CN103548863B - Insecticidal composition containing pyriminostrobin and hexythiazox - Google Patents
Insecticidal composition containing pyriminostrobin and hexythiazox Download PDFInfo
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- CN103548863B CN103548863B CN201310580262.5A CN201310580262A CN103548863B CN 103548863 B CN103548863 B CN 103548863B CN 201310580262 A CN201310580262 A CN 201310580262A CN 103548863 B CN103548863 B CN 103548863B
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Abstract
The invention discloses an insecticidal composition containing pyriminostrobin and hexythiazox. The insecticidal composition is characterized in that the active ingredients of the insecticidal composition are pyriminostrobin and hexythiazox; the weight ratio of pyriminostrobin to hexythiazox is (1:5)-(10:1). The composition can be prepared into the dosage forms such as suspension concentrates, wettable powder, water dispersible granules, dispersible oil suspension concentrates, microemulsion or emulsifiable concentrates. The insecticidal composition has the advantages that the insecticidal composition has reasonable components and good acaricidal effects; the activity and acaricidal effects of the insecticidal composition are not simple superposition of the activities of the components; compared with existing single preparations, the insecticidal composition has obvious synergistic effects besides obvious insecticidal effects, has good safety to crops and has obvious control effects on Panonychus citfi McGregor, Panonychus ulmi or Tetranychus cinnabarinnum Boisduval.
Description
Technical field
The present invention relates to a kind of Pesticidal combination, its active component is phonetic mite amine and Hexythiazox, belongs to technical field of compounded pesticide.
Background technology
Harmful mite in agricultural production is also two spotted spider mite, yellow spider etc., belongs to arachnids Acarina.The crop such as main harm oranges and tangerines, apple, cotton, vegetables, wheat, evil mite be gathered in vacuum side of blade more, with adult, nymph with mouthpart thrust in leaf suck juice harm.When evil mite occurs, preventing and treating with miticide is the most effective means, Avermectin, pyridaben, propargite, fenbutatin oxide etc. are mainly contained at present at the medicament of Ministry of Agriculture's registration control Agricultural Mites, evil mite produces resistance to it, in the urgent need to developing a kind of agricultural chemicals effectively can preventing and treating harmful mite and safety nuisance free.
Phonetic mite amine, English common name: pyriminostrobin, its structural formula is as follows:
Phonetic mite amine is methoxy acrylic miticide, has bactericidal activity simultaneously, if all have greater activity to one-tenth mite mite, ovum, quick-acting is good, and lasting effect is general.As a kind of new miticide, in use there is resistance risk in phonetic mite amine.
Hexythiazox, has another name called hexythiazox, English common name: hexythiazox, chemical name: 5-(4-chlorphenyl)-3-(N-cyclohexyl carboxyamide)-4-methylthiazol alkane-2-ketone.Hexythiazox is the novel miticide of thiazolidine ketone, has good penetrability to plant epidermis layer, but without Uptake and translocation effect.If have strong ovicidal to various plants evil mite, kill the characteristic of children mite, the longevity of residure is long.Hexythiazox should use when becoming mite negligible amounts, if when mite evil occurs serious, should not be used alone.
Inventor does not also find that there is through retrieval the bibliographical information being used for phonetic mite amine and Hexythiazox mixture to prevent and treat Agricultural Mites, find phonetic mite amine and Hexythiazox mixture to use have good control efficiency to Agricultural Mites by lot of experiments, have the advantages that quick-acting is good, the lasting period is long, there is significant synergistic effect, have received beyond thought effect, can use cost be reduced, effectively solve the problem of control of pest mite difficulty.
Summary of the invention
The object of the present invention is to provide a kind of component reasonable, remarkable synergy, good disinsection effect, the Pesticidal combination containing phonetic mite amine and Hexythiazox that drug cost is low.
Another object of the present invention is to provide the application of the Pesticidal combination containing phonetic mite amine and Hexythiazox.
In order to overcome the defect of existing unitary agent, technical scheme of the present invention solves like this:
A kind of Pesticidal combination containing phonetic mite amine and Hexythiazox, its Pesticidal combination active component is phonetic mite amine and Hexythiazox, and the weight ratio of phonetic mite amine and Hexythiazox is 1:5 ~ 10:1, is preferably 1:3 ~ 5:1, be more preferably 1:2 ~ 3:1, most preferably be 1:1 ~ 3:1.
In above-mentioned composition, the content sum of phonetic mite amine and Hexythiazox is 5% ~ 60% of described composition total weight.
The formulation that above-mentioned composition can be prepared is suspending agent, wetting powder, water dispersible granules, dispersible oil-suspending agent, microemulsion or missible oil.
Above-mentioned composition can be used for preventing and treating Agricultural Mites, and described Agricultural Mites is citrus red mite, European red mite or cotton red spider.
To suspending agent, spendable auxiliary agent has: dispersant such as polycarboxylate, lignosulfonates, alkylnaphthalene sulfonate, Huntsman Corporation of TERSPERSE 2020(U.S. HUNTSMAN produce, alkyl naphthalene sulfonic acid salt) in one or more; Emulsifier is as Nongru-700 #(common name: alkyl phenol formaldehyde resin polyoxyethylene ether), this dish-60#(common name: sorbitan monostearate), Tween-60 #(common name: sorbitan monostearate APEO), agriculture breast 1601#(common name: phenethyl phenol polyoxyethylene poly-oxygen propylene aether), one or more in TERSPERSE 4894; Wetting agent as in alkylphenol-polyethenoxy base ether formaldehyde condensation products sulphate, alkylphenol-polyethenoxy base ether phosphate, phenethyl phenol polyethenoxy base ether phosphate, alkyl sulfate, alkylsulfonate, naphthalene sulfonate, TERSPERSE 2500 one or more; Thickener as in xanthans, polyvinyl alcohol, bentonite, aluminium-magnesium silicate one or more; Preservative as in formaldehyde, benzoic acid, Sodium Benzoate one or more; Defoamer is as organic silicon defoamer; Antifreezing agent as ethylene glycol, propane diols, glycerine, urea, inorganic salts as in sodium chloride one or more.
To wetting powder, spendable auxiliary agent has: dispersant as in polycarboxylate (TERSPERSE 2700, T36, GY-D06 etc.), lignosulfonates, alkylnaphthalene sulfonate one or more; Wetting agent as in alkyl sulfate, alkylsulfonate, naphthalene sulfonate one or more; Filler as ammonium sulfate, urea, sucrose, glucose, diatomite, kaolin, white carbon, precipitated calcium carbonate, imvite, talcum powder, attapulgite, potter's clay sodium sulphate, sodium polyphosphate one or more.
For water dispersible granules, those skilled in the art are familiar with the corresponding auxiliary agent of use and complete the present invention very much.Dispersant as in polycarboxylate (TERSPERSE 2700, T36, GY-D06 etc.), lignosulfonates, alkylnaphthalene sulfonate one or more; Wetting agent as in alkyl sulfate, alkylsulfonate, naphthalene sulfonate one or more; Disintegrant as in ammonium sulfate, sodium sulphate, polyvinylpyrrolidone, starch and derivative thereof, bentonite one or more; Binding agent is as one or more in starch, glucose, polyvinyl alcohol, polyethylene glycol, sodium carboxymethylcellulose, sucrose; Filler as diatomite, kaolin, white carbon, fine particle calcium carbonate, talcum powder, attapulgite, potter's clay one or more.
To dispersibling oil-suspending agent, spendable auxiliary agent has: dispersant such as polycarboxylate, lignosulfonates, alkylnaphthalene sulfonate (dispersing agent NNO), Huntsman Corporation of TERSPERSE 2020(U.S. HUNTSMAN produce, alkyl naphthalene sulfonic acid salt) in one or more; Emulsifier is as BY(castor oil polyoxyethylene ether) serial emulsifier (BY-110, BY-125, BY-140), Nongru-700 #(common name: alkyl phenol formaldehyde resin polyoxyethylene ether), agriculture breast 2201, this dish-60#(common name: sorbitan monostearate), Tween-60 #(common name: sorbitan monostearate APEO), agriculture breast 1601#(common name: phenethyl phenol polyoxyethylene poly-oxygen propylene aether), one or more in TERSPERSE 4894; Wetting agent as in alkylphenol-polyethenoxy base ether formaldehyde condensation products sulphate, alkylphenol polyoxyethylene phosphate, phenethyl phenol polyethenoxy base ether phosphate, alkyl sulfate, alkylsulfonate, naphthalene sulfonate, TERSPERSE 2500 one or more; Thickener as in white carbon, polyvinyl alcohol, bentonite, aluminium-magnesium silicate one or more; Antifreezing agent as ethylene glycol, propane diols, glycerine, urea, inorganic salts as in sodium chloride one or more; Dispersion medium as in soybean oil, rapeseed oil, corn oil, methyl oleate, diesel oil, machine oil, mineral oil one or more.
To microemulsion, spendable auxiliary agent has: emulsifier is as calcium dodecyl benzene sulfonate (agriculture breast 500#), Nongru-700 #(common name: alkyl phenol formaldehyde resin polyoxyethylene ether), agriculture breast 2201#, this dish-60#(common name: sorbitan monostearate), Tween-60 #(common name: sorbitan monostearate APEO), TX-10(common name: octyl phenol polyoxyethylene (10) ether), agriculture breast 1601(common name: phenethyl phenol polyoxyethylene poly-oxygen propylene aether), in agriculture breast 600#, agriculture breast 400# one or more; Assistant for emulsifying agent as in methyl alcohol, isopropyl alcohol, n-butanol, ethanol one or more; Solvent as cyclohexanone, 1-METHYLPYRROLIDONE, dimethylbenzene, toluene, solvent naphtha (trade mark: S-150, S-180, S-200) one or more; Water is deionized water.
For missible oil, spendable auxiliary agent has: emulsifier is as calcium dodecyl benzene sulfonate (agriculture breast 500#), Nongru-700 #(common name: alkyl phenol formaldehyde resin polyoxyethylene ether), agriculture breast 2201#, Span-60#(common name: sorbitan monostearate), emulsifier T-60(common name: sorbitan monostearate APEO), TX-10(common name: octyl phenol polyoxyethylene (10) ether), agriculture breast 1601#(common name: phenethyl phenol polyoxyethylene poly-oxygen propylene aether), in agriculture breast 600#, agriculture breast 400# one or more; Solvent is as dimethylbenzene, solvent naphtha (S-150, S-180, S-200), toluene, biodiesel, methylated vegetable oil; Cosolvent: in ethyl acetate, methyl alcohol, dimethyl formamide, cyclohexanone, acetone, MEK one or more.
Instant component is reasonable, and miticidal effect is good, and drug cost is low, and its activity and insecticidal effect are not the simple superposition of each composition activity, but has significant synergistic effect, good to crop safety, meets the security requirement of pesticidal preparations.The present invention has good control efficiency to all kinds of harmful mite in agricultural production.
Embodiment
In order to prevent and treat the harmful mite in agricultural production, inventor has carried out mutual composite synergy with phonetic mite amine and Hexythiazox and has studied.Concrete grammar is:
Subjects be citrus red mite (
panonychus citfimcGregor), European red mite (
panonychus ulmi), cotton red spider (Tetranychus cinnabarinnum Boisduval).Former medicine is mixed with the test medicine of needs, test method is with reference to " People's Republic of China (PRC) agricultural industry criteria NY/T1154.13-2008 ".First single dose and each Mixed Pharmacy are arranged 5 variable concentrations gradients (on the basis of preliminary experiment result, two spotted spider mite lethality sets by geometric progression in the scope of 5% ~ 90%).Examination worm is the two spotted spider mite of picking up from field, if select the mite of uniformity in the length of time in laboratory, put into blade-carrying culture dish, 40, every ware, often process 4 culture dishes, repeat 3 times, spray under 50PSI pressure with potter spray tower, each spray ware, every ware spraying liquid 3ml, then the culture dish processed is put into 12H/12H illumination box to cultivate, within 48 hours, check dead borer population, calculate lethality.Blank spray equivalent clear water
,calculate lethality.By the linear regression analysis between the probit value of lethality and the logarithm value of series concentration, obtain the LC of each medicament
50value, calculates the co-toxicity coefficient (CTC) of mixture by the abundant method of Sun Yun, evaluate the activity of reagent agent to examination worm with this.
The co-toxicity coefficient (CTC) >=120 of complex preparation shows as synergistic effect; CTC≤80 show as antagonism; 80 < CTC < 120 show as summation action.
Toxicity Determination result shows: phonetic mite amine and Hexythiazox are that 1:5 ~ 10:1 is mixed with weight ratio all has good virulence to citrus red mite, European red mite, cotton red spider, has significant synergistic effect.
Below in conjunction with embodiment, the invention will be further described.
Example of formulations 1
Take 10% phonetic mite amine, 3% Hexythiazox, 2.5% Huntsman Corporation of the TERSPERSE 4894(U.S. produce), 2% Huntsman Corporation of the TERSPERSE 2500(U.S. produces), 0.5% xanthans, 5% propane diols, 0.5% benzoic acid, 0.5% silicone defoaming agent (trade name: s-29, Nanjing "four news" (new ideas applied chemistry product Company), deionized water add to 100% weight portion.Above-mentioned raw materials is through mixing, and high speed shear dispersion 30min, with 13% phonetic mite amine hexythiazox suspension agent obtained after sand mill sand milling.
Example of formulations 2
Take 12.5% phonetic mite amine, 2.5% Hexythiazox, 4% this dish-60#, 3% agriculture breast 1601#, 2% alkylphenol-polyethenoxy base ether phosphate, 1% Huntsman Corporation of the TERSPERSE 2020(U.S. produce), 0.2% polyvinyl alcohol, 5% ethylene glycol, 0.5% Sodium Benzoate, 0.5% silicone defoaming agent, deionized water add to 100% weight portion.Above-mentioned raw materials is through mixing, and high speed shear dispersion 30min, with 15% phonetic mite amine hexythiazox suspension agent obtained after sand mill sand milling.
Example of formulations 3
Take 2% phonetic mite amine, 10% Hexythiazox, 4%GY-D06,3% dispersing agent NNO (alkylnaphthalene sulfonate formaldehyde condensation products), 1% lauryl sodium sulfate, 3% white carbon, 3% sodium polyphosphate, kaolin fill up weight portion to 100%.Above-mentioned raw materials is through mixing, the obtained 12% phonetic mite amine Hexythiazox wetting powder of ultra micro air-flow crushing, hybrid technique step.
Example of formulations 4
Take 15% phonetic mite amine, 5% Hexythiazox, 4% calcium lignosulfonate, 3% dispersing agent NNO, 1.5% lauryl sodium sulfate, 5% potter's clay sodium sulphate, fine particle calcium carbonate fill up weight portion to 100%.Above-mentioned raw materials is prepared into 20% phonetic mite amine Hexythiazox wetting powder through mixing, ultra micro air-flow crushing, hybrid technique step.
Example of formulations 5
Take 50% phonetic mite amine, 10% Hexythiazox, 4% GY-D06(polycarboxylate), 3% dispersing agent NNO, 2% Nekal BX (nekal), 2% K-12(lauryl sodium sulfate), 3% diatomite, 5% bentonite, attapulgite add to 100% weight portion.Namely the method for above-mentioned raw materials frequent regulation water intaking dispersible granule mixes, ultra micro air-flow crushing, mixing, granulation step produce 60% phonetic mite amine Hexythiazox water dispersible granules.
Example of formulations 6
Take 5% phonetic mite amine, 10% Hexythiazox, 2% TERSPERSE 2700(polycarboxylate, Huntsman Corporation of the U.S. produces), 2% sodium lignin sulfonate, 3% Nekal BX, 2%K-12,3%PVA(molecular weight 2000), 2% polyvinylpyrrolidone, kaolin adds to 100% weight portion.Namely the method for above-mentioned raw materials frequent regulation water intaking dispersible granule mixes, ultra micro air-flow crushing, mixing, granulation step produce 15% phonetic mite amine Hexythiazox water dispersible granules.
Example of formulations 7
Take 2% phonetic mite amine, 6% Hexythiazox, this dish of 2%TERSPERSE 2020,4%-60#, 3% agriculture breast 2201#, 4% Nongru-700 #, 1%TERSPERSE 2500,0.5% white carbon, 5% propane diols, methyl oleate add to 100% weight portion.Above-mentioned raw materials is through mixing, and high speed shear dispersion 30min, dispersibles oil-suspending agent with 8% phonetic mite amine Hexythiazox obtained after sand mill sand milling.
Example of formulations 8
Take 10% phonetic mite amine, 5% Hexythiazox, 2% dispersing agent NNO, 3% agriculture breast 2201#, 3% Tween-60 #, 10% BY-110,1%TERSPERSE 2500,1% aluminium-magnesium silicate, 5% glycerine, soybean oil add to 100% weight portion.Above-mentioned raw materials is through mixing, and high speed shear dispersion 30min, dispersibles oil-suspending agent with 15% phonetic mite amine Hexythiazox obtained after sand mill sand milling.
Example of formulations 9
Take 3% phonetic mite amine, 2% Hexythiazox, 4%TX-10,5% Nongru-700 #, 6% agriculture breast 500#, agriculture breast 2201#, 5% cyclohexanone, 5%N-methyl pyrrolidone, 5% n-butanol, through dissolving completely and mixing, deionized water adds to 100% weight portion, obtained 5% phonetic mite amine hexythiazox micro-emulsion after stirring.
Example of formulations 10
Take 5% phonetic mite amine, 5% Hexythiazox, 5% this dish-60#, 3% agriculture breast 500#, 6% agriculture breast 600#, 5% dimethylbenzene, 20% cyclohexanone, 5% ethanol, through dissolving completely and mixing, deionized water adds to 100% weight portion, obtained 10% phonetic mite amine hexythiazox micro-emulsion after stirring.
Example of formulations 11
Take 20% phonetic mite amine, 2% Hexythiazox, 5% agriculture breast 500#, 2% agriculture breast 400#, 3% Nongru-700 #, 10% dimethyl formamide, dimethylbenzene adds to 100% weight portion.Above-mentioned raw materials is through mixing, and stirring and dissolving is obtained 22% phonetic mite amine Hexythiazox missible oil completely afterwards.
Example of formulations 12
Take 7.5% phonetic mite amine, 2.5% Hexythiazox, 5% agriculture breast 500#, 3% agriculture breast 400#, 3% agriculture breast 600#, 25% cyclohexanone, dimethylbenzene adds to 100% weight portion.Above-mentioned raw materials is through mixing, and stirring and dissolving is obtained 10% phonetic mite amine Hexythiazox missible oil completely afterwards.
Biological Examples: control European red mite field trial
Inventor has carried out example of formulations 2(15% phonetic mite amine hexythiazox suspension agent in April, 2013 in Liquan County, Shaanxi Province) prevent and treat the field control effectiveness test of European red mite, demonstrate this medicament to the control efficiency of European red mite, effective dose and the safety to apple.Test medicine and extension rate refer to table 4, separately establish blank.Often process and repeat for 4 times, every plot area 5 tree, Gong24Ge community, random district group arranges.Manual sprayer is adopted evenly to spray.Borer population investigation is respectively once remained respectively at before medicine, after medicine 1 day, 7 days, 14 days.2 trees are looked in every community, and every tree looks into 5 leaves respectively by orientation, 4, the four corners of the world, and every community looks into 40 leaves altogether, record mite number of living, carry out control efficiency statistics.Simultaneously viewing test medicament is on the impact of other insect with produce with or without poisoning apple.
Computational methods:
Control efficiency (%)=[1-(before the medicine of check plot after borer population × treatment region medicine borer population)/(before borer population after the medicine of check plot × treatment region medicine borer population)] × 100.
Result of the test shows, 15% phonetic mite amine hexythiazox suspension agent 2000 times, 2500 times, 3000 times have good control efficiency to European red mite, after medicine, the preventive effect of 1,7,14 day is all more than 90.8%, show excellent quick-acting and lasting effect, be obviously better than the control efficiency (table 4) of 10% phonetic mite amine suspending agent 1000 times, 5% Hexythiazox missible oil 1500 times.
Security survey, duration of test is observed, and all reagent agents, to Apple Leaves, tender tip growth safety, occur without poisoning phenomenon.
Result of the test shows, after phonetic mite amine and Hexythiazox mixture, significantly improves the control efficiency to European red mite, and synergistic effect is obvious, shows excellent quick-acting and lasting period, reduces dosage, saved drug cost, to apple development safety.
In sum, composition of the present invention is employing two kinds of active component compound schemes, its activity and insecticidal effect are not the simple superposition of each composition activity, compared with existing unitary agent, except there is significant insecticidal effect, and have significant synergistic effect, and good to crop safety, meet the security requirement of pesticidal preparations.
Claims (10)
1. contain a Pesticidal combination for phonetic mite amine and Hexythiazox, it is characterized in that each constituent content is: 10% phonetic mite amine, 3% Hexythiazox, 2.5% TERSPERSE 4894,2% TERSPERSE 2500,0.5% xanthans, 5% propane diols, 0.5% benzoic acid, 0.5% silicone defoaming agent, deionized water add to 100% weight portion.
2. contain a Pesticidal combination for phonetic mite amine and Hexythiazox, it is characterized in that each constituent content is: 12.5% phonetic mite amine, 2.5% Hexythiazox, 4% this dish-60#, 3% agriculture breast 1601#, 2% alkylphenol-polyethenoxy base ether phosphate, 1% TERSPERSE 2020,0.2% polyvinyl alcohol, 5% ethylene glycol, 0.5% Sodium Benzoate, 0.5% silicone defoaming agent, deionized water add to 100% weight portion.
3. contain a Pesticidal combination for phonetic mite amine and Hexythiazox, it is characterized in that each constituent content is: 2% phonetic mite amine, 10% Hexythiazox, 4%GY-D06,3% dispersing agent NNO, 1% lauryl sodium sulfate, 3% white carbon, 3% sodium polyphosphate, kaolin fill up the weight portion to 100%.
4. contain a Pesticidal combination for phonetic mite amine and Hexythiazox, it is characterized in that each constituent content is: 15% phonetic mite amine, 5% Hexythiazox, 4% calcium lignosulfonate, 3% dispersing agent NNO, 1.5% lauryl sodium sulfate, 5% potter's clay sodium sulphate, fine particle calcium carbonate fill up the weight portion to 100%.
5. contain a Pesticidal combination for phonetic mite amine and Hexythiazox, it is characterized in that each constituent content is: 50% phonetic mite amine, 10% Hexythiazox, 4% GY-D06,3% dispersing agent NNO, 2% Nekal BX, 2% K-12,3% diatomite, 5% bentonite, attapulgite add to 100% weight portion.
6. contain a Pesticidal combination for phonetic mite amine and Hexythiazox, it is characterized in that each constituent content is: 5% phonetic mite amine, 10% Hexythiazox, 2% TERSPERSE 2700,2% sodium lignin sulfonate, 3% Nekal BX, 2%K-12,3%PVA, 2% polyvinylpyrrolidone, kaolin add to 100% weight portion.
7. containing a Pesticidal combination for phonetic mite amine and Hexythiazox, it is characterized in that each constituent content is: this dish of 2% phonetic mite amine, 6% Hexythiazox, 2%TERSPERSE 2020,4%-60#, 3% agriculture breast 2201#, 4% Nongru-700 #, 1%TERSPERSE 2500,0.5% white carbon, 5% propane diols, methyl oleate add to 100% weight portion.
8. containing a Pesticidal combination for phonetic mite amine and Hexythiazox, it is characterized in that each constituent content is: 10% phonetic mite amine, 5% Hexythiazox, 2% dispersing agent NNO, 3% agriculture breast 2201#, 3% Tween-60 #, 10% BY-110,1%TERSPERSE 2500,1% aluminium-magnesium silicate, 5% glycerine, soybean oil add to 100% weight portion.
9. one kind contains the Pesticidal combination of phonetic mite amine and Hexythiazox, it is characterized in that each constituent content is: 3% phonetic mite amine, 2% Hexythiazox, 4%TX-10,5% Nongru-700 #, 6% agriculture breast 500#, agriculture breast 2201#, 5% cyclohexanone, 5%N-methyl pyrrolidone, 5% n-butanol, through dissolving completely and mixing, deionized water adds to 100% weight portion, obtained 5% phonetic mite amine hexythiazox micro-emulsion after stirring.
10. one kind contains the Pesticidal combination of phonetic mite amine and Hexythiazox, it is characterized in that each constituent content is: 5% phonetic mite amine, 5% Hexythiazox, 5% this dish-60#, 3% agriculture breast 500#, 6% agriculture breast 600#, 5% dimethylbenzene, 20% cyclohexanone, 5% ethanol, through dissolving completely and mixing, deionized water adds to 100% weight portion, obtained 10% phonetic mite amine hexythiazox micro-emulsion after stirring.
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| CN103518764A (en) * | 2012-07-02 | 2014-01-22 | 中国中化股份有限公司 | Acaricidal composition and application thereof |
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| CN103518764A (en) * | 2012-07-02 | 2014-01-22 | 中国中化股份有限公司 | Acaricidal composition and application thereof |
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