CN103563968B - A kind of containing phonetic mite amine and the acaricidal miticide composition of organic tin - Google Patents
A kind of containing phonetic mite amine and the acaricidal miticide composition of organic tin Download PDFInfo
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- CN103563968B CN103563968B CN201310556023.6A CN201310556023A CN103563968B CN 103563968 B CN103563968 B CN 103563968B CN 201310556023 A CN201310556023 A CN 201310556023A CN 103563968 B CN103563968 B CN 103563968B
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Abstract
The invention discloses a kind of containing phonetic mite amine and the acaricidal miticide composition of organic tin, its effective active composition is phonetic mite amine and organic tin miticide, and phonetic mite amine and the acaricidal weight ratio of organic tin are 1:8 ~ 5:1.This composition can be mixed with agriculturally allow suspending agent, wetting powder, water dispersible granules, dispersible oil-suspending agent or missible oil formulation.Instant component is reasonable, and miticidal effect is good, and its activity and miticidal effect are not the simple superposition of each composition activity, compared with existing unitary agent, except having significant insecticidal effect, and have significant synergistic effect, good to crop safety.The present invention has significant control efficiency to citrus red mite, European red mite, cotton red spider.
Description
Technical field
The present invention relates to a kind of miticide composition, its active component is phonetic mite amine and organic tin miticide fenbutatin oxide or azacyclotin, belongs to technical field of compounded pesticide.
Background technology
Harmful mite in agricultural production is also two spotted spider mite, yellow spider etc., belongs to arachnids Acarina.The crop such as main harm oranges and tangerines, apple, cotton, vegetables, wheat, evil mite be gathered in vacuum side of blade more, with adult, nymph with mouthpart thrust in leaf suck juice harm.When evil mite occurs, preventing and treating with miticide is the most effective means, Avermectin, pyridaben, propargite, fenbutatin oxide etc. are mainly contained at present at the medicament of Ministry of Agriculture's registration control Agricultural Mites, evil mite produces resistance to it, in the urgent need to inventing a kind of agricultural chemicals effectively can preventing and treating harmful mite and safety nuisance free.
Phonetic mite amine, English common name: pyriminostrobin, its structural formula is as follows:
Phonetic mite amine is methoxy acrylic miticide, has bactericidal activity simultaneously, if all have greater activity to one-tenth mite mite, ovum, quick-acting is good, and lasting effect is general.As a kind of new miticide, in use there is resistance risk in phonetic mite amine, and rationally uses with from the miticide of the different mechanism of action, for fully effectively promoting phonetic mite amine, extending its service life and having important function.
Organic tin miticide mainly based on action of contace poison, has quick-acting general to evil mite, the feature that the longevity of residure is long.This kind of miticide mainly contains 3 kinds at present: fenbutatin oxide, azacyclotin, three phosphor tins.Three phosphor tins are poor not multiplex to crop safety because of it.
Fenbutatin oxide, chemical name: two [three 2-methylphenyl propyl group) tin] oxide, English common name fenbutatinoxide.Fenbutatin oxide is to evil mite to tag, and after spray medicine, initial virulence is slow, and after 3 days, activity starts to increase, and peaks by 14 days.This medicine longevity of residure is one longer in miticide, 2-5 month can be reached, if to young mite with to become the lethality of mite comparatively strong, but little to the lethality of ovum, use all very safe each vegetative period crop, as very little in impacts such as Predatory Mites, wooden dipper first and Chrysopas on evil mite natural enemy.
Azacyclotin, chemical name: 1-(three cyclohexyl stannyls)-1-hydrogen-1,2,4-triazole, English common name azocyclotin.For the broad spectrum activity miticide that action of contace poison is stronger.If mite can be killed, become mite and summer egg.Have good stability to light and rainwater, the longevity of residure is longer.To crop safety under typical concentrations.
Inventor does not find that there is through retrieval the bibliographical information being used for phonetic mite amine and organic tin miticide fenbutatin oxide, azacyclotin mixture to prevent and treat Agricultural Mites, find that phonetic mite amine is had good control efficiency with fenbutatin oxide, the use of azacyclotin mixture to Agricultural Mites respectively by lot of experiments, have the advantages that quick-acting is good, the lasting period is long, there is significant synergistic effect, have received beyond thought effect, can use cost be reduced, effectively solve the problem of control of pest mite difficulty.
Summary of the invention
The object of the present invention is to provide a kind of component reasonable, remarkable synergy, miticidal effect is good, the phonetic mite amine that drug cost is low and the acaricidal miticide composition of organic tin.
Another object of the present invention is to provide and preventing and treating the application in Agricultural Mites containing phonetic mite amine and the acaricidal miticide composition of organic tin.
In order to overcome the defect of existing unitary agent, technical scheme of the present invention solves like this:
A kind of containing phonetic mite amine and the acaricidal miticide composition of organic tin, composition active component is phonetic mite amine and organic tin miticide fenbutatin oxide or azacyclotin, phonetic mite amine and the acaricidal weight ratio of organic tin are 1:8 ~ 5:1, be preferably 1:5 ~ 3:1, be more preferably 1:3 ~ 2:1, most preferably be 1:2 ~ 1:1.
Above-mentioned phonetic mite amine and organic tin acaricidal content sum are 8% ~ 70% of described composition total weight, and described combination dosage form is suspending agent, wetting powder, water dispersible granules, dispersible oil-suspending agent or missible oil.
Above-mentionedly can be used for preventing and treating Agricultural Mites containing phonetic mite amine and the acaricidal miticide composition of organic tin, described Agricultural Mites is citrus red mite, European red mite or cotton red spider.
To suspending agent, spendable auxiliary agent has: dispersant such as polycarboxylate, lignosulfonates, alkylnaphthalene sulfonate, Huntsman Corporation of TERSPERSE2020(U.S. HUNTSMAN produce, alkyl naphthalene sulfonic acid salt) in one or more; Emulsifier is as Nongru-700 #(common name: alkyl phenol formaldehyde resin polyoxyethylene ether), this dish-60#(common name: sorbitan monostearate), Tween-60 #(common name: sorbitan monostearate APEO), agriculture breast 1601#(common name: phenethyl phenol polyoxyethylene poly-oxygen propylene aether), one or more in TERSPERSE4894; Wetting agent as in alkylphenol-polyethenoxy base ether formaldehyde condensation products sulphate, alkylphenol-polyethenoxy base ether phosphate, phenethyl phenol polyethenoxy base ether phosphate, alkyl sulfate, alkylsulfonate, naphthalene sulfonate, TERSPERSE2500 one or more; Thickener as in xanthans, polyvinyl alcohol, bentonite, aluminium-magnesium silicate one or more; Preservative as in formaldehyde, benzoic acid, Sodium Benzoate one or more; Defoamer is as organic silicon defoamer; Antifreezing agent as ethylene glycol, propane diols, glycerine, urea, inorganic salts as in sodium chloride one or more.
To wetting powder, spendable auxiliary agent has: dispersant as in polycarboxylate (TERSPERSE2700, T36, GY-D06 etc.), lignosulfonates, alkylnaphthalene sulfonate one or more; Wetting agent as in alkyl sulfate, alkylsulfonate, naphthalene sulfonate one or more; Filler as ammonium sulfate, urea, sucrose, glucose, diatomite, kaolin, white carbon, precipitated calcium carbonate, imvite, talcum powder, attapulgite, potter's clay sodium sulphate, sodium polyphosphate one or more.
For water dispersible granules, those skilled in the art are familiar with the corresponding auxiliary agent of use and complete the present invention very much.Dispersant as in polycarboxylate (TERSPERSE2700, T36, GY-D06 etc.), lignosulfonates, alkylnaphthalene sulfonate one or more; Wetting agent as in alkyl sulfate, alkylsulfonate, naphthalene sulfonate one or more; Disintegrant as in ammonium sulfate, sodium sulphate, polyvinylpyrrolidone, starch and derivative thereof, bentonite one or more; Binding agent is as one or more in starch, glucose, polyvinyl alcohol, polyethylene glycol, sodium carboxymethylcellulose, sucrose; Filler as diatomite, kaolin, white carbon, fine particle calcium carbonate, talcum powder, attapulgite, potter's clay one or more.
To dispersibling oil-suspending agent, spendable auxiliary agent has: dispersant such as polycarboxylate, lignosulfonates, alkylnaphthalene sulfonate (dispersing agent NNO), Huntsman Corporation of TERSPERSE2020(U.S. HUNTSMAN produce, alkyl naphthalene sulfonic acid salt) in one or more; Emulsifier is as BY(castor oil polyoxyethylene ether) serial emulsifier (BY-110, BY-125, BY-140), Nongru-700 #(common name: alkyl phenol formaldehyde resin polyoxyethylene ether), agriculture breast 2201, this dish-60#(common name: sorbitan monostearate), Tween-60 #(common name: sorbitan monostearate APEO), agriculture breast 1601#(common name: phenethyl phenol polyoxyethylene poly-oxygen propylene aether), one or more in TERSPERSE4894; Wetting agent as in alkylphenol-polyethenoxy base ether formaldehyde condensation products sulphate, alkylphenol polyoxyethylene phosphate, phenethyl phenol polyethenoxy base ether phosphate, alkyl sulfate, alkylsulfonate, naphthalene sulfonate, TERSPERSE2500 one or more; Thickener as in white carbon, polyvinyl alcohol, bentonite, aluminium-magnesium silicate one or more; Antifreezing agent as ethylene glycol, propane diols, glycerine, urea, inorganic salts as in sodium chloride one or more; Dispersion medium as in soybean oil, rapeseed oil, corn oil, methyl oleate, diesel oil, machine oil, mineral oil one or more.
For missible oil, spendable auxiliary agent has: emulsifier is as calcium dodecyl benzene sulfonate (agriculture breast 500#), Nongru-700 #(common name: alkyl phenol formaldehyde resin polyoxyethylene ether), agriculture breast 2201#, Span-60#(common name: sorbitan monostearate), emulsifier T-60(common name: sorbitan monostearate APEO), TX-10(common name: octyl phenol polyoxyethylene (10) ether), agriculture breast 1601#(common name: phenethyl phenol polyoxyethylene poly-oxygen propylene aether), in agriculture breast 600#, agriculture breast 400# one or more; Solvent is as dimethylbenzene, solvent naphtha (S-150, S-180, S-200), toluene, biodiesel, methylated vegetable oil; Cosolvent: in ethyl acetate, methyl alcohol, dimethyl formamide, cyclohexanone, acetone, MEK one or more.
Instant component is reasonable, and miticidal effect is good, and drug cost is low, and its activity and insecticidal effect are not the simple superposition of each composition activity, but has significant synergistic effect, good to crop safety, meets the security requirement of pesticidal preparations.The present invention has good control efficiency to all kinds of harmful mite in agricultural production.
Embodiment
In order to prevent and treat the harmful mite in agricultural production, inventor has carried out mutual composite synergy respectively with phonetic mite amine and has studied with fenbutatin oxide, azacyclotin.Concrete grammar is:
Subjects be citrus red mite (
panonychuscitfimcGregor), European red mite (
panonychusulmi), cotton red spider (TetranychuscinnabarinnumBoisduval).Former medicine is mixed with the test medicine of needs, test method is with reference to " People's Republic of China (PRC) agricultural industry criteria NY/T1154.13-2008 ".First single dose and each Mixed Pharmacy are arranged 5 variable concentrations gradients (on the basis of preliminary experiment result, two spotted spider mite lethality sets by geometric progression in the scope of 5% ~ 90%).Examination worm is the two spotted spider mite of picking up from field, select the one-tenth mite of uniformity in the length of time in laboratory, put into blade-carrying culture dish, 40, every ware, often process 4 culture dishes, repeat 3 times, spray under 50PSI pressure with potter spray tower, each spray ware, every ware spraying liquid 3ml, then the culture dish processed is put into 12H/12H illumination box to cultivate, within 48 hours, check dead borer population, calculate lethality.Blank spray equivalent clear water
.calculate lethality.By the linear regression analysis between the probit value of lethality and the logarithm value of series concentration, obtain the LC of each medicament
50value, calculates the co-toxicity coefficient (CTC) of mixture by the abundant method of Sun Yun, evaluate the activity of reagent agent to examination worm with this.
The co-toxicity coefficient (CTC) >=120 of complex preparation shows as synergistic effect; CTC≤80 show as antagonism; 80 < CTC < 120 show as summation action.
Toxicity Determination result shows: phonetic mite amine is that 1:8 ~ 5:1 is mixed respectively with weight ratio with fenbutatin oxide, azacyclotin all has good virulence to citrus red mite, European red mite, cotton red spider, has significant synergistic effect.
Embodiment
Below in conjunction with embodiment, the invention will be further described.
Example of formulations 1
Take 10% phonetic mite amine, 10% fenbutatin oxide, Huntsman Corporation of the 3%TERSPERSE4894(U.S. produce), Huntsman Corporation of the 1%TERSPERSE2500(U.S. produces), 0.3% xanthans, 5% propane diols, 0.5% benzoic acid, 0.5% silicone defoaming agent (trade name: s-29, Nanjing "four news" (new ideas applied chemistry product Company), deionized water add to 100% weight portion.Above-mentioned raw materials is through mixing, and high speed shear dispersion 30min, with 20% phonetic mite amine fenbutatin oxide suspending agent obtained after sand mill sand milling.
Example of formulations 2
Take 10% phonetic mite amine, 30% azacyclotin, 4% this dish-60#, 3% agriculture breast 1601#, 2% alkylphenol-polyethenoxy base ether phosphate, Huntsman Corporation of the 1%TERSPERSE2020(U.S. produce), 0.2% polyvinyl alcohol, 5% ethylene glycol, 0.5% Sodium Benzoate, 0.5% silicone defoaming agent, deionized water add to 100% weight portion.Above-mentioned raw materials is through mixing, and high speed shear dispersion 30min, with 40% phonetic mite amine azocyclotin dispersant obtained after sand mill sand milling.
Example of formulations 3
Take 20% phonetic mite amine, 10% fenbutatin oxide, 4%GY-D06,3% dispersing agent NNO (alkylnaphthalene sulfonate formaldehyde condensation products), 1% lauryl sodium sulfate, 3% white carbon, 3% sodium polyphosphate, kaolin fill up weight portion to 100%.Above-mentioned raw materials is through mixing, the obtained 30% phonetic mite amine fenbutatin oxide wetting powder of ultra micro air-flow crushing, hybrid technique step.
Example of formulations 4
Take 8% phonetic mite amine, 40% azacyclotin, 4% calcium lignosulfonate, 3% dispersing agent NNO, 1.5% lauryl sodium sulfate, 5% potter's clay sodium sulphate, fine particle calcium carbonate fill up weight portion to 100%.Above-mentioned raw materials is prepared into 48% phonetic mite amine azacyclotin wetting powder through mixing, ultra micro air-flow crushing, hybrid technique step.
Example of formulations 5
Take 5% phonetic mite amine, 40% fenbutatin oxide, 4%GY-D06(polycarboxylate), 3% dispersing agent NNO, 2% Nekal BX (nekal), 2%K-12(lauryl sodium sulfate), 5% diatomite, 8% bentonite, attapulgite add to 100% weight portion.Namely the method for above-mentioned raw materials frequent regulation water intaking dispersible granule mixes, ultra micro air-flow crushing, mixing, granulation step produce 45% phonetic mite amine fenbutatin oxide water dispersible granule.
Example of formulations 6
Take 20% phonetic mite amine, 50% azacyclotin, 2%TERSPERSE2700(polycarboxylate, Huntsman Corporation of the U.S. produces), 2% sodium lignin sulfonate, 1% Nekal BX, 1%K-12,1%PVA(molecular weight 2000), 2% polyvinylpyrrolidone, kaolin adds to 100% weight portion.Namely the method for above-mentioned raw materials frequent regulation water intaking dispersible granule mixes, ultra micro air-flow crushing, mixing, granulation step produce 70% phonetic mite amine azocyclotin water dispersible granule.
Example of formulations 7
Take 6% phonetic mite amine, 2% fenbutatin oxide, 2%TERSPERSE2020,4% this dish-60#, 3% Tween-60 #, 4% agriculture breast 2201#, 3% Nongru-700 #, 1%TERSPERSE2500,0.5% white carbon, 5% propane diols, methyl oleate add to 100% weight portion.Above-mentioned raw materials is through mixing, and high speed shear dispersion 30min, dispersibles oil-suspending agent with 8% phonetic mite amine fenbutatin oxide obtained after sand mill sand milling.
Example of formulations 8
Take 25% phonetic mite amine, 5% azacyclotin, 2% dispersing agent NNO, 3% agriculture breast 2201#, 10%BY-110,1%TERSPERSE2500,1% aluminium-magnesium silicate, 3% glycerine, soybean oil add to 100% weight portion.Above-mentioned raw materials is through mixing, and high speed shear dispersion 30min, dispersibles oil-suspending agent with 30% phonetic mite amine azacyclotin obtained after sand mill sand milling.
Example of formulations 9
Take 4% phonetic mite amine, 8% fenbutatin oxide, 5% agriculture breast 500#, 2% agriculture breast 400#, 3% Nongru-700 #, 10% dimethyl formamide, dimethylbenzene adds to 100% weight portion.Above-mentioned raw materials is through mixing, and stirring and dissolving is obtained 12% phonetic mite amine fenbutatin oxide missible oil completely afterwards.
Example of formulations 10
Take 3% phonetic mite amine, 9% azacyclotin, 5% agriculture breast 500#, 3% agriculture breast 400#, 3% agriculture breast 600#, 25% cyclohexanone, dimethylbenzene adds to 100% weight portion.Above-mentioned raw materials is through mixing, and stirring and dissolving is obtained 12% phonetic mite amine azacyclotin missible oil completely afterwards.
Biological Examples: control citrus red mite field trial
Inventor has carried out example of formulations 1(20% phonetic mite amine fenbutatin oxide suspending agent in April, 2013 in Deqing County, Zhaoqing City of Guangdong Province), example of formulations 4(48% phonetic mite amine azacyclotin wetting powder) prevent and treat the field control effectiveness test of citrus red mite, demonstrate this medicament to the control efficiency of citrus red mite, effective dose and the safety to oranges and tangerines.Test medicine and extension rate refer to table 4, separately establish blank.Often process and repeat for 4 times, every plot area 5 tree, Gong40Ge community, random district group arranges.Manual sprayer is adopted evenly to spray.Borer population investigation is respectively once remained respectively at before medicine, after medicine 1 day, 7 days, 14 days.2 trees are looked in every community, and every tree looks into 5 leaves respectively by orientation, 4, the four corners of the world, and every community looks into 40 leaves altogether, record mite number of living, carry out control efficiency statistics.Simultaneously viewing test medicament is on the impact of other insect with produce with or without poisoning oranges and tangerines.
Computational methods:
Control efficiency (%)=[1-(before the medicine of check plot after borer population × treatment region medicine borer population)/(before borer population after the medicine of check plot × treatment region medicine borer population)] × 100.
Result of the test shows, 20% phonetic mite amine fenbutatin oxide suspending agent 2000 times, 2500 times, 3000 times, 48% phonetic mite amine azacyclotin wetting powder 3000 times, 3500 times, 4000 times, good control efficiency is had to citrus red mite, after medicine, the preventive effect of 1,7,14 day is all more than 87.2%, show excellent quick-acting and lasting effect, be obviously better than the control efficiency (table 4) of 10% phonetic mite amine suspending agent 1000 times, 25% fenbutatin oxide suspending agent 1000 times, 25% azacyclotin wetting powder 1000 times.
Security survey, duration of test is observed, and 25% azacyclotin wetting powder 1000 doubly has slight poisoning to the tender tip of oranges and tangerines.Other reagent agent, to Citrus leaf, the tender tip, flower, growth of young safety, occurs without poisoning phenomenon.
Result of the test shows, phonetic mite amine respectively with fenbutatin oxide, azacyclotin mixture after, significantly improve the control efficiency to citrus red mite, synergistic effect is obvious, shows excellent quick-acting and lasting period, reduces dosage, save drug cost, to Ci trus growth safety.
In sum, composition of the present invention is employing two kinds of active component compound schemes, its activity and insecticidal effect are not the simple superposition of each composition activity, compared with existing unitary agent, except there is significant insecticidal effect, and have significant synergistic effect, and good to crop safety, meet the security requirement of pesticidal preparations.
Claims (10)
1. one kind contains phonetic mite amine and the acaricidal miticide composition of organic tin, it is characterized in that composition active component is 10% phonetic mite amine, 10% fenbutatin oxide, 3%TERSPERSE4894,1%TERSPERSE2500,0.3% xanthans, 5% propane diols, 0.5% benzoic acid, 0.5% silicone defoaming agent, deionized water add to 100% weight portion, described silicone defoaming agent commodity are called s-29, Nanjing "four news" (new ideas applied chemistry product Company.
2., containing phonetic mite amine and the acaricidal miticide composition of organic tin, it is characterized in that composition active component is 10% phonetic mite amine, 30% azacyclotin, 4% this dish-60#, 3% agriculture breast 1601#, 2% alkylphenol-polyethenoxy base ether phosphate, 1%TERSPERSE2020,0.2% polyvinyl alcohol, 5% ethylene glycol, 0.5% Sodium Benzoate, 0.5% silicone defoaming agent, deionized water add to 100% weight portion.
3., containing phonetic mite amine and the acaricidal miticide composition of organic tin, it is characterized in that composition active component is 20% phonetic mite amine, 10% fenbutatin oxide, 4% polycarboxylate GY-D06,3% dispersing agent NNO, 1% lauryl sodium sulfate, 3% white carbon, 3% sodium polyphosphate, kaolin fill up weight portion to 100%.
4., containing phonetic mite amine and the acaricidal miticide composition of organic tin, it is characterized in that composition active component is 8% phonetic mite amine, 40% azacyclotin, 4% calcium lignosulfonate, 3% dispersing agent NNO, 1.5% lauryl sodium sulfate, 5% potter's clay sodium sulphate, fine particle calcium carbonate fill up weight portion to 100%.
5. one kind contains phonetic mite amine and the acaricidal miticide composition of organic tin, it is characterized in that composition active component is 5% phonetic mite amine, 40% fenbutatin oxide, 4% polycarboxylate GY-D06,3% dispersing agent NNO, 2% Nekal BX, 2%K-12,5% diatomite, 8% bentonite, attapulgite add to 100% weight portion, described K-12 is lauryl sodium sulfate.
6. one kind contains phonetic mite amine and the acaricidal miticide composition of organic tin, it is characterized in that composition active component is 20% phonetic mite amine, 50% azacyclotin, 2%TERSPERSE2700,2% sodium lignin sulfonate, 1% Nekal BX, 1%K-12, the 1%PVA of molecular weight 2000,2% polyvinylpyrrolidone, kaolin adds to 100% weight portion, described K-12 is lauryl sodium sulfate, and described PVA is polyvinyl alcohol.
7., containing phonetic mite amine and the acaricidal miticide composition of organic tin, it is characterized in that composition active component is 6% phonetic mite amine, 2% fenbutatin oxide, 2%TERSPERSE2020,4% this dish-60#, 3% Tween-60 #, 4% agriculture breast 2201#, 3% Nongru-700 #, 1%TERSPERSE2500,0.5% white carbon, 5% propane diols, methyl oleate add to 100% weight portion.
8., containing phonetic mite amine and the acaricidal miticide composition of organic tin, it is characterized in that composition active component is 25% phonetic mite amine, 5% azacyclotin, 2% dispersing agent NNO, 3% agriculture breast 2201#, 10%BY-110,1%TERSPERSE2500,1% aluminium-magnesium silicate, 3% glycerine, soybean oil add to 100% weight portion.
9., containing phonetic mite amine and the acaricidal miticide composition of organic tin, it is characterized in that composition active component is 4% phonetic mite amine, 8% fenbutatin oxide, 5% agriculture breast 500#, 2% agriculture breast 400#, 3% Nongru-700 #, 10% dimethyl formamide, dimethylbenzene add to 100% weight portion.
10., containing phonetic mite amine and the acaricidal miticide composition of organic tin, it is characterized in that composition active component is 3% phonetic mite amine, 9% azacyclotin, 5% agriculture breast 500#, 3% agriculture breast 400#, 3% agriculture breast 600#, 25% cyclohexanone, dimethylbenzene add to 100% weight portion.
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| CN103875676A (en) * | 2012-12-20 | 2014-06-25 | 中国中化股份有限公司 | Composition for killing insects and mites and applications thereof |
| CN103891761A (en) * | 2012-12-28 | 2014-07-02 | 陕西汤普森生物科技有限公司 | Compound acarid-killing composition containing pyriminostrobin |
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| WO2011144593A1 (en) * | 2010-05-18 | 2011-11-24 | Basf Se | Pesticidal mixtures comprising insecticides and pyraclostrobin |
| CN103875676A (en) * | 2012-12-20 | 2014-06-25 | 中国中化股份有限公司 | Composition for killing insects and mites and applications thereof |
| CN103891761A (en) * | 2012-12-28 | 2014-07-02 | 陕西汤普森生物科技有限公司 | Compound acarid-killing composition containing pyriminostrobin |
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