CN102265901A - Abamectin.lythidathion pesticide composition - Google Patents
Abamectin.lythidathion pesticide composition Download PDFInfo
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- CN102265901A CN102265901A CN2011101275597A CN201110127559A CN102265901A CN 102265901 A CN102265901 A CN 102265901A CN 2011101275597 A CN2011101275597 A CN 2011101275597A CN 201110127559 A CN201110127559 A CN 201110127559A CN 102265901 A CN102265901 A CN 102265901A
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Abstract
The invention relates to an abamectin.lythidathion pesticide composition. The abamectin.lythidathion pesticide composition is prepared into suspending agents, granules, wettable powder, water dispersible granules, aqueous emulsions, micro-capsule suspending agents, and the like in the weight ratio of 1:(5-40). The abamectin.lythidathion pesticide composition disclosed by the invention has enlarged insecticidal spectrum compared with that of the abamectin and the lythidathion, has multiple acting sites on insects, is used for controlling various aboveground and underground insects of lepidoptera, homoptera, coleoptera, diptera, and the like on field crops, fruit trees, vegetables and other special crops and in greensward, can be applied to various pesticide application modes, such as, spraying, soil blending spreading, furrow application, hole application, fertigation, and the like, and can reduce the application dosages of various bioactivators, thereby having reduced using cost, achieving the chemical complementarity and playing obvious roles in synergizing and delaying the generation of insect resistance; and in addition, the abamectin.lythidathion pesticide composition disclosed by the invention has the advantages of high efficiency, long acting period, and the like.
Description
Technical field
The present invention relates to a kind of composition pesticide, relate to a kind of insecticides that contains Avermectin and lythidathion specifically.
Background technology
Avermectin is a kind of macrolide disaccharide compounds, and tool is tagged, stomach poison function, and very strong penetration is arranged.Avermectin is the natural products that separates from edaphon, insect and mite class had tag and stomach poison function and faint fumigation action is arranged, no systemic action, but it has very strong osmosis to blade, can kill subepidermal insect, and the longevity of residure is long, and it all has good preventive effect to various pests such as Lepidoptera, coleoptera, thripss.
Lythidathion is the novelty of Japanese Shi Yuan company exploitation, the non-fumigation type organic phosphor desinsection nematocide of efficient, broad spectrum activity, and has put on market in many countries such as Japan.Primary Study shows, inhales translocation in lythidathion has in plant corpus, and plant nematode and insect are had broad spectrum of activity.Plant nematode endangers many important crops, and the biology of lythidathion and physicochemical property are fit to native top application medicine very much, so become the desirable medicament of control plant nematode, therefore lythidathion is the nematocide of a kind of efficient, low toxicity, wide spectrum, safety, will become following main component at root-knot nematode.
At present existingly contain Avermectin and the retrieval of lythidathion insecticides is as follows:
Chinese patent: 200910173092.2, denomination of invention: a kind of composition pesticide, this invention relates to a kind of composition pesticide, and its active ingredient is selected from least a in Avermectin and the nimbin for (A) fosthiazate with (B), and the mass ratio of A and B is 100: 1-1: 50.Have synergistic effect preferably after A and B are composite, be used for the control of insect of fruit tree, cotton, wheat, paddy rice, rape, vegetables, flowers and other crops, especially nematoda control.
But because Avermectin is the highly active composition of a class, its usage amount can reach the control efficiency of the comparison rational faculty under lower situation, and under composite situation of carrying out composition, the content of Avermectin needs strict consideration.Verifying through test and actual the use, fosthiazate and Avermectin make up and have very big relation between the ratio of its combination and content and the preventive effect, A that speaks approvingly of in this patent and the mass ratio of B are 100: 1-1: 50, this mass ratio comprises that scope is wider, but both combinations do not reach rational synergy and control efficiency under the part mass ratio.
Summary of the invention
The objective of the invention is shortcoming and the existing problem that contains these two kinds single agent compositions existence in order to overcome above-mentioned two kinds of one-pack type insecticides, and provide a kind of optimal proportion that contains Avermectin and fosthiazate to make up synergistic formula, not only enlarge the range of application of these two kinds of insecticides, under guaranteeing the situation of optimum control efficiency, notable synergistic reduces simultaneously the usage amount of medicament, reduce a mu usage amount, thereby reduce cost and reduce environmental hazard.
The present invention is achieved in that
Avermectin lythidathion insecticides is characterized in that: the weight ratio of Avermectin and lythidathion is: 1: 5~40.
With above-described Avermectin. the lythidathion insecticides is configured to suspending agent, and its component comprises Avermectin and lythidathion, and dispersant, wetting agent, thickener, stabilizing agent and solvent, and the percentage by weight of various components is:
Above-described dispersant be NNO, MF, SOPA270, lignosulfonates, polyethers, in a kind of or any several combination.
Above-described wetting agent is K12, NPE, AEO series, ooze a kind of or any several combination in T, alkyl phenol (or fatty alcohol) polyoxyethylene poly-oxygen propylene aether and the sulphate (or phosphoric acid fat) thereof.
Above-described stabilizing agent is potassium sorbate, Sodium Benzoate, formaldehyde, BIT (1, the 2-benzisothiazole-3-ketone), triumphant pine, epoxychloropropane, epoxidized vegetable oil, tributyl phosphate, alkylphenol polyoxyethylene phosphoric acid fat and salt thereof, 2 hexylene glycol [2,4], hexylene glycol [2,5], a kind of or any several combination in the pentanediol [1,5].
A kind of or any several combination in above-described thickener: CMC, xanthic acid, PVA, sodium alginate, gum Arabic, bentonite, white carbon, aluminium-magnesium silicate, the starch.
Above-described solvent is a deionized water.
Above-described composition also can be prepared into common formulations such as missible oil, granule, wetting powder, water dispersible granules, aqueous emulsion, microcapsule suspending agent.
The collocation method of insecticides suspending agent of the present invention is: Avermectin, lythidathion, dispersant, wetting agent, stabilizing agent, thickener are dropped in the mixing kettle and stir, at first the material of mixing is crossed colloid mill, open cycle water then, with the material ball milling with a certain amount of flow, below temperature control 40 degree, fineness is crossed 325 mesh sieves, treat every index detect qualified after, carry out packing, semi-finished product get final product Pesticidal combination suspending agent of the present invention.
Advantage of the present invention:
(1) enlarged the insecticidal spectrum of Avermectin and lythidathion, Avermectin and lythidathion belong to the pesticide compositional of different insecticidal action mechanism, many to the insect action site, the present composition can be used for preventing and treating various grounds and underground insects such as Lepidoptera in field crops, fruit tree, vegetables, other special crops and the turf, Homoptera, coleoptera, diptera.
(2) composition of the present invention can be applicable to spray, mixes that soil spreads fertilizer over the fields, ditch spread, spreads manuer in holes, irritates and various possible insecticide-applying way such as execute, and can reduce the application dosage of each bioactivator, thereby reduced use cost, and can reach the medicament complementation, play notable synergistic, delay the effect that pest resistance produces.
(3) insecticides of the present invention provides the portfolio ratio of Avermectin and two kinds of insecticide the bests of fosthiazate, make it reach the effect of the low preventive effect optimum of usage amount, reduce peasant household and use mu to become, reach top gain, and reduced harm when reducing usage amount environment.
Description of drawings
Embodiment
The invention will be further described below in conjunction with specific embodiment, but be not limitation of the invention.
Embodiment 1: Avermectin: lythidathion=2: 20 suspending agents
648 gram deionized waters in the suction agitator tank, with 40 gram SOPA270,25 gram K12,5 gram formaldehyde, 50 grams, pentanediol [1,5], in the suction agitator tank, the limit is stirred 20 gram Avermectin, 200 gram lythidathions, 2 gram Sodium Benzoates, 10 gram white carbons, is dropped in order and shear jar then, shears to make mixing of materials even in 30 minutes.Open cycle water, with a certain amount of flow, below temperature control 40 degree, fineness is crossed 325 mesh sieves, promptly gets 22% Avermectin lythidathion insecticides suspending agent with the material ball milling.
Embodiment 2: Avermectin: lythidathion=1: 30 suspending agent
551 gram deionized waters in the suction agitator tank, with 45 gram NNO, 25 gram lignosulfonates and 5 gram NPE, 2 Ke Kaisong, 50 grams hexylene glycol [2,5], in the suction agitator tank, the limit is stirred 10 gram Avermectin, 300 gram lythidathions, 2 gram xanthans, 10 gram aluminium-magnesium silicates, is dropped in order and shear jar then, shears to make mixing of materials even in 30 minutes.Open cycle water, with a certain amount of flow, below temperature control 40 degree, fineness is crossed 325 mesh sieves, promptly gets 31% Avermectin lythidathion insecticides suspending agent with the material ball milling.
Embodiment 3: Avermectin: lythidathion=5: 25 suspending agents
550 gram deionized waters in the suction agitator tank, with 40 gram NNO, 20 gram lignosulfonates and 10 gram NPE, 3 Ke Kaisong, 60 grams hexylene glycol [2,5], in the suction agitator tank, the limit is stirred 50 gram Avermectin, 250 gram lythidathions, 2 gram xanthans, 15 gram aluminium-magnesium silicates, is dropped in order and shear jar then, shears to make mixing of materials even in 30 minutes.Open cycle water, with a certain amount of flow, below temperature control 40 degree, fineness is crossed 325 mesh sieves, promptly gets 30% Avermectin lythidathion insecticides suspending agent with the material ball milling.
Embodiment 4: Avermectin: lythidathion=0.5: 20 microcapsule suspending agent
With Avermectin 5 grams, lythidathion 200 grams are dissolved in the 50 gram dimethylbenzene, suction tributyl phosphate 3 restrains again, CMC 30 grams, sodium alginate 30 grams were sheared 30 minutes in high shear still high speed, add 200 gram urea resin prepolymer, 2000 rev/mins of stirrings heat up down and solidified 60 minutes, add 400 gram deionized waters afterwards, 60 gram NNO dispersants, 22 the gram bentonites, stir get final product 20.5% Avermectin fosthiazate microcapsule suspending agent.
Embodiment 5: Avermectin: lythidathion=5: 30 microcapsule suspending agents
With Avermectin 50 grams, lythidathion 300 grams are dissolved in the 80 gram dimethylbenzene, suction tributyl phosphate 3 restrains again, the CMC30 gram, sodium alginate 30 grams were sheared 30 minutes in high shear still high speed, add 250 gram urea resin prepolymer, 2000 rev/mins of stirrings heat up down and solidified 60 minutes, add 178 gram deionized waters afterwards, 54 gram NNO dispersants, 25 the gram bentonites, stir get final product 35% Avermectin fosthiazate microcapsule suspending agent.
Embodiment 6: Avermectin: lythidathion=0.1: 2 granule
Avermectin 1 gram, lythidathion 20 grams, polyvinyl alcohol 10 grams, ethanol 10 grams, gum Arabic 1 gram stirs, adopt the mode of high-pressure fog evenly to be sprayed onto on the load weighted 958 gram zeolites then, fully after the stirring and adsorbing, get final product 2.1% Avermectin lythidathion insecticides granule.
Embodiment 7: Avermectin: lythidathion=1: 10 granule
With Avermectin 10 grams, lythidathion 100 grams, the MF10 gram, potassium sorbate 20 grams, PVA3 gram, epoxidized vegetable oil 30 grams, stir, adopt the mode of high-pressure fog evenly to be sprayed onto on the load weighted 827 gram activation sepiolites then, fully after the stirring and adsorbing, get final product 11% Avermectin lythidathion insecticides granule.
Embodiment 8: Avermectin: lythidathion=2: 30 wetting powders
With Avermectin 20 grams, lythidathion 300 grams, sodium lignin sulfonate 40 grams, alkyl phenol (or fatty alcohol) polyoxyethylene poly-oxygen propylene aether sulphate 40 grams, 2 hexylene glycol [2,4] 30 grams, white carbon 100 grams, kaolin 470 grams stir, employing comminution by gas stream processing, get final product 32% Avermectin lythidathion insecticides wetting powder.
Embodiment 9: Avermectin: lythidathion=0.5: 20 wetting powder
With Avermectin 5 grams, lythidathion 200 grams, calcium lignosulfonate 50 grams, naphthalenesulfonate formaldehyde condensation compound 50 grams, alkylphenol polyoxyethylene phosphoric acid fat and salt 30 grams thereof, white carbon 100 grams, precipitated calcium carbonate 565 grams, stir, adopt comminution by gas stream processing, get final product 20.5% Avermectin lythidathion insecticides wetting powder.
Embodiment 10: Avermectin: lythidathion=2: 10 water dispersible granules
With Avermectin 20 grams, lythidathion 100 grams, triethanolamine 2 grams, white carbon 100 grams, MF 60 grams, starch 45 grams, kaolin 200 grams, ammonium sulfate 473 grams mix laggard comminution by gas stream, in mixer, spray into and mediate about 180 grams of agent deionized water, adjust extrusion equipment, carry out extruder grain, it is qualified to dry to moisture under 50~80 ℃ of conditions, get final product 12% A Wei fosthiazate water dispersible granules.
Embodiment 11: Avermectin: lythidathion=1: 20 water dispersible granules
With Avermectin 10 grams, lythidathion 200 grams, polyethers 2 grams, white carbon 150 grams, BIT (1, the 2-benzisothiazole-3-ketone) 70 grams, the AEO-535 gram, kaolin 130 grams, ammonium sulfate 403 grams, mix laggard comminution by gas stream, in mixer, spray into and mediate about 180 grams of agent deionized water, adjust extrusion equipment, carry out extruder grain, it is qualified to dry to moisture under 50~80 ℃ of conditions, get final product 21% Avermectin fosthiazate water dispersible granules.
Experiment embodiment 1:2.1% Avermectin lythidathion granule is to the control efficiency of big race tie lines worm
The place: period is investigated in Anqiu, Shandong: 10 months: 2010
Table 12.1% Avermectin lythidathion granule is to the control efficiency of big race tie lines worm
Chemicals treatment | Usage amount | Preventive effect (%) |
10% lythidathion GR | 2.5kg/ mu | 79.6 |
0.5% Avermectin GR | 10kg/ mu | 75.9 |
2.1% Avermectin lythidathion GR | 10kg/ mu | 86.8 |
2.1% Avermectin lythidathion GR | 12kg/ mu | 91.5 |
Know that by last table 1 result the composite actual preventive effect to big race tie lines worm of Avermectin and lythidathion is apparently higher than the preventive effect that these two kinds of compositions use separately, this shows that the present invention makes up and has obvious synergistic effect.
Experiment embodiment 2:11% A Wei lythidathion granule is to the control efficiency of cucumber root-knot nematode
The place: period is investigated in Shouguang, Shandong: 6 months: 2010
Table 211% A Wei lythidathion granule is to the control efficiency of cucumber root-knot nematode
Chemicals treatment | Usage amount | Preventive effect (%) |
10% lythidathion GR | 2.5kg/ mu | 77.2 |
0.5% Avermectin GR | 10kg/ mu | 73.8 |
11% Avermectin lythidathion GR | 2kg/ mu | 85.2 |
11% Avermectin lythidathion GR | 2.5kg/ mu | 93.1 |
Know that by last table 2 result 11% Avermectin lythidathion GR is to the actual preventive effect of the plastic tent cucumber root-knot nematode preventive effect apparently higher than its single agent, this shows that the present invention makes up and has obvious synergistic effect.
Experiment embodiment 3:22% A Wei lythidathion suspending agent is to the control efficiency of big race tie lines worm
The place: period is investigated in Shouguang, Shandong: 10 months: 2010
Table 322% A Wei lythidathion suspending agent is to the control efficiency of big race tie lines worm
Chemicals treatment | Usage amount | Preventive effect (%) |
1% Avermectin SC | 2.5kg/ mu | 74.8 |
22% Avermectin lythidathion SC | 0.5kg/ mu | 80.4 |
22% Avermectin lythidathion SC | 1kg/ mu | 93.7 |
This test is adopted and to be watered the mode executed after medicament dilution and irritate mid-term in the Da Jiang growth and execute, and by last table result as can be known, 22% A Wei lythidathion suspending agent is to the preventive effect excellence of big race tie lines worm, and as seen this combination has obvious synergistic effect.
Experiment embodiment 4:31% A Wei lythidathion suspending agent is to the control efficiency of capsicum root-knot nematode
The place: period is investigated in Shouguang, Shandong: 7 months: 2010
Table 431% A Wei lythidathion suspending agent is to the control efficiency of capsicum root-knot nematode
Chemicals treatment | Usage amount | Preventive effect (%) |
1% Avermectin SC | 2.5kg/ mu | 71.6 |
31% Avermectin lythidathion SC | 0.5kg/ mu | 82.5 |
31% Avermectin lythidathion SC | 1kg/ mu | 89.9 |
The mode that this test adopts medicament dilution back to execute along ridge irrigation is carried out dispenser, by last table result as can be known, 31% A Wei lythidathion suspending agent has excellent control efficiency to the capsicum root-knot nematode, and its preventive effect is significantly higher than Avermectin and uses separately, and as seen this combination has obvious synergistic effect.
Experiment embodiment 5:32% A Wei lythidathion WP is to the control efficiency of tomato root-knot eelworm
The place: period is investigated in Shouguang, Shandong: 7 months: 2010
Table 532% A Wei lythidathion WP is to the control efficiency of tomato root-knot eelworm
Chemicals treatment | Usage amount | Preventive effect (%) |
1% Avermectin WP | 2kg/ mu | 82.7 |
32% Avermectin lythidathion WP | 0.5kg/ mu | 80.4 |
32% Avermectin lythidathion WP | 1kg/ mu | 88.3 |
32% Avermectin lythidathion WP | 1.5kg/ mu | 95.5 |
This test employing medicament is converted water dilution back and is carried out dispenser at the mode that crop root sprays, and by last table result as can be known, 32% A Wei lythidathion WP has excellent control efficiency to tomato root-knot eelworm.
Experiment embodiment 6:20.5% A Wei lythidathion WP is to the control efficiency of peanut root-knot nematode
The place: period is investigated in Xinxiang, Henan: 10 months: 2009
Table 620.5% A Wei lythidathion WP is to the control efficiency of peanut root-knot nematode
Chemicals treatment | Usage amount | Preventive effect (%) |
1% Avermectin WP | 2kg/ mu | 79.4 |
10% fosthiazate WP | 2.5kg/ mu | 81.9 |
20.5% Avermectin lythidathion WP | 0.5kg/ mu | 73.5 |
20.5% Avermectin lythidathion WP | 1kg/ mu | 86.7 |
20.5% Avermectin lythidathion WP | 1.5kg/ mu | 94.8 |
By last table result as can be known, 20.5% A Wei lythidathion WP has excellent control efficiency to peanut root-knot nematode, and effect is better than the preventive effect of Avermectin and the agent of fosthiazate list, and as seen these two kinds of composition combinations have obvious synergistic effect.
Experiment embodiment 7:12% A Wei lythidathion WDG is to the control efficiency of watermelon root-knot nematode
The place: period is investigated in the Kaifeng: 8 months: 2010
Table 712% A Wei lythidathion WDG is to the control efficiency of watermelon root-knot nematode
Chemicals treatment | Usage amount | Preventive effect (%) |
1% Avermectin WDG | 2kg/ mu | 81.2 |
10% fosthiazate WDG | 2.5kg/ mu | 80.6 |
12% Avermectin lythidathion WDG | 1kg/ mu | 87.2 |
12% Avermectin lythidathion WDG | 1.5kg/ mu | 94.5 |
By last table result as can be known, 12% A Wei lythidathion WDG has excellent control efficiency to the watermelon root-knot nematode, and effect is better than the preventive effect of Avermectin and the agent of fosthiazate list, and as seen these two kinds of composition combinations have obvious synergistic effect.
Experiment embodiment 8:21% A Wei lythidathion WDG is to the control efficiency of Chinese yam Pratylenchidae
The place: period is investigated in Shouguang, Shandong: 11 months: 2010
Table 821% A Wei lythidathion WDG is to the control efficiency of Chinese yam Pratylenchidae
Chemicals treatment | Usage amount | Preventive effect (%) |
1% Avermectin WDG | 2kg/ mu | 76.5 |
10% fosthiazate WDG | 2kg/ mu | 74.8 |
21% Avermectin lythidathion WDG | 0.5kg/ mu | 82.6 |
21% Avermectin lythidathion WDG | 1kg/ mu | 90.7 |
By last table result as can be known, 21% A Wei lythidathion WDG has excellent control efficiency to the Chinese yam Pratylenchidae, and as seen these two kinds of composition combinations have obvious synergistic effect.
Experiment embodiment 9:42% A Wei lythidathion missible oil is to the control efficiency of muskmelon root-knot nematode
The place: period is investigated in the Weishi, Henan: 8 months: 2010
Table 942% A Wei lythidathion EC is to the control efficiency of muskmelon root-knot nematode
Chemicals treatment | Usage amount | Preventive effect (%) |
1.8% Avermectin EC | 2kg/ mu | 81.3 |
5% fosthiazate EC | 5kg/ mu | 83.5 |
42% Avermectin lythidathion WDG | 0.25kg/ mu | 89.1 |
42% Avermectin lythidathion WDG | 0.5kg/ mu | 97.2 |
By last table result as can be known, 42% A Wei lythidathion EC is remarkable to muskmelon root-knot nematode control efficiency, and as seen these two kinds of composition combinations have obvious synergistic effect.
Claims (8)
1. Avermectin lythidathion insecticides, it is characterized in that: the weight ratio of Avermectin and lythidathion is: 1: 5~40.
3. the suspending agent of Avermectin lythidathion insecticides according to claim 3 is characterized in that: described dispersant be NNO, MF, SOPA270, lignosulfonates, polyethers, in a kind of or any several combination.
4. the suspending agent of Avermectin lythidathion insecticides according to claim 3 is characterized in that: described wetting agent is K12, NPE, AEO series, ooze a kind of or any several combination in T, alkyl phenol (or fatty alcohol) polyoxyethylene poly-oxygen propylene aether and the sulphate (or phosphoric acid fat) thereof.
5. the suspending agent of Avermectin lythidathion insecticides according to claim 3, it is characterized in that: described stabilizing agent is potassium sorbate, Sodium Benzoate, formaldehyde, BIT (1, the 2-benzisothiazole-3-ketone), triumphant pine, epoxychloropropane, epoxidized vegetable oil, tributyl phosphate, alkylphenol polyoxyethylene phosphoric acid fat and salt thereof, 2 hexylene glycol [2,4], hexylene glycol [2,5], a kind of or any several combination in the pentanediol [1,5].
6. the suspending agent of Avermectin lythidathion insecticides according to claim 3 is characterized in that: a kind of or any several combination in described thickener: CMC, xanthic acid, PVA, sodium alginate, gum Arabic, bentonite, white carbon, aluminium-magnesium silicate, the starch.
7. the suspending agent of Avermectin lythidathion insecticides according to claim 3 is characterized in that: described solvent is a deionized water.
8. according to claim 1 and/or 2 described Avermectin lythidathion insecticides, it is characterized in that: said composition can be prepared into other common formulations, and described common formulations comprises microcapsule suspending agent, water dispersible granules, aqueous emulsion, granule, wetting powder.
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CN102349539A (en) * | 2011-08-10 | 2012-02-15 | 陕西美邦农药有限公司 | Insecticidal composition containing lythidathion and antibiotic compound |
CN102972439A (en) * | 2012-12-18 | 2013-03-20 | 联保作物科技有限公司 | Abamectin.fosthiazate slow-release granule and preparation method thereof |
CN105660627A (en) * | 2016-01-06 | 2016-06-15 | 广东省农业科学院植物保护研究所 | Microcapsule nematicide |
CN105707101A (en) * | 2016-04-13 | 2016-06-29 | 南通清安健无水印染研究所(普通合伙) | Preparation method of microencapsulated powder for controlling root-knot nematodes of vegetables in greenhouses |
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CN102349539A (en) * | 2011-08-10 | 2012-02-15 | 陕西美邦农药有限公司 | Insecticidal composition containing lythidathion and antibiotic compound |
CN102349539B (en) * | 2011-08-10 | 2014-04-09 | 陕西美邦农药有限公司 | Insecticidal composition containing lythidathion and antibiotic compound |
CN102972439A (en) * | 2012-12-18 | 2013-03-20 | 联保作物科技有限公司 | Abamectin.fosthiazate slow-release granule and preparation method thereof |
CN105660627A (en) * | 2016-01-06 | 2016-06-15 | 广东省农业科学院植物保护研究所 | Microcapsule nematicide |
CN105707101A (en) * | 2016-04-13 | 2016-06-29 | 南通清安健无水印染研究所(普通合伙) | Preparation method of microencapsulated powder for controlling root-knot nematodes of vegetables in greenhouses |
CN106332910A (en) * | 2016-08-23 | 2017-01-18 | 广西易多收生物科技有限公司 | Pharmaceutical composition for killing burrowing nematode of banana trees and preparation method thereof |
CN108849868A (en) * | 2018-05-23 | 2018-11-23 | 深圳诺普信农化股份有限公司 | A kind of microcapsule formulation and preparation method thereof containing avermectin and fosthiazate |
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