape Turbatrix (Rotylenchulus), cyst roundworm (Heterodera (Heterodera)), root spot nematode (Pratylenchidae belongs to (Pratykenchus)).Directly searching for food of nematode can significantly reduce the absorption of plant to nutrition and moisture, and the nematode plant that searches for food is caused wound, returns the phytopathogen invasion and provides convenience.
Nematode chemical control possibility is few at present, and the control nematode concentrates on substantially and prevents the invasion and attack of nematode to plant on the agricultural.In case plant by parasitism, must be caused the infringement to plant, thereby to provide new nematoda control composition to prevent or reduce nematode damage be favourable.
And, still adopt phonamiphos, cadusafos, the contour malicious agricultural chemicals of carbofuran to a great extent at present for nematoda control, and there is very big environment secret worry, alternative low toxicity nematocide is seldom.Fosthiazate is a kind of organic phosphor low toxicity desinsection, nematocide, and is effective to a lot of harmful insects, and various nematodes are had the good activity of killing.But fosthiazate uses consumption big separately, and long-term use must bring out nematode and produce resistance, is unfavorable for Sustainable Control.
Summary of the invention
The objective of the invention is to: the safety that contains fosthiazate, the synergetic pesticide composition that use on a kind of suitable agricultural, nematode, soil insect had outstanding control efficiency are provided.
We find to have synergistic effect by the composition that comprises fosthiazate (A) and at least a biogenic pesticide (B) Avermectin (B-1) or nimbin (B-2) when preventing and treating nematodosis, with only use independent active component and can obtainable control efficiency compare, active components A and B are mixed the back use, or use compd A and B simultaneously separately, or use A and B to provide better control efficiency successively to pest.
Mixture of the present invention has synergistic function, and therefore is specially adapted to prevent and treat the parasitic nematode in parasitic nematode and soil insect, especially cereal class, vegetables, fruit, the ornamental plants that endangers plant root.
Comprise fosthiazate (A) and at least a biogenic pesticide (B) Avermectin (B-1) or nimbin (B-2) in the present composition, even a small amount of A or B are for realizing that Synergistic also is enough, A and B mass ratio are 100: 1-1: 50, preferred 50: 1-1: 10, most preferably 20: 1-1: 1.
When the preparation mixture, preferred pure active components A and B, also can use the former medicine of high-load, can also be to wherein adding other reactive compound to harmful fungoid or other insect such as insect, spider or nematode, or have the compound or the fertilizer of herbicide effect or growth regulating effect.
The present composition can be prevented and treated the pest in various crops such as cotton, vegetables (as cucumber, beans, tomato, potato and cucurbitaceous plant), barley, dogstail, oat, banana, coffee, corn, fruits, rice, rye, soybean, wheat, ornamental plants, sugarcane and the seed, as nematode, diamond-back moth, cabbage caterpillar, rice leaf roller, smaller green leaf hopper, tea geometrid etc.
The present composition is particularly suitable for preventing and treating plant nematode, for example Pratylenchidae (Pratykenchusspp), similar similes thorne (Radopholous similis), fuller's teasel stem eelworm (Ditylenchusdipsaci), the nematode (Tylenchulus semipenetrans) of partly puncturing, Heterodera kind (Heterodera spp.), ball Heterodera kind (Globodera spp.), Meloidogyne kind (Meloidogyne spp.), kidney shape Turbatrix kind (Rotylenchulus spp.), Aphelenchoides kind (Aphelenchoides spp.), minute hand Turbatrix kind (Longidorus spp.), Xiphinema kind (Xiphinema spp.), burr Turbatrix kind (Trichodorus spp.), umbrella Aphelenchoides kind (Bursaphelenchus spp.).
Preferably mixture of the present invention is used to prevent and treat the nematodosis of oil crop such as cereal class, paddy rice, wheat, fruit tree, cotton, vegetables, soybean, flowers etc., as wheat root-knot nematode, oranges and tangerines root-knot nematode, cucumber root-knot nematode, soy bean cyst roundworm, capsicum root-knot nematode etc.
The present composition can be prepared into known method and be fit to the formulation that agricultural is used, and the total content of active ingredient is 1%-90% in the preparation, preferred 5-80%, and all the other are the pesticide adjuvant composition.
Forming the effective constituents A of the present composition and B can be simultaneously (be about to A and B uses together or use compd A and B simultaneously separately), also can use A and B successively, and this moment, order was usually to the not influence of result of control.
Agricultural chemicals cooperative compositions of the present invention can be formulated as suspending agent, aqueous emulsion, microemulsion, missible oil, wetting powder, the water dispersible granules that directly to spray or to carry out soil treatment, also can be made into granule and directly carry out soil treatment.
Control crop nematode preferred dosage form is a granule.
Preparation prepares in a known way, for example prepares by reactive compound is mixed with solvent and/or carrier, if the words that need are used other pesticide adjuvant compositions such as emulsifier and dispersant.
Insecticide-applying way can take spraying, irritate root, soak root, get rid of and execute, spread fertilizer over the fields, ditch spread, spread manuer in holes etc., preferred ditch spread during the control nematode, spreads manuer in holes, irritates soil treatment such as root or soak root and handle.
Compared with prior art, the beneficial effect of the present invention's generation is: (1) is compared with single agent, and this Pesticidal combination is obvious to insect synergy, has improved control efficiency, has enlarged insecticidal spectrum; (2) can significantly reduce the field dosage, reduce the possibility that causes poisoning, reduce and produce and use cost, and can effectively reduce environmental pollution and residue of pesticide; (3) mechanism of action of active ingredient is different in the Pesticidal combination, has reduced the single selection pressure to pest, helps overcoming the disease resistance and delays the drug-fast generation speed of pest; (4) Pesticidal combination has good control efficiency to all kinds of nematodosis.
Embodiment
In order to make purpose of the present invention, technical scheme and advantage clearer, the present invention describes with following specific embodiment, but the present invention is only limited to these examples absolutely not.
The synergistic function of the present composition can illustrate by following test:
Biologicall test example: the composite toxicity test of fosthiazate and Avermectin or nimbin to the capsicum root-knot nematode
Subjects: capsicum root-knot nematode (Meloidogyne incognita)
Evaluation method soup infusion method.Reactive compound adds an amount of acetone solution on request, is diluted to the mother liquor of 10000ppm as testing liquid with purified water then.Then mother liquor is diluted to 2 times of concentration of experimental concentration, in each hole of 96 orifice plates, add 100 μ l respectively, and then add the root-knot nematode suspension of equivalent, place in the dark place under 25 ℃ one week the back with survival number of the nematode in each hole of microscopic counting and death toll.
The drug effect computational methods:
Figure G2009101730922D00041
The expection effectiveness use Colby formula of active compound combinations is determined and is compared with observed effectiveness:
Colby formula: E=X+Y-X*Y/100
E: reactive compound A working concentration is a in composition, and the compositions contemplated when reactive compound B working concentration is b is renderd a service,
X: the effectiveness when reactive compound A using dosage is a,
Y: the effectiveness when reactive compound B using dosage is b.
When surpassing the effectiveness of calculating, observed control efficiency shows as synergistic effect.
Toxicity test result referring to table 1 to table 3.
The independent reactive compound of table 1 is to the Toxicity Determination result of capsicum root-knot nematode
Figure G2009101730922D00051
Table 2 mixture of the present invention is to the Toxicity Determination result of capsicum root-knot nematode
Implement Activity compound concentration in the mixed liquor (ppm) Observed effectiveness (%) The effectiveness of calculating (%)
??1 Fosthiazate 1500: Avermectin 30 ??90.5 ????74.4
??2 Fosthiazate 1000: Avermectin 50 ??92.9 ????69.9
??3 Fosthiazate 500: Avermectin 50 ??84.9 ????63.8
??4 Fosthiazate 500: Avermectin 100 ??90.3 ????76.0
??5 Fosthiazate 100: Avermectin 100 ??82.4 ????66.3
??6 Fosthiazate 30: Avermectin 150 ??89.1 ????72.1
??7 Fosthiazate 20: Avermectin 200 ??96.4 ????79.6
??8 Fosthiazate 10: Avermectin 200 ??93.8 ????78.9
??9 Fosthiazate 4ppm: Avermectin 200ppm ??91.5 ????78.9
Result of the test shows, fosthiazate and abamectin compounded control capsicum root-knot nematode, and proportioning is 50: 1-1: in the time of between 50, all have synergistic effect.
The serial proportioning of table 3 fosthiazate and nimbin is to the Toxicity Determination result of capsicum root-knot nematode
Implement Reactive compound proportioning (ppm) Observed effectiveness (%) The effectiveness of calculating (%)
??1 Fosthiazate 1500: nimbin 30 ??96.5 ??84.2
??2 Fosthiazate 1000 nimbins 50 ??96.8 ??82.3
??3 Fosthiazate 500: nimbin 50 ??91.8 ??78.7
??4 Fosthiazate 100: nimbin 20 ??78.2 ??44.5
??5 Fosthiazate 30: nimbin 30 ??68.7 ??54.0
??6 Fosthiazate 20: nimbin 100 ??92.5 ??81.9
??7 Fosthiazate 10: nimbin 100 ??91.7 ??81.2
??8 Fosthiazate 4: nimbin 80 ??88.4 ??76.5
??9 Fosthiazate 2: nimbin 100 ??90.8 ??81.2
Result of the test shows, the composite control of fosthiazate and nimbin capsicum root-knot nematode, and proportioning is 50: 1-1: in the time of between 50, all have synergistic effect.
Bactericidal composition of the present invention can be prepared into known method and be fit to granule, suspending agent, aqueous emulsion, microemulsion, missible oil, wetting powder or the water dispersible granules that agricultural is used.Below describe with specific embodiment, percentage is mass percent in the prescription.Active component refers to fosthiazate and Avermectin or nimbin in the present specification, below repeats no more.
One, suspending agent processing and application example
The ratio of each component such as active component, wetting dispersing agent, thickener, carrier and water in prescription mixed, after grinding and/or high speed shear, obtain suspending agent.
Embodiment 1:10.2% fosthiazate Avermectin suspending agent
Fosthiazate 10%, Avermectin 0.2%, methyl naphthalene sulfonate formaldehyde condensate 10%, sodium lignosulfonate 10% xanthans 1%, silicone oil 1%, glycerine 5%, water complements to 100%.
This embodiment is applied to prevent and treat the capsicum root knot nematode disease.10.2% fosthiazate Avermectin suspending agent is drenched ground by 1020ga.i./ha (ga.i./ha is the per hectare effective ingredient consumption) consumption thin up, and the control efficiency of 10 days and 20 days is respectively 85.5%, 84.2% behind the medicine.1500ga.i./ha pressed by 15% fosthiazate suspending agent and 1.8% abamectin emulsifiable concentrate is pressed 80ga.i./ha, in kind uses.The preventive effect of 10 days and 20 days is respectively 76.1%, 73.2% behind the 15% fosthiazate suspending agent medicine; The preventive effect of 10 days and 20 days is respectively 71.7%, 64.6% behind the 1.8% abamectin emulsifiable concentrate medicine.Fosthiazate and the synergistic effect of abamectin compounded back are obvious, to the preventive effect of capsicum root-knot nematode significantly better than single agent.
Embodiment 2:24% fosthiazate nimbin suspending agent
Fosthiazate 20%, nimbin 4%, polyoxyethylene nonylphenol ether phosphate 8%, carboxymethyl cellulose 1%, white carbon 1%, glycerine 4%, water complements to 100%.
This embodiment is applied to prevent and treat tomato root-knot eelworm.24% fosthiazate nimbin suspending agent is soaked root 12h by the 300ga.i./ha thin up handle, the control efficiency of 10 days and 20 days is respectively 91.5%, 86.2% behind the medicine.1000ga.i./ha pressed by 10% fosthiazate missible oil and 8% nimbin suspending agent is pressed 70ga.i./ha, in kind uses, and the preventive effect of 10 days and 20 days is respectively 72.3%, 66.3% behind the 10% fosthiazate suspending agent medicine; The preventive effect of 10 days and 20 days is respectively 67.4%, 65.6% behind the 8% nimbin suspending agent medicine.The synergistic effect of the composite back of fosthiazate and nimbin is obvious, to the preventive effect of tomato root-knot eelworm significantly better than single agent.
Two, aqueous emulsion processing and application example
Active component, solvent, emulsifier are added together, make and be dissolved into even oil phase; Under high-speed stirred, oil phase added in the entry mix, make aqueous emulsion.
Embodiment 3:20% fosthiazate abamectin aqueous emulsion
Fosthiazate 15%, Avermectin 5%, N-Methyl pyrrolidone 10%, calcium dodecyl benzene sulfonate 5%, agricultural newborn 600#5%, water complements to 100%.
This embodiment is applied to prevent and treat the cucumber root-knot nematode.20% fosthiazate abamectin aqueous emulsion is pressed the 600ga.i./ha thin up drench ground, the control efficiency of 10 days and 20 days is respectively 91.7%, 86.3% behind the medicine.60% fosthiazate water dispersible granules presses 1500ga.i./ha and 5% abamectin emulsifiable concentrate is pressed 300ga.i./ha, in kind uses.The preventive effect of 10 days and 20 days is respectively 73.2%, 68.2% behind the 60% fosthiazate water dispersible granules medicine; The preventive effect of 10 days and 20 days is respectively 80.8%, 74.3% behind the 8% abamectin emulsifiable concentrate medicine.Fosthiazate and the synergistic effect of abamectin compounded back are obvious, to the preventive effect of cucumber root-knot nematode significantly better than single agent.
Three, microemulsion processing and application example
Active component, solvent, cosolvent, emulsifier are added together, make and be dissolved into even oil phase; Water-soluble substances is added in the entry, even water in the dissolving, under agitation that oil phase is mixed with water evenly, make microemulsion.
Embodiment 4:5% fosthiazate micro nimbin emulsion
Fosthiazate 4%, nimbin 1%, N-Methyl pyrrolidone 10%, isopropyl alcohol 10%, agricultural newborn 500#5%, agricultural newborn 1601#5%, water complements to 100%.
This embodiment is applied to prevent and treat peanut root-knot nematode.5% fosthiazate micro nimbin emulsion is pressed the 500ga.i./ha thin up drench ground, the control efficiency of 10 days and 20 days is respectively 97.2%, 96.3% behind the medicine.1000ga.i./ha pressed by 10% fosthiazate suspending agent and 12% nimbin suspending agent is pressed 120ga.i./ha, in kind uses, and the preventive effect of 10 days and 20 days is respectively 77.4%, 71.3% behind the 10% fosthiazate suspending agent medicine; The preventive effect of 10 days and 20 days is respectively 86.3%, 84.3% behind the 12% nimbin suspending agent medicine.The synergistic effect of the composite back of fosthiazate and nimbin is obvious, to the preventive effect of peanut root-knot nematode significantly better than single agent.
Embodiment 5:1.1% fosthiazate avermectin micro-emulsion
Fosthiazate 0.1%, Avermectin 1%, N-Methyl pyrrolidone 10%, isopropyl alcohol 10%, agricultural newborn 500#5%, agricultural newborn 1601#5%, water complements to 100%.
This embodiment is applied to prevent and treat soy bean cyst roundworm.1.1% fosthiazate avermectin micro-emulsion is pressed 120ga.i./ha consumption thin up irritate root, the control efficiency of 10 days and 20 days is respectively 80.7%, 74.3% behind the medicine.500ga.i./ha pressed by 20% fosthiazate missible oil and 5% abamectin emulsifiable concentrate is pressed 150ga.i./ha, in kind uses, and the preventive effect of 10 days and 20 days is respectively 67.4%, 60.3% behind the 20% fosthiazate missible oil medicine; The preventive effect of 10 days and 20 days is respectively 70.1%, 68.4% behind the 5% abamectin emulsifiable concentrate medicine.Fosthiazate and the synergistic effect of abamectin compounded back are obvious, to the preventive effect of soy bean cyst roundworm significantly better than single agent.
Four, missible oil processing and application example
Active component, solvent, emulsifier are added in the mixing kettle successively in the ratio of prescription, stir, make missible oil.
Embodiment 6:21% fosthiazate abamectin emulsifiable concentrate
Fosthiazate 20%, Avermectin 1%, N-Methyl pyrrolidone 10%, agricultural newborn 1601#5%, agricultural newborn 500#5%, calcium dodecyl benzene sulfonate 3%, dimethylbenzene complements to 100%.
This embodiment is applied to the balsam pear root-knot nematode.21% fosthiazate abamectin emulsifiable concentrate is pressed 700ga.i./ha thin up root irrigation, and the control efficiency of 10 days and 20 days is respectively 84.8%, 83.4% behind the medicine.1000ga.i./ha pressed by 20% fosthiazate suspending agent and 5% abamectin emulsifiable concentrate is pressed 100 μ g/ml, in kind uses.The preventive effect of 10 days and 20 days is respectively 74.9%, 68.5% behind the 20% fosthiazate suspending agent medicine; The preventive effect of 10 days and 20 days is respectively 71.7%, 67.4% behind the 5% abamectin emulsifiable concentrate medicine.Fosthiazate and the synergistic effect of abamectin compounded back are obvious, to the preventive effect of balsam pear root-knot nematode significantly better than single agent.
Five, wetting powder processing and application example
Active component, various auxiliary agent and filler etc. are fully mixed in the ratio of prescription, after ultrafine crusher is pulverized, promptly get wetting powder.
Embodiment 7:20.4% fosthiazate nimbin wetting powder
Fosthiazate 0.4%, nimbin 20%, lauryl sodium sulfate 2%, sodium lignin sulfonate 5%, naphthalene sulfonate 3%, kaolin complements to 100%.
This embodiment is applied to the romaine lettuce root-knot nematode.20.4% fosthiazate nimbin wetting powder is pressed 102ga.i./ha consumption thin up drench ground, the control efficiency of 10 days and 20 days is respectively 88.6%, 87.3% behind the medicine.1000ga.i./ha pressed by 10% fosthiazate suspending agent and 20% nimbin wetting powder is pressed 120ga.i./ha, in kind uses.The preventive effect of 10 days and 20 days is respectively 68.1%, 62.2% behind the 10% fosthiazate suspending agent medicine; The preventive effect of 10 days and 20 days is respectively 84.4%, 81.3% behind the 20% nimbin wetting powder medicine.The synergistic effect of the composite back of fosthiazate and nimbin is obvious, to the preventive effect of romaine lettuce root-knot nematode significantly better than single agent.
Six, water dispersible granules processing and application example
Active component, dispersant, wetting agent, disintegrant and the filler ratio in prescription is mixed, become wetting powder, add a certain amount of water mixing extruding again and make material through comminution by gas stream.Obtain water dispersible granules after the drying screening.
Embodiment 8:60% fosthiazate water dispersed nimbin granule
Fosthiazate 50%, nimbin 10%, Negel 4%, sodium lignin sulfonate 2%, lauryl sodium sulfate 5%, sulfuric acid amine 2% kaolin complements to 100%.
This embodiment is applied to prevent and treat the tobacco root-knot nematode.60% fosthiazate water dispersed nimbin granule is pressed the 300ga.i./ha thin up drench ground, the control efficiency of 10 days and 20 days is respectively 93.9%, 90.2% behind the medicine.40% fosthiazate water dispersible granules is pressed 1000ga.i./ha, and 20% water dispersed nimbin granule is pressed 100ga.i./ha, in kind uses.The preventive effect of 10 days and 20 days is respectively 71.2%, 65.1% behind the 40% fosthiazate water dispersible granules medicine; The preventive effect of 10 days and 20 days is respectively 84.6%, 82.4% behind the 20% water dispersed nimbin granule medicine.The synergistic effect of the composite back of fosthiazate and nimbin is obvious, to the preventive effect of tobacco root-knot nematode significantly better than single agent.
Seven, granule processing and application example
Active component, other auxiliary element are mixed successively in the ratio of prescription, and dressing makes granule
Embodiment 9:5% fosthiazate Avermectin granule
Fosthiazate 4%, Avermectin 1%, white carbon 2%, adhesive 1%, colouring agent 0.5%, granular calcium carbonate complements to 100%.
This embodiment is applied to prevent and treat the oranges and tangerines root-knot nematode.5% fosthiazate Avermectin granule is pressed the 600g.a.i/ha ditch spread handle, the control efficiency of 10 days and 20 days is respectively 93.9%, 91.4% behind the medicine.8% fosthiazate granule is pressed 800g.a.i/ha, and 5% Avermectin granule is pressed 250g.a.i/ha, in kind uses, and the preventive effect of 10 days and 20 days is respectively 71.7%, 65.4% behind the 8% fosthiazate granule medicine; The preventive effect of 10 days and 20 days is respectively 80.4%, 74.5% behind the 5% Avermectin granule medicine.Fosthiazate and the synergistic effect of abamectin compounded back are obvious, to the preventive effect of oranges and tangerines root-knot nematode significantly better than single agent.
Embodiment 10:6% fosthiazate nimbin granule
Fosthiazate 5%, nimbin 1%, potter's clay 10%, adhesive 1%, colouring agent 0.5%, dispersant 0.5%, silica sand complements to 100%.
This embodiment is applied to prevent and treat root-knot nematode.6% fosthiazate nimbin granule is pressed the ditch spread of 480g.a.i/ha consumption handle, the control efficiency of 10 days and 20 days is respectively 95.9%, 94.7% behind the medicine.5% fosthiazate granule is pressed 1000g.a.i/ha, and 3% nimbin granule is pressed 100g.a.i/ha, in kind uses.The preventive effect of 10 days and 20 days is respectively 73.2%, 68.1% behind the 5% fosthiazate granule medicine; The preventive effect of 10 days and 20 days is respectively 81.6%, 77.4% behind the 3% nimbin granule medicine.The synergistic effect of the composite back of fosthiazate and nimbin is obvious, to the preventive effect of root-knot nematode significantly better than single agent.

Claims (8)

1, a kind of composition pesticide is characterized in that: contain fosthiazate (A) and at least a biogenic pesticide (B) in the composition, wherein, biogenic pesticide (B) is Avermectin (B-1) or nimbin (B-2).
2, according to claim 1, it is characterized in that: the mass ratio of effective constituents A and B is 100: 1-1: 50.
3, according to claim 1, it is characterized in that: the mass ratio of effective constituents A and B is 50: 1-1: 10.
4, according to claim 1, it is characterized in that: the mass ratio of effective constituents A and B is 20: 1-1: 1.
5, according to claim 1 to 4 each, it is characterized in that: effective constituents A and the B gross mass percentage composition in composition is 1%-90%, and all the other are the pesticidal preparations auxiliary element.
6, according to claim 5, it is characterized in that: the formulation of described composition pesticide is suspending agent, aqueous emulsion, microemulsion, missible oil, wetting powder, water dispersible granules or granule.
7, the described composition pesticide of claim 1 is used to prevent and treat the crop pest.
8, the described composition pesticide of claim 1 is is preferably prevented and treated crop nematode, soil insect.
CN200910173092A 2009-09-08 2009-09-08 Pesticide composition Pending CN101642131A (en)

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CN102204564A (en) * 2011-04-27 2011-10-05 成都科利隆生化有限公司 Pesticide composition containing fosthiazate and carbosulfan
CN102265901A (en) * 2011-05-17 2011-12-07 广西田园生化股份有限公司 Abamectin.lythidathion pesticide composition
CN102349539A (en) * 2011-08-10 2012-02-15 陕西美邦农药有限公司 Insecticidal composition containing lythidathion and antibiotic compound
CN102972439A (en) * 2012-12-18 2013-03-20 联保作物科技有限公司 Abamectin.fosthiazate slow-release granule and preparation method thereof
CN103416426A (en) * 2012-05-23 2013-12-04 陕西韦尔奇作物保护有限公司 Insecticide composition containing fosthiazate and pyrethroids
WO2014034155A1 (en) * 2012-08-27 2014-03-06 丸和バイオケミカル株式会社 Chemical agent for controlling soil nematode which comprises macrolide-type compound
CN103749530A (en) * 2013-12-30 2014-04-30 孙蒙蒙 Insecticidal composition containing abamectin
CN103798283A (en) * 2014-02-19 2014-05-21 罗晓丹 Nematicide containing azadirachtin and lythidathion
CN103918731A (en) * 2014-04-14 2014-07-16 山东圣鹏科技股份有限公司 Pesticide composition for killing plant root-knot nematode
CN104782653A (en) * 2015-02-11 2015-07-22 佛山市盈辉作物科学有限公司 Avermectin B 2 and fosthiazate insecticidal pesticide composition
CN105028470A (en) * 2015-06-23 2015-11-11 肇庆市真格生物科技有限公司 Nematicidal composition containing fosthiazate and application thereof
CN107047609A (en) * 2017-04-20 2017-08-18 深圳诺普信农化股份有限公司 A kind of microcapsule suspending agent
CN107347908A (en) * 2017-08-21 2017-11-17 山东华阳农药化工集团有限公司 A kind of compound Avermectins compound finish of ultra-low volume fosthiazate and preparation method
CN108651496A (en) * 2018-07-03 2018-10-16 陕西康禾立丰生物科技药业有限公司 A kind of composition pesticide containing fenbendazole

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CN102204564B (en) * 2011-04-27 2013-10-23 成都科利隆生化有限公司 Pesticide composition containing fosthiazate and carbosulfan
CN102204564A (en) * 2011-04-27 2011-10-05 成都科利隆生化有限公司 Pesticide composition containing fosthiazate and carbosulfan
CN102265901A (en) * 2011-05-17 2011-12-07 广西田园生化股份有限公司 Abamectin.lythidathion pesticide composition
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Application publication date: 20100210