CN103891749A - Insecticidal combination containing sulfoxaflore and metaflumizone - Google Patents
Insecticidal combination containing sulfoxaflore and metaflumizone Download PDFInfo
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- CN103891749A CN103891749A CN201410162780.XA CN201410162780A CN103891749A CN 103891749 A CN103891749 A CN 103891749A CN 201410162780 A CN201410162780 A CN 201410162780A CN 103891749 A CN103891749 A CN 103891749A
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- metaflumizone
- worm amine
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Abstract
The invention discloses an insecticidal combination containing sulfoxaflore and metaflumizone and an application thereof. Effective active ingredients of the insecticidal combination comprise a first active ingredient, namely the sulfoxaflore, and a second active ingredient, namely the metaflumizone, wherein the weight ratio of the first active ingredient to the second active ingredient is 1:9-9: 1, and the preferable weight ratio is 1: 5-5: 1. The insecticidal combination can be prepared into suspending agents, wettable powder, water dispersible granules or dispersible suspending agents which are agriculturally allowable. The insecticidal combination is reasonable in ingredients and has a good insecticidal effect; and the activity and insecticidal effect of the insecticidal combination are not the simple superposition of the activity of the ingredients. Compared with a conventional single-component preparation, the insecticidal combination containing the sulfoxaflore and the metaflumizone has an obvious insecticidal effect, an obvious synergistic effect, good safety for crops and an obvious control effect on rice planthoppers and rice leaf rollers and meets the safety requirements of pesticide preparations.
Description
Technical field
The present invention relates to a kind of Pesticidal combination, formed by the first active component fluorine pyridine worm amine nitrile and the second active component metaflumizone, belong to technical field of compounded pesticide.
Background technology
Fluorine pyridine worm amine nitrile, English common name: sulfoxaflor, chemical name: [1-[6-(trifluoromethyl) pyridin-3-yl] ethyl] methyl (oxygen)-λ 4-sulfydryl cyanamide.Fluorine pyridine worm amine nitrile is sulfimide insecticide, acts on binding site unique in insect choline receptor and brings into play insecticidal function.Can be through leaf, stem, root absorption and enter in plant corpus.Be applicable to prevent and treat crop aphid, fleahopper, aleyrodid, plant hopper, scale insect etc.As a kind of new insecticide, in use there is resistance risk in fluorine pyridine worm amine nitrile, and rationally mixed from the insecticide of the different mechanisms of action, for fully effectively promoting fluorine pyridine worm amine nitrile, extends its service life and have important function.
Metaflumizone, English common name: metaflumizone, chemical name: (E+Z)-[2-(4-cyano group benzene)-1-[3-(trifluoromethyl) benzene] ethylidene]-N-[4-(trifluoromethyl) benzene]-hydrazine carbonyl oxamides.Metaflumizone is a kind of insecticide of brand-new mechanism of action, by being attached on the acceptor of sodium-ion channel, hinders sodium ion current, it is mainly stomach poison function, there is certain action of contace poison, Lepidoptera and coleopteran pest are had to obvious control efficiency, to mammal and non-target organism low-risk.
Rice fulgorid, rice leaf roller are the important pests in Rice Production, two kinds of insects often mix and occur simultaneously, on classification of insect, rice fulgorid belongs to Homoptera, rice leaf roller belongs to Lepidoptera, in control, the selection of agricultural chemicals is had to larger difference, must use and just can receive desirable control efficiency by two kinds of mixed pesticides while sending out two kinds of insects are mixed, but in practical application, agricultural chemicals user often causes preventive effect to reduce, even occurs poisoning because mixture is improper, therefore be badly in need of that a kind of pesticide mixed preparation of invention is can be simultaneously double controls rice fulgorid and rice leaf roller.
As a kind of anabasine insecticide, fluorine pyridine worm amine nitrile is good to rice fulgorid preventive effect, general to rice leaf roller preventive effect, exists the risk that resistance risk increases gradually; Metaflumizone is effective to lepidoptera pest, has used for many years, and resistance development is very fast.Inventor surprisingly finds fluorine pyridine worm amine the nitriles different mechanism of action and metaflumizone mixture to use, and has significant synergies, and can doublely control rice fulgorid and rice leaf roller, reduces use cost, slows down the effect of the generation of pest resistance.
Summary of the invention
The object of the present invention is to provide a kind of component reasonable, significantly synergy, good disinsection effect and double controlling, the fluorine pyridine worm amine nitrile that drug cost is low and the Pesticidal combination of metaflumizone.
Another object of the present invention is to provide the Pesticidal combination preparation formulation of fluorine-containing pyridine worm amine nitrile and metaflumizone.
A further object of the present invention is the application of the Pesticidal combination that fluorine pyridine worm amine nitrile and metaflumizone are provided.
In order to overcome the defect of existing unitary agent, technical scheme of the present invention is to solve like this:
The Pesticidal combination of fluorine-containing pyridine worm amine nitrile and metaflumizone, comprising:
A) the first active component fluorine pyridine worm amine nitrile;
B) the second active component metaflumizone;
The weight ratio of the first active component and the second active component is 1:9～9:1, is preferably 1:5～5:1.
The content sum of the first active component and the second active component is described composition total weight 10%～70%, is preferably 15%～60%.
The Pesticidal combination of fluorine pyridine worm amine nitrile of the present invention and metaflumizone, the preparation formulation that can prepare according to the known method of the art personnel is suspending agent, wetting powder, water dispersible granules or dispersibles oil-suspending agent.
To suspending agent, spendable auxiliary agent has: dispersant is produced as polycarboxylate, lignosulfonates, alkylnaphthalene sulfonate, the HUNTSMAN of Huntsman Corporation of the TERSPERSE 2020(U.S., alkyl naphthalene sulfonic acid salt) in one or more; Emulsifier is as Nongru-700 #(common name: alkyl phenol formaldehyde resin polyoxyethylene ether), this dish-60#(common name: sorbitan monostearate), Tween-60 #(common name: sorbitan monostearate APEO), agriculture breast 1601#(common name: phenethyl phenol polyoxyethylene poly-oxygen propylene aether), Huntsman Corporation of the TERSPERSE 4894(U.S. produces) in one or more; Wetting agent is produced as alkylphenol-polyethenoxy base ether formaldehyde condensation products sulphate, alkylphenol-polyethenoxy base ether phosphate, phenethyl phenol polyethenoxy base ether phosphate, alkyl sulfate, alkylsulfonate, naphthalene sulfonate, Huntsman Corporation of the TERSPERSE 2500(U.S.) in one or more; Thickener as in xanthans, polyvinyl alcohol, bentonite, aluminium-magnesium silicate one or more; Preservative as in formaldehyde, benzoic acid, Sodium Benzoate one or more; Defoamer is as organic silicon defoamer; Antifreezing agent as ethylene glycol, propane diols, glycerine, urea, inorganic salts as in sodium chloride one or more.
To wetting powder, spendable auxiliary agent has: dispersant as in polycarboxylate (TERSPERSE 2700, T36, GY-D06 etc.), lignosulfonates, alkylnaphthalene sulfonate one or more; Wetting agent as in alkyl sulfate, alkylsulfonate, naphthalene sulfonate one or more; Filler as ammonium sulfate, urea, sucrose, glucose, diatomite, kaolin, white carbon, precipitated calcium carbonate, imvite, talcum powder, attapulgite, potter's clay sodium sulphate, sodium polyphosphate one or more.
For water dispersible granules, those skilled in the art are familiar with the corresponding auxiliary agent of use and complete the present invention very much.Dispersant as in polycarboxylate (TERSPERSE 2700, T36, GY-D06 etc.), lignosulfonates, alkylnaphthalene sulfonate one or more; Wetting agent as in alkyl sulfate, alkylsulfonate, naphthalene sulfonate one or more; Disintegrant as in ammonium sulfate, sodium sulphate, polyvinylpyrrolidone, starch and derivative thereof, bentonite one or more; Binding agent is as one or more in starch, glucose, polyvinyl alcohol, polyethylene glycol, sodium carboxymethylcellulose, sucrose; Filler as diatomite, kaolin, white carbon, fine particle calcium carbonate, talcum powder, attapulgite, potter's clay one or more.
To dispersibling oil-suspending agent, spendable auxiliary agent has: dispersant is produced as polycarboxylate, lignosulfonates, alkylnaphthalene sulfonate (dispersing agent NNO), the HUNTSMAN of Huntsman Corporation of the TERSPERSE 2020(U.S., alkyl naphthalene sulfonic acid salt) in one or more, emulsifier is as BY(castor oil polyoxyethylene ether) serial emulsifier (BY-110, BY-125, BY-140), Nongru-700 #(common name: alkyl phenol formaldehyde resin polyoxyethylene ether), agriculture breast 2201, this dish-60#(common name: sorbitan monostearate), Tween-60 #(common name: sorbitan monostearate APEO), agriculture breast 1601#(common name: phenethyl phenol polyoxyethylene poly-oxygen propylene aether), Huntsman Corporation of the TERSPERSE 4894(U.S. produce) in one or more, wetting agent is produced as alkylphenol-polyethenoxy base ether formaldehyde condensation products sulphate, alkylphenol polyoxyethylene phosphate, phenethyl phenol polyethenoxy base ether phosphate, alkyl sulfate, alkylsulfonate, naphthalene sulfonate, Huntsman Corporation of the TERSPERSE 2500(U.S.) in one or more, thickener as in white carbon, polyvinyl alcohol, bentonite, aluminium-magnesium silicate one or more, antifreezing agent as in ethylene glycol, propane diols, glycerine, urea, inorganic salts one or more, dispersion medium as in soybean oil, rapeseed oil, corn oil, peanut oil, palm oil, methyl oleate one or more.
Component of the present invention is reasonable, good disinsection effect, and drug cost is low, and its active and insecticidal effect is not the simple superposition of each composition activity, but has significant synergistic effect, good to crop safety, meets the security requirement of pesticidal preparations.The present invention has higher insecticidal activity to rice fulgorid, rice leaf roller etc.
Embodiment
In order to prevent and treat water rice hopper, we have carried out mutual composite synergy research with fluorine pyridine worm amine nitrile and metaflumizone.It is tested object that test adopts Brown Planthopper, and concrete grammar is:
Brown plant-hopper formal name used at school Nilaparvata lugens, Homoptera, Delphacidae.Former medicine is mixed with to the test medicine needing, test method is with reference to " People's Republic of China's agricultural industry criteria NY/T1154.7-2006 ".First single dose and each Mixed Pharmacy are arranged to 5 variable concentrations gradients (on the basis of preliminary experiment result, brown plant-hopper lethality is set by geometric progression in 5%～90% scope).Examination worm be the brown planthopper ovum that picks up from field, in greenhouse, raised for 3 generations with rice seedlings, select uniformity 3 age nymph, the culture dish of rice seedling diameter 12cm is put in access, every ware connects and anaesthetizes 30 of nymphs, and every processing connects 4 culture dishes, sprays with potter spray tower under 50PSI pressure, a ware of each spray, every ware spraying liquid 3ml, after insect revives, puts into 12H/12H illumination box by the culture dish of processing and cultivates, within 72 hours, check dead borer population, calculate lethality.Blank spray equivalent clear water.By the linear regression analysis between the probit value of lethality and the logarithm value of series concentration, obtain the LC of each medicament
50value, with the co-toxicity coefficient (CTC) of the abundant method calculating of Sun Yun mixture, evaluates the activity of reagent agent to examination worm with this.
The co-toxicity coefficient (CTC) >=120 of complex preparation shows as synergistic effect; CTC≤80 show as antagonism; 80 < CTC < 120 show as summation action.
Toxicity Determination result shows: fluorine pyridine worm amine nitrile has good virulence as 1:9～9:1 is mixed to brown plant-hopper take weight ratio with metaflumizone, all has significant synergistic effect, especially take weight ratio as 1:5～5:1 synergy the most remarkable.
In order to prevent and treat the paddy rice rice leaf roller in agricultural production, inventor has carried out mutual composite synergy research with fluorine pyridine worm amine nitrile and metaflumizone.Concrete grammar is:
Subjects: rice leaf roller formal name used at school Cnaphalocrocis medinalis Guenee, the vertical volume of another name snout moth's larva, tortrix moth, Lepidoptera, Pyralidae.Former medicine is mixed with to the test medicine needing, test method is with reference to " the agricultural industry criteria NY/T1154.2-2006 of the People's Republic of China (PRC) ".First single dose and each Mixed Pharmacy are arranged to 5 variable concentrations gradients (on the basis of preliminary experiment result, rice leaf roller lethality is set by geometric progression in 5%～90% scope).Examination worm is the rice leaf roller larvae that field gathers, select the larva of uniformity in the length of time in laboratory, hungry 4～8 hours, beat and get leaf dish with the card punch of 1 centimetre of diameter, put into culture dish, and note moisturizing. with capillary dropper from low concentration, every leaf dish point 1 μ L～2 μ L liquid that drips, after solvent evaporates, scribble the involutory malicious leaf dish of folder of making of leaf dish of gelatinized corn starch with another sheet, make in the complete hole that is put in 12 hole tissue culturing plates.Every processing 4 times repeats, and often repeats to be no less than 12 malicious leaf dish of folder, and establishes not containing the processing of the corresponding organic solvent of medicament in contrast.In the each hole of tissue culturing plate, connect 1 examination worm, be placed under normal condition and cultivate.Connect worm after 2～4 hours, taken food after pastille leaf dish wait trying worm, in cultivation plate hole, add clean feed to continue to raise to investigating, eliminate the examination worm that has not eaten an intact leaves dish, within 24 hours, check dead borer population, calculate lethality.By the linear regression analysis between the probit value of lethality and the logarithm value of series concentration, obtain the LC of each medicament
50value, with the co-toxicity coefficient (CTC) of the abundant method calculating of Sun Yun mixture, evaluates the activity of reagent agent to examination worm with this.
The co-toxicity coefficient (CTC) >=120 of complex preparation shows as synergistic effect; CTC≤80 show as antagonism; 80 < CTC < 120 show as summation action.
Toxicity Determination result shows: fluorine pyridine worm amine nitrile has good virulence as 1:9～9:1 is mixed to rice leaf roller take weight ratio with metaflumizone, all has significant synergistic effect, especially take weight ratio as 1:5～5:1 synergy the most remarkable.
Below in conjunction with embodiment, the invention will be further described.
FORMULATION EXAMPLE 1
Taking 3% fluorine pyridine worm amine nitrile, 27% metaflumizone, 3% Tween-60 #, Huntsman Corporation of the 1%TERSPERSE 2500(U.S. produces), 0.3% xanthans, 5% propane diols, 0.5% benzoic acid, 0.5% silicone defoaming agent (trade name: s-29, Nanjing "four news" (new ideas applied chemistry product company produces), deionized water add to 100% weight portion.Above-mentioned raw materials is through mixing, and high speed shear is disperseed 30min, with making 30% fluorine pyridine worm amine nitrile metaflumizone suspending agent after sand mill sand milling.
FORMULATION EXAMPLE 2
Taking 20% fluorine pyridine worm amine nitrile, 20% metaflumizone, Huntsman Corporation of the 4%TERSPERSE 4894(U.S. produces), 1.5% alkylphenol-polyethenoxy base ether phosphate, Huntsman Corporation of the 1%TERSPERSE 2020(U.S. produce), 0.2% aluminium-magnesium silicate, 5% ethylene glycol, 0.5% formaldehyde, 0.5% silicone defoaming agent (trade name: s-29 Nanjing "four news" (new ideas applied chemistry product company produces), deionized water add to 100% weight portion.Above-mentioned raw materials is through mixing, and high speed shear is disperseed 30min, with making 40% fluorine pyridine worm amine nitrile metaflumizone suspending agent after sand mill sand milling.
FORMULATION EXAMPLE 3
Take 36% fluorine pyridine worm amine nitrile, 4% metaflumizone, 4%GY-D06,3% alkylnaphthalene sulfonate formaldehyde condensation products (dispersing agent NNO), 1% lauryl sodium sulfate, 3% white carbon, 3% sodium polyphosphate, kaolin and fill up the weight portion to 100%.Above-mentioned raw materials is prepared into 40% fluorine pyridine worm amine nitrile metaflumizone wetting powder through mixing, ultra micro air-flow crushing, hybrid technique step.
FORMULATION EXAMPLE 4
Take 30% fluorine pyridine worm amine nitrile, 15% metaflumizone, 4% calcium lignosulfonate, 4% T36,1.5% lauryl sodium sulfate, 5% potter's clay sodium sulphate, fine particle calcium carbonate and fill up the weight portion to 100%.Above-mentioned raw materials is prepared into 45% fluorine pyridine worm amine nitrile metaflumizone wetting powder through mixing, ultra micro air-flow crushing, hybrid technique step.
FORMULATION EXAMPLE 5
Take 50% fluorine pyridine worm amine nitrile, 20% metaflumizone, 2%TERSPERSE 2700(polycarboxylate, Huntsman Corporation of the U.S. produces), 2% sodium lignin sulfonate, 1% Nekal BX (nekal), 1%K-12(lauryl sodium sulfate), 1%PVA(molecular weight 2000), 2% polyvinylpyrrolidone, kaolin add to 100% weight portion.The method of the frequent regulation of above-mentioned raw materials water intaking dispersible granule mixes, ultra micro air-flow crushing, mixing, granulation step are produced 70% fluorine pyridine worm amine nitrile metaflumizone water dispersible granules.
FORMULATION EXAMPLE 6
Take 10% fluorine pyridine worm amine nitrile, 20% metaflumizone, 4% GY-D06(polycarboxylate), 3% dispersing agent NNO (alkylnaphthalene sulfonate formaldehyde condensation products), 2% Nekal BX (nekal), 2%K-12(lauryl sodium sulfate), 5% diatomite, 8% bentonite, attapulgite adds to 100% weight portion.The method of the frequent regulation of above-mentioned raw materials water intaking dispersible granule mixes, ultra micro air-flow crushing, mixing, granulation step are produced 30% fluorine pyridine worm amine nitrile metaflumizone water dispersible granules.
FORMULATION EXAMPLE 7
Taking 30% fluorine pyridine worm amine nitrile, 10% metaflumizone, Huntsman Corporation of the 2%TERSPERSE 2020(U.S. produces), 4% this dish-60#, 3% BY-125,4% agriculture breast 2201#, 3% Nongru-700 #, Huntsman Corporation of 2%TERSPERSE 2500(U.S. product), 0.5% white carbon, 5% propane diols, methyl oleate add to 100% weight portion.Above-mentioned raw materials is through mixing, and high speed shear is disperseed 30min, dispersibles oil-suspending agent with making 40% fluorine pyridine worm amine nitrile metaflumizone after sand mill sand milling.
FORMULATION EXAMPLE 8
Take 6% fluorine pyridine worm amine nitrile, 4% metaflumizone, 2% dispersing agent NNO, 3% agriculture breast 2201#, 10% BY-110, Huntsman Corporation of the 1%TERSPERSE 2500(U.S. produces), 1% aluminium-magnesium silicate, 3% glycerine, soybean oil add to 100% weight portion.Above-mentioned raw materials is through mixing, and high speed shear is disperseed 30min, dispersibles oil-suspending agent with making 10% fluorine pyridine worm amine nitrile metaflumizone after sand mill sand milling.
Biological Examples 1: control paddy rice rice leaf roller, rice fulgorid field trial
Inventor has carried out formulation examples 2(40% fluorine pyridine worm amine nitrile metaflumizone suspending agent on April 10th, 2013 at Beihai, Guangxi Hepu County) control paddy rice rice leaf roller, rice fulgorid field control effectiveness test, trial crops is paddy rice, controlling object rice leaf roller (Cnaphalocrocis medinalis), brown planthopper (Nilaparvata lugens).Test medicine and extension rate refer to table 3.The cultivation condition of each community, water and fertilizer management uniformity.With amount of liquid medicine be 45kg/667 ㎡, adopt manual sprayer evenly spray, require each community rice leaf positive and negative even medicine.Separately establish blank, every processing repeats for 4 times, every community area 30 ㎡, and Gong24Ge community, random district group is arranged.Investigation radix before medicine, after medicine, 1,7,14 day investigation preventive effect is observed paddy growth situation simultaneously, and visual test medicament has or not poisoning to produce to paddy rice.
Investigation statistics method
Rice leaf roller:
Take parallel great-jump-forward random sampling, 25 clumps of rice are looked in the sampling of 5 of every communities altogether, and statistics leaf roll rate, with check plot leaf roll rate comparison, calculates relative control effect.
The total number of sheets × 100 of leaf roll rate (%)=investigation leaf roll number/investigate
Leaf roll rate × 100 after control efficiency (%)=(after blank district medicine after leaf roll rate-chemicals treatment district medicine leaf roll rate)/blank district medicine
Rice fulgorid:
Take the random sampling of balance-jump formula, every community 10 points, 2 clumps every (totally 20 clumps), record rice fulgorid borer population by basin bat method, by the borer population calculation correction preventive effect before every clump of medicine, after medicine.
control efficiency (%)=[1-(borer population after the front borer population × treatment region medicine of check plot medicine)/(the front borer population of borer population × treatment region medicine after the medicine of check plot)] × 100
Result of the test shows, 40% 4000 times, 4500 times, 5000 times of fluorine pyridine worm amine nitrile metaflumizone suspending agents have significant control efficiency to paddy rice rice leaf roller, brown planthopper, after medicine, the preventive effect of 1,7,14 day, all more than 80%, is obviously better than the control efficiency (table 3) of 20% 3000 times of fluorine pyridine worm amine nitrile suspending agents, 1000 times of 20% metaflumizone suspending agents.
Security survey, duration of test is observed, and all reagent agents, to paddy growth safety, occur without poisoning phenomenon.
Result of the test shows, after fluorine pyridine worm amine nitrile and metaflumizone mixture, control efficiency and lasting period to rice leaf roller, rice fulgorid are obviously improved, in the time that these two kinds of insects occur simultaneously, a dispenser reaches double and controls, reduce dosage, reduced medication number of times and drug cost, to paddy growth safety.
In sum, composition of the present invention is to adopt two kinds of active component compound schemes, its activity and insecticidal effect are not the simple superposition of each composition activity, compared with existing unitary agent, except having significant insecticidal effect, and have significant synergistic effect, and good to crop safety, meet the security requirement of pesticidal preparations.
Claims (6)
1. a Pesticidal combination for fluorine-containing pyridine worm amine nitrile and metaflumizone, is characterized in that: be made up of the first active component fluorine pyridine worm amine nitrile and the second active component metaflumizone, the weight ratio of the first active component and the second active component is 1:9～9:1.
2. the Pesticidal combination of fluorine-containing pyridine worm amine nitrile and metaflumizone according to claim 1, is characterized in that: the weight ratio of the first active component and the second active component is 1:5～5:1.
3. the Pesticidal combination of fluorine-containing pyridine worm amine nitrile and metaflumizone according to claim 1, is characterized in that, the content sum of the first active component and the second active component is described composition total weight 10%～70%.
4. the Pesticidal combination of fluorine-containing pyridine worm amine nitrile and metaflumizone according to claim 3, is characterized in that, the content sum of the first active component and the second active component is described composition total weight 15%～60%.
5. the Pesticidal combination of fluorine-containing pyridine worm amine nitrile and metaflumizone according to claim 1, is characterized in that described combination dosage form is suspending agent, wetting powder, water dispersible granules or dispersibles oil-suspending agent.
6. the purposes of the Pesticidal combination of fluorine-containing pyridine worm amine nitrile and metaflumizone on control rice fulgorid and rice leaf roller according to claim 1.
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105941454A (en) * | 2016-06-21 | 2016-09-21 | 南京华洲药业有限公司 | Synergistic insecticidal composition containing sulfoxaflor and metaflumizone and application thereof |
| CN106689177A (en) * | 2015-07-20 | 2017-05-24 | 江苏龙灯化学有限公司 | Insecticidal composition |
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| CN102014639A (en) * | 2008-05-07 | 2011-04-13 | 拜耳作物科学股份公司 | Synergistic active ingredient combinations |
| JP2011126837A (en) * | 2009-12-21 | 2011-06-30 | Nippon Nohyaku Co Ltd | Agricultural and horticultural pest-controlling agent composition, and method for applying them |
| WO2014019983A1 (en) * | 2012-07-31 | 2014-02-06 | Bayer Cropscience Ag | Compositions comprising a pesticidal terpene mixture and an insecticide |
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- 2014-04-22 CN CN201410162780.XA patent/CN103891749A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102014639A (en) * | 2008-05-07 | 2011-04-13 | 拜耳作物科学股份公司 | Synergistic active ingredient combinations |
| JP2011126837A (en) * | 2009-12-21 | 2011-06-30 | Nippon Nohyaku Co Ltd | Agricultural and horticultural pest-controlling agent composition, and method for applying them |
| WO2014019983A1 (en) * | 2012-07-31 | 2014-02-06 | Bayer Cropscience Ag | Compositions comprising a pesticidal terpene mixture and an insecticide |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106689177A (en) * | 2015-07-20 | 2017-05-24 | 江苏龙灯化学有限公司 | Insecticidal composition |
| CN105941454A (en) * | 2016-06-21 | 2016-09-21 | 南京华洲药业有限公司 | Synergistic insecticidal composition containing sulfoxaflor and metaflumizone and application thereof |
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Application publication date: 20140702 |