CN103283770B - Insecticidal composition containing cycolxylidin and metaflumizone - Google Patents
Insecticidal composition containing cycolxylidin and metaflumizone Download PDFInfo
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- CN103283770B CN103283770B CN201310254891.9A CN201310254891A CN103283770B CN 103283770 B CN103283770 B CN 103283770B CN 201310254891 A CN201310254891 A CN 201310254891A CN 103283770 B CN103283770 B CN 103283770B
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Abstract
The present invention discloses an insecticidal composition containing cycolxylidin and metaflumizone and applications thereof. The active ingredients of the insecticidal composition consists of a first active ingredient cycolxylidin and a second active ingredient metaflumizone, wherein the weight ratio of the first active ingredient to the second active ingredient is from 1:15 to 10:1, preferably from 1:10 to 5:1. The composition of the invention may be formulated as agriculturally permissible suspending agents, wettable powders, water dispersible granules or suspension emulsions. The insecticidal composition of the invention has reasonable ingredients, good insecticidal effects, and the activity and insecticidal effects are not simply addition of that of each active ingredient; compared with preparations having a single active ingredient, the insecticidal composition of the invention has significant insecticidal effects and significant synergies, is safe on crops, meets the safety requirements for pesticide preparations, and has a significant control effect on rice planthoppers and rice leaf rollers.
Description
Technical field
The present invention relates to a kind of Pesticidal combination, formed by the first active component epoxy insect quinoline and the second active component metaflumizone, belong to technical field of compounded pesticide.
Background technology
Epoxy insect quinoline is anabasine insecticide, is formulated chemical name by Wuhan Engineering Univ: 1-(2,3-glycidyl)-N-Nitroimidazoline-2-base amine, chemical molecular formula C
6h
10n
4o
3.Insect is had to interior suction, stomach toxicity and action of contace poison.As a kind of anabasine insecticide, in use there is resistance risk in epoxy insect quinoline, and rationally mixed with dissimilar insecticide, for fully effectively promoting epoxy insect quinoline, extends its service life and have important function.
Metaflumizone, English common name: metaflumizone, chemical name: (E+Z)-[2-(4-cyano group benzene)-1-[3-(trifluoromethyl) benzene] ethylidene]-N-[4-(trifluoromethyl) benzene]-hydrazine carbonyl oxamides.Metaflumizone is a kind of insecticide of brand-new mechanism of action, by being attached on the acceptor of sodium-ion channel, hinders sodium ion current, it is mainly stomach poison function, there is certain action of contace poison, Lepidoptera and coleopteran pest are had to obvious control efficiency, to mammal and non-target organism low-risk.
Rice fulgorid, rice leaf roller are the important pests in Rice Production, two kinds of insects often mix and occur simultaneously, on classification of insect, rice fulgorid belongs to Homoptera, rice leaf roller belongs to Lepidoptera, in control, the selection of agricultural chemicals is had to larger difference, must use and just can receive desirable control efficiency by two kinds of mixed pesticides while sending out two kinds of insects are mixed, but in practical application, agricultural chemicals user often causes preventive effect to reduce, even occurs poisoning because mixture is improper, therefore be badly in need of that a kind of pesticide mixed preparation of invention is can be simultaneously double controls rice fulgorid and rice leaf roller.
As a kind of anabasine insecticide, epoxy insect quinoline is good to rice fulgorid preventive effect, general to rice leaf roller preventive effect, exists the risk that resistance risk increases gradually; Metaflumizone is effective to lepidoptera pest, has used for many years, and resistance development is very fast.Inventor surprisingly finds epoxy insect the quinolines different mechanism of action and metaflumizone mixture to use, and has significant synergies, and can doublely control rice fulgorid and rice leaf roller, reduces use cost, slows down the effect of the generation of pest resistance.
Summary of the invention
The object of the present invention is to provide a kind of component reasonable, significantly synergy, good disinsection effect and double controlling, the epoxy insect quinoline that drug cost is low and the Pesticidal combination of metaflumizone.
Another object of the present invention is to provide the Pesticidal combination preparation formulation containing epoxy insect quinoline and metaflumizone.
A further object of the present invention is the application of the Pesticidal combination that epoxy insect quinoline and metaflumizone are provided.
In order to overcome the defect of existing unitary agent, technical scheme of the present invention is to solve like this:
Containing the Pesticidal combination of epoxy insect quinoline and metaflumizone, comprising:
A) the first active component epoxy insect quinoline;
B) the second active component metaflumizone;
The weight ratio of the first active component and the second active component is 1:15～10:1, is preferably 1:10～5:1.
The content sum of the first active component and the second active component is described composition total weight 8%～70%, is preferably 10%～60%.
The Pesticidal combination of epoxy insect quinoline of the present invention and metaflumizone, the preparation formulation that can prepare according to the known method of the art personnel is suspending agent, wetting powder, water dispersible granules or suspended emulsion.
To suspending agent, spendable auxiliary agent has: dispersant is produced as polycarboxylate, lignosulfonates, alkylnaphthalene sulfonate, the HUNTSMAN of Huntsman Corporation of the TERSPERSE 2020(U.S., alkyl naphthalene sulfonic acid salt) in one or more; Emulsifier is as Nongru-700 #(common name: alkyl phenol formaldehyde resin polyoxyethylene ether), this dish-60#(common name: sorbitan monostearate), Tween-60 #(common name: sorbitan monostearate APEO), agriculture breast 1601#(common name: phenethyl phenol polyoxyethylene poly-oxygen propylene aether), Huntsman Corporation of the TERSPERSE 4894(U.S. produces) in one or more; Wetting agent is produced as alkylphenol-polyethenoxy base ether formaldehyde condensation products sulphate, alkylphenol-polyethenoxy base ether phosphate, phenethyl phenol polyethenoxy base ether phosphate, alkyl sulfate, alkylsulfonate, naphthalene sulfonate, Huntsman Corporation of the TERSPERSE 2500(U.S.) in one or more; Thickener as in xanthans, polyvinyl alcohol, bentonite, aluminium-magnesium silicate one or more; Preservative as in formaldehyde, benzoic acid, Sodium Benzoate one or more; Defoamer is as organic silicon defoamer; Antifreezing agent as ethylene glycol, propane diols, glycerine, urea, inorganic salts as in sodium chloride one or more.
To wetting powder, spendable auxiliary agent has: dispersant as in polycarboxylate (TERSPERSE 2700, T36, GY-D06 etc.), lignosulfonates, alkylnaphthalene sulfonate one or more; Wetting agent as in alkyl sulfate, alkylsulfonate, naphthalene sulfonate one or more; Filler as ammonium sulfate, urea, sucrose, glucose, diatomite, kaolin, white carbon, precipitated calcium carbonate, imvite, talcum powder, attapulgite, potter's clay sodium sulphate, sodium polyphosphate one or more.
For water dispersible granules, those skilled in the art are familiar with the corresponding auxiliary agent of use and complete the present invention very much.Dispersant as in polycarboxylate (TERSPERSE 2700, T36, GY-D06 etc.), lignosulfonates, alkylnaphthalene sulfonate one or more; Wetting agent as in alkyl sulfate, alkylsulfonate, naphthalene sulfonate one or more; Disintegrant as in ammonium sulfate, sodium sulphate, polyvinylpyrrolidone, starch and derivative thereof, bentonite one or more; Binding agent is as one or more in starch, glucose, polyvinyl alcohol, polyethylene glycol, sodium carboxymethylcellulose, sucrose; Filler as diatomite, kaolin, white carbon, fine particle calcium carbonate, talcum powder, attapulgite, potter's clay one or more.
To suspended emulsion, spendable auxiliary agent has: dispersant is produced as polycarboxylate, lignosulfonates, alkylnaphthalene sulfonate (dispersing agent NNO), Huntsman Corporation of the TERSPERSE 2425(U.S., alkyl naphthalene sulfonic acid salt) in one or more; Emulsifier is as Nongru-700 #(common name: alkyl phenol formaldehyde resin polyoxyethylene ether), agriculture breast 2201, this dish-60#(common name: sorbitan monostearate), Tween-60 #(common name: sorbitan monostearate APEO), agriculture breast 1601#(common name: phenethyl phenol polyoxyethylene poly-oxygen propylene aether), triphen ethyl phenol polyoxyethylene groups ether phosphate, Huntsman Corporation of the TERSPERSE 4894(U.S. produce) in one or more; Wetting agent is produced as alkylphenol-polyethenoxy base ether formaldehyde condensation products sulphate, alkylphenol-polyethenoxy base ether phosphate, phenethyl phenol polyethenoxy base ether phosphate, alkyl sulfate, alkylsulfonate, naphthalene sulfonate, Huntsman Corporation of the TERSPERSE 2500(U.S.) in one or more; Solvent: one or more in dimethylbenzene, toluene, methyl oleate, soybean oil, castor oil, rapeseed oil, mineral oil, cyclohexanone, acetone, ethyl acetate, solvent naphtha (S-150, S-180, S-200); Thickener as in xanthans, polyvinyl alcohol, bentonite, aluminium-magnesium silicate one or more; Preservative as in formaldehyde, benzoic acid, Sodium Benzoate one or more; Defoamer is as organic silicon defoamer; Antifreezing agent as ethylene glycol, propane diols, glycerine, urea, inorganic salts as in sodium chloride one or more; Stabilizing agent as in triphenyl phosphite, epoxychloropropane, aceticanhydride one or more; Water is deionized water.
Component of the present invention is reasonable, good disinsection effect, and drug cost is low, and its active and insecticidal effect is not the simple superposition of each composition activity, but has significant synergistic effect, good to crop safety, meets the security requirement of pesticidal preparations.The present invention has higher insecticidal activity to rice fulgorid, rice leaf roller etc.
In order to prevent and treat water rice hopper, we have carried out mutual composite synergy research with epoxy insect quinoline and metaflumizone.It is tested object that test adopts Brown Planthopper, and concrete grammar is:
Brown plant-hopper formal name used at school Nilaparvata lugens, Homoptera, Delphacidae.Former medicine is mixed with to the test medicine needing, test method is with reference to " People's Republic of China's agricultural industry criteria NY/T1154.7-2006 ".First single dose and each Mixed Pharmacy are arranged to 5 variable concentrations gradients (on the basis of preliminary experiment result, brown plant-hopper lethality is set by geometric progression in 5%～90% scope).Examination worm be the brown planthopper ovum that picks up from field, in greenhouse, raised for 3 generations with rice seedlings, select uniformity 3 age nymph, the culture dish of rice seedling diameter 12cm is put in access, every ware connects and anaesthetizes 30 of nymphs, and every processing connects 4 culture dishes, sprays with potter spray tower under 50PSI pressure, a ware of each spray, every ware spraying liquid 3ml, after insect revives, puts into 12H/12H illumination box by the culture dish of processing and cultivates, within 72 hours, check dead borer population, calculate lethality.Blank spray equivalent clear water.By the linear regression analysis between the probit value of lethality and the logarithm value of series concentration, obtain the LC of each medicament
50value, with the co-toxicity coefficient (CTC) of the abundant method calculating of Sun Yun mixture, evaluates the activity of reagent agent to examination worm with this.
The co-toxicity coefficient (CTC) >=120 of complex preparation shows as synergistic effect; CTC≤80 show as antagonism; 80 < CTC < 120 show as summation action.
Table 1 epoxy insect quinoline and metaflumizone combine the Toxicity Determination to brown planthopper
Toxicity Determination result shows: epoxy insect quinoline has good virulence as 1:15～10:1 is mixed to brown plant-hopper taking weight ratio with metaflumizone, all has significant synergistic effect, especially taking weight ratio as 1:10～5:1 synergy the most remarkable.
In order to prevent and treat the paddy rice rice leaf roller in agricultural production, inventor has carried out mutual composite synergy research with epoxy insect quinoline and metaflumizone.Concrete grammar is:
Subjects: rice leaf roller formal name used at school Cnaphalocrocis medinalis Guenee, the vertical volume of another name snout moth's larva, tortrix moth, Lepidoptera, Pyralidae.Former medicine is mixed with to the test medicine needing, test method is with reference to " the agricultural industry criteria NY/T1154.2-2006 of the People's Republic of China (PRC) ".First single dose and each Mixed Pharmacy are arranged to 5 variable concentrations gradients (on the basis of preliminary experiment result, rice leaf roller lethality is set by geometric progression in 5%～90% scope).Examination worm is the rice leaf roller larvae that field gathers, select the larva of uniformity in the length of time in laboratory, hungry 4～8 hours, beat and get leaf dish with the card punch of 1 centimetre of diameter, put into culture dish, and note moisturizing. with capillary dropper from low concentration, every leaf dish point 1 μ L～2 μ L liquid that drips, after solvent evaporates, scribble the involutory malicious leaf dish of folder of making of leaf dish of gelatinized corn starch with another sheet, make in the complete hole that is put in 12 hole tissue culturing plates.Every processing 4 times repeats, and often repeats to be no less than 12 malicious leaf dish of folder, and establishes not containing the processing of the corresponding organic solvent of medicament in contrast.In the each hole of tissue culturing plate, connect 1 examination worm, be placed under normal condition and cultivate.Connect worm after 2～4 hours, taken food after pastille leaf dish wait trying worm, in cultivation plate hole, add clean feed to continue to raise to investigating, eliminate the examination worm that has not eaten an intact leaves dish, within 24 hours, check dead borer population, calculate lethality.By the linear regression analysis between the probit value of lethality and the logarithm value of series concentration, obtain the LC of each medicament
50value, with the co-toxicity coefficient (CTC) of the abundant method calculating of Sun Yun mixture, evaluates the activity of reagent agent to examination worm with this.
The co-toxicity coefficient (CTC) >=120 of complex preparation shows as synergistic effect; CTC≤80 show as antagonism; 80 < CTC < 120 show as summation action.
Table 2 epoxy insect quinoline and metaflumizone combine the Toxicity Determination to rice leaf roller
Toxicity Determination result shows: epoxy insect quinoline has good virulence as 1:15～10:1 is mixed to rice leaf roller taking weight ratio with metaflumizone, all has significant synergistic effect, especially taking weight ratio as 1:10～5:1 synergy the most remarkable.
Embodiment
Below in conjunction with embodiment, the invention will be further described.
Example of formulations 1
Taking 4% epoxy insect quinoline, 20% metaflumizone, Huntsman Corporation of the 3%TERSPERSE 4894(U.S. produces), Huntsman Corporation of the 1%TERSPERSE 2500(U.S. produces), 0.3% xanthans, 5% propane diols, 0.5% benzoic acid, 0.5% silicone defoaming agent (trade name: s-29, Nanjing "four news" (new ideas applied chemistry product company produces), deionized water add to 100% weight portion.Above-mentioned raw materials is through mixing, and high speed shear is disperseed 30min, with making 24% epoxy insect quinoline metaflumizone suspending agent after sand mill sand milling.
Example of formulations 2
Taking 10% epoxy insect quinoline, 20% metaflumizone, Huntsman Corporation of the 4%TERSPERSE 4894(U.S. produces), Huntsman Corporation of the 1.5%TERSPERSE 2500(U.S. produces), Huntsman Corporation of the 1%TERSPERSE 2020(U.S. produces), 0.2% aluminium-magnesium silicate, 5% ethylene glycol, 0.5% formaldehyde, 0.5% silicone defoaming agent (trade name: s-29 Nanjing "four news" (new ideas applied chemistry product company produces), deionized water add to 100% weight portion.Above-mentioned raw materials is through mixing, and high speed shear is disperseed 30min, with making 30% epoxy insect quinoline metaflumizone suspending agent after sand mill sand milling.
Example of formulations 3
Take 50% epoxy insect quinoline, 5% metaflumizone, 4%GY-D06,3% alkylnaphthalene sulfonate formaldehyde condensation products (dispersing agent NNO), 1% lauryl sodium sulfate, 3% white carbon, 3% sodium polyphosphate, kaolin and fill up the weight portion to 100%.Above-mentioned raw materials is prepared into 55% epoxy insect quinoline metaflumizone wetting powder through mixing, ultra micro air-flow crushing, hybrid technique step.
Example of formulations 4
Take 30% epoxy insect quinoline, 15% metaflumizone, 4% calcium lignosulfonate, 3% alkylnaphthalene sulfonate formaldehyde condensation products (dispersing agent NNO), 1.5% lauryl sodium sulfate, 5% potter's clay sodium sulphate, fine particle calcium carbonate and fill up the weight portion to 100%.Above-mentioned raw materials is prepared into 45% epoxy insect quinoline metaflumizone wetting powder through mixing, ultra micro air-flow crushing, hybrid technique step.
Example of formulations 5
Take 20% epoxy insect quinoline, 50% metaflumizone, 2%TERSPERSE 2700(polycarboxylate, Huntsman Corporation of the U.S. produces), 2% sodium lignin sulfonate, 1% Nekal BX (nekal), 1%K-12(lauryl sodium sulfate), 1%PVA(molecular weight 2000), 2% polyvinylpyrrolidone, kaolin add to 100% weight portion.The method of the frequent regulation of above-mentioned raw materials water intaking dispersible granule mixes, ultra micro air-flow crushing, mixing, granulation step are produced 70% epoxy insect quinoline metaflumizone water dispersible granules.
Example of formulations 6
Take 3% epoxy insect quinoline, 45% metaflumizone, 4% GY-D06(polycarboxylate), 3% dispersing agent NNO (alkylnaphthalene sulfonate formaldehyde condensation products), 2% Nekal BX (nekal), 2%K-12(lauryl sodium sulfate), 5% diatomite, 8% bentonite, attapulgite adds to 100% weight portion.The method of the frequent regulation of above-mentioned raw materials water intaking dispersible granule mixes, ultra micro air-flow crushing, mixing, granulation step are produced 48% epoxy insect quinoline metaflumizone water dispersible granules.
Example of formulations 7
Take 2% epoxy insect quinoline, 6% metaflumizone, 2.5% triphen ethyl phenol polyoxyethylene groups ether phosphate, 1.5% dispersing agent NNO, Huntsman Corporation of the 4%TERSPERSE4894(U.S. produces), 15% methyl oleate, 2.5% this dish-60#, 3.5% Tween-60 #, 1% Huntsman Corporation of the TERSPERSE 2500(U.S. produces), 2% aluminium-magnesium silicate, 0.2% xanthans, 5% ethylene glycol, 1% epoxychloropropane, 0.3% benzoic acid, 0.5% silicone defoaming agent (trade name: s-29 Nanjing "four news" (new ideas applied chemistry product company produces), deionized water adds to 100% weight portion.Operating procedure: 1, in above-mentioned raw materials, solvent and emulsifier mix, 2, unclassified stores is through mixing, 3, drop in 2 materials mixing material in 1, high speed shear is disperseed 30min, with making 8% epoxy insect quinoline metaflumizone suspended emulsion after sand mill sand milling.
Example of formulations 8
Take 10% epoxy insect quinoline, 10% metaflumizone, 1% dispersing agent NNO, Huntsman Corporation of the 1%TERSPERSE2425(U.S. produces), 20% castor oil, 5% solvent naphtha S-180,2.5% agriculture breast 1601#, 3.5% Tween-60 #, 1% alkylphenol-polyethenoxy base ether phosphate, 2% polyvinyl alcohol, 0.2% xanthans, 5% ethylene glycol, 3% triphenyl phosphite, 0.3% Sodium Benzoate, 0.5% silicone defoaming agent (trade name: s-29 Nanjing "four news" (new ideas applied chemistry product company produces), deionized water adds to 100% weight portion.Operating procedure: 1, in above-mentioned raw materials, solvent and emulsifier mix, 2, unclassified stores is through mixing, 3, drop in 2 materials mixing material in 1, high speed shear is disperseed 30min, with making 20% epoxy insect quinoline metaflumizone suspended emulsion after sand mill sand milling.
Biological Examples 1: control paddy rice rice leaf roller, rice fulgorid field trial
Inventor has carried out formulation examples 1(30% epoxy insect quinoline metaflumizone suspending agent on April 5th, 2012 at Beihai, Guangxi Hepu County) control paddy rice rice leaf roller, rice fulgorid field control effectiveness test, trial crops is paddy rice, controlling object rice leaf roller (Cnaphalocrocis medinalis), brown planthopper (Nilaparvata lugens).Test medicine and extension rate refer to table 3.The cultivation condition of each community, water and fertilizer management uniformity.With amount of liquid medicine be 45kg/667 ㎡, adopt manual sprayer evenly spray, require each community rice leaf positive and negative even medicine.Separately establish blank, every processing repeats for 4 times, every community area 50 ㎡, and Gong24Ge community, random district group is arranged.Investigation radix before medicine, 3,7,14 days investigation preventive effects after rice leaf roller medicine, after rice fulgorid medicine, 1,7,14 day investigation preventive effect is observed paddy growth situation simultaneously, and visual test medicament has or not poisoning to produce to paddy rice.
Investigation statistics method
Rice leaf roller:
Take parallel great-jump-forward random sampling, 25 clumps of rice are looked in the sampling of 5 of every communities altogether, and statistics leaf roll rate, with check plot leaf roll rate comparison, calculates relative control effect.
The total number of sheets × 100 of leaf roll rate (%)=investigation leaf roll number/investigate
Leaf roll rate × 100 after control efficiency (%)=(after blank district medicine after leaf roll rate-chemicals treatment district medicine leaf roll rate)/blank district medicine
Rice fulgorid:
Take the random sampling of balance-jump formula, every community 10 points, 2 clumps every (totally 20 clumps), record rice fulgorid borer population by basin bat method, by the borer population calculation correction preventive effect before every clump of medicine, after medicine.
Control efficiency (%)=[1-(borer population after the front borer population × treatment region medicine of check plot medicine)/(the front borer population of borer population × treatment region medicine after the medicine of check plot)] × 100
Table 3 is prevented and treated rice grub field test results
Result of the test shows, 30% 2000 times, 2500 times, 3000 times of epoxy insect quinoline metaflumizone suspending agents have significant control efficiency to paddy rice rice leaf roller, brown planthopper, after medicine, the preventive effect of 1,3,7,14 day, all more than 80%, is obviously better than the control efficiency (table 3) of 1000 times of 10% epoxy insect quinoline suspending agents, 1000 times of 25% metaflumizone suspending agents.
Security survey, duration of test is observed, and all reagent agents, to paddy growth safety, occur without poisoning phenomenon.
Result of the test shows, after epoxy insect quinoline and metaflumizone mixture, control efficiency and lasting period to rice leaf roller, rice fulgorid are obviously improved, in the time that these two kinds of insects occur simultaneously, a dispenser reaches double and controls, reduce dosage, reduced medication number of times and drug cost, to paddy growth safety.
In sum, composition of the present invention is to adopt two kinds of active component compound schemes, its activity and insecticidal effect are not the simple superposition of each composition activity, compared with existing unitary agent, except having significant insecticidal effect, and have significant synergistic effect, and good to crop safety, meet the security requirement of pesticidal preparations.
Claims (5)
1. containing a Pesticidal combination for epoxy insect quinoline and metaflumizone, it is characterized in that: active component is made up of the first active component epoxy insect quinoline and the second active component metaflumizone, and the weight ratio of the first active component and the second active component is 1:10～2:1.
2. according to claim 1 containing the Pesticidal combination of epoxy insect quinoline and metaflumizone, it is characterized in that, the content sum of the first active component and the second active component is described composition total weight 8%～70%.
3. according to claim 2 containing the Pesticidal combination of epoxy insect quinoline and metaflumizone, it is characterized in that, the content sum of the first active component and the second active component is described composition total weight 10%～60%.
4. according to claim 1 containing the Pesticidal combination of epoxy insect quinoline and metaflumizone, it is characterized in that described combination dosage form is suspending agent, wetting powder, water dispersible granules or suspended emulsion.
5. contain according to claim 1 the Pesticidal combination of epoxy insect quinoline and metaflumizone in the purposes of preventing and treating on rice fulgorid and rice leaf roller.
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| CN103444761B (en) * | 2013-09-16 | 2015-05-13 | 陕西农心作物科技有限公司 | Cycolxylidin-containing pesticidal composition |
| CN103444764B (en) * | 2013-09-16 | 2015-09-02 | 陕西农心作物科技有限公司 | A kind of Pesticidal combination containing cycolxylidin |
| CN106942259A (en) * | 2017-03-22 | 2017-07-14 | 京博农化科技股份有限公司 | A kind of Pesticidal combination containing indoxacarb and cycolxylidin |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1119646A (en) * | 1994-06-03 | 1996-04-03 | 三井东压化学株式会社 | Insecticidal tetrahydrofuran-compound |
| CN101503406A (en) * | 2008-12-17 | 2009-08-12 | 武汉工程大学 | 1-(1,2-epoxy propyl)-N-nitroimidazolene amine-2, preparation and use thereof |
| CN101524087A (en) * | 2009-04-28 | 2009-09-09 | 北京燕化永乐农药有限公司 | Pesticide composition containing metaflumizone and acephate |
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| CN101622996A (en) * | 2009-08-12 | 2010-01-13 | 深圳诺普信农化股份有限公司 | Insecticidal composition |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1119646A (en) * | 1994-06-03 | 1996-04-03 | 三井东压化学株式会社 | Insecticidal tetrahydrofuran-compound |
| CN101503406A (en) * | 2008-12-17 | 2009-08-12 | 武汉工程大学 | 1-(1,2-epoxy propyl)-N-nitroimidazolene amine-2, preparation and use thereof |
| CN101524087A (en) * | 2009-04-28 | 2009-09-09 | 北京燕化永乐农药有限公司 | Pesticide composition containing metaflumizone and acephate |
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