CN111165503A - Pesticide composition containing fluxapyroxad and rotenone - Google Patents

Pesticide composition containing fluxapyroxad and rotenone Download PDF

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Publication number
CN111165503A
CN111165503A CN202010070218.XA CN202010070218A CN111165503A CN 111165503 A CN111165503 A CN 111165503A CN 202010070218 A CN202010070218 A CN 202010070218A CN 111165503 A CN111165503 A CN 111165503A
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rotenone
agent
fluxapyroxad
fluxapyroxamide
pesticide
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陈佳佳
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Zhejiang Zhongshan Chemical Industry Group Co ltd
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Zhejiang Zhongshan Chemical Industry Group Co ltd
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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/40—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having a double or triple bond to nitrogen, e.g. cyanates, cyanamides

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  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

A pesticide composition containing fluxapyroxad and rotenone comprises the active ingredients of fluxapyroxad and rotenone which are compounded in a binary manner, wherein the mass ratio of the fluxapyroxad to the rotenone is 1: 8-8: 1; the mass percentage of the fluxapyroxamide and rotenone in the pesticide composition is 1-20%; the pesticide composition is prepared into any one dosage form by taking the fluxapyroxad and the rotenone as active ingredients and pesticide preparation auxiliary ingredients allowed in pesticides; the auxiliary components of the pesticide preparation comprise an auxiliary agent and a filler; the auxiliary agent comprises a solvent, a cosolvent, an emulsifier, a dispersant, a wetting agent, a disintegrating agent, a binder, a defoaming agent, an antifreeze agent and a thickening agent; the preparation formulation comprises a suspending agent, wettable powder, water dispersible granules, a water agent and missible oil. After the fluxapyroxad and the rotenone are compounded according to different proportions, the control effect on agricultural insect pests is obviously improved, and the use amount of the effective components is greatly reduced under the condition of the same control effect, so that the harm to the environment is reduced and the resistance of the pests is delayed.

Description

Pesticide composition containing fluxapyroxad and rotenone
Technical Field
The invention relates to the field of pesticide preparations, in particular to a pesticide composition containing fluxapyroxad and rotenone.
Background
Fluxaflutole is a novel isoxazole insecticide created by japanese chemical company, english name: fluxamamide, molecular formula: c20H16Cl2F3N3O3The fluxaflutole is an antagonist of a gamma-aminobutyric acid gated chloride channel and a glutamic acid gated chloride channel, has wide insecticidal activity, and is suitable for lepidoptera pests, thrips and powder on crops such as fruit trees, vegetables, soybeans, cotton, tea trees and the likeControl of lice, leaf miner, beetle and mites. The term "fluxazolamides" as used herein is understood to mean compounds or isomers having the structure.
Figure BDA0002377095910000011
Rotenone is a high-efficiency insecticidal active substance extracted from a derris vine plant of derris, plays a role in contact poisoning and stomach poisoning, and is a green pesticide recognized in the world.
At present, in agricultural production, the application of pesticides is an important means for preventing and controlling plant diseases and insect pests, but with the repeated use of a large amount of existing pesticides and the improper application of pesticides by some farmers, some pests gradually begin to have relatively large resistance to the existing common pesticides, and the difficulty of pesticide control becomes greater and greater. For the problem, a common solution is to develop a new medicament and a compound medicament, but the former has high cost and long time consumption, so that the effective components of the two medicaments with different action mechanisms are combined into a compound pesticide, and the method is effective and shortcut for developing and researching the pesticide and treating the problem of resistance of pests. Therefore, the development of a novel high-efficiency, low-toxicity and safe botanical and chemical pesticide compound insecticide has important significance for preventing and treating insect pests.
Disclosure of Invention
In order to solve the resistance of the pesticide to pests in actual field application, the inventor of the application discovers that after rotenone and fluxapyroxad are mixed in a certain range through a large amount of indoor screening and field efficacy test effect analysis, the obtained novel compound pesticide has an obvious synergistic effect on lepidoptera pests, thrips, whiteflies, leaf miners, beetles, mites and the like, and is not only the addition of two simple medicaments, so that the use cost can be reduced, the safety to crops is high, and the application and the compounded pesticide composition of the rotenone plant-derived pesticide and the fluxapyroxad chemical pesticide are not reported at present.
The method for preparing the pesticide preparation by combining the effective components of different pesticides is a quick and effective method for developing and researching new pesticides at present. The mixing of different types of pesticidal active ingredients generally shows three types of action: additive action, synergistic action and antagonistic action. However, after different types of pesticide active ingredients are mixed, the specific action is unpredictable; and the active ingredients of the pesticide are not simply mixed, and auxiliary ingredients of the pesticide preparation are required to be added, and the different types and the different amounts of the auxiliary ingredients of the pesticide preparation directly influence the exertion of the active ingredients of the pesticide.
The invention aims to provide a pesticide composition containing fluxapyroxad and rotenone, which solves the problem of resistance of pesticides to pests in actual field application.
The purpose is realized by the following technical scheme:
the pesticide composition comprises the active ingredients of fluxapyroxamide and rotenone, and is a binary complex formulation, wherein the mass ratio of the fluxapyroxamide to the rotenone is 1: 8-8: 1.
Preferably, the mass ratio of the fluxapyroxamide to the rotenone is 1: 6-6: 1, and the mass percentage of the fluxapyroxamide to the rotenone in the pesticide composition is 1-20%.
Preferably, the mass ratio of the fluxapyroxamide to the rotenone is 1: 4-4: 1.
Further, the mass ratio of the fluxapyroxamide to the rotenone is 1: 2-2: 1.
Preferably, the mass ratio of the fluxapyroxamide to the rotenone is 1: 1.
Furthermore, the pesticide composition is prepared into any dosage form by taking the fluxapyroxad and the rotenone as active ingredients and pesticide preparation auxiliary ingredients allowed in pesticides.
Preferably, the auxiliary components of the pesticide preparation are an auxiliary agent and a filler, and different auxiliary agents and/or fillers are selected from different pesticide formulations.
Furthermore, the auxiliary agent comprises a solvent, a cosolvent, an emulsifier, a dispersant, a wetting agent, a disintegrating agent, a binder, a defoaming agent, an antifreeze agent and a thickening agent.
Furthermore, the preparation formulation comprises a suspending agent, wettable powder, water dispersible granules, a water agent and missible oil.
the solvent in the invention is selected from one or more of xylene, No. 100 solvent oil, No. 150 solvent oil, No. 200 solvent oil and formaldehyde, the cosolvent is selected from one or more of methanol, ethanol, ethyl acetate, cyclohexanone, toluene, acetone and N-methyl pyrrolidone, the emulsifier is selected from one or more of fatty acid diethanolamide, calcium dodecyl benzene sulfonate, fatty alcohol polyoxyethylene ether, alkylphenol polyoxyethylene ether, Nongru No. 500, Nongru No. 700, alkyl glycoside and α -olefin sodium sulfonate, the dispersant is selected from one or more of sodium lignosulfonate, calcium lignosulfonate, sodium naphthalene sulfonate formaldehyde condensate, methylene dinaphthalene sodium sulfonate, formaldehyde condensate sulfate, polycarboxylate, alkylphenol polyoxyethylene phosphate, alkylphenol polyoxyethylene ether and fatty acid polyoxyethylene ester, the wetting agent is selected from one or more of sodium dodecyl sulfate, nekal BX, gleditsia sinensis lam powder, sodium dodecyl benzene sulfonate, silkworm excrement, soapberry powder, alkyl polyglycoside and tea cumyl powder, the disintegrant is selected from one or more of bentonite, ammonium sulfate, aluminum chloride, urea, magnesium chloride, glucose, one or more of bentonite, one or more of ethylene glycol, sodium alginate, cellulose, sodium alginate, cellulose, sodium chloride, cellulose, one or more of sodium alginate, one or more of bentonite, one or more of sodium alginate, one or more of silicone oil, one or sodium alginate, one or more of silicone oil, one or sodium acrylate, silicone oil, sodium acrylate, one or sodium acrylate, silicone oil, one or sodium acrylate, one.
Has the advantages that:
1. after the fluxapyroxad and the rotenone are compounded, cabbage diamondback moth can be effectively prevented and treated, the prevention and treatment effect is superior to that of a control medicament, the duration is long, and the pesticide damage to target crops is avoided.
2. After the fluxapyroxad and the rotenone are compounded according to different proportions, the control effect on agricultural insect pests is obviously improved, and under the condition of the same control effect, the use amount of the effective components is greatly reduced, so that the harm to the environment is reduced, and the resistance of the pests is delayed.
Detailed Description
In order to make the objects, technical solutions and advantages of the present invention more apparent, the present invention is described with the following embodiments, but the present invention is by no means limited to these examples. The following description is only for the purpose of explanation and should not be construed as limiting the scope of the invention. It should be understood that any modification, equivalent substitution, and improvement made within the spirit and principle of the present invention should be included in the scope of the present invention.
In the following, a detailed description will be given of an insecticidal composition according to the present invention in combination with examples, wherein 50g/L of a fluxaflutole soluble agent and 2.0% of an aqueous rotenone solution are commercially available.
Example 1:
7% of fluxaflutole-rotenone suspension
6% of fluxapyroxamide, 1% of rotenone, 2.2% of saponin powder, 3.6% of calcium lignosulfonate, 0.3% of sodium chloride, 2.5% of propylene glycol, 4.8% of sodium carboxymethylcellulose and the balance of deionized water to 100%. The raw materials are mixed according to a conventional method for preparing the suspending agent to prepare the 7 percent of the fluoro-oxazole amide-rotenone suspending agent.
Example 2;
3% of fluxaflutole-rotenone suspension
0.6% of fluxapyroxamide, 2.4% of rotenone, 4.4% of sodium dodecyl benzene sulfonate, 4.8% of calcium lignosulfonate, 2.3% of ethylene glycol, 0.25% of xanthan gum and deionized water for making up to 100%. The raw materials are mixed according to a conventional method for preparing the suspending agent to prepare the 3 percent of the fluoro-oxazole amide-rotenone suspending agent.
Example 3:
5% fluxapyroxad-rotenone wettable powder
4.0% of fluxapyroxamide, 1.0% of rotenone, 4.3% of tea seed cake powder, 3.2% of ethanol, 4.6% of sodium lignosulfonate and diatomite for making up 100%. The raw materials are mixed according to a conventional method for preparing wettable powder, crushed to a certain fineness and mixed uniformly to obtain the product, so that 5% of fluxaflutolamide-rotenone wettable powder is obtained.
Example 4:
9% fluxapyroxad-rotenone wettable powder
8% of fluxapyroxamide, 1% of rotenone, 3.6% of tea seed cake powder, 2.1% of ethanol, 4.7% of sodium lignosulfonate and the balance of diatomite to 100%. The raw materials are mixed according to a conventional method for preparing wettable powder, crushed to a certain fineness and mixed uniformly to obtain the product, so that 9% of fluxaflutolamide-rotenone wettable powder is obtained.
Example 5:
1.8% water dispersible granule of fluxapyroxad-rotenone
0.2% of fluxapyroxamide, 1.6% of rotenone, 4.3% of sodium lignosulfonate, 3.2% of ammonium sulfate, 3.5% of polycarboxylate, 2.8% of starch and the balance of light calcium carbonate to 100%. The raw materials are mixed according to a conventional method for preparing water dispersible granules to obtain the 1.8% water dispersible granules of the fluxapyroxamide-rotenone.
Example 6:
6% water dispersible granule of fluxapyroxad-rotenone
4% of fluxapyroxamide, 2% of rotenone, 5.6% of sodium lignosulfonate, 3.4% of ammonium sulfate, 2.7% of polycarboxylate, 2.4% of starch and the balance of light calcium carbonate to 100%. The 6% water dispersible granule of the fluxapyroxamide-rotenone is prepared by mixing the raw materials according to a conventional method for preparing the water dispersible granule.
Example 7:
4.0% aqueous solution of fluxaflutolamide and rotenone
2% of fluxapyroxamide, 2% of rotenone, 3.5% of N-methyl pyrrolidone, 4.2% of alkyl polyglycoside and deionized water for making up 100%. The 4% aqueous solution of the fluxaflutolamide and the rotenone is prepared by mixing the raw materials according to a conventional method for preparing the aqueous solution.
Example 8:
3% aqueous solution of fluxapyroxamide and rotenone
1% of fluxapyroxamide, 2% of rotenone, 2.6% of N-methyl pyrrolidone, 3.3% of sodium dodecyl benzene sulfonate, 4.8% of calcium lignosulfonate and deionized water for making up 100%. The raw materials are mixed according to a conventional method for preparing the water aqua to obtain the 3 percent aqueous agent of the fluxapyroxamide and the rotenone.
Example 9:
10.0% of fluxapyroxad-rotenone emulsifiable concentrate
8.0 percent of fluxapyroxad, 2.0 percent of rotenone, 3.6 percent of Nongru 500, 4.8 percent of Nongru 700, 4.2 percent of dimethylbenzene, 2.5 percent of methanol and the solvent oil No. 200 which are the balance of 100 percent. The raw materials are mixed according to a conventional method for preparing emulsifiable concentrate to prepare 10.0 percent of emulsifiable concentrate of the fluxapyroxamide and the rotenone.
The combination of the fluxapyroxad and rotenone has obvious synergistic effect on plutella xylostella, but is not only a simple addition of the insecticidal effects of the two pesticide active ingredients, and is specifically illustrated by the following examples.
Example 10: indoor toxicity determination method for compounding of fluxapyroxamide and rotenone
1. Joint toxicity test of different proportions of fluxaflutolide and rotenone on plutella xylostella
1.1 test agent
95% of fluxapyroxamide raw drug, rotenone raw drug, and different proportion mixed preparation of fluxapyroxamide and rotenone
1.2 preparation of test specimens
Selecting diamondback moths which are raised in a laboratory and have consistent physiological state.
1.3 preparation of the medicament
Dissolving fluxapyroxamide and rotenone with methanol, adding 0.1% Tween 80 emulsifier, preparing medicinal liquids with different proportions according to the proportions of fluxapyroxamide and rotenone (1:10, 1:8, 1:6, 1:4, 1:2, 1:1, 2:1, 4:1, 6:1, 8:1 and 10: 1), and making blank control by using the treatment containing only solvent and surfactant but no effective components.
1.4 pharmaceutical agent treatment
Soaking the leaf segments in the medicinal solution for 10s, air drying, placing in a culture dish containing 1% moisture-keeping filter paper, inoculating 20 heads of Plutella xylostella, and repeating for 4 times. Placing the treated test insects at the temperature of 25 +/-1 ℃, the humidity of 75 percent, the illumination period L: and D (16:8) h for feeding and observation.
1.5 investigation
And investigating the death condition of the test insects 24 hours after treatment, and recording the total number of the insects and the number of dead insects.
1.6 data statistics and analysis
Corrected mortality was calculated for each treatment as a percentage (%) based on survey data. And (4) calculating according to the formulas (1) and (2), wherein the calculation results both reserve the last two digits of the decimal point.
Figure BDA0002377095910000061
In the formula:
P1-mortality rate;
k is the number of dead insects;
n-total number of treated insects;
Figure BDA0002377095910000062
in the formula:
P2-correcting mortality;
Pt-managing mortality;
P0-blank control mortality;
1.7 combined virulence determination method based on different proportions
According to the toxicity measurement result of the single agent, the method of 1.6 is adopted to measure the fluxapyroxamide and the rotenone with different proportions, and LC is calculated50And calculating the co-toxicity coefficient (CTC) according to the Sun Yunpei method and the following formula:
ATI＝(S/M)*100…………………………………………(3)
in the formula:
ATI-actually measured toxicity index of mixed agent;
S-LC of Standard insecticide50In mg/L;
LC of M-mixtures50In mg/L.
TTI＝TIA*PA+TIB*PB…………………………………………(4)
In the formula:
TTI-mixture theory virulence index;
TIA-A Agents theoretical virulence index;
the PA-A medicament accounts for the percentage of the mixture and the unit is percentage;
TIB — B agent theoretical virulence index;
the percentage content of the PB-B medicament in the mixed medicament is percentage;
CTC＝(ATI/TTI)*100…………………………………………(5)
in the formula:
CTC-co-toxicity coefficient;
ATI-actually measured toxicity index of mixed agent;
TTI-mixture theory virulence index.
The co-toxicity coefficient (CTC) is more than or equal to 120 and shows a synergistic effect; CTC is less than or equal to 80 and shows antagonism; 80 < CTC < 120 showed additive effect, and the results are shown in tables 1 and 2.
Table 1: results of toxicity determination of different proportions of fluxaflutole and rotenone on plutella xylostella
Medicament LC50(mg/L) TTI ATI CTC
Fluorooxazolamides 9.93 － 100.0 －
Rotenone 14.58 － 68.1 －
A fluoro-oxazole amide: rotenone 1:8 10.57 71.7 93.9 137.9
A fluoro-oxazole amide: rotenone 1:6 10.02 72.7 99.1 145.5
A fluoro-oxazole amide: rotenone 1:4 9.75 74.5 101.8 149.5
A fluoro-oxazole amide: rotenone 1:2 9.51 78.7 104.4 153.3
A fluoro-oxazole amide: rotenone 1:1 9.38 84.1 105.9 155.4
A fluoro-oxazole amide: rotenone 2:1 9.26 89.4 107.2 157.5
A fluoro-oxazole amide: rotenone is 4:1 9.04 93.6 109.8 161.3
A fluoro-oxazole amide: rotenone ═ 6:1 9.16 95.4 108.4 159.2
A fluoro-oxazole amide: rotenone is 8:1 9.21 96.5 107.8 158.3
It can be seen from table 1 that the co-toxicity coefficient of the two components is higher than 120, which indicates that the two components have obvious synergistic effect after being compounded, and thus, the compounding of the two components has strong rationality.
Example 11:
drug effect test of compounding of fluxapyroxad and rotenone
The compound preparation obtained in example 1 to example 9 and each component are used for field efficacy test. Selecting windless and rainless weather for testing, taking the cabbage diamondback moth as a test object, applying the drug for 1 time, investigating survival number of the cabbage diamondback moth at 1d, 3d and 7d after application, and calculating the control effect.
The control effect is calculated according to the following formula:
Figure BDA0002377095910000081
CK0a blank control zone for the number of live insects before application;
CK1-number of live insects after application to the placebo zone;
PT0-number of live insects before application to the agent treatment area;
PT1live insect count after application to the agent treatment area.
The test results are as follows:
table 2: fluroxazolecarboxamide-rotenone composition for preventing and treating plutella xylostella
Figure BDA0002377095910000082
As can be seen from the table 2, the compound of the fluxapyroxad and the rotenone can effectively prevent and treat cabbage diamondback moth, the prevention and treatment effect is superior to that of a control medicament, the duration is long, the prevention effect reaches more than 85% 7 days after the pesticide is applied, and in the application range of the test, the pesticide has no phytotoxicity on target crops.
The test results are combined, so that the control effect on agricultural insect pests is obviously improved after the fluxapyroxad and the rotenone are compounded according to different proportions, and the use amount of the effective components is greatly reduced under the condition of the same control effect, so that the harm to the environment is reduced, and the resistance of pests is delayed.

Claims (9)

1. The pesticide composition is characterized in that the active ingredients of the pesticide composition are compounded of the fluxapyroxamide and rotenone amine, wherein the mass ratio of the fluxapyroxamide to the rotenone is 1: 8-8: 1.
2. The pesticide composition containing the fluxapyroxamide and the rotenone according to claim 1, characterized in that the mass ratio of the fluxapyroxamide to the rotenone is 1: 6-6: 1, and the mass percentage of the fluxapyroxamide to the rotenone in the pesticide composition is 1% -20%.
3. The pesticide composition containing the fluxapyroxamide and the rotenone according to claim 2, wherein the mass ratio of the fluxapyroxamide to the rotenone is 1: 4-4: 1.
4. The pesticide composition containing the fluxapyroxamide and the rotenone according to claim 3, wherein the mass ratio of the fluxapyroxamide to the rotenone is 1: 2-2: 1.
5. The pesticide composition containing the fluxapyroxamide and the rotenone according to claim 4, wherein the mass ratio of the fluxapyroxamide to the rotenone is 1: 1.
6. The pesticidal composition comprising fluxapyroxad and rotenone according to claim 1, characterized in that: the pesticide composition is prepared into any one dosage form by taking the fluxapyroxad and the rotenone as active ingredients and pesticide preparation auxiliary ingredients allowed in pesticides.
7. The pesticidal composition comprising fluxapyroxad and rotenone according to claim 6, characterized in that: the auxiliary components of the pesticide preparation comprise an auxiliary agent and a filler.
8. The pesticidal composition comprising fluxapyroxad and rotenone according to claim 7, characterized in that: the auxiliary agent comprises a solvent, a cosolvent, an emulsifier, a dispersant, a wetting agent, a disintegrating agent, a binder, a defoaming agent, an antifreeze agent and a thickening agent.
9. The pesticidal composition comprising fluxapyroxad and rotenone according to claim 6, characterized in that: the preparation formulation comprises a suspending agent, wettable powder, water dispersible granules, a water agent and missible oil.
CN202010070218.XA 2020-01-21 2020-01-21 Pesticide composition containing fluxapyroxad and rotenone Pending CN111165503A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115530185A (en) * 2022-09-15 2022-12-30 安徽省四达农药化工有限公司 Composition containing oxazole fluoride amide and preparation method and application thereof

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
ASAHI, ET AL.: "Fluxametamide: A novel isoxazoline insecticide that acts via distinctive antagonism of insect ligand-gated chloride channels", PESTICIDE BIOCHEMISTRY AND PHYSIOLOGY, no. 151, pages 252 - 260 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115530185A (en) * 2022-09-15 2022-12-30 安徽省四达农药化工有限公司 Composition containing oxazole fluoride amide and preparation method and application thereof

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Application publication date: 20200519