CN111066798A - Pesticide composition containing cyclic bromoantraniliprole and matrine - Google Patents
Pesticide composition containing cyclic bromoantraniliprole and matrine Download PDFInfo
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- CN111066798A CN111066798A CN201911201246.4A CN201911201246A CN111066798A CN 111066798 A CN111066798 A CN 111066798A CN 201911201246 A CN201911201246 A CN 201911201246A CN 111066798 A CN111066798 A CN 111066798A
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- matrine
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
Abstract
The invention relates to a pesticide composition containing cyclic bromoantraniliprole and matrine, which comprises the active ingredients of the pesticide composition, namely, the binary combination of the cyclic bromoantraniliprole and the matrine, wherein the weight ratio of the cyclic bromoantraniliprole to the matrine is 1: 8-8: 1; the pesticide composition is prepared into any one dosage form by taking the cyclic bromantraniliprole and the matrine as active ingredients and auxiliary agents allowed in pesticides; the preparation formulation is a suspending agent, wettable powder, water dispersible granules or water solution; the auxiliary agent comprises solvent, cosolvent, emulsifier, dispersant, wetting agent, disintegrating agent, binder, defoaming agent, antifreeze agent and thickener. After the cyclic bromoantraniliprole and the matrine are compounded, the cabbage aphid can be effectively controlled, the duration is long, and no phytotoxicity is caused to target crops; after the cyclic bromoantraniliprole and the matrine are compounded according to different proportions, the control effect on agricultural insect pests is obviously improved, and under the condition of the same control effect, the use amount of effective components is greatly reduced, so that the harm to the environment is reduced and the resistance of the pests is delayed.
Description
Technical Field
The invention belongs to the technical field of pesticides, and particularly relates to a pesticide composition containing cyclic bromodiamide and matrine.
Background
The cyclic bromoantraniliprole is an o-formylaminobenzamide insecticide developed by Japan stone original industry company, the English common name is cyclaniliprole, the development code is IKI-3106, and the CAS registry number is 1031756-98-5. Like chlorantraniliprole, the cyclic bromanilide also has a bisamide structure, but the cyclic bromanilide does not act on a ryanodine receptor but acts on a ryanodine receptor variant, and the characteristic enables the cyclic bromanilide to be expected to play an important role in the field of controlling resistant pests, which is different from other bisamide insecticides.
The cyclic bromoantraniliprole has broad-spectrum insecticidal activity, can be used for numerous crops such as fruit trees, vegetables, potatoes, tea trees, soybeans, cotton and the like, and can be used for preventing and treating lepidoptera, coleoptera, thysanoptera, diptera and homoptera pests. Japan stone source corporation filed a registration application in japan and the european union by 2013, and a cyclic bromoxynamide product (50SL) was registered in the united states in 2017 for fruit trees, vegetables, grapes, and the like.
Matrine (Matrine) is an alkaloid, is prepared by extracting dried roots, plants and fruits of sophora flavescens of leguminous plants by using organic solvents such as ethanol and the like, is a natural plant pesticide, can be degraded in nature, has stomach toxicity and contact poisoning effects, and has ideal control effects on lepidoptera insects such as cabbage caterpillar, tea caterpillar, diamond back moth, rice stem borer, tryporyza incertulas, tea lesser leafhopper, whitefly, aphid, red spider and the like. Has the characteristics of low toxicity and low residue, is relatively safe to human beings and livestock, is friendly to the environment and natural enemies, is difficult to generate antibodies to pests, and is a green and environment-friendly pesticide.
At present, in agricultural production, the application of pesticides is an important means for preventing and controlling plant diseases and insect pests, but with the repeated use of a large amount of existing pesticides and the improper application of pesticides by some farmers, some pests gradually begin to have relatively large resistance to the existing common pesticides, and the difficulty of pesticide control becomes greater and greater. For the problem, a common solution is to develop a new medicament and a compound medicament, but the former has high cost and long time consumption, so that the effective components of the two medicaments with different action mechanisms are combined into a compound pesticide, and the method is effective and shortcut for developing and researching the pesticide and treating the problem of resistance of pests.
To solve this problem, the present invention is hereby provided.
Disclosure of Invention
The method for preparing the pesticide preparation by combining the effective components of different pesticides is a quick and effective method for developing and researching new pesticides at present. The mixing of different types of pesticidal active ingredients generally shows three types of action: additive action, synergistic action and antagonistic action. However, after different types of pesticide active ingredients are mixed, the specific action is unpredictable; and the active ingredients of the pesticide are not simply mixed, and auxiliary ingredients of the pesticide preparation are required to be added, and the different types and the different amounts of the auxiliary ingredients of the pesticide preparation directly influence the exertion of the active ingredients of the pesticide.
In order to solve the resistance of the pesticide to pests in actual field application, the applicant finds that after matrine and cyclic bromodiamide are mixed in a certain range, the obtained novel compound pesticide has an obvious synergistic effect on whiteflies, aphids and scale insects, but not only two simple agents are added, so that the use cost can be reduced, the safety to crops is high, and no report is made on a compound pesticide composition of a matrine plant source pesticide and a cyclic bromodiamide chemical pesticide and an application of the compound pesticide composition.
In order to solve the problems, the invention adopts the following technical scheme:
the pesticide composition comprises the effective components of the binary combination of the cyclic bromine amide and the matrine, wherein the weight ratio of the cyclic bromine amide to the matrine is 1: 8-8: 1.
Further, the weight ratio of the cyclic bromantraniliprole to the matrine is 1: 4-4: 1.
Furthermore, the pesticide composition is prepared into any one dosage form by taking the cyclic bromantraniliprole and the matrine as active ingredients and auxiliary agents allowed in pesticides.
The auxiliary components of the pesticide preparation are auxiliary agents and fillers, and different auxiliary agents and/or fillers are selected from different pesticide formulations.
Furthermore, the preparation formulation is a suspending agent, wettable powder, water dispersible granules and an aqueous solution.
Furthermore, the auxiliary agent comprises solvent, cosolvent, emulsifier, dispersant, wetting agent, disintegrating agent, binder, defoaming agent, antifreeze agent and thickener.
Further, the solvent is selected from one or more of xylene, 100 # solvent oil, 150 # solvent oil, 200 # solvent oil and formaldehyde; the disintegrating agent is one or more selected from bentonite, ammonium sulfate, aluminum chloride, urea, magnesium chloride and glucose.
Further, the cosolvent is selected from one or more of methanol, ethanol, ethyl acetate, cyclohexanone, toluene, acetone and N-methyl pyrrolidone; the binder is selected from one or more of starch, diatomite, cyclodextrin, PVA and rosin.
Further, the emulsifier is selected from one or more of fatty acid diethanolamide, calcium dodecyl benzene sulfonate, fatty alcohol-polyoxyethylene ether, alkylphenol polyoxyethylene, Nongru No. 500, Nongru No. 700, alkyl glycoside and α -alkenyl sodium sulfonate, and the defoamer is selected from one or more of C8-210 fatty alcohol compounds, epoxidized soybean oil, ethanol, silicone compounds, organic silicone oil and C10-C20 saturated fatty acid compounds.
Further, the dispersing agent is selected from one or more of sodium lignosulfonate, calcium lignosulfonate, sodium naphthalene sulfonate formaldehyde condensate, sodium methylene dinaphthalene sulfonate, formaldehyde condensate sulfate, polycarboxylate, alkylphenol polyoxyethylene phosphate, alkylphenol polyoxyethylene ether and fatty acid polyoxyethylene ester; the antifreeze agent is selected from one or more of sorbitol, ethylene glycol, polyethylene glycol, propylene glycol, glycerol, urea and sodium chloride.
Further, the wetting agent is selected from one or more of sodium dodecyl sulfate, nekal BX, Chinese honeylocust fruit powder, sodium dodecyl benzene sulfonate, silkworm excrement, soapberry powder, alkyl polyglycoside and tea seed cake powder; the thickening agent is selected from one or more of gelatin, xanthan gum, polyethylene glycol and polyvinyl alcohol.
Has the advantages that:
1. after the cyclic bromoantraniliprole and the matrine are compounded, the cabbage aphid can be effectively controlled, the control effect is better than that of a control medicament, the duration is long, and no phytotoxicity is caused to target crops in the experimental application range.
2. After the cyclic bromoantraniliprole and the matrine are compounded according to different proportions, the control effect on agricultural insect pests is obviously improved, and under the condition of the same control effect, the use amount of effective components is greatly reduced, so that the harm to the environment is reduced and the resistance of the pests is delayed.
Detailed Description
In order to make the objects, technical solutions and advantages of the present invention more apparent, the present invention is described with the following embodiments, but the present invention is by no means limited to these examples. The following description is only for the purpose of explanation and should not be construed as limiting the scope of the invention. It should be understood that any modification, equivalent substitution, and improvement made within the spirit and principle of the present invention should be included in the scope of the present invention.
The following will explain in detail an insecticidal composition according to the present invention with reference to the examples, wherein 50g/L of the cyclic bromodiamide solubles and 2.0% matrine aqueous solution are commercially available.
Example 1:
7% of cyclic bromantraniliprole and matrine suspending agent
6% of cyclic bromodiamide, 1% of matrine, 2.5% of saponin powder, 3.5% of calcium lignosulfonate, 0.3% of sodium chloride, 2.0% of propylene glycol, 4.5% of sodium carboxymethylcellulose and the balance of deionized water to 100%. Mixing the above materials by conventional method to obtain 7% Cyclobromantraniliprole matrine suspension.
Example 2;
3% of cyclic bromantraniliprole and matrine suspending agent
0.6% of cyclic bromoantraniliprole, 2.4% of matrine, 4.5% of sodium dodecyl benzene sulfonate, 4% of calcium lignosulfonate, 2.5% of ethylene glycol, 0.2% of xanthan gum and deionized water for making up to 100%. Mixing the above materials by conventional method to obtain 3% Cyclobromantraniliprole matrine suspension.
Example 3:
5% cyclic bromantraniliprole and matrine wettable powder
4.0% of cyclic bromoantraniliprole, 1.0% of matrine, 4% of tea seed cake powder, 3% of ethanol, 4% of sodium lignosulfonate and diatomite for 100%. The raw materials are mixed according to a conventional method for preparing wettable powder, crushed to a certain fineness and mixed uniformly to obtain the product, so that the 5% of the cyromonamid-matrine wettable powder is obtained.
Example 4:
9% Cyclobromantraniliprole and matrine wettable powder
8% of cyclic bromoantraniliprole, 1% of matrine, 3.5% of tea seed cake powder, 2.5% of ethanol, 4.5% of sodium lignosulfonate and the balance of diatomite to 100%. The raw materials are mixed according to a conventional method for preparing wettable powder, crushed to a certain fineness and mixed uniformly to obtain the product, so that 9% of the cyclic bromantraniliprole-matrine wettable powder is obtained.
Example 5:
1.8% of cyclic bromantraniliprole and matrine water dispersible granule
0.2 percent of cyclic bromodiamide, 1.6 percent of matrine, 4.5 percent of sodium lignosulfonate, 3.0 percent of ammonium sulfate, 3 percent of polycarboxylate, 2.5 percent of starch and the balance of light calcium carbonate to 100 percent. The 1.8 percent of the cyclic bromantraniliprole and matrine water dispersible granule is prepared by mixing the raw materials according to a conventional method for preparing the water dispersible granule.
Example 6:
6% cyclic bromantraniliprole and matrine water dispersible granule
The pesticide composition comprises, by weight, 4% of cyclic bromodiamide, 2% of matrine, 6% of sodium lignosulfonate, 3.5% of ammonium sulfate, 2.5% of polycarboxylate, 2.5% of starch and the balance of light calcium carbonate to 100%. The above raw materials are mixed according to a conventional method for preparing water dispersible granules to obtain 6% of the cyclic bromantraniliprole-matrine water dispersible granules.
Example 7:
4.0% aqueous solution of cyclic bromantraniliprole and matrine
2% of cyclic bromoantraniliprole, 2% of matrine, 3% of N-methylpyrrolidone, 4.5% of alkyl polyglycoside and deionized water for making up 100%. Mixing the above materials according to conventional method to obtain 4% aqueous solution of cyclic bromantraniliprole and matrine.
Example 8:
3% aqueous solution of cyclic bromoantraniliprole and matrine
1% of cyclic bromoantraniliprole, 2% of matrine, 2.5% of N-methyl pyrrolidone, 3.5% of sodium dodecyl benzene sulfonate, 4.5% of calcium lignosulfonate and deionized water for making up 100%. Mixing the above materials according to conventional method to obtain 3% aqueous solution of cyclic bromantraniliprole and matrine.
The combination of the cyclic bromoantraniliprole and the matrine has obvious synergistic effect on aphids, and is not only a simple addition of the insecticidal effects of the two pesticide active ingredients, and the specific description is provided in the following examples.
Example 9: indoor toxicity determination method for compounding of cyclic bromoantraniliprole and matrine
1. Combined toxicity test of different proportions of cyclic bromoantraniliprole and matrine on aphids
1.1 test agent
98% of cyclic bromantraniliprole technical, matrine mother liquor, cyclic bromantraniliprole and matrine mixed preparation with different proportions
1.2 preparation of test specimens
And selecting aphid nymphs which are fed in a laboratory and have consistent insect ages.
1.3 preparation of the medicament
Dissolving the technical grade of the cyclic bromantraniliprole and the stock solution of the matrine by using ethanol, adding 0.1 percent of Tween 80 emulsifier, and preparing liquid medicines with different proportions according to the proportion of the cyclic bromantraniliprole and the matrine (1:8, 1:4, 1:2, 1:1, 2:1, 4:1, 6:1 and 8: 1).
1.4 pharmaceutical agent treatment
Soaking target insects into the medicinal liquid for 5-10s, sucking redundant medicinal liquid with filter paper, transferring the test insects to normal condition for raising, repeating the treatment for 4 times, soaking 15 insects for each time, and setting the treatment containing only solvent and surfactant but no effective component as blank control;
1.5 investigation
And investigating the death condition of the test insects 24 hours after treatment, and recording the total number of the insects and the number of dead insects.
1.6 data statistics and analysis
Corrected mortality was calculated for each treatment as a percentage (%) based on survey data. And (4) calculating according to the formulas (1) and (2), wherein the calculation results both reserve the last two digits of the decimal point.
In the formula:
P1-mortality rate;
k is the number of dead insects;
n-total number of treated insects;
in the formula:
P2-correcting mortality;
Pt-managing mortality;
P0-blank control mortality;
1.7 combined virulence determination method based on different proportions
According to the toxicity test result of the single agent, the cyclic bromantraniliprole and the matrine with different proportions are tested by the method of 1.6, and LC is calculated50And calculating the co-toxicity coefficient (CTC) according to the Sun Yunpei method and the following formula:
ATI＝(S/M)*100…………………………………………(3)
in the formula:
ATI-actually measured toxicity index of mixed agent;
S-LC of Standard insecticide50In mg/L;
LC of M-mixtures50In mg/L.
TTI＝TIA*PA+TIB*PB…………………………………………(4)
In the formula:
TTI-mixture theory virulence index;
TIA-A Agents theoretical virulence index;
the PA-A medicament accounts for the percentage of the mixture and the unit is percentage;
TIB — B agent theoretical virulence index;
the percentage content of the PB-B medicament in the mixed medicament is percentage;
CTC＝(ATI/TTI)*100…………………………………………(5)
in the formula:
CTC-co-toxicity coefficient;
ATI-actually measured toxicity index of mixed agent;
TTI-mixture theory virulence index.
The co-toxicity coefficient (CTC) is more than or equal to 120 and shows a synergistic effect; CTC is less than or equal to 80 and shows antagonism; 80 < CTC < 120 showed additive effect, and the results are shown in tables 1 and 2.
Table 1: results of measuring toxicity of cyclic bromoantraniliprole and matrine on aphids at different ratios
| Medicament | LC50(mg/L) | TTI | ATI | CTC |
| Cyclic bromodiamide | 9.93 | － | 100.0 | － |
| Matrine | 14.58 | － | 68.1 | － |
| Cyclic bromodiamide: 1:8 matrine | 10.57 | 71.7 | 93.9 | 137.9 |
| Cyclic bromodiamide: 1:4 matrine | 9.75 | 74.5 | 101.8 | 149.5 |
| Cyclic bromodiamide: matrine 1:2 | 9.51 | 78.7 | 104.4 | 153.3 |
| Cyclic bromodiamide: 1:1 matrine | 9.38 | 84.1 | 105.9 | 155.4 |
| Cyclic bromodiamide: matrine 2:1 | 9.26 | 89.4 | 107.2 | 157.5 |
| Cyclic bromodiamide: matrine 4:1 | 9.04 | 93.6 | 109.8 | 161.3 |
| Cyclic bromodiamide: matrine 6:1 | 9.16 | 95.4 | 108.4 | 159.2 |
| Cyclic bromodiamide: matrine 8:1 | 9.21 | 96.5 | 107.8 | 158.3 |
As can be seen from the table 1, the co-toxicity coefficient of the compound of the cyclic bromantraniliprole and the matrine is higher than 120, which shows that the compound of the two components has obvious synergistic effect, so that the compound of the cyclic bromantraniliprole and the matrine has strong rationality.
Example 10:
drug effect test of compounding of cyclic bromoantraniliprole and matrine
The compound preparation obtained in example 1 to example 8 and each component are used for field efficacy test. Selecting windless and rainless weather for testing, using cabbage aphids as test objects, applying the pesticide for 1 time, investigating survival numbers of the cabbage aphids at 1d, 3d and 7d after the pesticide application, and calculating the control effect. The control effect is calculated according to the following formula:
CK0a blank control zone for the number of live insects before application;
CK1-number of live insects after application to the placebo zone;
PT0-number of live insects before application to the agent treatment area;
PT1live insect count after application to the agent treatment area.
The test results are as follows:
table 2: control effect of cyclic bromoantraniliprole and matrine composition on downy mildew
As can be seen from the table 2, after the cyclic bromoantraniliprole and the matrine are compounded, the cabbage aphid can be effectively controlled, the control effect is superior to that of a control medicament, the duration is long, the control effect reaches more than 85% 7 days after the pesticide is applied, and in the application range of the test, the pesticide has no phytotoxicity on target crops.
The test results are combined, so that the prevention and control effect on agricultural insect pests is obviously improved after the cyclic bromoantraniliprole and the matrine are compounded according to different proportions, and the use amount of the effective components is greatly reduced under the condition of the same prevention and control effect, so that the harm to the environment is reduced and the resistance of pests is delayed.
Claims (10)
1. The pesticide composition containing the cyclic bromantraniliprole and the matrine is characterized in that the active ingredients of the pesticide composition are binary complex formulation of the cyclic bromantraniliprole and the matrine, wherein the weight ratio of the cyclic bromantraniliprole to the matrine is 1: 8-8: 1.
2. The pesticide composition containing the cyclic bromantraniliprole and the matrine as claimed in claim 1, wherein the weight ratio of the cyclic bromantraniliprole to the matrine is 1: 4-4: 1.
3. The pesticide composition containing the cyclic bromantraniliprole and the matrine as claimed in claim 1, wherein the pesticide composition is prepared into any one dosage form by taking the cyclic bromantraniliprole and the matrine as active ingredients and auxiliary agents allowed in pesticides.
4. The pesticide composition containing the cyclic bromantraniliprole and the matrine as claimed in claim 3, wherein the dosage form is a suspending agent, a wettable powder, a water dispersible granule or a water aqua.
5. The pesticide composition containing the cyclic bromantraniliprole and the matrine as claimed in claim 3, wherein the auxiliary agent comprises a solvent, a cosolvent, an emulsifier, a dispersant, a wetting agent, a disintegrating agent, a binder, a defoaming agent, an antifreeze agent and a thickening agent.
6. The pesticide composition containing the cyclic bromodiamide and the matrine as claimed in claim 5, wherein the solvent is selected from one or more of xylene, 100 # solvent oil, 150 # solvent oil, 200 # solvent oil and formaldehyde; the disintegrating agent is one or more selected from bentonite, ammonium sulfate, aluminum chloride, urea, magnesium chloride and glucose.
7. The pesticide composition containing the cyclic bromantraniliprole and the matrine as claimed in claim 5, wherein the cosolvent is selected from one or more of methanol, ethanol, ethyl acetate, cyclohexanone, toluene, acetone and N-methyl pyrrolidone; the binder is selected from one or more of starch, diatomite, cyclodextrin, PVA and rosin.
8. The pesticide composition containing the cyclic bromantraniliprole and the matrine as claimed in claim 5, wherein the emulsifier is one or more selected from fatty acid diethanolamide, calcium dodecylbenzenesulfonate, fatty alcohol polyoxyethylene ether, alkylphenol polyoxyethylene ether, Nongru 500, Nongru 700, alkyl glycoside and α -sodium alkenyl sulfonate, and the defoamer is one or more selected from C8-210 fatty alcohol compounds, epoxidized soybean oil, ethanol, silicone compounds, silicone oil and C10-C20 saturated fatty acid compounds.
9. The pesticide composition containing the cyclic bromantraniliprole and the matrine as claimed in claim 5, wherein the dispersant is selected from one or more of sodium lignosulfonate, calcium lignosulfonate, sodium naphthalene sulfonate formaldehyde condensate, sodium methylene bis naphthalene sulfonate, formaldehyde condensate sulfate, polycarboxylate, alkylphenol polyoxyethylene phosphate, alkylphenol polyoxyethylene ether and polyoxyethylene fatty acid ester; the antifreeze agent is selected from one or more of sorbitol, ethylene glycol, polyethylene glycol, propylene glycol, glycerol, urea and sodium chloride.
10. The pesticide composition containing the cyclic bromodiamide and the matrine as claimed in claim 5, wherein the wetting agent is selected from one or more of sodium dodecyl sulfate, nekal BX, saponin powder, sodium dodecyl benzene sulfonate, silkworm excrement, soapberry powder, alkyl polyglycoside and tea seed powder; the thickening agent is selected from one or more of gelatin, xanthan gum, polyethylene glycol and polyvinyl alcohol.
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114271288A (en) * | 2022-01-05 | 2022-04-05 | 安徽丰乐农化有限责任公司 | Granular pesticide fertilizer containing meptyldinocap and matrine and application thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN107306976A (en) * | 2017-06-22 | 2017-11-03 | 北京清源保生物科技有限公司 | A kind of Pesticidal combination containing matrine and bromine worm fluorobenzene bisamide and its application |
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Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107306976A (en) * | 2017-06-22 | 2017-11-03 | 北京清源保生物科技有限公司 | A kind of Pesticidal combination containing matrine and bromine worm fluorobenzene bisamide and its application |
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| 张毓琪等: "环境生物毒理学", 天津大学出版社, pages: 252 - 260 * |
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| CN114271288A (en) * | 2022-01-05 | 2022-04-05 | 安徽丰乐农化有限责任公司 | Granular pesticide fertilizer containing meptyldinocap and matrine and application thereof |
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