CN106417330A - Insecticidal composition containing cyclaniliprole and spirotetramat - Google Patents
Insecticidal composition containing cyclaniliprole and spirotetramat Download PDFInfo
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- CN106417330A CN106417330A CN201610829478.4A CN201610829478A CN106417330A CN 106417330 A CN106417330 A CN 106417330A CN 201610829478 A CN201610829478 A CN 201610829478A CN 106417330 A CN106417330 A CN 106417330A
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- Prior art keywords
- spiral shell
- ethyl ester
- shell worm
- insect amide
- worm ethyl
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having no bond to a nitrogen atom
- A01N47/06—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having no bond to a nitrogen atom containing —O—CO—O— groups; Thio analogues thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
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- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention relates to insecticidal composition containing cyclaniliprole and spirotetramat. The weight ratio of the two active ingredients is 1:20-20:1, the total content of the active ingredients in the insecticidal composition is 1%-90% by mass, and the remaining is auxiliary ingredients which are permissible and acceptable in the pesticide. The insecticidal composition can be prepared in forms of wettable powder, a water emulsion, a suspending agent, a microemulsion, emulsifiable concentrate, a microcapsule suspension, water dispersible granules, soluble powder, soluble granules and a dispersible oil suspension. The composition has a significant synergistic effect on crops, can reduce the use rate of pesticides and is environment-friendly and safe.
Description
Technical field
The present invention relates to composition pesticide field and in particular to be a kind of agriculture containing ring bromine insect amide and spiral shell worm ethyl ester
Medicine Pesticidal combination.
Background technology
Ring bromine insect amide（cyclaniliprole）, chemical name：The bromo- N- of 3- { the chloro- 6- of the bromo- 4- of 2- { [(1- cyclopropyl second
Base) amine] carbonyl } phenyl } -1- (3- chloro-2-pyridyl) -1H-Pyrazoles -5- Methanamide, its structural formula is：
.
Ring bromine insect amide is a kind of novelty bisamide insecticides of Japanese Shi Yuan industry companies exploitation, because of its mechanism of action
Extensively concerned different from other bisamide classes, future is expected to play a significant role in preventing and treating resistant insect field.This agent is to target
Mark pest efficient, to non-Target crops safety, has the insecticidal activity of wide spectrum, can be used for fruit tree, vegetable, Rhizoma Solani tuber osi, Camellia sinensis, big
The various crop such as bean and Cotton Gossypii, preventing and treating Lepidoptera, coleoptera, Thysanoptera, Diptera and homoptera pest etc..
Spiral shell worm ethyl ester is a kind of novelty insecticide in research and development in 2009 for the Bayer Cropscience Co., Ltd, chemical name：Cis -4-
(ethyl oxy carbonyl) -8- methoxyl group -3- (2,5- xylyl) -1- azaspiro [4.5] decyl- 3- alkene -2- ketone, molecular formula：
C21H27O5N, belongs to tetronic acid class compound.Its structural formula is：
.
Spiral shell worm ethyl ester is the novel compounds of a kind of efficient interior suction and Bidirectional Conduction.By suppressing the synthesis of insect body fat
During acetyl-CoA carboxylase activity, thus suppress fat synthesis, block the normal energy metabolism of insect, finally
Lead to death.Spiral shell worm ethyl ester is used for preventing and treating multiple suckings pest, and this compound has two-way in xylem and phloem
Uptake and translocation performance, can move down upwards in whole plant, arrive at blade face and bark, thus preventing and treating such as Caulis et Folium Lactucae Sativae and white
On dish internal lobe, and the insect in skin of fruit tree.This unique interior suction performance can protect newborn stem, leaf and root, prevents insect
Ovum and larval growth；Its another feature was that the lasting period is long, it is possible to provide up to effective preventing and treating of 8 weeks.Spiral shell worm ethyl ester is except right
Outside the efficient effect of scale insect, simultaneously to red spider, aphid (eriosoma lanigerum, citrus aphid, black peach aphid, radicola), wood louse, pear sucker,
The pierce-suck type implication insects such as aleyrodid, thrips (flower thripss, Scirothrips dorsalis, onion thrips) have good preventive effect.
In the real process of agricultural production, apply the maximally efficient means that chemical agent is preventing and treating plant pest, but
It is to be easiest to generate the problem that the drug-fast generation of insect pest by chemical prevention insect pest.Practical application proves, pesticide single dose pair
Pest control effect is gradually reduced, and some pesticide activity components compound and can reach raising drug effect, and delay insect pest drug-fast
Produce.We screen indoors with field test on the basis of, filter out ring bromine insect amide and spiral shell worm ethyl ester compounded, have
Significantly potentiation；And the compounding composition pesticide with regard to ring bromine insect amide and spiral shell worm ethyl ester and application not yet report at present
Cross.
Content of the invention
It is an object of the invention to being not enough for prior art, providing a kind of applied widely, low cost, effect good, can solve
The certainly ring bromine insect amide of plant resistance problems and the Pesticidal combination of spiral shell worm ethyl ester.
The present invention is achieved by the following technical programs：
A kind of Pesticidal combination containing ring bromine insect amide and spiral shell worm ethyl ester is it is characterised in that include the first active component（A）Ring
Bromine insect amide, the second active component（B）Spiral shell worm ethyl ester, active components A and active component B preferred weight ratio are 1:50～50:1,
More preferably 1:20～20:1；The cumulant of the first active component and the second active component in the Pesticidal combination of the present invention（Weight
Amount plus and）For said composition gross weight preferably 1%～90%.
Described Pesticidal combination is re-dubbed, with known auxiliary agent and excipient, the dosage form allow on pesticide：It can be for example breast
Oil, wettable powder, water dispersible granules, suspending agent, aqueous emulsion, microemulsion, suspension emulsion, dispersible oil-suspending agent, microcapsule suspension
In agent any one.
In the Pesticidal combination of the present invention, two kinds of effective ingredient show obvious potentiation, and thrips prevention effect is shown
Write, show excellent quick-acting and lasting effect, the shortcoming overcoming each single dose.
Compared with prior art, the present invention has following beneficial effect：（1）Compared with single dose, this combination is to thrips, shell
The insect potentiation such as worm, aphid, wood louse, red spider substantially, overcomes and has delayed Drug resistance, expands preventing and treating spectrum, improves anti-
Control effect；（2）Decrease preventing and treating recruitment, drug cost；（3）Alternative routine medicine and the easy pesticide producing resistance；（4）With list
Agent is compared, and two kinds of single dose combinations can reduce application cost.
Specific embodiment
In order that the objects, technical solutions and advantages of the present invention become more apparent, present invention specific examples below
Illustrate, but the present invention is limited to absolutely not these examples.Described below is only the preferable embodiment of the present invention, is used only for explaining
The present invention, but can not be therefore understands that being the restriction to the scope of the claims of the present invention.It should be understood that when, all spirit in the present invention and
Any modification, equivalent or improvement of being made within principle etc., should be included within the scope of the present invention, therefore,
The protection domain of patent of the present invention should be defined by claims.
First, example of formulations
Embodiment 1：51% ring bromine insect amide spiral shell worm ethyl ester wettable powder
Ring bromine insect amide 1%
Spiral shell worm ethyl ester 50%
Sodium lauryl sulphate 2%
Sodium lignin sulfonate 10%
Citric acid 0.5%
White carbon 5%
Kaolin complements to 100%
The concrete procedure of processing of said composition wettable powder is：By above-mentioned formula by ring bromine insect amide and spiral shell worm ethyl ester, and
Dispersant, wetting agent and filler mixing, uniform stirring in stirred tank, mix homogeneously after comminution by gas stream, you can this is obtained
The bright described wettable powder containing ring bromine insect amide and spiral shell worm ethyl ester.
Embodiment 2：42% ring bromine insect amide spiral shell worm ethyl ester suspending agent
Ring bromine insect amide 2%
Spiral shell worm ethyl ester 40%
Polycarboxylate 4%
Lignosulfonates 2%
Hydroxyl poly- oxepane block copolymer 1.5%
Xanthan gum 0.2%
Aluminium-magnesium silicate 0.4%
Antibacterial 0.2%
Citric acid 0.5%
Propylene glycol 4%
Defoamer 0.5%
Water complements to 100%
The concrete procedure of processing of said composition suspending agent is：By in above-mentioned formula by water and wetting agent, dispersant, thickening agent, anti-
Freeze agent, antibacterial, stabilizer and defoamer mixing, through high speed shear mix homogeneously, add ring bromine insect amide and spiral shell worm ethyl ester,
Continue shearing to mix, grind subsequently in horizontal sand mill, make preparation particle diameter all in below 5um, be obtained of the present invention
The suspending agent containing ring bromine insect amide and spiral shell worm ethyl ester.
Embodiment 3：30% ring bromine insect amide spiral shell worm ethyl ester suspending agent
Ring bromine insect amide 5%
Spiral shell worm ethyl ester 25%
Polycarboxylate 3%
Lignosulfonates 2%
Hydroxyl poly- oxepane block copolymer 1%
White carbon 1%
Xanthan gum 0.3%
Aluminium-magnesium silicate 0.3%
Antibacterial 0.3%
Citric acid 0.5%
Propylene glycol 4%
Defoamer 0.5%
Water complements to 100%
The concrete procedure of processing of said composition suspending agent is：By in above-mentioned formula by water and wetting agent, dispersant, thickening agent, anti-
Freeze agent, antibacterial, stabilizer and defoamer mixing, through high speed shear mix homogeneously, add ring bromine insect amide and spiral shell worm ethyl ester,
Continue shearing to mix, grind subsequently in horizontal sand mill, make preparation particle diameter all in below 5um, be obtained of the present invention
The suspending agent containing ring bromine insect amide and spiral shell worm ethyl ester.
Embodiment 4：2% ring bromine insect amide spiral shell worm ethyl ester microemulsion
Ring bromine insect amide 1%
Spiral shell worm ethyl ester 1%
N-Methyl pyrrolidone 8%
Ketohexamethylene 6%
Citric acid 0.3%
Calcium dodecyl benzene sulfonate 4%
Phenethyl phenol polyoxyethylene ether 11%
Water complements to 100%
The concrete procedure of processing of said composition suspending agent is：By in above-mentioned formula by ring bromine insect amide and spiral shell worm ethyl ester, solvent, breast
Agent is added together, and makes to be dissolved into homogeneous oil phase, and water-soluble component and water are mixed to prepare aqueous phase, under agitation, by oil phase with
The transparent liquid of aqueous phase mix homogeneously, is obtained the microemulsion containing ring bromine insect amide and spiral shell worm ethyl ester of the present invention.
Embodiment 5：25% ring bromine insect amide spiral shell worm ethyl ester dispersibles oil-suspending agent
Ring bromine insect amide 15%
Spiral shell worm ethyl ester 10%
Calcium dodecyl benzene sulfonate 10%
Castor oil polyoxyethylene ether 10%
Organobentonite 3%
Methyl oleate polishing is to 100%
The concrete procedure of processing that said composition dispersibles oil-suspending agent is：By above-mentioned formula by oil and dispersant, thickening agent, emulsifying
Agent mixes, and through high speed shear mix homogeneously, adds ring bromine insect amide and spiral shell worm ethyl ester, continues shearing and mixes, subsequently into horizontal
In sand mill grind, make preparation particle diameter all in below 10um, be obtained of the present invention containing ring bromine insect amide and spiral shell worm second
Ester dispersible oil-suspending agent.
Embodiment 6：30% ring bromine insect amide spiral shell worm ethyl ester suspending agent
Ring bromine insect amide 25%
Spiral shell worm ethyl ester 5%
Polycarboxylate 3%
Lignosulfonates 2%
Hydroxyl poly- oxepane block copolymer 1%
White carbon 1%
Xanthan gum 0.3%
Aluminium-magnesium silicate 0.3%
Antibacterial 0.3%
Citric acid 0.3%
Propylene glycol 4%
Defoamer 0.5%
Water complements to 100%
The concrete procedure of processing of said composition suspending agent is：By in above-mentioned formula by water and wetting agent, dispersant, thickening agent, anti-
Freeze agent, antibacterial, stabilizer and defoamer mixing, through high speed shear mix homogeneously, add ring bromine insect amide and spiral shell worm ethyl ester,
Continue shearing to mix, grind subsequently in horizontal sand mill, make preparation particle diameter all in below 5um, be obtained of the present invention
The suspending agent containing ring bromine insect amide and spiral shell worm ethyl ester.
Embodiment 7：42% ring bromine insect amide spiral shell worm ethyl ester water dispersion granule
Ring bromine insect amide 40%
Spiral shell worm ethyl ester 2%
Polycarboxylate 4%
Sodium lauryl sulphate 2%
Alkyl naphthalene formaldehyde condensate sulfonates 2%
Citric acid 0.5%
Kaolin complements to 100%
The concrete procedure of processing of said composition water dispersible granules is：By above-mentioned formula by ring bromine insect amide, spiral shell worm ethyl ester and dispersion
Agent, wetting agent, disintegrating agent and filler mix homogeneously, are pulverized with micro jet, through mediating, subsequently into extruder grain
Machine pelletize, in boiling drier be dried, through sample analysis after screening, be obtained of the present invention containing ring bromine insect amide and spiral shell worm
The water dispersible granules of ethyl ester.
Embodiment 8：51% ring bromine insect amide spiral shell worm ethyl ester wettable powder
Ring bromine insect amide 50%
Spiral shell worm ethyl ester 1%
Sodium lauryl sulphate 2%
Sodium lignin sulfonate 8%
Alkyl naphthalene formaldehyde condensate sulfonates 2%
Citric acid 0.2%
White carbon 5%
Kaolin complements to 100%
The concrete procedure of processing of said composition wettable powder is：By above-mentioned formula by ring bromine insect amide and spiral shell worm ethyl ester, and
Dispersant, wetting agent and filler mixing, uniform stirring in stirred tank, mix homogeneously after comminution by gas stream, you can this is obtained
The bright described wettable powder containing ring bromine insect amide and spiral shell worm ethyl ester.
2nd, efficiency test example
1st, Toxicity Determination
For bromine insect amide and the definite virulence to thrips for the spiral shell worm ethyl ester mixture compositionss of unlinking, first pass through Toxicity Determination pair
Screened in its proportioning, the co-toxicity coefficient after clear and definite two kinds of medicaments are compounding by a certain percentage（CTC）, CTC ＜ 80 is antagonism
Effect, 80≤CTC≤120 are summation action, and CTC ＞ 120 is potentiation.
Concrete test method：Respectively the mother solution of each mixed agent is diluted to five series concentration, is respectively placed in standby in beaker
With.Using first soaking the method that leaf is followed by worm, the blade of the same size not in contact with any medicament is put in the medicinal liquid having configured
Soak 5s, naturally dry after taking-up, put in insect box, then connect for examination nymph, raise under the conditions of 26 DEG C, each process
Be repeated 3 times, repeat test worm number used every time and be 50, set blank simultaneously, after 72h, check dead borer population, calculate mortality rate and
Corrected mortality, tries to achieve virulence regression equation and calculates LC50Value.If comparison mortality rate is more than 10%, it is considered as invalid test.Meter
Calculate formula as follows：
Mortality rate（%）=（Borer population alive after borer population medicine alive before medicine）Borer population × 100 alive before/medicine
Corrected mortality（%）=（Treatment group mortality rate control group mortality rate）/（1 matched group mortality rate）×100
Insect corrected mortality is converted into probit value（y）, concentration for the treatment of（μg/ml）It is converted into logarithm value（x）, with least square
Method draws virulence regression equation, and thus calculates the LC of every kind of medicament50Value.Calculate co-toxicity coefficient according to the abundant equation of Sun Yun
CTC.Computing formula is as follows（With ring bromine insect amide as standard agent, its toxicity index is 100）：
The toxicity index of spiral shell worm ethyl ester（TI）The LC of=ring bromine insect amide50The LC of spiral shell worm ethyl ester50×100
The actual toxicity index of M（ATI）The LC of=ring bromine insect amide50The LC of M50×100
The theoretical toxicity index of M（TTI）TI × the P of=ring bromine insect amideRing bromine insect amideTI × the P of+spiral shell worm ethyl esterSpiral shell worm ethyl ester
Co-toxicity coefficient（CTC）TTI × 100 of the ATI M of=M
In formula：M is the mixture of different ratio
PSpiral shell worm ethyl esterFor spiral shell worm ethyl ester ratio shared in the composition
PRing bromine insect amideFor ring bromine insect amide ratio shared in the composition
For trying insect：Semen vignae sinensiss thrips
Test medicine is provided by Foshan Brightmart Crop Science Co., Ltd..EXPERIMENTAL DESIGN：Determine ring bromine through pilot study
Insect amide and effective lethasl concentration scope of spiral shell worm ethyl ester active compound and the two different ratio mixture.Experimental result such as following table：
As shown in Table 1, ring bromine insect amide and the compounding Toxicity Determination to thrips of spiral shell worm ethyl ester, co-toxicity coefficient is all higher than 120,
I.e. the present composition has preferable synergistic function, and its effect is all better than single dose.
2nd, field control effectiveness test
Experiment process：This experiment separately designs two dosings according to the difference of each composition, and dosing is effective ingredient
The quality of ring bromine insect amide and spiral shell worm ethyl ester and.Comparison medicament is 20% ring bromine insect amide preparation and 24% spiral shell worm ethyl ester preparation and sky
White clean water experiment.
Test method：Each plot area is 66.7m2, it is repeated 3 times；Investigation drug effect side after investigating before dispenser and preventing and treating
Method is, 5 points of randomization in test process area, carries out severity Scaling according to national field test relevant criterion, calculates preventive effect.
Result of the test such as following table：
From table 2, field control effectiveness test result shows, ring bromine insect amide and spiral shell worm ethyl ester can effectively prevent and treat Semen vignae sinensiss after compounding
Insect, the compositionss of the present invention have obvious synergistic function, and prevention effect is all better than single dose, and preventive effect phase is long；In examination
Test in scope of medication and Semen vignae sinensiss are had no adverse effects, there is using value.
Claims (6)
1. a kind of Pesticidal combination is it is characterised in that active component comprises ring bromine insect amide and spiral shell worm ethyl ester.
2. Pesticidal combination according to claim 1 is it is characterised in that the weight of described ring bromine insect amide and spiral shell worm ethyl ester
Than for 1:50～50:1.
3. the Pesticidal combination according to any one of claim 1～2 requires is it is characterised in that described ring bromine insect amide
Weight ratio preferably 1 with spiral shell worm ethyl ester:20～20:1.
4. the Pesticidal combination according to any one of claims 1 to 3 requires is it is characterised in that described Pesticidal combination
It is aided with insecticidal preparation processing auxiliary element and be processed into any one dosage form being suitable for agriculturally using.
5. Pesticidal combination according to claim 4 is it is characterised in that the dosage form of described pesticide combination is wettable powder
Agent, aqueous emulsion, suspending agent, microemulsion, cream, microcapsule suspending agent, water dispersible granules, dispersible oil-suspending agent, solvable powder, can
In molten granule any one.
6. Pesticidal combination according to any one of Claims 1 to 5 claim is used for preventing and kill off the use of crop pests
On the way.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201610829478.4A CN106417330A (en) | 2016-09-19 | 2016-09-19 | Insecticidal composition containing cyclaniliprole and spirotetramat |
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| CN201610829478.4A CN106417330A (en) | 2016-09-19 | 2016-09-19 | Insecticidal composition containing cyclaniliprole and spirotetramat |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110150296A (en) * | 2019-06-06 | 2019-08-23 | 青岛润农化工有限公司 | A kind of Tolfenpyrad and the Pesticidal combination of spiral shell worm ethyl ester and the preparation method and application thereof |
| CN115119837A (en) * | 2021-08-10 | 2022-09-30 | 永农生物科学有限公司 | Flonicamid-spirotetramat mixed preparation and application thereof |
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| CN101557710A (en) * | 2006-12-14 | 2009-10-14 | 石原产业株式会社 | Pesticidal compositions |
| CN104488943A (en) * | 2014-10-23 | 2015-04-08 | 东莞市瑞德丰生物科技有限公司 | Insecticidal composition |
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- 2016-09-19 CN CN201610829478.4A patent/CN106417330A/en active Pending
Patent Citations (3)
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| CN1591004A (en) * | 2003-08-29 | 2005-03-09 | 中国石油化工股份有限公司 | Method of analyzing diesel oil hydrocarbon composition using solid phase extraction and mass chromatogrophy |
| CN101557710A (en) * | 2006-12-14 | 2009-10-14 | 石原产业株式会社 | Pesticidal compositions |
| CN104488943A (en) * | 2014-10-23 | 2015-04-08 | 东莞市瑞德丰生物科技有限公司 | Insecticidal composition |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN110150296A (en) * | 2019-06-06 | 2019-08-23 | 青岛润农化工有限公司 | A kind of Tolfenpyrad and the Pesticidal combination of spiral shell worm ethyl ester and the preparation method and application thereof |
| CN115119837A (en) * | 2021-08-10 | 2022-09-30 | 永农生物科学有限公司 | Flonicamid-spirotetramat mixed preparation and application thereof |
| CN115119837B (en) * | 2021-08-10 | 2023-12-26 | 永农生物科学有限公司 | Flonicamid-spirotetramat mixed preparation and application thereof |
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Application publication date: 20170222 |