CN103430943A - Synergistic kasugamycin composition containing tea saponin - Google Patents
Synergistic kasugamycin composition containing tea saponin Download PDFInfo
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- CN103430943A CN103430943A CN2013102820208A CN201310282020A CN103430943A CN 103430943 A CN103430943 A CN 103430943A CN 2013102820208 A CN2013102820208 A CN 2013102820208A CN 201310282020 A CN201310282020 A CN 201310282020A CN 103430943 A CN103430943 A CN 103430943A
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- kasugarnycin
- septichen
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- tea saponin
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Abstract
The invention provides a synergistic kasugamycin composition containing tea saponin. The kasugamycin composition has insecticidal, bactericidal and antiviral functions and is capable of inducing a plant to generate a disease-resistant function; the composition specifically comprises 1 to 50% of kasugamycin, 9 to 70% of tea saponin, 1 to 10% of salicylic acid and 5 to 30% of a surfactant, with the balance being a carrier or accessory material. The composition provided by the invention has stable properties; a formula for the composition is reasonable; a wettable powder, a water dispersible granule, a water aqua, a soluble powder and a soluble granule containing 1 to 50% of the effective component kasugamycin can be prepared by using a production method for a common pesticide preparation; the composition has wide-spectrum prevention and treatment effects on bacteria, fungi, viruses and insects on crops, can induce a plant to generate stress resistance and is a purely biological pesticide composition.
Description
Technical field:
The present invention relates to the composition that a kind of all kinds of crops field sterilization, desinsection, antiviral and inducing plant produce degeneration-resistant function, can strengthen the resistance against diseases of plant itself, be specifically related to kasugarnycin preparation and production method.
Background technology
The disease of crops, worm, evil are generally to occur simultaneously, interact, and the environment-stress such as low temperature, high temperature also impel the generation of damage by disease and insect, cause vicious circle.The seed of some plants carries bacterium, virus, and along with plant growth, plant is infected morbidity also, and the plant plant of morbidity is weakened, and the competitiveness that absorbs water, fertilizer, light descends, and more easily suffers new bacterium, virus, the invasion and attack of black worm.Lack at present a kind of environmental friendliness, environmental protection, possess the biopesticide of simultaneously preventing and treating vegetative bacteria, virus, insect efficiently.
Summary of the invention:
The object of the invention is to, solve above-mentioned existing all kinds of corps diseases, and the traditional chemical pesticide pollution is serious, residual life is long, dangerous to the user, and it is mutually incompatible to have a desinsection, sterilization, antiviral three kinds of agricultural chemicals, should not manufacture multi-functional a kind of agricultural chemicals; Thereby to crops field bacterium, virus, insect pest effectively control simultaneously.There are the problem of preventive effect deficiency in kasugarnycin single dose or other complex preparations, the invention provides a kind of synergy kasugarnycin preparation containing poor saponin, can be used for the control of the crop disease and insects such as all kinds of cereal crops, fruit, vegetables, strengthen the anti-adversity ability of plant, there are green, environmental protection, safety, efficient characteristics.
For addressing the above problem, the present invention by the following technical solutions:
1%～50% kasugarnycin, 9%～70% Tea Saponin, 1～10% septichen, 5～20% auxiliary agent, all the other complement to 100% with carrier or auxiliary material; All percentage is mass percent.
Affiliated kasugarnycin (Universal Chinese character name: kasugarnycin; Kasugarnycin; (5-amino-2-methyl-6-(2,3,4,5,6-hydroxy-cyclohexyl oxo) tetrahydropyran-3-base) amino-α-IMDA, English common name: kasugamycin; Kasumin; Kasurabcide; Kasumin-bordeaux; KSM), kasugarnycin is the desirable medicament of preventing and treating various bacteria and fungal disease, and prevention, treatment, growth adjustment function are arranged.It is outside the special-purpose antibiotic of control rice blast, also to X. c. pv. oryzicola, and oranges and tangerines gummosis, rubber disease, Prospect on Kiwifruit Bacterial Canker, pepper bacterial scab disease, early blight of celery, the confused rot of Kidney bean, the control efficiency that the white helminthosporium leaf spot of water chestnut etc. has had.
Described Tea Saponin is (English common name: Tea Saponin), TS belongs to the triterpenes saponin, there is the toil pungent, stimulate nasal membrane to cause sneeze, sterling is white fine columnar crystal, and hygroscopicity is strong, it is acid that paramethyl red is, be insoluble in absolute methanol, ethanol, be insoluble to the organic solvents such as ether, acetone, benzene, benzinum, be soluble in aqueous methanol, hydrous ethanol and glacial acetic acid, aceticanhydride, pyridine etc.Add hydrochloric acid in TS solution, when acid, saponin is precipitation just.Fusing point: 224 ℃.It is the class candy glucoside compound extracted in the tea tree seed; it is the accessory substance of producing tea oil; it is a kind of well behaved natural surfactant; it can be widely used in the fields such as light industry, chemical industry, agricultural chemicals, feed, cultivation, weaving, oil recovery, mining, building materials and expressway construction, manufactures emulsifier, abluent, feed addictive, crab shrimp aquaculture protectant, textile auxiliary, oilfield foaming agent etc.Tea Saponin has unique desinsection, antiviral-mechanism, but while using separately, large usage quantity, slowly, range of application is narrower in effect.
Described surfactant can be and can promote the absorption of weeds to kasugarnycin and Tea Saponin, and environment is easily degraded, and meets environmental requirement, is suitable as the surfactant of agricultural chemicals.Be specially sodium lignin sulfonate (M-9), calcium lignosulfonate, neopelex, lauryl sodium sulfate (K12), di-2-ethylhexylphosphine oxide bitter edible plant sodium sulfonate (NNO), polycarboxylate (Tersperse2700, SC213), sodium butylnaphthalenesulfonate, alkyl phenol formaldehyde resin polyoxyethylene ether sulphate (SOPA270), fatty alcohol-polyoxyethylene ether (AEO), methyl glucamine (APA), (Morwet D425, MF-5 etc. are suitable for one or several compositions in the surfactant of agricultural chemicals to the sodium salt of alkylnaphthalene sulfonate formaldehyde condensation products.
Described carrier or auxiliary material are: kaolin, and diatomite, sodium sulphate, urea, ammonium sulfate,, potassium dihydrogen phosphate, white carbon, glycerine, ethylene glycol, water, corn starch, glucose, sucrose etc. are applicable does one or several compositions in the inert substance of agricultural chemicals auxiliary material.
Preparation method of the present invention is:
The synergy kasugarnycin containing poor saponin the present invention relates to has sterilization, desinsection, antiviral functions, and most preferred dosage form is wetting powder, also can be the formulations such as water dispersible granules, soluble granule, soluble powder, aqua; Adopt conventional formulations of pesticide processing method, the synergy kasugarnycin preparation that the percentage composition that can be made into active ingredient is 1%～50%, possess sterilization, desinsection, antiviral functions composition.
Wetting powder (WP): by active ingredient, applicable surfactant combination, auxiliary material mixes through air-flow or ultramicro grinding to 325～1000 orders.General 1%～50% the active ingredient that contains, the composition of 5～20% suitable surfactant, all the other are suitable carrier or the composition of auxiliary material.
Water dispersible granules (WDG): by active ingredient; applicable surfactant combination; auxiliary material mixes through air-flow or ultramicro grinding to 600～1000 orders; add appropriate water; with rotational shear comminutor or other applicable granulator granulations, after fluid bed or other suitable equipment dryings both the water dispersible granules of the particle diameter column that is 0.5～1.5 millimeter or the particle diameter orbicule that is 0.1～0.5 millimeter.General 1%～50% the active ingredient that contains, the composition of 5～20% suitable surfactant, all the other are suitable carrier or the composition of auxiliary material.
Soluble powder (SP): by active ingredient, applicable surfactant combination, auxiliary material mixes through air-flow or ultramicro grinding to 325～500 orders.General 1%～50% the active ingredient that contains, the composition of 5～20% suitable surfactant, all the other are suitable water-solubility carrier or the composition of auxiliary material.
Soluble granula (WSG): by active ingredient; applicable surfactant combination; water soluble adjuvant mixes through air-flow or ultramicro grinding to 325～500 orders; add appropriate water; with rotational shear comminutor or other applicable granulator granulations, after fluid bed or other suitable equipment dryings both the soluble granula of the particle diameter column that is 0.5～1.5 millimeter or the particle diameter orbicule that is 0.1～0.5 millimeter.General 1%～50% the active ingredient that contains, the composition of 5～20% suitable surfactant, all the other are suitable water-solubility carrier or the composition of auxiliary material.
Aqua (AS): by active ingredient, applicable surfactant combination, ethylene glycol or glycerine, be dissolved in appropriate water, is stirred to fully and dissolves and get final product aqua.General 1%～50% the active ingredient that contains, the composition of 5～20% suitable surfactant, all the other are suitable water or the composition of auxiliary material.
Advantage of the present invention is: kasugarnycin belongs to biopesticide, poor saponin is the accessory substance of Tea Production, by the distinctive desinsection of Tea Saponin, sterilization, the sterilizing function of antiviral functions and kasugarnycin combines, and septichen can impel plant to produce the ability of anti-environment-stress, strengthen disease-resistant anti-adversity ability, this assembly has obvious synergistic function, and its production and processing, use link are to operator's safety, to the natural environment close friend, noresidue harm; Sterilization, desinsection and antiviral functions with wide spectrum, to all kinds of Crop securifies.Said composition can be prevented and kill off all kinds of crops field bacterium, and fungi, and the harm of Disease have the function of kill pests simultaneously.Solved traditional kasugarnycin preparation extremely after composition dispenser for many years resistance increase, the deficiency that effect is single.And said composition is to all kinds of Crop securifies, and the dispenser window phase is wider, can dispenser in the random time scope of plant production, do not affect the growth of all kinds of crops, pesticide application technology is simple, does not need complicated field management.The production of said composition can be made according to common Pesticide formulation method, but dispersible granule, wetting powder, soluble powder, aqua, soluble granula.The safety that sterilization of the present invention, desinsection, antiviral functions combination agent have improved agricultural product, greatly reduced the consumption of chemical pesticide, saved human cost, and production cost is lower, for Development of Organic Agriculture, pollution-free food provides effective safety guarantee, and higher economic benefit and social benefit are arranged.
The anti-effect data of sterilization of the present invention, desinsection, antiviral functions composition are in Table 1.
Embodiment:
Example 1:
The kasugarnycin 714g that is 70% by purity, Tea Saponin 150g, calcium lignosulfonate 50g, septichen 50g, di-2-ethylhexylphosphine oxide bitter edible plant sodium sulfonate (NNO) 10g, lauryl sodium sulfate 10g, white carbon 10g, kaolin complements to 1000g.Fully mix in cone blender or other blender, then carry out air-flow or ultramicro grinding to 325～1000 orders, be i.e. 50% kasugarnycin wetting powder of system.The all percentage of embodiment is mass percent.
Example 2
The kasugarnycin 714g that is 70% by purity, Tea Saponin 180g, calcium lignosulfonate 50g, septichen 20g, di-2-ethylhexylphosphine oxide bitter edible plant sodium sulfonate (NNO) 10g, lauryl sodium sulfate 10g, white carbon 2g, sodium sulphate complements to 1000g.Fully mix in cone blender or other blender, then carry out air-flow or ultramicro grinding to 325～500 orders, be i.e. the present invention's 50% kasugarnycin soluble powder of system.The all percentage of embodiment is mass percent.
Example 3
The kasugarnycin 714g that is 70% by purity; Tea Saponin 190g; polycarboxylate 50g; septichen potassium 10g; naphthalene sulfonate 10g; lauryl sodium sulfate 10g; white carbon 2g; kaolin complements to 1000g; then carry out air-flow or ultramicro grinding; add appropriate water, with rotational shear comminutor or other applicable granulator granulations, after fluid bed or other suitable equipment dryings both the spherical particle agent that is 0.1～0.5 millimeter of the particle diameter column that is 0.5～1.5 millimeter or particle diameter.The present invention's 50% kasugarnycin water dispersion granule of making.The all percentage of embodiment is mass percent.
Example 4:
The kasugarnycin 86g that is 70% by purity, Tea Saponin 400g, polycarboxylate 50g, septichen sodium 100g, the sodium salt 100g of alkylnaphthalene sulfonate formaldehyde condensation products, lauryl sodium sulfate 10g, ammonium sulfate 100g, corn starch 100g, white carbon 20g, kaolin 34g.Then carry out air-flow or ultramicro grinding; add appropriate water; with rotational shear comminutor or other applicable granulator granulations, after fluid bed or other suitable equipment dryings both the spherical particle agent that is 0.1～0.5 millimeter of the particle diameter column that is 0.5～1.5 millimeter or particle diameter.The present invention's 6% kasugarnycin water dispersion granule of making.The all percentage of embodiment is mass percent.
Example 5
The kasugarnycin 120g that is 50% by purity, Tea Saponin 550g, calcium lignosulfonate 50g, di-2-ethylhexylphosphine oxide bitter edible plant sodium sulfonate (NNO) 50g, septichen potassium 50g, lauryl sodium sulfate 10g, white carbon 80g, kaolin 90g.Fully mix in cone blender or other blender, then carry out air-flow or ultramicro grinding to 325～500 orders, be i.e. 6% kasugarnycin wetting powder of system.The all percentage of embodiment is mass percent.
Example 6
The kasugarnycin 86g that is 70% by purity; Tea Saponin 490g; polycarboxylate 50g; the sodium salt 100g of alkylnaphthalene sulfonate formaldehyde condensation products; septichen 10g; lauryl sodium sulfate 10g; ammonium sulfate 134g; corn starch 100g; white carbon 20g, then carry out air-flow or ultramicro grinding, adds appropriate water; with rotational shear comminutor or other applicable granulator granulations, after fluid bed or other suitable equipment dryings both the spherical particle agent that is 0.1～0.5 millimeter of the particle diameter column that is 0.5～1.5 millimeter or particle diameter.The present invention's 6% kasugarnycin soluble granule of making.The all percentage of embodiment is mass percent.
Example 7
The kasugarnycin 40g that is 50% by purity, Tea Saponin 570g, sodium butylnaphthalenesulfonate 50g, di-2-ethylhexylphosphine oxide bitter edible plant sodium sulfonate (NNO) 50g, lauryl sodium sulfate 10g, septichen 30g, white carbon 80g, diatomite 170g.Fully mix in cone blender or other blender, then carry out air-flow or ultramicro grinding to 325～500 orders, be i.e. 2% kasugarnycin wetting powder of system.The all percentage of embodiment is mass percent.
Example 8
The kasugarnycin 120g that is 50% by purity, Tea Saponin 190g, septichen 10g, fatty alcohol-polyoxyethylene ether (AEO9) 100g, ethylene glycol 50g, add above-mentioned material in container, then adds water 530g, stirring and be brown liquid, has been both 6% kasugarnycin aqua of the present invention.The all percentage of embodiment is mass percent.
Example 9
The kasugarnycin 40g that is 50% by purity, Tea Saponin 185g, septichen 15g, fatty alcohol-polyoxyethylene ether (AEO9) 100g, glycerine 50g, urea 50g, above-mentioned material is added in container, then adding water 560g, stir and be brown liquid, has been both 2% kasugarnycin aqua of the present invention.The all percentage of embodiment is mass percent.
Example of the present invention adopts the method for field efficacy, medicament arranges unified treating capacity according to active ingredient, respectively in bacterium, the virus of preventing and treating Different Crop in different geographical, aphid, after dispenser the 7th, 15,30 days respectively, image data, observe, calculate average preventive effect, finally draws following data.
Table 1 synergy kasugarnycin preparation preventive effect data
The experimental data explanation, the kasugarnycin preparation, after having added a certain amount of Tea Saponin, has obvious synergistic effect, has significantly improved to the crop bacterium control efficiency of virus and aphid.
Claims (5)
1. sterilization, desinsection, antiviral functions composition containing kasugarnycin and a Tea Saponin, it is characterized in that comprising following component: specifically comprise 1%～50% kasugarnycin, 9%～70% Tea Saponin, 1～10% septichen, 5～20% auxiliary agent, all the other complement to 100% with carrier or auxiliary material; All percentage is mass percent.
2. according to right 1, it is characterized in that containing 9～70%, poor saponin being arranged in the kasugarnycin preparation.
3. according to right 1 or 2, it is characterized in that described septichen is one or several compositions in septichen or septichen potassium or septichen sodium.
4. according to right 1 or 2, it is characterized in that described auxiliary agent is sodium lignin sulfonate (M-9), calcium lignosulfonate, neopelex, lauryl sodium sulfate (K12), di-2-ethylhexylphosphine oxide bitter edible plant sodium sulfonate (NNO), polycarboxylate (Tersperse2700, SC213), sodium butylnaphthalenesulfonate, fatty alcohol-polyoxyethylene ether (AEO), methyl glucamine (APA), the sodium salt of alkylnaphthalene sulfonate formaldehyde condensation products (Morwet D425), MF-5 etc. are suitable for one or several compositions in the surfactant of agricultural chemicals.
5. according to right 1 or 2, it is characterized in that described carrier or auxiliary material are: kaolin, diatomite, sodium sulphate, urea, ammonium sulfate, potassium dihydrogen phosphate, white carbon, glycerine, ethylene glycol, fatty alcohol-polyoxyethylene ether (AEO9), water, corn starch, glucose, sucrose etc. are applicable does one or several compositions in the inert substance of agricultural chemicals auxiliary material.
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| CN104255801A (en) * | 2014-08-29 | 2015-01-07 | 浙江大洋生物科技集团股份有限公司 | Crop potassium supplement composition with sterilization function as well as preparation method and application of crop potassium supplement composition |
| CN105145633A (en) * | 2015-07-31 | 2015-12-16 | 北京泰克美高新技术有限公司 | Drug controlling plant nematodes |
| CN105145629A (en) * | 2015-09-10 | 2015-12-16 | 中国烟草总公司郑州烟草研究院 | Prevention preparation for tobacco weather fleck and use method |
| CN108496970A (en) * | 2018-05-11 | 2018-09-07 | 四川国光农化股份有限公司 | A kind of composition, preparation and its application for desinsection |
| CN112042653A (en) * | 2020-09-22 | 2020-12-08 | 江门市植保有限公司 | Bactericidal composition containing kasugamycin and hymexazol and preparation method thereof |
| WO2022185037A1 (en) * | 2021-03-01 | 2022-09-09 | UPL Corporation Limited | Agricultural composition comprising kasugamycin |
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Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN104255801A (en) * | 2014-08-29 | 2015-01-07 | 浙江大洋生物科技集团股份有限公司 | Crop potassium supplement composition with sterilization function as well as preparation method and application of crop potassium supplement composition |
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| CN105145629A (en) * | 2015-09-10 | 2015-12-16 | 中国烟草总公司郑州烟草研究院 | Prevention preparation for tobacco weather fleck and use method |
| CN108496970A (en) * | 2018-05-11 | 2018-09-07 | 四川国光农化股份有限公司 | A kind of composition, preparation and its application for desinsection |
| CN112042653A (en) * | 2020-09-22 | 2020-12-08 | 江门市植保有限公司 | Bactericidal composition containing kasugamycin and hymexazol and preparation method thereof |
| CN112042653B (en) * | 2020-09-22 | 2021-10-29 | 江门市植保有限公司 | Bactericidal composition containing kasugamycin and hymexazol and preparation method thereof |
| WO2022185037A1 (en) * | 2021-03-01 | 2022-09-09 | UPL Corporation Limited | Agricultural composition comprising kasugamycin |
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Application publication date: 20131211 |