CN101999382A - Mite-killing composition containing etoxazole and bifenazate - Google Patents
Mite-killing composition containing etoxazole and bifenazate Download PDFInfo
- Publication number
- CN101999382A CN101999382A CN2011100000582A CN201110000058A CN101999382A CN 101999382 A CN101999382 A CN 101999382A CN 2011100000582 A CN2011100000582 A CN 2011100000582A CN 201110000058 A CN201110000058 A CN 201110000058A CN 101999382 A CN101999382 A CN 101999382A
- Authority
- CN
- China
- Prior art keywords
- mite
- bifenazate
- mite azoles
- azoles
- active component
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000005653 Bifenazate Substances 0.000 title claims abstract description 133
- VHLKTXFWDRXILV-UHFFFAOYSA-N bifenazate Chemical compound C1=C(NNC(=O)OC(C)C)C(OC)=CC=C1C1=CC=CC=C1 VHLKTXFWDRXILV-UHFFFAOYSA-N 0.000 title claims abstract description 92
- 239000000203 mixture Substances 0.000 title claims abstract description 68
- 239000005897 Etoxazole Substances 0.000 title abstract description 4
- IXSZQYVWNJNRAL-UHFFFAOYSA-N etoxazole Chemical compound CCOC1=CC(C(C)(C)C)=CC=C1C1N=C(C=2C(=CC=CC=2F)F)OC1 IXSZQYVWNJNRAL-UHFFFAOYSA-N 0.000 title abstract description 4
- 241000488583 Panonychus ulmi Species 0.000 claims abstract description 35
- 229920000742 Cotton Polymers 0.000 claims abstract description 25
- 239000000839 emulsion Substances 0.000 claims abstract description 7
- 239000004530 micro-emulsion Substances 0.000 claims abstract description 7
- 240000006962 Gossypium hirsutum Species 0.000 claims abstract 2
- 150000003851 azoles Chemical class 0.000 claims description 75
- 239000000375 suspending agent Substances 0.000 claims description 56
- 241000488581 Panonychus citri Species 0.000 claims description 29
- 239000004562 water dispersible granule Substances 0.000 claims description 17
- 239000000642 acaricide Substances 0.000 claims description 14
- 239000000843 powder Substances 0.000 claims description 7
- 238000009736 wetting Methods 0.000 claims description 5
- 238000009472 formulation Methods 0.000 claims description 4
- 241000607479 Yersinia pestis Species 0.000 claims description 2
- 239000003814 drug Substances 0.000 abstract description 58
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 17
- 230000000694 effects Effects 0.000 abstract description 14
- 240000007119 Malus pumila Species 0.000 abstract description 7
- 235000011430 Malus pumila Nutrition 0.000 abstract description 7
- 235000015103 Malus silvestris Nutrition 0.000 abstract description 7
- 238000002360 preparation method Methods 0.000 abstract description 7
- 238000004519 manufacturing process Methods 0.000 abstract description 5
- 229940079593 drugs Drugs 0.000 abstract description 4
- 239000000575 pesticide Substances 0.000 abstract description 2
- 241000207199 Citrus Species 0.000 abstract 1
- 235000020971 citrus fruits Nutrition 0.000 abstract 1
- 230000001934 delay Effects 0.000 abstract 1
- 239000012053 oil suspension Substances 0.000 abstract 1
- 239000002245 particle Substances 0.000 abstract 1
- 239000000725 suspension Substances 0.000 abstract 1
- 239000004563 wettable powder Substances 0.000 abstract 1
- -1 hydrazine ester Chemical class 0.000 description 52
- 241000219146 Gossypium Species 0.000 description 23
- 238000005303 weighing Methods 0.000 description 18
- RTZKZFJDLAIYFH-UHFFFAOYSA-N diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 17
- 239000002994 raw material Substances 0.000 description 16
- 231100000419 toxicity Toxicity 0.000 description 16
- 230000001988 toxicity Effects 0.000 description 16
- 238000002156 mixing Methods 0.000 description 15
- KAESVJOAVNADME-UHFFFAOYSA-N pyrrole Chemical compound C=1C=CNC=1 KAESVJOAVNADME-UHFFFAOYSA-N 0.000 description 15
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicium dioxide Chemical group O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 15
- 239000003795 chemical substances by application Substances 0.000 description 14
- WSFSSNUMVMOOMR-UHFFFAOYSA-N formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 14
- 239000003995 emulsifying agent Substances 0.000 description 12
- LYCAIKOWRPUZTN-UHFFFAOYSA-N glycol Chemical group OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 12
- 239000003921 oil Substances 0.000 description 12
- 235000019198 oils Nutrition 0.000 description 12
- 239000004576 sand Substances 0.000 description 12
- NBIIXXVUZAFLBC-UHFFFAOYSA-K [O-]P([O-])([O-])=O Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 11
- 239000010452 phosphate Substances 0.000 description 11
- WPYMKLBDIGXBTP-UHFFFAOYSA-N Benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 10
- 238000009114 investigational therapy Methods 0.000 description 10
- 230000002045 lasting Effects 0.000 description 10
- XSQUKJJJFZCRTK-UHFFFAOYSA-N urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 10
- LRWZZZWJMFNZIK-UHFFFAOYSA-N 2-chloro-3-methyloxirane Chemical compound CC1OC1Cl LRWZZZWJMFNZIK-UHFFFAOYSA-N 0.000 description 9
- 241001672694 Citrus reticulata Species 0.000 description 8
- 241000238631 Hexapoda Species 0.000 description 8
- 238000004458 analytical method Methods 0.000 description 8
- 239000008367 deionised water Substances 0.000 description 8
- 239000002270 dispersing agent Substances 0.000 description 8
- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical class CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 description 8
- 239000002904 solvent Substances 0.000 description 8
- HVLLSGMXQDNUAL-UHFFFAOYSA-N Triphenyl phosphite Chemical group C=1C=CC=CC=1OP(OC=1C=CC=CC=1)OC1=CC=CC=C1 HVLLSGMXQDNUAL-UHFFFAOYSA-N 0.000 description 7
- 238000000034 method Methods 0.000 description 7
- 230000003449 preventive Effects 0.000 description 7
- 239000011780 sodium chloride Substances 0.000 description 7
- 229920001285 xanthan gum Polymers 0.000 description 7
- JHIVVAPYMSGYDF-UHFFFAOYSA-N Cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 6
- CSCPPACGZOOCGX-UHFFFAOYSA-N acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 6
- VTYYLEPIZMXCLO-UHFFFAOYSA-L calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 6
- 231100000225 lethality Toxicity 0.000 description 6
- QYDYPVFESGNLHU-KHPPLWFESA-N methyl oleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC QYDYPVFESGNLHU-KHPPLWFESA-N 0.000 description 6
- 238000003801 milling Methods 0.000 description 6
- FAPWRFPIFSIZLT-UHFFFAOYSA-M sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- 230000002195 synergetic Effects 0.000 description 6
- YXFVVABEGXRONW-UHFFFAOYSA-N toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- 239000005711 Benzoic acid Substances 0.000 description 5
- 229940051841 POLYOXYETHYLENE ETHER Drugs 0.000 description 5
- HVUMOYIDDBPOLL-XWVZOOPGSA-N Sorbitan monostearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O HVUMOYIDDBPOLL-XWVZOOPGSA-N 0.000 description 5
- LSNNMFCWUKXFEE-UHFFFAOYSA-L Sulphite Chemical compound [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 description 5
- 235000010233 benzoic acid Nutrition 0.000 description 5
- 239000004202 carbamide Substances 0.000 description 5
- 239000006229 carbon black Substances 0.000 description 5
- 239000007789 gas Substances 0.000 description 5
- 238000005259 measurement Methods 0.000 description 5
- CTQNGGLPUBDAKN-UHFFFAOYSA-N o-xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 5
- 229920005646 polycarboxylate Polymers 0.000 description 5
- 229920000056 polyoxyethylene ether Polymers 0.000 description 5
- SRAWNDFHGTVUNZ-UHFFFAOYSA-M sodium;3,6-dibutylnaphthalene-1-sulfonate Chemical compound [Na+].[O-]S(=O)(=O)C1=CC(CCCC)=CC2=CC(CCCC)=CC=C21 SRAWNDFHGTVUNZ-UHFFFAOYSA-M 0.000 description 5
- 239000003549 soybean oil Substances 0.000 description 5
- 235000012424 soybean oil Nutrition 0.000 description 5
- 238000003756 stirring Methods 0.000 description 5
- HMFKFHLTUCJZJO-UHFFFAOYSA-N 2-{2-[3,4-bis(2-hydroxyethoxy)oxolan-2-yl]-2-(2-hydroxyethoxy)ethoxy}ethyl dodecanoate Chemical compound CCCCCCCCCCCC(=O)OCCOCC(OCCO)C1OCC(OCCO)C1OCCO HMFKFHLTUCJZJO-UHFFFAOYSA-N 0.000 description 4
- PZZYQPZGQPZBDN-UHFFFAOYSA-N Aluminium silicate Chemical compound O=[Al]O[Si](=O)O[Al]=O PZZYQPZGQPZBDN-UHFFFAOYSA-N 0.000 description 4
- 239000005995 Aluminium silicate Substances 0.000 description 4
- 210000000481 Breast Anatomy 0.000 description 4
- 229920001732 Lignosulfonate Polymers 0.000 description 4
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 4
- 210000004681 Ovum Anatomy 0.000 description 4
- 229920001214 Polysorbate 60 Polymers 0.000 description 4
- 239000004372 Polyvinyl alcohol Substances 0.000 description 4
- 241000344246 Tetranychus cinnabarinus Species 0.000 description 4
- 241001454293 Tetranychus urticae Species 0.000 description 4
- WFDIJRYMOXRFFG-UHFFFAOYSA-N acetic anhydride Chemical compound CC(=O)OC(C)=O WFDIJRYMOXRFFG-UHFFFAOYSA-N 0.000 description 4
- 239000002390 adhesive tape Substances 0.000 description 4
- 150000008051 alkyl sulfates Chemical group 0.000 description 4
- 150000008052 alkyl sulfonates Chemical class 0.000 description 4
- 235000012211 aluminium silicate Nutrition 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 239000002131 composite material Substances 0.000 description 4
- 230000001276 controlling effect Effects 0.000 description 4
- 230000002950 deficient Effects 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
- 238000009313 farming Methods 0.000 description 4
- 230000012010 growth Effects 0.000 description 4
- KFZMGEQAYNKOFK-UHFFFAOYSA-N iso-propanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 4
- 230000003129 miticidal Effects 0.000 description 4
- LRHPLDYGYMQRHN-UHFFFAOYSA-N n-butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 4
- PSZYNBSKGUBXEH-UHFFFAOYSA-M naphthalene-1-sulfonate Chemical compound C1=CC=C2C(S(=O)(=O)[O-])=CC=CC2=C1 PSZYNBSKGUBXEH-UHFFFAOYSA-M 0.000 description 4
- 230000000361 pesticidal Effects 0.000 description 4
- 229920001296 polysiloxane Polymers 0.000 description 4
- 229920002451 polyvinyl alcohol Polymers 0.000 description 4
- 235000019422 polyvinyl alcohol Nutrition 0.000 description 4
- 230000002265 prevention Effects 0.000 description 4
- 235000014347 soups Nutrition 0.000 description 4
- 239000007921 spray Substances 0.000 description 4
- 239000003381 stabilizer Substances 0.000 description 4
- 239000000080 wetting agent Substances 0.000 description 4
- DMAXMXPDVWTIRV-UHFFFAOYSA-N 2-(2-phenylethyl)phenol Chemical compound OC1=CC=CC=C1CCC1=CC=CC=C1 DMAXMXPDVWTIRV-UHFFFAOYSA-N 0.000 description 3
- HXDOZKJGKXYMEW-UHFFFAOYSA-N 4-Ethylphenol Chemical compound CCC1=CC=C(O)C=C1 HXDOZKJGKXYMEW-UHFFFAOYSA-N 0.000 description 3
- 229960003563 Calcium Carbonate Drugs 0.000 description 3
- WQZGKKKJIJFFOK-GASJEMHNSA-N D-Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 3
- CZMRCDWAGMRECN-UGDNZRGBSA-N D-sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 3
- 240000004282 Grewia occidentalis Species 0.000 description 3
- 241000488533 Tetranychus viennensis Species 0.000 description 3
- HWKQNAWCHQMZHK-UHFFFAOYSA-N Trolnitrate Chemical compound [O-][N+](=O)OCCN(CCO[N+]([O-])=O)CCO[N+]([O-])=O HWKQNAWCHQMZHK-UHFFFAOYSA-N 0.000 description 3
- 239000002518 antifoaming agent Substances 0.000 description 3
- 239000000440 bentonite Substances 0.000 description 3
- 229910000278 bentonite Inorganic materials 0.000 description 3
- 230000033228 biological regulation Effects 0.000 description 3
- 229910000019 calcium carbonate Inorganic materials 0.000 description 3
- 239000007859 condensation product Substances 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- 239000010419 fine particle Substances 0.000 description 3
- 239000008103 glucose Substances 0.000 description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
- 235000011187 glycerol Nutrition 0.000 description 3
- 239000008187 granular material Substances 0.000 description 3
- 238000005469 granulation Methods 0.000 description 3
- 230000003179 granulation Effects 0.000 description 3
- 238000005286 illumination Methods 0.000 description 3
- 239000000391 magnesium silicate Substances 0.000 description 3
- 229910052919 magnesium silicate Inorganic materials 0.000 description 3
- 229940073769 methyl oleate Drugs 0.000 description 3
- 230000008506 pathogenesis Effects 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 239000001587 sorbitan monostearate Substances 0.000 description 3
- 235000011076 sorbitan monostearate Nutrition 0.000 description 3
- 229940035048 sorbitan monostearate Drugs 0.000 description 3
- 238000010998 test method Methods 0.000 description 3
- 239000002562 thickening agent Substances 0.000 description 3
- 230000002588 toxic Effects 0.000 description 3
- 231100000331 toxic Toxicity 0.000 description 3
- 230000017613 viral reproduction Effects 0.000 description 3
- 230000001018 virulence Effects 0.000 description 3
- WQZGKKKJIJFFOK-VFUOTHLCSA-N β-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 3
- BFNBIHQBYMNNAN-UHFFFAOYSA-N Ammonium sulfate Chemical group N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 2
- 229920002261 Corn starch Polymers 0.000 description 2
- WXMKPNITSTVMEF-UHFFFAOYSA-M Sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 description 2
- CZMRCDWAGMRECN-GDQSFJPYSA-N Sucrose Natural products O([C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@H](CO)O1)[C@@]1(CO)[C@H](O)[C@@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-GDQSFJPYSA-N 0.000 description 2
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 2
- 235000011130 ammonium sulphate Nutrition 0.000 description 2
- 230000003042 antagnostic Effects 0.000 description 2
- 229960000892 attapulgite Drugs 0.000 description 2
- 229920005551 calcium lignosulfonate Polymers 0.000 description 2
- HCWYXKWQOMTBKY-UHFFFAOYSA-N calcium;dodecyl benzenesulfonate Chemical group [Ca].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 HCWYXKWQOMTBKY-UHFFFAOYSA-N 0.000 description 2
- 239000004927 clay Substances 0.000 description 2
- 229910052570 clay Inorganic materials 0.000 description 2
- 239000008120 corn starch Substances 0.000 description 2
- 230000034994 death Effects 0.000 description 2
- 239000002283 diesel fuel Substances 0.000 description 2
- YDEXUEFDPVHGHE-GGMCWBHBSA-L disodium;(2R)-3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Na+].[Na+].COC1=CC=CC(C[C@H](CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O YDEXUEFDPVHGHE-GGMCWBHBSA-L 0.000 description 2
- 238000004945 emulsification Methods 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 235000019256 formaldehyde Nutrition 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 238000001802 infusion Methods 0.000 description 2
- 238000007689 inspection Methods 0.000 description 2
- SECXISVLQFMRJM-UHFFFAOYSA-N n-methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 2
- 125000001400 nonyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 229910052625 palygorskite Inorganic materials 0.000 description 2
- 230000002335 preservative Effects 0.000 description 2
- 239000003755 preservative agent Substances 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 239000004299 sodium benzoate Substances 0.000 description 2
- 235000010234 sodium benzoate Nutrition 0.000 description 2
- 239000005720 sucrose Substances 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
- 239000000454 talc Substances 0.000 description 2
- 235000012222 talc Nutrition 0.000 description 2
- 229910052623 talc Inorganic materials 0.000 description 2
- 150000003738 xylenes Chemical group 0.000 description 2
- DUIOKRXOKLLURE-UHFFFAOYSA-N 2-octylphenol Chemical compound CCCCCCCCC1=CC=CC=C1O DUIOKRXOKLLURE-UHFFFAOYSA-N 0.000 description 1
- 241000239290 Araneae Species 0.000 description 1
- 210000001161 Embryo, Mammalian Anatomy 0.000 description 1
- 239000001293 FEMA 3089 Substances 0.000 description 1
- BTCSSZJGUNDROE-UHFFFAOYSA-N GABA Chemical compound NCCCC(O)=O BTCSSZJGUNDROE-UHFFFAOYSA-N 0.000 description 1
- 241000488585 Panonychus Species 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 235000019484 Rapeseed oil Nutrition 0.000 description 1
- 210000003491 Skin Anatomy 0.000 description 1
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- XZZNDPSIHUTMOC-UHFFFAOYSA-N Triphenyl phosphate Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)(=O)OC1=CC=CC=C1 XZZNDPSIHUTMOC-UHFFFAOYSA-N 0.000 description 1
- 239000002671 adjuvant Substances 0.000 description 1
- 230000000240 adjuvant Effects 0.000 description 1
- 239000003905 agrochemical Substances 0.000 description 1
- 229960003692 aminobutyric acid Drugs 0.000 description 1
- 239000005557 antagonist Substances 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 235000005687 corn oil Nutrition 0.000 description 1
- 239000002285 corn oil Substances 0.000 description 1
- 230000000875 corresponding Effects 0.000 description 1
- 125000002243 cyclohexanonyl group Chemical group *C1(*)C(=O)C(*)(*)C(*)(*)C(*)(*)C1(*)* 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 239000007884 disintegrant Substances 0.000 description 1
- 239000002612 dispersion media Substances 0.000 description 1
- OAKJQQAXSVQMHS-UHFFFAOYSA-N hydrazine Substances NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 1
- 230000036039 immunity Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 230000000749 insecticidal Effects 0.000 description 1
- 239000002917 insecticide Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000008297 liquid dosage form Substances 0.000 description 1
- 239000010721 machine oil Substances 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 230000003151 ovacidal Effects 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N oxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 230000001340 slower Effects 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
Abstract
The invention discloses a mite-killing composition containing etoxazole and bifenazate, wherein the weight ratio of the etoxazole to the bifenazate is (30:1)-(1:60), is preferably (10:1)-(1:25) and is more preferably (3:1)-(1:16). The composition can be prepared into a water dispersing particle, a suspension, wettable powder, a dispersible oil suspension, missible oil, an emulsion in water or a microemulsion. The mite-killing composition has reasonable component, good mite-killing effect and low cost of used medicines, achieves the activity and the mite-killing effect not by the simple superposition of all the components, and has obvious synergism. The mite-killing composition takes effect quickly, has long effect-holding period, delays the resistance production, is safe to crops, meets the safety requirement of a pesticide preparation, and has better effect of preventing and treating citrus tree, apple tree and cotton red spiders.
Description
Technical field
The present invention relates to a kind of miticide composition that contains second mite azoles and Bifenazate, be used to prevent and treat the harmful mite of crops such as cotton, oranges and tangerines, apple, belong to technical field of compounded pesticide.
Background technology
Second mite azoles is the miticide of a kind of brand-new tool special construction of SUMITOMO CHEMICAL KCC research and development, English common name: etoxazole, chemical molecular formula NC
21H
23F
2NO
2Its mode of action is that the embryo who suppresses the mite ovum forms and the process of casting off a skin from young mite to the one-tenth mite, and is effective to ovum and young mite, to becoming mite invalid.Therefore the control time of its best is the evil mite harm initial stage.This medicament rain fastness is strong, and the lasting period reaches 50 days.Using dosage is low.Environmentally safe, useful insect and beneficial mite are not had harm or endanger minimum.The tetranychid of crops such as oranges and tangerines, cotton, apple, flowers, vegetables, the mite classes such as tetranychid, Panonychus citri, Tetranychus urticae, Tetranychus cinnabarinus that begin there is remarkable preventive effect.As a kind of new professional miticide, second mite azoles in use exists the use cost height, and the risk that resistance risk increases gradually is effective to ovum and young mite, to becoming the invalid defective of mite.
Bifenazate english common name bifenazate, chemical molecular formula C
17H
20N
2O
3Bifenazate is a kind of γ-An Jidingsuan (GABA) antagonist, mainly prevents and treats the active stage tetranychid, and quick-acting is good, to young mite with become, if mite effective, to some other mite classes, especially Tetranychus urticae is had ovicidal action.Laboratory research shows that Bifenazate does not have negative effect to predatism benefit mite; To the low (LD of mammalian toxicity
50Be 5 000mg/kg); Lasting period weak point in environment (DT50＜1d).The Bifenazate of Xiao Shouing is 43% suspending agent in the market, is mainly used in control apple tree two spotted spider mite.As a kind of new hydrazine ester class specialty miticide, in use there is the use cost height equally in Bifenazate, the risk that resistance risk increases gradually, the defective that the lasting period is short.
At present, the pesticidal preparations that with second mite azoles is effective ingredient is based on 110 grams per liter suspending agents, and in actual use, effective to ovum and young mite, quick-acting is poor, but lasting effect is good, the use cost height; Bifenazate quick-acting is good, to young mite with become, if mite preventive effect height, in use exist the use cost height, the risk that resistance risk increases gradually, the defective that the lasting period is short.The inventor is unexpected to be found the use that is mixed of second mite azoles and Bifenazate can be improved its quick-acting, and the good lasting period is arranged again, slows down the generation of pest resistance, can also improve the safety to crop.
Summary of the invention
The object of the present invention is to provide a kind of component reasonable, miticidal effect is good, and drug cost is low, the miticide composition that contains second mite azoles and Bifenazate that is difficult for developing immunity to drugs.
Another object of the present invention is to provide the farm killing mite composite preparation that contains second mite azoles and Bifenazate formulation.
In order to overcome the defective of existing unitary agent, technical scheme of the present invention is to solve like this:
Contain the Pesticidal combination of second mite azoles and Bifenazate, comprising:
A) the first active component second mite azoles;
B) the second active component Bifenazate;
The weight ratio of first active component and second active component is (30:1)～(1:60), is preferably (10:1)～(1:25), most preferably is (3:1)～(1:16).
The cumulant of first active component and second active component is 3%～80% of a described composition total weight, be preferably 5%～50%, the size of active component cumulant is also closely related with formulation, but is no more than 50% as the active component cumulant of liquid dosage form suspending agent, suspended emulsion dispersed oil suspending agent, missible oil, microemulsion.
But the preparation formulation that the Pesticidal combination of second mite azoles of the present invention and Bifenazate can be prepared according to method known in those skilled in the art is water dispersible granules, suspending agent, wetting powder dispersed oil suspending agent, missible oil, aqueous emulsion or microemulsion.
For water dispersible granules, those skilled in the art are familiar with the use corresponding adjuvants and finish the present invention very much.Dispersant is selected from polycarboxylate, lignosulfonates, alkylnaphthalene sulfonate; Wetting agent is selected from alkyl sulfate, alkylsulfonate, naphthalene sulfonate; Disintegrant is selected from ammonium sulfate, urea, sucrose, glucose; Binding agent is selected from diatomite, corn starch, PVA, carboxymethyl (ethyl) cellulose family; Filler is selected from diatomite, kaolin, white carbon, fine particle calcium carbonate, talcum powder, attapulgite, potter's clay.
To suspending agent, spendable auxiliary agent has: dispersant is selected from polycarboxylate, lignosulfonates, alkylnaphthalene sulfonate, TERSPERSE 2425(U.S. Huntsman Corporation product, alkyl naphthalene sulfonic acid salt); Emulsifier is selected from Nongru-700 #(common name: alkyl phenol formaldehyde resin polyoxyethylene ether), farming breast 2201, this dish-60#(common name sorbitan monostearate), emulsifier T-60(common name: the sorbitan monostearate APEO), agricultural newborn 1601#(common name: phenethyl phenol polyoxyethylene poly-oxygen propylene aether), TERSPERSE 4894(U.S. Huntsman Corporation produces) TERSPERSE 2500(U.S. Huntsman Corporation produces); Wetting agent is selected from alkylphenol-polyethenoxy base ether formaldehyde condensation products sulphate, alkylphenol-polyethenoxy base ether phosphate, phenethyl phenol polyethenoxy base ether phosphate, alkyl sulfate, alkylsulfonate, naphthalene sulfonate, TERSPERSE 2500; Thickener is selected from xanthans, polyvinyl alcohol, bentonite; Preservative is selected from formaldehyde, benzoic acid, Sodium Benzoate; Defoamer is selected from silicone based defoamer; Antifreezing agent is selected from ethylene glycol, propane diols, glycerine, urea, inorganic salts (as sodium chloride).
But to the dispersed oil suspending agent, spendable auxiliary agent has: dispersant is selected from polycarboxylate, lignosulfonates, alkylnaphthalene sulfonate (dispersing agent NNO), TERSPERSE 2425; Emulsifier is selected from the BY(castor oil polyoxyethylene ether) serial emulsifier (BY-110, BY-125, BY-140) Nongru-700 #, farming breast 2201, this dish-60#, Tween-60 #(common name: the sorbitan monostearate APEO), agricultural newborn 1601#, TERSPERSE 4894; Wetting agent is selected from alkylphenol-polyethenoxy base ether formaldehyde condensation products sulphate, alkylphenol polyoxyethylene phosphate, phenethyl phenol polyethenoxy base ether phosphate, alkyl sulfate, alkylsulfonate, naphthalene sulfonate, TERSPERSE 2500; Thickener is selected from white carbon, polyvinyl alcohol, bentonite, aluminium-magnesium silicate; Antifreezing agent is selected from ethylene glycol, propane diols, glycerine, urea, inorganic salts such as sodium chloride; Stabilizing agent is selected from epoxidized soybean oil, epoxychloropropane, triphenyl phosphate; Dispersion medium is selected from soybean oil, rapeseed oil, corn oil, methyl oleate, diesel oil, machine oil, mineral oil.
To wetting powder, spendable auxiliary agent has: dispersant is selected from polycarboxylate, lignosulfonates, alkylnaphthalene sulfonate; Wetting agent is selected from alkyl sulfate, alkylsulfonate, naphthalene sulfonate; Filler is selected from ammonium sulfate, urea, sucrose, glucose diatomite, kaolin, white carbon, fine particle calcium carbonate, talcum powder, attapulgite, potter's clay.
For missible oil, spendable auxiliary agent has: emulsifier is selected from calcium dodecyl benzene sulfonate (agricultural newborn 500#), Nongru-700 #, agricultural newborn 2201#, this dish-60#, emulsifier T-60, agricultural newborn 1601#, agricultural newborn 600#, agricultural newborn 400#; Solvent is selected from dimethylbenzene, solvent naphtha (S-150, S-180, S-200), toluene, turpentine oil, methyl alcohol, dimethyl formamide, cyclohexanone, acetone, diesel oil; Stabilizing agent is selected from triphenyl phosphite, epoxychloropropane, aceticanhydride.
To aqueous emulsion, spendable auxiliary agent has: emulsifier is selected from Nonyl pheno (EO=10) ether phosphate, triphen ethyl-phenol polyoxyethylene ether phosphate (agricultural newborn 600# phosphate), Nongru-700 #, agricultural newborn 2201#, this dish-60#, emulsifier T-60, farming breast 1601, agricultural newborn 600#, agricultural newborn 400#; Solvent is selected from dimethylbenzene, toluene, cyclohexanone, solvent naphtha (trade mark: S-150, S-180, S-200); Stabilizing agent is selected from triphenyl phosphite, epoxychloropropane, aceticanhydride; Antifreezing agent is selected from ethylene glycol, propane diols, glycerine, urea, inorganic salts such as sodium chloride; Thickener is selected from xanthans, polyvinyl alcohol, bentonite, aluminium-magnesium silicate; Preservative is selected from formaldehyde, benzoic acid, Sodium Benzoate, and water is deionized water.
Octyl phenol polyoxy ethene (10) ether), farming breast 1601, agricultural newborn 600#, agricultural newborn 400# to microemulsion, spendable auxiliary agent has: emulsifier is selected from calcium dodecyl benzene sulfonate (agricultural newborn 500#), Nongru-700 #, agricultural newborn 2201#, this dish-60#, Tween-60 #, TX-10(common name:; Assistant for emulsifying agent is selected from methyl alcohol, isopropyl alcohol, n-butanol, ethanol; Solvent is selected from cyclohexanone, N-Methyl pyrrolidone, dimethylbenzene, toluene, solvent naphtha (trade mark: S-150, S-180, S-200); Stabilizing agent is selected from triphenyl phosphite, epoxychloropropane.
Component of the present invention is reasonable, good disinsection effect, and drug cost is low, and its active and miticidal effect is not the simple superposition of each composition activity, but significant synergistic effect is arranged, and quick-acting height, lasting effect are long, slow down the generation of resistance, good to crop safety, meet the security requirement of pesticidal preparations.The present invention has better control efficiency to the mite class on citrus red mite, European red mite, the cotton crop.
Embodiment
Toxicity Determination 1: citrus red mite indoor virulence test
In order to prevent and treat the insects such as citrus red mite in the agricultural production, the inventor has carried out mutual composite synergy research with compositions such as second mite azoles, Bifenazates.It is tested object that citrus red mite is adopted in test, and concrete grammar is:
Citrus red mite (panonychus citri, formal name used at school
Panonychus citfiMcGregor) the former medicine of test medicine second mite azoles adopts the former medicine of SUMITOMO CHEMICAL KCC production, the former medicine that the former medicine of Bifenazate adopts U.S. Chemtura Corporation to produce, by technology department of Shanggezhilu Biosciences Co., Ltd., Shaanxi former medicine is mixed with the test medicine that needs, test method is with reference to " the agricultural industry criteria Y/T1282-2007 of the People's Republic of China (PRC) ".At first single agent and each Mixed Pharmacy are provided with 5 variable concentrations gradients (on preliminary experiment result's basis, citrus red mite becomes the mite lethality to set by geometric progression) in the scope of 5%-90%.The examination worm is the one-tenth mite of picking up from the field, selects the one-tenth mite of uniformity in the length of time in the laboratory, puts into blade-carrying culture dish, every ware 40 cephalont, 4 culture dishes of every processing repeat 3 times, spray under 50PSI pressure with the potter spray tower, ware of each spray, every ware spraying liquid 3ml, the culture dish that will handle is put into 25 ℃ then, cultivates in the 12H/12H illumination box, check dead borer population in 48 hours, calculate lethality.Blank spray equivalent clear water.
The co-toxicity coefficient of mixture (CTC value) calculates by following formula:
In the formula:
ATI---mixture actual measurement toxicity index;
S---standard insecticide LC
50, unit is every liter (mg/L) of milligram;
The LC of M---mixture
50, unit is every liter (mg/L) of milligram;
TTI=TI
A×P
A+?TI
B×P
B
In the formula:
The theoretical toxicity index of TTI---mixture;
TI
A---A medicament toxicity index;
P
A---the percentage composition of A medicament in mixture, unit are percentage (%);
TI
B---B medicament toxicity index;
P
B---the percentage composition of B medicament in mixture, unit are percentage (%);
In the formula:
CTC---co-toxicity coefficient;
ATI---mixture actual measurement toxicity index;
The theoretical toxicity index of TTI---mixture;
The co-toxicity coefficient of complex preparation (CTC) 〉=120 shows as synergistic effect; CTC≤80 show as antagonism; 80＜CTC＜120 show as summation action.The measurement result of citrus red mite sees Table 1 respectively, table 2.
Table 1 second mite azoles and Bifenazate are to citrus red mite Toxicity Determination result
Table 2 second mite azoles with Bifenazate the citrus red mite co-toxicity coefficient is added up
Toxicity Determination result shows: second mite azoles becomes mite that good toxic effect is arranged with being mixed with Bifenazate to citrus red mite, and weight ratio all has remarkable synergistic effect between 30:1-1:60.
Toxicity Determination 2: cotton red spider indoor virulence test
In order to prevent and treat the insects such as cotton red spider in the agricultural production, the inventor has carried out mutual composite synergy research with compositions such as second mite azoles, Bifenazates.It is tested object that cotton red spider is adopted in test, and concrete grammar is:
Cotton red spider has 4 kinds, and the inventor chooses representative Tetranychus cinnabarinus (formal name used at school Tetranychus cinnabarinus) and is subjects.The former medicine that the former medicine of test medicine second mite azoles adopts SUMITOMO CHEMICAL KCC to produce, the former medicine that the former medicine of Bifenazate adopts U.S. Chemtura Corporation to produce, by technology department of Shanggezhilu Biosciences Co., Ltd., Shaanxi former medicine is mixed with the test medicine that needs, the slide infusion process that test method adopts FAO to recommend.At first single agent and each Mixed Pharmacy are provided with 5 variable concentrations gradients (on preliminary experiment result's basis, cotton red spider becomes the mite lethality to set by geometric progression) in the scope of 5%-90%.The examination worm is the one-tenth mite of picking up from the field, sticks double faced adhesive tape at an end of slide, becomes mite with the writing brush picking, and the back sticks in downwards on the double faced adhesive tape, and every about 30 of slide tries worm, 3 slides of every processing, triplicate.Soaked in the soup for preparing 5 seconds, and inhaled with filter paper and remove unnecessary soup, put into the glass ware that is covered with filter paper, put into 25 ± 1 ℃, relative moisture 60%-70% is raised under the illumination 14L:10D condition.Handle back 48h inspection and add up into the mite death condition, observe under anatomical lens, it is motionless for dead to touch foot.Calculate lethality.Blank is handled with clear water.The measurement result of cotton red spider sees Table 3 respectively, table 4.
Table 3 second mite azoles and Bifenazate are to cotton red spider Toxicity Determination result
Table 4 second mite azoles and Bifenazate are added up the cotton red spider co-toxicity coefficient
Toxicity Determination result shows: second mite azoles and Bifenazate are mixed has good toxic effect to cotton red spider, and weight ratio all has remarkable synergistic effect between 30:1-1:60.
Toxicity Determination 3: European red mite indoor virulence test
In order to prevent and treat the insects such as European red mite in the agricultural production, the inventor has carried out mutual composite synergy research with compositions such as second mite azoles, Bifenazates.It is tested object that European red mite is adopted in test, and concrete grammar is:
European red mite is mainly hawthron spider mite, has another name called tetranychus viennensis (formal name used at school Tetranychus viennensis Zacher).The former medicine that the former medicine of test medicine second mite azoles adopts SUMITOMO CHEMICAL KCC to produce, the former medicine that the former medicine of Bifenazate adopts U.S. Chemtura Corporation to produce, by technology department of Shanggezhilu Biosciences Co., Ltd., Shaanxi former medicine is mixed with the test medicine that needs, the slide infusion process that test method adopts FAO1980 to recommend.At first single agent and each Mixed Pharmacy are provided with 5 variable concentrations gradients (on preliminary experiment result's basis, European red mite becomes the mite lethality to set by geometric progression) in the scope of 5%-90%.The examination worm is the one-tenth mite of picking up from the field, sticks double faced adhesive tape at an end of slide, becomes mite with the writing brush picking, and the back sticks in downwards on the double faced adhesive tape, and every about 30 of slide tries worm, 3 slides of every processing, triplicate.In the soup for preparing, soaked 5 seconds, and inhaled with filter paper and remove unnecessary soup, put into the glass ware that is covered with filter paper, put into insectary (25 ± 1 ℃, relative moisture 60%-70%, illumination 14L:10D).Handle back 48h inspection and add up into the mite death condition, observe under anatomical lens, it is motionless for dead to touch foot.Calculate lethality.Blank is handled with clear water.The measurement result of European red mite sees Table 5 respectively, table 6.
Table 5 second mite azoles and Bifenazate are to European red mite Toxicity Determination result
Table 6 second mite azoles and Bifenazate are added up the European red mite co-toxicity coefficient
Toxicity Determination result shows: second mite azoles and Bifenazate are mixed has good toxic effect to European red mite, and weight ratio all has remarkable synergistic effect between 30:1-1:60.
Below in conjunction with embodiment content of the present invention is described further.
Example of formulations 1
Take by weighing 60% second mite azoles, 20% Bifenazate, 3% TERSPERSE 2700(polycarboxylate, U.S. Huntsman Corporation produces), 2% dispersing agent NNO (alkylnaphthalene sulfonate formaldehyde condensation products), 2% Nekal BX (nekal), 1%K-12(lauryl sodium sulfate), 2% white carbon black, 5% sulphur ammonium, diatomite add to 100% weight portion.The method of the frequent regulation of above-mentioned raw materials water intaking dispersible granule is promptly mixed, ultra micro comminution by gas stream, mixing, granulation step are produced 80% second mite azoles Bifenazate water dispersible granules.
The part by weight of second mite azoles and Bifenazate can change between 30:1-1:60 in the present embodiment, and both total weight items still are 80%, form new embodiment.
Example of formulations 2
Take by weighing 2% second mite azoles, 50% Bifenazate, 3% TERSPERSE 2700,3% sodium lignin sulfonate, 2% Nekal BX, 2% K-12,3% white carbon black, 3% soluble starch, 5% sulphur ammonium, diatomite and add to 100% weight portion.The method of the frequent regulation of above-mentioned raw materials water intaking dispersible granule is promptly mixed, ultra micro comminution by gas stream, mixing, granulation step are produced 52% second mite azoles Bifenazate water dispersible granules.
The part by weight of second mite azoles and Bifenazate can change between 30:1-1:60 in the present embodiment, and both total weight items still are 52%, form new embodiment.
Example of formulations 3
Take by weighing 4% second mite azoles, 32% Bifenazate, 4% TERSPERSE 2700,3% dispersing agent NNO, 2% K-12,3% white carbon black, 3% corn starch, 10% glucose, kaolin and add to 100% weight portion.The method of the frequent regulation of above-mentioned raw materials water intaking dispersible granule is promptly mixed, ultra micro comminution by gas stream, mixing, granulation step are produced 36% second mite azoles Bifenazate water dispersible granules.
The part by weight of second mite azoles and Bifenazate can change between 30:1-1:60 in the present embodiment, and both total weight items still are 36%, form new embodiment.
Example of formulations 4
Take by weighing 10% second mite azoles, 20% Bifenazate, 3%TERSPERSE 4894,2%TERSPERSE 2500,1%TERSPERSE 2425,0.2% xanthans, 5% ethylene glycol, 0.3% benzoic acid, 0.5% silicone defoaming agent (trade name: s-29 Nanjing "four news" (new ideas applied chemistry product company produces) deionized water and add to 100% weight portion.Above-mentioned raw materials is through mixing, and high speed shear is disperseed 30min, with the second mite azoles Bifenazate suspending agent that makes 30% behind the sand mill sand milling.
The part by weight of second mite azoles and Bifenazate can change between 30:1-1:60 in the present embodiment, and both total weight items still are 30%, form new embodiment.
Example of formulations 5
Take by weighing 5% second mite azoles, 40% Bifenazate, 2500 of 3%TERSPERSE 4894,2%TERSPERSE, 1% TERSPERSE 2700,0.2% xanthans, 5% propane diols, 0.5% formaldehyde, 0.5% silicone defoaming agent s-29, deionized water adds to 100% weight portion.Above-mentioned raw materials is through mixing, and high speed shear is disperseed 30min, with the second mite azoles Bifenazate suspending agent that makes 45% behind the sand mill sand milling.
The part by weight of second mite azoles and Bifenazate can change between 30:1-1:60 in the present embodiment, and both total weight items still are 45%, form new embodiment.
Example of formulations 6
Take by weighing 30% second mite azoles, 3% Bifenazate, 2% sodium lignin sulfonate, 1.5%TERSPERSE 2500,3%TERSPERSE 2425,0.15% xanthans, 5% ethylene glycol, 0.3% benzoic acid, 0.5% silicone defoaming agent s-29, deionized water adds to 100% weight portion.Above-mentioned raw materials is through mixing, and high speed shear is disperseed 30min, with the second mite azoles Bifenazate suspending agent that makes 33% behind the sand mill sand milling.
The part by weight of second mite azoles and Bifenazate can change between 30:1-1:60 in the present embodiment, and both total weight items still are 33%, form new embodiment.
Example of formulations 7
Take by weighing 11% second mite azoles, 50% Bifenazate, 5% calcium lignosulfonate, 3%TERSPERSE 2425,2% Nekal BX, 2%K-12,5% white carbon black, kaolin and add to 100% weight portion.Above-mentioned raw materials makes 61% second mite azoles Bifenazate wetting powder through mixing behind the comminution by gas stream.
The part by weight of second mite azoles and Bifenazate can change between 30:1-1:60 in the present embodiment, and both total weight items still are 61%, form new embodiment.
Example of formulations 8
Take by weighing 3% second mite azoles, 48% Bifenazate, 5% calcium lignosulfonate, 1% TERSPERSE 2700,2% Nekal BX, 1%K-12,3% white carbon black, fine particle calcium carbonate and add to 100% weight portion.Above-mentioned raw materials makes 51% second mite azoles Bifenazate wetting powder through mixing behind the comminution by gas stream.
The part by weight of second mite azoles and Bifenazate can change between 30:1-1:60 in the present embodiment, and both total weight items still are 51%, form new embodiment.
Example of formulations 9
Take by weighing 30% second mite azoles, 1% Bifenazate, 4% agricultural newborn 500#, 2% agricultural newborn 600#, 3% agricultural newborn 2201#, 3% triphenyl phosphite, 10% dimethyl formamide, dimethylbenzene add to 100% weight portion.Above-mentioned raw materials makes 31% second mite azoles Bifenazate missible oil after mix, stirring and dissolving is complete.
The part by weight of second mite azoles and Bifenazate can change between 30:1-1:60 in the present embodiment, and both total weight items still are 31%, form new embodiment.
Example of formulations 10
Take by weighing 20% second mite azoles, 2% Bifenazate, 5% agricultural newborn 500#, 4% Nongru-700 #, 3% agricultural newborn 1601#, 1% epoxychloropropane, 20% acetone, solvent naphtha S-180 adds to 100% weight portion.Above-mentioned raw materials makes 22% second mite azoles Bifenazate missible oil after mix, stirring and dissolving is complete.
The part by weight of second mite azoles and Bifenazate can change between 30:1-1:60 in the present embodiment, and both total weight items still are 22%, form new embodiment.
Example of formulations 11
Take by weighing 12% second mite azoles, 4% Bifenazate, 4% agricultural newborn 500#, 4% agricultural newborn 400#, 5% emulsifier T-60,1% triphenyl phosphite, 3% epoxychloropropane, solvent naphtha S-180 adds to 100% weight portion.Above-mentioned raw materials makes 16% second mite azoles Bifenazate missible oil after mix, stirring and dissolving is complete.
The part by weight of second mite azoles and Bifenazate can change between 30:1-1:60 in the present embodiment, and both total weight items still are 16%, form new embodiment.
Example of formulations 12
Take by weighing 5% second mite azoles, 5% Bifenazate, 3% agricultural newborn 2201#, 2% Nonyl pheno (EO=10) ether phosphate, 2% triphen ethyl-phenol polyoxyethylene ether phosphate (agricultural newborn 600# phosphate), 2%Span-60#, 1% epoxychloropropane, 5% ethylene glycol, 10% cyclohexanone, 20% dimethylbenzene, 0.3% xanthans, 0.5% benzoic acid, deionized water adds to 100% weight portion.Above-mentioned raw materials is through mixing, and high speed shear emulsification makes 10% second mite azoles Bifenazate aqueous emulsion.
The part by weight of second mite azoles and Bifenazate can change between 30:1-1:60 in the present embodiment, and both total weight items still are 10%, form new embodiment.
Example of formulations 13
Take by weighing 1% second mite azoles, 4% Bifenazate, 3% triphen ethyl-phenol polyoxyethylene ether phosphate (agricultural newborn 600# phosphate), 2%Span-60#, 3% emulsifier T-60,1% triphenyl phosphite, 5% propane diols, 10% cyclohexanone, 10% dimethylbenzene, 0.3% xanthans, 0.5% formaldehyde, deionized water adds to 100% weight portion.Above-mentioned raw materials is through mixing, and high speed shear emulsification makes 5% second mite azoles Bifenazate aqueous emulsion.
The part by weight of second mite azoles and Bifenazate can change between 30:1-1:60 in the present embodiment, and both total weight items still are 5%, form new embodiment.
Example of formulations 14
Take by weighing 3% second mite azoles, 15% Bifenazate, 2%TERSPERSE 2425,4% this dish-60#, 3% Tween-60 #, 2% Nongru-700 #, 2%TERSPERSE 4894,1%TERSPERSE 2500,0.5% white carbon, 5% propane diols, 1% epoxychloropropane, methyl oleate and add to 100% weight portion.Above-mentioned raw materials is through mixing, and high speed shear is disperseed 30min, but with making 18% second mite azoles Bifenazate dispersed oil suspending agent behind the sand mill sand milling.
The part by weight of second mite azoles and Bifenazate can change between 30:1-1:60 in the present embodiment, and both total weight items still are 18%, form new embodiment.
Example of formulations 15
Take by weighing 3% second mite azoles, 22% Bifenazate, 2% dispersing agent NNO, 3% agricultural newborn 2201#, 8% BY-110,1%TERSPERSE 2500,1% aluminium-magnesium silicate, 3% propane diols, 15% epoxidized soybean oil, soybean oil and add to 100% weight portion.Above-mentioned raw materials is through mixing, and high speed shear is disperseed 30min, but with making 25% second mite azoles Bifenazate dispersed oil suspending agent behind the sand mill sand milling.
The part by weight of second mite azoles and Bifenazate can change between 30:1-1:60 in the present embodiment, and both total weight items still are 25%, form new embodiment.
Example of formulations 16
Take by weighing 3% second mite azoles, 27% Bifenazate, 1.5%TERSPERSE 2425,3% this dish-60#, 3% Tween-60 #, 8% BY-110,1%TERSPERSE 2500,0.5% white carbon, 5% propane diols, 20% epoxidized soybean oil, methyl oleate and add to 100% weight portion.Above-mentioned raw materials is through mixing, and high speed shear is disperseed 30min, but with making 30% second mite azoles Bifenazate dispersed oil suspending agent behind the sand mill sand milling.
The part by weight of second mite azoles and Bifenazate can change between 30:1-1:60 in the present embodiment, and both total weight items still are 30%, form new embodiment.
Example of formulations 17
Take by weighing 0.5% second mite azoles, 5.5% Bifenazate, 4%TX-10,5% Nongru-700 #, 6% agricultural newborn 500#, 3% agricultural newborn 1601#, 15% cyclohexanone, 5%N-methyl pyrrolidone, 5% n-butanol, 1% epoxychloropropane, through dissolving fully and mixing, deionized water adds to 100% weight portion, makes 6% second mite azoles Bifenazate microemulsion after the stirring.
The part by weight of second mite azoles and Bifenazate can change between 30:1-1:60 in the present embodiment, and both total weight items still are 6%, form new embodiment.
Example of formulations 18
Take by weighing 2% second mite azoles, 13% Bifenazate, 5% agricultural newborn 400#, 4% agricultural newborn 500#, 6% agricultural newborn 1601#, 20% cyclohexanone, 5% dimethylbenzene, 5% isopropyl alcohol, 3% triphenyl phosphite, through dissolving fully and mixing, deionized water adds to 100% weight portion, makes 15% second mite azoles Bifenazate microemulsion after the stirring.
The part by weight of second mite azoles and Bifenazate can change between 30:1-1:60 in the present embodiment, and both total weight items still are 15%, form new embodiment.
Biological Examples 1: control citrus red mite field trial
Carried out the field control effectiveness test of 52% second mite azoles Bifenazate (2+50) the water dispersible granules control citrus red mite of example of formulations 2 in Zhaoqing Deqing County, Guangdong Province, verified that this medicament is to the control efficiency of citrus red mite, effective dose and to the safety of mandarin tree.Trial crops is the granulated sugar tangerine, the controlling object citrus red mite (
Panonychus citri Me Gregor).Test medicine and dosage are 2000 times, 3000 times, 4000 times of 52% second mite azoles Bifenazate water dispersible granules, 5000 times of 110 grams per liter second mite azole suspending agents, 2000 times of 43% Bifenazate suspending agents.Adopt conventional spray-on process.Investigation insect population radix before the dispenser, 3d, 7d, 14d, 30d, 45d investigate residual borer population alive respectively behind the medicine, and 2 strains are looked in every sub-district during investigation, every strain is looked into 5 leaves respectively by 4 orientation, the four corners of the world, every sub-district is looked into 40 leaves altogether, and record mite number alive carries out the control efficiency statistics.
The preventive effect computational methods
In the formula: Pt
0Before-----treatment region medicine; Pt
1Behind-----treatment region medicine
CK
0Before the medicine of-----check plot; CK
1Behind the medicine of-----check plot
Table 7 52% second mite azoles Bifenazate water dispersible granules control citrus red mite result of the test
Table 7 for behind the medicine the 14th day the time each sub-district preventive effect carry out the biostatistics analysis, analysis result shows: handle differences and reach utmost point significance level, district's group difference is not remarkable.Significance of difference comparative result shows: consistent with the significance of difference on 0.01 level on 0.05 level, 2000 times, 3000 times two processing of 52% second mite azoles Bifenazate water dispersible granules differences is not remarkable, respectively handles differences with other and all reaches utmost point significance level.4000 times of 52% second mite azoles Bifenazate water dispersible granules and 5000 times of contrast medicament 110 grams per liter second mite azole suspending agents, comparing difference is all not remarkable between 2000 times of 3 processing in twos of 43% Bifenazate suspending agent.
Field trial shows: 52% second mite azoles Bifenazate water dispersible granules has than remarkable prevention effect citrus red mite, its 2000 times, 3000 times control efficiency obviously is better than contrasting 5000 times of medicament 110 grams per liter second mite azole suspending agents, the control efficiency that 43% Bifenazate suspending agent is 2000 times, its 4000 times with 5000 times of 110 grams per liter second mite azole suspending agents, the control efficiency that 43% Bifenazate suspending agent is 2000 times is suitable substantially, result of the test shows: after second mite azoles and Bifenazate are mixed, quick-acting and lasting period have obviously been improved to citrus red mite, greatly reduce dosage, to mandarin tree growth safety.
Biological Examples 2: control European red mite field trial
Carried out the field control effectiveness test of 36% second mite azoles Bifenazate (4+32) the water dispersible granules control European red mite of example of formulations 3 in the Liquan County, Shaanxi Province, verified that this medicament is to the control efficiency of European red mite, effective dose and to the safety of apple tree.Trial crops is an apple tree, the controlling object European red mite (
Tetranychus viennensis Zacher).Test medicine and dosage are 2000 times, 3000 times, 4000 times of 36% second mite azoles Bifenazate water dispersible granules, 5000 times of 110 grams per liter second mite azole suspending agents, 2000 times of 43% Bifenazate suspending agents.Adopt conventional spray-on process.Investigation insect population radix before the dispenser, 3d, 7d, 14d, 30d, 45d investigate residual borer population alive respectively behind the medicine, and 2 strains are looked in every sub-district during investigation, every strain is looked into 5 leaves respectively by 4 orientation, the four corners of the world, every sub-district is looked into 40 leaves altogether, and record mite number alive carries out the control efficiency statistics.
Table 8 36% second mite azoles Bifenazate water dispersible granules control European red mite result of the test
Table 8 for behind the medicine the 14th day the time each sub-district preventive effect carry out the biostatistics analysis, analysis result shows: handle differences and reach utmost point significance level, district's group difference is not remarkable.Significance of difference comparative result shows: consistent with the significance of difference on 0.01 level on 0.05 level, compare difference in twos between 2000 times, 3000 times, 4000 times 3 processing of 36% second mite azoles Bifenazate water dispersible granules and all reach utmost point significance level, 3 handle all and contrast 5000 times of medicament 110 grams per liter second mite azole suspending agents, 43% Bifenazate suspending agent is handled differences for 2000 times and is reached utmost point significance level, and 5000 times of contrast medicament 110 grams per liter second mite azole suspending agents are not remarkable with 2000 times of two processing of 43% Bifenazate suspending agent differences.
Field trial shows: 36% second mite azoles Bifenazate water dispersible granules has than remarkable prevention effect European red mite, its 2000 times, 3000 times, 4000 times control efficiency obviously is better than contrasting 5000 times of medicament 110 grams per liter second mite azole suspending agents, the control efficiency that 43% Bifenazate suspending agent is 2000 times, result of the test shows: after second mite azoles and Bifenazate are mixed, quick-acting and lasting period have obviously been improved to European red mite, greatly reduce dosage, to apple tree growth safety.
Biological Examples 3: control citrus red mite field trial
Carried out the field control effectiveness test of 30% second mite azoles Bifenazate (10+20) the suspending agent control citrus red mite of example of formulations 4 in area, Yangjiang, Guangdong Province, verified that this medicament is to the control efficiency of citrus red mite, effective dose and to the safety of mandarin tree.Trial crops is oranges and tangerines, the controlling object citrus red mite (
Panonychus citri Me Gregor).Test medicine and dosage are 6000 times, 7000 times, 8000 times of 30% second mite azoles Bifenazate suspending agents, 5000 times of 110 grams per liter second mite azole suspending agents, 2000 times of 43% Bifenazate suspending agents.Adopt conventional spray-on process, investigation insect population radix before the dispenser, 3d, 7d, 14d, 30d, 45d investigate residual borer population alive respectively behind the medicine, 2 strains are looked in every sub-district during investigation, and every strain is looked into 5 leaves respectively by 4 orientation, the four corners of the world, and every sub-district is looked into 40 leaves altogether, record mite number alive carries out the control efficiency statistics.
Table 9 30% second mite azoles Bifenazate suspending agent control citrus red mite result of the test
Table 9 for behind the medicine the 7th day the time each sub-district preventive effect carry out the biostatistics analysis, analysis result shows: handle differences and reach extremely outstanding level, district's group difference is not remarkable.Significance of difference comparative result shows: consistent with the significance of difference on 0.01 level on 0.05 level, 30% second mite azoles Bifenazate suspending agent is respectively handled differences with other for 6000 times, 7000 times and is all reached utmost point significance level, 8000 times of 30% second mite azoles Bifenazate suspending agents and 5000 times of contrast medicament 110 grams per liter second mite azole suspending agents, 2000 times of 3 processing of 43% Bifenazate suspending agent, differences is not remarkable in twos.
Field trial shows: 30% second mite azoles Bifenazate suspending agent has than remarkable prevention effect citrus red mite, its 6000 times, 7000 times control efficiency obviously is better than contrasting the control efficiency of medicament 110 5000 times of grams per liter second mite azole suspending agents, 2000 times of 43% Bifenazate suspending agents, its the 8000 times control efficiency with 5000 times of 110 grams per liter second mite azole suspending agents are suitable substantially, after result of the test shows that second mite azoles and Bifenazate are mixed, obviously improved control efficiency to citrus red mite, greatly reduce dosage, to mandarin tree growth safety.
Biological Examples 4: control cotton red spider field trial
Carried out the field control effectiveness test of 45% second mite azoles Bifenazate (5+40) the suspending agent control cotton red spider of example of formulations 5 in the solid town of Shaanxi Province's Weinan City, verified that this medicament is to the control efficiency of cotton red spider, effective dose and to the safety of cotton.Trial crops is a cotton, controlling object cotton red spider (Tetranychuscinnabarinus (Boisduval)).Test medicine and dosage are 4000 times, 5000 times, 6000 times of 45% second mite azoles Bifenazate suspending agents, 5000 times of 110 grams per liter second mite azole suspending agents, 2000 times of 43% Bifenazate suspending agents.Adopt conventional spray-on process.Investigation insect population radix before the dispenser, 3d, 7d, 14d, 30d investigate residual borer population alive respectively behind the medicine, 5 samplings in every sub-district during investigation, fix the investigation of 2 strain cottons at every, every strain fixedly upper blade has 5, the two spotted spider mite number on the investigation fixed blade, record mite number alive carries out the control efficiency statistics.
Table 10 45% second mite azoles Bifenazate suspending agent control cotton red spider result of the test
Table 10 for behind the medicine the 7th day the time each sub-district preventive effect carry out the biostatistics analysis, analysis result shows: handle differences and reach extremely outstanding level, district's group difference is not remarkable.Significance of difference comparative result shows: consistent with the significance of difference on 0.01 level on 0.05 level, 45% 4000 times, 5000 times, 6000 times processing of second mite azoles Bifenazate suspending agent and other are respectively handled differences and are all reached utmost point significance level; 2000 times of processing of 110 5000 times of processing of grams per liter second mite azole suspending agent and 43% Bifenazate suspending agent differences is not remarkable.
Field trial shows: 45% second mite azoles Bifenazate suspending agent has remarkable prevention effect to cotton red spider, its 4000 times, 5000 times, 6000 times control efficiency obviously is better than contrasting the control efficiency of medicament 110 5000 times of grams per liter second mite azole suspending agents, 2000 times of 43% Bifenazate suspending agents, after result of the test shows that second mite azoles and Bifenazate are mixed, obviously improved control efficiency to cotton red spider, greatly reduce dosage, to cotton growth safety.
In sum, composition of the present invention is to adopt two kinds of active component compound schemes, its activity and miticidal effect are not the simple superposition of each composition activity, compare with existing unitary agent, except having significant miticidal effect, and significant synergistic effect arranged, quick-acting height, lasting effect are long, slow down the generation of resistance, and be good to crop safety, dosage reduces, and meets the security requirement of agricultural chemicals preparation.
Claims (8)
1. miticide composition that contains second mite azoles and Bifenazate is characterized in that comprising:
A) the first active component second mite azoles;
B) the second active component Bifenazate;
The weight ratio of first active component and second active component is (30:1)～(1:60).
2. the miticide composition that contains second mite azoles and Bifenazate according to claim 1 is characterized in that: the weight ratio of first active component and second active component is (10:1)～(1:25).
3. the miticide composition that contains second mite azoles and Bifenazate according to claim 2, the weight ratio that it is characterized in that first active component and second active component is (3:1)～(1:16).
4. according to one of any described miticide composition that contains second mite azoles and Bifenazate of claim 1 to 3, it is characterized in that: the cumulant of first active component and second active component is 3%～80% of a described composition total weight.
5. the miticide composition that contains second mite azoles and Bifenazate according to claim 4 is characterized in that: the cumulant of first active component and second active component is 5%～50% of a described composition total weight.
6. according to the described miticide composition that contains second mite azoles and Bifenazate of claim 1, it is characterized in that any formulation that described composition upward allows for agricultural.
7. the miticide composition that contains second mite azoles and Bifenazate according to claim 6 is characterized in that: but described composition is water dispersible granules, suspending agent, wetting powder dispersed oil suspending agent, missible oil, aqueous emulsion or microemulsion.
8. the described miticide composition application in the mite pest on control citrus red mite, European red mite, cotton crop that contains second mite azoles and Bifenazate of claim 1.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201110000058.2A CN101999382B (en) | 2011-01-01 | 2011-01-01 | Mite-killing composition containing etoxazole and bifenazate |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201110000058.2A CN101999382B (en) | 2011-01-01 | 2011-01-01 | Mite-killing composition containing etoxazole and bifenazate |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101999382A true CN101999382A (en) | 2011-04-06 |
| CN101999382B CN101999382B (en) | 2014-03-19 |
Family
ID=43807271
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201110000058.2A Active CN101999382B (en) | 2011-01-01 | 2011-01-01 | Mite-killing composition containing etoxazole and bifenazate |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101999382B (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103906430A (en) * | 2011-11-04 | 2014-07-02 | 住友化学株式会社 | Aqueous agrochemical suspension composition and aqueous agrochemical suspension formulation |
| CN103907630A (en) * | 2012-12-29 | 2014-07-09 | 陕西汤普森生物科技有限公司 | Pyriminostrobin-containing acaricidal composition |
| CN104054732A (en) * | 2014-06-25 | 2014-09-24 | 陕西省蒲城美尔果农化有限责任公司 | Agricultural acaricide and water suspension composition |
| CN105613542A (en) * | 2016-01-19 | 2016-06-01 | 新疆锦华农药有限公司 | Synergistic acaricidal composition containing etoxazole and bifenazate |
| CN107136062A (en) * | 2017-06-16 | 2017-09-08 | 桂林集琦生化有限公司 | A kind of agricultural synergist and Bifenazate, the mixture of etoxazole compound mixture and its preparation and application |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2000297003A (en) * | 1999-04-15 | 2000-10-24 | Nissan Chem Ind Ltd | Insecticide, miticide and insecticidal or miticidal method |
-
2011
- 2011-01-01 CN CN201110000058.2A patent/CN101999382B/en active Active
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2000297003A (en) * | 1999-04-15 | 2000-10-24 | Nissan Chem Ind Ltd | Insecticide, miticide and insecticidal or miticidal method |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103906430A (en) * | 2011-11-04 | 2014-07-02 | 住友化学株式会社 | Aqueous agrochemical suspension composition and aqueous agrochemical suspension formulation |
| US9000019B2 (en) | 2011-11-04 | 2015-04-07 | Sumitomo Chemical Company, Limted | Aqueous agrochemical suspension composition and aqueous agrochemical suspension formulation |
| CN106305708A (en) * | 2011-11-04 | 2017-01-11 | 住友化学株式会社 | Aqueous agrochemical suspension composition and aqueous agrochemical suspension formulation |
| CN103907630A (en) * | 2012-12-29 | 2014-07-09 | 陕西汤普森生物科技有限公司 | Pyriminostrobin-containing acaricidal composition |
| CN103907630B (en) * | 2012-12-29 | 2016-05-25 | 陕西汤普森生物科技有限公司 | A kind of miticide composition containing phonetic mite amine |
| CN104054732A (en) * | 2014-06-25 | 2014-09-24 | 陕西省蒲城美尔果农化有限责任公司 | Agricultural acaricide and water suspension composition |
| CN104054732B (en) * | 2014-06-25 | 2016-05-11 | 陕西省蒲城美尔果农化有限责任公司 | Agricultural acaricides aqueous suspension agent composition |
| CN105613542A (en) * | 2016-01-19 | 2016-06-01 | 新疆锦华农药有限公司 | Synergistic acaricidal composition containing etoxazole and bifenazate |
| CN107136062A (en) * | 2017-06-16 | 2017-09-08 | 桂林集琦生化有限公司 | A kind of agricultural synergist and Bifenazate, the mixture of etoxazole compound mixture and its preparation and application |
| CN107136062B (en) * | 2017-06-16 | 2020-10-16 | 桂林集琦生化有限公司 | Mixture prepared by blending agricultural synergist, bifenazate and etoxazole compound and preparation and application thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN101999382B (en) | 2014-03-19 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101669508B (en) | Bifenazate-containing insecticide composition | |
| CN103548879B (en) | Insecticidal composition containing pyriminostrobin | |
| CN102017978B (en) | Pesticidal composition containing Sulfoxaflor and butene-fipronil | |
| CN101697728B (en) | Acaricide compound containing biphenyl hydrazine ester | |
| CN101999382B (en) | Mite-killing composition containing etoxazole and bifenazate | |
| CN103271073B (en) | Insecticidal composition containing epoxy worm moiety and buprofezin | |
| CN102017960B (en) | Acaricidal composition containing etoxazole and pyridaben | |
| CN102293208B (en) | Pesticide composition containing cycloxaprid and buprofezin | |
| CN102405914B (en) | Synergistic mite killing composition containing cyflumetofen and clofentezine | |
| CN103271074B (en) | Insecticide composition containing cycolxylidin and pymetrozine | |
| CN101743981A (en) | Insecticidal composite with paichongding and ethofenprox | |
| CN103493831A (en) | Insecticide composition with insecticides of pyriminostrobin and tetronic acid | |
| CN105707118A (en) | Pesticide composition containing phosmet and bifenazate | |
| CN101642107B (en) | Insect-killing composition containing pymetrozine and etofenprox | |
| CN104814031B (en) | A kind of Pesticidal combination containing butene-fipronil and clothianidin | |
| CN102823606B (en) | Acaricidal composition containing bifenazate | |
| CN104855399A (en) | Insecticidal combination containing butene-fipronil and fluorine benzene worm amide | |
| CN103548863B (en) | Insecticidal composition containing pyriminostrobin and hexythiazox | |
| CN104255751A (en) | Mite-killing composition containing etoxazole and vermectin | |
| CN103329913A (en) | Bifenazate-containing insecticidal composition | |
| CN108124890A (en) | A kind of Pesticidal combination containing jervine | |
| CN103563904B (en) | A kind of miticide composition containing phonetic mite amine and tebufenpyrad | |
| CN103875700A (en) | Insecticidal composition and applications thereof in controlling insects with piercing-sucking mouthpart | |
| CN102007922A (en) | Acaricide composition containing etoxazole and propargite | |
| CN102326583B (en) | Insecticidal composition containing epoxy insect pyridine and organic phosphorus insecticide |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |