CN102669157B - Mite-killing composition and preparation thereof - Google Patents
Mite-killing composition and preparation thereof Download PDFInfo
- Publication number
- CN102669157B CN102669157B CN201110063462.4A CN201110063462A CN102669157B CN 102669157 B CN102669157 B CN 102669157B CN 201110063462 A CN201110063462 A CN 201110063462A CN 102669157 B CN102669157 B CN 102669157B
- Authority
- CN
- China
- Prior art keywords
- mite
- miticide
- spiromesifen
- composition
- present
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Abstract
The invention relates to the field of pesticide preparations and discloses a mite-killing composition. The mite-killing composition consists of spiromesifen and one of azocyclotin, propargite, clofentezine or pyridaben, wherein the weight ratio of the spiromesifen to the azocyclotin, propargite, clofentezine or pyridaben is 1-99:99-1. The invention also discloses a mite-killing preparation for controlling mites of farmlands and fruit trees, and the active ingredient of the mite-killing preparation is the mite-killing composition which accounts for 1 to 99 percent of the weight of the mite-killing preparation. The mite-killing composition and the preparation thereof have the advantages of obviously improving mite-controlling efficiency, reducing the amount of active ingredients, delaying the generation of drug resistance of mites and lowering environmental pollution, has an obvious synergistic effect, and can be widely applied to agricultural fields.
Description
Technical field
The present invention relates to pesticidal preparations field, relate to specifically a kind of miticide composition and preparation thereof.
Background technology
Mite class is commonly called as " two spotted spider mite " or " tick ", is under the jurisdiction of arachnids, Acari.Mite class body is long conventionally below 2mm.Cephalothorax abdomen healing is integrated and without body segment, is divided into gnathosoma and the individual section of body two, if overwhelming majority mite and become 4 pairs enough of mite tools, with tracheal respiration.500,000 kinds of the nearly acarians in the whole world, wherein Agricultural Mites mainly contains the monoids such as tetranychid, leaf pawl mite, false spider mite, tarsonemid and goitre mite.The Agricultural Mites kind of China has kind more than 500, wherein endanger serious approximately kind more than 40, such as citrus red mite, oranges and tangerines tick, apple tetranychus etc., the field-crop such as their main harm fruit trees and cotton, wheat class, vegetables, tobacco, tealeaves, corn, soybean, peanut.Agricultural Mites volume is little, breeding fast, strong adaptability, easily produces resistance, and under the suitableeest condition, 1 month breeding limit of 1 female one-tenth mite can be up to 10,000 bulls, is the pest communities of the most difficult control of generally acknowledging.
Their most tissues that thrust the leaf of plant, tender stem, leaf sheath, bud, calyx, fruit, piece root, stem tuber etc. with a pair of lancet, draw cell juice, destroy Stoma of Leaves, spongy tissue and palisade tissue, and secrete poisonous and harmful substances, obstruction plant normal growth is grown, thereby causes following Major Diseases symptom: make blade chlorisis, jaundice, rubescent, shrivelled or formation insect gall; Disease bud deformity; Make blade, pericarp be rust; Make blade become felt shape; Cause dehiscent fruit.When serious, can make plant defoliation, fallen flowers, shedding, even large area plant is withered, causes yield and quality significantly to decline.
Of a great variety for preventing and treating the miticide of harmful mite on market, there are the unsafe amidine class of pair crop, organic phosphates, the contour malicious miticide of organochlorine class; Have couple person poultry toxicity low, to the effective chrysanthemum ester of mite class class miticide, but the lasting period is short, repeatedly use, and produce cross resistance.Spiromesifen is the miticide of a brand-new mechanism of action developing of Bayer Cropscience Co.,Ltd, and its killing mechanism is different from existing various miticide completely, can effectively improve the control efficiency to evil mite.Spiromesifen belongs to novel tetronic acid class miticide, by suppressing the Fatty synthesis in evil mite body, destroy the energy metabolism activity of acarid, finally kill harmful mite, it is a kind of brand-new, efficient non-internal-absorting leaf surface treatment miticide, is particularly suitable for the pest mite class of control to existing miticide generation resistance.But the miticidal effect of single use Spiromesifen is still unsatisfactory.
Chinese patent CN101437402A discloses a kind of " having the active ingredient combinations that kills insect and kill acarid characteristic ", and this patent combines with Spiromesifen and smart gamma cyhalothrin, for preventing and treating acarid and other subject insects.But smart gamma cyhalothrin mainly prevents the insect such as Lepidoptera, coleoptera, invalid to acarid.Therefore, this patent composition is still to realize by Spiromesifen to the control of evil mite, cannot improve its preventive effect to evil mite.
Summary of the invention
In view of this, the object of the invention is to provide a kind of miticide composition and preparation thereof, makes said composition and preparation thereof can improve the preventive effect to evil mite.
For realizing object of the present invention, the present invention adopts following technical scheme:
A kind of miticide composition, is made up of the one in Spiromesifen and azacyclotin, propargite, clofentezine or pyridaben.
Spiromesifen is spirocyclic tetronic acid class miticide, and two spotted spider mite, yellow spider, blister mite, the yellow mite of the bitter edible plant, Tetranychus cinnabarinus and Tetranychus urticae etc. are all had to fine preventive effect, and the mite evil that can be used for the solanaceous crops such as the fruit tree such as citrus, grape and eggplant, capsicum, tomato is administered.Its mechanism of action is the growth of impact evil mite, disturbs the biosynthesis of its liposome, especially larval stage is had to good activity, also can produce ovarian duct closure function simultaneously, reduces evil mite adult fertility, greatly reduces the quantity of laying eggs.Between Spiromesifen and existing miticide, without cross resistance, be applicable to the pest mite class of control to existing miticide generation resistance.
Azacyclotin belongs to moderate toxicity, tagging property miticide, is applicable to prevent and treat multiple harmful mite on fruit tree, vegetables, if can kill mite, one-tenth mite and summer egg, stable to light, the longevity of residure is long, to crop safety, without teratogenesis, carcinogenic, mutagenesis, low to honeybee toxicity, be a kind of wide spectrum miticide.Its mechanism of action is by suppressing the transmission of nerve fiber information, makes evil mite paralysis dead.
Propargite is the high-efficiency low-toxicity succeeded in developing Uniroyal company nineteen sixty-eight of the U.S., without interior absorption, low-residual, have and tag and the organic sulfur wide spectrum miticide of stomach toxicity double action, can effectively preventing and treating apple-tree, cotton, cucumber, grape, corn, nut, soybean, drupe, the golden mite genus on tomato and vegetables and Tetranychus and widely planting property of food mite class.Propargite can not only be killed multiple harmful mite, also can kill the harmful mite that other miticide has been developed immunity to drugs, no matter all better if kill into mite mite, young mite and mite ovum effect.Its mechanism of action is that medicament enters and in insect bodies, is oxidized to the insect killing substance that poisoning ability is stronger, suppresses in pest body the activity of acetylcholinesterase in nerve fiber, destroys the normal nerve conduction of insect, makes insect paralysis, food refusal and death.In addition, propargite has selectivity, and safer to honeybee and natural enemy, residual effect is lasting, little to people and animals and natural environment harm.
Pyridaben is wide spectrum, tagging property miticide, without interior suction, conduction, fumigation action.The longevity of residure is longer, with Acaricides without cross resistance.Be mainly used in the crops such as oranges and tangerines, apple, cotton, pears, grape, tomato, the bitter edible plant, cucumber, watermelon, control two spotted spider mite, tetranychid, Panonychus citri, tarsonemid and goitre mite.Its mechanism of action is to enter the hematological system of harmful mite from the body wall chrotoplast of evil mite, arrives nervous system, and in nervous system, disturb the normal conduction of nerve impulse by sanguimotor conveying, causes evil mite conduct disorder, thereby causes harmful mite death.If pyridaben is to being ovum, young mite mite and becoming mite to have good effect the one-tenth mite of mobile phase to be had to obvious speed equally and kill effect the whole vegetative period of evil mite.This medicine is not acted upon by temperature changes, and no matter uses in early spring or autumn, all can reach promising result.
Clofentezine is tetrazine class, tagging property miticide, belongs to efficient, low toxicity wide spectrum miticide, and for crops such as fruit tree, pea, oranges and tangerines, ornamental plants, cottons, if children mite is had to good activity, to temperature-insensitive, the four seasons all can be used.Medicament has stronger penetration, and if suppress the process of casting off a skin of children mite, control Panonychus citri belongs to and the harmful mite of Tetranychus, effective especially to the winter egg of elm Panonychus citri (European red mite).To predacious mite and useful insect safety.
The weight ratio of Spiromesifen of the present invention and azacyclotin, propargite, clofentezine or pyridaben is 1-99: 99-1, is preferably 20-80: 80-20, more preferably 28.6-71.4: 71.4-28.6.Wherein, more preferably 50-58.8 of the weight ratio of described Spiromesifen and azacyclotin: 50-41.2, more preferably 28.6-33.3 of the weight ratio of described Spiromesifen and propargite: 66.7-71.4, more preferably 52.6-62.5 of the weight ratio of described Spiromesifen and clofentezine: 47.4-37.5, more preferably 62.5-71.4 of the weight ratio of described Spiromesifen and pyridaben: 37.5-28.6.
Different miticide active components are mixed the difference of rear each active component due to composition, structure, physicochemical property, make the synergy between each active component be typically expressed as synergistic effect, summation action or antagonism.So-called synergistic effect is exactly the mutual synergism between different material, and the effect of its generation is greater than the sum total of each composition effect; And the effect that summation action is exactly its generation equals the sum total of each composition effect; Antagonism refers to that when two kinds of materials act on living organism, a kind of material disturbs the effect of another kind of material, or the effect of interfering with an opponent each other, the phenomenon that general effect is declined.
The present invention has carried out control of pest mite test to each composition single dose in miticide composition and miticide composition respectively, and in miticide composition, each composition consumption is less than each composition single dose consumption, result shows, the preventive effect of miticide composition of the present invention is than the high 5-10% of preventive effect of each composition single dose in composition, show that in miticide composition of the present invention, each composition is without cross tolerance, control efficiency has synergistic effect.
In addition, the present invention also provides a kind of miticide of preventing and treating farmland, fruit tree evil mite, and active component is made up of miticide composition of the present invention, and it is 1-99% that described miticide composition accounts for described acaricidal percentage by weight, is preferably 20-80%.
Miticide of the present invention can be made wetting powder, missible oil, suspending agent, microcapsule suspending agent or water dispersible granules by miticide composition of the present invention and conventional auxiliary material as required.Experiment shows, miticide of the present invention can be prevented and treated farmland and fruit tree evil mite effectively.
From above technical scheme, the harmful mite preventive effect of miticide composition of the present invention and preparation thereof significantly improves, and has notable synergistic effect, reduce the consumption of active ingredient, delay the drug-fast generation of evil mite, and reduce the pollution to environment, can be widely used in agriculture field.
Embodiment
The embodiment of the invention discloses a kind of miticide composition and preparation thereof.Those skilled in the art can use for reference content herein, suitably improve technological parameter and realize.Special needs to be pointed out is, all similar replacements and change apparent to those skilled in the artly, they are all deemed to be included in the present invention.Product of the present invention is described by preferred embodiment, and related personnel obviously can change product as herein described in content of the present invention, spirit and scope or suitably change and combination not departing from, and realizes and apply the technology of the present invention.
According to the present invention, described a kind of miticide composition, is made up of the one in Spiromesifen and azacyclotin, propargite, clofentezine or pyridaben.
The weight ratio of Spiromesifen of the present invention and azacyclotin, propargite, clofentezine or pyridaben is 1-99: 99-1, is preferably 20-80: 80-20, more preferably 28.6-71.4: 71.4-28.6.Wherein, more preferably 50-58.8 of the weight ratio of described Spiromesifen and azacyclotin: 50-41.2, more preferably 28.6-33.3 of the weight ratio of described Spiromesifen and propargite: 66.7-71.4, more preferably 52.6-62.5 of the weight ratio of described Spiromesifen and clofentezine: 47.4-37.5, more preferably 62.5-71.4 of the weight ratio of described Spiromesifen and pyridaben: 37.5-28.6.
The present invention has carried out control of pest mite test to each composition single dose in miticide composition and miticide composition respectively, and in miticide composition, each composition consumption is less than each composition single dose consumption, result shows, miticide composition of the present invention, mixes use with azacyclotin, propargite, clofentezine or pyridaben with certain proportion respectively by Spiromesifen and has notable synergistic effect.
The former medicine of agricultural chemicals is that active component generally can not directly be used, and must process and be mixed with various types of preparations, could use.Therefore, the present invention also provides a kind of miticide of preventing and treating farmland, fruit tree evil mite, and active component is made up of miticide composition of the present invention, and it is 1-99% that described miticide composition accounts for described acaricidal percentage by weight, is preferably 20-80%.
The form of preparation claims formulation, and what agricultural chemicals use was at present more is that pulvis, aqua, wetting powder, missible oil, suspending agent, microcapsule suspending agent, water dispersible granules etc. more than ten are planted formulation.Miticide of the present invention comprises wetting powder, missible oil, suspending agent, microcapsule suspending agent and water dispersible granules.
Wherein, wetting powder of the present invention comprises miticide composition, wetting agent, dispersant, carrier and inserts.Missible oil of the present invention comprises miticide composition, benzene or dimethylbenzene and surfactant.Suspending agent of the present invention comprises miticide composition, wetting dispersing agent, viscosity modifier, antifreezing agent and defoamer.Microcapsule suspending agent of the present invention comprises miticide composition, solvent, curing agent and viscosity modifier.Water dispersible granules of the present invention comprises miticide composition, wetting agent, disintegrant, dispersant, adhesive, interleaving agent and carrier.
Miticide of the present invention can also be made the multiple formulations such as conventional granule except above-mentioned formulation, fumicants, aerosol, ultra low volume preparation, fumigant as required, to be applied to agricultural production.
Above various preparations auxiliary agent, surfactant, carrier and other auxiliary materials used of preparation is and well known to a person skilled in the art, if wetting agent is sulfonated oil, Nekal BX, soybean lecithin, thio-alcohol, hydrazides class, mercaptan acetals and polyethylene glycol oxide alkanisation ether etc.; Dispersant is sodium phosphate trimer, sodium pyrophosphate, lauryl sodium sulfate, cellulose derivatives, polyacrylamide, fatty acid polyethylene glycol ester and fatty alcohol oxirane etc.; Disintegrant is dried starch, sodium carboxymethyl starch, low substituted hydroxy-propyl methylcellulose, crospolyvinylpyrrolidone etc.; Adhesive is polyurethane, polystyrene, polyacrylate, vinyl acetate resin etc.; Solvent can be various aromatic hydrocarbons, aliphatic hydrocarbon, ketone etc.
Experiment shows, miticide of the present invention can be prevented and treated farmland and fruit tree evil mite effectively, as citrus red mite, oranges and tangerines tick, apple tetranychus etc.
In order further to understand the present invention, below in conjunction with embodiment, a kind of miticide composition provided by the invention and preparation thereof are elaborated.
Embodiment 1: the efficiency test of miticide composition of the present invention to citrus red mite
Test in Zhengzhou, henan one peasant household orchard and carry out, miticide composition is with Spiromesifen and azacyclotin, propargite, clofentezine or pyridaben mixture, and test processing and formulation rate are in table 1, and described miticide composition and each composition single dose are all dissolved rear dispenser with clear water.
Table 1 test is processed and formulation rate
4 strain tree of the same size is selected in each processing, every strain tree select east, south, west, north, in the blade in 5 orientation, 10, each orientation leaf, every processing repeats 4 times, before dispenser, record the quantity of citrus red mite with dispenser " Invest, Then Investigate " respectively, calculate control efficiency, the results are shown in Table 2.
Wherein, computing formula is as follows:
Insect population decline rate=[the worm amount of living before (the worm amount of living after the worm amount-medicine of living before medicine) ÷ medicine] × 100%
Proofread and correct preventive effect=[(applying area insect population decline rate-check plot insect population decline rate) ÷ (1-check plot insect population decline rate)] × 100%
The control efficiency of table 2 miticide composition of the present invention to citrus red mite
As seen from the results in Table 2, a kind of mixture in active ingredient Spiromesifen and azacyclotin, propargite, clofentezine or pyridaben, consumption minimizing compared with each composition single dose, but the borer population of living after dispenser obviously reduces, insect population decline rate is high, while proofreading and correct preventive effect higher than each composition single dose use, the 5-10% of preventive effect, shows that the harmful mite preventive effect of miticide composition of the present invention significantly improves, and has notable synergistic effect.
Embodiment 2: the efficiency test of miticide composition of the present invention to oranges and tangerines tick
With reference to the test method of embodiment 1, miticide composition of the present invention is carried out to the efficiency test of oranges and tangerines tick, test processing and formulation rate are with table 1, and preventive effect computational methods, with embodiment 1, the results are shown in Table 3.
The control efficiency of table 3 miticide composition of the present invention to oranges and tangerines tick
As seen from the results in Table 3, a kind of mixture in active ingredient Spiromesifen and azacyclotin, propargite, clofentezine or pyridaben, consumption minimizing compared with each composition single dose, but the borer population of living after dispenser obviously reduces, insect population decline rate is high, while proofreading and correct preventive effect higher than each composition single dose use, the 5-10% of preventive effect, shows that the harmful mite preventive effect of miticide composition of the present invention significantly improves, and has notable synergistic effect.
Embodiment 3: the efficiency test of miticide composition of the present invention to apple tetranychus
With reference to the test method of embodiment 1, miticide composition of the present invention is carried out to the efficiency test of oranges and tangerines tick, test processing and formulation rate are with table 1, and preventive effect computational methods, with embodiment 1, the results are shown in Table 4.
The control efficiency of table 4 miticide composition of the present invention to oranges and tangerines tick
As seen from the results in Table 4, a kind of mixture in active ingredient Spiromesifen and azacyclotin, propargite, clofentezine or pyridaben, consumption minimizing compared with each composition single dose, but the borer population of living after dispenser obviously reduces, insect population decline rate is high, while proofreading and correct preventive effect higher than each composition single dose use, the 5-10% of preventive effect, shows that the harmful mite preventive effect of miticide composition of the present invention significantly improves, and has notable synergistic effect.
Embodiment 4:80% Spiromesifen azacyclotin wetting powder
45% Spiromesifen, 35% azacyclotin, 5% alkylphenol polyoxyethylene are fully mixed in proportion with 7% fatty alcohol oxirane, and diatomite is mended to 100%, makes wetting powder after ultra-fine pulverizer disintegrating.
Embodiment 5:65% Spiromesifen propargite missible oil
20% Spiromesifen, 45% propargite, 10% benzene and 15% dimethylbenzene and 10% dodecyl sodium sulfate fully mix in proportion, through mix and blend processing, obtain cream preparation successively.
Embodiment 6:50% Spiromesifen clofentezine suspension agent
30% Spiromesifen, 20% mite piperazine, 2% xylonic acid sodium sulfonate, 3% alumina silicate, 5% ethylene glycol, 1% isopropyl alcohol, water is mended to 100% common process and is made suspending agent.
Embodiment 7:35% Spiromesifen pyridaben microcapsule suspending agent
23% Spiromesifen, 12% pyridaben, 13% benzene, 30% curing agent is directly scattered in 11% polyvinyl alcohol, then adds other solvent to mend to 100% after mixing by proportioning, makes microcapsule suspending agent after slow reaction.
Embodiment 8:20% Spiromesifen propargite water dispersible granules
6% Spiromesifen, 14% propargite, 10% sulfonated oil, 19% sodium carboxymethyl starch, 26% sodium phosphate trimer and polystyrene, 16% calcium carbonate, 9% carrier mix, after pulverizing, make wetting powder, add afterwards a certain amount of water mixing extruder grain, after drying screening, make water dispersible granules.
Embodiment 9:90% Spiromesifen pyridaben missible oil
60% Spiromesifen, 30% pyridaben, 3% benzene and 5% dimethylbenzene and 2% polyoxyethylene fatty amine fully mix, and through mix and blend processing, obtain cream preparation successively
Embodiment 10: acaricidal field trial of the present invention
The miticide of embodiment 4 to 9 is carried out to efficiency test according to the method for embodiment 1 to citrus red mite, oranges and tangerines tick, apple tetranychus, and concrete preventive effect is in table 5.
Table 5 is of the present invention except the preventive effect of mite agent to evil mite
As shown in Table 5, miticide of the present invention and described miticide composition have the control efficiency of same degree, can be applied to agricultural production.
The explanation of above embodiment is just for helping to understand method of the present invention and core concept thereof.It should be pointed out that for those skilled in the art, under the premise without departing from the principles of the invention, can also carry out some improvement and modification to the present invention, these improvement and modification also fall in the protection domain of the claims in the present invention.
Claims (6)
1. a miticide composition, is characterized in that, is made up of Spiromesifen and azacyclotin; The weight ratio of described Spiromesifen and azacyclotin is 20-80:80-20.
2. miticide composition according to claim 1, is characterized in that, the weight ratio of described Spiromesifen and azacyclotin is 28.6-71.4:71.4-28.6.
3. miticide composition according to claim 2, is characterized in that, the weight ratio of described Spiromesifen and azacyclotin is 50-58.8:50-41.2.
4. a miticide of preventing and treating farmland, fruit tree evil mite, is characterized in that, active component is made up of miticide composition described in claim 1, and it is 1-99% that described miticide composition accounts for described acaricidal percentage by weight.
5. miticide according to claim 4, is characterized in that, it is 20-80% that described miticide composition accounts for described acaricidal percentage by weight.
6. miticide according to claim 4, is characterized in that, makes wetting powder, missible oil, suspending agent, microcapsule suspending agent or water dispersible granules by described miticide composition and conventional adjuvant.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201110063462.4A CN102669157B (en) | 2011-03-16 | 2011-03-16 | Mite-killing composition and preparation thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201110063462.4A CN102669157B (en) | 2011-03-16 | 2011-03-16 | Mite-killing composition and preparation thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102669157A CN102669157A (en) | 2012-09-19 |
| CN102669157B true CN102669157B (en) | 2014-08-13 |
Family
ID=46802250
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201110063462.4A Active CN102669157B (en) | 2011-03-16 | 2011-03-16 | Mite-killing composition and preparation thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102669157B (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102657178B (en) * | 2012-04-12 | 2013-11-06 | 广东中迅农科股份有限公司 | Synergistic acaricidal composition containing spiromesifen and pyridaben |
| CN103621524B (en) * | 2012-08-21 | 2015-07-08 | 陕西美邦农药有限公司 | Pesticide composition |
| CN103621549B (en) * | 2012-08-25 | 2015-10-28 | 陕西美邦农药有限公司 | A kind of miticide composition |
| CN103039448A (en) * | 2012-12-17 | 2013-04-17 | 广东中迅农科股份有限公司 | Acaricidal composition containing spiromesifen and propargite |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101250173A (en) * | 2008-04-01 | 2008-08-27 | 浙江大学 | Preparation method of spiromesifen |
| CN101380026A (en) * | 2008-08-06 | 2009-03-11 | 张少武 | Acaricide composition containing benzamide and azocyclotin |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101300979A (en) * | 2008-07-08 | 2008-11-12 | 广西田园生化股份有限公司 | Compounded pesticide composition containing Spirodiclofen |
-
2011
- 2011-03-16 CN CN201110063462.4A patent/CN102669157B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101250173A (en) * | 2008-04-01 | 2008-08-27 | 浙江大学 | Preparation method of spiromesifen |
| CN101380026A (en) * | 2008-08-06 | 2009-03-11 | 张少武 | Acaricide composition containing benzamide and azocyclotin |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102669157A (en) | 2012-09-19 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102038007B (en) | Sarmentose pepper herb extract and application thereof in preparing insecticidal bacteriostat | |
| CN103271041B (en) | A kind of Compositional type farmland, fruit tree miticide | |
| CN101715777B (en) | Pesticide composition containing ethirimol and thiophanate-methyl, and application thereof | |
| KR101132712B1 (en) | Environment-friendly organic agricultural products for soil insect pest control | |
| CN101836633A (en) | Pesticide composition containing amino-oligosaccharide and kresoxim-methyl and use method and application thereof | |
| CN105272633A (en) | Method of preparing fertilizer with effects of prevention and control of underground pests of crops | |
| CN102669157B (en) | Mite-killing composition and preparation thereof | |
| CN103430943A (en) | Synergistic kasugamycin composition containing tea saponin | |
| CN105272630A (en) | Method for preparing fertilizer capable of controlling soil crop pests | |
| CN103518769B (en) | Insecticidal composition | |
| CN101248798A (en) | Compounded pesticides containing multiple killing teichomycin | |
| CN102939985B (en) | Pesticide composition | |
| CN101919403B (en) | Pesticide composition of allyl isothiocyanate and phoxim | |
| CN102696655B (en) | Compound pesticide composition containing spirodiclofen and preparation thereof | |
| CN105010368B (en) | Composition pesticide and its application | |
| CN105265497A (en) | Preparation method for fertilizer-mixing biological disinsection additive | |
| CN105532719A (en) | Weeding composition and application and preparation thereof | |
| CN105315075A (en) | Fertilizer capable of controlling underground crop pests | |
| CN102715168B (en) | Sterilization combination containing phenylate diazole and azoxystrobin and application thereof | |
| CN104938496A (en) | Herbicide composition comprising mesotrione, terbuthylazine and metolachlor | |
| CN104522006B (en) | A kind of preventing and treating Lepidoptera and homoptera pest compositions | |
| CN107318866A (en) | A kind of Pesticidal combination | |
| CN105272634A (en) | Preparation method of fertilizer capable of preventing and controlling underground harmful insects | |
| CN103719115A (en) | Insecticidal composition | |
| CN101524086B (en) | Desinsection composition containing nitenpyram and orthene |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| PP01 | Preservation of patent right |
Effective date of registration: 20220321 Granted publication date: 20140813 |
|
| PP01 | Preservation of patent right |