CN103828827B - Insecticidal composition containing sulfoxaflor and spirotetramat - Google Patents
Insecticidal composition containing sulfoxaflor and spirotetramat Download PDFInfo
- Publication number
- CN103828827B CN103828827B CN201410104206.9A CN201410104206A CN103828827B CN 103828827 B CN103828827 B CN 103828827B CN 201410104206 A CN201410104206 A CN 201410104206A CN 103828827 B CN103828827 B CN 103828827B
- Authority
- CN
- China
- Prior art keywords
- ethyl ester
- spiral shell
- amine nitrile
- active component
- fluorine
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Abstract
The invention discloses an insecticidal composition containing sulfoxaflor and spirotetramat and application of the insecticidal composition. Active ingredients comprise a first active ingredient sulfoxaflor and a second active ingredient spirotetramat in a weight ratio of 1:10 to 10:1. The composition can be prepared into agriculturally acceptable suspension, water dispersible granules, wettable powder or dispersible oil suspension. The composition contains reasonable ingredients, and has good insecticidal effects; the activity and insecticidal effects of the composition are not the simple superimposition of the activity of all ingredients, and compared with a conventional single preparation, the composition has remarkable insecticidal effects, remarkable synergistic effects and high safety to crops. The composition has remarkable prevention and control effects on pear psylla, scale insects, aphids and trialeurodes vaporariorum.
Description
Technical field
The present invention relates to a kind of Pesticidal combination, be made up of the first active component fluorine pyridine worm amine nitrile and the second active component spiral shell worm ethyl ester, belong to technical field of compounded pesticide.
Background technology
Fluorine pyridine worm amine nitrile, English common name: sulfoxaflor, chemical name: [1-[6-(trifluoromethyl) pyridin-3-yl] ethyl] methyl (oxygen)-λ 4-sulfydryl cyanamide.Fluorine pyridine worm amine nitrile is sulfimide insecticide, acts on binding site unique in insect choline receptor and plays insecticidal function.Can through leaf, stem, root absorption and entering in plant corpus.Be applicable to control crop aphid, fleahopper, aleyrodid, plant hopper, scale insect etc.As a kind of new insecticide, in use there is resistance risk in fluorine pyridine worm amine nitrile, and rationally uses with from the insecticide of the different mechanism of action, for fully effectively promoting fluorine pyridine worm amine nitrile, extending its service life and having important function.
Spiral shell worm ethyl ester, English common name: spirotetramat, chemical name: 4-(ethoxy carbonyl oxygen base)-8-methoxyl group-3-(2,5-xylyl)-1-azaspiro [4, the 5]-last of the ten Heavenly stems-3-alkene-2-ketone.Spiral shell worm ethyl ester is novel tetronic acid insecticides, and insecticidal spectrum is wide, and the lasting period is long.It causes dead larvae by the fatty biosynthesis of interference insect, reduces the fertility of adult.Due to the mechanism of action of its uniqueness, can effectively prevent and treat various sucking pest, as aphid, thrips, mealybug, aleyrodid and scale insect etc.
Inventor does not also find that there is through retrieval the bibliographical information being used for fluorine pyridine worm amine nitrile and spiral shell worm ethyl ester mixture to prevent and treat pest, find fluorine pyridine worm amine nitrile and spiral shell worm ethyl ester mixture to use have good control efficiency to pest by lot of experiments, have the advantages that quick-acting is good, the lasting period is long, there is significant synergistic effect, have received beyond thought effect, can use cost be reduced, effectively solve the problem that the resistant insect controls such as wood louse, aleyrodid, scale insect, aphid are difficult.
Summary of the invention
The object of the present invention is to provide a kind of component reasonable, remarkable synergy, good disinsection effect, the Pesticidal combination of the fluorine pyridine worm amine nitrile that drug cost is low and spiral shell worm ethyl ester.
Another object of the present invention is to the Pesticidal combination preparation formulation that fluorine-containing pyridine worm amine nitrile and spiral shell worm ethyl ester are provided.
Another object of the present invention is the application of the Pesticidal combination providing fluorine pyridine worm amine nitrile and spiral shell worm ethyl ester.
In order to overcome the defect of existing unitary agent, technical scheme of the present invention solves like this:
The Pesticidal combination of fluorine-containing pyridine worm amine nitrile and spiral shell worm ethyl ester, comprising:
A) the first active component fluorine pyridine worm amine nitrile;
B) the second active component spiral shell worm ethyl ester;
The weight ratio of the first active component and the second active component is 1:10 ~ 10:1, is preferably 1:5 ~ 5:1.
The content sum of the first active component and the second active component is 6% ~ 70% of described composition total weight.
The Pesticidal combination of fluorine pyridine worm amine nitrile of the present invention and spiral shell worm ethyl ester, the preparation formulation can prepared according to the method that the art personnel are known is suspending agent, water dispersible granules, wetting powder, dispersible oil-suspending agent.
To suspending agent, spendable auxiliary agent has: dispersant such as polycarboxylate, lignosulfonates, alkylnaphthalene sulfonate, Huntsman Corporation of TERSPERSE 2020(U.S. HUNTSMAN produce, alkyl naphthalene sulfonic acid salt) in one or more; Emulsifier is as Nongru-700 #(common name: alkyl phenol formaldehyde resin polyoxyethylene ether), this dish-60#(common name: sorbitan monostearate), Tween-60 #(common name: sorbitan monostearate APEO), agriculture breast 1601#(common name: phenethyl phenol polyoxyethylene poly-oxygen propylene aether), Huntsman Corporation of the TERSPERSE 4894(U.S. produces) in one or more; Wetting agent such as alkylphenol-polyethenoxy base ether formaldehyde condensation products sulphate, alkylphenol-polyethenoxy base ether phosphate, phenethyl phenol polyethenoxy base ether phosphate, alkyl sulfate, alkylsulfonate, naphthalene sulfonate, Huntsman Corporation of the TERSPERSE 2500(U.S. produce) in one or more; Thickener as in xanthans, polyvinyl alcohol, bentonite, aluminium-magnesium silicate one or more; Preservative as in formaldehyde, benzoic acid, Sodium Benzoate one or more; Defoamer is as organic silicon defoamer; Antifreezing agent as ethylene glycol, propane diols, glycerine, urea, inorganic salts as in sodium chloride one or more.
For water dispersible granules, those skilled in the art are familiar with the corresponding auxiliary agent of use and complete the present invention very much.Dispersant as in polycarboxylate (TERSPERSE 2700, T36, GY-D06 etc.), lignosulfonates, alkylnaphthalene sulfonate one or more; Wetting agent as in alkyl sulfate, alkylsulfonate, naphthalene sulfonate one or more; Disintegrant as in ammonium sulfate, sodium sulphate, polyvinylpyrrolidone, starch and derivative thereof, bentonite one or more; Binding agent is as one or more in starch, glucose, polyvinyl alcohol, polyethylene glycol, sodium carboxymethylcellulose, sucrose; Filler as diatomite, kaolin, white carbon, fine particle calcium carbonate, talcum powder, attapulgite, potter's clay one or more.
To wetting powder, spendable auxiliary agent has: dispersant is as polycarboxylic acid salt (TERSPERSE 2700, T36, GY-D06 etc.), lignin sulfonate (Ufoxane 3A, Borresperse NA, Borresperse CA-SA etc.), naphthalene and alkyl naphthalene formaldehyde condensate sulfonates class (NNO, MF, Morwet D-425, Tamol NN, TERSPERSE2020 etc.), Nekal BX (nekal), EO-PO block polyether class, alkylphenol-polyethenoxy base ether phosphate, alkylphenol-polyethenoxy base ether formaldehyde condensation products sulphate (SOPA), in one or more, wetting agent as in Sulfates (K-12), Sulfonates (ABS-Na, BX, Terwet 1004 etc.), compound wetting agent (Morwet EFW) one or more, filler as diatomite, kaolin, fine particle calcium carbonate, talcum powder, white carbon, attapulgite, potter's clay, ammonium sulfate, urea, sucrose, glucose, corn starch, sodium sulphate, sodium polyphosphate etc. one or more.
To dispersibling oil-suspending agent, spendable auxiliary agent has: dispersant such as polycarboxylate, lignosulfonates, alkylnaphthalene sulfonate (dispersing agent NNO), Huntsman Corporation of TERSPERSE 2020(U.S. HUNTSMAN produce, alkyl naphthalene sulfonic acid salt) in one or more, emulsifier is as BY(castor oil polyoxyethylene ether) serial emulsifier (BY-110, BY-125, BY-140), Nongru-700 #(common name: alkyl phenol formaldehyde resin polyoxyethylene ether), agriculture breast 2201, this dish-60#(common name: sorbitan monostearate), Tween-60 #(common name: sorbitan monostearate APEO), agriculture breast 1601#(common name: phenethyl phenol polyoxyethylene poly-oxygen propylene aether), Huntsman Corporation of the TERSPERSE 4894(U.S. produce) in one or more, wetting agent such as alkylphenol-polyethenoxy base ether formaldehyde condensation products sulphate, alkylphenol polyoxyethylene phosphate, phenethyl phenol polyethenoxy base ether phosphate, alkyl sulfate, alkylsulfonate, naphthalene sulfonate, Huntsman Corporation of the TERSPERSE 2500(U.S. produce) in one or more, thickener as in white carbon, polyvinyl alcohol, bentonite, aluminium-magnesium silicate one or more, antifreezing agent as ethylene glycol, propane diols, glycerine, urea, inorganic salts as in sodium chloride one or more, dispersion medium as in soybean oil, rapeseed oil, corn oil, methyl oleate, diesel oil, machine oil, mineral oil one or more.
Instant component is reasonable, good disinsection effect, and drug cost is low, and its activity and insecticidal effect are not the simple superposition of each composition activity, but has significant synergistic effect, good to crop safety, meets the security requirement of pesticidal preparations.The present invention has good control efficiency to the pear sucker in agricultural production, scale insect, aphid, trialeurodes vaporariorum.
Embodiment
In order to prevent and treat the pear sucker in agricultural production, we have carried out mutual composite synergy with fluorine pyridine worm amine nitrile and spiral shell worm ethyl ester and have studied.Concrete grammar is:
Pear sucker (Psylla chinensis Yang et Li) belongs to Homoptera Psyllidae.Test adopts medicine embrane method and is improved.Selected shape is complete, well-grown, growing way are homogeneous without worm pears leaf, washes away the dust on surface, dries in the shade for subsequent use.Fluorine pyridine worm amine nitrile and spiral shell worm ethyl ester single dose and different proportion Mixed Pharmacy are arranged 5 variable concentrations gradients (on the basis of preliminary experiment result, pear sucker lethality in the scope of 5% ~ 90% by geometric progression setting).Get clean pears leaf to flood 10 seconds in each concentration liquid respectively, for subsequent use in the culture dish being placed on diameter 9cm after drying in the shade, and be wrapped in the moisturizing of petiole place with moistening absorbent cotton, bottom culture dish, place the blotting paper containing appropriate moisture content, to keep culture dish interior humidity simultaneously.Then in the same size with No. zero writing brush picking, take action active 3 age nymph on the blade of above-mentioned process, 20-30, every leaf, cover culture dish lid, repeat 3 times, separately establish clear water to contrast, put in 12H/12H illumination box (temperature is 25 DEG C, and humidity is 60%) and cultivate, within 48 hours, check dead borer population, calculate lethality.By the linear regression analysis between the probit value of lethality and the logarithm value of series concentration, obtain the LC of each medicament
50value, calculates the co-toxicity coefficient (CTC) of mixture by the abundant method of Sun Yun, evaluate the activity of reagent agent to examination worm with this.
The co-toxicity coefficient (CTC) >=120 of complex preparation shows as synergistic effect; CTC≤80 show as antagonism; 80 < CTC < 120 show as summation action.
Toxicity Determination result shows: fluorine pyridine worm amine nitrile is that 1:10 ~ 10:1 is mixed with spiral shell worm ethyl ester with weight ratio has good virulence to pear sucker, all has significant synergistic effect, is that 1:5 ~ 5:1 synergy is the most remarkable especially with weight ratio.
In order to prevent and treat scale insect on crops, aphid, trialeurodes vaporariorum, we have carried out mutual composite synergy with fluorine pyridine worm amine nitrile and spiral shell worm ethyl ester and have studied.Test adopts Kang Shi mealybug, apple yellow aphid, trialeurodes vaporariorum to be tested object, and concrete grammar is:
Kang Shi mealybug (Pseudococcus comstocki Kuwana), belongs to Homoptera Pseudococcidae.Apple yellow aphid (Aphis pomi DeGeer), has another name called spiraea aphid, belongs to Homoptera, Aphidiadae.Trialeurodes vaporariorum (Trialeurodes vaporariorum), has another name called little Bai moth, belongs to Homoptera Aleyrodidae.Former medicine is mixed with the test medicine of needs, test method is with reference to " People's Republic of China (PRC) agricultural industry criteria NY/T1154.6-2006 ".First single dose and each Mixed Pharmacy are arranged 5 variable concentrations gradients (on the basis of preliminary experiment result, examination worm lethality sets by geometric progression in the scope of 5% ~ 90%).Examination worm is the Kang Shi mealybug, apple yellow aphid, the trialeurodes vaporariorum that pick up from field, select the nymph of uniformity in laboratory, put into blade-carrying culture dish, every ware 40 cephalont, often process 4 culture dishes, repeat 3 times, spray under 50PSI pressure with potter spray tower, each spray ware, every ware spraying liquid 3ml, then the culture dish processed is put into 12H/12H illumination box to cultivate, within 72 hours, check dead borer population, calculate lethality.Blank spray equivalent clear water.By the linear regression analysis between the probit value of lethality and the logarithm value of series concentration, obtain the LC of each medicament
50value, calculates the co-toxicity coefficient (CTC) of mixture by the abundant method of Sun Yun, evaluate the activity of reagent agent to examination worm with this.
Toxicity Determination result shows: fluorine pyridine worm amine nitrile and spiral shell worm ethyl ester are that 1:10 ~ 10:1 is mixed with weight ratio has good virulence to Kang Shi mealybug, apple yellow aphid, trialeurodes vaporariorum, all having significant synergistic effect, is that 1:5 ~ 5:1 synergy is the most remarkable especially with weight ratio.
Below in conjunction with embodiment, the invention will be further described.
Example of formulations 1
Take 20% fluorine pyridine worm amine nitrile, 10% spiral shell worm ethyl ester, Huntsman Corporation of the 3%TERSPERSE 4894(U.S. produce), Huntsman Corporation of the 1%TERSPERSE 2500(U.S. produces), 0.3% xanthans, 5% propane diols, 0.5% benzoic acid, 0.5% silicone defoaming agent (trade name: s-29, Nanjing "four news" (new ideas applied chemistry product Company), deionized water add to 100% weight portion.Above-mentioned raw materials is through mixing, and high speed shear dispersion 30min, with 30% fluorine pyridine worm amine nitrile spiral shell worm ethyl ester suspending agent obtained after sand mill sand milling.
Example of formulations 2
Take 30% fluorine pyridine worm amine nitrile, 3% spiral shell worm ethyl ester, 4% this dish-60#, 3% agriculture breast 1601#, 2% alkylphenol-polyethenoxy base ether phosphate, Huntsman Corporation of the 1%TERSPERSE 2020(U.S. produce), 0.2% polyvinyl alcohol, 5% ethylene glycol, 0.5% Sodium Benzoate, 0.5% silicone defoaming agent (trade name: s-29 Nanjing "four news" (new ideas applied chemistry product Company), deionized water add to 100% weight portion.Above-mentioned raw materials is through mixing, and high speed shear dispersion 30min, with 33% fluorine pyridine worm amine nitrile spiral shell worm ethyl ester suspending agent obtained after sand mill sand milling.
Example of formulations 3
Take 20% fluorine pyridine worm amine nitrile, 50% spiral shell worm ethyl ester, 2% TERSPERSE 2700(polycarboxylate, Huntsman Corporation of the U.S. produces), 2% sodium lignin sulfonate, 1% Nekal BX (nekal), 1%K-12(lauryl sodium sulfate), 1%PVA(molecular weight 2000), 2% polyvinylpyrrolidone, kaolin adds to 100% weight portion.Namely the method for above-mentioned raw materials frequent regulation water intaking dispersible granule mixes, ultra micro air-flow crushing, mixing, granulation step produce 70% fluorine pyridine worm amine nitrile spiral shell worm ethyl ester water dispersible granules.
Example of formulations 4
Take 20% fluorine pyridine worm amine nitrile, 20% spiral shell worm ethyl ester, 4% GY-D06(polycarboxylate), 3% dispersing agent NNO (alkylnaphthalene sulfonate formaldehyde condensation products), 2% Nekal BX (nekal), 2%K-12(lauryl sodium sulfate), 5% diatomite, 8% bentonite, attapulgite add to 100% weight portion.Namely the method for above-mentioned raw materials frequent regulation water intaking dispersible granule mixes, ultra micro air-flow crushing, mixing, granulation step produce 40% fluorine pyridine worm amine nitrile spiral shell worm ethyl ester water dispersible granules.
Example of formulations 5
Take 5% fluorine pyridine worm amine nitrile, 50% spiral shell worm ethyl ester, 6% calcium lignosulfonate (Ufoxane 3A), 3% alkylnaphthalene sulfonate formaldehyde condensation products (Tamol NN), 1% lauryl sodium sulfate, 5% white carbon, kaolin fill up weight portion to 100%.Above-mentioned raw materials is prepared into 55% fluorine pyridine worm amine nitrile spiral shell worm ethyl ester wetting powder through mixing, ultra micro air-flow crushing, hybrid technique step.
Example of formulations 6
Take 10% fluorine pyridine worm amine nitrile, 20% spiral shell worm ethyl ester, 6% calcium lignosulfonate, 4% alkylnaphthalene sulfonate formaldehyde condensation products (Morwet D-425), 1.5% lauryl sodium sulfate, 12% white carbon, fine particle calcium carbonate fill up weight portion to 100%.Above-mentioned raw materials is prepared into 30% fluorine pyridine worm amine nitrile spiral shell worm ethyl ester wetting powder through mixing, ultra micro air-flow crushing, hybrid technique step.
Example of formulations 7
Take 30% fluorine pyridine worm amine nitrile, 10% spiral shell worm ethyl ester, Huntsman Corporation of the 2%TERSPERSE 2020(U.S. produce), 4% this dish-60#, 3% Tween-60 #, 4% agriculture breast 2201#, 3% Huntsman Corporation of Nongru-700 #, 1%TERSPERSE 2500(U.S. produce), 0.5% white carbon, 5% propane diols, methyl oleate add to 100% weight portion.Above-mentioned raw materials is through mixing, and high speed shear dispersion 30min, dispersibles oil-suspending agent with 40% fluorine pyridine worm amine nitrile spiral shell worm ethyl ester obtained after sand mill sand milling.
Example of formulations 8
Take 1% fluorine pyridine worm amine nitrile, 5% spiral shell worm ethyl ester, 2% dispersing agent NNO, 3% agriculture breast 2201#, 10% Huntsman Corporation of BY-110,1%TERSPERSE 2500(U.S. produce), 1% aluminium-magnesium silicate, 3% glycerine, soybean oil add to 100% weight portion.Above-mentioned raw materials is through mixing, and high speed shear dispersion 30min, dispersibles oil-suspending agent with 6% fluorine pyridine worm amine nitrile spiral shell worm ethyl ester obtained after sand mill sand milling.
Biological Examples: control pear sucker field trial
Inventor has carried out example of formulations 1(30% fluorine pyridine worm amine nitrile spiral shell worm ethyl ester suspending agent in April, 2013 in Jinzhou City, Hebei) prevent and treat pear sucker field control effectiveness test, demonstrate this medicament to the control efficiency of pear sucker, effective dose and the safety to pear tree.Test is located at faro township, Jinzhou City, test pear tree 5 years raw pears, and theatre managerial skills are medium, and tree vigo(u)r growth is general, and pear sucker is laid particular stress on.Test medicine and dosage refer to table 3, separately establish blank.Often process and repeat for 4 times, 5, every community tree, Gong24Ge community, random district group arranges.Adopt manual sprayer evenly to spray, the positive back side of complete stool blade is evenly sprayed onto liquid for dripping for degree.Borer population investigation is respectively once remained respectively at before medicine, after medicine 3 days, 7 days, 15 days.2 trees are investigated in every community, and every strain fixes 5 brachyplasts by 5 orientation, the movable borer population on every random searching 10 leaves, record pear sucker borer population alive, and calculate preventive effect.Viewing test medicament produces with or without poisoning Pears, the tender tip, young fruit simultaneously.
Computational methods:
Control efficiency (%)=[1-(before the medicine of check plot after borer population × treatment region medicine borer population)/(before borer population after the medicine of check plot × treatment region medicine borer population)] × 100
Result of the test shows, 30% fluorine pyridine worm amine nitrile spiral shell worm ethyl ester suspending agent dilutes 4000 times, 5000 times, 6000 times, good control efficiency is had to pear sucker, after medicine, the preventive effect of 3,7,14 days is all more than 89.2%, show excellent quick-acting and lasting effect, be obviously better than the control efficiency (table 5) of 20% fluorine pyridine worm amine nitrile suspending agent 3000 times, 10% spiral shell worm ethyl ester suspending agent 1000 times.Advise that 30% fluorine pyridine worm amine nitrile spiral shell worm ethyl ester suspending agent control pear sucker dilution 4000-6000 times is advisable.
Security survey, duration of test is observed, and all reagent agents, to Pears, the tender tip, growth of young safety, occur without poisoning phenomenon.
Result of the test shows, after fluorine pyridine worm amine nitrile and spiral shell worm ethyl ester mixture, significantly improves the control efficiency to pear sucker, and synergistic effect is obvious, shows excellent quick-acting and lasting period, reduces dosage, saved drug cost, to Growth of Pear Trees safety.
In sum, composition of the present invention is employing two kinds of active component compound schemes, its activity and insecticidal effect are not the simple superposition of each composition activity, compared with existing unitary agent, except there is significant insecticidal effect, and have significant synergistic effect, and good to crop safety, meet the security requirement of pesticidal preparations.
Claims (5)
1. a Pesticidal combination for fluorine-containing pyridine worm amine nitrile and spiral shell worm ethyl ester, is characterized in that: comprise the first active component fluorine pyridine worm amine nitrile and the second active component spiral shell worm ethyl ester, the weight ratio of the first active component and the second active component is 1:10 ~ 10:1.
2. the Pesticidal combination of fluorine-containing pyridine worm amine nitrile and spiral shell worm ethyl ester according to claim 1, is characterized in that: the weight ratio of the first active component and the second active component is 1:5 ~ 5:1.
3. the Pesticidal combination of fluorine-containing pyridine worm amine nitrile and spiral shell worm ethyl ester according to claim 1, it is characterized in that, the content sum of the first active component and the second active component is 6% ~ 70% of described composition total weight.
4. the Pesticidal combination of fluorine-containing pyridine worm amine nitrile and spiral shell worm ethyl ester according to claim 1, is characterized in that described combination dosage form is suspending agent, water dispersible granules, wetting powder or dispersibles oil-suspending agent.
5. according to claim 1 fluorine-containing pyridine worm amine nitrile and spiral shell worm ethyl ester Pesticidal combination control agricultural production on pear sucker, scale insect, aphid, trialeurodes vaporariorum purposes.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410104206.9A CN103828827B (en) | 2014-03-20 | 2014-03-20 | Insecticidal composition containing sulfoxaflor and spirotetramat |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410104206.9A CN103828827B (en) | 2014-03-20 | 2014-03-20 | Insecticidal composition containing sulfoxaflor and spirotetramat |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103828827A CN103828827A (en) | 2014-06-04 |
| CN103828827B true CN103828827B (en) | 2015-02-04 |
Family
ID=50792979
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410104206.9A Active CN103828827B (en) | 2014-03-20 | 2014-03-20 | Insecticidal composition containing sulfoxaflor and spirotetramat |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103828827B (en) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104054737A (en) * | 2014-06-30 | 2014-09-24 | 海利尔药业集团股份有限公司 | Insecticidal combination containing sulfoxaflor and spirodiclofen |
| CN104054736A (en) * | 2014-06-30 | 2014-09-24 | 海利尔药业集团股份有限公司 | Insecticidal combination containing sulfoxaflor and spirotetramat |
| CN104304301A (en) * | 2014-09-29 | 2015-01-28 | 青岛康合伟业商贸有限公司 | High-efficiency pesticide containing sulfoxaflor, sulfur fluoride oxime ether, dinotefuran and spirotetramat |
| CN104286012A (en) * | 2014-09-30 | 2015-01-21 | 青岛康合伟业商贸有限公司 | Efficient insecticide containing sulfoxaflor, cypermethrin, phoxim and spirotetramat |
| CN104322546A (en) * | 2014-09-30 | 2015-02-04 | 青岛康合伟业商贸有限公司 | High-efficient pesticide containing triazophos, sulfoxaflor, spirotetramat and spinetoram |
| CN106472549A (en) * | 2015-08-27 | 2017-03-08 | 江苏龙灯化学有限公司 | A kind of Pesticidal combination |
| CN106937574A (en) * | 2017-02-17 | 2017-07-11 | 中国农业科学院棉花研究所 | A kind of prevention and controls of fleahopper |
| CN107494602A (en) * | 2017-07-25 | 2017-12-22 | 戴润平 | A kind of insecticide for preventing and treating citrus sucking pest |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102077835A (en) * | 2011-03-10 | 2011-06-01 | 陕西汤普森生物科技有限公司 | Insecticidal composition containing sulfoxaflor |
| WO2011104087A1 (en) * | 2010-02-25 | 2011-09-01 | Syngenta Participations Ag | Pesticidal mixtures containing isoxazoline derivatives and insecticide or nematoicidal biological agent |
-
2014
- 2014-03-20 CN CN201410104206.9A patent/CN103828827B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2011104087A1 (en) * | 2010-02-25 | 2011-09-01 | Syngenta Participations Ag | Pesticidal mixtures containing isoxazoline derivatives and insecticide or nematoicidal biological agent |
| CN102077835A (en) * | 2011-03-10 | 2011-06-01 | 陕西汤普森生物科技有限公司 | Insecticidal composition containing sulfoxaflor |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103828827A (en) | 2014-06-04 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103828827B (en) | Insecticidal composition containing sulfoxaflor and spirotetramat | |
| CN103355314A (en) | Acaricidal composition containing pyriminostrobin and etoxazole | |
| CN103271073B (en) | Insecticidal composition containing epoxy worm moiety and buprofezin | |
| CN102246799A (en) | Insecticidal composition containing spinetoram | |
| CN102405914B (en) | Synergistic mite killing composition containing cyflumetofen and clofentezine | |
| CN102017964B (en) | Insecticidal composite containing sulfoxaflor and paichongding (ipp) | |
| CN103493831B (en) | A kind of Pesticidal combination containing phonetic mite amine and tetronic acid insecticides | |
| CN103271074B (en) | Insecticide composition containing cycolxylidin and pymetrozine | |
| CN103329914B (en) | Acaricidal composition containing pyriminostrobin and bifenazate | |
| CN102919251B (en) | Bactericidal composition containing benthiavalicarb isopropyl and captan | |
| CN102484994B (en) | Synergy composition of matrine and chlorantraniliprole | |
| CN103858920A (en) | Spinetoram-containing insecticidal composition | |
| CN103314986B (en) | Cycloxaprid and spirotetramat-containing insecticidal composition | |
| CN103283770B (en) | Insecticidal composition containing cycolxylidin and metaflumizone | |
| CN103444761B (en) | Cycolxylidin-containing pesticidal composition | |
| CN103548832B (en) | Acaricidal composition containing pyriminostrobin and cyflumetofen | |
| CN103300047B (en) | Insecticidal composition containing cycolxylidin and tolfenpyrad | |
| CN103444725B (en) | A kind of miticide composition containing phonetic mite amine and clofentezine | |
| CN103380779B (en) | A kind of Pesticidal combination containing cycolxylidin and biological source insecticide | |
| CN103891749A (en) | Insecticidal combination containing sulfoxaflore and metaflumizone | |
| CN104430490A (en) | Bactericidal composition containing oxalate diacetone amine copper | |
| CN103548863B (en) | Insecticidal composition containing pyriminostrobin and hexythiazox | |
| CN104397019B (en) | Bactericidal composition containing boscalid and sulfur | |
| CN103444764B (en) | A kind of Pesticidal combination containing cycolxylidin | |
| CN105410026A (en) | Insecticidal composition for controlling whiteflies, and use thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant |