CN106489952A - Pesticidal combination containing afidopyropen and nitrile pyrrole demodicid mite ester - Google Patents

Pesticidal combination containing afidopyropen and nitrile pyrrole demodicid mite ester Download PDF

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Publication number
CN106489952A
CN106489952A CN201610918187.2A CN201610918187A CN106489952A CN 106489952 A CN106489952 A CN 106489952A CN 201610918187 A CN201610918187 A CN 201610918187A CN 106489952 A CN106489952 A CN 106489952A
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CN
China
Prior art keywords
afidopyropen
pesticidal combination
demodicid mite
nitrile pyrrole
mite ester
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610918187.2A
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Chinese (zh)
Inventor
王景阳
李达忠
李次平
叶宇平
杨建江
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Foshan Yinghui Crop Science Co Ltd
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Foshan Yinghui Crop Science Co Ltd
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Publication date
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Priority to CN201610918187.2A priority Critical patent/CN106489952A/en
Publication of CN106489952A publication Critical patent/CN106489952A/en
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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
    • A01N43/40Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/561,2-Diazoles; Hydrogenated 1,2-diazoles

Abstract

The present invention relates to the Pesticidal combination of a kind of afidopyropen and nitrile pyrrole demodicid mite ester, the weight ratio of two kinds of effective ingredient is 1:20~20:1, the total mass percent content of effective ingredient in Pesticidal combination is 5%~85%, remaining is to allow to use and acceptable auxiliary element in pesticide, can be prepared into wettable powder, suspending agent, aqueous emulsion, microemulsion, cream, suspension emulsion, water dispersible granules, microcapsule suspending agent, solvable powder, soluble granule.The compositionss of the present invention have obvious potentiation crop, it is possible to decrease the utilization rate of pesticide, and pesticide residues are low and easy decomposition, more environmentally-friendly, are a kind of environmentally friendly highly effective pesticides.

Description

Pesticidal combination containing afidopyropen and nitrile pyrrole demodicid mite ester
Technical field
The present invention relates to composition pesticide field, and in particular to be a kind of agriculture containing afidopyropen and nitrile pyrrole demodicid mite ester Medicine Pesticidal combination.
Background technology
Afidopyropen is a kind of new of Japanese Meiji Pharmaceutial Ltd. and Japanese Kitasato Kenkyusho's joint development Insecticide, with brand-new mechanism of action, is respectively provided with cause well to sucking pest such as aphid, plant hopper, scale insect and leafhopper Dead effect, can be used for vegetable, fruit tree, imtertilled crop and ornamental plant etc., and either foliar treatment, plantation is processed at still soil Reason all has good effect, and toxicity is very low.
Nitrile pyrrole demodicid mite ester(cyenopyrafen)It is novel pyrazoles acaricide that Japanese chemical company develops, the mechanism of action is Medicament forms OH- form by metabolism and activates generation activity;This OH- form is on respiratory electron transport chain by upsetting Complex-(Succinate dehydrogenase)Reach the mitochondrial efficiency of suppression, so as to hinder electron transmission, disruptive oxidation phosphorylation mistake Journey.Be mainly used in preventing and treating Fructus Solani melongenae, Fructus Capsici, Fructus Cucumidis sativi, pears, Fructus Fragariae Ananssae, the various demodicid mites evils on fruit tree, vegetable, the Folium Camelliae sinensis such as Citrus, with compared with Good quick-acting and lasting effect.
The resistance problems of agriculture mite pest are global problems, always the weight of agricultural science and technology worker concern Want problem.With the continuity year in year out to mite class chemical prevention, the increase of Pesticide use amount and unscientific use The impact of the factors such as pesticide, causes mite pest resistance increasingly serious, and the mite pest species for producing resistance is continuously increased.Actual Application attestation, pesticide single dose are gradually reduced to mite pest prevention effect, and some pesticide activity component compoundings can reach raising Drug effect, and delay the drug-fast generation of insect pest.We are screened indoors with the basis of field test, are filtered out Afidopyropen and nitrile pyrrole demodicid mite ester are compounded, with obvious potentiation.And with regard to afidopyropen and nitrile pyrrole demodicid mite The composition pesticide of the compounding of ester and application were not yet reported at present.
Content of the invention
It is an object of the invention to being not enough for prior art, there is provided a kind of applied widely, low cost, effect are good, The Pesticidal combination of the afidopyropen and nitrile pyrrole demodicid mite ester of plant resistance problems can be solved.
The present invention is achieved by the following technical programs:
A kind of Pesticidal combination containing afidopyropen and nitrile pyrrole demodicid mite ester, it is characterised in that including the first active component(A) Afidopyropen, the second active component nitrile pyrrole demodicid mite ester(B), active components A is 1 with active component B preferred weight ratios:20~ 20:1, more preferably 1:10~10:1;The accumulation of the first active component and the second active component in the Pesticidal combination of the present invention Amount(Weight add and)For said composition gross weight 5%~85%.
The Pesticidal combination is re-dubbed the dosage form that allow on pesticide with known auxiliary agent and excipient:It can for example be breast Oil, wettable powder, water dispersible granules, suspending agent, aqueous emulsion, suspension emulsion, microemulsion, dispersible oil-suspending agent, microcapsule suspension In agent, solvable powder any one.
In the Pesticidal combination of the present invention, two kinds of effective ingredient show obvious potentiation, to red spider prevention effect Significantly, excellent quick-acting and lasting effect is shown, the shortcoming of each single dose is overcome.
Compared with prior art, the present invention has following beneficial effect:(1)Compared with single dose, the combination to citrus red mite, The potentiation of the insect such as tetranychid substantially, overcomes and has delayed Drug resistance, expands preventing and treating spectrum, improves prevention effect;(2)Reduce Preventing and treating recruitment, drug cost;(3)Alternative conventional medicine and the easily pesticide of generation resistance;(4)Compared with single dose, two kinds of single doses Combination can reduce should cost.
Specific embodiment
In order that the objects, technical solutions and advantages of the present invention become more apparent, present invention specific examples below Illustrate, but the present invention is limited to absolutely not these examples.Described below is only the present invention preferably embodiment, is used only for explaining The present invention, but can not be therefore understands that being the restriction to the scope of the claims of the present invention.It should be pointed out that all the present invention spirit and Any modification, equivalent or improvement for being made within principle etc., should be included within the scope of the present invention, therefore, The protection domain of patent of the present invention should be defined by claims.
First, example of formulations
1st, embodiment 1:84%afidopyropen nitrile pyrrole demodicid mite ester wettable powders
afidopyropen 80%
Nitrile pyrrole demodicid mite ester 4%
Alkylnaphthalene sulfonate 2%
Citric acid 1%
Sodium lignin sulfonate polishing is to 100 %
The concrete procedure of processing of said composition wettable powder is:By above-mentioned formula by afidopyropen, nitrile pyrrole demodicid mite ester and The mixing of dispersant, wetting agent and filler, uniform stirring in stirred tank, mix homogeneously after comminution by gas stream, you can this is obtained The bright described wettable powder containing afidopyropen and nitrile pyrrole demodicid mite ester.
2nd, embodiment 2:44%afidopyropen nitrile pyrrole demodicid mite ester suspending agents
afidopyropen 40%
Nitrile pyrrole demodicid mite ester 4%
Fatty alcohol-polyoxyethylene ether 1.5%
EO-PO block polyethers 1.5%
Alkylnaphthalene sulfonate 4%
Xanthan gum 0.1%
Citric acid 0.5%
Carbamide 4%
Defoamer 0.1%
Water polishing is to 100%
The concrete procedure of processing of said composition suspending agent is:By in above-mentioned formula by water and wetting agent, dispersant, thickening agent, anti- Freeze agent and defoamer mixing, through high speed shear mix homogeneously, add afidopyropen, nitrile pyrrole demodicid mite ester, continue shearing and mix, Subsequently in horizontal sand mill grind, make preparation particle diameter all in below 5UM, be obtained of the present invention containing Afidopyropen and the suspending agent of nitrile pyrrole demodicid mite ester.
3rd, embodiment 3:6%afidopyropen nitrile pyrrole demodicid mite ester microemulsions
afidopyropen 5%
Nitrile pyrrole demodicid mite ester 1%
N-Methyl pyrrolidone 5%
Ketohexamethylene 8%
Calcium dodecyl benzene sulfonate 5%
Styryl phenol polyethenoxy ether 10%
Water polishing is to 100%
The concrete procedure of processing of said composition microemulsion is:Above-mentioned formula is pressed by afidopyropen, nitrile pyrrole demodicid mite ester N- methyl After ketopyrrolidine and Ketohexamethylene are completely dissolved, other auxiliary agent mix homogeneously are added, water is eventually adding and is sufficiently stirred for.Can be prepared by this The described microemulsion containing afidopyropen and nitrile pyrrole demodicid mite ester of invention.
4th, embodiment 4:30%afidopyropen nitrile pyrrole demodicid mite ester suspending agents
afidopyropen 15%
Nitrile pyrrole demodicid mite ester 15%
Aliphatic alcohol polyethenoxy phosphate ester 1%
Alkylnaphthalene sulfonate 4%
Citric acid 0.2%
Xanthan gum 0.1%
Propylene Glycol 4%
Defoamer 0.1%
Water polishing is to 100%
The concrete procedure of processing of said composition suspending agent is:By in above-mentioned formula by water and wetting agent, dispersant, thickening agent, anti- Freeze agent and defoamer mixing, through high speed shear mix homogeneously, add afidopyropen, nitrile pyrrole demodicid mite ester, continue shearing and mix, Subsequently in horizontal sand mill grind, make preparation particle diameter all in below 5UM, be obtained of the present invention containing Afidopyropen, the suspending agent of nitrile pyrrole demodicid mite ester.
5th, embodiment 5:18%afidopyropen nitrile pyrrole demodicid mite emulsifiable concentrates
afidopyropen 8%
Nitrile pyrrole demodicid mite ester 10%
N-Methyl pyrrolidone 20%
Calcium dodecyl benzene sulfonate 4%
Styryl phenol polyoxyethylene polyoxypropylene ether 7%
Sec-butyl acetate polishing is to 100%
The concrete procedure of processing of said composition cream is:Above-mentioned formula is pressed by afidopyropen, nitrile pyrrole demodicid mite ester N methylpyrroles Alkanone, sec-butyl acetate fully dissolve, and add other auxiliary agents to stir, you can be obtained of the present invention containing Afidopyropen and the cream of nitrile pyrrole demodicid mite ester.
6th, embodiment 6:30%afidopyropen nitrile pyrrole demodicid mite ester suspension emulsions
afidopyropen 5%
Nitrile pyrrole demodicid mite ester 25%
Fatty acid methyl ester 15%
Fatty alcohol-polyoxyethylene ether 2%
EO-PO block polyethers 2%
Alkyl phenol alcohol ether phosphate 4%
Xanthan gum 0.1%
Propylene Glycol 4%
Defoamer 0.1%
Water polishing is to 100%
The concrete procedure of processing of said composition suspension emulsion is:Afidopyropen and fatty acid methyl ester are mixed by above-mentioned formula Stirring, adds the mixing of alkyl phenol alcohol ether phosphate, adds suitable water under stirring condition after dissolving completely, open when closing on phase inversion point Cutter, disperses at a high speed afidopyropen EW parts are obtained;By in above-mentioned formula by wetting agent, dispersant, antifreezing agent, disappear Infusion, suitable water mixing and stirring, add nitrile pyrrole demodicid mite ester, continue shearing and mix, grind subsequently in horizontal sand mill, make Particle diameter is all obtained SC parts in below 5um, and proceeds to above-mentioned afidopyropen EW parts, and shearing is mixed, and the present invention is obtained The described suspension emulsion containing afidopyropen and nitrile pyrrole demodicid mite ester.
7th, embodiment 7:22%afidopyropen nitrile pyrrole demodicid mite esters dispersible oil-suspending agent
afidopyropen 2%
Nitrile pyrrole demodicid mite ester 20%
Alkylphenol polyoxyethylene 5%
Polyoxyethylene hydrogenated Oleum Ricini 20%
Organobentonite 1%
Mineral oil polishing is to 100%
Said composition dispersibles the concrete procedure of processing of oil-suspending agent:Above-mentioned formula is pressed by mineral oil, afidopyropen, nitrile Pyrrole demodicid mite ester, dispersant, thickening agent, emulsifying agent mixing, through high speed shear mix homogeneously, grind subsequently in horizontal sand mill, Make preparation particle diameter all in below 10um, be obtained and of the present invention dispersible oil containing afidopyropen and nitrile pyrrole demodicid mite ester Suspending agent.
8th, embodiment 8:63%afidopyropen nitrile pyrrole demodicid mite ester water dispersible granules
afidopyropen 3%
Nitrile pyrrole demodicid mite ester 60%
Alkylbenzenesulfonate 3%
Sodium methylene bis-naphthalene sulfonate 6%
Polyvinyl alcohol 2%
White carbon polishing is to 100%
The concrete procedure of processing of said composition water dispersible granules is:And divide afidopyropen, nitrile pyrrole demodicid mite ester by above-mentioned formula Powder, wetting agent, disintegrating agent and filler mix homogeneously, are crushed with micro jet, through mediating, are made subsequently into extruding Grain machine pelletize, dries in boiling drier, through sample analysis after screening, be obtained of the present invention containing afidopyropen and The water dispersible granules of nitrile pyrrole demodicid mite ester.
2nd, bioassay example
For afidopyropen being understood with nitrile pyrrole demodicid mite ester with definite virulence of the compositionss to citrus red mite, first pass through indoor virulence Determine and its proportioning screened, clear and definite two kinds of medicaments compound by a certain percentage after co-toxicity coefficient(CTC), CTC < 80 For antagonism, 80≤CTC≤120 are summation action, and CTC > 120 are potentiation.
Concrete test method:The mother solution of each mixed agent is diluted to five series concentrations respectively, is respectively placed in standby in beaker With.Using the method that first leaching leaf is followed by worm, the blade of the same size not in contact with any medicament is put in the medicinal liquid for having configured Immersion 5s, dries after taking-up naturally, is put in insect box, then connects for examination nymph, raises under the conditions of 26 DEG C, each process Be repeated 3 times, repeat test worm number used every time for 50, while setting blank, after 72h, check dead borer population, calculate mortality rate and Corrected mortality, tries to achieve virulence regression equation and calculates LC50Value.If control mortality rate is considered as invalid test more than 10%.Meter Calculate formula as follows:
Mortality rate(%)=(Borer population living after borer population-medicine living before medicine)Borer population × 100 living before/medicine
Corrected mortality(%)=(Treatment group mortality rate-matched group mortality rate)/(1- matched group mortality rates)×100
Insect corrected mortality is converted into probit value(y), concentration for the treatment of(μg/ml)It is converted into logarithm value(x), with least square Method draws virulence regression equation, and thus calculates the LC of every kind of medicament50Value.Co-toxicity coefficient is calculated according to the abundant equations of Sun Yun CTC.Computing formula is as follows(With afidopyropen as standard agent, its toxicity index is 100):
The toxicity index of nitrile pyrrole demodicid mite ester(TI)The LC of=afidopyropen50The LC of/nitrile pyrrole demodicid mite ester50×100
The actual toxicity index of M(ATI)The LC of=afidopyropen50The LC of/M50×100
The theoretical toxicity index of M(TTI)TI × the P of=afidopyropenafidopyropenTI × the P of+nitrile pyrrole demodicid mite esterNitrile pyrrole demodicid mite ester
Co-toxicity coefficient(CTC)TTI × 100 of the ATI M of=M
In formula:M is the mixture of afidopyropen and nitrile pyrrole demodicid mite ester different ratio
PNitrile pyrrole demodicid mite esterFor the shared ratio in mixture of nitrile pyrrole demodicid mite ester
PafidopyropenFor the shared ratios in mixture of afidopyropen
For trying insect:Red spider
Experiment reagent is provided by Foshan Brightmart Crop Science Co., Ltd..EXPERIMENTAL DESIGN:Determine through pilot study Afidopyropen and nitrile pyrrole demodicid mite ester active compound and effective lethasl concentration scope of the two different ratio mixture.Result of the test is as follows Table:
As shown in Table 1, the Toxicity Determination of afidopyropen and nitrile pyrrole demodicid mite ester compounding to red spider, co-toxicity coefficient are big There is preferable synergistic function in 120, the i.e. present composition, its effect is better than single dose.When afidopyropen with The proportioning of nitrile pyrrole demodicid mite ester is 5:1~1:In the range of 5, potentiation is optimal, and potentiation is the most obvious.
2nd, field control effectiveness test
Experiment process:This experiment separately designs two dosings according to the difference of each composition, and dosing is effective ingredient The quality of afidopyropen and nitrile pyrrole demodicid mite ester and.Comparison medicament is that 20%afidopyropen suspending agents and 30% nitrile pyrrole demodicid mite ester are outstanding Floating agent and blank clean water experiment.
Test method:Each plot area is 66.7m2, it is repeated 3 times;Investigation drug effect side after investigating and prevent and treat before dispenser Method is, 5 points of randomization in the test process area, carries out severity Scaling according to national field test relevant criterion, calculates preventive effect. Result of the test such as following table:
From table 2, field control effectiveness test result shows, can effectively prevent and treat Citrus chachiensis Hort. after afidopyropen and nitrile pyrrole demodicid mite ester compounding Fructus Citri tangerinae insect, the compositionss of the present invention have obvious synergistic function, and prevention effect is better than single dose, and preventive effect phase is long;Real It is 4 with nitrile pyrrole demodicid mite ester proportioning to apply afidopyropen in example 5:When 5, preventive effect can reach more than 90%, and preventive effect is optimal;In examination Test and Citrus are had no adverse effects in scope of medication, be worth popularization and application in agricultural production.

Claims (7)

1. a kind of Pesticidal combination, it is characterised in that active component includes afidopyropen and nitrile pyrrole demodicid mite ester.
2. Pesticidal combination according to claim 1, it is characterised in that the weight of the afidopyropen and nitrile pyrrole demodicid mite ester Amount is than being 1:20~20:1.
3. described Pesticidal combination is required according to any one of claim 1~2, it is characterised in that described Afidopyropen and the weight ratio preferably 1 of nitrile pyrrole demodicid mite ester:10~10:1.
4. described Pesticidal combination is required according to any one of claims 1 to 3, it is characterised in that the Pesticidal combination It is aided with insecticidal preparation processing auxiliary element and is processed into any one dosage form for being suitable for agriculturally using.
5. Pesticidal combination according to claim 4, it is characterised in that the dosage form of the Pesticidal combination is wettable powder Agent, suspending agent, aqueous emulsion, microemulsion, cream, suspension emulsion, microcapsule suspending agent, water dispersible granules, solvable powder, in soluble granule Any one.
6. Pesticidal combination according to any one of Claims 1 to 5 claim is used for the use for preventing and kill off crop pests On the way.
7. purposes according to claim 6, it is characterised in that the crop pests are preferably citrus red mite, Cinnabaris Tetranychid.
CN201610918187.2A 2016-10-21 2016-10-21 Pesticidal combination containing afidopyropen and nitrile pyrrole demodicid mite ester Pending CN106489952A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109691451A (en) * 2017-10-24 2019-04-30 沈阳中化农药化工研发有限公司 A kind of Insecticiding-miticiding synergistic composition of the mite of azoles containing second nitrile and its application
CN109744242A (en) * 2017-11-06 2019-05-14 佛山市盈辉作物科学有限公司 A kind of Pesticidal combination of fluorine-containing worm pyrrole quinoline and nitrile pyrrole mite ester
CN109845742A (en) * 2017-11-30 2019-06-07 佛山市盈辉作物科学有限公司 A kind of Pesticidal combination containing afidopyropen and spirodiclofen

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102905528A (en) * 2010-05-28 2013-01-30 巴斯夫欧洲公司 Pesticidal mixtures

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102905528A (en) * 2010-05-28 2013-01-30 巴斯夫欧洲公司 Pesticidal mixtures

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109691451A (en) * 2017-10-24 2019-04-30 沈阳中化农药化工研发有限公司 A kind of Insecticiding-miticiding synergistic composition of the mite of azoles containing second nitrile and its application
CN109691451B (en) * 2017-10-24 2021-03-05 沈阳中化农药化工研发有限公司 Insecticidal and acaricidal synergistic composition containing ethacrylonitrile and application thereof
CN109744242A (en) * 2017-11-06 2019-05-14 佛山市盈辉作物科学有限公司 A kind of Pesticidal combination of fluorine-containing worm pyrrole quinoline and nitrile pyrrole mite ester
CN109845742A (en) * 2017-11-30 2019-06-07 佛山市盈辉作物科学有限公司 A kind of Pesticidal combination containing afidopyropen and spirodiclofen

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